Process for the production of light-colored isocyanates

Abstract

The invention relates to an improved process for the production of isocyanates by the reaction of an amine or a mixture of two or more amines with phosgene, the improvement involving the phosgene containing less than about 100 ppm of sulfur in elemental or bound form. The inventive process yields light-colored isocyanates that are suitable for the production of polyurethanes or their precursors (e.g. prepolymers) without the treatment processes heretofore required.

Description

Claims

1. In an improved process for the production of isocyanates by the reaction of an amine or a mixture of two or more amines with phosgene, the improvement comprising including phosgene containing less than about 100 ppm of sulfur in elemental or bound form.

2. The process according to claim 1, wherein the phosgene contains less than about 60 ppm of sulfur in elemental or bound form.

3. The process according to claim 1, wherein the phosgene contains less than about 20 ppm of sulfur in elemental or bound form.

4. The process according to claim 1, wherein the reaction is carried out in a solvent.

5. The process according to claim 1, wherein the amine is a di- and polyamines of the diphenylmethane series.

6. The process according to claim 1, wherein the amine is toluene diaamine.

7. The process according to claim 1, wherein the amine is hexamethylenediamine or isophoronediamine or diaminodicyclohexylmethane.