The present invention relates to a production method of a reinforced hose, such as a hydraulic hose, used for a fuel path of a pressure fluid and configured to have reinforcing yarn braided on an inner tube rubber layer.
A known method of producing a brake hose used for the automobile, which is included in such reinforced hoses, forms a reinforcing yarn layer on an inner tube rubber layer, additionally forms an outer surface rubber layer on the reinforcing yarn layer and places this layered structure in a sealed vulcanizing vessel to heat and vulcanize the layered structure under a pressure of or over atmospheric pressure, so as to produce the brake hose. The vulcanizing step which is one step of this production method uses the sealed and pressurized vulcanizing vessel and accordingly has low productivity. The technique disclosed in Patent Literature 1 has been proposed to improve the productivity. More specifically, the method of Patent Literature 1 forms a hose intermediate product by braiding a reinforcing yarn layer made of fibers on an inner tube rubber layer, heats the hose intermediate body by radio-frequency heating to coat the outer circumference of the hose intermediate body with an outer surface rubber layer and a cover layer and then causes the coated hose intermediate product to pass through a vulcanizing vessel set under ordinary pressure, so as to continuously vulcanize the coated hose intermediate product. This method continuously vulcanizes the hose intermediate product and accordingly has excellent productivity.
In the application of the above prior art method to a brake hose, however, there is a problem that the outer surface rubber layer and the cover layer are likely to be partly swelled.
PLT 1: JP 3960362B
By taking account such circumstances, an object of the invention is to provide a production method of producing a brake hose without causing any partial well of an outer surface rubber layer with excellent productivity.
In order to achieve at least part of the above object, the present invention may be implemented by the following aspects or embodiments.
According to Aspect 1, there is provided a production method of a reinforced hose having: an inner tube rubber layer; a reinforcing yarn layer formed on braiding a reinforcing yarn on the inner tube rubber layer; and an outer surface rubber layer formed to coat the reinforcing yarn layer. The production method comprises: a step of providing a braided hose body having the reinforcing yarn layer formed on the inner tube rubber layer; and an outer surface rubber forming step of extruding an unvulcanized rubber material on the braided hose body to form the outer surface rubber layer. The outer surface rubber forming step heats the braided hose body such that surface temperature Th of the braided hose body is equal to or higher than 50° C., sets an atmosphere in a region where the braided hose body is to be coated with the rubber material to an atmosphere of a lower pressure than atmospheric pressure, which is equal to or lower than 0.8 atmospheres, and coats the braided hose body with the unvulcanized rubber material under the atmosphere to produce a hose intermediate product.
In the outer surface rubber forming step according to Aspect 1, the braided hose body is heated to or over 50° C. for evaporation and removal of moisture on its surface, before the braided hose body is coated with the unvulcanized rubber material. Additionally, the atmosphere in the region where the braided hose body is to be coated with the unvulcanized rubber material is set to the atmosphere of the reduced pressure to be not greater than 0.8 atmospheres. The braided hose body is coated with the rubber material under this atmosphere. The rubber material accordingly coats the braided hose body without taking in the moisture or the air in the atmosphere of removed moisture and reduced pressure and enters into the depth of even narrow gaps between reinforcing yarns of the braided hose body. This eliminates a potential defect caused by evaporation of the moisture or expansion of the air between the braided hose body and the outer surface rubber layer by the heat in the process of vulcanizing the hose intermediate product having the braided hose body coated with the outer surface rubber material under atmospheric pressure, e.g., a partial swell of the outer surface of the reinforced hose.
According to Aspect 2, there is provided the production method of the reinforced hose, further comprising a step of vulcanizing the hose intermediate product having the braided hose body coated with the outer surface rubber material under atmospheric pressure, after the outer surface rubber forming step.
According to Aspect 3, there is provided the production method of the reinforced hose, wherein when the surface temperature Th of the braided hose body is lower than temperature Tr, a temperature difference between Th and Tr is equal to or less than 10° C., wherein Tr is the temperature of the rubber material during the step of coating the braided hose body with the rubber material.
According to Aspect 4, there is provided the production method of the reinforced hose, wherein the step of heating the braided hose body blows a hot blast onto outer surface of the braided hose body. This method enables the moisture on the braided hose body to be removed efficiently.
According to Aspect 5, there is provided the production method of the reinforced hose, wherein the reinforcing yarn has a product of thickness and number of carriers equal to 40000 to 70000 dtex·carriers. More preferably, the reinforcing yarn has a product of 50000 to 650000 dtex·carriers. The number of carriers herein is expressed by the sum of the number of carriers in an upper yarn layer and the number of carriers in a lower yarn layer, when the reinforcing yarn layer has the upper yarn layer and the lower yarn layer.
According to Aspect 6, there is provided the production method of the reinforced hose, wherein. the reinforcing yarn layer is formed by sequentially stacking a lower yarn layer, an intermediate rubber layer and an upper yarn layer from an inner tube rubber layer side, and the lower yarn layer and the upper yarn layer are formed by using 20 to 24 carriers.
According to Aspect 7, there is provided the production method of the reinforced hose, wherein the reinforcing yarn layer is formed by sequentially stacking a lower yarn layer, an intermediate rubber layer and an upper yarn layer from an inner tube rubber layer side, and the lower yarn layer is formed by using a reinforcing yarn made of polyester yarn having a tensile strength per unit decitex equal to or greater than 6.9 g and an elongation rate of 2.6±1.0% under 2.7 g load.
According to Aspect 8, there is provided the production method of the reinforced hose, wherein a reinforcing yarn of the lower yarn layer is braided at a braid angle of 59±1 degrees relative to an axial direction of the hose.
According to Aspect 9, there is provided the production method of the reinforced hose, wherein the inner tube rubber layer has a thickness of 0.6±0.2 mm.
According to Aspect 10, there is provided the production method of the reinforced hose, wherein the intermediate rubber layer has a thickness of 0.1 to 0.35 mm.
In order to further clarity the configurations and the functions of the present invention described above, the following describes embodiments of the present invention.
The materials, the thicknesses, the braid angles and other conditions of the respective layers are specified to obtain the properties such as the pressure resistance to be resistant against the brake fluid pressure up to 50 MPa, the durability and the expansion resistance.
(2)-1. Inner Tube Rubber Layer 12
The inner tube rubber layer 12 is formed by extrusion molding using, for example, ethylene propylene diene monomer (EPDM) rubber or styrene butadiene rubber (SBR) copolymer to obtain mainly the oil resistance. The inner tube rubber layer 12 has the inner diameter of 3.0 to 3.4 mm and the thickness of 0.4 to 0.8 mm.
(2)-2. Lower Yarn Layer 14
The lower yarn layer 14 is formed by braiding 1100-dtex lower yarn 15 comprised of two-strand or three-strand high modulus PET yarns, on the inner tube rubber layer 12 by 20 carriers or 24 carriers. The high modulus PET yarn is comprised of polyester filament yarns having the tensile strength of not less than 6.9 g per unit decitex and the elongation rate of 2.6±1.0% under 2.7 g load or more preferably polyester filament yarns having the tensile strength of not less than 6.9 g per unit decitex and the elongation rate of 2.6±0.5% under 2.7 g load. The high modulus PET yarn of the lower yarn 15 is formed by bundling 200 to 400 filament yarns. The thickness of the lower yarn layer 14 is 0.55 to 0.95 mm and is preferably 0.65 to 0.85 mm.
(2)-3. Intermediate Rubber Layer 16
The intermediate rubber layer 16 is provided as a layer to prevent misalignment of the lower yarn layer 14 and the upper yarn layer 18 and is formed by extruding a rubber material on the lower yarn layer 14, by winding a sheet material 16A on the lower yarn layer 14 or applying a gum on the lower yarn layer 14. The rubber material used may be, for example, EPDM, isobutylene-isoprene copolymer (IIR) or natural rubber (NR). Using EPDM, IIR, or a blended material thereof enhances the heat resistance, due to their physical properties. The thickness of the intermediate rubber layer 16 is preferably 0.1 to 0.35 mm. More specifically, the intermediate rubber layer 16 of less than 0.1 mm is too thin to be formed on the lower yarn layer 14. The thickness of greater than 0.35 mm, on the other hand, causes the thick intermediate rubber layer 16 to serve as an elastic layer that allows misalignment of the lower yarn layer 14 and reduces the effect of preventing misalignment of the lower yarn layer 14.
(2)-4. Upper Yarn Layer 18
The upper yarn layer 18 is formed by braiding 1700-dtex upper yarn 19 on the intermediate rubber layer 16 by 20 carriers or 24 carriers. The upper yarn 19 is comprised of two-strand or three-strand high modulus PET yarns, each obtained by bundling 200 to 400 filament yarns like the lower yarn 15 and subjected to RFL treatment. Like the lower yarn layer 14, the braid angle of the upper yarn layer 18 is preferably set to 59±1 degrees, in order to reduce the volume expansion. The upper yarn layer 18 is obtained by applying an undercoat layer after bundling the filament yarns and performing RFL treatment. The RFT treatment herein causes the surface of the yarn to he coated with an adhesive thin film that serves as an adhesive mainly consisting of resorcinol formaldehyde latex resin and rubber latex. The lower yarn layer 14 may also be subjected to the RFL treatment. This further enhances the adhesive strength with the intermediate rubber layer 16.
(2)-5. Outer Surface Rubber Layer 20
The outer surface rubber layer 20 is made of, for example, EPDM or a blended material of EPDM and CR, in order to mainly obtain the ozone resistance. The thickness of the outer surface rubber layer 20 is 0.8 to 1.3 mm.
The following describes the production method of the brake hose 10. The brake hose 10 is produced by sequentially performing an inner tube rubber forming step, a reinforcing yarn braiding step, an adhesive applying step, an outer surface rubber forming step and a vulcanizing step. Other steps, for example, a drying step may be added adequately to these steps.
(3)-1. Inner Tube Rubber Forming Step
(3)-2. Reinforcing Yarn Braiding Step
The step of braiding the reinforcing yarn on the rubber tubular body 12A using this apparatus first braids the lower yarn 15 on the rubber tubular body 12A to form the lower yarn layer 14 by the first braiding device 34. The step subsequently winds the sheet material 16A, which is pulled out from the roller to coat the lower yarn layer 14, on the lower yarn layer 14 to form the intermediate rubber layer 16 by the intermediate sheet forming device 35. The step subsequently braids the upper yarn 19 on the intermediate rubber layer 16 to form the upper yarn layer 18 by the second braiding device 36. The braid angle θ of the lower yarn layer 14 and the upper yarn layer 18 is set to 59±1 degrees by the ratio of the pull-out speed of the inner tube rubber layer 12 to the rotation speed of the drum. This step accordingly forms a braided hose body 12B.
(3)-3. Adhesive Applying Step
(3)-4. Outer Surface Rubber Forming Step
The braided hose body 12C is coated with the outer surface rubber layer 20 by the following steps using the devices shown in
(3)-5. Vulcanizing Step
A vulcanizer 60 is heated with a heater (not shown) to be set to an atmosphere of ordinary pressure and a specified temperature. A hose intermediate product 12D is continuously vulcanized by this vulcanizer 60. The vulcanizing conditions may be set to 120 to 250° C. for 5 to 60 minutes. The heating in this vulcanizing step causes the RFL-treated upper yarn layer 18 and the lower yarn layer 14 to adhere to the inner tube rubber layer 12, the intermediate rubber layer 16 and the outer surface rubber layer 20.
A hose 12E is then subjected to a post process, for example, cutting to a specified length. This completes the brake hose 10 shown in
(4)-1. With referring to
In order to check the properties of the brake hose according to the above embodiment, a brake hose 10 having the inner diameter of 3.1 to 3.2 mm and the outer diameter of 10.2 to 10.5 mm was produced. The appearance of the brake hose 10 was visually checked. According to the result of checking, no partial swell was observed on the outer surface rubber layer 20.
The conditions set for the preheating device 40 and the decompression device 45 shown in
(4)-2. It is preferable to set the temperature of the hot air in the preheating process to satisfy the following conditions. With referring to
(4)-3. With referring to
(4)-4. With referring to
(4)-5. The brake hose 10 has the inner tube rubber layer 12, the lower yarn layer 14, the intermediate rubber layer 16 and the upper yarn layer 18 of the following configuration to reduce the volume expansion of the brake hose by the brake fluid pressure and ensure the excellent brake operation feeling in the application of the brake hose mounted on the vehicle. Specifically, the reinforcing yarns of the lower yarn layer 14 and the upper yarn layer 13 are made of the polyester yarns having the tensile strength of not less than 6.9 g per unit decitex and the elongation rate of 2.6±1.0% under 2.7 g load and have the thickness of 1100±100 dtex. The braid angle of the lower yarn layer 14 to the axial direction of the hose is set to 59±1 degrees. The thickness of the inner tube rubber layer 12 is set to 0.6±0.2 mm, and the thickness of the intermediate rubber layer 16 is set to 0.1 to 0.35 mm.
The invention is not limited to the above embodiment, but a diversity of variations and modifications may be made to the embodiment without departing from the scope of the invention. Some examples of possible modification are described below.
In the above embodiment the vulcanizing step vulcanizes the hose intermediate product 12D with continuously conveying the hose intermediate product 12D as shown in
The above embodiment describes the process of heating the braided hose body 12C with the hot air of the preheating device 40 as shown in
The above embodiment describes the production method of the brake hose as an application of the production method of the reinforced hose. This is, however, not restrictive. The production method of the reinforced hose is applicable to any high-pressure hose, for example, a hose for power steering of the automobile and a hydraulic hose for construction machines.
Number | Date | Country | Kind |
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2012-75460 | Mar 2012 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2013/001437 | 3/7/2013 | WO | 00 |