Claims
- 1. In a process for the production of catalysts wherein a catalytically effective amount of cobalt is impregnated and dispersed on the outer surface of a particulate porous inorganic oxide support to form a catalyst useful for the conversion of synthesis gas to hydro-carbons, and the support particles are contacted with a spray containing a decomposable compound of cobalt,
- the improvement comprising
- maintaining a bed of the support particles in a fluidized state at temperature ranging from about 50.degree. C. to about 100.degree. C. by contact with a gas at temperature ranging from about 50.degree. C. to about 100.degree. C.,
- spraying the bed of the heated support particles with a liquid in which a cobalt compound is dispersed at flow rate sufficient to provide a ratio between the flow rate of the liquid: flow rate of the fluidizing gas below about 0.6 grams liquid/ft.sup.3 of fluidizing gas to form on the particles a surface layer of cobalt compound in average thickness ranging from about 20 microns to about 250 microns, with the loading of cobalt compound ranging from about 0.01 g/cc to about 0.15 g/cc, calculated as metallic cobalt per packed bulk volume of catalyst.
- 2. The process of claim 1 wherein the ratio of the flow rate of the liquid:flow rate of the fluidizing gas ranges from about 0.3 g/ft.sup.3 to about 0.5 g/ft.sup.3.
- 3. The process of claim 1 wherein the spray liquid contains an additional decomposable promoter metal compound the metal being selected from the group consisting of rhenium, hafnium, zirconium, cerium, thorium, uranium, and mixtures thereof, and cobalt compound is dispersed and impregnated with said additional metal compound as a surface layer on said support, the weight ratio of cobalt:promoter of about 30:1 to about 2:1.
- 4. The process of claim 1 wherein the catalytically active surface layer of the catalyst is of average thickness ranging from about 40 microns to about 150 microns with the cobalt loading ranging from about 0.03 g/cc to about 0.09 g/cc.
- 5. The process of claim 1 wherein the support is comprised of alumina, silica, silica-alumina, titania or admixtures comprised of alumina, silica or titania.
- 6. The process of claim 5 wherein the support is comprised of titania.
- 7. The process of claim 6 wherein the titania has a rutile:anatase weight ratio of at least about 3:2.
- 8. The process of claim 7 wherein the titania has a rutile:anatase weight ratio ranging at least about 3:2 to about 100:1, and higher.
- 9. The process of claim 1 wherein the liquid within which the compound, or compounds, of cobalt is dispersed is water.
- 10. The process of claim 1 wherein the fluidizing gas is air.
- 11. The process of claim 1 wherein the temperature of the fluidizing gas ranges from about 70.degree. C. to about 90.degree. C.
- 12. The process of claim 11 wherein the fluidizing gas is air.
- 13. The process of claim 1 wherein the cobalt compound is converted to cobalt oxide at temperatures below about 500.degree. C.
CROSS REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of U.S. Ser. No. 072,517, now abandoned filed Jul. 13, 1987, which is a continuation-in-part of U.S. Ser. No. 046,649, now abandoned filed May 7, 1987.
US Referenced Citations (9)
Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
72517 |
Jul 1987 |
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Parent |
46649 |
May 1987 |
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