Claims
- 1. A process for the preparation of foamed particles of a polyolefin polymer, which comprises
- (a) charging a pressure-resistant reactor with a dispersion consisting essentially of polyolefin particles, a liquid dispersion medium, and a mixture of a volatile organic blowing agent and an additive;
- (b) heating the dispersion such that the polyolefin particles are impregnated with said mixture of volatile blowing agent and additive, said additive being dissolved in said blowing agent and being thereby incorporated into said particles; and subsequently,
- (c) discharging the dispersion through an orifice into a low-pressure space, to effect foaming of the polyolefin particles.
- 2. The process of claim 1, wherein said additive is selected from the group consisting of flame retardants, antistatic agents, and dyes.
- 3. The process of claim 1, wherein said polyolefin is an ethylene-propylene random copolymer containing from 1 to 15% by weight of ethylene.
- 4. The process of claim 1, wherein said blowing agent is selected from the group consisting of ethane, propane, n-butane, i-butane, pentane, hexane, cyclopentane, cyclohexane, trichloromonofluoromethane, dichlorodifluoromethane, dichlorotetrafluoroethane, trichlorotrifluoroethane, dichloromonofluoromethane, methyl chloride, methylene chloride, and ethyl chloride.
- 5. The process of claim 1, wherein said dispersion further consists essentially of a finely divided dispersant and/or a surface-active compound selected from the group consisting of calcium phosphate, basic magnesium carbonate, basic zinc carbonate, calcium carbonate, aluminum oxide, barium sulfate, talc, alkyl benzenesulfonates, alkyl paraffinsulfonates, and ethoxylates.
- 6. The process of claim 1, wherein said polyolefin particles have a mean particle diameter of 0.5 to 5 mm.
- 7. The process of claim 1, wherein said heating is carried out at a temperature of T.sub.m -30 to T.sub.m +10.degree. C., wherein T.sub.m is the melting point of said polyolefin particle.
- 8. The process of claim 1, wherein the additive is a flame retardant.
- 9. The process of claim 1, wherein the additive is an antistatic agent.
- 10. The process of claim 1, wherein the additive is a dye.
- 11. The process of claim 1, wherein the additive penetrates into said particles to a depth dependent on the degree of softening of the polyolefin and the impregnation time.
- 12. The process of claim 1, wherein the additive is a combination of hexabromocyclododecane and dicumyl peroxide.
Priority Claims (1)
Number |
Date |
Country |
Kind |
195 42 734 |
Nov 1995 |
DEX |
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Parent Case Info
This application is a Division of application Ser. No. 08/746,812, filed on Nov. 18, 1996, now abandoned.
US Referenced Citations (15)
Foreign Referenced Citations (3)
Number |
Date |
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0 095 109 |
Nov 1983 |
EPX |
0 323 719 |
Jul 1989 |
EPX |
0 377 186 |
Jul 1990 |
EPX |
Divisions (1)
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Number |
Date |
Country |
Parent |
746812 |
Nov 1996 |
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