Claims
- 1. The process for the production of allyl halide-halohydrinamine copolymers by the following steps:
- (a) admixing an allyl halide and an amine compound in ratio of 1 mol of the amine to 0.5 to 6 mols of the allyl halide with an oxidated silicon compound in the ratio of 1 part by weight of the oxidated silicon compound to 1 to 3 parts by weight of the allyl halide;
- (b) agitating said mixture for 10 to 60 minutes at a temperature between ambient temperature and the boiling point of the reactants;
- (c) adding a halohydrin to said mixture in the ratio of 0.5 to 2 mols of the halohydrin to one mol of the organic amine compound;
- (d) agitating the mixture at a temperature between ambient and 70.degree. C. for 10 to 60 minutes, thereby
- (e) producing a liquid thermosetting resinous product;
- (f) heating the liquid resinous product between 80.degree. C. and 120.degree. C. for 10 to 60 minutes, thereby
- (g) producing a solid or cellular solid resinous product.
- 2. The process of claim 1 wherein the amine is selected from the group consisting of alkylenepolyamines, polyalkylenepolyamines, arylenediamines, alkyleneamines and mixtures thereof.
- 3. The process of claim 1 wherein the allyl halide is selected from the group consisting of allyl chlorine, methyl allyl chloride, allyl bromide, beta-methylallyl bromide and mixtures thereof.
- 4. The process of claim 1 wherein the oxidated silicon compound is selected from the group consisting of silica, hydrated silica, alkali metal silicates, alkaline earth metal silicates, natural occurring silicates containing active silicic acid radicals and mixtures thereof.
- 5. The process of claim 1 wherein the halohydrin is selected from the group consisting of alpha-dichlorohydrin, dibromohydrin, di-iodohydrin, epichlorohydrin, epibromohydrin and mixtures thereof.
- 6. The process of claim 1 wherein water is added in step (a) in the amount of 20% to 200% by weight, percentage based on the weight of the reactants.
- 7. The process of claim 1 wherein water, in the amount of 20% to 300% by weight, percentage based on weight of the reactants, is added in step (e) of claim 1; then said liquid thermosetting resinous product is filtered to remove the oxidated silicon compound.
- 8. The product produced by the process of claim 1.
CROSS-REFFERENCE TO RELATED APPLICATIONS
This Application is a continuation-in-part of my copending Application, Ser. No. 862,020, filed Dec. 19, 1977, which is a continuation-in-part of my copending Application, Ser. No. 757,239, filed Jan. 6, 1977, now U.S. Pat. No. 4,069,391 which is a continuation-in-part of U.S. Patent Application Ser. No. 622,525, filed Oct. 15, 1975, now U.S. Pat. No. 4,020,259.
US Referenced Citations (4)
Non-Patent Literature Citations (1)
Entry |
Chem. Abs., vol. 58-5907(b). |
Continuation in Parts (3)
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Number |
Date |
Country |
Parent |
862020 |
Dec 1977 |
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Parent |
757239 |
Jan 1977 |
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Parent |
622525 |
Oct 1975 |
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