Product release system for atomizing compositions containing hair-keratin-reducing or oxidative active ingredients

Abstract
A product release system for atomizing compositions is described, which has (a) a pressure-resistant packaging, (b) a capillary-containing spray head, and (c) a propellant-containing composition. The atomization occurs using the capillary and the composition contains at least one reactive agent, which is selected from hair-keratin-reducing compounds or is selected from oxidizing agents. The capillary preferably has a diameter of 0.1 to 1 mm and a length of 5 to 100 mm. The spray rate is preferably 0.01 to 5 g/s. The propellant-free composition can, in particular, be gel-like, waxy, non-fluid, or solid and can be used in a method for permanent hair shaping.
Description
EXAMPLES

In the following examples, the individual active ingredient compositions were filled, along with the individually indicated propellants, into a pressure-resistant aerosol can and equipped with a capillary spray system, as can be obtained, for example, under the trade name TRUSPRAY® from Boehringer Ingelheim microParts GmbH. Valve diameters and valve balls of different sizes can be used; however, the following sizes are preferred:


















Valve diameter
 0.5 mm



Valve ball
0.35 mm










Example
Permanent Wave Cream

Active ingredient composition:
















4.0
g
Cetyl/stearyl alcohol (Lanette ® O, Cognis)


1.0
g
Ceteareth-25


0.7
g
Polyquaternium-6


14-18
g
Ammonium thioglycolate, 70%


2.8
g
Ammonia, 25%


3.8
g
Ammonium hydrogen carbonate


0.75
g
Cetyltrimethylammonium chloride


0.4-0.7
g
Scent


balance to 100
g
Water, completely desalinated










optional addition:















1-5 g
Cysteine


1-4 g
2-Mercaptopropionic acid (thiolactic acid)









Viscosity: 1,000- 1,200 mPas (25° C.))


pH value: 8.6


Fill ratios in wt %:















Example
Active ingredient solution
propane/butane 4.8 bar
DME







1A
50

50


1B
60

40


1C
50
50


1D
60
40









The time-consuming application with the brush is no longer necessary. The product can also be of particular good use as a hair root cream for targeted shaping of the hair roots. The product is also particularly well suited for use in conjunction with an aqueous, non-viscous permanent wave lotion for optimum targeting of the structural differences between the hair roots and the hair tips during the permanent wave procedure.


Example 2
Emulsion Fixing Agent For Permanent Wave Cream

Active ingredient composition:
















5
g
Cetyl/stearyl alcohol (Lanette ® O, Cognis)


1.7
g
Ceteareth-25


0.5-1.0
g
Polyquaternium-35


6
g
Hydrogen peroxide, 50%


0.1-0.2
g
p-Acetaminophenol


0.1
g
Disodium hydrogen phosphate


0.1
g
Etidronic acid, 60% in water


0.4-0.7
g
Scent


balance to 100
g
Water, completely desalinated









Viscosity: 400- 1,000 mPas (shear speed 12.9 s-l, 25° C.)


pH value: 2.2- 2.8


Fill ratios in wt %:















Example
Active ingredient solution
propane/butane 4.8 bar
DME







2A
50

50


2B
60

40


2C
50
50


2D
60
40


2E
70
30


2F
70

30









Example 3
Hair Smoothing Cream

Active ingredient composition:
















10
g
Cetyl/stearyl alcohol (Lanette ® O, Cognis)


2
g
Ceteareth-25


3
g
Vaseline


16-18
g
Ammonium thioglycolate, 70%


3
g
Ammonia, 25%


0.4-0.7
g
Scent


balance to 100
g
Water, completely desalinated









Viscosity: 2,000- 3,000 mPas (25° C.)


pH value: 9.0


Fill ratios in wt %:















Example
Active ingredient solution
propane/butane 4.8 bar
DME







3A
50

50


3B
60

40


3C
50
50


3D
60
40


3E
70
30


3F
70

30









Example 4
Cream Fixing For Hair Smoothing Agent

Active ingredient composition:
















11
g
Cetyl/stearyl alcohol (Lanette ® O, Cognis)


2.2
g
Ceteareth-25


3
g
Vaseline


6
g
Hydrogen peroxide, 50%


0.1-0.2
g
Salicylic acid


0.1
g
Disodium hydrogen phosphate


0.1
g
Etidronic acid, 60% in water


0.4-0.7
g
Scent


balance to 100
g
Water, completely desalinated









Viscosity: 4,000-6,000 mPas (shear speed 12.9 sol, 25° C.)


pH value:2.0- 2.6


Fill ratios in wt %:















Example
Active ingredient solution
propane/butane 4.8 bar
DME







4A
50

50


4B
60

40


4C
50
50


4D
60
40


4E
70
30


4F
70

30









The creamy composition of Examples 1 through 4 mean that they are very user-friendly in their application, i.e., they can be sprayed directly and precisely on the parts of the hair to be treated or on the hair roots without requiring any awkward use of the brush.


Example 5
Permanent Wave Gel For Root Perm Touch Up

Active ingredient composition:
















Ammonium thioglycolate (70% aqueous solution)
18.2
g


Ammonia (25% aqueous solution)
2.20
g


Ammonium hydrogen carbonate
3.50
g


Polydimethyldiallyl ammonium chloride
0.2
g


(INCI: Polyquaternium-6)


1,3-Butanediol
1.00
g


1,2-Propylene glycol
1.50
g


Dipropylene glycol monoethyl ether
2.00
g


Urea
3.50
g


Cremophor ® EL (INCI: PEG-35 Castor Oil)
1.50
g


Hydrogenated castor triglyceride polyglycol ether
1.00
g


(INCI: PEG-40 Hydrogenated Castor Oil)


Natrosol ® 250 HHX (INCI: Hydroxyethyl
1.0
g


Cellulose


Perfume oil
0.5
g


Water
balance to 100
g










pH 8.6; viscosity: 2,700 mPas)(Haake visc. VT 550, SV DIN, shear speed 12.9 s−1, 25° C.)


Aerosol fill:


The active ingredient composition is filled with dimethylether in a weight ratio of active ingredient: propellant=50:50 and 60:40.


Treatment of the hair for a root perm touch up:


Spraying gel onto the rolled-up root hair using the product release system, rinsing after an action period (8-15 min), then fixing. Only the root perm is touched up.


Results: New wave and movement in the hair root area; gentle treatment of the middle hair sections and tips, because they are not re-permed. This results in the following: excellent hold and very good combing properties in the hair, convenience and safety for the user due to the drop stability of the wave agent gel, user-friendly application of the thickened permanent wave agent, and the labor-intensive application with the brush no longer needed.


Example 6
Two-Phase Permanent Wave To Even Out Large Structural Differences Of Hair

Active ingredient composition phase 1:
















Ammonium thioglycolate (70% aqueous solution)
12.5
g


Ammonia (25% aqueous solution)
0.8
g


Ammonium hydrogen carbonate
4.0
g


Polydimethyldiallyl ammonium chloride
0.8
g


(INCI: Polyquaternium-6)


Antara ® 430 (INCI: Styrene/VP Copolymer)
0.3
g


1,2-Propylene glycol
1.5
g


Urea
2.0
g


Coconut fatty alcohol, ethoxylated with 8 moles of
1.0
g


ethylene oxide (INCI: Coceth-8)


Hydrogenated castor triglyceride polyglycol ether
1.0
g)


(INCI: PEG-40 Hydrogenated Castor Oil)


Natrosol ® 250 HHX (INCI: Hydroxyethyl
0.25
g


Cellulose


Perfume oil
0.5
g


Water
balance to 100
g










pH 8.2


Active ingredient composition phase 2:
















Ammonium thioglycolate (70% aqueous solution)
18.2
g


Ammonia (25% aqueous solution)
2.20
g


Ammonium hydrogen carbonate
3.50
g


Plydimethyldiallyl ammonium chloride
0.2
g


(INCI: Polyquaternium-6)


1,3-Butanediol
1.00
g


1,2-Propylene glycol
1.50
g


Dipropylene glycol monoethyl ether
2.00
g


Urea
3.50
g


Cremophor ® EL (INCI: PEG-35 Castor Oil)
1.50
g


Hydrogenated castor triglyceride polyglycol ether
1.00
g


(INCI: PEG-40 Hydrogenated castor oil)


Natrosol ® 250 HHX (INCI: Hydroxyethyl
0.9
g


Cellulose


Perfume oil
0.5
g


Water
balance to 100
g










pH 8.6; viscosity: 2,700 mPas (Haake viscometer VT 550, SV DIN, shear speed 12.9s−1, 25° C.) Phase 1 is used as a low-viscosity lotion; phase 2 is filled together with propellant to be used in a product release system according to the invention.


Aerosol filling of phase 2:


The common propellants can be used; dimethylether is preferably used. The active ingredient composition is filled in a weight ratio of active ingredient: propellant=50:50 and 60:40.


The 2-phase use enables evening out of large structural differences in the hair from the hair roots up to the hair tips.


Hair treatment: Application of liquid phase 1 of the wave agent to the rolled-up hair, then spraying thickened phase 2 of the gel to the rolled-up hair roots using the product release system according to the invention, rinsing after an action period (6-15 min), then fixing.


Results: Even wave from the hair roots to the tips, gentle treatment of the hair tips, excellent hold and very good combing properties for the hair; user-friendly application of the thickened permanent wave, agent of phase 2, omission of the otherwise customary and labor-intensive application with the brush.


Example 7
Fixing Gel For Liquid And Thickened Permanent Wave Agent

Active ingredient composition:
















Hydrogen peroxide (50% aqueous solution)
5.0
g


Methacryloyl ethyl trimethyl ammonium chloride
0.7
g


homopolymer (INCI: Polyquaternium-37)


Polysorbate 40
1.0
g


Salicylic acid
0.15
g


Eethylene diamine tetraacetic acid (INCI: EDTA)
0.1
g


1,2-Propylene glycol
1.50
g


Phosphoric acid, 85% aqueous solution
0.1
g


Perfume oil
0.5
g


Water
balance to 100
g










pH 3.5; viscosity: 750 mPa s (Haake viscometer VT 550, SV DIN, 25° C.)


Aerosol fill:


The common propellants can be used; dimethylether is preferably used. The active ingredient composition is filled in a weight ratio of active ingredient: propellant=50:50, 60:40, and 70: 30.


Hair treatment:


Spraying the fixing gel on the rolled-up hair roots with the product release system according to the invention after rinsing out the wave agent, rinsing out after an action period (5-12 min), reapplying the fixing agent to the hair (post-fixing) after unrolling, rinsing out after another action period of 2-5 min.


Advantages: User-friendly application of the thickened fixing agent. The labor-intensive application of the agent with the mixing bowl and brush is no longer necessary.


Example 8
Hair Smoothing Gel

Active ingredient composition:
















Ammonium thioglycolate (70% aqueous solution)
18.2
g


Ammonia (25% aqueous solution)
2.20
g


Ammonium hydrogen carbonate
3.50
g


Polydimethyldiallyl ammonium chloride
0.9
g


(INCI: Polyquaternium-6)


1,2-Propylene glycol
2.50
g


Glycerol
3.00
g


Cremophor ® EL (INCI: PEG-35 Castor Oil)
1.50
g


Hydrogenated castor triglyceride polyglycol ether
1.00
g


(INCI: PEG-40 Hydrogenated Castor Oil)


Natrosol ® 250 HHX (INCI: Hydroxyethyl
1.5
g


Cellulose


Perfume oil
0.5
g


Water
balance to 100
g










pH 9.0; viscosity: 5,100 mPas (Haake visc. VT 550, SV DIN, shear speed 12.9 s−1, 25° C.)


Aerosol fill:


The common propellants can be used; dimethylether is preferably used. The active ingredient composition is filled in a weight ratio of active ingredient: propellant=50:50 and 60 40.


Hair treatment:


Spraying the gel on dry hair with the product release system according to the invention and smoothing the hair with a comb (the comb can also be a part of the applicator), rinsing out after an action period (10 to 30 min), then fixing (action period of the fixing agent is 5 to 12 min); then, if necessary, use of a hot smoothing iron.


Results: Smooth hair with excellent hold and very good combing properties; the product release system according to the invention enables the application of very viscous gel that does not drip off or run onto the scalp; the convenience and safety for the user is therefore significantly improved; user-friendly application of the thickened permanent wave agent; time-consuming application with the brush no longer necessary.


Example 9
Gel Fixing For Hair Smoothing Agent

Active ingredient composition:
















Hydrogen peroxide (50% aqueous solution)
5.0
g


Ammonium acryloyl dimethyltaurate/VP copolymer
1.8
g


Polysorbate 40
1.0
g


Salicylic acid
0.15
g


Ethylene diamine tetraacetic acid (INCI: EDTA)
0.15
g


Glycerol
3.0
g


1,2-Propylene glycol
3.0
g


Phosphoric acid (85% aqueous solution)
0.1
g


Perfume oil
0.5
g


Water
balance to 100
g










pH 3.5; viscosity: 3,550 mPas (Haake viscometer VT 550, SV DIN, shear speed 12.9 s−1, 25° C.)


Aerosol fill:


The common propellants can be used; dimethylether is preferably used. The active ingredient composition is filled in a weight ratio of active ingredient: propellant=50:50, 60:40,and70 :30.


Hair treatment:


Spraying the fixing gel on the smoothed hair with the assistance of the product release system according to the invention after the reduction-agent-containing smoothing agent is rinsed out, rinsing out the fixing gel after an action period (5-12 min), and subsequently, if necessary, use of a hot smoothing iron.


Advantages: The product release system according to the invention enables the application of very viscous oxidizing-agent-containing gel that does not drip off or run off onto the scalp. The convenience and safety for the user is therefore significantly improved. An additional advantage is the user-friendly use of the thickened fixing agent. The time-consuming application with the brush is no longer necessary.


All documents cited in the Detailed Description of the Invention are, in relevant part, incorporated herein by reference; the citation of any document is not to be construed as an admission that it is prior art with respect to the present invention. To the extent that any meaning or definition of a term in this written document conflicts with any meaning or definition of the term in a document incorporated by reference, the meaning or definition assigned to the term in this written document shall govern.


While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this invention.

Claims
  • 1. A product release system for atomizing compositions comprising a pressure-resistant packaging, a spray head comprising a capillary, and a composition comprising a propellant, wherein the atomization occurs using said capillary and wherein said composition comprises at least one reactive agent, which is selected from the group consisting of hair-keratin-reducing compounds, oxidizing agents, and mixtures thereof.
  • 2. A product release system according to claim 1, wherein said composition comprises at least one hair-keratin-reducing compound, which is selected from the group consisting of mercaptoacetic acid, cysteine, thiolactic acid, and salts thereof.
  • 3. A product release system according to claim 1, wherein said hair-keratin-reducing compound is contained in a quantity of from 0.5 to 25 wt % of the composition.
  • 4. A product release system according to claim 1, wherein said composition comprises a disulfide of a hair-keratin-reducing compound.
  • 5. A product release system according to claim 1, wherein said composition further comprises at least one oxidizing agent in a quantity of from 0.1 to 25 wt % of the composition, and wherein said oxidizing agent is selected from the group consisting of hydrogen peroxide, bromates, persulfates, perborates, percarbonates, peroxides, iodates, and mixtures thereof.
  • 6. A product release system according to claim 5, wherein said composition has a pH of between 6 and 9 in the presence of a bromate and a pH value of between 2 and 6 in the absence of a bromate.
  • 7. The product release system according to claim 5, wherein said composition comprises at least one peroxide as said oxidizing agent and additionally comprises at least one peroxide stabilizer.
  • 8. The product release system according to claim 7, comprising said peroxide stabilizer in a quantity of from 0.01 to 2 wt % of the composition and wherein said peroxide stabilizer is selected from the group consisting of dialkali hydrogen phosphates, p-acetamidophenol, oxyquinoline salts, salicylic acid, salts of salicylic acid, 1-hydroxyethane- 1,1-diphosphonic acid, tetrasodium- 1-hydroxyethane- 1,1-diphosphonate, tetrasodium iminodisuccinate, ethylenediamine tetrasodium acetate, N-(4-ethoxyphenyl)acetamide and mixtures thereof.
  • 9. A product release system according to claim 1, wherein said capillary has a diameter of 0.1 to 1 mm and a length of 5 to 100 mm.
  • 10. A product release system according to claim 1, wherein the spray rate is 0.01 to 5 g/s.
  • 11. A product release system according to claim 1, wherein said propellant is selected from the group consisting of propane, butane, dimethyl ether, fluorinated hydrocarbons, and mixtures thereof.
  • 12. A product release system according to claim 1, wherein said composition is non-fluid, gel-like, waxy, emulsion-like, creamy, pasty, or solid.
  • 13. A product release system according to claim 5, wherein said composition comprises at least one thickener or at least one gel-former in a quantity of from 0.01 to 20 wt % of the propellant-free composition.
  • 14. A product release system according to claim 13, wherein said thickener or said gel-former is a thickening polymer, selected from the group consisting of copolymers which are made from at least one first type of monomer and from at least one second type of monomer, wherein said first type of monomer is selected from the group consisting of acrylic acid and methacrylic acid and wherein said second type of monomer is an ethoxylated fatty alcohol acrylic acid ester, crosslinked polyacrylic acid, crosslinked copolymers which are made from at least one first type of monomer, and from at least one second type of monomer, wherein said first type of monomer is selected from the group consisting of acrylic acid and methacrylic acid and wherein said second type of monomer is a C10 to C30 alcohol acrylic acid ester, copolymers made from at least one first type of monomer and from at least one second type of monomer, wherein said first type of monomer is selected from the group consisting of acrylic acid and methacrylic acid and wherein said at least one second type of monomer is an ester of itaconic acid or an ethoxylated fatty alcohol, copolymers from at least one first type of monomer, from at least one second type of monomer and from at least one third type of monomer, wherein said first type of monemer is selected from the group consisting of acrylic acid and methacrylic acid and wherein said at least one second type of monomer is an ester of itaconic acid and ethoxylated C10 to C30 alcohol and wherein said third type of monomer is a C1 to C4 aminoalkyl acrylate, copolymers of two or more monomers selected from the group consisting of acrylic acid, methacrylic acid, acrylic acid esters, and methacrylic acid esters, copolymers of vinyl pyrrolidone and ammonium acryloyl dimethyltaurate, copolymers of ammonium acryloyl dimethyltaurate and at least one second monomer, wherein said second monomer is an ester of methacrylic acid and ethoxylated fatty alcohol, hydroxyethyl cellulose, hydroxypropyl cellulose, hydroxypropyl guar, glyceryl polyacrylate, glycerylpoly methacrylate, ccopolymers of at least one first type of monomer and styrene, wherein said first type of monomer is selected from the group consisting of C2 alkylene, C3 alkylene and C4 alkylene, polyurethanes, hydroxypropyl starch phosphate, polyacrylamide, copolymers of maleic acid anhydride and methyl vinyl ether, wherein said copolymers of maleic acid anhydride is crosslinked with decadiene, locust bean gum, guar gum, xanthan, dehydroxanthan, carrageenan, karaya gum, hydrolyzed corn starch, copolymers of polyethylene oxide, fatty alcohols, and saturated methylene diphenyl diisocyanate.
  • 15. A product release system according claim 1, wherein said composition has a viscosity of at least 200 mPa s, measured at 25° C. and at a shear rate of 12.9 s−1.
  • 16. A product release system according to claim 1, wherein said composition is either a water-in-oil emulsion, or an oil-in-water emulsion, or a microemulsion, and wherein said composition comprises from 0.1 to 30 wt % of the propellant-free composition of at least one emulsifier, from 1 to 20 wt % of the propellant-free composition of at least one hydrophobic material, and water, wherein said hydrophobic material is selected from the group consisting of fatty alcohols, oils, and mixtures thereof.
  • 17. A product release system according to claim 16, wherein said hydrophobic material is selected from the group consiting of silicone oils, mineral oils, isoparaffin oils, paraffin oils, squalane, plant oils, decanol, octanol, octene, dodecanol, dodecenol, decenol, octadienol, dodecadienol, decadienol, oleyl alcohol, eruca alcohol, ricinol alcohol, stearyl alcohol, isostearyl alcohol, cetyl alcohol, lauryl alcohol, myristyl alcohol, arachidyl alcohol, capryl alcohol, caprin alcohol, linoleyl alcohol, linolenyl alcohol, behenyl alcohol, guerbet alcohols, and mixtures thereof.
  • 18. A product release system according to claim 16, wherein said emulsifier is selected from the group consisting of addition products of 2 to 30 mol ethylene oxide to C8 to C22 fatty alcohols, addition products of 1 to 5 mol propylene oxide to C8 to C22 fatty alcohols, addition products of 2 to 30 mol ethylene oxide and 1 to 5 mol propylene oxide to C8 to C22 fatty alcohols, addition products of 2 to 30 mol ethylene oxide to C12 to C22 fatty acids, addition products of 1 to 5 mol propylene oxide to C12 to C22 fatty acids, addition products of 2 to 30 mol ethylene oxide and 1 to 5 mol propylene oxide to C12 to C22 fatty acids, addition products of 2 to 30 mol ethylene oxide alkyl phenols with 8 to 15 C atoms in the alkyl group, addition products of 1 to 5 mol propylene oxide to alkyl phenols with 8 to 15 C atoms in the alkyl group, addition products of 2 to 30 mol ethylene oxide and 1 to 5 mol propylene oxide alkyl phenols with 8 to 15 C atoms in the alkyl group, C12 to C22 fatty acid monoesters of addition products of 1 to 30 mol ethylene oxide to glycerol, C12 to C22 fatty acid diesters of addition products of 1 to 30 mol ethylene oxide to glycerol, addition products of 5 to 60 mol ethylene oxide to castor oil, addition products of 5 to 60 mol ethylene oxide to hydrogenated castor oil, mono-, di-, or triesters of phosphoric acid with addition products of 2 to 30 mol ethylene oxide to C8 to C22 fatty alcohols, esters of saccharose with one or two C8 to C22 fatty acids, esters of sorbitan and one, two, or three C8 to C22 fatty acids and having a degree of ethoxylation of from 4 to 20, polyglyceryl fatty acid esters of one, two, or more C8 to C22 fatty acids with polyglycerol of 2 to 20 glyceryl units, alkylglycosides, C8-22 alkyldimethyl benzyl ammonium compounds, C8-22 alkyltrimethyl ammonium compounds, C8-22 alkyldimethyl hydroxyethyl ammonium compounds, di-(C8-22-alkyl)-dimethyl ammonium compounds, C8-22 alkylpyridinium salts, C8-22 alkylamido ethyl trimethyl ammonium ether sulfates, C8-22 alkylmethyl amine oxides, C8-22 alkyl amino ethyl dimethyl amine oxides, amidoamines, and quatemized amidoamines.
  • 19. A product release system according to claim 1, wherein said composition comprises at least one cationic polymer.
  • 20. A product release system according to claim 19, wherein said cationic polymer comprises cationic groups or groups that can be cationized, and wherein said cationic polymer is contained in said composition in an amount of from 0.01 to 5 wt % of the propellant-free composition, and wherein said cationic polymer is selected from the group consisting of cationic cellulose compounds made from hydroxyethyl cellulose and diallyldimethyl ammonium chloride, cationic cellulose compounds made from hydroxyethyl cellulose and epoxide substituted with trimethyl ammonium, poly(dimethyldiallyl ammonium chloride), copolymers of acrylamide and dimethyldiallyl ammonium chloride, quaternary ammonium polymers, formed by the reaction of diethylsulfate with a copolymer of vinyl pyrrolidone and dimethylaminoethyl methacrylate, quaternary ammonium polymers of methylvinylimidazolium chloride and vinyl pyrrolidone, polyquatemium-35, polymers of trimethyl ammonium ethyl methacrylate chloride, polyquaternium-57, dimethylpolysiloxanes terminally substituted with quaternary ammonium groups, copolymers of vinyl pyrrolidone, dimethylaminopropyl methacrylamide and methacryloylamino propyl lauryl dimethyl ammonium chloride, chitosan, chitosan salts, hydroxyalkyl chitosan, hydroxyalkyl chitosan salts, alkyl hydroxyalkyl chitosans, alkyl hydroxyalkyl chitosan salts, N-hydroxyalkyl chitosan alkyl ether, a copolymer of vinyl caprolactam, vinyl pyrrolidone, dimethylaminoethyl methacrylate, copolymers of vinyl pyrrolidone, copolymers of dimethylaminoethyl methacrylate, vinyl caprolactam, dimethylaminopropylacrylamide, polyesters, formed from at least one monomer, which is a hydroxy acid that is substituted with at least one quaternary ammonium group, oligoesters, formed from at least one monomer, which is a hydroxy acid that is substituted with at least one quaternary ammonium group, and methacryloyl ethyl trimethyl ammonium chloride homopolymer.
  • 21. A product release system according to claim 1, wherein said composition comprises at least one additional active ingredient selected from the group consisting of hair-conditioning materials, hair-setting materials, silicone compounds, light-protection materials, preservatives, pigments, direct-penetrating hair dyes, particle-shaped materials, oxidative hair dye precursor products, and mixtures thereof.
  • 22. A product release system according to claim 21, comprising said active ingredients in a quantity of from 0.01 to 20 wt %, of the propellant-free composition.
  • 23. A two-phase product for permanent hair shaping comprising; (A) a product release system according to claim 1, wherein the composition of the product release system comprises at least one keratin-reducing material and wherein the composition is non-fluid or highly viscous and(B) an additional composition, which comprises at least one keratin-reducing material and is fluid and of a lower viscosity than the composition of product release system (A).
  • 24. A combination product for permanent hair shaping comprising; (A) a first composition, which comprises at least one keratin-reducing material, and(B) a second composition, which comprises at least one oxidizing agent, wherein one or both compositions (A) and (B) are present in the form of a product release system according to claim 1.