Claims
- 1. Process for the preparation of a mixture of .epsilon.-caprolactam, 6-aminocaproic acid and 6-aminocaproic amide by heating an aqueous mixture containing ammonia, 6-aminocaproic amide and lineair and/or cyclic oligomers of 6-aminocaproic acid and/or of 6-aminocaproic amide and optionally 6-aminocaproic acid and/or .epsilon.-caprolactam, characterised in that the aqueous mixture contains 0.5-7 wt. % of equivalent ammonia (calculated as NH.sub.3), 1-20 wt. % of the oligomers, 5-40 wt. % 6-aminocaproic amide, that the concentration of the oligomers and 6-aminocaproic amide and optionally 6-aminocaproic acid and/or .epsilon.-caprolactam in the aqueous mixture is between 10 and 40 wt. % and that the temperature is between 280.degree. C. and 330.degree. C., in which by "equivalent ammonia" is meant free ammonia and ammonia present in the form of a terminal amide group of one of the compounds present in the aqueous mixture.
- 2. Process according to claim 1, characterised in that the aqueous mixture contains less than 3 wt. % of equivalent ammonia.
- 3. Process according to claim 2, characterised in that the aqueous mixture contains between 8 and 20 wt. % 6-aminocaproic amide.
- 4. Process for the preparation of .epsilon.-caprolactam, according to which .epsilon.-caprolactam is separated from the aqueous reaction mixture obtained according to the process according to any one of claims 1-3 and according to which the thus obtained .epsilon.-caprolactam-poor mixture, which mixture contains at least an amount of non-converted oligomers, 6-aminocaproic acid and 6-aminocaproic amide, is reused in the process according to any one of claims 1-3.
- 5. Process according to claim 4, characterized in that the separation of .epsilon.-caprolactam is performed by extraction using an organic extraction agent.
- 6. Process according to claim 5, characterized in that the extraction agent is a (poly)alcohol having 5-12 carbon atoms.
Priority Claims (1)
Number |
Date |
Country |
Kind |
1002429 |
Feb 1996 |
NLX |
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Parent Case Info
This is a Continuation of: International Appln. No. PCT/NL97/00057 filed Feb. 12,1997 which designated the U.S.
US Referenced Citations (4)
Non-Patent Literature Citations (1)
Entry |
Abstract JP 47010715, Mar. 30, 1972. |
Continuations (1)
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Number |
Date |
Country |
Parent |
PCTNL9700057 |
Feb 1997 |
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