Claims
- 1. A process for separating the ortho, meta and para isomers of chloronitrobenzene from a feed mixture comprising said isomers, which process comprises contacting in a first adsorption stage at adsorption conditions said mixture with an adsorbent comprising a type X or type Y zeolite containing at the exchangeable cationic sites one or more cations selected from the group consisting of Groups IA, IIA and the transition metals of the Periodic Table of Elements, selectively adsorbing the ortho-isomers to the substantial exclusion of the meta and para isomers, recovering high-purity ortho-chloronitrobenzene as a first extract product and said meta and para isomers as a raffinate stream, contacting in a second adsorption stage at adsorption conditions said raffinate stream with an adsorbent selective for either said meta or para isomer and comprising a type X or type Y zeolite containing at the exchangeable cationic sites one or more cations selected from the group consisting of Group IA, IIA and the transition metals of the Periodic Table of Elements, selectively adsorbing said meta or para isomer as the selected isomer, to the substantial exclusion of the non-selected isomer and recovering high-purity selected isomer as a second extract product and high-purity non-selected isomer as a raffinate product.
- 2. The process of claim 1 further characterized in that the adsorbent used in said second adsorption stage is physically the same adsorbent used in said first adsorbent stage.
- 3. The process of claim 1 further characterized in that the adsorbent used in said first adsorption stage is physically distinct from the adsorbent used in the second adsorption stage.
- 4. The process of claim 1 further characterized in that said zeolite in one or both of said adsorption stages, is essentially completely exchanged with potassium.
- 5. The process of claim 1 further characterized in that said zeolite in one or both of said adsorption stages is essentially completely exchanged with calcium.
- 6. The process of claim 1 further characterized in that said zeolite in one or both of said adsorption stages is essentially completely exchanged with cobalt.
- 7. The process of claim 1 including the step of treating the adsorbents containing adsorbed isomers with desorbent material to remove said isomers therefrom as fluid extract streams.
- 8. The process of claim 7 further characterized in that said desorbent material has an average boiling point substantially different from that of the feed mixture.
- 9. The process of claim 8 further characterized in that said desorbent material comprises one compound or a mixture of compounds selected from the group consisting of nitrobenzene, toluene and 1-heptanol.
Parent Case Info
REFERENCE TO PRIOR RELATED APPLICATION
This application is a continuation-in-part of my prior, copending application Ser. No. 14,656 filed Feb. 23, 1979. All of the teachings of this prior application are specifically incorporated herein by reference.
US Referenced Citations (3)
Non-Patent Literature Citations (3)
Entry |
De Rossef et al., "Separation of Pinene Isomers", Chem. Abstracts, vol. 82 (1975) 73245m. |
Chmielowiec et al., "Usefulness of Ion Exchange Resins . . . ", Chem. Abstracts. vol. 85 (1976) 85:136947h. |
Suzuki et al., "Separation of Cresol Isomers", Chem. Abstracts, vol. 85 (1976), 85:77876c. |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
14656 |
Feb 1979 |
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