Claims
- 1. A process for the preparation of a chlorinated isobutylene-multiolefin copolymer having a multiolefin unit containing 4 to 6 carbon atoms, which comprises contacting a chlorinating agent with a solution of an isobutylene-multiolefin copolymer composed of 80 to 99.5 mol percent of isobutylene units and 20 to 0.5 mol percent of the multiolefin units in an inert organic solvent at a temperature of 0.degree. to 100.degree.C. and in the presence of 0.01 to 10 parts by weight per 100 parts by weight of the copolymer of an aliphatic diamine derivative of the formula ##EQU6## wherein X is an aliphatic hydrocarbon residue of 2 - 6 carbon atoms, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are each a member selected from the group of hydrogen and an alkyl group of 1 - 3 carbon atoms, any two of which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 taken together may form an aliphatic hydrocarbon residue of 2 - 6 carbon atoms, said chlorination reaction being carried out to such an extent that from 1.5 to 1.9 chlorine atoms per double bond contained in the copoloymer are introduced into the copolymer.
- 2. The process of claim 1, wherein said copolymer comprises 90 to 99.5 mol percent of isobutylene units and 10 to 0.5 mol percent of isoprene units.
- 3. The process of claim 1, wherein the amount of said aliphatic diamine derivative is 0.05 to 2 parts by weight per 100 parts by weight of said copolymer.
- 4. The process of claim 1, wherein said diamine derivative is expressed by the following formula (1-a) ##EQU7## wherein X is an aliphatic hydrocarbon residue having 2 to 6 carbon atoms, each of R.sub.1 ', R.sub.2 ', R.sub.3 ' and R.sub.4 ' is a hydrogen atom or a monovalent aliphatic hydrocarbon residue of 1 to 3 carbon atoms, and these groups may be the same or different.
- 5. The process one of claim 1 wherein said diamine derivative is expressed by the following formula (1-b) ##EQU8## wherein X and X' each represent an aliphatic hydrocarbon residue of 2 to 6 carbon atoms and may be the same or different, and R.sub.2 ' and R.sub.4 ' each represent a hydrogen atom or a monovalent hydrocarbon residue of 1 to 3 carbon atoms and may be the same or different.
- 6. The process one of claim 1 wherein said diamine derivative is expressed by the following formula (1-c) ##EQU9## wherein each of X, X' and X" is a divalent aliphatic hydrocarbon residue having 2 to 6 carbon atoms and these groups may be the same or different.
- 7. The process of claim 1, wherein said organic solvent is selected from the group consisting of inert hydrocarbons and inert halogenated hydrocarbons.
- 8. The process of claim 1 wherein the chlorination is carried out at 20.degree. to 80.degree.C.
Parent Case Info
This is a continuation, of application Ser. No. 257,865, filed May 30, 1972.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
3779979 |
Tsuchiya |
Dec 1973 |
|
Foreign Referenced Citations (1)
Number |
Date |
Country |
1,150,815 |
Jun 1963 |
DT |
Continuations (1)
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Number |
Date |
Country |
Parent |
257865 |
May 1972 |
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