Claims
- 1. A process for the preparation of a polyglycidamide represented by the formula Y(R).sub.m, wherein Y is a nucleus selected from the group consisting of ##STR6## wherein R is selected from the group consisting of: ##STR7## wherein R.sub.1 is a C.sub.1 to C.sub.10, linear or branched or cyclic, saturated or unsaturated or epoxidized, divalent hydrocarbyl radical; wherein R.sub.2 is H, or a C.sub.1 to C.sub.10, linear or branched or cyclic, saturated or unsaturated or epoxidized aromatic or aliphatic, monovalent hydrocarbyl radical but not more than one R.sub.2 per Y nucleus is H; wherein R.sub.3 and R.sub.4 are individually selected form hydrogen and methyl; wherein R.sub.5 is
- (Y(R).sub.m-2 --(CH.sub.2 O).sub.r --CH.sub.2).sub.s --Y(R).sub.m-1 ;
- wherein X is R.sub.2 as defined hereinabove; wherein m is the equivalence of the Y nucleus and is in the range of 4 to 8; wherein n, p, q and r are individually in the range of 0 to 1; wherein the average s is the range of 0 to 2; wherein the average number of A groups per Y nucleus is in the range of 1 to m-1, the average number of B groups per Y nucleus is in the range of 0 to m-2, the average number of C groups per Y nucleus is in the range of 1 to m-1 and wherein the average number of Y nuclei per molecule is in the range of about 1 to about 4 and the average number of C groups per molecule is in the range of about 1.2 to about 10; wherein the process comprises the epoxidation of the precursor acrylamido composition in which the C groups are ##STR8## with a nitrile solution of hydrogen peroxide; wherein the hydrogen peroxide is present in an excess of up to 2.5 equivalents per unsaturated group of the precursor acrylamido composition and wherein the equivalent ratio of nitrile to hydrogen peroxide is in the range of about 3 to about 5.
- 2. The process of claim 1 wherein the excess of hydrogen peroxide is in the range of 2.0 to 2.5 equivalents per unsaturated group of the precursor acrylamido composition.
- 3. The process of claim 2 wherein the nitrile is acetonitrile.
Parent Case Info
This is a division of application Ser. No. 06/606,030, filed May 2, 1984, now U.S. Pat. No. 4,861,881.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
3145207 |
Wohnsiedler |
Aug 1964 |
|
3793321 |
Habermeier |
Feb 1974 |
|
Divisions (1)
|
Number |
Date |
Country |
Parent |
606030 |
May 1984 |
|