Claims
- 1. A process for drying gases, comprising the step of passing a water-containing gas stream over a modified silicate-containing material, hereafter termed the absorbent, said absorbent consisting essentially of the primary reaction product from the reaction of a silicate-containing material with at least one reagent selected from the group consisting of silane, borane, and substituted silanes and boranes containing at least one substituent selected from the group consisting of F, Cl, Br and alkyl groups of 1-4 carbon atoms;
- said reaction producing said primary reaction product generally according to the equation ##STR4## wherein X is B or Si, and
- Y is at least one material selected from the group consisting of H, F, Cl, Br, and alkyl groups containing 1 to 4 carbon atoms;
- said gas stream coming into contact with said absorbent as an entering stream and passing from said absorbent as an exit stream;
- water in said gas stream reacting with said absorbent, resulting in the water content of the exiting gas stream being substantially less than the water content of the gas stream entering said absorbent.
- 2. The process according to claim 1, wherein the silicate containing material is chosen from the group consisting of zeolites and silica.
- 3. The process according to claim 1, wherein the silane or borane modifying reagents are selected from the group consisting of monosilane, dimethylsilane, monochloro-trimethylsilane, dichlorodimethylsilane, methyltrichlorosilane, diborane, boron trichloride and boron trifluoride.
- 4. The process according to claim 1, further comprising subjecting said modified silicate-containing material to oxidation after said modifying step.
- 5. The process according to claim 1, wherein hydrochloric acid is the gaseous material to be dried.
- 6. The process according to claim 2 wherein the silicate-containing material is selected from the group consisting of mordenite, clinoptilolite, and silicagel.
- 7. The process according to claim 1 wherein the water to be removed from said gaseous material is tritium oxide.
- 8. The process of claim 1 wherein the water content of said gaseous material is reduced to below 1 ppm as a result of contacting said gaseous material with said modified silicate-containing material.
- 9. The process of claim 1 wherein the silicate-containing material is silica gel and the modifying reagent is BCl.sub.3.
Priority Claims (1)
Number |
Date |
Country |
Kind |
85200678 |
May 1985 |
EPX |
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Parent Case Info
This application is a continuation of application Ser. No. 855,095, filed Apr. 22, 1986, now abandoned.
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3533220 |
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3536521 |
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4178350 |
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Continuations (1)
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Number |
Date |
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Parent |
855095 |
Apr 1986 |
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