Process of preventing junction leakage in field emission devices

Abstract
An apparatus and a method for stabilizing the threshold voltage in an active matrix field emission device. The method includes the formation of radiation-blocking elements between a cathodoluminescent display screen of the FED and semiconductor junctions formed on a baseplate of the FED.
Description




BACKGROUND OF THE INVENTION




1. Field of the Invention




This invention relates generally to stabilizing the threshold voltage active elements in active matrix Field Emission Displays (FEDs).




2. State of the Art




A cold cathode FED uses electron emissions to illuminate a cathodoluminescent screen and generate a visual image. An individual field emission cell typically includes one or more emitter sites formed on a baseplate. The baseplate in active matrix FEDs typically contains the active semiconductor devices (e.g., field effect transistors) that control electron emissions from the emitter sites. The emitter sites may be formed directly on a baseplate formed of a material such as silicon or on an interlevel conductive layer (e.g., polysilicon) or interlevel insulating layer (e.g., silicon dioxide, silicon nitride) formed on the baseplate. A gate electrode structure, or grid, is typically associated with the emitter sites. The emitter sites and grids are connected to an electrical source for establishing a voltage differential to cause a Fowler-Nordheim electron emission from the emitter sites. These electrons strike a display screen having a phosphor coating, releasing the photons that illuminate the screen. A single pixel of the display screen is typically illuminated by one or more emitter sites.




In a gated FED, the grid is separated from the base by an insulating layer. This insulating layer provides support for the grid and prevents the breakdown of the voltage differential between the grid and the baseplate. Individual field emission cells are sometimes referred to as vacuum microelectronic triodes. The triode elements include the cathode (field emitter site), the anode (cathodoluminescent element) and the gate (grid). U.S. Pat. 5,210,472, granted to Stephen L. Casper and Tyler A. Lowrey, entitled “Flat Panel Display In Which Low-Voltage Row and Column Address Signals Control A Much Higher Pixel Activation Voltage,” and incorporated herein by reference, describes a flat panel display that utilizes FEDs.




The quality and sharpness of an illuminated pixel site of the display screen is dependent upon the precise control of the electron emission from the emitter sites that illuminate a particular pixel site. In forming a visual image, such as a number or letter, different groups of emitter sites must be cycled on or off to illuminate the appropriate pixel sites on the display screen. To form a desired image, electron emissions may be initiated in the emitter sites for certain pixel sites while the adjacent pixel sites are held in an off condition. For a sharp image, it is important that those pixel sites required to be isolated remain in an off condition. Thus, shifts in the threshold voltage (V


T


) (the voltage necessary to turn on the transistor for the pixel) are undesirable, and there is difficulty in maintaining the V


T


at a level such that unwanted activation will not occur.




SUMMARY OF THE INVENTION




It is an object of the present invention to provide an improved method of constructing an FED with a light-blocking element that prevents photons generated in the environment and by a display screen of the FED from affecting semiconductor junctions on a baseplate of the FED. It is a still further object of the present invention to provide an improved method of constructing FEDs using an opaque layer that protects semiconductor junctions on a baseplate from light and which may also perform other circuit functions. It is a still further object of the present invention to provide an FED with improved junction leakage characteristics using techniques that are compatible with large-scale semiconductor manufacture. A further object of this invention is to provide a means for protecting the cathode structure of an FED. A still further object of the present invention is to shield transistors and semiconductor junctions of an FED against X-rays and other electromagnetic radiation. Finally, it is still further an object of the present invention to manufacture a high-quality FED display having a long life.




In accordance with the present invention, an improved method of constructing FEDs for flat panel displays and other electronic equipment is provided. The method, generally stated, comprises the formation of radiation-blocking elements between a cathodoluminescent display screen and baseplate of the FED. A light-blocking element protects semiconductor junctions on a substrate of the FED from photons generated in the environment and by the display screen. An X-ray-blocking element prevents damage to the cathode structures from X-rays generated when electrons bombard the phosphor screen. The light-blocking element may be formed as an opaque layer adapted to absorb or reflect light. In addition to protecting the semiconductor junctions from the effects of photons, the opaque layer may serve other circuit functions. The opaque layer, for example, may be patterned to form interlevel connecting lines for circuit components of the FED.




In an illustrative embodiment, the light-blocking element is formed as an opaque, light-absorbing material deposited on a baseplate for the FED. As an example, a metal such as titanium that tends to absorb light can be deposited on the baseplate of an FED. Other suitable opaque materials include insulative light-absorbing materials such as carbon black, impregnated polyamide, manganese oxide and manganese dioxide. Moreover, such a light-absorbing layer may be patterned to cover only the areas of the baseplate that contain semiconductor junctions. The light-blocking element may also be formed of a layer of a material, such as aluminum, adapted to reflect rather than absorb light.




In another embodiment, an X-ray-blocking layer is formed, the layer comprising an X-ray-blocking material disposed between the picture elements and the cathodes. As an example, a metal such as tungsten that has a high atomic number Z and tends to block X-rays may be used in order to prevent, at least partially, X-ray radiation from damaging the cathode structures. Lead, titanium, and other metals, ceramics and compounds that have a high atomic number Z and tend to block X-rays may serve as suitable alternative materials. The X-ray-blocking layer can also be patterned to cover only particular areas that house sensitive cathode structures and semiconductor junctions, and may be formed of layers of more than one type of X-ray-blocking material.




Other objects, advantages and capabilities of the present invention will become more apparent as the description proceeds.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a cross-sectional schematic view of a prior art FED showing a pixel site and portions of adjacent pixel sites;





FIG. 2

is a cross-sectional schematic view of an emitter site for an FED having a light-blocking element formed in accordance with the invention;





FIG. 3

is a perspective view of a cathode structure for an FED having an X-ray-blocking element formed in accordance with the invention;





FIGS. 4A and 4B

are elevational views of a pixel/emission site of an FED; and





FIG. 5

is another elevational view of a pixel/emission site of an FED according to the present invention.











DETAILED DESCRIPTION OF THE INVENTION




It has been found that photons generated by the luminescent display screen, as well as photons present in the environment (e.g. sunshine), cause an emitter site to emit electrons unexpectedly. In some FEDs, P/N junctions can be used to electrically isolate each pixel site an to construct row-column drive circuitry and current regulation circuitry for the pixel operation. During operation of the FED, some of the photons generated at a display screen, as well as photons from the environment, may strike the semiconductor junctions on the substrate. This may affect the junctions by changing their electrical characteristics. In some cases, this may cause unwanted current to pass across the junction. This is one type of junction leakage in an FED that may adversely affect the address or activation of pixel sites and cause stray emissions and consequently a degraded image quality.




In experiments conducted by the inventors, junction leakage currents have been measured in the laboratory as a function of different lighting conditions at the junction. At a voltage of about 50 volts, and depending on the intensity of light directed at a junction, junction leakage may range from picoamps (i.e., 10


−12


amps) for dark conditions, to microamps (i.e., 10


−6


amps) for well-lit conditions. In FEDs, even relatively small leakage currents (i.e., picoamps) will adversely affect the image quality. The treatise entitled “Physics of Semiconducting Devices” by S. M. Sze, copyright 1981 by John Wiley and Sons, Inc., at paragraphs 1.6.1 to 1.6.3, briefly describes the effect of photon energy on semiconductor junctions.




Moreover, it has been found by the inventors that unblocked electromagnetic radiation may damage the semiconductor junctions or the cathode structure. Exposure to photons from the display screen and external environment may change the properties of some junctions on the substrate associated with the emitter sites, causing current flow and the initiation of electron emissions from the emitter sites on the adjacent pixel sites. The electron emissions may cause the adjacent pixel sites to illuminate when a dark background is desired, again causing a degraded or blurry image. In addition to isolation and activation problems, light from the environment and display screen striking junctions on the substrate may cause other problems in addressing and regulating current flow to the emitter sites of the FED cell.




For example, a problem may occur when photons (i.e., light) generated by a light source strike the semiconductor junctions formed in the substrate. Further, photons from an illuminated pixel site may strike the junctions formed at the N-type conductivity regions on the adjacent pixel sites. The photons are capable of passing through the spacers, grid and insulating layer of the FED, because these layers are often formed of materials that are translucent to most wavelenghts of light, such as spacers formed of a translucent polyamide (e.g., kapton or silicon nitride), or an insulative layer may be formed of translucent silicon dioxide, silicon nitride or silicon oxynitride. The grid may also be formed of translucent polysilicon.




U.S. Pat. No. 3,814,968, granted to Nathanson et al., addresses the problem with aluminization deposited on the screen member. However, such an approach does not work for high resolution active matrix FEDs, because cathode voltages are relatively low (e.g., 200 volts), and an aluminum layer formed on the inside surface of the display screen cannot be penetrated by enough electrons emitted at these low voltages. Therefore this approach is not suitable in an active matrix FED.




It is also known in the art to construct FEDs with circuit traces formed of an opaque material, such as chromium, that overlie the semiconductor junctions contained in the FED baseplate. As an example, U.S. Pat. No. 3,970,887, granted to Smith et al., describes such a structure (see FIG.


8


). However, these circuit traces are constructed to conduct signals, and are not specifically adapted for isolating the semiconductor junctions from photon bombardment. Accordingly, most of the junction areas are left exposed to photon emission and the resultant junction leakage.




Another problem which may arise is caused by the presence of X-rays or radiation, often generated when electrons impinge upon the phosphor screen. The term “X-ray” means an electromagnetic radiation which has wavelengths in the range of 0.06 nm to 12.5 nm; visible light has wavelengths in the range of 400 nm to 800 nm. In FEDs, generated X-rays are emitted in virtually all directions. Because of the close proximity of the cathode to the X-ray emitting anode in an FED, it has been found that the cathode structure may be damaged by such exposure. In particular, if a silicon chip is used as a substrate on which the cathode structure is built up, the transistors or semiconductor junctions on the baseplate are susceptible to damage from these X-rays.




Referring now to drawing

FIG. 1

, an example embodiment is shown with a pixel site


10


of a field emission display (FED)


13


and portions of adjacent pixel sites


10


′ on either side. The FED


13


includes a baseplate


11


having a substrate


12


comprising, for example, single crystal P-type silicon. A plurality of emitter sites


14


is formed on an N-type conductivity region


30


of the substrate


12


. The P-type substrate


12


and N-type conductivity region


30


form a P/N junction. This type of junction can be combined with other circuit elements to form electrical devices, such as FEDs, for activating and regulating current flow to the pixel sites


10


and


10


′.




The emitter sites


14


are adapted to emit electrons


28


that are directed at a cathodoluminescent display screen


18


coated with a phosphor material


19


. A gate electrode or grid


20


, separated from the substrate


12


by an insulating layer


23


, surrounds each emitter site


14


. Support structures


24


, also referred to as spacers, are located between the baseplate


11


and the display screen


18


.




An electrical source


26


establishes a voltage differential between the emitter sites


14


and the grid


20


and display screen


18


. The electrons


28


from activated emitter sites


14


generate the emission of photons from the phosphor material contained in the corresponding pixel site


10


of the display screen


18


. To form a particular image, it may be necessary to illuminate pixel site


10


while adjacent pixel sites


10


′ on either side remain dark.




Referring now to drawing

FIG. 2

, an emitter site


40


of an FED is illustrated schematically. The emitter site


40


can be formed with one or more sharpened tips as shown or with one or more sharpened cones, apexes or knife edges. The emitter site


40


is formed on a substrate


36


. In the illustrative embodiment, the substrate


36


is single crystal P-type silicon. Alternately, the emitter site


40


may be formed on another substrate material or on an intermediate layer formed of a glass layer or an insulator-glass composite. In the illustrative embodiment, the emitter site


40


is formed on an N-type conductivity region


58


of the substrate


36


. The N-type conductivity region may be part of a source or drain of an FED transistor that controls the emitter site


40


. The N-type conductivity region


58


and P-type substrate


36


form a semiconductor P/N junction.




Surrounding the emitter site


40


is a gate structure or grid


42


. The grid


42


is separated from the substrate


36


by an insulating layer


44


. The insulating layer


44


includes an etched opening


52


for the emitter site


40


. The grid


42


is connected to conductive lines


60


formed on an interlevel insulating layer


62


. The conductive lines


60


are embedded in an insulating layer and/or passivation layer


66


and are used to control operation of the grid


42


or other circuit components.




A display screen


48


is aligned with the emitter site


40


and includes a phosphor coating


50


in the path of electrons


54


emitted by the emitter site


40


. An electrical source


46


is connected directly or indirectly to the emitter site


40


which functions as a cathode. The electrical source


46


is also connected to the grid


42


and to the display screen


48


which function as an anode.




When a voltage differential is generated by the electrical source


46


between the emitter site


40


, the grid


42


and the display screen


48


, electrons


54


are emitted at the emitter site


40


. These electrons


54


strike the phosphor coating


50


on the display screen


48


. This produces the photons


56


that illuminate the display screen


48


.




For all of the circuit elements described thus far, fabrication processes that are known in the art can be utilized. As an example, U.S. Pat. No. 5,186,670, granted to Doan et al. and incorporated herein by reference, describes suitable processes for forming the substrate


36


, emitter site


40


and grid


42


.




The substrate


36


and grid


42


and their associated circuitry form the baseplate


70


of the FED. The silicon substrate contains semiconductor devices that control the operation of the emitter site


40


. These devices are combined to form row-column drive circuitry, current regulation circuitry, and circuitry for electrically activating or isolating the emitter site


40


. As an example, the previously cited U.S. Pat. No. 5,210,472, granted to Casper et al. and incorporated herein by reference, describes pairs of MOSFETs formed on a silicon substrate and connected in series to emitter sites. One of the series connected MOSFETs is gated by a signal on the row line. The other MOSFET is gated by a signal on the column line.




In accordance with one embodiment of the present invention, a light-blocking layer


64


is formed on the baseplate


70


. The light-blocking layer


64


prevents light from the environment and light generated at the display screen


48


from striking semiconductor junctions, such as the junction formed by the N-type conductivity region


58


, on the substrate


36


. A passivation layer


72


is formed over the light-blocking layer


64


.




The light-blocking layer


64


is formed of a material that is opaque to light. Further, light-blocking layer


64


is, in the alternative, a conductive or an insulative material. In addition, the light-blocking layer


64


is, also in the alternative, either light absorptive or light reflective. Suitable materials include both absorptive materials and reflective materials (for example, titanium or aluminum). Other suitable conductive materials include: aluminum-copper alloys, refractory metals, and refractory metal silicides. In addition, suitable insulative materials include manganese oxide, manganese dioxide or a chemical polymer (for example, carbon black impregnated polyamide). These insulative materials tend to absorb light and can be deposited in a relatively thick layer.




For a light-blocking layer


64


formed of metal, acceptable deposition techniques include: CVD, sputtering, or electron beam deposition (EBD). For a light-blocking layer


64


formed of an insulative material or chemical polymer, acceptable techniques include liquid deposition, and cure processes are used according to some embodiments to form a layer having a desired thickness.




The light-blocking layer


64


is blanket deposited in some embodiments to cover substantially all of the baseplate


70


. Alternatively, light-blocking layer


64


is patterned using a photolithography process, thus protecting predetermined areas on the substrate


36


(i.e., areas occupied by junctions). Furthermore, according to still further embodiments, light-blocking layer


64


is constructed to serve other circuit functions. As an example, in one embodiment, light-blocking layer


64


is patterned to function as an interlevel connector.




An acceptable process sequence for forming an emitter site


40


with the light-blocking layer


64


is as follows:




1. Form electron emitter sites


40


as protuberances, tips, wedges, cones or knife edges by masking and etching the silicon substrate


36


.




2. Form N-type conductivity regions


58


for the emitter sites


40


by patterning and doping a single crystal silicon substrate


36


.




3. Oxidation sharpen the emitter sites


40


using a suitable oxidation process.




4. Form the insulating layer


44


by the conformal deposition of a layer of silicon dioxide. Other insulating materials such as silicon nitride and silicon oxynitride may also be used.




5. Form the grid


42


by deposition of doped polysilicon followed by chemical mechanical planarization (CMP) for self aligning the grid


42


and emitter site


40


. Such a process is detailed in U.S. Pat. No. 5,229,331 to Rolfson et al., incorporated herein by reference. In place of polysilicon, other conductive materials such as chromium, molybdenum and other metals may also be used.




6. Photopattern and dry etch the grid


42


.




7. Form interlevel insulating layer


62


on grid


42


. Form contacts through the insulating layer


62


by photopatterning and etching.




8. Form metal conductive lines


60


for grid connections and other circuitry. Form passivation layer


66


.




9. Form the light-blocking layer


64


. According to some embodiments, for example, for a light-blocking layer formed of titanium or other metal, the light-blocking layer is deposited to a thickness of between about 2000 Å and about 4000 Å. Other materials are deposited to a thickness suitable for that particular material.




10. Photopattern and dry etch the light-blocking layer


64


, passivation layer


66


and insulating layer


62


to open emitter and bond pad connection areas.




11. Form passivation layer


72


on light-blocking layer


64


.




12. Form openings through the passivation layer


72


for the emitter sites


40


.




13. Etch the insulating layer


44


to open the etched opening


52


for the emitter sites


40


. This is accomplished according to one embodiment using photopatterning and wet etching. For silicon emitter sites


40


oxidation sharpened with a layer of silicon dioxide, one suitable wet etchant is diluted HF acid.




14. Continue processing to form spacers and display screen.




Thus the invention provides a method for preventing junction leakage in an FED utilizing a light-blocking element formed on the baseplate of the FED. It is understood that the above process sequence is merely exemplary and may be varied, depending upon differences in the baseplate, emitter site and grid materials and their associated formation technology.




It has also been found that, in addition to visible light, X-rays are emitted by the phosphor, which also contribute to an unstable threshold voltage V


T


. Therefore, referring now to drawing

FIG. 3

, an embodiment of the invention is seen in which an X-ray blocker


110


is disposed between the faceplate


112


and the baseplate


14


′ of an FED


16


. More particularly, in this embodiment, the blocker


110


is disposed adjacent to a grid structure or gate


15


with an aperture


10




a


allowing electrons to pass therethrough. X-rays from faceplate


112


are then blocked from transistor gate


15


.




Referring still to

FIG. 3

, a cathode structure of an example embodiment of the present invention is shown at baseplate


14


′, wherein a silicon wafer provides a P-substrate


14




a


. Two P/N junctions


11




a


and


11




b


are formed by doping two N+ transistors


19




a


and


19




b


into the P-substrate


14




a


. A further conductive layer


17




a


overlays the P/N junctions, so a transistor


19




a


/


19




b


is formed on the substrate. The transistor


19




a


/


19




b


belongs to an active matrix stack useful for controlling so-called cold cathode emission sites. One of the cold cathode emission sites is depicted in drawing

FIG. 3

, comprising an emitter


13




a


formed on N+ region transistor


19




b


. The emitter


13




a


is surrounded by an extraction grid structure


15


. The various conducting layers are separated by insulating layers (not shown in FIG.


3


). The cathode is connected to a negative potential, whereas the extraction grid is connected to a positive potential, as is known to those skilled in this art.




Most materials useful for blocking X-rays have a mass attenuation coefficient which varies as a function of X-ray energy. Also, while two materials may be useful for blocking X-rays, one may absorb more X-rays of lower energy (higher wavelength) while the other material may absorb more for higher energy (lower wavelength) X-rays. Therefore, in some embodiments, multiple X-ray-blocking materials are used to facilitate absorption of X-rays over a broader range of energy levels than could be accomplished with each material individually.




Acceptable X-ray-blocking materials for the present invention extend to any chemical elements or compounds having a high atomic number Z. Tungsten and lead are examples of such materials. Titanium is also a good material for blocking X-rays. Blocking materials, in particular, materials having high atomic numbers Z, are provided according to various embodiments of the invention in the form of metals, oxides, ceramics, etc.




Materials employed for light-blocking are not necessarily good for X-ray blocking. Such limitations in selecting protective materials are overcome, according to the invention, in stacking more than one layer of protective materials, one on top of the other. A further approach contemplated by the present invention is to apply several blocking materials simultaneously, each blocking differing wavelengths of the electromagnetic spectrum (although some overlap is permissible).




As discussed above, in some embodiments, two X-ray-blocking layers are employed. In one such embodiment, the bottom layer blocks the main portion of X-rays produced by the anodes, whereas the top layer of the stack is selected to aid in light-blocking as well as filling the X-ray band gaps in the bottom material. Tungsten as a bottom layer with aluminum as the top layer is one example. However, any other combination or coordination of the location and the blocking ability of a layer is also contemplated by the present invention.




Referring again to the drawing

FIG. 3

embodiment, an aperture


10




a


is shown at the sites of the cold cathode emitters. However, in embodiments using X-ray-blocking materials that are permeable for electron beams, no aperture is used.




Drawing

FIG. 4A

shows a structure similar to the structure shown in drawing

FIG. 2

of U.S. Pat. No. 5,186,670, and this patent has been assigned to the assignee of the present invention and is hereby incorporated by reference. The basic structure of this FED has been described in conjunction with drawing FIG.


3


.

FIG. 4A

also includes a power supply


200


. In addition, a focus ring


22


is established at a distance from the gate


15


. The function of the focus ring


22


is to focus the electron beam


21


onto the faceplate


112


. According to a further embodiment of the present invention, focus ring


22


is made impermeable to X-rays by application of an X-ray-blocking material on, alternatively, the top side


22




a


of focus ring


22


or the bottom side


22




b


of the focus ring


22


, or both. In some embodiments, the X-ray-blocking material comprises a conductor and functions also as the focus ring


22


. Drawing

FIG. 4B

depicts a modification of Drawing

FIG. 4A

, wherein an X-ray protection layer


101


is disposed on top of focus ring


22


.




Referring now to drawing

FIG. 5

, a further embodiment of the present invention is shown in which an insulating layer


100


, X-ray protection layer


101


and blocking layer


102


is disposed between the faceplate


112


and the cathode structure. Layers


101


and


102


are placed adjacent to the gate


15


, separated by an insulating layer


100


. More particularly, the insulating layer


100


and one or more of the layers


101


and


102


are deposited on the stack of the silicon substrate by methods known to those skilled in this art.




Examples of blocking material for X-ray blocker


110


of drawing

FIG. 3

or layers


101


and


102


comprise: tungsten, lead, titanium.




The layers


101


,


102


are also selected according to other requirements necessary for the functioning of the vacuum device according to drawing FIG.


5


. For example, the following materials and combinations may be applied to gate


15


of drawing

FIG. 5

by vapor deposition or direct sputter and etched in the same process as the etching of the cathode in the forming of a self-aligned gate structure (as described in U.S. Pat. 5,372,973, incorporated herein by reference): tungsten, lead, titanium.




The thickness of the blocker


110


or layers


101


,


102


may be determined using the following equation:








I




(X)




/I




0




=e




−μpx








Restated, radiation traversing a layer of substance is reduced in intensity by a constant fraction μ per centimeter. After penetrating to a depth x, the intensity is:








I




(X)




=I




0




e




−μpx








In the above equations, I


o


is the initial intensity, I


(x)


is the intensity after path length x, ρ is the mass density of the element in question, and μ is the mass attenuation coefficient describing the attenuation of radiation as it passes through matter by the above equation. The term μ/ρ is the mass absorption coefficient where ρ is the density of the material. The mass attenuation coefficients to be used are for photons for elements at energies corresponding to the wavelengths of the X-rays (radiation) to be blocked by the blocker


110


or layers


101


,


102


should be used. Since X-rays of differing wavelengths are to be blocked, the calculation is required for the desired energy levels of X-rays to be blocked by the desired material to be used. Further, since thin films of blocking materials are used, mass attenuation coefficients for materials applied in thin films should be used.




According to another aspect of the present invention, a process for making a field emission device is also provided comprising: forming an emitter on a substrate; forming a dielectric layer over the emitter; forming an X-ray- (radiation-) blocking layer over the dielectric; and positioning, in a vacuum, the emitter in opposed relation to a phosphor screen. Examples of acceptable methods for forming the emitter on the substrate are seen in U.S. Pat. Nos. 5,391,259; 5,374,868; 5,358,908; 5,358,601; 5,358,599; 5,329,207; 5,372,973; 4,859,304; and 4,992,137; all of which are incorporated herein by reference.




According to a further embodiment, the forming of an X-ray-blocking layer comprises forming a conductive layer of X-ray material as a grid over the emitter. According to an alternative embodiment, the process further includes the steps of: forming a grid over the dielectric and forming an insulator over the grid, wherein said forming an X-ray-blocking layer comprises forming an X-ray-blocking layer over the insulator. According to a still further embodiment, forming an X-ray-blocking layer further comprises forming a conductive X-ray-blocking layer over the insulator.




According to a still further embodiment, a focus ring is formed over the emitter and forming an X-ray-blocking layer comprises forming an X-ray-blocking layer on a surface of the focus ring between the focus ring and the emitter. According to an alternative embodiment, forming an X-ray-blocking layer comprises forming an X-ray-blocking layer on a surface of the focus ring between the focus ring and the phosphor screen.




According to a still further embodiment of the invention, the light-blocking layer is tied to a fixed potential in relation to the anode or cathode. This fixing of the potential avoids charge build-up on the blocking layer, which would degrade performance of the device.




All of the United States patents cited herein are hereby incorporated by reference as are set forth in their entirety.




While the particular process as herein shown and disclosed in detail is fully capable of obtaining the object and advantages hereinbefore stated, it is to be understood that it is merely illustrative of the example embodiments of the invention and that no limitations are intended to the details of construction or design herein shown other than as mentioned in the appended claims.



Claims
  • 1. A process for making a field emission device having a substrate and a phosphor screen comprising:forming a plurality of emitters on the substrate; forming a dielectric layer surrounding at least one emitter of the plurality of emitters; forming a radiation-blocking layer over at least a portion of the dielectric layer surrounding the at least one emitter of the plurality of emitters, the radiation-blocking layer comprises two layers of X-ray-absorbing material having different gaps in an X-ray-absorbing bandwidth; a first of the two layers of X-ray-absorbing material comprising tungsten and a second of the two layers of X-ray-absorbing material comprises lead; positioning the at least one emitter of the plurality of emitters in an opposed position to the phosphor screen; and forming a vacuum between the at least one emitter of the plurality of emitters and the phosphor screen.
  • 2. The process according to claim 1, wherein the forming a radiation-blocking layer comprises forming an X-ray-absorbing layer.
  • 3. The process according to claim 1, wherein the radiation-blocking layer comprises an X-ray-absorbing material.
  • 4. The process according to claim 3, wherein the radiation-blocking layer comprises a material chosen from a group consisting of: tungsten and lead.
  • 5. The process according to claim 1, wherein the radiation-blocking layer comprises a material from the group consisting of tungsten and lead.
  • 6. The process according to claim 1, wherein the radiation-blocking layer comprises an X-ray-absorbing material.7.A process for making a field emission device having a substrate and a screen comprising:forming at least one emitter on the substrate; forming a dielectric layer over a portion of the substrate located adjacent the at least one emitter; forming a focus ring; forming an X-ray-blocking layer over a portion of the dielectric layer and a portion of the focus ring; positioning the at least one emitter opposite in relation to the screen having a space therebetween; and evacuating the space.
  • 8. A process for making a field emission device comprising:forming at least one emitter for a substrate; forming a dielectric layer over a portion of the substrate located adjacent the at least one emitter; forming a focus ring; forming an X-ray-blocking layer over a portion of the dielectric layer and a portion of the focus ring, the X-ray-blocking layer for blocking radiation having a wavelength in a range of 0.06 to 12.5 nanometers; and positioning the at least one emitter opposite a screen.
  • 9. A process for making a field emission device comprising:forming at least one emitter for a substrate; forming a dielectric layer over a portion of the substrate located adjacent the at least one emitter; forming a focus ring; placing the focus ring above the at least one emitter; forming an X-ray-blocking layer over a portion of the focus ring; and positioning the at least one emitter opposite a screen.
  • 10. A process for making a field emission device comprising:forming at least one emitter for a substrate; forming a dielectric layer over a portion of the substrate located adjacent the at least one emitter; forming a focus ring; placing the focus ring above the at least one emitter; forming an X-ray-blocking layer over at least a portion of the focus ring, the X-ray-blocking layer blocking X-rays having a wavelength in a range of 0.06 to 12.5 nanometers; and positioning the at least one emitter opposite a screen.
  • 11. A process for making a field emission device comprising:forming at least one emitter for a substrate; forming a dielectric layer over a portion of the substrate located adjacent the at least one emitter; forming a focus ring: forming a conductive X-ray-blocking layer over at least a portion of the dielectric layer and a portion of the focus ring; and positioning the at least one emitter opposite a screen.
  • 12. A process for making a field emission device comprising:forming at least one emitter for a substrate; forming a dielectric layer over a portion of the substrate located adjacent the at least one emitter; forming a focus ring; forming a conductive X-ray-blocking layer over the dielectric and a portion of the focus ring, the X-ray-blocking layer for blocking radiation having a wavelength in a range of 0.06 to 12.5 nanometers; and positioning the at least one emitter opposite a screen.
  • 13. A process for making a field emission device comprising:forming at least one emitter for a substrate; forming an insulating layer over a portion of the substrate located adjacent the at least one emitter; forming a focus ring; forming an X-ray-blocking layer over a portion of the insulating layer and a portion of the focus ring; and positioning the at least one emitter opposite a screen.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a divisional of U.S. patent application Ser. No. 09/159,245, filed Sep. 23, 1998, now U.S. Pat. No. 6,417,605 B1, issued Jul. 9, 2002, which is a continuation-in-part of U.S. patent application Ser. No. 08/907,256, filed Aug. 6, 1997, now abandoned, which is a continuation of Ser. No. 08/542,718, filed Oct. 13, 1995, now abandoned, which is a continuation-in-part of Ser. No. 08/307,365, filed Sep. 16, 1994, now abandoned.

GOVERNMENT RIGHTS

This invention was made with Government support under Contract No. DABT63-93-C-0025 awarded to Advanced Research Projects Agency (ARPA). The Government has certain rights in this invention.

US Referenced Citations (59)
Number Name Date Kind
3500102 Crost et al. Mar 1970 A
3814968 Nathanson et al. Jun 1974 A
3883760 Cunningham May 1975 A
3970887 Smith et al. Jul 1976 A
4575765 Hirt Mar 1986 A
4859304 Cathey et al. Aug 1989 A
4874981 Spindt Oct 1989 A
4940916 Borel et al. Jul 1990 A
4992137 Cathey et al. Feb 1991 A
5000208 Ludwig et al. Mar 1991 A
5015912 Spindt et al. May 1991 A
5024722 Cathey Jun 1991 A
5049520 Cathey Sep 1991 A
5090932 Dieumegard et al. Feb 1992 A
5100355 Marcus et al. Mar 1992 A
5141461 Nishimura et al. Aug 1992 A
5151061 Sandhu Sep 1992 A
5162704 Kobori et al. Nov 1992 A
5186670 Doan et al. Feb 1993 A
5191217 Kane et al. Mar 1993 A
5199917 MacDonald et al. Apr 1993 A
5204581 Andreadakis et al. Apr 1993 A
5205770 Lowrey et al. Apr 1993 A
5210472 Casper et al. May 1993 A
5212426 Kane May 1993 A
5219310 Tomo et al. Jun 1993 A
5229331 Doan et al. Jul 1993 A
5229682 Komatsu Jul 1993 A
5232549 Cathey et al. Aug 1993 A
5259799 Doan et al. Nov 1993 A
5283500 Kochanski Feb 1994 A
5329207 Cathey et al. Jul 1994 A
5342477 Cathey Aug 1994 A
5358599 Cathey et al. Oct 1994 A
5358601 Cathey Oct 1994 A
5358908 Reinberg et al. Oct 1994 A
5372973 Doan et al. Dec 1994 A
5374868 Tjaden et al. Dec 1994 A
5391259 Cathey et al. Feb 1995 A
5394006 Liu Feb 1995 A
5448133 Ise Sep 1995 A
5451830 Huang Sep 1995 A
5483118 Nakamoto et al. Jan 1996 A
5500750 Kanbe et al. Mar 1996 A
5620832 Sung et al. Apr 1997 A
5621272 Levine et al. Apr 1997 A
5632664 Scoggan et al. May 1997 A
5633560 Huang May 1997 A
5637023 Itoh et al. Jun 1997 A
5643033 Gnade et al. Jul 1997 A
5643817 Kim et al. Jul 1997 A
5648698 Makishima et al. Jul 1997 A
5648699 Jin et al. Jul 1997 A
5865657 Haven et al. Feb 1999 A
5866979 Cathey et al. Feb 1999 A
5975975 Hofmann et al. Nov 1999 A
6020683 Cathey et al. Feb 2000 A
6186850 Cathey et al. Feb 2001 B1
6398608 Cathey et al. Jun 2002 B1
Foreign Referenced Citations (3)
Number Date Country
2 139 868 Mar 1972 DE
549 133 Jun 1993 EP
1 311 406 Mar 1973 GB
Non-Patent Literature Citations (11)
Entry
Martin J. Berger et al.; “Photon Attenuation Coefficients”; CRC Handbook of Chemistry and Physics; pps. 10-284 and 10-287.
S.M. Sze; “Phonon Spectra and Optical, Thermal, and High-Field Properties of Semiconductors”; Physics of Semiconductor Devices; pps. 38-43.
R. Meyer; “6” Diagonal Microtips Fluorescent Display for T.V. Applications; pps. 374-377.
H.B. Garg et al., “Soft X-Ray Absorption in the Bulk”, X-Ray Absorption in Bulk and Surfaces, Aug. 18-20, 1992, pps. 123-141.
“Physics of Semiconductor Devices,” S.M. Sze., Bell Laboratories, Inc. 1981.
“Vacuum Microelectronics,” Heinz H. Busta, Journal of Micronmechanics and Microengineering, 1992.
Micron Display Technology, Inc., Overview, Micron Technology, Inc., Rev. 2: Oct. 26, 1992.
“The Flat Panel Display Market,” Electronic Trend Publications, 1991.
The Cathode-Ray Tube, Technology, History, and Applications, Peter A. Keller, 1991.
Elements of Physics, A. Smith et al., McGraw-Hill, pp. 618-620.
The Photonics Dictionary™, p. D-125.
Continuations (1)
Number Date Country
Parent 08/542718 Oct 1995 US
Child 08/907256 US
Continuation in Parts (2)
Number Date Country
Parent 08/907256 Aug 1997 US
Child 09/159245 US
Parent 08/307365 Sep 1994 US
Child 08/542718 US