Claims
- 1. A process for the preparation of an unsubstituted cyclic ether which comprises reacting an unsubstituted alkanediol in which the hydroxyl groups are separated by a chain of at least four carbon atoms in the liquid phase, in a molecular oxygen gaseous atmosphere, at a temperature of from about 150.degree. C. to 300.degree. C. in the presence of a catalytic amount of a catalyst comprising about 0.45 to 0.71 grams of palladium in a palladium salt, about 0.30 to 1.2 grams of copper in a copper salt and about 0.30 to 1.1 grams of chloride ion, all per mole of alkanediol.
- 2. A process as recited in claim 1 in which the palladium salt is palladium chloride.
- 3. A process as recited in claim 2 in which the copper salt is selected from the group consisting of cupric chloride, cupric nitrate and mixtures thereof.
- 4. A process as recited in claim 1 in which the catalyst concentration in the reaction mixture is in the range from about 0.1 to 1% by weight thereof.
- 5. A process for the preparation of an unsubstituted cyclic ether which comprises reacting an unsubstituted alkanediol selected from the group consisting of 1,4-butanediol, 1,5-pentanediol, and 1,6-hexanediol in the liquid phase, in a molecular oxygen gaseous atmosphere, at a temperature of from about 150.degree. C. to 300.degree. C. in the presence of a catalytic amount of a catalyst comprising about 0.45 to 0.71 grams of palladium in a palladium salt, about 0.30 to 1.2 grams of copper in a copper salt and about 0.30 to 1.1 grams of chloride ion, all per mole of alkanediol.
- 6. A process as recited in claim 5 in which the palladium salt is palladium chloride.
- 7. A process as recited in claim 6 in which the copper salt is selected from the group consisting of cupric chloride, cupric nitrate and mixtures thereof.
- 8. A process as recited in claim 5 in which the catalyst concentration in the reaction mixture is in the range from about 0.1 to 1% by weight thereof.
- 9. A process for the preparation of tetrahydrofuran which comprises reacting 1,4-butanediol in the liquid phase, in a molecular oxygen gaseous atmosphere, at a temperature of from about 150.degree. C. to 300.degree. C. in the presence of a catalytic amount of a catalyst comprising palladium chloride and a copper salt wherein palladium is present in an amount of about 0.45 to 0.71 grams, copper is present in an amount of about 0.30 to 1.2 grams and chloride is present in an amount of about 0.30 to 1.1 grams, all per mole of butanediol.
- 10. A process as recited in claim 9 in which the copper salt is cupric chloride, cupric nitrate or a mixture thereof.
- 11. A process for the preparation of tetrahydropyran which comprises reacting 1,5-pentanediol in the liquid phase, in a molecular oxygen gaseous atmosphere, at a temperature of from about 150.degree. C. to 300.degree. C. in the presence of a catalytic amount of a catalyst comprising palladium chloride and a copper salt wherein palladium is present in an amount of about 0.45 to 0.71 grams, copper is present in an amount of about 0.30 to 1.2 grams and chloride is present in an amount of about 0.30 to 1.1 grams, all per mole of butanediol.
- 12. A process as recited in claim 11 in which the copper salt is cupric chloride, cupric nitrate or a mixture thereof.
- 13. A process for the preparation of 2,5-dimethyltetrahydrofuran which comprises reacting 2,5-hexanediol in the liquid phase, in a molecular oxygen gaseous atmosphere, at a temperature of from about 150.degree. C. to 300.degree. C. in the presence of a catalytic amount of a catalyst comprising palladium chloride and a copper salt wherein palladium is present in an amount of about 0.45 to 0.71 grams, copper is present in an amount of about 0.30 to 1.2 grams and chloride is present in an amount of about 0.30 to 1.1 grams, all per mole of butanediol.
- 14. A process as recited in claim 13 in which the copper salt is cupric chloride, cupric nitrate or a mixture thereof.
- 15. A process for the preparation of 2,2,5,5-tetramethyldihydrofuran which comprises reacting 2,5-dimethylhexane-2,5-diol in the liquid phase, in a molecular oxygen gaseous atmosphere, at a temperature of from about 150.degree. C. to 300.degree. C. in the presence of a catalytic amount of a catalyst comprising palladium chloride and a copper salt wherein palladium is present in an amount of about 0.45 to 0.71 grams, copper is present in an amount of about 0.30 to 1.2 grams and chloride is present in an amount of about 0.30 to 1.1 grams, all per mole of butanediol.
- 16. A process as recited in claim 15 in which the copper salt is cupric chloride, cupric nitrate or a mixture thereof.
- 17. A process according to claim 1, wherein said chloride ion is the anion of said palladium or copper salt.
- 18. A process according to claim 1, wherein said chloride ion is supplied as the anion of a salt other than said palladium and copper salt.
Parent Case Info
This application is a Continuation-in-Part of copending application Ser. No. 816,941, filed on July 19, 1977, now abandoned.
Non-Patent Literature Citations (2)
Entry |
M. Bartok et al., Acta Physica et Chemica, vol. 18, (1972), No. 3-4, pp. 207-211. |
W. G. Lloyd, Jour. Org. Chem., (1967), pp. 2816-2819, vol. 32. |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
816941 |
Jul 1977 |
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