Claims
- 1. A process for the carbonylation of reactants selected from the group consisting of tetrahydrofuran and non-vicinal acyclic glycols wherein the hydroxyl groups are on different carbon atoms and there are from 3 to 20 carbon atoms in the glycol, said process comprising contacting
- 1. at least one of said reactants,
- 2. carbon monoxide, and
- 3. a catalyst system consisting essentially of
- a. a metal compound selected from the group consisting of rhodium compounds, and iridium compounds and
- b. a halogen component which is bromine, iodine, a bromide compound or an iodide compound, wherein during said contacting, said metal compound and said halogen component are present in an amount sufficient to catalyze the carbonylation of said reactants, said contacting being carried out at a temperature in the range of 125.degree. C to 250.degree. C.
- 2. The process of claim 1 wherein said metal compound of 3(a) is dispersed upon an inert solid support.
- 3. The process of claim 2 wherein at least one of said reactants is 1,4-butanediol.
- 4. The process of claim 2 wherein said carbonylation is carried out in the vapor phase.
- 5. The process of claim 4 wherein said metal compound of 3(a) is an iridium compound.
- 6. The process of claim 4 wherein said metal compound of 3(a) is a rhodium compound.
- 7. The process of claim 1 wherein said contacting is also in the presence of water.
- 8. The process of claim 7 wherein at least a portion of said halogen component of 3(b) is provided by hydrogen iodide, hydrogen bromide, methyl iodide or methyl bromide.
- 9. The process of claim 7 wherein said metal compound of 3(a) is provided by a material selected from the group consisting of iridium salts, rhodium salts, iridium oxides, rhodium oxides, iridium carbonyls consisting only of iridium and carbonyl moieties and rhodium carbonyls consisting only of rhodium and carbonyl moieties.
- 10. The process of claim 7 wherein at least one of said reactants is 1,4-butanediol.
- 11. The process of claim 7 wherein said halogen component of 3(b) is provided by iodine or an iodide compound and said iodine or iodide compound is present in an amount such as to produce an iodine to iridium or an iodine to rhodium atomic ratio in the range of 1:1 to 2500:1.
- 12. The process of claim 11 wherein said metal compound of 3(a) is dispersed upon an inert solid support.
- 13. The process of claim 12 wherein said carbonylation is carried out with said reactants in the vapor phase.
- 14. The process of claim 7 wherein said metal compound of 3(a) and said halogen component of 3(b) are present in a liquid reaction medium.
- 15. The process of claim 14 wherein said metal compound of 3(a) is an iridium compound.
- 16. The process of claim 15 wherein the halogen component of 3(b) is present in an amount of from 1:1 to 2500:1 atoms of halogen per atom of iridium.
- 17. The process of claim 16 wherein said halogen component of 3(b) is iodine or an iodide compound.
- 18. The process of claim 14 wherein said metal compound of 3(a) is a rhodium compound.
- 19. The process of claim 18 wherein the halogen component 3(b) is present in an amount of from 1:1 to 2500:1 atoms of halogen per atom of rhodium.
- 20. The process of claim 19 wherein said halogen component of 3(b) is iodine or an iodide compound.
- 21. The process of claim 20 wherein at least one of said reactants is 1,4-butanediol.
Parent Case Info
This is a continuation, of application Ser. No. 752,762, filed Aug. 15, 1968, now abandoned, which was a continuation-in-part of appln. Ser. No. 628,581, filed Apr. 5, 1967, now abandoned.
US Referenced Citations (6)
Continuations (1)
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Number |
Date |
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Parent |
752762 |
Aug 1968 |
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Continuation in Parts (1)
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Number |
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628581 |
Apr 1967 |
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