Claims
- 1. A process for the amidation of a material having at least one carboxyl-containing polysaccharide, comprising:
- reacting in a solvent said material having at least one carboxyl-containing polysaccharide with an ammonium donor having the general formula >NH, to convert the carboxyl groups of said carboxyl-containing polysaccharide, into amido groups.
- 2. The process according to claim 1 wherein said solvent is an aqueous medium.
- 3. The process according to claim 1 wherein said ammonium donor is ammonia.
- 4. The process according to claim 1 wherein said ammonium donor compound is an ammonium salt selected from the group consisting of organic and inorganic acids.
- 5. The process according to claim 1 wherein said ammonium donor is a member selected from the group consisting of ammonium acetate and ammonium chloride.
- 6. The process according to claim 1 wherein said ammonium donor is an amine selected from the class consisting of primary and secondary amines.
- 7. The process according to claim 1 wherein said ammonium donor is a diamino compound.
- 8. The process according to claim 1 wherein said ammonium donor is a member selected from the group consisting of amino acids, salts of amino acids and esters of amino acids.
- 9. The process according to claim 1 wherein said ammonium donor is an amino thio compound.
- 10. The process according to claim 1 wherein said ammonium donor is an amino alkyl sulphate.
- 11. The process according to claim 1 wherein said ammonium donor is a member selected from the group consisting of polypeptides and proteins.
- 12. The process according to claim 1 wherein said ammonium donor is the salt of an omega amino acid.
- 13. The process according to claim 12 wherein said omega amino acid is an alkyl hydrochloride ester of an amino acid.
- 14. The process according to claim 1 wherein said ammonium donor is an amino alcohol.
- 15. The process according to claim 1 wherein said ammonium donor is an aminoalkoxyalcohol.
- 16. The process according to claim 1 wherein said ammonium donor is an amide.
- 17. The process according to claim 1 wherein said ammonium donor is selected from the group consisting of: alkylene amide, acrylamide, 2-(2-aminoethoxy), and 1-amino-2-propanol.
- 18. The process according to claim 1 wherein said ammonium donor is a cyclic amino compound.
- 19. The process according to claim 1 wherein said ammonium donor is a member selected from the group consisting of: piperazine, 1,3-diaminopropane, iminobispropylamine, alphaomega-diamine, glucosamine hydrochloride, 2-aminoethyl hydrogen sulfate, beta-alanine, and diethylaminoethylchloride hydrochloride.
- 20. The process according to claim 1 wherein said amidation is for carboxymethyl cellulose, said carboxyl-containing polysaccharide is sodium carboxymethyl cellulose, said ammonium donor is ammonium acetate to convert said carboxymethyl cellulose into cellulose amido ethylethers.
- 21. The process according to claim 20 wherein said amidation is conducted at room temperature in an aqueous medium.
- 22. The process according to claim 21 wherein the reaction is conducted in the presence of sodium cyanoborohydride for at least the last portion of the amidation stage.
- 23. The process according to claim 1 wherein said amidation is for carboxymethyl cellulose, said carboxyl-containing polysaccharide is sodium carboxymethyl cellulose, said ammonium donor is glucosamine-hydrochloride in the presence of an amount of a base equimolar to the amount of glucosamine hydrochloride to convert said carboxymethyl cellulose into 2-amido-2-deoxyglucose derivatives of carboxymethyl cellulose.
- 24. The process according to claim 23 wherein said reaction is conducted in the presence of a reducing agent to convert said carboxymethyl cellulose into 2-amino-2-deoxyglucose derivatives of carboxymethyl cellulose.
- 25. The process according to claim 1 wherein at least a portion of said process is conducted in the presence of a reducing agent to obtain the amine product.
- 26. The process according to claim 25 wherein the reducing agent is sodium cyanoborohydride.
- 27. The process according to claim 25 wherein the reducing agent is a member selected from the group consisting of lithium aluminum hydride, sodium borohydride, sodium hypochlorite and catalytic hydrogenation.
- 28. The process according to claim 1 wherein said process includes the conversion of said amido groups by means of a Hoffman reaction into an amine.
- 29. The process according to claim 1 wherein said carboxyl-containing polysaccharide is a carboxymethylcellulose.
- 30. The process according to claim 1 wherein said carboxyl-containing polysaccharide is xanthan gun.
- 31. The process according to claim 1 wherein the resulting reaction products are quenched with methanol.
Parent Case Info
This is a division of application Ser. No. 07/201,438, filed 06/02/88.
US Referenced Citations (4)
Divisions (1)
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Number |
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201438 |
Jun 1988 |
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