Claims
- 1. A method for decarbonylating an oxygen-containing condensed polycyclic aromatic hydrocarbon having at least one group selected from the group consisting of carbonyl, hydroxyl, and carboxyl which consists essentially of heating said oxygen-containing condensed polycyclic aromatic hydrocarbon at a temperature of from about 500.degree. C to about 900.degree. C under atmospheric pressure in contact with hydrogen and in the absence of a catalyst, to thereby stoichiometrically split off carbon monoxide.
- 2. A method according to claim 1, wherein said oxygen-containing condensed polycyclic aromatic hydrocarbon is prepared by oxidation of the corresponding condensed polycyclic aromatic hydrocarbon.
- 3. A method according to claim 2 wherein said oxygen-containing condensed polycyclic aromatic hydrocarbon is a member selected from a group consisting of naphthoquinone, naphthalenesemiquinone, naphthalenehydroquinone, indenone, anthraquinone, anthracenesemiquinone, anthracenehydroquinone, phenanthrenequinone, phenanthrenesemiquinone, phenanthrenehydroquinone, pyrenequinone, pyrenesemiquinone, pyrenehydroquinone, chrysequinone, chrysenesemiquinone, chrysenehydroquinone and a member selected from the group consisting of those represented by the formula ##STR9##
- 4. A method according to claim 1 wherein said condensed polycyclic aromatic hydrocarbon is a member selected from the group consisting of unsubstituted polycyclic aromatic hydrocarbons and substituted polycyclic aromatic hydrocarbons substituted by one or two alkyl groups having up to 2 carbon atoms, alkylene groups having up to 3 carbon atoms, and an aryl group having up to 6 carbon atoms.
- 5. A method according to claim 2 wherein said condensed polycyclic aromatic hydrocarbon is a member selected from the group consisting of topped crude oil, asphalt, cracked residue, coal tar and brown coal.
- 6. A method for decarbonylating phenanthrenequinone whch consists essentially of heating said phenanthrenequinone at a temperature of about 400.degree. C to 650.degree. C under atmospheric pressure in contact with hydrogen and in the absence of a catalyst, to thereby stoichiometrically split off carbon monoxide.
- 7. A method according to claim 4 wherein said oxygen-containing condensed polycyclic aromatic hydrocarbon is anthraquinone.
- 8. A method according to claim 4 wherein said oxygen-containing condensed polycyclic aromatic hydrocarbon is 1,4-naphthoquinone.
- 9. A method according to claim 2 wherein said condensed polycyclic aromatic hydrocarbon is a member selected from the group consisting of naphthalene, anthracene, phenanthrene, pyrene, chrysene and fluorene.
- 10. The process of claim 1 wherein the oxygen containing condensed polycyclic aromatic hydrocarbon is a composition selected from the group consisting of polycyclic aromatic hydrocarbons having at least one enone group in the rings, polycyclic aromatic hydrocarbons having at least one enol group in the rings and the corresponding dibasic acids and mixtures thereof.
Priority Claims (4)
Number |
Date |
Country |
Kind |
48-69221 |
Jun 1973 |
JA |
|
49-28046 |
Mar 1974 |
JA |
|
49-28541 |
Mar 1974 |
JA |
|
49-28542 |
Mar 1974 |
JA |
|
Parent Case Info
This is a continuation, of application Ser. No. 479,285, filed June 14, 1974 and now abandoned.
US Referenced Citations (10)
Foreign Referenced Citations (7)
Number |
Date |
Country |
1,270,703 |
Jul 1960 |
FR |
1,392,912 |
Apr 1964 |
FR |
348,252 |
May 1931 |
UK |
273,493 |
Jul 1927 |
UK |
397,901 |
Aug 1933 |
UK |
403,708 |
Dec 1933 |
UK |
435,192 |
Sep 1935 |
UK |
Continuations (1)
|
Number |
Date |
Country |
Parent |
479285 |
Jun 1974 |
|