Promoted amines catalysis

Abstract

This invention relates to a process for making amines by condensing an amino compound in the presence of a condensation catalyst and a condensation catalyst promoter, wherein said condensation catalyst promoter is present in an amount sufficient to promote the condensation catalyst. This invention also relates to an alkyleneamines producers composition rich in triethylenetetramine (TETA), tetraethylenepentamine (TEPA) and pentaethylenehexamine (PEHA).

Description

RELATED APPLICATIONS

U.S. patent application Ser. No. 136,615, filed Dec. 22, 1987, commonly assigned.

The following are related, commonly assigned applications, filed on an even date herewith: U.S. patent application Ser. No. 390,829; U.S. Pat. No. 4,986,736; U.S. patent application Ser. No. 390,706; U.S. Pat. No. 5,101,074; and U.S. patent application Ser. No. 390,708; (now abandoned in favor of Ser. No. 742,731, filed Aug. 16, 1991, which in turn has been abandoned in favor of Ser. No. 934,901, filed Aug. 26, 1992). all incorporated herein by reference.

BRIEF SUMMARY OF THE INVENTION

1. Technical Field

This invention relates to a process for making amines by condensing an amino compound in the presence of a condensation catalyst and a condensation catalyst promoter.

This invention also relates to an alkyleneamines producers composition rich in higher polyalkylene polyamines such as triethylenetetramine (TETA), tetraethylenepentamine (TEPA) and pentaethylenehexamine (PEHA).

2. Background of the Invention

There is a substantial body of literature directed to the use of various acid catalysts to effect intramolecular and intermolecular condensation of amino compounds. U.S. Pat. No. 2,073,671 and U.S. Pat. No. 2,467,205 constitute early prior work on the use of acid condensation catalysts to condense amino compounds. U.S. Pat. No. 2,073,671 discusses, in a general fashion, the catalytic intermolecular condensation of alcohols and amines or ammonia using the same phosphate catalysts later favored by U.S. Pat. No. 2,467,205 for the intramolecular condensation of amines. The two patents are not in harmony over the use of other materials as catalysts. To illustrate this point, U.S. Pat. No. 2,073,671 states:

"Alumina, thoria, blue oxide of tungsten, titania, chromic oxide, blue oxide of molybdenum and zirconia have been mentioned in the literature for use as catalysts in carrying out these reactions but their effectiveness is so low that no practical application has been made of their use."

whereas U.S. Pat. No. 2,467,205 in describing the self condensation of ethylenediamine (EDA) under vapor phase conditions, to initially produce ethyleneamines, but after recycle, eventually generates piperazine through multistep condensation reactions, followed by deamination, recommends "dehydration catalysts" which are thereafter characterized as

"silica gel, titania gel, alumina, thoria, boron phosphate, aluminum phosphate, and the like."

U.S. Pat. No 2,073,671 describes the condensation catalyst in the following terms:

". . . a heated catalyst or contact mass containing phosphorus and especially one or more of the oxygen acids of phosphorus, their anhydrides, their polymers, and their salts; for example, orthophosphoric acid, metaphosphoric acid, pyrophosphoric acid, phosphorous pentoxide, dimetaphosphoric acid, trimetaphosphoric acid, primary ammonium phosphate, secondary ammonium phosphate, normal ammonium phosphate, ammonium metaphosphate, secondary ammonium pyrophosphate, normal ammonium pyrophosphate, aluminum phosphate, aluminum acid phosphate and mixtures of two or more of such materials." whereas U.S. Pat. No. 2,467,205 describes one of the preferred catalysts as "basic aluminum phosphate".

U.S. Pat. No. 2,454,404 describes the "catalytic deamination of alkylene polyamines" by reacting diethylenetriamine (DETA) vapor over solid catalysts such as activated alumina, bauxite, certain aluminum silicates such as kaolin and oxides of thorium, titanium and zirconium.

U.S. Pat. Nos. 2,073,671 and 2,467,205 demonstrate a common experience in using aluminum phosphate as a condensation catalyst to produce aliphatic amines, and U.S. Pat. Nos. 2,454,404 and 2,467,205 contemplate the other solid catalysts for deamination of amines to make heterocyclic noncyclic amines. In general, the reaction conditions under which deamination to effect cyclization occurs are more severe than those employed for condensation to generate noncyclic molecules, all other factors being comparable.

U.S. Pat. Nos. 4,540,822, 4,584,406 and 4,588,842 depict the use of Group IVB metal oxides as supports for phosphorus catalysts used to effect the condensation of amino compounds with alkanolamines.

U.S. Pat. No. 4,683,335 describes the use of tungstophosphoric acid, molybdophosphoric acid or mixtures deposited on titania as catalysts for the condensation of amines and alkanolamines to make polyalkylenepolyamines.

U.S. Pat. Nos. 4,314,083, 4,316,840, 4,362,886 and 4,394,524 disclose the use of certain metal sulfates as useful catalysts for the condensation of alkanolamine and an amino compound. No distinction is made between the sulfur compounds in respect to catalytic efficacy. Sulfuric acid is as good as any metal sulfate, and all metal sulfates are treated as equivalents. At column 8 of U.S. Pat. No. 4,314,083, it is noted that boron sulfate "gave extremely high selectivity at a low level" of EDA. However, selectivity in general was shown to increase with an increase of EDA relative to MEA in the feed. The only specific metal surfaces disclosed in the patents are antimony sulfate, beryllium sulfate, iron sulfate and aluminum sulfate.

In the typical case of the manufacture of alkyleneamines, mixtures with other alkyleneamines (including a variety of polyalkylenepolyamines and cyclic alkylenepolyamines) are formed. The same holds true when the object of the process is to produce polyalkylenepolyamines whether acyclic or cyclic, in that a variety of amino compounds are also formed each of these cyclic and acyclic alkyleneamines can be isolated from the mixture.

The acid catalyzed condensation reaction involving the reaction of an alkanolamine with an amino compound in the presence of an acidic catalyst is believed to proceed through the mechanism of esterifying free surface hydroxyl groups on the acid catalyst with the alkanolamine and/or by protonating the alkanolamine in the presence of the acid catalyst, followed by loss of water and amine condensation of the ester or the hydrated species, as the case may be, to form the alkyleneamine. Illustrative prior art directed primarily to the cyclic polyalkylenepolyamines (heterocyclic polyamines), but not necessarily limited to the aforementioned acid condensation reaction, are: U.S. Pat. Nos. 2,937,176, 2,977,363, 2,977,364, 2,985,658, 3,056,788, 3,231,573, 3,167,555, 3,242,183, 3,297,701, 3,172,891, 3,369,019, 3,342,820, 3,956,329, 4,017,494, 4,092,316, 4,182,864, 4,405,784 and 4,514,567; European Patent Applications 0 069 322, 0 111 928 and 0 158 319; East German Patent No. 206,896; Japanese Paten Publication No. 51-141895; and French Patent No. 1,381,243. The evolution of the art to the use of the acid catalyzed condensation reaction to generate acyclic alkyleneamines, particularly acyclic polyalkylenepolyamines, as the predominant products stemmed from the initial disclosure in U.S. Pat. No. 4,036,881, though earlier patent literature fairly well characterized such an effect without labeling it so, see U.S. Pat. No 2,467,205, supra. The acid catalysts are phosphorus compounds and the reaction is carried out in the liquid phase. The trend in this catalyst direction was early set as demonstrated by U.S. Pat. Nos. 2,073,671 and 2,467,205, supra. A modification of this route includes the addition of ammonia to the reaction, see, for example, U.S. Pat. No. 4,394,524 and U.S. Pat. No. 4,463,193 for the purpose of converting alkanolamine such as MEA in situ to alkylene amine such as EDA by reaction with ammonia, and the EDA is in situ reacted with MEA according to the process of U.S. Pat. No. 4,036,881 to form alkyleneamines.

A summary of the prior art employing acid catalysts for making alkyleneamines is set forth in Table 1 below.

TABLE 1__________________________________________________________________________CITATION CATALYST TYPE REACTANTS__________________________________________________________________________U.S. 2,467,205 Silica gel, titania gel, alumina, Vapor phase condensation of thoria, aluminum phosphate. EDA over a fixed bed of the Preferred catalyst is basic catalyst, multipass process aluminum phosphate. shifts from polyethylene- polyamines with the first few cycles.U.S.4,036,881 Phosphorus containing substances Alkanolamine and alkylene- selected from the group consisting amine in liquid phase of acidic metal phosphates, reaction. phosphoric acid compounds and their anhydrides, phosphorus acid comounds and their anhydrides, alkyl or aryl phosphate esters, alkyl or aryl phosphite esters, alkyl or aryl substituted phosphorous and phosphoric acids wherein said alkyl groups have from 1 to about 8 carbon atoms and said aryl groups have from 6 to about 20 carbon atoms, alkali metal monosalts of phosphoric acid, the thioanalogs of the fore- going, and mixtures of the above.U.S. 4,044,053 Phosphorus containing substances Alkanepolyols and alkylene- selected from the group consisting amine in liquid phase of acidic metal phosphates, reaction. phosphoric acid compounds and their anhydrides phosphorus acid compounds and their anhydrides, alkyl or aryl phosphate esters, alkyl or aryl phosphite esters, alkyl or aryl substituted phosphorous acids and phosphoric acids wherein said alkyl groups have from 1 to about 8 carbon atoms and said aryl groups have from 6 to about 20 carbon atoms, alkali metal mono- salts of phosphoric acid and mixtures of the above.U.S. 4,314,083 Salt of a nitrogen or sulfur con- Alkanolamine and an taining substance or the corres- alkyleneamine in liquid ponding acid. phase reaction.U.S. 4,316,840 Metal nitrates and sulfates Reforming linear polyamines. including zirconium sulfate.U.S. 4,316,841 Phosphate, preferably boron Reforming linear polyamines. phosphate.U.S. 4,324,917 Phosphorus-containing cation Alkanolamine and an alkylene- exchange resin. amine in liquid phase reaction.U.S. 4,362,886 Arsenic, antimony or bismuth Alkanolamie and an alkylene- containing compounds. Antimony amine in liquid phase sulfate specifically disclosed. reaction.U.S. 4,399,308 Lewis acid halide. Alkanolamine and an alkylene- amine in liquid phase reaction.U.S. 4,394,524 Phosphorus-containing substance Ammonia, alkanolamine and an or salt of a sulfur-containing alkyleneamine in liquid phase substance, or the corresponding reaction. acid.U.S. 4,448,997 Reacts alumina with phosphoric EDA with MEA. acid, adds ammonium hydroxide.U.S. 4,463,193 Group IIIB metal acid phosphate. Ammonia, alkanolamine and an alkyleneamine.U.S. 4,503,253 Supported phosphoric acid. Ammonia, alkanolamine and an alkyleneamine.U.S. 4,521,600 Select hydrogen phosphates and Alkanolamine and an alkylene- pyrophosphates. amine.U.S. 4,524,143 Phosphorus impregnated onto Alkanolamine and an alkylene- zirconium silicate support. amine.U.S. 4,540,822 Phosphorus compound deposited Alkanolamine and an alkylene- on a Group IVB metal oxide amine, regenerates the support. catalyst with O.sub.2 -containing gas.U.S. 4,547,591 Silica-alumina alone or in An ethyleneamine and an combination with an acidic alkanolamine; ethyleneamines; phosphorus cocatalyst. or ammonia and an alkanol- amine.U.S. 4,550,209 An intercalatively catalytically EDA and MEA. active tetravalent zirconium polymeric reaction product of an organo phosphonic acid or an ester thereof with a compound of tetravalent zirconium reactive therewith.U.S. 4,552,961 Phosphorus amide compound. Alkyleneamine and alkanolamine and/or alkylene glycol.U.S. 4,555,582 Phosphorus chemically bonded to MEA and EDA. a zirconium silicate support.U.S. 4,60,798 Rare earth metal or strontium MEA. acid phosphate.U.S. 4,578,517 Group IIIB metal acid phosphate. Ammonia or p-/s-amine and alkanolamine.U.S. 4,578,518 Thermally activated, calcined, MEA and EDA. pelleted titania containing titanium triphosphate, "...the titania that was used was... anatase." (Col. 9, lines 18-19).U.S. 4,578,519 Thermally activated, calcined, MEA and EDA with optional pelleted titania with chemically recycle of DETA. bonded phosphorus derived from polyphosphoric acid.U.S. 4,584,405 Activated carbon, optionally MEA and EDA. treated to incorporate phosphorus. Activated carbon may be washed with strong mineral acid to remove impurities followed by water wash. Optional treatment follows.U.S. 4,584,406 Pelleted Group IVB metal oxide MEA and EDA. with chemically bonded phosphorus derived from phosphoryl chloride or bromideU.S. 4,588,842 Thermally activated pelleted MEA and EDA. Group IVB metal oxide with chemically bonded phosphorus.U.S. 4,605,770 Group IIA or IIIB metal acid Alkanolamine and an phosphate. alkyleneamine "in liquid phase".U.S. 4,609,761 Thermally activated pelleted MEA and EDA. titania with chemically bonded phosphorus.U.S. 4,612,397 Thermally activated pelleted MEA and EDA. titania with chemically bonded phosphorus.U.S. 4,617,418 Acid catalysts, mentions "beryl- Ammonia, alkanolamine and lium sulfate". an alkylenamine "under vapor phase contitions".Japanese Patent Variety of phosphorus and metal Ammonia, alkanolamine andApplication phosphates including Group IVB ethyleneamine, with ammonia/#1983-185,871, phosphates. alkanolamine molar ratioPublication greater than 11.#1985-78,945U.S. 4,683,335 Tungstophosphoric acid, molybdo- Claims reaction of MEA and phosphoric acid or mixtures EDA, but discloses self- deposited on titania. Examples condensation reaction of 2-7 characterize titania surface EDA and DETA areas of 51, 60 and 120 m.sup.2 /gm.Japanese Patent Group IVB metal oxide with Ammonia and MEA.Application bonded phosphorus.#1985-078,391,Publication#1986-236,752Japanese Patent Group IVB metal oxide with Ammonia and MEA.Application bonded phosphorus.#1985-078,392,Publication#1986-236,753U.S. 4,698,427 Titania having phosphorus Diethanolamine and/or thermally chemically bonded hydroxyethyldiethylene- to the surface thereof in the triamine in EDA. form of phosphate bonds.U.S. 4,806,517 Pelleted Group IVB metal oxide MEA and EDA. with phosphorus thermally chemically bonded to the surface thereof.__________________________________________________________________________

The market demand for higher polyalkylene polyamines such as TETA, TEPA and PEHA has been progressively increasing in recent years. These higher polyalkylene polyamines are desirable co-products with DETA. It would be desirable to satisfy the existing demand from a cost standpoint by modifying slightly the commercial processes directed to the manufacture of DETA from the reaction of MEA and EDA or other suitable starting raw materials such as DETA and AEEA, to the production of TETA, TEPA and PEHA as major products.

It would be desirable to have continuously produced compositions, generated by the reaction of MEA and EDA or other suitable starting raw materials such as DETA and AEEA over a fixed bed of a condensation catalyst under commercial conditions, that are rich in TETA, TEPA and PEHA, and that are not disproporationately high in PIP and other cyclics.

It would be very beneficial to have a process which increases one's ability to generate the manufacture of desirable higher polyalkylene polyamine products such as TETA, TEPA and PEHA without generating large amounts of cyclic alkylenepolyamine products. In addition, it would also be desirable to have a process with raw material flexibility which provides the potential to control congener distribution, linear to cyclic selectivity and linear to branched selectivity of the higher polyalkylene polyamines products. As used herein, congener distribution refers to polyalkylene polyamines containing the same number of nitrogen atoms but not necessarily having the same molecular weight or structure.

The above features are provided by this invention.

SUMMARY OF THE INVENTION

This invention relates in general to a process of making amines which comprises condensing an amino compound in the presence of a condensation catalyst and a condensation catalyst promoter, wherein said condensation catalyst promoter is present in an amount sufficient to promote the condensation catalyst. The condensation catalysts and promoters used herein contain sufficient residual bound hydroxyl groups or other groupings which renders catalyst formation possible by loss of water or its chemical equivalent such as ammonium hydroxide.

More particularly, this invention relates to a process of making amines by the (i) intramolecular condensation of an amino compound to an amine having a lower molecular weight or (ii) the intermolecular condensation of an amino compound with one or more of another amino compound or a compound containing an alcoholic hydroxyl group using a condensation catalyst and a condensation catalyst promoter. A preferred process involves the manufacture of alkyleneamines, most desirably higher polyalkylene polyamines, by such condensation reactions utilizing a Group IVB metal oxide, sodium dihydrogen phosphate, disodium dihydrogen pyrophosphate or sodium trimetaphosphate as the condensation catalyst and a metal oxide as the condensation catalyst promoter.

The invention further relates to a continuously generated alkyleneamines producers composition comprising, based on 100 percent of the weight of the composition and exclusive of any water and/or ammonia present,

a) greater than about 3.0 weight percent of the combination of TETA and TEPA, b) greater than about 0.1 weight percent of TEPA, c) greater than about 3.0 weight percent of TETA, d) less than about 90.0 weight percent of DETA and/or EDA, e) less than about 90.0 weight percent of MEA and/or AEEA, f) less than about 12.5 weight percent of the combination of PIP and AEP, g) less than about 15.0 weight percent of other polyalkylene polyamines, h) a TETA+TAEA to PIP+AEP+PEEDA+DAEP+DPE weight ratio of greater than about 0.5, i) a TEPA+AETAEA to PIP+AEP+PEEDA+DAEP+DPE+AEPEEDA+iAEPEEDA+AEDAEP+AEDPE+BPEA weight ratio of greater than about 0.5, j) a TETA to TAEA weight ratio of greater than about 2 0, and k) a TEPA to AETAEA weight ratio of greater than about 1.0.

As used herein, the term "amino compound" embraces ammonia and any compound containing nitrogen to which is bonded an active hydrogen. Also, as used herein, the term "oxide" embraces oxides, hydroxides and/or mixtures thereof.

For purposes of this invention, the chemical elements are identified in accordance with the Periodic Table of the Elements, CAS version, Handbook of Chemistry and Physics, 67th Ed., 1986-87, inside cover. Also, for purposes of this invention, Group IIIB metal oxides embraces the lanthanides and actinides.

DETAILED DESCRIPTION

The higher polyalkylene polyamines such as TETA, TEPA and PEHA are very useful commercial products for a variety of applications including fuel oil additives, corrosion inhibitors, fabric softeners, fungicides and others. As indicated above, there is lacking a commercial process for the manufacture of enhanced quantities of TETA, TEPA and PEHA especially as significant products of reaction. There is thus a need for the ability to commercially generate larger production quantities of TETA, TEPA and PEHA and that is the direction of this invention. The process of this invention provides for the reaction of MEA and DETA or other suitable starting raw materials such as EDA and AEEA to produce in a continuous manner a reaction product mixture, termed herein an "alkyleneamines producers composition", in which TETA, TEPA and PEHA are principal products of the reaction.

The process of this invention is distinctive insofar as it achieves the generation of high concentrations of TETA, TEPA and PEHA in a manner which can be suitably employed in a commercial process, particularly a continuous process, for the manufacture of alkyleneamines. In particular, the process of this invention allows the production of TETA, TEPA and PEHA in relatively high yields without generating large amounts of cyclic polyalkylene polyamine products. The process of this invention provides starting raw material flexibility thereby allowing the potential to control congener distribution, linear to cyclic selectivity and linear to branched selectivity of the higher polyalkylene polyamine products.

As indicated above, this invention relates to a process of making amines which comprises condensing an amino compound in the presence of a catalytically effective amount of a condensation catalyst and a condensation catalyst promoter, wherein said condensation catalyst promoter is present in an amount sufficient to promote the condensation catalyst.

As also indicated above, this invention relates to a continuously generated alkyleneamines producers composition comprising, based on 100 percent of the weight of the composition and exclusive of any water and/or ammonia present,

a) greater than about 3.0 weight percent of the combination of TETA and TEPA, b) greater than about 0.1 weight percent of TEPA, c) greater than about 3.0 weight percent of TETA, d) less than about 90.0 weight percent of DETA and/or EDA, e) less than about 90.0 weight and/or AEEA, f) less than about 12.5 weight percent of the combination of PIP and AEP, g) less than about 15.0 weight percent of other polyalkylene polyamines, h) a TETA+TAEA to PIP+AEP+PEEDA+DAEP+DPE weight ratio of greater than about 0.5, i) a TEPA+AETAEA to PIP+AEP+PEEDA+DAEP+DPE+AEPEEDA+iAEPEEDA+AEDAEP+AEDPE+BPEA weight ratio of greater than about 0.5, j) a TETA to TAEA weight ratio of greater than about 2.0, and k) a TEPA to AETAEA weight ratio of greater than about 1.0.

The alkyleneamines producers composition of this invention can be subjected to conventional separations techniques for recovering the individual components of the composition. Such techniques are well known in the art and include, for example, distillation.

This invention contemplates the catalyzed condensation by (i) intramolecular condensation of an amino compound to an amine having a lower molecular weight, and (ii) intermolecular condensation of an amino compound with one or more of another amino compound or a compound containing an alcohol hydroxyl group to an amine having a lower, same or higher molecular weight than the reactants, in the presence of a condensation catalyst and a condensation catalyst promoter.

A wide variety of condensation catalysts can be used in this invention. Suitable condensation catalysts should be capable of being promoted by a condensation catalyst promoter described below. For purposes of this invention, the promotion effect can relate to catalytic activity, product selectivity and/or catalyst stability (mechanical or dimensional strength of the catalyst). Illustrative of suitable condensation catalysts for use in this invention include, for example, Group IVB metal oxides, metallic phosphates which may or may not have a cyclic structure, metallic polyphosphates which may or may not have a condensed structure, Group VIB metal containing substances and conventional condensation catalysts known in the art.

The Group IVB metal oxide condensation catalysts are preferred catalysts for use in this invention. Suitable Group IVB metal oxide condensation catalysts a-re disclosed in U.S. patent application Ser. No. 390,829), filed on an even date herewith and incorporated herein by reference. Illustrative of Group IVB metal oxide condensation catalysts include, for example, titanium oxide and zirconium oxide, preferably titanium dioxide and zirconium dioxide including mixtures thereof.

The metallic phosphate and polyphosphate condensation catalysts are also preferred catalysts for use in this invention. The metallic phosphate and polyphosphate condensation catalysts may or may not have a cyclic structure and may or may not have a condensed structure. Suitable metallic phosphate condensation catalysts having a cyclic structure or an acyclic structure are disclosed in U.S. patent application Ser. No 390,706), filed on an even date herewith and incorporated herein by reference. Suitable metallic polyphosphate condensation catalysts having a condensed structure are disclosed in U.S. Pat. No. 4,983,736, filed on an even date herewith and incorporated herein by reference. Illustrative of metallic phosphate and polyphosphate condensation catalysts include, for example, metallic orthophosphates (PO.sub.4 .sup.-3), metallic pyrophosphates (P.sub.2 O.sub.7 .sup.-4), metallic polyphosphates (including tripolyphosphates (P.sub.3 O.sub.10 .sup.-5), tetrapolyphosphates (P.sub.4 O.sub.13 .sup.-6), pentapolyphosphates (P.sub.5 O.sub.16 .sup.-7) and higher polyphosphates), metallic metaphosphates (including trimetaphosphates (P.sub.3 O.sub.9 .sup.-3), tetrametaphosphates (P.sub.4 O.sub.12 .sup.-4) and other lower and higher metaphosphates) and metallic ultraphosphates (condensed phosphates containing more P.sub.2 O.sub.5 than corresponds to the metaphosphate structure). Corresponding metallic metaphosphimates, metallic phosphoramidates and metallic amido and imidophosphates of the above may also be used as condensation catalysts in accordance with this invention. Suitable metals which can be incorporated into the metallic phosphate and polyphosphate condensation catalysts include, for example, Group IA metals, Group IIA metals, Group IIIB metals, Group IVB metals, Group VB metals, Group VIB metals, Group VIIB metals, Group VIII metals, Group IB metals, Group IIB metals, Group IIIA metals, Group IVA metals, Group VA metals, Group VIA metals and mixtures thereof.

Illustrative of metallic orthophosphate catalysts which may be utilized in this invention include, for example, NaH.sub.2 PO.sub.4, KH.sub.2 PO.sub.4, RbH.sub.2 PO.sub.4, LiH.sub.2 PO.sub.4, CsH.sub.2 PO.sub.4, MgHPO.sub.4, CaHPOO.sub.4, YPO.sub.4, CePO.sub.4, LaPO.sub.4, ThPO.sub.4, MnPO.sub.4, FePO.sub.4, BPO.sub.4, AlPO.sub.4, BiPO.sub.4, Mg(H.sub.2 PO.sub.4).sub.2, Ba(H.sub.2 PO.sub.4).sub.2, Mg(NH.sub.4).sub.2 PO.sub.4, Ca(H.sub.2 PO.sub.4).sub.2, La(H.sub.2 PO.sub.4).sub.3 and the like. Illustrative of metallic pyrophosphate catalysts which may be utilized in this invention include, for example, Na.sub.2 H.sub.2 P.sub.2 O.sub.7, K.sub.2 H.sub.2 P.sub.2 O.sub.7, Ca.sub.2 P.sub.2 O.sub.7, Mg.sub.2 P.sub.2 O.sub.7, KMnP.sub.2 O.sub.7, AgMnP.sub.2 O.sub.7, BaMnP.sub.2 O.sub.7, NaMnP.sub.2 O.sub.7, KCrP.sub.2 O.sub.7, NaCrP.sub.2 O.sub.7, Na.sub.4 P.sub.2 O.sub.7, K.sub.4 P.sub.2 O.sub.7, Na.sub.3 HP.sub.2 O.sub.7, NaH.sub.3 P.sub.2 O.sub.7, SiP.sub.2 O.sub.7, Na.sub.6 Fe.sub.2 (P.sub.2 O.sub.7).sub.3, Na.sub.8 Fe.sub.4 (P.sub.2 O.sub.7).sub.5, Na.sub.6 Cu(P.sub.2 O.sub.7).sub.2, Na.sub.32 Cu.sub.14 (P.sub.2 O.sub.7).sub.15, Na.sub.4 Cu.sub.18 (P.sub.2 O.sub.7).sub.5, Na(NH.sub.4).sub.2 P.sub.2 O.sub.7, Ca(NH.sub.4).sub.2 P.sub.2 O.sub.7, MgH.sub. 2 P.sub.2 O.sub.7, Mg(NH.sub.4).sub.2 P.sub.2 O.sub.7) and the like. Illustrative of metallic polyphosphate catalysts which may be utilized in this invention include, for example, NaSr.sub.2 P.sub.3 O.sub.10, NaCa.sub.2 P.sub.3 O.sub.10, NaNi.sub.2 P.sub.3 O.sub.13, Na.sub.5 P.sub.3 O.sub.10, K.sub.5 P.sub.3 O.sub.10, Na.sub.3 MgP.sub.3 O.sub.10, Na.sub.3 CuP.sub.3 O.sub.10, Cu.sub.5 (P.sub.3 O.sub.10).sub.2, Na.sub.3 ZnP.sub.3 O.sub.10, Na.sub.3 CdP.sub.3 O.sub.10, Na.sub.6 Pb(P.sub.3 O.sub.10).sub.2, Na.sub.3 CoP.sub.3 O.sub.10, K.sub.3 CoP.sub.3 O.sub.10, Na.sub.3 NiP.sub.3 O.sub.10, K.sub.2 (NH.sub.4).sub.3 P.sub.3 O.sub.10, Ca(NH.sub.4).sub.2 P.sub.3 O.sub.10, La(NH.sub.4).sub.3 P.sub.3 O.sub.10, NaMgH.sub.2 P.sub.3 O.sub.10 and the like. Illustrative of metallic metaphosphate catalysts which may be utilized in this invention include, for example, Na.sub.3 P.sub.3 O.sub.9, K.sub.3 P.sub.3 O.sub.9, Ag.sub.3 P.sub.3 O.sub.9, Na.sub.4 P.sub.4 O.sub.12, K.sub.4 P.sub.4 O.sub.12, Na.sub.2 HP.sub.3 O.sub.9, Na.sub.4 Mg(P.sub.3 O.sub.9).sub.2, NaSrP.sub.3 O.sub.9, NaCaP.sub.3 O.sub.9, NaBaP.sub.3 O.sub.9, KBaP.sub.3 O.sub.9, Ca.sub.3 (P.sub.3 O.sub.9).sub.2, Ba(P.sub.3 O.sub.9).sub.2, Na.sub.2 Ni.sub.2 (P.sub.3 O.sub.9).sub.2, Na.sub.4 Ni(P.sub.3 O.sub.9).sub.2, Na.sub.4 Co(P.sub.3 O.sub.9).sub.2, Na.sub.4 Cd(P.sub.3 O.sub.9).sub.2 and the like. Illustrative of metallic ultraphosphate catalysts which may be utilized in this invention include, for example, CaP.sub.4 O.sub.11, Ca.sub.2 P.sub.6 O.sub.17, Na.sub.8 P.sub.10 O.sub.29, Na.sub.6 P.sub.8 O.sub.23, Na.sub.2 CaP.sub.6 O.sub.17, Na.sub.2 P.sub.4 O.sub.11, NaBaP.sub.7 O.sub.18, Na.sub.2 P.sub.8 O.sub.21, K.sub.4 P.sub.6 O.sub.17 and the like. The preferred metallic phosphate and polyphosphate condensation catalysts for use in this invention include Group IA metal dihydrogen orthophosphates, Group IA metal metaphosphates and Group IA metal dihydrogen pyrophosphates, more preferably NaH.sub.2 PO.sub.4, Na.sub.3 P.sub.3 O.sub.9 and Na.sub.2 H.sub.2 P.sub.2 O.sub.7. Other suitable metallic phosphate and polyphosphate condensation catalysts having a condensed structure which are embraced within the scope of this invention are disclosed by Van Wazer, J. R., Phosphorus and Its Compounds, Vol. 1, Interscience Publishers, Inc., N.Y. (1958).

The metallic phosphate and polyphosphate condensation catalysts can be prepared by conventional methods known in the art. Sodium is believed to be one of a small group of cations effective for stabilizing six-membered cyclic metaphosphates at their temperatures of fusion (about 625.degree. C.) without decomposition to linear and/or other condensed phosphates including mixtures. The formation of cyclic and acyclic metallic phosphate and polyphosphate structures appears to depend on the cation ionic size, the coordination number of the cation and the ionic or covalent nature of the metal-oxygen bond.

While not wishing to be bound to any particular theory, it is believed that those metallic phosphates and polyphosphates encompassed within the scope of this invention having a cyclic structure and possessing ionic character and/or ion exchange capacity exhibit desired catalytic activity and provide desired product selectivity in association with a condensation catalyst promoter. While the reaction mixture may initially include one or more metallic phosphates and/or metallic polyphosphates other than metallic phosphates and polyphosphates having a cyclic structure and possessing ionic character and/or ion exchange capacity, it is believed to be desirable that such metallic phosphates and polyphosphates having a cyclic structure and possessing ionic character and/or ion exchange capacity be formed in situ in association with a condensation catalyst promoter in order to provide desired catalytic activity and product selectivity. In such instances, the catalyst preparation conditions or reaction conditions should allow for the formation of metallic phosphates and polyphosphates having a cyclic structure and possessing ionic character and/or ion exchange capacity in association with a condensation catalyst promoter. Mixtures of metallic phosphates and polyphosphates having a cyclic structure and possessing ionic character and/or ion exchange capacity with metallic phosphates and polyphosphates having other than a cyclic structure and other than ionic character and/or ion exchange capacity are believed to exhibit desired catalytic activity and provide desired product selectivity in association with a condensation catalyst promoter.

The Group VIB metal containing condensation catalysts are preferred catalysts for use in this invention. Suitable Group VIB metal containing condensation catalysts are disclosed in U.S. patent application Ser. No. 390,708, filed on an even date herewith and incorporated herein by reference (now abandoned in favor of Ser. No. 742,731, filed Aug. 16, 1991, which in turn has been abandoned in favor of Ser. No. 934,901, filed Aug. 26, 1992). Illustrative of Group VIB metal-containing condensation catalysts include, for example, one or more oxides of tungsten, chromium, molybdenum or mixtures thereof.

A variety of conventional condensation catalysts may be suitable for use in this invention. As indicated above, the conventional condensation catalysts should be capable of being promoted by a condensation catalyst promoter. Illustrative of conventional condensation catalysts may include, for example, those disclosed in U.S. Pat. No. 4,036,881, U.S. Pat. No. 4,806,517, U.S. Pat. No. 4,617,418, U.S. Pat. No. 4,720,588, U.S. Pat. No. 4,394,524, U.S. Pat. No. 4,540,822, U.S. Pat. No. 4,588,842, U.S. Pat. No. 4,605,770, U.S. Pat. No. 4,683,335, U.S. Pat. No. 4,316,841, U.S. Pat. No. 4,463,193, U.S. Pat. No. 4,503,253, U.S. Pat. No. 4,560,798 and U.S. Pat. No. 4,578,517.

Suitable conventional catalysts which can be employed in this invention include phosphorus containing substances such as acidic metal phosphates, phosphoric acid compounds and their anhydrides, phosphorous acid compounds and their anhydrides, alkyl or aryl phosphate esters, alkyl or aryl phosphite esters, alkyl or aryl substituted phosphorous acids and phosphoric acids, alkali metal monosalts of phosphoric acid, the thioanalogs of the foregoing, and mixtures of any of the above.

This invention also embraces the use of promoted vicinal di(hetero)alkylene organometalates in the preparation of amines. Suitable vicinal di(hetero)alkylene organometalates are disclosed in U.S. Pat. No. 5,101,074, filed on an even date herewith and incorporated herein by reference.

The level of activity of the promoted condensation catalysts of the invention is that level which of itself makes the catalysts at least as active in the condensation of amines as, for example, is phosphoric acid on an equivalent basis. Preferably, the promoted condensation catalysts on a support should have a surface area greater than about 70 m.sup.2 /gm to as high as about 260 m.sup.2 /gm or greater depending upon which metal oxide described below that is employed. In the case of titanium oxides, the surface area should be greater than about 140 m.sup.2 /gm to as high as about 260 m.sup.2 /gm, more preferably, greater than about 160 m.sup.2 /gm to as high as about 260 m.sup.2 /gm, determined according to the single point N.sub.2 method. In the case of zirconia oxides, the surface area should be greater than about 70 m.sup.2 /gm to as high as about 150 m.sup.2 /gm, more preferably, greater than about 90 m.sup.2 /gm to as high as about 135 m.sup. 2 /gm, determined according to the single point N.sub.2 method. It is appreciated that the metal oxide promoters described below which can be used in association with the condensation catalyst and the other condensation catalyst promoters described below can affect the surface area of the condensation catalyst. While surface areas described above may be preferred, for purposes of this invention, the surface area of the promoted condensation catalyst should be sufficient to contribute to product selectivity, catalytic activity and/or mechanical or dimensional strength of the catalyst.

Though the condensation catalyst of the invention provides sufficient activity to effect the condensation reaction, certain combinations of reactants and/or product formation can be benefited by employing a condensation catalyst promoter with the condensation catalyst. Condensation catalyst promoters can be used to promote the performance of catalysts in areas of selectivity to certain products. A range of suitable materials may impact the condensation catalysts of this invention in the variety of reaction products. The condensation catalyst promoter may be any material which impacts the condensation catalyst's selection of reaction products or which changes the proportion of any one or more of the reaction products which the condensation catalyst generates at comparable processing conditions. In addition to contributing to product selectivity, the condensation catalyst promoter may be any material which contributes to catalytic activity and/or catalyst stability (mechanical or dimensional strength).

The condensation catalyst promoter for use in this invention should be capable of promoting the condensation catalyst. As indicated above, the promoting effect can relate to catalytic activity, product selectivity and/or catalyst stability (mechanical or dimensional strength of the catalyst). Illustrative of condensation catalyst promoters for use in this invention can include, for example, one or more metal oxides, one or more metallic phosphates which may or may not have a cyclic structure, one or more metallic polyphosphates which may or may not have a condensed structure, one or more Group VIB metal containing substances and one or more conventional materials such as mineral acids or compounds derived from mineral acids. Mixtures of condensation catalyst promoters may also be employed in this invention. For purposes of this invention, the condensation catalyst promoter should be different from the condensation catalyst.

Illustrative of metal oxides which may be utilized as condensation catalyst promoters in association with the condensation catalyst include, for example, one or more of the following: Group IA metal oxides, Group IIA metal oxides, Group IIIB metal oxides (including lanthanides and actinides), Group VB metal oxides, Group VIB metal oxides, Group VIIB metal oxides, Group VIII metal oxides, Group IB metal oxides, Group IIB metal oxides, Group IIIA metal oxides, Group IVA metal oxides, Group VA metal oxides, Group VIA metal oxides and Group IVB metal oxides or mixtures thereof. Certain of these metal oxides may also be used as condensation catalysts in accordance with this invention such as Group IVA and IVB metal oxides. Preferred metal oxides are amphoteric or slightly acidic or slightly basic. Preferred metal oxides which may be utilized in association with the condensation catalyst include, for example, one or more oxides of beryllium, scandium, yttrium, terbium, dysprosium, holmium, erbium, thulium, ytterbium, lutetium, titanium, zirconium, hafnium, vanadium, niobium, tantalum, tungsten, iron, cobalt, zinc, silver, aluminum, gallium, indium, silicon, germanium, tin, lead, arsenic, antimony and bismuth.

Group IVB metal oxides such as titanium dioxide and zirconium dioxide and Group IVA metal oxides such as silica are preferred for use in this invention. For mixed metal oxides in which at least one of the metals is titanium, suitable metals in association with titanium may include, for example, one or more of the following: Group IIIB metals such as scandium, yttrium and lanthanum including the lanthanides, Group VB metals such as niobium and tantalum, Group VIB metals such as chromium, molybdenum and tungsten, Group VIII metals such as iron, cobalt and nickel, Group IIB metals such as zinc and cadmium, Group IIIA metals such as boron, aluminum, gallium and indium, Group IVA metals such as silicon, germanium, tin and lead, Group VA metals such as arsenic, antimony and bismuth, and Group IVB metals such as zirconium and hafnium. For mixed metal oxides in which at least one of the metals is zirconium, suitable metals in association with zirconium may include, for example, one or more of the following: Group IVA metals such as silicon, germanium, tin and lead, Group VB metals such as niobium and tantalum, and Group VIB metals such as chromium, molybdenum and tungsten. Certain of these metal oxides may also be effective as condensation catalysts for use in this invention.

Illustrative of mixed metal oxides which may be used as condensation catalyst promoters in association with the condensation catalyst include, for example, TiO.sub.2 --SiO.sub.2, TiO.sub.2 --Al.sub.2 O.sub.3, TiO.sub.2 --CdO, TiO.sub.2 --Bi.sub.2 O.sub.3, TiO.sub.2 --Sb.sub.2 O.sub.5, TiO.sub.2 --SnO.sub.2, TiO.sub.2 --ZrO.sub.2, TiO.sub.2 --BeO, TiO.sub.2 --MgO, TiO.sub.2 --CaO, TiO.sub.2 --SrO, TiO.sub.2 --ZnO, TiO.sub.2 --Ga.sub.2 O.sub.3, TiO.sub.2 --Y.sub.2 O.sub.3, TiO.sub.2 --La203, TiO.sub.2 --MoO.sub.3, TiO.sub.2 --Mn.sub.2 O.sub.3, TiO.sub.2 --Fe.sub.2 O.sub.3, TiO.sub.2 --Co.sub.3 O.sub.4, TiO.sub.2 --WO.sub.3, TiO.sub.2 --BaO, TiO.sub.2 --Cr.sub.2 O.sub.3, TiO.sub.2 --ThO.sub.2, TiO.sub.2 --Na.sub.2 O, TiO.sub.2 --BaO, TiO.sub.2 --CaO, TiO.sub.2 --HfO.sub.2, TiO.sub.2 --Li.sub.2 O, TiO.sub.2 --Nb.sub.2 O.sub.5, TiO.sub. 2 --Ta.sub.2 O.sub.5, TiO.sub.2 --PbO, TiO.sub.2 --Lu.sub.2 O.sub.3, TiO.sub.2 --Yb.sub.2 O.sub.3, TiO.sub.2 --CeO.sub.2, TiO.sub.2 --Sc.sub.2 O.sub.3, TiO.sub.2 --PbO, TiO.sub.2 --NiO, TiO.sub.2 --CuO, TiO.sub.2 --CoO, TiO.sub.2 --B.sub.2 O.sub.3, ZrO.sub.2 --SiO.sub.2, ZrO.sub.2 --Al.sub.2 O.sub.3, ZrO.sub.2 SnO, ZrO.sub.2 --PbO, ZrO.sub.2 --ZrO.sub.2 --Ta.sub.2 O.sub.5, ZrO.sub.2 Cr.sub.2 O.sub.3, ZrO.sub.2 --MoO.sub.3, ZrO.sub.2 --WO.sub.3, ZrO.sub.2 --TiO.sub.2, ZrO.sub.2 HfO.sub.2, TiO.sub.2 --SiO.sub.2 --Al.sub.2 O.sub.3, TiO.sub.2 --SiO.sub.2 --ZnO, TiO.sub.2 --SiO.sub.2 --ZrO.sub.2, TiO.sub.2 --SiO.sub.2 --CuO, TiO.sub.2 --SiO.sub.2 MgO, TiO.sub.2 --SiO TiO.sub.2 --SiO.sub.2 --B.sub.2 O.sub.3, TiO.sub.2 --SiO.sub.2 --WO.sub.3, TiO.sub.2 --SiO TiO.sub. 2 --SiO.sub.2 --MgO, TiO.sub.2 --SiO.sub.2 --La.sub.2 O.sub.3, TiO.sub.2 --SiO TiO.sub.2 --SiO.sub.2 --Mn.sub.2 O.sub.3, TiO.sub.2 --SiO.sub.2 --Co.sub.3 O.sub.4, TiO.sub.2 --SiO.sub.2 NiO, TiO.sub.2 --SiO.sub.2 PbO, TiO.sub.2 --SiO.sub.2 Bi.sub.2 O.sub.3, TiO.sub.2 --Al.sub.2 O.sub.3 --ZnO, TiO.sub.2 --Al.sub.2 O.sub.3 --ZrO.sub.2, TiO.sub.2 --Al.sub.2 O.sub.3 --Fe.sub.2 O .sub.3, TiO.sub.2 --Al.sub.2 O.sub.3 --WO.sub.3, TiO.sub.2 --Al.sub.2 O.sub.3 --La.sub.2 O.sub.3, TiO.sub.2 --Al.sub.2 O.sub.3 --Co.sub.3 O.sub.4, ZrO.sub.2 --SiO.sub.2 --Al.sub.2 O.sub.3, ZrO.sub.2 --SiO.sub.2 --SnO, ZrO.sub.2 --SiO.sub.2 --Nb.sub.2 O.sub.5, ZrO.sub.2 --SiO.sub.2 --WO.sub.3, ZrO.sub.2 --SiO.sub.2 --TiO.sub.2, ZrO.sub.2 --SiO.sub.2 --MoO.sub.3, ZrO.sub.2 --SiO.sub.2 --HfO.sub.2, ZrO.sub.2 --SiO.sub.2 --Ta.sub.2 O.sub.5, ZrO.sub.2 --Al.sub.2 O.sub.3 --SiO.sub.2 , ZrO.sub.2 --Al.sub.2 O.sub.3 --PbO, ZrO.sub.2 --Al.sub.2 O.sub.3 --Nb.sub.2 O.sub.5, ZrO.sub.2 --Al.sub.2 O.sub.3 --WO .sub.3, ZrO.sub.2 --Al.sub.2 O.sub.3 --TiO.sub.2, ZrO.sub.2 --Al.sub.2 O.sub.3 --MoO.sub.3, ZrO.sub.2 --HfO.sub.2 --Al.sub.2 O .sub.3, ZrO.sub.2 --HfO.sub.2 --TiO.sub.2, and the like. Other suitable mixed metal oxide promoters embraced within the scope of this invention are disclosed by Tanabe et al., Bulletin of the Chemical Society of Japan, Vol. 47(5). pp. 1064-1066 (1974).

The metal oxides described herein which can be used as condensation catalyst promoters in association with the condensation catalyst may contribute to product selectivity and/or catalytic activity of the reaction and/or stability of the catalyst. The catalyst structure can comprise from about 0 to about 90 percent or greater by weight of the metal oxide, preferably from about 0 to about 75 percent by weight of the metal oxide, and more preferably from about 0 to about 50 percent by weight of the metal oxide, the remainder being the weight of the condensation catalyst. For mixed metal oxides containing titania, higher concentrations of titania can provide very desirable product selectivities including acyclic to cyclic selectivities and linear to branched selectivities of higher polyalkylene polyamine products. As discussed hereinafter, the condensation catalyst of this invention may also contain support(s), binding agent(s) or other additives to stabilize or otherwise help in the manufacture of the catalyst.

Illustrative of metallic phosphates which may or may not have a cyclic structure and metallic polyphosphates which may or may not have a condensed structure which can be utilized as condensation catalyst promoters in association with the condensation catalyst are described hereinabove. Corresponding metallic metaphosphimates, metallic phosphoramidates and metallic amido- and imidophosphates of the above may also be used as condensation catalyst promoters in accordance with this invention. Such metallic phosphates and polyphosphates can contribute to product selectivity, catalytic activity and/or catalyst stability (mechanical or dimensional strength of the catalyst.) Certain of these metallic phosphates and polyphosphates may also be effective as condensation catalysts for use in this invention.

Illustrative of Group VIB metal-containing substances which can be utilized as condensation catalyst promoters in association with the condensation catalyst are described hereinabove. Such Group VIB metal containing substances can contribute to product selectivity, catalytic activity and/or catalyst stability (mechanical or dimensional strength of the catalyst). Certain of these Group VIB metal-containing substances may also be effective as condensation catalysts for use in this invention.

Illustrative of conventional materials which can be utilized as condensation catalyst promoters in association with the condensation catalyst include a mineral acid or a compound derived from a mineral acid. Suitable for use as condensation catalyst promoters are one or more phosphoric acid or a salt of phosphoric acid, hydrogen fluoride, hydrofluoric acid or a fluoride salt, sulfuric acid or a salt of sulfuric acid, and the like. The promoter may also be organic esters of phosphoric acid or a salt of phosphoric acid, hydrogen fluoride organic complexes, hydrofluoric acid organic complexes or a fluoride salt organic complexes, organic esters of sulfuric acid or a salt of sulfuric acid, and the like. Suitable salts of phosphoric acid include sodium dihydrogen phosphate, disodium hydrogen phosphate, sodium phosphate and the like.

The amount of the condensation catalyst promoter of the mineral acid type used with the condensation catalyst of the invention is not narrowly critical. Generally, the amount does not exceed 25 weight percent of the weight of the catalyst. As a rule, it is desirable to use at least 0.01 weight percent of the weight of the catalyst. Preferably, the amount of condensation catalyst promoter will range from about 0.2 to about 10 weight percent of the weight of the catalyst. Most preferably, the amount of condensation promoter will range from about 0.5 to about 5 weight percent of the weight of the catalyst.

The amount of condensation catalyst promoter other than the mineral acid type used with the condensation catalyst is not narrowly critical. Generally, the amount does not exceed 90 weight percent of the weight of the catalyst. The amount of condensation catalyst promoter can range from about 0 to about 90 or greater weight percent of the weight of the catalyst, preferably from about 0 to about 75 weight percent of the weight of the catalyst, and more preferably from about 0 to about 50 weight percent of the weight of the catalyst. Most preferably, the amount of condensation catalyst promoter will range from about 0.5 to about 25 weight percent of the weight of the catalyst.

The condensation catalyst promoter can be provided to the condensation catalyst by conventional procedures known in the art. For example, the promoter can be provided to the catalyst by impregnating particles or monolithic structures comprising the catalyst with liquid comprising the promoter. This is a well known procedure in the art for incorporating additives to a solid support material. The condensation catalyst of the invention may be utilized as solid powders or as fused, bonded or compressed solid pellets, or larger structures in association with the one or more metal oxides, or as coated, fused, bonded or compressed solid pellets, or larger structures, composited with one or more support materials, in association with one or more metal oxides. These solid structures may be treated with the promoter by mixing a liquid body of the promoter with the solid structure. For example, the condensation catalyst solids may be slurried in the promoter, drained, washed and suctioned to remove excess promoter and then dried with heat to remove any volatiles accompanying the promoter. The drying temperature chosen will depend on the nature of the volatiles to be removed. Usually, the time/temperature for effecting drying will be below the conditions for effecting dehydration to remove bound water from the metal oxide in association with the condensation catalyst. Normally the drying temperature will be greater than about 120.degree. C. and below about 600.degree. C. depending on the thermal stability of the catalyst. The drying time will generally go down as the drying temperature rises and vice versus, and may extend from 5 seconds to about 24 hours.

Alternatively, the condensation catalyst promoter can be provided to the condensation catalyst at the time of preparing the catalyst in association with one or more metal oxides. For example, one or more metal oxides may be condensed from their respective hydrolyzable monomers to the desired oxides to form oxide powders which can thereafter be blended and compressed with the catalyst to form pellets and larger structures of the metal oxide-containing condensation catalyst of this invention. The one or more metal oxides which can be used in association with the catalyst in accordance with this invention can be provided from metal salts which can be heated to form the metal oxide. It is appreciated that the promoter can be incorporated into the molecular bonding configuration of the metal oxide containing condensation catalyst by conventional procedures known in the art.

The condensation catalysts in association with one or more metal oxides prior to the treatment of the promoter may be prepared in a wide variety of ways. For example, one or more metal oxides may be provided as a partial condensate on a support, such as a silica or alpha, beta or gamma alumina, silicon carbide, and the like, and then condensed by heating to effect polymerization to the desired oxide form. The metal oxide(s) may be condensed from hydrolyzable monomers to the desired oxide, indeed, to form an oxide powder which can thereafter be compressed in the presence of a condensation catalyst to form pellets and larger structures of the metal oxide containing condensation catalyst of the invention. A blend of the powder and condensation catalyst can be made into a shapeable paste which can be extruded and cut into pellets according to conventional procedures. The extrudate may thereafter be fired to cure the condensation catalyst and fix the structure. The cut extrudate may be blended with a support material such as those characterized above, and the blend fired to fuse the metal oxide-containing catalyst to the support.

In a preferred embodiment of this invention, a high surface area silica or titania can be slurried with an aqueous solution of sodium dihydrogen phosphate, disodium dihydrogen pyrophosphate or sodium trimetaphosphate, extruded, and calcined at a temperature of about 400.degree. C.

A preferred promoted catalyst structure comprises sodium dihydrogen phosphate, disodium dihydrogen pyrophosphate or sodium trimetaphosphate in association with a Group IVA or IVB metal oxide having a surface area of at least a 140 m.sup.2 /gm which may or may not be bonded to a support material. The term "support," as used herein and in the claims, means a solid structure which does not adversely affect the catalytic properties of the promoted catalyst and is at least as stable as the promoted catalyst to the reaction medium. The support can function as an amine condensation catalyst independent of the condensation catalyst used herein, although it may have lower catalytic activity to the reaction. The support may act in concert with the promoted catalyst to moderate the reaction. Some supports may contribute to the selectivity of the reaction. The promoted catalyst structure can comprise from about 2 to about 60 percent by weight or greater of the support, more preferably from about 10 to about 50 percent by weight of the support, the remainder being the weight of the metal oxide(s) and condensation catalyst. Included in the weight of the support is the weight of any binding agent such as phosphates, sulfates, silicates, fluorides, and the like, and any other additive provided to stabilize or otherwise help in the manufacture of the promoted catalyst. The support may be particles as large or larger than the catalyst component and "glued" to the condensation catalyst and/or metal oxide by virtue of a binding medium.

The support may constitute a separate phase in the process of extruding the catalytic structure. In this embodiment, the support forming material, preferably as a paste is blended with a paste of the condensation catalyst and one or more metal oxides or a partial condensate thereof. The paste may comprise the oxide forms of the support and the condensation catalyst, each blended with water, and/or binding agents. The extrudate of the blend is passed through a multiorificed die and chopped into pellets of the desired sizes. The particles may be doughnut shaped, spherical, and the like. Then the particles are calcined to dry them and complete any condensation reaction in the support and/or the metal oxide containing condensation catalyst.

The use of supports for the condensation catalyst provides a number of significant advantages. It has been determined that some of the promoted condensation catalysts are not as stable in the amines reaction media when utilized over an extended period of time. When the reaction is effected as a batch reaction, this matter is not a problem. However, when the reaction is effected with the promoted condensation catalyst as part of a fixed bed in a tubular reactor, the preferred procedure for carrying out the invention, it is desirable to have the promoted catalyst be more stable. When the promoted catalyst is combined with the support, it has greater stability for the reaction medium, and therefore, it is better able to be used in a fixed bed of a continuous reactor. The supported catalysts suffer from none of the leaching problems that the promoted catalyst per se may have or the problems that are associated with the prior art catalysts, such as acidic phosphorus compounds on silica.

The reactants used in the condensation process of the invention may be ammonia or organic compound containing --NH-- and any compound possessing an alcoholic hydroxyl group, subject to the following: the intramolecular condensation of an amino compound produces an amine having a lower molecular weight, and the intermolecular condensation of an amino compound with one or more of another amino compound or a compound containing an alcoholic hydroxyl group produces an amine having a lower, same or higher molecular weight than the reactants.

Illustrative of suitable reactants in effecting the process of the invention, include by way of example:

Ammonia

MEA--monoethanolamine EDA--ethylenediamine MeEDA--methylethylenediamine EtEDA--ethylethylenediamine AEEA--N-(2-aminoethyl)ethanolamine HEP--N-(2-hydroxyethyl)piperazine DETA--diethylenetriamine AEP--N-(2-aminoethyl)piperazine TAEA--trisaminoethylamine TETA--triethylenetetramine TEPA--tetraethylenepentamine PEHA--pentaethylenehexamine

TETA Isomers

TAEA--trisaminoethylamine TETA--triethylenetetramine DPE--dipiperazinoethane DAEP--diaminoethylpiperazine PEEDA--piperazinoethylethylenediamine

TEPA Isomers

AETAEA--aminoethyltrisaminoethylamine TEPA--tetraethylenepentamine AEDAEP--aminoethyldiaminoethylpiperazine AEPEEDA--aminoethylpiperazinoethylethylenediamine iAEPEEDA--isoaminoethylpiperazinoethylethylenediamine BPEA--bispiperazinoethylamine

The foregoing also can represent the products of the reaction. For example, ammonia and MEA are frequently employed to produce EDA along with a variety of other amines, most of which are set forth above.

Glycol compounds can also be employed in the preparation of amines in accordance with this invention. For purposes of this invention, glycol compounds embrace diols and polyols. Illustrative of suitable glycol compounds include alkylene glycols such as ethylene glycol, propylene glycol, 1,3-propane diol or mixtures thereof

The process may be effected in the liquid or vapor or supercritical liquid states or mixtures thereof though the actual reaction is believed to occur on the catalyst s solid surface in the absorbed state. In this context, the vapor phase reaction is intended to refer to the general vapor state of the reactants. Though the reaction conditions may range from subatmospheric to superatmospheric conditions, it is desirable to run the reaction from about 50 psig to about 3,000 psig, preferably from about 200 psig to about 2,000 psig

The temperature of the reaction may be as low as about 125.degree. C. to about 400.degree. C. Preferably, the reaction temperature ranges from about 150.degree. C. to about 350.degree. C., and most preferably from about 225.degree. C. to about 325.degree. C.

The reaction may be effected by the incremental addition of one of the reactants to the other or by the joint addition of the reactants to the promoted catalyst. The preferred process effects the reaction in a continuous manner over a fixed bed of the promoted condensation catalyst in a tubular reactor. However, the reactor may be carried out by slurrying the promoted catalyst in the reactants or in a batch mode in an autoclave. An inert such as nitrogen, methane and the like can be used in the reaction process.

The preferred process involves the formation of alkyleneamines from the intermolecular condensation of alkanolamines and alkyleneamines or the intramolecular condensation of alkyleneamines or alkanolamines. Illustrative of such reactions are the following reactant combinations:

______________________________________REACTANT REACTANT PRODUCTS______________________________________Ammonia Methanol Monomethylamine Dimethylamine TrimethylamineAmmonia MEA EDA, DETA, AEEA, TETA, TEPA, PIPAmmonia AEEA DETA, PIPMEA, Ammonia EDA EDA, AEEA, HEP, DETA, AEP, TETA, TEPA, PEHA, TETA Isomers: TAEA, TETA, DAEP, PEEDA, DPE TEPA, TEPA Isomers: AETAEA, AEPEEDA, AEDAEP, AEDPE, BPEAMEA EDA AEEA, HEP, DETA, AEP, TETA, TEPA, PEHA, TETA Isomers: TAEA, TETA, DAEP, PEEDA, DPE TEPA, TEPA Isomers: AETAEA, AEPEEDA, AEDAEP, AEDPE, BPEAEDA AEEA HEP, AEP, TETA, TEPA, PEHA, TETA Isomers: TAEA, TETA, DAEP, PEEDA, DPE TEPA, TEPA Isomers: AETAEA, AEPEEDA, AEDAEP, AEDPE, BPEADETA AEEA TEPA Isomers, AEPEDA EDA DETA, TETA AND TEPA Isomers______________________________________

The process of the invention provides the ability to generate the manufacture of desirable higher polyalkylene polyamine products such as TETA, TEPA and PEHA without generating large amounts of cyclic alkylenepolyamine products such as PIP, AEP and HEP. The alkyleneamines producers composition of this invention has a TETA+TAEA to PIP+AEP+PEEDA+DAEP+DPE weight ratio of greater than about 0.5 and a TETA to TAEA weight ratio of greater than about 2.0. The process of this invention provides the potential to control congener distribution, linear to cyclic selectivity and linear to branched selectivity of the higher polyalkylene polyamines.

It is appreciated that the condensation catalysts and condensation catalyst promoters of this invention may also be useful in the production of alkylamines. For example, an alcohol and at least one of ammonia, a primary amine, a secondary amine or a tertiary amine may be contacted in the presence of a condensation catalyst and a condensation catalyst promoter under conditions effective to produce alkylamines.

This invention is further illustrated by certain of the following examples:

EXAMPLES

In the examples set forth in Tables I-XXIV and XLV-LXXI below, the catalyst of choice was placed in a tubular reactor having an outside diameter of 1 inch and an overall length of 30 inches. The catalyst portion of the reactor comprised a length of 24 inches, accommodating 150 cubic centimeters of catalyst. The reactor was made of 316 stainless steel. In the examples set forth in Tables XXV-XLIV and LXXII-CXXXV, the catalyst of choice was placed in one of 3 tubular reactors, each having an outside diameter of 1 inch, and heated by a sand bath. The catalyst portion of the reactor comprised a length of 24 inches, accommodating 100 cubic centimeters of catalyst. As used herein, ABl refers to a material obtained from Norton Company, Akron, Ohio, which is a mixture of sodium trimetaphosphate and sodium tripolyphosphate. As used in certain of the tables below, acyclic (N4)/cyclic (<=N4) refers to the weight ratio of TETA+TAEA to PIP+AEP+PEEDA+DAEP+DPE, and acyclic (N5)/cyclic (<= N5) refers to the weight ratio of TEPA+AETAEA to PIP+AEP+PEEDA+DAEP+DPE+AEPEEDA+iAEPEEDA+AEDAEP+AEDPE+BPEA. The catalysts and promoters employed are identified as follows:

__________________________________________________________________________DESIGNATION COMPOSITION PHYSICAL PROPERTIES__________________________________________________________________________A Titanium dioxide (anatase), 2% Particle size: 1/16" cylindrical sulfur (presumed to be --OSO.sub.3 H) extrudates; Surface area: 188.4 content m.sup.2 /gm; Pore vol. Hg, cc/gm: 0.274; Med. Pore Diam., 0.0092; Crush strength, FPCS, LBS.: 10.8.B TiO.sub.2 (anatase)-.gamma.-Al.sub.2 O.sub.3 Particle size: 1/16" cylindrical extrudates TiO.sub.2 -.gamma.-Al.sub.2 O.sub.3 ; Catalyst surface area: 162.8 m.sub.2 /gm.; Pore vol. N.sub.2, cc/gm.: 0.338.C TiO.sub.2 (anatase)-SiO.sub.2 Particle size: 1/16: cylindrical extrudates; TiO.sub.2 --SiO.sub.2 ; Catalyst surface area: 210.9 m.sup.2 /gm.; Pore vol. N.sub.2, cc/gm.: 0.334.D Catalyst B/small amount of Particle size: 1/16" cylindrical H.sub.3 PO.sub.4 from diammonium extrudates TiO.sub.2 -.gamma.-Al.sub.2 O.sub.3 ; hydrogen phosphate Catalyst surface area: 162.8 m.sub.2 /gm.; Pore vol. N.sub.2, cc/gm.: 0.338.E Catalyst C/small amount of Particle size: 1/16" cylindrical H.sub.3 PO.sub.4 from diammonium extrudates TiO.sub.2 --SiO.sub.2 ; Catalyst hydrogen phosphate surface area: 210.9 m.sup.2 /gm.; Pore vol. N.sub.2, cc/gm.: 0.334.F Catalyst B/small amount of HF Particle size: 1/16" cylindrical from NH.sub.4 F extrudates TiO.sub.2 -.gamma.-Al.sub.2 O.sub.3 ; Catalyst surface area: 162.8 m.sub.2 /gm.; Pore vol. N.sub.2, cc/gm.: 0.338.G Catalyst B/small amount of Particle size: 1/16" cylindrical H.sub.2 SO.sub.4 from (NH.sub.4).sub.2 SO.sub.4 extrudates TiO.sub.2 -.gamma.-Al.sub.2 O.sub.3 ; Catalyst surface area: 162.8 m.sub.2 /gm.; Pore vol. N.sub.2, cc/gm.: 0.338.H Catalyst C/small amount of HF Particle size: 1/16: cylindrical from NH.sub.4 F extrudates; TiO.sub.2 --SiO.sub.2 ; Catalyst surface area: 210.9 m.sup.2 /gm.; Pore vol. N.sub.2, cc/gm.: 0.334.I Catalyst C/small amount of Particle size: 1/16: cylindrical H.sub.2 SO.sub.4 from (NH.sub.4).sub.2 SO.sub.4 extrudates; TiO.sub.2 --SiO.sub.2 ; Catalyst surface area: 210.9 m.sup.2 /gm.; Pore vol. N.sub.2, cc/gm.: 0.334.J TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch SnO cylindrical extrudates; Catalyst surface area: 125.0 m.sup.2 /gm.K TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch H.sub.3 BO.sub.3 cylindrical extrudates; Catalyst surface area: 154.0 m.sup.2 /gm.L TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch Nb.sub.2 O.sub.5 /H.sub.3 VO.sub.4 cylindrical extrudates; Catalyst surface area: 111.0 m.sup.2 /gm.M TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch La.sub.2 O.sub.3 /H.sub.3 PO.sub.4 cylindrical extrudates; Catalyst surface area 136.0 m.sup.2 /gm.N TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch La.sub.2 O.sub.3 cylindrical extrudates; Catalyst surface area: 136.0 m.sup.2 /gm.O TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch Nb.sub.2 O.sub.5 /H.sub.3 BO.sub.3 cylindrical extrudates; Catalyst surface area: 111.0 m.sup.2 /gm.P TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch H.sub.3 VO.sub.4 cylindrical extrudates; Catalyst surface area: 149 m.sup.2 /gm.Q TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch SnO/H.sub.3 PO.sub.4 cylindrical extrudates; Catalyst surface area: 125 m.sup.2 /gm.R TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 185 m.sup.2 /gm.S TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch SnO/H.sub.3 BO.sub.3 cylindrical extrudates; Catalyst surface area: 141 m.sup.2 /gm.T TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch La.sub.2 O.sub.3 /H.sub.3 VO.sub.4 cylindrical extrudates; Catalyst surface area: 148 m.sup.2 /gm.U TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Nb.sub.2 O.sub.5 /H.sub.3 PO.sub.4 cylindrical extrudates; Catalyst surface area: 129 m.sup.2 /gm.V TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Nb.sub.2 O.sub.5 cylindrical extrudates; Catalyst surface area: 146 m.sup.2 /gm.W TiO.sub.2 (anatase)/Al.sub. 2 O.sub.3 / Particle size: 1/16 inch La.sub.2 O.sub.3 /H.sub.3 BO.sub.3 cylindrical extrudates; Catalyst surface area: 135 m.sup.2 gm.X TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch SnO/H.sub.3 VO.sub.4 cylindrical extrudates; Catalyst surface area: 143 m.sup.2 /gm.Y TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch H.sub.3 PO.sub.4 cylindrical extrudates; Catalyst surface area: 150 m.sup.2 /gm.Z TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch La.sub.2 O.sub.3 /H.sub.3 PO.sub.4 cylindrical extrudates; Catalyst surface area: 139 m.sup.2 /gm.AA TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Na.sub.2 B.sub.4 O.sub.7 cylindrical extrudates; Catalyst surface area: 99 m.sup.2 /gm.BB TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Na.sub.2 SnO.sub.6 cylindrical extrudates; Catalyst surface area: 112 m.sup.2 /gm.CC ZrO.sub.2 /SiO.sub.2 Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 127 m.sup.2 /gm.DD ZrO.sub.2 /SiO.sub.2 / Particle size: 1/16 inch Nb.sub.2 O.sub.5 cylindrical extrudates; Catalyst surface area: 126 m.sup.2 /gm.EE ZrO.sub.2 /SiO.sub.2 / Particle size: 1/16 inch H.sub.3 BO.sub.3 cylindrical extrudates; Catalyst surface area: 126 m.sup.2 /gm.FF ZrO.sub.2 /SiO.sub.2 / Particle size: 1/16 inch NH.sub.4 VO.sub.3 (2 wt. % cylindrical extrudates; Catalyst as V.sub.2 O.sub.5) surface area: 169 m.sup.2 /gm.GG TiO.sub.2 (anatase)/SiO.sub.2 Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 169 m.sup.2 /gm.HH TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Al.sub.2 O.sub.3 cylindrical extrudates; Catalyst surface area: 204 m.sup.2 /gm.II TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch B.sub.2 O.sub.3 cylindrical extrudates; Catalyst surface area: 219 m.sup.2 /gm.JJ TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch NH.sub.4 HB.sub.2 O.sub.7 (2 wt. % cylindrical extrudates; Catalyst as B.sub.2 O.sub.3) surface area: 146 m.sup.2 /gm.KK TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch NH.sub.4 HB.sub.4 O.sub.7 /WO.sub.3 cylindrical extrudates; Catalyst surface area: 148 m.sup.2 /gm.LL TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch NH.sub.4 HB.sub.4 O.sub.7 /NH.sub.4 VO.sub.3 cylindrical extrudates; Catalyst surface area: 142 m.sup.2 /gm.MM TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch NH.sub.4 HB.sub.4 O.sub.7 /NH.sub.4 VO.sub.3 cylindrical extrudates; Catalyst surface area: 144 m.sup.2 /gm.NN TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch NH.sub.4 HB.sub.4 O.sub.7 /NaVO.sub.3 cylindrical extrudates; Catalyst surface area: 110 m.sup.2 /gm.OO TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch (NH.sub.4).sub.5 W.sub.12 O.sub.41 cylindrical extrudates; Catalyst surface area: 141 m.sup.2 /gm.PP TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch (NH.sub.4).sub.6 H.sub.2 W.sub.12 O.sub.41 cylindrical extrudates; Catalyst (8 wt. %) surface area: 156 m.sup.2 /gm.QQ TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Na.sub.2 WO.sub.4.9 WO.sub.3 cylindrical extrudates; Catalyst (2 wt. % as WO.sub.3) surface area: 145 m.sup.2 /gm.RR TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch V.sub.2 O.sub.5 cylindrical extrudates; Catalyst surface area: 127 m.sup.2 /gm.SS TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch NaVO.sub.3 (2 wt. %) cylindrical extrudates; Catalyst surface area: 83 m.sup.2 /gm.TT TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch La.sub.2 O.sub.3 /B.sub.2 O.sub.5 /WO.sub.3 cylindrical extrudates; Catalyst surface area: 152 m.sup.2 /gm.UU ZrO.sub.2 /SiO.sub.2 /TiO.sub.2 Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 127 m.sup.2 /gm.VV ZrO.sub.2 /SiO.sub.2 / Particle size: 1/16 inch (NH.sub.4).sub.6 H.sub.2 W.sub.12 O.sub.40 cylindrical extrudates; Catalyst (2 wt. % as WO.sub.3) surface area: 120 m.sup.2 /gm.WW TiO.sub.2 (anatase)/ Particle size: 1/16 inch (NH.sub.4).sub.2 HPO.sub.4 cylindrical extrudates; Catalyst surface area: 100 m.sup.2 /gm.XX TiO.sub.2 (rutile)/ Particle size: 1/16 inch (NH.sub.4).sub.2 HPO.sub.4 cylindrical extrudates; Catalyst surface area: 0.34 m.sup.2 /gm.YY TiO.sub.2 (rutile)/ Particle size: 1/16 inch H.sub.3 PO.sub.4 cylindrical extrudates; Catalyst surface area: 1.08 m.sup.2 /gm.ZZ TiO.sub.2 (anatase) Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 188.4 m.sup.2 /gm.AAA TiO.sub.2 (anatase)/SiO.sub.2 Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 186 m.sup.2 /gm.BBB TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch H.sub.3 BO.sub.3 cylindrical extrudates; Catalyst surface area: 154 m.sup.2 /gm.CCC TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch H.sub.3 VO.sub.4 cylindrical extrudates; Catalyst surface area: 146 m.sup.2 gm.DDD TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch NH.sub.4 BF.sub.4 /H.sub.3 PO.sub.4 cylindrical extrudates; Catalyst surface area: 94 m.sup.2 /gm.EEE TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch NaBF.sub.4 cylindrical extrudates; Catalyst surface area: 107 m.sup.2 /gm.FFF TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch H.sub.2 B.sub.4 O.sub.7 /H.sub.3 PO.sub.4 cylindrical extrudates; Catalyst surface area: 142 m.sup.2 /gm.GGG TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Nb.sub.2 O.sub.5 cylindrical extrudates; Catalyst surface area: 151 m.sup.2 /gm.HHH TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch ZrO.sub.2 cylindrical extrudates; Catalyst surface area: 151 m.sup.2 /gm.III TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Fe.sub.2 O.sub.3 cylindrical extrudates; Catalyst surface area: 142 m.sup.2 /gm.JJJ TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch SnO cylindrical extrudates; Catalyst surface area: 253 m.sup.2 /gm.KKK TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch H.sub.3 BO.sub.3 /H.sub.3 VO.sub.4 cylindrical extrudates; Catalyst surface area: 152 m.sup.2 /gm.LLL TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Na.sub.2 O cylindrical extrudates; Catalyst surface area: 151 m.sup.2 /gm.MMM TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch ZnO cylindrical extrudates; Catalyst surface area: 137 m.sup.2 /gm.NNN TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch La.sub.2 O.sub.3 cylindrical extrudates; Catalyst surface area: 134 m.sup.2 /gm.OOO TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 inch Li.sub.2 O cylindrical extrudates; Catalyst surface area: 127 m.sup.2 /gm.PPP TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 185 m.sup.2 /gm.QQQ TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch Na.sub.2 O cylindrical extrudates; Catalyst surface area: 117 m.sup.2 /gm.RRR TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch La.sub.2 O.sub.3 cylindrical extrudates; Catalyst surface area: 142 m.sup.2 /gm.SSS TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch La.sub.2 O.sub.3 /H.sub.3 PO.sub.4 cylindrical extrudates; Catalyst surface area: 115 m.sup.2 /gm.TTT TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch MgO cylindrical extrudates; Catalyst surface area: 137 m.sup.2 /gm.UUU TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch Li.sub.2 O cylindrical extrudates; Catalyst surface area: 105 m.sup.2 /gm.VVV TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch NaBF.sub.4 cylindrical extrudates; Catalyst surface area: 138 m.sup.2 /gm.WWW TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch SrO cylindrical extrudates; Catalyst surface area: 141 m.sup.2 /gm.XXX TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch H.sub.3 BO.sub.3 cylindrical extrudates; Catalyst surface area: 159 m.sup.2 /gm.YYY TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch ZnO cylindrical extrudates; Catalyst surface area: 141 m.sup.2 /gm.ZZZ TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch SnO cylindrical extrudates; Catalyst surface area: 125 m.sup.2 /gm.AAAA TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 / Particle size: 1/16 inch Fe.sub.2 O.sub.3 cylindrical extrudates; Catalyst surface area: 147 m.sup.2 /gm.BBBB Titanium dioxide (anatase)/ Particle size: 1/16 inch sodium trimetaphosphate; cylindrical extrudates; Ti:P atom ratio = 5.7:1 Catalyst surface area: 133.3 m.sup.2 /gm; Pore volume N.sub.2 : 0.344 cc/gm; Pore area: 83.5 m.sup.2 /gm; Bulk density: 1.55 gm/cc.CCCC Titanium dioxide (anatase)/ Particle size: 1/16 inch sodium tripolyphosphate; inch cylindrical extrudates; Ti:P atom ratio = 5.7:1 Catalyst surface area: 80.3 m.sup.2 /gm; Pore volume N.sub.2 : 0.236 cc/gm; Pore area: 54.2 m.sup.2 /gm; Bulk density: 1.72 gm/cc.DDDD Titanium dioxide (anatase)/ Particle size: 1/16 inch ABl; Ti:P atom ratio = cylindrical extrudates; 5.7:1 Catalyst surface area: 115.0 m.sup.2 gm; Pore volume N.sub.2 : 0.429 cc/gm; Pore area: 87.4 m.sup.2 /gm; Bulk density: 1/39 gm/cc.EEEE Titanium dioxide (anatase)/ Particle size: 1/16 inch sodium pyrophosphate; cylindrical extrudates; Ti:P atom ratio = 5.7:1 Catalyst surface area: 78.6 m.sup.2 /gm; Pore volume N.sub.2 : 0.339 cc/gm; Pore area 72.1 m.sup.2 /gm; Bulk density: 1.59 gm/cc.FFFF Titanium dioxide (anatase)/ Particle size: 1/16 inch ABl/boric acid (2 wt. %) cylindrical extrudates; Catalyst surface area: 97.1 m.sup.2 /gm; Pore volume N.sub.2 : 0.440 cc/gm; Pore area: 84.2 m.sup.2 /gm; Bulk density: 1.32 gm/cc.GGGG Titanium dioxide (anatase)/ Particle size: 1/16 inch ABl/ammonium tetra- cylindrical extrudates; fluoroborate Catalyst surface area: (2 wt. %) 39.6 m.sup.2 /gm; Pore volume N.sub.2 : 0.442 cc/gm; Pore area: 66.7 m.sup.2 /gm; Bulk density: 1.34 gm/cc.HHHH Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; sodium tetra- Catalyst surface area: 44.1 fluoroborate m.sup.2 /gm; Pore volume N.sub.2 : 0.432 (8 wt. %) cc/gm; Pore area: 69.1 m.sup.2 /gm; Bulk density: 1.35 gm/cc.IIII Titanium dioxide (anatase)/ Particle size: 1/16 inch ABl/sodium tetra- cylindrical extrudates; fluoroborate Catalyst surface area: 23.0 (8 wt. %) m.sup.2 /gm; Pore volume N.sub.2 : 0.373 cc/gm; Pore area: 36.6 m.sup.2 /gm; Bulk density: 1.57 gm/cc.JJJJ Titanium dioxide (anatase)/ Particle size: 1/16 inch ABl/sodium metatungstate cylindrical extrudates; (1 wt. %) Catalyst surface area: 91.3 m.sup.2 /gm; Pore volume N.sub.2 : 0.414 cc/gm; Pore area: 75.7 m.sup.2 /gm; Bulk density: 1.40 gm/cc.KKKK Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; sodium metatungstate Catalyst surface area: 101.2 (2 wt. %) m.sup.2 /gm; Pore volume N.sub.2 : 0.442 cc/gm; Pore area: 94.2 m.sup.2 /gm; Bulk density: 1.38 gm/cc.LLLL Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates: sodium metatungstate Catalyst surface area: 100.2 (4 wt. %) m.sup.2 /gm; Pore volume N.sub.2 : 0.429 cc/gm; Pore area: 90.0 m.sup.2 /gm; Bulk density: 1.43 gm/cc.MMMM Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; ammonium metatungstate Catalyst surface area: 97.9 (2 wt. % as WO.sub.3) m.sup.2 /gm; Pore volume N.sub.2 : 0.431 cc/gm; Pore area: 79.4 m.sup.2 /gm; Bulk density: 1.43 gm/cc.NNNN Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; ammonium metatungstate Catalyst surface area: 91.8 (4 wt. % as WO.sub.3) m.sup.2 /gm; Pore volume N.sub.2 : 0.402 cc/gm; Pore area: 69.2 m.sup.2 /gm; Bulk density: 1.51 gm/cc.OOOO Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; ammonium metatungstate Catalyst surface area: 78.1 (8 wt. % as WO.sub.3) m.sup.2 /gm; Pore volume N.sub.2 : 0.403 cc/gm; Pore area: 74.0 m.sup.2 /gm; Bulk density: 1.47 gm/cc.PPPP Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; lanthanum oxide Catalyst surface area: (2 wt. %) 102.8 m.sup.2 /gm; Pore volume N.sub.2 : 0.409 cc/gm; Pore area: 65.3 m.sup.2 /gm; Bulk density: 1.49 gm/cc.QQQQ Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; lanthanum oxide Catalyst surface area: (4 wt. %) 102.6 m.sup.2 /gm; Pore volume N.sub.2 : 0.418 cc/gm; Pore area: 85.4 m.sup.2 /gm; Bulk density: 1.41 gm/cc.RRRR Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; niobium oxide Catalyst surface area: (2 wt. %) 102.8 m.sup.2 /gm; Pore volume N.sub.2 : 0.435 cc/gm; Pore area: 85.5 m.sup.2 /gm; Bulk density: 1.35 gm/cc.SSSS Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; sodium bicarbonate Catalyst surface area: (2 wt. %) 99.5 m.sup.2 /gm; Pore volume N.sub.2 : 0.417 cc/gm; Pore area: 76.4 m.sup.2 /gm; Bulk density: 1.41 gm/cc.TTTT Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; vanadium oxide Catalyst surface area: (2 wt. %) 88.7 m.sup.2 /gm; Pore volume N.sub.2 : 0.411 cc/gm; Pore area: 63.9 m.sup.2 /gm; Bulk density: 1.44 gm/cc.UUUU Titanium dioxide Particle size: 1/16 inch (anatase)/SiO.sub.2 / cylindrical extrudates; Al.sub.2 O.sub.3 /sodium Catalyst surface area: 129.9 trimetaphosphate m.sup.2 /gm; Pore volume N.sub.2 : 0.321 (10 wt. %) cc/gm; Pore area: 163 m.sup.2 /gm; Bulk density: 1.59 gm/cc.VVVV Titanium dioxide Particle size: 1/16 inch (anatase)/SiO.sub.2 / cylindrical extrudates; B.sub.2 O.sub.3 /sodium Catalyst surface area: 159.5 trimetaphosphate m.sup.2 /gm; Pore volume N.sub.2 : 0.312 (10 wt. %) cc/gm; Pore area: 129.8 m.sup.2 /gm; Bulk density: 1.54 gm/cc.WWWW Titanium dioxide Particle size: 1/16 inch (anatase)/SiO.sub.2 / cylindrical extrudates; sodium trimetaphosphate Catalyst surface area: 136.5 (10 wt. %) m.sup.2 /gm; Pore volume N.sub.2 : 0.399 cc/gm; Pore area: 162.5 m.sup.2 /gm; Bulk density: 1.48 gm/cc.XXXX Titanium dioxide/ABl Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 4.40 m.sup.2 /gm; Pore volume N.sub.2 : 0.184 cc/gm; Pore area: 19.2 m.sup.2 /gm; Bulk density: 2.10 gm/cc.YYYY Titanium dioxide Particle size: 1/16 inch (anatase)/ABl cylindrical extrudates; Catalyst surface area: 102.0 m.sup.2 /gm; Pore volume N.sub.2 : 0.406 cc/gm; Pore area: 68.6 m.sup.2 /gm; Bulk density: 1.43 gm/cc.ZZZZ Magnesium oxide/ABl Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 18.1 m.sup.2 /gm; Pore volume N.sub.2 : 0.298 cc/gm; Pore area: 52.9 m.sup.2 /gm; Bulk density: 1.78 gm/cc.AAAAA Silicon dioxide/ABl Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 33.7 m.sup.2 /gm; Pore volume N.sub.2 : 0.496 cc/gm; Pore area: 81.0 m.sup.2 /gm; Bulk density: 1.06 gm/cc.BBBBB Aluminum oxide/ Particle size: 1/16 inch lanthanum metaphosphate cylindrical extrudates; Catalyst surface area: 86.0 m.sup.2 /gm; Pore volume N.sub.2 : 0.327 cc/gm; Pore area: 129.5 m.sup.2 /gm; Bulk density: 1.57 gm/cc.CCCCC Silicon dioxide/ Particle size: 1/16 inch lanthanum metaphosphate cylindrical extrudates; Catalyst surface area: 38.7 m.sup.2 /gm; Pore volume N.sub.2 : 0.656 cc/gm; Pore area: 90.5 m.sup.2 /gm; Bulk density: 0.99 gm/cc.DDDDD Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ZnO cylindrical extrudates; (2 wt. %) Catalyst surface area: 90.4 m.sup.2 /gm; Pore volume N.sub.2 : 0.427 cc/gm; Pore area: 74.5 m.sup.2 /gm; Bulk density: 1.49 gm/cc.EEEEE Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ZnO cylindrical extrudates; (4 wt. %) Catalyst surface area: 78.3 m.sup.2 /gm; Pore volume N.sub.2 : 0.412 cc/gm; Pore area: 75.1 m.sup.2 /gm; Bulk density: 1.42 gm/cc.FFFFF Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; Nb.sub.2 O.sub.5 (4 wt. %) Catalyst surface area: 102.2 m.sup.2 /gm; Pore volume N.sub.2 : 0.407 cc/gm; Pore area: 75.4 m.sup.2 /gm; Bulk density: 1.44 gm/cc.GGGGG Titanium dioxide Particle size: 1/16 inch (anatase)/ABl/ cylindrical extrudates; NaBF.sub.4 (8 wt. %) Catalyst surface area: 22.5 m.sup.2 /gm; Pore volume N.sub.2 : 0.421 cc/gm; Pore area: 55.8 m.sup.2 /gm; Bulk density: 1.38 gm/cc.HHHHH Titanium dioxide Particle size: 1/16 inch (anatase)/sodium cylindrical extrudates; dihydrogen phosphate; Catalyst surface area: Ti:P atom ratio = 5.7:1 117.1 m.sup.2 /gm; Pore volume N.sub.2 : 0.321 cc/gm; Pore area: 85.7 m.sup.2 /gm; Bulk density: 1.64 gm/cc.IIIII Titanium dioxide Particle size: 1/16 inch (anatase)/disodium cylindrical extrudates; dihydrogen pyrophosphate; Catalyst surface area: Ti:P atom ratio = 5.7:1 133.5 m.sup.2 /gm; Pore N.sub.2 : 0.291 cc/gm; Pore area: 89.6 m.sup.2 /gm; Bulk density: 1.66 gm/cc.JJJJJ Titanium dioxide Particle size: 1/16 inch (anatase)/disodium cylindrical extrudates; hydrogen phosphate; Catalyst surface area: Ti:P atom ratio = 5.7:1 117/4 m.sup.2 /gm; Pore volume N.sub.2 : 0.346 cc/gm; Pore area 86.5 m.sup.2 /gm; Bulk density: 1.53 gm/cc.KKKKK Titanium dioxide Particle size: 1/16 inch (anatase)/sodium cylindrical extrudates; phosphate; Ti:P Catalyst surface area: 88.4 atom ratio = 5.7:1 m.sup.2 /gm; Pore volume N.sub.2 : 0.365 cc/gm; Pore area: 76.90 m.sup.2 /gm; Bulk density: 1.48 gm/cc.LLLLL TiO.sub.2 (anatase)/ Particle size: (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 1/16 inch cylindri- (15 wt. % W). cal extrudates; TiO.sub.2 surface area: 200 m.sup.2 /gm.MMMMM TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 inch cylindrical (15 wt. % W); TiO.sub.2 /SiO.sub.2 extrudates; TiO.sub.2-- wt. ratio = 88/12. SiO.sub.2 surface area: 175 m.sup.2 /gm.NNNNN ZrO.sub.2 /SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 inch cylindrical (15 wt. % W). extrudates; ZrO.sub.2 -- SiO.sub.2 surface area: 127 m.sup.2 /gm.OOOOO TiO.sub.2 (anatase)/SiO.sub.2 Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 inch cylindrical (7.5 wt. % W); extrudates; TiO.sub.2 -- TiO.sub.2 /SiO.sub.2 wt. ratio = 88/12. SiO.sub.2 surface area: 175 m.sup.2 /gm.PPPPP TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 inch cylindrical (15 wt. % W)/La.sub.2 O.sub.3 extrudates; TiO.sub.2 -- (1 wt. % La); SiO.sub.2 surface area: TiO.sub.2 /SiO.sub.2 wt. ratio = 88/12. 175 m.sup.2 /gm.QQQQQ TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 inch cylindrical (7.5 wt. % W)/La.sub.2 O.sub.3 extrudates; TiO.sub.2 -- (0.5 wt. % La); SiO.sub.2 surface area: TiO.sub.2 /SiO.sub.2 wt. ratio = 88/12. 175 m.sup.2 /gm.RRRRR ZrO.sub.2 /SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 inch cylindrical (15 wt. % W)/ extrudates; ZrO.sub.2 -- La.sub.2 O.sub.3 (1.0 wt. % La). SiO.sub.2 surface area: 127 m.sup.2 /gm.SSSSS TiO.sub.2 (anatase)/SiO.sub.2 /WO.sub.3 Particle size: 1/16 (3.0 wt. % WO.sub.3) inch cylindrical extrudates; Cata- lyst surface area: 234 m.sup.2 /gm.TTTTT TiO.sub.2 (anatase)/SiO.sub.2 /WO.sub.3 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 inch cylindrical (7.5 wt. % W) extrudates; TiO.sub.2 -- SiO.sub.2 --WO.sub.3 surface area: 234 m.sup.2 /gm.UUUUU TiO.sub.2 (anatase)/SiO.sub.2 /SiO.sub.2 12 WO.sub.3. Particle size: 1/16 26 H.sub.2 O (7.5 wt. % W). inch cylindrical extrudates; TiO.sub.2 -- SiO.sub.2 surface area: 175 m.sup.2 /gm.VVVVV TiO.sub.2 (anatase)/SiO.sub.2 /Al.sub.2 O.sub.3 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 inch cylindrical (7.5 wt. % W). extrudates; TiO.sub.2 -- SiO.sub.2 --Al.sub.2 O.sub.3 surface area: 175 m.sup.2 /gm.WWWWW TiO.sub.2 (anatase)/Al.sub.2 O.sub.3 /SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 (7.5 wt. % inch cylindrical extrudates; TiO.sub.2 -- Al.sub.2 O.sub.3 --SiO.sub.2 surface area: 175 m.sup.2 /gm.XXXXX TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 (7.5 wt. % inch cylindrical TiO.sub.2 /SiO.sub.2 wt. ratio = 70/30. extrudates; TiO.sub.2 -- SiO.sub.2 surface area: 195 m.sup.2 /gm.YYYYY TiO.sub.2 (anatase). Particle size: 1/16 inch cylindrical extrudates; Cata- lyst surface area: 200 m.sup.2 /gm.ZZZZZ TiO.sub.2 (anatase)/SiO.sub.2 ; Particle size: 1/16 TiO.sub.2 /SiO.sub.2 wt. ratio = 70/30. inch cylindrical extrudates; Cata- lyst surface area: 195 m.sup.2 /gm.AAAAAA TiO.sub.2 (anatase)/SiO.sub.2 ; TiO.sub.2 /SiO.sub.2 Particle size: 1/16 wt. ratio = 88/12. inch cylindrical extrudates; Cata- lyst surface area: 175 m.sup.2 /gm.BBBBBB ZrO.sub.2 /SiO.sub.2. Particle size: 1/16 inch cylindrical extrudates; Cata- lyst surface area: 127 m.sup.2 /gm.CCCCCC .gamma.-Al.sub.2 O.sub.3 /(NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 Particle size: 1/16 (7.5 wt. % W). inch cylindrical extrudates; .gamma.-Al.sub.2 O.sub.3 surface area: 105 m.sup.2 /gm.DDDDDD TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 (7.5 wt. % inch cylindrical TiO.sub.2 /SiO.sub.2 wt. ratio = 70/30. extrudates; TiO.sub.2 -- SiO.sub.2 surface area: 195 m.sup.2 /gm.EEEEEE TiO.sub.2 (anatase)/SiO.sub.2 /WO.sub.3 Particle size: 1/16 (7 wt. % WO.sub.3). inch cylindrical extrudates; Catalyst surface area: 224 m.sup.2 /gm.FFFFFF TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 (7.5 wt. % inch cylindrical B.sub.2 O.sub.3 (1.0 wt. % B). extrudates; TiO.sub.2 -- SiO.sub.2 surface area: 195 m.sup.2 /gm.GGGGGG TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 (7.5 wt. % inch cylindrical ZnO (1.0 wt. % Zn); extrudates; TiO.sub.2 -- TiO.sub.2 /SiO.sub.2 wt. ratio = 70/30. SiO.sub.2 surface area: 195 m.sup.2 /gm.HHHHHH TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 (7.5 wt. % inch cylindrical ThO.sub.2 (1.0 wt. % Th); extrudates; TiO.sub.2 -- TiO.sub.2 /SiO.sub.2 wt. ratio = 70/30. SiO.sub.2 surface area: 195 m.sup.2 /gm.IIIIII TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 (7.5 wt. % inch cylindrical NH.sub.4 F--HF (1.0 wt. % F); extrudates; TiO.sub.2 -- TiO.sub.2 /SiO.sub.2 wt. ratio = 70/30. SiO.sub.2 surface area: 195 m.sup.2 /gm.JJJJJJ TiO.sub.2 (anatase)/SiO.sub.2 / Particle size: 1/16 (NH.sub.4).sub.6 H.sub.6 W.sub.12 O.sub.40 (7.5 wt. % inch cylindrical CeO.sub.2 (1.0 wt. % Ce); extrudates; TiO.sub.2 -- TiO.sub.2 /SiO.sub.2 wt. ratio = 70/30. SiO.sub.2 surface area: 195 m.sup.2 /gm.KKKKKK TiO.sub.2 (anatase)/WO.sub.3 (10 wt. % WO.sub.3). Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 253 m.sup.2 /gm.LLLLLL SiO.sub.2 /WO.sub.3 (10 wt. % WO.sub.3). Particle size: 1/16 inch cylindrical extrudates; Catalyst surface area: 144 m.sup.2 /gm.MMMMMM TiO.sub.2 (anatase)/SiO.sub.2 ; TiO.sub.2 /SiO.sub.2 Particle size: 1/16 wt. ratio = 40/60 inch cylindrical extrudates; Catalyst surface area: 201 m.sup.2 /gm.__________________________________________________________________________

For each run in Tables I-XXIV and XLV-LXXI, the tubular reaction system was brought up to the desiqnated conditions. The ammonia feed was established first, then the EDA-MEA, DETA-AEEA or DETA MEA feed, as appropriate. After a sufficient line out period, a two hour timed run was conducted, then the experiment was run overnight and sampled. The feed was changed to another reactant set and the above procedure was repeated for each of the examples in Tables I-XXIV and XLV-LXXI.

For each run in Tables XXV-XLIV and LXXII-CXXXV, the tubular reaction system was brought up to the designated conditions. The premixed ammonia-DETA feed was established first, then the DETA-MEA feed. After a sufficient line out period, a two hour timed run was conducted and a sample taken. The temperature was then adjusted for the next experiment. This procedure was repeated for each of the examples in Tables XXV-XLIV and LXXII-CXXXV.

The catalysts employed in the examples hereinafter were prepared as follows:

Diammonium hydrogen phosphate preparation to provide a performance moderator: Catalyst pellets (150 cc) were added to a saturated solution of diammonium hydrogen phosphate in water. Enough solution was added to completely immerse the pellets. The slurry was allowed to stand at a temperature of 55.degree.-60.degree. C. for a period of 8 hours. The catalyst was filtered, washed with water until the wash water was neutral, dried at a temperature of 100.degree. C., and then calcined at a temperature of 600.degree. C. for a period of 6-8 hours.

Hydrogen fluoride preparation to provide a performance moderator: Catalyst pellets (150 cc) were added to a saturated solution of ammonium fluoride in water. Enough solution was added to completely immerse the pellets. The slurry was allowed to stand at a temperature of 55.degree.-60.degree. C. for a period of 8 hours. The catalyst was filtered, washed with water until the wash water was neutral, dried at a temperature of 100.degree. C., and then calcined at a temperature of 600.degree. C. for a period of 6-8 hours.

Sulfuric acid preparation to provide a performance moderator: Catalyst pellets (150 cc) were added to a saturated solution of ammonium sulphate in water. Enough solution was added to completely immerse the pellets. The slurry was allowed to stand at a temperature of 55.degree.-60.degree. C. for a period of 8 hours. The catalyst was filtered, washed with water until the wash water was neutral, dried at a temperature of 100.degree. C., and then calcined at a temperature of 600.degree. C. for a period of 6-8 hours.

Catalyst J Preparation: Tin (II) ethylene glycoxide (9.88 grams) was dissolved in 150 milliliters of monoethanolamine. The resulting solution was diluted with isopropanol (80 milliliters) and the TiO.sub.2 Al.sub.2 O.sub.3 support (280 grams) was impregnated. The support turned yellow. After a period of 1 hour, the catalyst was filtered and washed with excess isopropanol, dried and then calcined at a temperature of 600.degree. C. for a period of 16 hours. The catalyst was divided into 2 equal parts--one part was used to make Catalyst Q.

Catalyst K Preparation: Boric acid (2.86 grams) was dissolved in just enough water to impregnate the TiO.sub.2 /SiO.sub.2 support (140 grams). The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst L Preparation: The TiO.sub.2 /Al.sub.2 O.sub.3 support (280 grams) was impregnated with niobium pentoxide-toluene solution (13.68 grams of niobium pentoxide). Excess toluene was removed under reduced pressure on a Buchi rotary evaporator. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. The catalyst was divided into 2 equal parts. One part was impregnated with ammonium vanadate (2.83 grams) dissolved in water. This catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. The second part was used to make Catalyst O described below.

Catalyst M Preparation: The TiO.sub.2 /SiO.sub.2 support (280 grams) was impregnated with lanthanum nitrate (7.59 grams) in sufficient water to wet all of the support. The wet catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. The catalyst (140 grams) was then soaked in 85% phosphoric acid for a period of 1 hour and washed with water until neutral. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst N Preparation: The TiO.sub.2 /SiO.sub.2 support (280 grams) was impregnated with lanthanum nitrate (7.59 grams) in sufficient water to wet all of the support. The wet catalyst was dried at a temperature of 100.degree. C. and then calcined at a 78mperature of 400.degree. C. for a period of 16 hours.

Catalyst O Preparation: The second part of Catalyst L greenware was impregnated with boric acid (2.86 grams) in sufficient water to wet the support The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst P Preparation: Ammonium vanadate (2.83 grams) was dissolved in sufficient water to impregnate the TiO.sub.2 /SiO.sub.2 support (140 grams). The wet catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst Q Preparation: The second part of Catalyst J greenware was impregnated with 85% phosphoric acid for a period of 1 hour and then washed with water until neutral. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst R Preparation: The TiO.sub.2 Al.sub.2 O.sub.3 support was used without further treatment.

Catalyst S Preparation: Tin (II) ethylene glycoxide (9.88 grams) was dissolved in 150 milliliters of monoethanolamine and the TiO.sub.2 /SiO.sub.2 support (280 grams) was impregnated therewith. The TiO.sub.2 /SiO.sub.2 support turned yellow. After a period of 1 hour, the catalyst was filtered and washed with excess isopropanol to remove excess monoethanolamine. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours The catalyst was divided into 2 equal parts. One part was impregnated with boric acid (2.86 grams) dissolved in sufficient water to wet the support. This catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. The second part was used to make Catalyst X described below.

Catalyst T Preparation: The TiO.sub.2 /Al.sub.2 O.sub.3 support (280 grams) was impregnated with lanthanum nitrate (7.59 grams) in sufficient water to wet the support. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. The catalyst was then impregnated with ammonium vanadate (2.83 grams) in sufficient water to wet the support. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst U Preparation: The TiO.sub.2 /SiO.sub.2 support (280 grams) was impregnated with niobium pentoxide in toluene (13.68 grams). Excess toluene was removed under reduced pressure on a Buchi rotary evaporator. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. The catalyst was divided into 2 equal parts. One portion was impregnated with 85% phosphoric acid for a period of 1 hour and then washed with water until neutral. The wet catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. The second part was used as Catalyst V described below.

Catalyst V Preparation: The second part of Catalyst U prior to impregnation with phosphoric acid was used without further treatment.

Catalyst W Preparation: The TiO.sub.2 Al.sub.2 O.sub.3 support (280 grams) was impregnated with lanthanum nitrate (7.59 grams) in sufficient water to wet the support. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. The catalyst was then impregnated with boric acid (2.86 grams) in sufficient water to wet the support. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst X Preparation: The second part of Catalyst S greenware was impregnated with ammonium vanadate (2.83 grams) in sufficient water to wet the support. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst Y Preparation: The TiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams) was impregnated with 85% phosphoric acid for a period of 1 hour and then washed with water until neutral. The wet catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst Z Preparation: The TiO.sub.2 /Al.sub.2 O.sub.3 support (280 grams) was impregnated with lanthanum nitrate (7.59 grams) in sufficient water to wet all of the support. The wet catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. The catalyst (140 grams) was then soaked in 85% phosphoric acid for a period of 1 hour and washed with water until neutral. The catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours

Catalyst AA Preparation: Sodium tetraborate (21 grams) was dissolved in water (112 grams) and used to impregnate the TiO.sub.2 /SiO.sub.2 support (140 grams). After a period of 1 hour, excess liquid was decanted and the material dried at a temperature of 100.degree. C. for a period of 1 hour. The catalyst was then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst BB Preparation: Sodium stannate (21 grams) was dissolved in just enough water (56.4 grams) to impregnate the TiO.sub.2 /SiO.sub.2 support (140 grams). After a period of 1 hour, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst CC Preparation: The ZrO.sub.2 /SiO.sub.2 support was used without further treatment.

Catalyst DD Preparation: A solution of niobium pentethoxide (25.28 grams) in toluene (84.18 grams) was prepared. The ZrO.sub.2 /SiO.sub.2 support (140 grams) was slurried with toluene (75 milliliters) and then the niobium pentethoxide solution (29.6 grams) was added. Excess toluene was removed under reduced pressure and the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour. The catalyst was then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst EE Preparation: Boric acid (2.86 grams) was dissolved in methanol (75 milliliters) and the ZrO.sub.2 /SiO.sub.2 support (140 grams) was impregnated with this solution. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst FF Preparation: Ammonium metavanadate (2.86 grams) was dissolved in water (75 milliliters) and the ZrO.sub.2 /SiO.sub.2 support (140 grams) was impregnated with this solution. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst GG Preparation: The TiO.sub.2 /SiO.sub.2 support was used without further treatment.

Catalyst HH Preparation: The TiO.sub.2 /SiO.sub.2 Al.sub.2 O.sub.3 support was used without further treatment.

Catalyst II Preparation: Boric acid (2.86 grams) was dissolved in just enough water to impregnate the TiO.sub.2 /SiO.sub.2 support (140 grams). The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and the calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst JJ Preparation: Ammonium hydrogentetraborate (4.19 grams) was dissolved in water (104.3 grams) to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour, the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst KK Preparation: Ammonium hydrogentetraborate (4.19 grams) and ammonium tungstate (5.89 grams) were dissolved in sufficient water (95.45 grams) to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst LL Preparation: Ammonium hydrogentetraborate (4.19 grams) and ammonium vanadate (5.62 grams) were dissolved in sufficient water (170.2 grams) to dissolve the inorganic salts. The TiO.sub.2 /SiO.sub.2 support (140 grams) was immersed in this solution for a period of 1 hour. Excess liquid was decanted and the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour. The catalyst was then calcined at a temperature of 600.degree. C. for a period of 16 hours.

Catalyst MM Preparation: Ammonium hydrogentetraborate (4.19 grams) and ammonium vanadate (5.62 grams) were dissolved in sufficient hot water (176 grams). The TiO.sub.2 /SiO.sub.2 support (140 grams) was added to the hot solution, stirred well and then allowed to cool to room temperature The catalyst slurry was transferred to a round bottom flask and stripped under reduced pressure using a Buchi evaporator. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst NN Preparation: Ammonium hydrogentetraborate (4.19 grams) was dissolved in sufficient water (94 grams) to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour, the catalyst was dried at a temperature of 100.degree. C. and then calcined at a temperature of 400.degree. C. for a period of 16 hours. Sodium vanadate (5.85 grams) was dissolved in water (94 grams) sufficient to wet the calcined material. After an impregnation period of 1 hour, the catalyst was redried at a temperature of 100.degree. C. and calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst OO Preparation: Ammonium metatungstate (3.12 grams) was dissolved in a sufficient amount of water (103 grams) to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst PP Preparation: Ammonium metatungstate (12.26 grams) was dissolved in a sufficient amount of water (94 grams) to wet the TiO.sub.2 /SiO.sub.2 support (140 grams) The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst QQ Preparation: Sodium metatungstate (2.86 grams) was dissolved in sufficient water (88.4 grams) to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst RR Preparation: A solution of vanadium triisopropoxide (7.60) grams in toluene (76.85 grams) was prepared and added to the TiO.sub.2 /SiO.sub.2 support (140 grams) in a round bottom flask on a Buchi evaporator. After mixing for a period of 1 hour, excess toluene was removed under reduced pressure and the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst SS Preparation: Sodium vanadate (21 grams) was dissolved in water (84.3 grams). A small amount (2.55 grams) did not dissolve and this was removed by filtration. The solution was poured over the TiO.sub.2 /SiO.sub.2 support with stirring. Excess liquid (14.85 grams) was removed and the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst TT Preparation: Boric acid (2.97 grams), lanthanum nitrate (10.39 grams) and ammonium tungstate (6 13 grams) were dissolved in water (94 grams) and the TiO.sub.2 /SiO.sub.2 support (140 grams) was impregnated with the solution. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst UU Preparation: Titanium isopropoxide (10 25 grams) was dissolved in toluene (45.44 grams). This solution was used to impregnate the ZrO.sub.2 /SiO.sub.2 support (140 grams). Excess toluene was removed under reduced pressure. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst VV Preparation: Ammonium tunqstate (3.12 grams) was dissolved in a sufficient amount of water (63.24 grams) to wet the ZrO.sub.2 /SiO.sub.2 support (140 grams). After impregnation for a period of 1 hour at room temperature, the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst WW Preparation: Diammonium hydrogen phosphate (65 grams) was dissolved in water (50 grams) in a round bottom flask and anatase TiO.sub.2 (150 cubic centimeters) was added to the flask. The flask was rotated on a Buchi rotary evaporator under reduced pressure for a period of 2 hours. The resulting slurry was filtered, washed with water (100 milliliters) and dried at a temperature of 100.degree. C. for a period of 1 hour and then at a temperature of 250.degree. C. for overnight.

Catalyst XX Preparation: Diammonium hydrogen phosphate (65 grams) was dissolved in water (50 grams) in a round bottom flask and rutile TiO.sub.2 (150 cubic centimeters) was added to the flask. The flask was rotated on a Buchi rotary evaporator under reduced pressure for a period of 2 hours. The resulting slurry was filtered, washed with water (100 milliliters) and dried at a temperature of 100.degree. C. for a period of 1 hour and then at a temperature of 250.degree. C. for overnight.

Catalyst YY Preparation: Orthophosphoric acid (52 grams), water (50 grams) and TiO.sub.2 (171.11 grams) were placed in a flask on a Buchi rotary evaporator at a pressure of 210 millimeters Hg for a period of 2 hours. The catalyst was filtered and washed with distilled water (2500 milliliters) to pH 6, dried at a temperature of 100.degree. C. for a period of 1 hour and then at a temperature of 250.degree. C. for a period of 16 hours. The resulting catalyst (171.11 grams) was slurried with phosphoric acid (52.37 grams) and water (50.05 grams) for a period of 2 hours on a Buchi rotary evaporator at a pressure of 310 mm Hg, filtered, washed with water (100 milliliters), evaporated dry and heated at a temperature of 100.degree. C. for a period of 1 hour and then at a temperature of 250.degree. C. for a period of 16 hours.

Catalyst ZZ Preparation: The TiO.sub.2 support was used without further treatment.

Catalyst AAA Preparation: Obtained from Norton Company, Akron, Ohio.

Catalyst BBB Preparation: Boric acid (1.81 grams) was mixed in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (100 grams). After an impregnation period of 1 hour, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst CCC Preparation: Ammonium vanadate (2.63 grams) was mixed in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst DDD Preparation: Ammonium tetrafluoroborate (8.39 grams) and diammonium hydroqen phosphate (10.52 grams) were dissolved in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst EEE Preparation: Sodium tetrafluoroborate (2.86 grams) was dissolved in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst FFF Preparation: Ammonium hydrogen tetraborate (4.18 grams) and diammonium hydrogen phosphate (10.52 grams) were dissolved in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was dried at a temperature of 100.degree. C. for a period of 8 hours and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst GGG Preparation: Niobium pentoxide (13.67 grams) dissolved in toluene (approximately 200 milliliters) was used to wet the TiO.sub.2 /SiO.sub.2 support (280 grams). After an impregnation period of 15 minutes at room temperature, toluene was removed under reduced pressure and the catalyst was dried at a temperature of 100.degree. C. for a period of 8 hours and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst HHH Preparation: Zirconium n-propoxide (7.59 grams) dissolved in toluene (62 grams) was used to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After standing overnight under a cover at room temperature, the catalyst was stripped under reduced pressure and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst III Preparation: Ferric nitrate 9H.sub.2 O (7.21 grams) was dissolved in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst JJJ Preparation: Tin (II) acetate (95%) (4.42 grams) was dissolved in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst KKK Preparation: Ammonium hydroqen borate (2.53 grams) and ammonium vanadate (5.62 grams) were dissolved at a temperature of 75.degree. C. in excess water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). The excess water was then evaporated. After an impregnation period of 1 hour, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst LLL Preparation: Sodium bicarbonate (4.15 grams) was dissolved in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (100 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst MMM Preparation: Zinc nitrate hexahydrate (10 44 grams) was dissolved in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst NNN Preparation: Lanthanum nitrate hexahydrate (3.79 grams) was dissolved in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst OOO Preparation: Lithium acetate dihydrate (9.74 grams) was dissolved in sufficient water to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst PPP Preparation: Obtained from Norton Company, Akron, Ohio.

Catalyst QQQ Preparation: Sodium bicarbonate (4.15 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (100 rams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst RRR Preparation: Lanthanum nitrate hexahydrate (3.79 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst SSS Preparation: Lanthanum nitrate hexahydrate (4.29 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (160 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours. This material (140 grams) was slurried with 85% phosphoric acid (90 milliliters) for a period of 1 hour, filtered, washed with water until pH of 6.5 and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst TTT Preparation: Magnesium nitrate hexahydrate (18.17 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst UUU Preparation: Lithium acetate dihydrate (9.74 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst VVV Preparation: Sodium tetrafluoroborate (2.86 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst WWW Preparation: Strontium nitrate (5.84 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst XXX Preparation: Boric acid (1.81 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (100 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst YYY Preparation: Zinc nitrate hexahydrate (10.44 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst ZZZ Preparation: Stannous acetate (95%) (4.42 grams) was dissolved in hot monoethanolamine, diluted with isopropanol (30 grams) and slurried with the TiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour. Excess liquid was then drained off. The catalyst was washed with isopropanol and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst AAAA Preparation: Ferric nitrate 9H.sub.2 O (7.21 grams) was dissolved in sufficient water to wet the TiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams). After an impregnation period of 1 hour at room temperature, the catalyst was calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst BBBB: Obtained from Norton Company, Akron, Ohio.

Catalyst CCCC: Obtained from Norton Company, Akron, Ohio.

Catalyst DDDD: Obtained from Norton Company, Akron, Ohio.

Catalyst EEEE: Obtained from Norton Company, Akron, Ohio.

Catalyst FFFF: Catalyst DDDD pellets (140 grams) were added to a solution of boric acid (5.07 grams) in methanol (94.2 grams). The methanol was removed using a Buchi rotary evaporator. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst GGGG: Catalyst DDDD pellets (140 grams) were added to a solution of ammonium tetrafluoroborate (2.86 grams) in water. Enough solution was prepared to completely wet the pellets. The resulting slurry was allowed to stand for a period of 1 hour at room temperature. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst HHHH: Catalyst DDDD pellets (140.1 grams) were added to a solution of sodium tetrafluoroborate (8.58 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst IIII: Catalyst DDDD pellets (140.1 grams) were added to a solution of sodium tetrafluoroborate (8.58 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst JJJJ: Catalyst DDDD pellets (140.2 grams) were added to a solution of sodium metatungstate (1.43 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst KKKK: Catalyst DDDD pellets (140.2 grams ) were added to a solution of sodium metatungstate (2.86 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst LLLL: Catalyst DDDD pellets (140.1 grams) were added to a solution of sodium metatungstate (5.71 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst MMMM: Catalyst DDDD pellets (140.1 grams) were added to a solution of ammonium metatungstate (3 12 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst NNNN: Catalyst DDDD pellets (140 grams) were added to a solution of ammonium metatungstate (6.24 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst 0000: Catalyst DDDD pellets (140.1 grams) were added to a solution of ammonium metatungstate (12.48 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst PPPP: Catalyst DDDD pellets (140.1 grams) were added to a solution of lanthanum nitrate hexahydrate (7.59 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst QQQQ: Catalyst DDDD pellets (143.1 grams) were added to a solution of lanthanum nitrate hexahydrate (15.18 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst RRRR: Catalyst DDDD pellets (140 grams) were added to a solution of niobium pentethoxide (6 84 grams) in toluene (66 grams). Enough solution was added to completely immerse the pellets. The resulting slurry was stripped on a Buchi rotary evaporator The catalyst was then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst SSSS: Catalyst DDDD pellets (140.4 grams) were added to a solution of sodium bicarbonate (3.87 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst TTTT: Catalyst DDDD pellets (143.5 grams) were added to a solution of vanadium triisopropoxide (7.63 grams) in toluene (66.74 grams). Enough solution was added to completely wet the pellets. The resulting slurry was stripped under reduced pressure. The catalyst was then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst UUUU: Sodium trimetaphosphate (14.0 grams) was dissolved in a sufficient amount of water (82 7 grams) to wet the TiO.sub.2 /SiO.sub.2 /Al.sub.2 O.sub.3 support (140 grams). After impregnation for a period of 1 hour at room temperature, the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst VVVV: Sodium trimetaphosphate (14.13 grams) were dissolved in water (56.0 grams) and isopropanol (87.0 grams). The TiO.sub.2 /SiO.sub.2 support (140 grams) was impregnated with the solution. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst WWWW: Sodium trimetaphosphate (14.05 grams) was dissolved in a sufficient amount of water (85 92 grams) to wet the TiO.sub.2 /SiO.sub.2 support (140 grams). After impregnation for a period of 1 hour at room temperature, the catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C for a period of 16 hours.

Catalyst XXXX: Obtained from Norton Company, Akron, Ohio.

Catalyst YYYY: Obtained from Norton Company, Akron, Ohio.

Catalyst ZZZZ: Obtained from Norton Company, Akron, Ohio.

Catalyst AAAAA: Obtained from Norton Company, Akron, Oh.:o.

Catalyst BBBBB: Obtained from Norton Company, Akron, Ohio.

Catalyst CCCCC: Obtained from Norton Company, Akron, Ohio.

Catalyst DDDDD: Catalyst DDDD pellets (140.5 grams) were added to a solution of zinc nitrate hexahydrate (10.45 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst EEEEE: Catalyst DDDD pellets (140.78 grams) were added to a solution of zinc nitrate hexahydrate (20.88 grams) in sufficient water to completely wet the pellets The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst FFFFF: Catalyst DDDD pellets (140.1 grams) were added to a solution of niobium pentethoxide (13.68 grams) in toluene (66.2 grams). Enough solution was added to completely wet the pellets. The resulting slurry was allowed to stand for a period of 1 hour. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst GGGGG: Catalyst DDDD pellets (140.15 grams) were added to a solution of sodium tetrafluoroborate (8.58 grams) in sufficient water to completely wet the pellets. The catalyst was dried at a temperature of 100.degree. C. for a period of 1 hour and then calcined at a temperature of 400.degree. C. for a period of 16 hours.

Catalyst HHHHH: Obtained from Norton Company, Akron, Ohio.

Catalyst IIIII: Obtained from Norton Company, Akron, Ohio.

Catalyst JJJJJ: Obtained from Norton Company, Akron, Ohio.

Catalyst KKKKK: Obtained from Norton Company, Akron, Ohio.

Catalyst LLLLL Preparation: Ammonium metatungstate (12.14 grams) was dissolved in water (60 grams) and an aliquot sufficient to wet the TiO.sub.2 support (140 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst MMMMM Preparation: Ammonium metatungstate (12.14 grams) was dissolved in water (48 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst NNNNN Preparation: Ammonium metatungstate (12.14 grams) was dissolved in water (48 grams) and an aliquot sufficient to wet the ZrO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst OOOOO Preparation: Ammonium metatungstate (6.07 grams) was dissolved in water (45 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst PPPPP Preparation: Ammonium metatungstate (12.14 grams) and lanthanum nitrate (5.0 grams) were dissolved in water (45 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst QQQQQ Preparation: Ammonium metatungstate (6.07 grams) and lanthanum nitrate (2.5 grams) were dissolved in water (45 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst RRRRR Preparation: Ammonium metatungstate (12.14 grams) and lanthanum nitrate (5.0 grams) were dissolved in water (45 grams) and an aliquot sufficient to wet the ZrO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst SSSSS Preparation: Obtained from Norton Company, Akron, Ohio.

Catalyst TTTTT Preparation: Ammonium metatungstate (6.07 grams) was dissolved in water (35 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 /WO.sub.3 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst UUUUU Preparation: Silicotungstic acid (6 8 grams) was dissolved in water (40 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst VVVVV Preparation: Ammonium metatungstate (6.07 grams) was dissolved in water (40 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 /Al.sub.2 O.sub.3 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst WWWWW Preparation: Ammonium metatungstate (6.07 grams) was dissolved in water (40 grams) and an aliquot sufficient to wet the TiO.sub.2 /Al.sub.2 O.sub.3 /SiO.sub.2 support was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst XXXXX Preparation: Ammonium metatungstate (6.07 grams) was dissolved in water (40 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst YYYYY Preparation: Obtained from LaRoche Chemical Company, Cleveland, Ohio.

Catalyst ZZZZZ Preparation: Obtained from Norton Company, Akron, Ohio.

Catalyst AAAAAA Preparation: Obtained from Norton Company, Akron, Ohio.

Catalyst BBBBBB Preparation: Obtained from Norton Company, Akron, Ohio.

Catalyst CCCCCC Preparation: Ammonium metatungstate (11.42 grams) was dissolved in water (45 grams) and an aliquot sufficient to wet the .gamma.-Al.sub.2 O.sub.3 support (52 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst DDDDDD Preparation: Ammonium metatungstate (6.07 grams) was dissolved in water (40 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst EEEEEE Preparation: Obtained from Norton Company, Akron, Ohio.

Catalyst FFFFFF Preparation: Ammonium metatungstate (6.07 grams) and boric acid (3.14 grams) were dissolved in water (30 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst GGGGGG Preparation: Ammonium metatungstate (6.07 grams) and zinc nitrate (1.6 grams) were dissolved in water (30 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst HHHHHH Preparation: Ammonium metatungstate (6.07 grams) and thorium nitrate (1.31 grams) were dissolved in water (35 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst IIIIII Preparation: Ammonium metatungstate (6.07 grams) and ammonium bifluoride (0.82 grams) were dissolved in water (35 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst JJJJJJ Preparation: Ammonium metatungstate (6.07 grams) and cerium nitrate (1.71 grams) were dissolved in water (35 grams) and an aliquot sufficient to wet the TiO.sub.2 /SiO.sub.2 support (55 grams) was used. After wetting, the catalyst was calcined at a temperature of 350.degree. C. for a period of 1 hour. The impregnation and calcination steps were repeated twice more to give the catalyst.

Catalyst KKKKKK Preparation: Obtained from Norton Company, Akron, Ohio.

Catalyst LLLLLL Preparation: Obtained from Norton Company, Akron, Ohio.

Catalyst MMMMMM Preparation: Obtained from Norton Company, Akron, Ohio.

TABLE I__________________________________________________________________________Example No. 1 2 3 4 5 6 7 8 9__________________________________________________________________________Catalyst Type A A A A A A A A ATEMP., .degree.C.; ave. 228 241 290 294 268 242 247 295 270PRES., psia 1172.7 1214.7 1214.7 1214.7 914.7 1214.7 1214.7 414.7 614.7AEEA SV;M/kg 1.61 1.44 1.5 1.56 0.9 0.57 0.69 1.18 2.21cat/hr.EDA/AEEA Mole 1.5 1.5 2 2 5 8 8 2 0.8RatioNH.sub.3 /AEEA Mole 24.2 45.83 34.9 36.33 55.94 107.9 91.22 66.88 30.36RatioH.sub.2 O/AEEA Mole 0.86 0.86 0.66 1.38 1.18 3.61 3.61 0.66 0.44RatioWt % H.sub.2 O 7.4 7.4 5 10 5 10 10 5 5% Conversion AEEA 70.4 73.2 97 61.8 97.3 43.3 23.3 98.6 27ANALYTICAL,area %EDA 62.81 65.97 60.95 62.65 77.39 87.72 84.11 60.49 43.42MEA 0.92 0.41 0.12 0.13 0 0 0 0 0PIP 5.52 5.84 9.66 6.36 5.23 0.68 0.64 11.37 3.72DETA 2.33 2.58 3.68 1.24 3.49 0 0.13 4.03 0AEEA 15.51 14.19 1.36 17.33 0.7 9.96 13.57 0.63 49.49AEP 0.89 1.03 2.13 0.35 2.49 0.06 0.05 3.82 0.06HEP 0.17 0.13 0.1 0.14 0.04 0 0.01 0.1 0.06TETA 5.1 4.45 4.47 1.78 4.64 0.40 0.46 3.36 0.20DAEP 1.70 1.77 4.42 3.10 2.00 0.16 0.16 5.78 1.52PEEDA 1.99 2.11 5.00 3.02 2.15 0.12 0.10 5.09 1.01DPE 0 0.56 0.14 0.19 0.07 0 0 0.32 --Total TETAS 8.79 8.38 14.02 8.08 8.91 0.68 0.71 14.26 2.72Total TEPAS 0.87 0.77 2.01 0.29 0.96 0.22 0.14 1.62 0.04Total Byproducts 2.18 0.72 5.98 3.43 0.79 0.68 0.64 3.67 0.49% Water 16.68 21.18 13.75 13.94 10.66 12 9.97 17.34 12.18__________________________________________________________________________Example No. 10 11 12 13 14__________________________________________________________________________Catalyst Type F G D D BTemp. .degree.C. 172 178 258 261 284Press. psig 614 614.7 614.7 614.7 614.7Space velocity 2.2 2.4 2.2 3.3 2gmol/kg-cat/hrFeed Comp. EDA/AEEA/NH.sub.3 EDA/AEEA/NH.sub.3 EDA/AEEA/NH.sub.3 DETA/MEA/NH.sub.3 DETA/MEA/NH.sub.3Feed Mole Ratio 2/1/37 2/1/12.5 2/1/10.8 2/1/11.9 2/1/10.7% water; feed 5 0 5 5 5% Conv. 40.4 40.7 41.5 34.5(DETA) 66.7R.sub.x Outlet Comp.Area % GGEDA 32.94 46.98 39.1 1.63 1.45MEA 0.38 0 0.66 24.16 7.75PIP 0.03 0 8.95 0.93 0.77DETA 8.03 24.37 1.3 50.93 75.48AEEA 57.53 27.91 27.01 2.22 0.19AEP 0.98 0.72 0.85 7.76 1.54nc-TETA.sup.2 0.02 0 7.96nc-TETA 8.21 9.67c-TETA.sup.3 0 6.68c-TETA 0.89 0.55TEPA's 0.02 0 1.73 1.88 1.13HPA/UNKNOWNS 0.06 0.02 5.55 1.35 1.45__________________________________________________________________________Example No. 15 16 17 18 19__________________________________________________________________________Catalyst Type H E E C CTemp. .degree.C. 180 268 266 257 279Press. psig 614.7 614.7 614.7 614.7 614.7Space velocity 3.3 2.4 2.1 2.4 2.3gmol/kg-cat/hrFeed Comp. EDA/AEEA/NH.sub.3 EDA/AEEA/NH.sub.3 DETA/MEA/NH.sub.3 DETA/MEA/NH.sub.3 DETA/MEA/NH.sub.3Feed Mole Ratio 2/1/9.5 2/1/18.5 2/1/16.2 2/1/11.7 2/1/13.2% water; feed 0 0 0 0 0% Conv. 23.5 96.2 42.9 45.3 75R.sub.x Outlet Comp.Area % GGEDA 58.46 43.41 2.32 .56 1.02MEA 0.03 0.14 13.14 12.7 5.71PIP 0.05 16.67 2.28 0.47 1.32DETA 6.12 5.16 42.38 80.17 78.73AEEA 35.27 1.74 0.96 0.35 0AEP 0 2.17 8.87 0.84 1.77nc-TETA.sup.2 0 8.3 14.84 3.95 6.43c-TETA.sup.3 0 12.17 3.46 0.17 0.55TEPA's 0 2.61 7.08 0.34 0.93HPA/UNKNOWNS 0.07 7.55 4.48 0.4 3.04__________________________________________________________________________ Example No. 20 21 22__________________________________________________________________________ Catalyst Type B I C Temp. .degree.C. 259 179 274 Press. psig 614.7 614.7 614.7 Space velocity 2.1 2.4 4.7 gmol/kg-cat/hr Feed Comp. EDA/AEEA/NH.sub.3 EDA/AEEA/NH.sub.3 EDA/MEA/NH.sub.3 Feed Mole Ratio 2/1/10.0 2/1/11.1 1/1/5.3 % water; feed 5 0 0 % Conv. 21.8 42.3 42 R.sub.x Outlet Comp. Area % GG EDA 44.38 61.7 56.03 MEA 0 0 29.12 PIP 2.25 0 1.83 DETA 8.92 10.43 4.58 AEEA 37.01 25.84 1.44 AEP 0.21 0.5 1.92 nc-TETA.sup.2 5.64 nc-TETA 0 1.00 c-TETA.sup.3 0.58 c-TETA 0 0.99 TEPA's 0.45 0 0.53 HPA/UNKNOWNS 0.47 1.53 2.54__________________________________________________________________________ .sup.2 nc = noncyclics .sup.3 c = cyclics TABLE II__________________________________________________________________________Example No. 23 24 25 26 27 28 29 30 31__________________________________________________________________________Catalyst Type J J J J J J J J JCatalyst weight, gm 81.0 81.0 81.0 81.0 81.0 81.0 81.0 81.0 81.0Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.7 269.5 280.7 260.2 270.9 258.8 279.7 268.7 268.9Time on organics, hrs. 25.0 27.0 30.0 47.5 53.0 72.5 78.5 96.0 104.0Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.65 4.99 5.19 4.45 4.75 3.91 4.36 4.43 4.87NH.sub.3 feedrate, gm/hr 40.6 43.8 46.3 36.7 38.6 30.9 35.8 38.5 42.3Liquid feed composition, wt. %DETA 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81MEA 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19Liquid product composition,wt. %EDA 1.06 0.96 1.65 0.58 0.93 0.44 1.29 0.76 0.71MeEDA 0 0 0 0 0 0 0 0 0MEA 27.97 29.69 25.97 33.84 31.26 33.34 25.75 31.85 32.53EtEDA 0 0 0 0 0 0 0 0 0PIP 0.41 0.35 0.65 0.13 0.26 0.09 0.38 0.15 0.12DETA 48.20 49.21 45.95 52.63 51.53 56.05 49.30 52.04 53.16AEEA 3.81 4.35 3.82 3.19 4.30 2.48 4.17 3.47 3.39AEP 0.47 0.36 0.67 0.22 0.30 0.17 0.47 0.26 0.25HEP 0 0 0 0 0 0 0 0 0TETA's 10.10 8.61 10.77 5.04 7.01 3.88 9.98 5.75 4.72TEPA's 3.39 1.88 3.55 0.11 0.82 0 2.63 0.63 0.44MEA Conversion % 22.93 17.73 26.84 5.52 13.89 7.65 28.09 10.64 8.96Acyclic (N4)/cyclic (< = N4), 43.8 46.8 41.4 100 119 AL 32.1 80.5 ALweight ratioAcyclic (N5)/cyclic (< = N5), 19.5 AL AL -- AL 0.2 ACweight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.26 0.17 0.25 0.02 0.09 0 0.20 0.08 0.07weight ratio__________________________________________________________________________ AL = All linear AC = All cyclic TABLE III__________________________________________________________________________Example No. 32 33 34 35 36 37 38 39 40 41 42 43__________________________________________________________________________Catalyst Type K K K K K K K K K K K KCatalyst weight, gm 69.8 69.8 69.8 69.8 69.8 69.8 69.8 69.8 69.8 69.8 69.8 69.8Pressure, psig 600 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.0 269.9 270.1 269.8 280.3 280.8 260.0 270.4 260.6 280.7 270.0 270.5Time on organics, hrs. 7.0 25.0 28.2 27.0 32.0 30.0 51.0 55.5 76.0 80.0 98.0 100.0Duration of run, hrs. 2 2 2.2 2 2 2 2 2 1 1 2 2MEA SV, gmol/hr/kgcat 6.58 4.13 5.83 4.39 6.7 3.45 5.23 1.85 5.05 5.44 5.46 5.60NH.sub.3 feedrate, gm/hr 57.2 38.4 52.1 41.1 48.5 32.7 40.3 15.1 19.8 21.6 44.6 46.2Liquid feed composition,wt. %DETA 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81MEA 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19Liquid product composition,wt. %EDA 1.24 1.60 0.95 1.21 1.43 1.80 0.74 0.74 0.74 1.34 0.74 0.87MeEDA 0 0 0 0 0 0 0 0 0 0 0 0MEA 19.67 22.54 26.20 25.34 19.49 20.13 29.73 29.73 29.73 23.12 28.77 29.57EtEDA 0 0 0 0 0 0 0 0 0 0 0 0PIP 0.65 1.03 0.53 0.72 0.93 1.19 0.38 0.38 0.38 0.86 0.40 0.44DETA 55.44 45.02 50.44 47.30 46.80 44.02 51.65 51.65 51.65 48.33 52.65 50.62AEEA 2.25 3.72 4.05 4.52 2.91 3.70 3.10 3.10 3.10 2.98 3.53 3.82AEP 0.70 1.12 0.49 0.69 1.01 1.09 0.37 0.37 0.37 0.82 0.34 0.38HEP 0 0 0 0 0 0 0 0 0 0 0 0TETA's 9.65 11.96 9.66 10.63 12.87 13.06 6.39 6.39 6.39 11.07 7.31 6.58TEPA's 4.85 6.85 2.52 3.79 7.21 6.64 1.70 1.70 1.70 5.04 0.69 1.22MEA Conversion % 46.11 37.81 27.53 29.68 45.85 43,35 16.29 16.29 16.29 35.76 19.42 16.21Acyclic (N4)/cyclic 27.7 12.2 32.7 35.6 21.4 23.5 29.0 29.0 54.2 21.4 24.9 26.3(< = N4),weight ratioAcyclic (N5)/cyclic 24.3 16.4 AL 42.8 14.0 17.2 AL AL 1.0 22.0 1.2 4.0(< = N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.39 0.44 0.20 0.28 0.43 0.39 0.21 0.21 0.21 0.35 0.07 0.14weight ratio__________________________________________________________________________ AL = All linear TABLE IV__________________________________________________________________________Example No. 44 45 46 47 48 49 50 51 52__________________________________________________________________________Catalyst Type L L L L L L L L LCatalyst weight, gm 81.0 81.0 81.0 81.0 81.0 81.0 81.0 81.0 81.0Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 280.0 260.0 270.0 261.1 281.0 270.0 271.1 280.8Time on organics, hrs. 5.5 8.5 25.5 30.5 49.0 55.0 63.0 65.0 83.5Duration of run, hrs. 1 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.82 2.44 5.36 5.37 5.39 5.95 5.42 5.82 5.02NH.sub.3 feedrate, gm/hr 21.8 22.1 55.8 54.8 55.0 69.9 57.3 61.5 56.6Liquid feed composition, wt. %DETA 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81MEA 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19Liquid product composition,wt. %EDA 2.69 2.69 1.29 1.35 1.28 3.69 2.47 2.35 4.26MeEDA 0 0 0 0 0 0 0 0 0MEA 26.60 26.60 35.62 32.63 34.35 25.96 31.23 30.52 27.27EtEDA 0 0 0 0 0 0 0 0 0PIP 0.37 0.37 0.08 0.14 0.05 0.19 0.09 0.08 0.14DETA 47.58 47.58 53.88 52.05 56.50 53.83 57.32 55.41 53.05AEEA 2.60 2.60 1.47 1.73 1.17 1.43 1.35 1.26 1.21AEP 0.43 0.43 0.20 0.26 0.19 0.38 0.27 0.27 0.44HEP 0 0 0 0 0 0 0 0 0TETA's 10.73 10.73 3.22 5.26 1.92 6.33 1.69 2.44 3.03TEPA's 1.91 1.91 0 0.28 0 0.67 0 1.71 1.16MEA Conversion % 24.56 24.56 0.03 6.94 3.40 25.65 11.47 13.43 19.76Acyclic (N4)/cyclic (<=N4), 151.7 21.9 14.4 19.4 7.9 25.5 3.0 5.5 4.7weight ratioAcyclic (N5)/cyclic (<=N5), 4.0 7.9 -- 2.1 -- 1.2 -- 1.4 1.6weight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.14 0.13 0 0.04 0 0.08 0 0.54 0.30weight ratio__________________________________________________________________________ TABLE V__________________________________________________________________________Example No. 53 54 55 56 57 58 59 60 61__________________________________________________________________________Catalyst Type M M M M M M M M MCatalyst weight, gm 85.2 85.2 85.2 85.2 85.2 85.2 85.2 85.2 85.2Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 280.0 260.0 270.0 260.8 280.5 270.0 271.1 280.3Time on organics, hrs. 5.5 8.5 25.5 30.5 49.0 55.0 63.0 65.0 83.5Duration of run, hrs. 1 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.28 5.07 5.48 5.84 5.52 6.52 5.81 6.13 5.44NH.sub.3 feedrate, gm/hr 24.7 48.6 56.6 61.3 58.5 58.5 62.6 66.0 62.2Liquid feed composition, wt. %DETA 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81MEA 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19Liquid product composition,wt. %EDA 1.32 2.15 0.85 1.26 0.90 2.02 1.37 1.38 2.33MeEDA 0 0 0 0 0 0 0 0 0MEA 15.57 10.16 24.66 18.69 22.60 8.57 15.60 15.52 7.94EtEDA 0 0 0 0 0 0 0 0 0PIP 1.21 1.79 0.67 1.08 0.67 1.48 1.10 1.14 1.74DETA 41.58 39.29 46.91 43.53 49.14 40.82 44.78 45.27 38.44AEEA 2.20 1.15 2.85 2.14 2.98 0.66 1.62 1.56 0.56AEP 1.22 1.98 0.54 1.04 0.61 1.67 1.07 1.11 1.93HEP 0 0 0 0 0 0 0 0 0TETA's 16.72 18.77 11.96 15.23 12.45 17.75 16.10 16.16 17.53TEPA's 11.40 12.43 4.91 8.93 4.19 15.36 10.78 10.47 17.18MEA Conversion % 56.69 71.01 31.16 47.92 37.24 75.81 57.10 57.41 77.50Acyclic (N4)/cyclic (<=N4), 28.1 10.7 39.8 27.5 58.3 10.0 28.4 20.2 7.7weight ratioAcyclic (N5)/cyclic (<=N5), 17.8 11.1 AL 28.1 AL 9.6 20.8 20.2 7.7weight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.53 0.51 0.32 0.45 0.26 0.67 0.52 0.50 0.76weight ratio__________________________________________________________________________ AL = All linear TABLE VI__________________________________________________________________________Example No. 62 63 64 65 66 67 68 69 70__________________________________________________________________________Catalyst Type N N N N N N N N NCatalyst weight, gm 77.8 77.8 77.8 77.8 77.8 77.8 77.8 77.8 77.8Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 270.0 280.0 260.0 270.0 260.0 280.0 270.0 270.0Time on organics, hrs. 5.7 24.0 29.9 46.7 50.7 70.0 73.2 94.5 96.2Duration of run, hrs. 1 2 2 2 2 2 1 1.5 1.5AEEA SV, gmol/hr/kgcat 6.67 4.63 4.91 3.59 2.96 2.58 3.91 3.41 3.48NH.sub.3 feedrate, gm/hr 21.8 50.0 46.9 32.5 28.0 23.2 18.2 22.2 22.7Liquid feed composition, wt. %DETA 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76AEEA 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24Liquid product composition,wt. %EDA 0.44 0.39 0.77 0.24 0.48 0.24 0.87 0.49 0.48MeEDA 0 0 0 0 0 0 0 0 0MEA 0.09 0 0.08 0 0 0 0.07 0.08 0.08EtEDA 0 0 0 0 0 0 0 0 0PIP 4.44 4.13 5.87 3.20 4.67 3.53 6.10 4.40 4.40DETA 43.18 42.76 43.32 44.28 43.52 42.38 42.49 42.87 42.71AEEA 26.48 26.78 16.71 37.36 26.70 34.34 16.74 27.84 28.30AEP 0.39 0.35 0.55 0.17 0.36 0.18 0.54 0.34 0.32HEP 0 0 0 0 0 0 0 0 0TETA's 3.69 4.01 5.95 1.76 3.48 2.16 5.38 3.50 3.11TEPA's 15.71 15.98 19.62 9.10 14.81 12.31 18.59 13.57 13.51AEEA Conversion % 45.75 45.11 65.52 23.95 45.05 29.69 64.66 42.02 40.92Acyclic (N4)/cyclic (<=N4), 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1weight ratioAcyclic (N5)/cyclic (<=N5), 34.1 27.3 26.5 28.9 32.0 5.2 31.0 31.9 38.4.SIGMA.(N5)/.SIGMA.(N4), 4.3 4.0 3.3 5.2 4.3 5.7 3.5 3.9 4.3weight ratio__________________________________________________________________________ TABLE VII__________________________________________________________________________Example No. 71 72 73 74 75 76 77 78 79__________________________________________________________________________Catalyst Type O O O O O O O O OCatalyst weight, gm 79.2 79.2 79.2 79.2 79.2 79.2 79.2 79.2 79.2Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 270.0 283.0 258.0 270.9 260.0 280.8 270.3 270.9Time on organics, hrs. 5.5 24.0 29.5 48.2 54.0 72.0 77.0 96.0 98.0Duration of run, hrs. 2 2 1 2.2 2 2 2 2 2AEEA SV, gmol/hr/kgcat -- -- -- -- -- -- -- -- --NH.sub.3 feedrate, gm/hr 23.9 44.4 23.5 60.7 63.0 38.0 50.5 43.3 42.4Liquid feed composition, wt. %DETA 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76AEEA 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24Liquid product composition,wt. %EDA 0.72 0.52 1.19 0.21 0.27 0 0.86 0.49 0.45MeEDA 0 0 0 0 0 0 0 0 0MEA 0.18 0 0.10 0 0 0 0.12 0.07 0.08EtEDA 0 0 0 0 0 0 0 0 0PIP 3.26 3.37 5.01 1.95 2.53 1.91 4.25 3.00 2.84DETA 44.51 41.52 43.07 43.76 42.61 42.89 43.51 44.61 43.96AEEA 21.05 28.04 18.66 41.43 34.60 41.04 22.86 32.99 33.50AEP 0.51 0.40 0.69 0.17 0.30 0.17 0.46 0.30 0.30HEP 0 0 0 0 0 0 0 0 0TETA's 4.12 3.89 5.55 1.56 2.66 1.64 4.87 2.56 2.65TEPA's 16.72 15.50 16.20 6.95 11.77 8.80 15.08 9.19 10.75AEEA Conversion % 55.29 41.70 60.26 15.17 28.72 16.50 51.95 30.81 30.79Acyclic (N4)/cyclic (<=N4), 0.1 0.2 0.2 0.2 0.1 0.2 0.2 0.1 0.1weight ratioAcyclic (N5)/cyclic (<=N5), 21.9 28.0 18.9 18.8 35.8 32.4 25.2 26.1 16.9weight ratio.SIGMA.(N5)/.SIGMA.(N4), 4.1 4.0 2.9 4.5 4.4 3.1 3.1 3.6 4.1weight ratio__________________________________________________________________________ TABLE VIII__________________________________________________________________________Example No. 80 81 82 83 84 85 86 87 88__________________________________________________________________________Catalyst Type P P P P P P P P PCatalyst weight, gm 70.3 70.3 70.3 70.3 70.3 70.3 70.3 70.3 70.3Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 270.0 280.0 260.0 270.0 260.0 280.0 270.6 269.0Time on organics, hrs. 5.5 22.5 29.0 52.0 54.5 72.2 78.0 96.5 98.5Duration of run, hrs. 2 1 2 1 1 2 2 2 2AEEA SV, gmol/hr/kgcat -- -- -- -- -- -- -- -- --NH.sub.3 feedrate, gm/hr 21.6 14.3 32.8 30.7 29.8 50.4 43.6 38.0 38.9Liquid feed composition, wt. %,DETA 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76AEEA 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24Liquid product composition,wt. %EDA 2.46 1.29 1.46 0.41 0.59 0.36 0.24 0.75 0.70MeEDA 0 0 0 0 0 0 0 0 0MEA 1.52 0.91 0.77 0.43 0.40 0.21 0.22 0.23 0.17EtEDA 0 0 0 0 0 0 0 0 0PIP 4.80 3.83 4.36 2.11 2.78 2.01 4.12 3.40 3.25DETA 37.58 41.15 42.68 44.21 41.99 43.58 39.66 43.51 41.45AEEA 16.78 26.05 23.62 42.66 33.98 43.20 23.91 34.37 33.86AEP 1.48 0.54 0.55 0.14 0.31 0.14 0.42 0.29 0.20HEP 0 0 0 0 0 0 0 0 0TETA's 7.37 3.99 3.66 0.85 2.68 1.01 4.52 2.37 2.61TEPA's 16.17 14.01 13.88 5.45 10.84 5.68 18.03 9.38 10.95AEEA Conversion % 63.30 44.80 49.70 12.60 29.00 11.50 49.67 28.70 29.10Acyclic (N4)/cyclic (<=N4), 0.9 0.3 0.1 0.1 0.1 0.3 0.1 0.1 0.1weight ratioAcyclic (N5)/cyclic (<=N5), 11.8 20.5 23.8 22.6 22.9 24.2 13.2 30.5 18.2weight ratio.SIGMA.(N5)/.SIGMA.(N4), 2.2 3.5 3.8 6.4 4.0 5.6 4.0 4.0 4.2weight ratio__________________________________________________________________________ TABLE IX__________________________________________________________________________Example No. 89 90 91 92 93 94 95 96 97__________________________________________________________________________Catalyst Type Q Q Q Q Q Q Q Q QCatalyst weight, gm 92.4 92.4 92.4 92.4 92.4 92.4 92.4 92.4 92.4Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 270.0 280.0 260.0 270.0 260.0 280.0 270.0 270.0Time on organics, hrs. 5.7 24.0 29.0 46.7 50.7 70.0 73.2 94.5 96.2Duration of run, hrs. 1 2 2 2 2 2 1 1.5 1.5AEEA SV, gmol/hr/kgcat -- -- -- -- -- -- -- -- --NH.sub.3 feedrate, gm/hr 20.7 54.6 46.1 39.5 43.8 36.2 19.9 23.6 24.5Liquid feed composition, wt. %DETA 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76AEEA 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24Liquid product composition,wt. %EDA 0.62 0.77 1.43 0.35 0.65 0.34 1.54 0.85 0.85MeEDA 0 0 0 0 0 0 0 0 0MEA 0.05 0.05 0.12 0 0 0 0.12 0.05 0.05EtEDA 0 0 0 0 0 0 0 0 0PIP 5.03 5.21 6.86 3.37 4.62 3.56 6.78 5 4.91DETA 41.13 41.09 41.25 41.84 41.18 42.24 40.18 40.78 40.48AEEA 22.03 21.43 12.01 33.20 23.91 32.48 12.42 22.88 23.37AEP 0.50 0.51 1.00 0.32 0.47 0.32 0.94 0.49 0.47HEP 0 0 0 0 0 0 0 0 0TETA's 4.09 4.42 6.08 2.05 3.98 1.87 4.49 3.99 3.92TEPA's 20.24 20.45 22.65 14.14 19.44 13.37 20.88 18.77 18.49AEEA Conversion % 54.80 56.17 74.97 32.22 51.14 32.91 72.86 52.54 51.35Acyclic (N4)/cyclic (<=N4), 0.2 0.2 0.2 0.2 0.2 0.2 0.3 0.2 0.2weight ratioAcyclic (N5)/cyclic (<=N5), 37.8 37.9 37.9 28.4 39.5 22.2 22.3 40.8 36.2weight ratio.SIGMA.(N5)/.SIGMA.(N4), 5.0 4.6 4.6 6.9 4.9 7.2 4.7 4.7 4.7weight ratio__________________________________________________________________________ TABLE X__________________________________________________________________________Example No. 98 99 100 101 102 103 104 105 106__________________________________________________________________________Catalyst Type R R R R R R R R RCatalyst weight, gm 83.0 83.0 83.0 83.0 83.0 83.0 83.0 83.0 83.0Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.3 269.2 280.3 260.0 270.7 258.8 279.4 268.6 268.9Time on organics, hrs. 25.0 27.0 30.0 47.5 53.0 72.5 78.5 96.0 104.0Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.36 5.83 4.87 4.24 4.63 4.25 4.23 4.49 4.84NH.sub.3 feedrate, gm/hr 3.93 42.6 44.5 35.7 38.8 34.3 35.5 39.3 42.8Liquid feed composition, wt. %DETA 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81MEA 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19Liquid product composition,wt. %EDA 1.48 1.57 2.02 0.69 1.06 0.53 1.45 0.83 0.78MeEDA 0 0 0 0 0 0 0 0 0MEA 22.85 29.24 17.65 29.77 25.97 31.82 20.10 27.71 29.07EtEDA 0 0 0 0 0 0 0 0 0PIP 0.64 0.66 0.94 0.22 0.41 0.15 0.60 0.26 0.23DETA 45.36 55.10 42.59 50.64 49.02 53.67 45.37 50.33 50.69AEEA 4.02 5.66 3.65 4.36 4.97 3.75 4.15 4.75 4.55AEP 0.79 0.77 1.15 0.28 0.45 0.23 0.79 0.79 0.30HEP 0 0 0 0 0 0 0 0 0TETA's 12.73 15.31 14.61 7.65 9.90 5.99 13.50 8.57 7.66TEPA's 5.73 6.96 8.41 1.55 2.93 0.37 6.56 2.11 1.74MEA Conversion % 36.63 34.01 50.31 17.19 28.09 12.29 43.92 23.51 19.12Acyclic (N4)/cyclic (<=N4), 26.3 37 19.1 59.2 49.2 73.5 30.6 56.3 91.8weight ratioAcyclic (N5)/cyclic (<=N5), 16.6 26.7 17.3 AL AL Al 16.1 AL ALweight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.35 0.35 0.44 0.16 0.23 0.05 0.38 0.19 0.18weight ratio__________________________________________________________________________ AL = All linear TABLE XI__________________________________________________________________________Example No. 107 108 109 110 111 112 113 114 115__________________________________________________________________________Catalyst Type S S S S S S S S SCatalyst weight, gm 87.0 87.0 87.0 87.0 87.0 87.0 87.0 87.0 87.0Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 280.0 260.0 270.0 260.0 280.2 270.0 270.8 279.6Time on organics, hrs. 5.5 8.5 25.5 30.5 49.0 55.0 63.0 65.0 83.5Duration of run, hrs. 1 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.98 3.19 5.17 5.40 4.94 5.17 2.91 3.20 2.01NH.sub.3 feedrate, gm/hr 23.8 22.8 28.4 28.8 26.7 31.6 16.1 17.5 11.7Liquid feed composition, wt. %DETA 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81MEA 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19Liquid product composition,wt. %EDA 1.41 2.05 0.56 0.87 0.58 1.66 1.73 1.61 3.20MeEDA 0 0 0 0 0 0 0 0 0MEA 19.33 14.89 32.59 28.88 30.91 19.92 22.47 22.59 14.36EtEDA 0 0 0 0 0 0 0 0 0PIP 0.90 1.42 0.34 0.61 0.30 1.17 1.29 1.22 2.55DETA 52.52 49.03 53.57 50.73 55.21 50.05 49.40 49.57 40.30AEEA 3.10 2.24 2.82 3.11 2.59 2.54 2.81 2.84 1.84AEP 0.85 1.56 0.26 0.44 0.23 1.07 0.95 0.90 2.16HEP 0 0 0 0 0 0 0 0 0TETA's 9.47 11.11 5.40 8.10 5.43 11.41 10.18 10.98 13.32TEPA's 5.10 7.91 0.97 2.28 0.46 5.29 4.71 5.15 11.87MEA Conversion % 46.07 57.87 10.12 19.83 14.19 44.75 37.61 38.21 59.43Acyclic (N4)/cyclic (<=N4), 27.7 11.6 29.1 31.2 29.4 19.7 18.6 24.8 5.9weight ratioAcyclic (N5)/cyclic (<=N5), 24.3 7.9 3.8 AL 0.5 12.4 13.9 20.6 8.8weight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.42 0.55 0.14 0.22 0.07 0.36 0.36 0.36 0.69weight ratio__________________________________________________________________________ AL = All linear TABLE XII__________________________________________________________________________Example No. 116 117 118 119 120 121 122 123 124__________________________________________________________________________Catalyst Type T T T T T T T T TCatalyst weight, gm 70.3 70.3 70.3 70.3 70.3 70.3 70.3 70.3 70.3Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.6 269.8 280.0 260.0 269.9 259.9 280.0 270.0 269.8Time on organics, hrs. 7.0 28.2 32.0 51.0 55.5 76.0 80.0 98.0 100.0Duration of run, hrs. 2 2.2 2 2 2 1 1 2 2MEA SV, gmol/hr/kgcat 6.41 5.47 5.54 5.55 5.99 4.94 4.87 5.13 5.09NH.sub.3 feedrate, gm/hr 57.0 50.0 47.4 42.9 51.0 19.5 20.2 42.8 42.6Liquid feed composition, wt. %DETA 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81MEA 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19Liquid product composition,wt. %EDA 1.76 1.72 2.79 1.20 1.54 1.03 3.28 1.62 1.77MeEDA 0 0 0 0 0 0 0 0 0MEA 28.93 31.18 25.30 34.17 32.94 36.96 29.76 34.70 34.76EtEDA 0 0 0 0 0 0 0 0 0PIP 0.31 0.20 0.35 0.11 0.13 0.05 0.26 0.08 0.08DETA 51.86 51.84 47.27 52.54 50.53 55.52 49.86 54.14 52.26AEEA 2.46 2.38 2.35 1.71 1.94 1.39 2.21 1.69 1.72AEP 0.34 0.26 0.43 0.27 0.22 0.18 0.37 0.23 0.23HEP 0 0 0 0 0 0 0 0 0TETA's 8.21 6.88 8.88 4.83 4.02 0.75 6.01 1.23 2.76TEPA's 1.20 0.40 1.93 0.61 0.28 0 0.77 0.75 0.69MEA Conversion % 19.48 12.50 25.30 4.19 3.61 3.96 14.28 1.23 0.93Acyclic (N4)/cyclic (<=N4), 61.5 34.2 29.6 8.2 10.8 5.2 15.9 5.1 10.0weight ratioAcyclic (N5)/cyclic (<=N5), 8.7 2.5 6.9 3.1 1.0 -- 1.6 0.8 0.9weight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.11 0.04 0.18 0.10 0.05 0.00 0.10 0.47 0.19weight ratio__________________________________________________________________________ TABLE XIII__________________________________________________________________________Example No. 125 126 127 128 129 130 131 132 133__________________________________________________________________________Catalyst Type U U U U U U U U UCatalyst weight, gm 80.0 80.0 80.0 80.0 80.0 80.0 80.0 80.0 80.0Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.2 270.6 280.0 260.0 270.6 260.3 280.3 270.0 270.4Time on organics, hrs. 7.0 28.2 32.0 51.0 55.5 76.0 80.0 98.0 100.0Duration of run, hrs. 2 2.2 2 2 2 1 1 2 2MEA SV, gmol/hr/kgcat 5.80 5.38 5.30 5.18 5.59 4.76 4.64 4.77 4.93NH.sub.3 feedrate, gm/hr 58.1 55.5 50.5 45.4 52.8 21.4 21.7 44.7 46.5Liquid feed composition, wt. %DETA 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81 62.81MEA 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19 37.19Liquid product composition,wt. %EDA 1.49 1.58 2.41 1.49 1.60 1.33 3.12 1.81 1.94MeEDA 0 0 0 0 0 0 0 0 0MEA 15.80 15.60 7.88 21.06 16.72 23.31 8.72 16.63 16.40EtEDA 0 0 0 0 0 0 0 0 0PIP 1.24 1.29 1.79 1.18 1.30 1.03 2.25 1.45 1.52DETA 43.99 41.88 35.04 44.83 41.24 45.12 38.12 42.49 42.23AEEA 1.68 1.76 0.69 2.11 1.79 2.59 0.65 1.94 1.78AEP 1.28 1.32 2.09 1.44 1.21 0.82 2.32 1.36 1.42HEP 0 0 0 0 0 0 0 0 0TETA's 16.06 16.67 18.12 12.97 15.56 12.51 17.44 15.73 15.55TEPA's 10.63 11.12 17.85 7.24 9.80 5.36 14.78 9.38 9.35MEA Conversion % 56.44 56.59 77.25 41.21 52.29 34.25 75.14 53.32 53.67Acyclic (N4)/cyclic (<=N4), 45.2 22.5 7.5 21.2 22.4 34.8 8.8 23.5 22.7weight ratioAcyclic (N5)/cyclic (<=N5), 22.8 18.1 7.8 16.0 18.1 30.1 9.5 16.3 16.1weight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.51 0.52 0.76 0.43 0.48 0.33 0.65 0.46 0.46weight ratio__________________________________________________________________________ TABLE XIV__________________________________________________________________________Example No. 134 135 136 137 138 139 140 141 142__________________________________________________________________________Catalyst Type V V V V V V V V VCatalyst weight, gm 73.7 73.7 73.7 73.7 73.7 73.7 73.7 73.7 73.7Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 270.0 280.0 260.0 270.0 260.0 280.0 270.7 270.0Time on organics, hrs. 5.5 22.5 29.0 52.0 54.5 72.2 78.0 96.5 98.5Duration of run, hrs. 2 1 2 1 1 2 2 2 2AEEA SV, gmol/hr/kgcat 6.67 4.63 4.91 3.59 2.96 2.58 3.91 3.41 3.48NH.sub.3 feedrate, gm/hr 23.9 9.9 48.8 23.5 28.5 31.0 25.0 26.9 26.3Liquid feed composition, wt. %DETA 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76AEEA 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24Liquid product composition,wt. %EDA 1.79 1.51 1.41 0.34 0.50 0.35 1.70 0.78 0.74MeEDA 0 0 0 0 0 0 0 0 0MEA 1.07 1.17 0.74 0.25 0.33 0.24 0.04 0.16 0.15EtEDA 0 0 0 0 0 0 0 0 0PIP 5.52 3.76 5.76 2.81 3.63 3.64 6.92 5.05 4.86DETA 35.90 41.93 41.57 41.16 41.76 42.48 39.49 41.16 39.75AEEA 12.93 27.03 18.11 36.99 28.20 33.45 13.29 23.75 23.90AEP 1.55 0.45 0.89 0.18 0.37 0.30 0.97 0.44 0.40HEP 0 0 0 0 0 0 0 0 0TETA's 8.53 3.5 6.04 2.12 3.43 2.57 7.05 4.24 3.96TEPA's 20.89 12.30 16.43 11.31 14.45 12.09 20.16 16.39 16.70AEEA Conversion % 71.98 42.53 61.68 24.04 40.94 31.50 71.70 50.18 49.03Acyclic (N4)/cyclic (< = N4), 0.6 0.3 0.3 0.1 0.1 0.1 0.2 0.1 0.1weight ratioAcyclic (N5)/cyclic (< = N5), 11.5 23.0 21.5 29.0 36.6 40.9 21.5 38.7 40.6weight ratio.SIGMA.(N5)/.SIGMA.(N4), 2.4 3.5 2.7 5.3 4.2 4.7 2.9 3.9 4.2weight ratio__________________________________________________________________________ TABLE XV__________________________________________________________________________Example No. 143 144 145 146 147 148 149 150 151__________________________________________________________________________Catalyst Type W W W W W W W W WCatalyst weight, gm 73.4 73.4 73.4 73.4 73.4 73.4 73.4 73.4 73.4Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 270.0 283.0 258.0 270.9 260.0 280.8 270.3 270.9Time on organics, hrs. 6.0 24.0 29.5 48.2 54.0 72.0 77.0 96.0 98.0Duration of run, hrs. 2 2 1 2.2 2 2 2 2 2AEEA SV, gmol/hr/kgcat -- -- -- -- -- -- -- -- --NH.sub.3 feedrate, gm/hr 49.4 47.0 25.3 63.8 66.2 40.9 55.0 45.8 45.5Liquid feed composition, wt. %DETA 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76AEEA 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24Liquid product composition,wt. %EDA 0.59 0.51 1.22 0.19 0.25 0.17 0.76 0.44 0.45MeEDA 0 0 0 0 0 0 0 0 0MEA 0.20 0.07 0.09 0 0 0 0.12 0.07 0.07EtEDA 0 0 0 0 0 0 0 0 0PIP 2.85 3.05 4.72 1.66 2.14 1.61 3.58 2.65 2.63DETA 45.65 41.32 44.05 44.34 42.13 42.52 43.04 44.85 44.90AEEA 24.65 30.56 20.44 43.92 36.81 42.99 25.69 25.38 36.09AEP 0.44 0.40 0.82 0.17 0.31 0.16 0.51 0.32 0.31HEP 0 0 0 0 0 0 0 0 0TETA's 3.12 2.96 4.96 0.73 1.76 0.98 4.05 1.48 1.46TEPA's 14.38 15.11 15.08 6.05 11.07 7.67 15.97 8.80 8.72AEEA Conversion % 47.86 36.83 56.81 10.83 23.78 12.00 46.91 40.95 25.27Acyclic (N4)/cyclic (< = N4), 0.2 0.2 0.3 0.1 0.1 0.2 0.2 0.1 0.1weight ratioAcyclic (N5)/cyclic (< = N5), 29.2 29.9 16.2 33.1 34.6 30.5 23.6 23.1 24.5weight ratio.SIGMA.(N5)/.SIGMA.(N4), 4.6 5.1 3.0 8.3 6.3 7.8 3.9 6.0 6.0weight ratio__________________________________________________________________________ TABLE XVI__________________________________________________________________________Example No. 152 153 154 155 156 157 158 159 160__________________________________________________________________________Catalyst Type X X X X X X X X XCatalyst weight, gm 84.4 84.4 84.4 84.4 84.4 84.4 84.4 84.4 84.4Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 270.0 280.0 260.0 270.0 260.0 280.0 270.6 270.0Time on organics, hrs. 5.5 22.5 29.0 52.0 54.5 72.2 78.0 96.5 98.5Duration of run, hrs. 2 1 2 1 1 2 2 2 2AEEA SV, gmol/hr/kgcat -- -- -- -- -- -- -- -- --NH.sub.3 feedrate, gm/hr 22.1 22.5 49.2 28.0 28.5 49.7 46.8 44.6 47.7Liquid feed composition, wt. %DETA 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76AEEA 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24Liquid product composition,wt. %EDA 2.27 4.55 1.74 0.58 0.94 0.50 1.87 1.19 0.98MeEDA 0 0 0 0 0 0 0 0 0MEA 1.91 0.49 0.96 0.60 0.48 0.27 0.22 0.28 0.28EtEDA 0 0 0 0 0 0 0 0 0PIP 4.38 8.82 4.05 1.76 2.73 1.76 4.35 3.33 3.06DETA 38.78 30.56 43.07 43.47 43.02 41.40 40.62 43.07 43.67AEEA 18.03 6.55 25.13 44.40 34.37 41.62 22.92 33.81 36.22AEP 1.04 3.42 0.47 0.13 0.29 0.13 0.45 0.29 0.20HEP 0 0 0 0 0 0 0 0 0TETA's 6.08 12.34 3.31 0.97 2.18 1.33 4.49 1.70 2.15TEPA's 15.92 19.32 12.10 4.88 8.78 6.37 13.97 9.45 8.66AEEA Conversion % 60.54 85.60 46.11 9.39 27.39 12.20 50.03 28.95 25.46Acyclic (N4)/cyclic (< = N4), 0.6 0.4 0.1 0.5 0.3 0.4 0.1 0.4 0.3weight ratioAcyclic (N5)/cyclic (< = N5), 11.7 4.9 20.9 19.5 28.4 21.5 8.5 25.7 24.0weight ratio.SIGMA.(N5)/.SIGMA.(N4), 2.6 1.6 3.7 5.0 4.0 4.8 3.1 3.1 4.0weight ratio__________________________________________________________________________ TABLE XVII__________________________________________________________________________Example No. 161 162 163 164 165 166 167 168 169__________________________________________________________________________Catalyst Type Y Y Y Y Y Y Y Y YCatalyst weight, gm 78.3 78.3 78.3 78.3 78.3 78.3 78.3 78.3 78.3Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 270.0 283.0 258.0 270.9 260.0 280.8 270.3 270.9Time on organics, hrs. 6.0 24.0 29.5 48.2 54.0 72.0 77.0 96.0 98.0Duration of run, hrs. 2 2 1 2.2 2 2 2 2 2AEEA SV, gmol/hr/kgcat -- -- -- -- -- -- -- -- --NH.sub.3 feedrate, gm/hr 47.8 42.9 23.8 60.8 63.8 38.3 51.1 44.1 43.5Liquid feed composition, wt. %DETA 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76AEEA 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24Liquid product composition,wt. %EDA 1.79 0.84 2.05 0.26 0.49 0.27 1.47 0.88 0.81MeEDA 0 0 0 0 0 0 0 0 0MEA 0.07 0.08 0.15 0 0 0 0.13 0.12 0.12EtEDA 0 0 0 0 0 0 0 0 0PIP 5.48 5.20 7.62 3.16 4.17 3.14 6.53 5.51 5.21DETA 40.75 39.06 40.46 42.44 41.21 41.62 39.57 44.13 42.64AEEA 21.03 20.82 10.49 34.11 26.14 34.43 12.94 23.33 23.17AEP 0.61 0.59 1.43 0.32 0.45 0.31 1.03 0.58 0.53HEP 0 0 0 0 0 0 0 0 0TETA's 4.60 5.02 7.77 1.84 3.81 2.33 7.05 3.48 3.34TEPA's 19.42 20.43 18.20 12.67 16.32 13.13 21.97 15.04 14.97AEEA Conversion % 56.84 56.59 77.33 29.89 45.43 29.60 72.79 51.60 50.71Acyclic (N4)/cyclic (< = N4), 0.2 0.2 0.3 0.1 0.2 0.2 0.3 0.1 0.1weight ratioAcyclic (N5)/cyclic (< = N5), 30.5 30.6 14.2 41.1 35.1 47.8 18.1 25.1 25.8weight ratio.SIGMA.(N5)/.SIGMA.(N4), 4.2 4.1 2.3 6.9 4.3 5.6 3.1 4.3 4.5weight ratio__________________________________________________________________________ TABLE XVIII__________________________________________________________________________Example No. 170 171 172 173 174 175 176 177 178__________________________________________________________________________Catalyst Type Z Z Z Z Z Z Z Z ZCatalyst weight, gm 84.8 84.8 84.8 84.8 84.8 84.8 84.8 84.8 84.8Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.0 270.0 280.0 260.0 270.0 260.0 280.0 270.0 270.0Time on organics, hrs. 5.7 24.0 29.0 46.7 50.7 70.0 73.2 94.5 96.2Duration of run, hrs. 1 2 2 2 2 2 1 1.5 1.5AEEA SV, gmol/hr/kgcat -- -- -- -- -- -- -- -- --NH.sub.3 feedrate, gm/hr 23.3 50.0 45.6 37.3 41.3 34.5 19.1 23.4 23.3Liquid feed composition, wt. %DETA 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76 49.76AEEA 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24 50.24Liquid product composition,wt. %EDA 0.46 0.56 1.34 0.26 0.50 0.25 1.36 0.64 0.65MeEDA 0 0 0 0 0 0 0 0 0MEA 0 0.09 0.11 0 0 0 0.09 0 0EtEDA 0 0 0 0 0 0 0 0 0PIP 4.46 4.64 6.90 3.48 4.69 3.53 8.83 4.93 4.96DETA 38.35 39.67 40.51 42.49 41.05 41.84 39.34 40.20 40.66AEEA 21.70 22.16 12.36 33.12 23.84 32.81 12.26 22.74 23.22AEP 0.54 0.54 1.08 0.35 0.51 0.36 1.06 0.54 0.53HEP 0 0 0 0 0 0 0 0 0TETA's 4.66 4.54 5.86 1.96 4.12 1.95 6.78 4.09 3.94TEPA's 22.98 21.35 22.56 13.30 18.84 13.34 21.88 19.39 18.23AEEA Conversion % 55.33 54.49 74.05 32.14 50.92 32.17 74.60 52.73 51.51Acyclic (N4)/cyclic (< = N4), 0.2 0.2 0 0.2 0.2 0.1 0.2 0.2 0.2weight ratioAcyclic (N5)/cyclic (< = N5), 33.9 27.1 19.1 18.8 36.7 14.2 18.5 32.2 36.5weight ratio.SIGMA.(N5)/.SIGMA.(N4), 4.9 4.7 3.9 4.5 4.6 6.8 3.2 4.7 4.6weight ratio__________________________________________________________________________ TABLE XIX__________________________________________________________________________Example No. 179 180 181 182 183 184 185 186__________________________________________________________________________Catalyst Type AA AA AA AA AA AA AA AACatalyst weight, gm 127.9 127.9 127.9 127.9 127.9 127.9 127.9 127.9Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 252.8 252.5 252.8 273.3 271.5 274.3 273.8 273.3Time on organics, hrs. 3.5 18.0 20.0 42.0 44.5 51.5 66.4 68.5Duration of run, hrs. 2 14.5 2 16.5 2.5 2 14.8 2.1MEA SV, gmol/hr/kgcat 1.82 1.81 1.82 1.75 1.79 1.39 1.52 1.63NH.sub.3 feedrate, gm/hr 49.0 59.9 59.9 50.7 48.4 55.0 48.0 67.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 -- -- --AEEA -- -- -- -- -- 33.54 33.54 33.54Liquid product composition,wt. %EDA 0.44 0 0 0.57 0.56 0.53 0.55 0.64MeEDA 0 0 0 0 0 0 0 0MEA 19.06 20.36 20.38 16.79 17.14 1.82 0 0EtEDA 0 0 0 0 0 0 0 0PIP 0.35 0.17 0.13 0.55 0.56 5.29 5.83 6.16DETA 73.70 76.19 77.06 74.38 74.02 70.73 66.69 69.84AEEA 0 0 0 0 0 5.43 8.01 8.11AEP 0.35 0.27 0.25 0.62 0.63 0.79 0.58 0.60HEP 0 0 0 0 0 0 0 0TETA's 3.10 3.40 1.18 3.97 3.94 3.94 4.98 4.71TEPA's 0.75 0 0 0.92 0.97 6.54 8.17 8.30ROH Conversion % 15.38 11.83 10.33 25.88 24.31 83.30 75.45 76.02Acyclic (N4)/cyclic (< = N4), AL AL AL 23.21 23.20 0.32 0.11 0.12weight ratioAcyclic (N5)/cyclic (< = N5), AL -- -- AL AL 12.43 18.50 41.50weight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.24 0 0 0.23 0.24 -- -- --weight ratio__________________________________________________________________________ AL = All linear TABLE XX__________________________________________________________________________Example No. 187 188 189 190 191 192 193 194__________________________________________________________________________Catalyst Type BB BB BB BB BB BB BB BBCatalyst weight, gm 125.7 125.7 125.7 125.7 125.7 125.7 125.7 125.7Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 260.8 260.0 280.5 280.5 281.5 281.3 279.8 260.5Time on organics, hrs. 16.7 18.7 24.1 41.1 48.1 64.8 66.8Duration of run, hrs. 15.7 2 2 16.7 2 15.8 2 15.7MEA SV, gmol/hr/kgcat 1.77 2.02 1.77 1.76 1.77 1.63 1.62 1.60NH.sub.3 feedrate, gm/hr 58.2 55.5 49.0 52.7 49.0 52.5 54.5 60.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 77.16MEA 22.84 22.84 22.84 22.84 22.84 -- -- 22.84AEEA -- -- -- -- -- 33.54 33.54 --Liquid product composition,wt. %EDA 0 0 1.64 1.13 1.40 2.21 2.12 0MeEDA 0 0 0 0 0 0 0 0MEA 24.27 24.79 18.55 15.91 20.12 0 0 29.98EtEDA 0 0 0 0 0 0 0 0PIP 0.48 0.31 1.35 1.37 1.20 7.44 6.49 0.49DETA 71.40 72.05 67.88 71.46 67.32 70.71 71.20 66.77AEEA 0 0 0 0 0 0 0 0AEP 0.34 0.32 1.14 1.08 0.98 1.10 1.08 0.25HEP 0 0 0 0 0 0 0 0TETA's 2.39 2.45 5.92 5.54 5.28 6.49 5.66 0.44TEPA's 0.93 0 2.51 2.18 2.79 11.91 12.44 0.99ROH Conversion % 6.29 8.67 19.20 30.97 12.19 100.00 100.00 0Acyclic (N4)/cyclic (< = N4), AL AL 8.42 8.58 8.53 0.23 0.25 3.97weight ratioAcyclic (N5)/cyclic (< = N5), AL -- 4.53 AL 6.19 10.77 11.11 ALweight ratio.SIGMA.(N5)/.SIGMA.(N4), 0.39 0 0.42 0.39 0.53 -- -- 2.25weight ratio__________________________________________________________________________ AL = All linear TABLE XXI__________________________________________________________________________Example No. 195 196 197 198 199__________________________________________________________________________Catalyst Type CC CC CC CC CCCatalyst weight, gm 132.3 132.3 132.3 132.3 132.3Pressure, psig 600 600 600 600 600Temperature, .degree.C. 255.5 253.5 253.3 277.3 276.3Time on organics, hrs. 5.5 22.2 24.2 29.7 46.5Duration of run, hrs. 2 15.4 2 1.2 16MEA SV, gmol/hr/kgcat 1.76 1.79 1.80 3.05 1.80NH.sub.3 feedrate, gm/hr 56 53 58 80 57.9Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16MEA 22.84 22.84 22.84 22.84 22.84Liquid product composition,wt. %EDA 0.72 0.57 0.61 4.72 5.56MeEDA 0 0 0 0 0MEA 19.39 18.82 18.97 10.58 10.88EtEDA 0 0 0 0 0PIP 0.58 0.75 0.78 4.57 5.28DETA 74.48 72.48 73.22 60.61 57.25AEEA 1.14 0.55 0 0 0AEP 0.59 0.73 0.75 4.56 5.02HEP 0 0 0 0 0TETA's 3.51 4.43 4.30 8.20 8.44TEPA's 0.74 1.50 1.20 4.98 5.47ROH Conversion % 16.90 18.49 17.80 54.71 53.33Acyclic (N4)/cyclic (< = N4), AL 14.38 14.15 1.84 1.69weight ratioAcyclic (N5)/cyclic (< = N5), AL AL AL 1.17 1.13weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- --weight ratio__________________________________________________________________________ AL = All linear AC = All cyclic TABLE XXII__________________________________________________________________________Example No. 200 201 202 203 204 205 206 207 208 209 210 211__________________________________________________________________________Catalyst Type DD DD DD DD DD DD DD DD DD DD DD DDCatalyst weight, gm 119.0 119.0 119.0 119.0 119.0 119.0 119.0 119.0 119.0 119.0 119.0 119.0Pressure, psig 600 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 256.8 262.3 258.5 277.3 280.8 280.8 280.8 255.8 274.8 280.3 280.0 259.0Time on organics, hrs. 4.5 20.5 22.5 27.5 35.5 57.0 59.0 80.5 87.5 104.5 106.5 111.5Duration of run, hrs. 2 16 2 2 1.5 21 2 20.7 2 16 2 2MEA SV, gmol/hr/kgcat 1.77 1.92 1.93 1.93 1.92 1.67 1.60 1.71 1.64 1.66 1.72 1.90NH.sub.3 feedrate, gm/hr 70.0 65.8 53.0 61.5 50.6 55.5 51.0 55.1 57 56.1 58 74.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 -- -- -- -- -- -- --AEEA -- -- -- -- -- 33.54 33.54 33.54 33.54 33.54 33.54 33.54Liquid product composition,wt. %EDA 0.44 0.46 0.48 2.39 5.14 4.62 4.73 0.69 3.82 4.27 4.42 0.75MeEDA 0 0 0 0 0 0 0 0 0 0 0 0MEA 17.17 16.69 16.56 11.29 8.13 0.93 0 0.35 0 0 0 18.51EtEDA 0 0 0 0 0 0 0 0 0 0 0 0PIP 0.62 0.74 0.75 2.63 4.42 9.83 10.45 5.60 9.71 10.22 10.06 1.17DETA 71.04 70.74 70.92 64.82 58.99 58.30 57.95 64.75 60.92 58.93 58.24 68.48AEEA 0.48 0.48 0.48 0.48 0.48 0.48 0.48 9.57 0 0 0 0.52AEP 0.60 0.70 0.71 2.82 4.88 3.71 3.66 0.61 3.10 3.40 3.52 0.94HEP 0 0 0 0 0 0 0 0 0 0 0 0TETA's 5.44 5.34 6.10 9.66 10.38 9.60 9.73 4.33 9.27 10.07 10.19 6.01TEPA's 1.89 2.14 2.19 4.62 5.30 8.66 9.12 11.34 8.91 8.88 9.52 3.26ROH Conversion % 24.22 26.14 27.45 51.68 65.20 100.00 98.57 71.43 100.00 100.00 100.00 20.00Acyclic (N4)/cyclic AL 20.27 18.61 2.93 2.23 0.39 0.33 0.13 0.30 0.33 0.38 9.99(< = N4),weight ratioAcyclic (N5)/cyclic AL AL AL 2.51 1.23 1.67 1.62 27.57 1.85 1.65 1.72 4.18(< = N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- -- -- -- -- -- --weight ratio__________________________________________________________________________ TABLE XXIII__________________________________________________________________________Example No. 212 213 214 215 216 217 218 219 220 221__________________________________________________________________________Catalyst Type EE EE EE EE EE EE EE EE EE EECatalyst weight, gm 117.0 117.0 117.0 117.0 117.0 117.0 117.0 117.0 117.0 117.0Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 263.3 264.5 264.5 282.3 283.0 283.8 283.3 277.5 282.8 262.8Time on organics, hrs. 15 17 17 23 39 41 45 63.5 65.5 70.5Duration of run, hrs. 14 2 2 2 15 2 2 17.5 2 2MEA SV, gmol/hr/kgcat 1.80 1.87 1.68 1.74 1.82 1.76 1.60 1.57 1.58 1.66NH.sub.3 feedrate, gm/hr 69.3 61.0 61.0 107.5 66.8 61.5 62.0 53.2 60.5 70Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- --AEEA -- -- -- -- -- -- 33.54 33.54 33.54 33.54Liquid product composition,wt. %EDA 0.34 0.33 0.31 1.45 1.71 1.75 2.27 2.48 2.68 0.50MeEDA 0 0 0 0 0 0 0 0 0 0MEA 19.00 19.14 18.85 13.73 13.66 13.73 1.37 0.78 0.82 0.68EtEDA 0 0 0 0 0 0 0 0 0 0PIP 0.45 0.45 0.44 1.77 2.06 2.14 6.70 6.85 7.15 3.16DETA 74.32 74.61 74.55 69.65 68.47 68.83 64.69 61.15 60.88 66.11AEEA 0.76 0.67 0.71 0.35 0.33 0.29 2.61 2.71 2.64 15.68AEP 0.51 0.49 0.51 2.02 2.23 2.30 2.23 2.42 2.52 0.46HEP 0 0 0 0 0 0 0.09 0.10 0.11 0.10TETA's 3.45 3.22 3.39 6.74 6.78 6.65 7.65 8.09 8.08 5.03TEPA's 1.05 0.96 1.09 3.63 3.95 3.89 9.99 10.75 10.78 7.59ROH Conversion % 17.59 16.93 18.24 41.12 41.39 41.33 92.30 91.79 92.00 53.98Acyclic (N4)/cyclic 30.61 34.71 19.41 20.90 3.06 3.12 0.32 0.29 0.31 0.60(< = N4),weight ratioAcyclic (N5)/cyclic AL AL AL 1.83 1.60 1.53 1.98 1.79 1.77 19.83(< = N5),weight ratio.SIGMA.(N5)/.SIGMA. (N4), 0.30 0.30 0.32 0.54 0.58 0.50 -- -- -- --weight ratio__________________________________________________________________________ AL = All linear TABLE XXIV__________________________________________________________________________Example No. 222 223 224 225 226 227 228 229 230 231__________________________________________________________________________Catalyst Type FF FF FF FF FF FF FF FF FF FFCatalyst weight, gm 119.4 119.4 119.4 119.4 119.4 119.4 119.4 119.4 119.4 119.4Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 232.8 230.0 231.8 248.5 244.0 247.3 248.8 250.5 249.5 230.3Time on organics, hrs. 4.0 19.7 22.2 27.1 43.7 45.7 51.0 68.0 70 93Duration of run, hrs. 2 15.7 2.6 2.2 15.7 2 2 16 2 21MEA SV, gmol/hr/kgcat 1.95 1.85 1.96 1.68 1.71 1.79 1.54 1.49 1.64 1.63NH.sub.3 feedrate, gm/hr 59.0 52.1 74.8 63.8 54.2 65.5 54.0 55.6 59 73Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- --AEEA -- -- -- -- -- -- 33.54 33.54 33.54 33.54Liquid product composition,wt. %EDA 1.32 1.44 1.38 4.97 4.71 4.33 3.75 4.12 4.10 0.88MeEDA 0 0 0 0 0 0 0 0 0 0MEA 22.49 22.38 23.57 16.24 15.26 16.13 0.96 0.79 0.89 0.46EtEDA 0 0 0 0 0 0 0 0 0 0PIP 0.15 0.16 0.15 0.66 0.70 0.68 4.48 4.55 4.47 1.85DETA 71.90 71.93 72.75 66.24 65.86 67.79 65.70 65.25 63.53 66.74AEEA 0 0 0 0 0 0 7.29 6.78 7.30 23.94AEP 0.30 0.29 0.28 0.71 0.71 0.73 0.85 1.01 0.83 0.27HEP 0 0 0 0 0 0 0 0 0 0TETA's 1.74 1.84 1.76 4.20 4.28 4.17 4.03 4.23 4.21 1.31TEPA's 0 0 0 1.02 1.00 1.02 5.49 5.53 6.01 3.03ROH Conversion % 0.60 0.05 3.44 24.99 28.48 26.24 76.87 78.43MEA Conversion % 76.53 28.00Acyclic (N4)/cyclic AL AL AL 9.42 10.16 9.87 0.41 0.41 0.40 0.49(<=N4),weight ratioAcyclic (N5)/cyclic -- -- -- 3.61 3.28 3.95 11.99 12.16 7.62 AL(<=N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), 0 0 0 0.24 0.23 0.24 -- -- -- --weight ratio__________________________________________________________________________ AL = All linear TABLE XXV__________________________________________________________________________Example No. 232 233 234 235 236 237 238 239 240__________________________________________________________________________Catalyst Type GG GG GG GG GG GG GG GG GGCatalyst weight, gm 71.7 71.7 71.7 71.7 71.7 71.7 71.7 71.7 71.7Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270 270 280 260 270 260 280 270 269.4Time on organics, hrs. 5.5 24.0 29.5 48.5 53.5 72.0 77.5 93.0 94.0Duration of run, hrs. 2 2 2 2 2 2 2 1 1MEA SV, gmol/hr/kgcat 4.14 4.46 4.36 5.52 4.51 4.41 4.26 4.15 4.18DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.411 2.048 2.803 0.721 0.985 0.509 2.082 1.210 1.044MEA 16.945 15.112 10.441 24.560 21.874 32.907 18.277 27.514 28.346PIP 1.144 1.466 1.969 0.566 0.916 0.444 1.962 1.108 1.004DETA 51.236 51.808 51.005 56.963 56.336 50.564 48.639 48.512 49.317AEEA 1.633 0.750 0.471 2.854 1.334 3.313 0.761 3.022 2.993AEP 1.408 1.792 2.383 0.570 0.907 0.527 2.313 1.179 1.053HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.906 1.541 1.048 0.803 0.704 0.531 0.684 0.714 0.7121-TETA 10.823 10.188 9.970 6.179 6.720 4.624 7.721 6.104 5.767DAEP 0.338 0.535 0.797 0.105 0.195 0.111 0.723 0.309 0.262PEEDA 0.223 0.461 0.644 0.087 0.173 0.000 0.675 0.341 0.227DPE 0.000 0.000 0.111 0.000 0.000 0.000 0.110 0.067 0.000AE-TAEA 1.379 1.180 1.543 0.441 0.741 0.374 1.397 0.543 0.4621-TEPA 4.588 3.926 4.570 1.388 1.867 0.952 3.120 1.724 1.606AE-DAEP 0.244 0.289 0.620 0.000 0.100 0.000 0.570 0.111 0.092AE-PEEDA 0.105 0.109 0.209 0.000 0.00 0.00 0.260 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.173 0.272 0.386 0.000 0.073 0.000 0.000 0.121 0.081Others 0.204 1.075 1.532 0.612 0.554 0.444 1.746 1.371 1.233MEA Conversion, % 53.39 58.54 71.07 33.10 39.32 8.35 48.80 23.43 21.10DETA Conversion, % 16.24 15.52 16.01 7.78 7.12 16.31 19.02 19.77 18.42Acyclic(N4), % 95.43 92.18 87.66 97.32 95.28 97.90 84.79 90.50 92.98Acyclic(N5), % 91.95 88.40 83.42 100.00 93.78 100.00 84.48 90.71 92.29.SIGMA.(N5)/.SIGMA.(N4), 0.53 0.45 0.58 0.25 0.36 0.25 0.54 0.33 0.32weight ratioAcyclic(N4)/cyclic 3.77 2.76 1.87 5.26 3.39 4.77 1.45 2.27 2.54(<=N4), weight ratio__________________________________________________________________________ TABLE XXVI__________________________________________________________________________Example No. 241 242 243 244 245 246 247 248 249__________________________________________________________________________Catalyst Type HH HH HH HH HH HH HH HH HHCatalyst weight, gm 73 73 73 73 73 73 73 73 73Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 267.3 271.6 280.3 269.1 261.9 278.4 268.9 268.5Time on organics, hrs. 6.5 25.5 30.5 49.5 54.5 73.5 78.5 97.0 99.2Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.79 3.55 3.59 3.31 3.30 3.15 3.16 2.93 3.01DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.819 1.510 2.684 0.504 1.224 0.583 2.338 1.353 1.183MEA 19.544 21.769 15.677 27.977 25.881 29.371 18.842 24.539 25.072PIP 2.131 1.958 2.907 0.791 1.591 0.810 2.955 1.830 1.645DETA 50.736 54.179 44.864 59.947 57.394 60.159 52.360 57.664 58.300AEEA 1.308 1.561 0.890 1.790 1.759 1.755 1.156 1.824 1.888AEP 2.087 1.610 2.837 0.614 0.959 0.559 2.442 1.151 1.012HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.474 0.468 0.382 0.280 0.349 0.222 0.415 0.272 0.2941-TETA 7.326 7.199 7.828 4.424 5.292 3.705 7.135 5.363 5.018DAEP 0.724 0.483 1.000 0.210 0.231 0.161 0.542 0.359 9.292PEEDA 0.625 0.332 1.108 0.086 0.180 0.101 0.599 0.000 0.173DPE 0.419 0.000 0.165 0.000 0.000 0.000 0.000 0.161 0.000AE-TAEA 0.941 0.687 1.356 0.000 0.305 0.000 0.786 1.117 0.2871-TEPA 3.854 2.896 4.945 0.160 0.979 0.000 3.242 0.000 0.839AE-DAEP 0.454 0.209 0.781 0.000 0.000 0.000 0.386 0.000 0.000AE-PEEDA 0.243 0.101 1.082 0.000 0.000 0.000 0.209 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.138 0.000 0.372 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.648 0.000 0.000 0.000 0.000 0.656 0.000Others 1.377 0.788 3.906 0.418 0.685 0.294 1.783 0.000 0.667MEA Conversion, % 47.04 41.40 57.92 24.31 30.19 20.72 49.47 33.74 32.35DETA Conversion, % 18.29 13.32 28.42 3.61 7.99 3.49 16.55 7.46 6.51Acyclic(N4), % 81.52 90.39 78.32 94.08 93.21 93.74 86.87 91.55 91.94Acyclic(N5), % 85.16 92.04 68.62 100.00 100.00 0.00 87.13 62.99 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.59 0.46 0.88 0.03 0.21 0.00 0.53 0.29 0.19weight ratioAcyclic(N4)/cyclic 1.30 1.75 1.02 2.77 1.91 2.41 1.15 1.61 1.70(<=N4), weight ratio__________________________________________________________________________ TABLE XXVII__________________________________________________________________________Example No. 250 251 252 253 254 255 256 257 258__________________________________________________________________________Catalyst Type II II II II II II II II IICatalyst weight, gm 81.2 81.2 81.2 81.2 81.2 81.2 81.2 81.2 81.2Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 274.4 274.4 280.9 259.8 270.6 259.9 281.6 270.4 270.4Time on organics, hrs. 22.0 26.0 45.5 50.5 69.0 74.5 95.0 119.0 120.0Duration of run, hrs. 2 2 2 2 2 2 2 1 1MEA SV, gmol/hr/kgcat 2.91 2.63 2.50 2.66 2.59 2.54 1.88 5.74 2.90DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.736 1.042 2.004 0.059 0.914 0.285 2.016 0.695 0.525MEA 21.698 25.193 18.576 29.894 25.669 27.372 16.604 25.555 23.517PIP 0.596 0.702 1.478 0.343 0.603 0.232 1.461 0.441 0.380DETA 56.344 55.631 51.168 57.632 56.035 63.408 49.886 55.967 57.620AEEA 3.232 3.031 2.286 2.679 3.151 1.296 2.181 2.896 3.070AEP 0.919 0.802 1.485 0.437 0.730 0.367 1.549 0.662 0.582HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.205 1.108 1.349 0.407 0.739 0.402 1.529 0.684 0.6041-TETA 7.587 6.573 10.443 4.085 6.496 2.782 9.613 6.122 6.727DAEP 0.164 0.130 0.275 0.056 0.100 0.000 0.490 0.102 0.089PEEDA 0.116 0.097 0.252 0.036 0.072 0.138 0.496 0.074 0.057DPE 0.000 0.000 0.000 0.000 0.030 0.101 0.040 0.044 0.066AE-TAEA 0.283 0.253 0.369 0.000 0.132 0.000 0.958 0.123 0.1731-TEPA 0.935 0.989 2.771 0.078 0.737 0.000 3.253 0.664 0.581AE-DAEP 0.000 0.000 0.161 0.000 0.000 0.000 0.196 0.075 0.000AE-PEEDA 0.000 0.000 0.125 0.000 0.000 0.000 0.156 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 0.666 0.639 1.229 1.336 0.741 0.467 2.672 0.616 0.819MEA Conversion, % 39.80 31.57 49.29 18.66 30.14 25.57 54.52 29.35 35.28DETA Conversion, % 8.23 10.19 16.98 6.80 9.36 2.48 18.80 8.04 5.76Acyclic(N4), % 96.92 97.13 95.72 98.01 97.29 93.00 91.57 96.87 97.18Acyclic(N5), % 100.00 100.00 91.66 100.00 100.00 0.00 92.28 91.26 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.13 0.16 0.28 0.02 0.12 0.00 0.38 0.12 0.10weight ratioAcyclic(N4)/cyclic 4.90 4.44 3.38 5.16 4.71 3.80 2.76 5.14 6.24(<=N4), weight ratio__________________________________________________________________________ TABLE XXVIII__________________________________________________________________________Example No. 259 260 261 262 263 264 265 266 267__________________________________________________________________________Catalyst Type JJ JJ JJ JJ JJ JJ JJ JJ JJCatalyst weight, gm 70.6 70.6 70.6 70.6 70.6 70.6 70.6 70.6 70.6Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 267.9 267.8 277.8 259.9 270.1 259.9 280.1 269.6 269Time on organics, hrs. 5.0 7.5 26.0 31.5 50.0 55.5 74.0 78.0 80.0Duration of run, hrs. 1 1 2 2 2 2 2 2 1.5MEA SV, gmol/hr/kgcat 7.43 7.71 3.35 3.61 3.27 3.62 3.67 3.54 3.54DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.791 0.623 1.276 0.399 0.923 0.398 1.559 0.813 0.864MEA 26.509 30.058 23.663 33.991 28.444 31.796 22.071 26.996 27.146PIP 1.147 0.517 1.058 0.224 0.638 0.217 1.106 0.510 0.513DETA 47.682 54.106 51.834 56.779 55.100 57.812 53.839 55.907 56.086AEEA 0.876 3.177 3.108 1.987 3.003 2.067 1.970 2.801 2.726AEP 1.015 0.506 1.073 0.246 0.586 0.243 0.935 0.458 0.457HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.944 0.557 0.833 0.309 0.576 0.340 0.831 0.577 0.5721-TETA 9.028 4.870 7.412 2.839 4.781 2.784 7.153 4.597 4.540DAEP 0.183 0.000 0.187 0.000 0.086 0.000 0.082 0.095 0.087PEEDA 0.136 0.000 0.165 0.000 0.000 0.000 0.169 0.000 0.069DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 1.392 0.209 0.543 0.000 0.357 0.119 0.545 0.238 0.2281-TEPA 2.723 0.634 2.000 0.109 0.910 0.179 1.995 0.719 0.686AE-DAEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.194 0.000 0.000Others 0.293 0.493 0.939 0.196 0.758 0.426 1.662 0.989 1.025MEA Conversion, % 26.38 17.06 34.61 6.67 22.13 12.36 39.22 25.04 24.86DETA Conversion, % 21.30 11.27 14.88 7.35 10.35 5.30 11.85 7.74 7.73Acyclic(N4), % 97.18 100.00 95.91 100.00 98.42 100.00 96.96 98.19 97.83Acyclic(N5), % 100.00 100.00 100.00 100.00 100.00 100.00 92.92 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.36 0.16 0.30 0.03 0.23 0.10 0.33 0.18 0.17weight ratioAcyclic(N4)/cyclic 4.42 5.30 3.32 6.42 4.09 6.79 3.48 4.87 4.54(<=N4), weight ratio__________________________________________________________________________ TABLE XXIX__________________________________________________________________________Example No. 268 269 270 271 272 273 274 275 276__________________________________________________________________________Catalyst Type KK KK KK KK KK KK KK KK KKCatalyst weight, gm 75.7 75.7 75.7 75.7 75.7 75.7 75.7 75.7 75.7Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.6 272.7 279.9 260.3 268.3 261.4 278.9 270.6 271.7Time on organics, hrs. 7.5 26.0 31.0 47.0 53.0 58.5 73.0 78.0 80.0Duration of run, hrs. 2 2 2 2 2 2.5 2 2 2MEA SV, gmol/hr/kgcat 3.78 3.60 4.14 2.88 4.21 4.57 4.11 4.29 4.20DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.512 2.957 2.611 0.873 1.230 0.581 2.105 1.136 1.147MEA 19.636 15.858 13.674 24.751 22.713 28.289 17.328 24.549 24.295PIP 0.850 1.545 1.281 0.362 0.559 0.213 0.983 0.499 0.466DETA 53.823 48.802 49.039 57.674 55.152 58.393 51.571 56.716 56.142AEEA 1.077 0.809 1.020 2.059 1.793 1.783 1.230 1.886 1.876AEP 0.980 2.034 1.569 0.409 0.641 0.321 1.189 0.550 0.582HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.511 1.463 1.689 0.877 1.037 0.668 1.665 0.917 0.9521-TETA 9.931 10.166 10.473 6.953 8.198 5.375 10.489 7.020 7.339DAEP 0.209 0.694 0.560 0.075 0.134 0.000 0.248 0.095 0.105PEEDA 0.118 0.559 0.497 0.000 0.091 0.000 0.182 0.000 0.067DPE 0.000 0.157 0.076 0.000 0.000 0.000 0.068 0.000 0.000AE-TAEA 1.152 1.307 1.509 0.447 0.967 0.273 1.060 0.599 0.6511-TEPA 2.758 3.629 3.880 0.863 1.812 0.388 3.088 0.995 1.169AE-DAEP 0.000 0.343 0.336 0.000 0.000 0.000 0.222 0.000 0.000AE-PEEDA 0.000 0.145 0.157 0.000 0.000 0.000 0.112 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.334 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.099 0.291 0.000 0.000 0.000 0.106 0.000 0.000Others 1.043 2.132 3.402 0.377 0.694 0.316 1.555 0.738 0.659MEA Conversion, % 46.54 56.52 62.58 32.37 37.89 22.83 52.40 32.99 33.57DETA Conversion, % 12.92 20.49 20.25 6.35 10.36 5.33 15.81 7.99 8.76Acyclic(N4), % 97.22 89.18 91.48 99.05 97.62 100.00 96.06 98.82 97.97Acyclic(N5), % 100.00 89.36 82.82 100.00 100.00 100.00 90.40 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.33 0.42 0.49 0.17 0.29 0.11 0.36 0.20 0.22weight ratioAcyclic(N4)/cyclic 5.31 2.33 3.05 9.26 6.48 11.31 4.55 6.94 6.80(<=N4), weight ratio__________________________________________________________________________ TABLE XXX__________________________________________________________________________Example No. 277 278 279 280 281 282 283 284 285__________________________________________________________________________Catalyst Type LL LL LL LL LL LL LL LL LLCatalyst weight, gm 70.6 70.6 70.6 70.6 70.6 70.6 70.6 70.6 70.6Pressure, psig 590 600 600 600 600 600 600 600 600Temperature, .degree.C. 267.9 267.8 277.8 259.9 270.1 259.9 280.1 269.6 269Time on organics, hrs. 5.0 7.5 26.0 31.5 50.0 55.5 74.0 78.0 80.0Duration of run, hrs. 1 1 2 2 2 2 2 2 1.5MEA SV, gmol/hr/kgcat 0.39 8.50 4.10 4.26 3.89 4.41 4.10 4.07 4.13DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 2.167 2.266 4.396 1.162 2.491 1.273 4.640 2.530 2.433MEA 28.978 28.688 26.446 33.928 28.222 33.924 23.574 29.868 29.121PIP 0.494 0.372 0.461 0.092 0.207 0.083 0.544 0.212 0.203DETA 48.084 52.021 51.406 57.383 55.479 56.855 50.221 53.418 55.210AEEA 1.425 1.525 1.038 1.006 1.321 1.043 1.027 1.313 1.296AEP 0.568 0.441 0.564 0.230 0.352 0.215 0.561 0.299 0.305HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.506 0.561 0.265 0.113 0.219 0.139 0.375 0.264 0.2661-TETA 7.871 6.131 3.828 1.714 4.080 1.741 5.218 3.019 3.221DAEP 0.101 0.000 0.095 0.124 0.000 0.000 0.085 0.000 0.000PEEDA 0.100 0.080 0.203 0.117 0.000 0.093 0.111 0.114 0.072DPE 0.117 0.000 0.254 0.107 0.132 0.000 0.309 0.118 0.097AE-TAEA 0.530 0.252 0.150 0.000 0.133 0.000 0.191 0.000 0.0001-TEPA 1.837 0.607 0.160 0.000 0.131 0.000 0.719 0.000 0.000AE-DAEP 0.100 0.000 0.000 0.000 0.000 0.000 0.112 0.000 0.000AE-PEEDA 0.000 0.157 0.147 0.000 0.000 0.000 0.178 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.101 0.093BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 2.103 1.740 5.237 1.773 2.532 1.674 5.777 2.917 2.755MEA Conversion, % 19.77 20.18 26.43 7.46 21.73 6.67 34.14 15.86 18.88DETA Conversion, % 20.89 13.97 15.01 6.98 8.55 7.04 16.62 10.56 8.60Acyclic(N4), % 96.35 98.82 88.13 84.00 97.03 95.30 91.72 93.42 95.39Acyclic(N5), % 95.93 84.54 67.84 0.00 100.00 0.00 75.87 0.00 0.00.SIGMA.(N5)/.SIGMA.(N4), 0.28 0.15 0.10 0.00 0.06 0.00 0.20 0.03 0.03weight ratioAcyclic(N4)/cyclic 6.07 7.50 2.60 2.72 6.22 4.81 3.47 4.42 5.16(<=N4), weight ratio__________________________________________________________________________ TABLE XXXI__________________________________________________________________________Example No. 286 287 288 289 290 291 292 293 294__________________________________________________________________________Catalyst Type MM MM MM MM MM MM MM MM MMCatalyst weight, gm 80.1 80.1 80.1 80.1 80.1 80.1 80.1 80.1 80.1Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.1 270 280.2 259.7 270.1 259.6 280 270 270Time on organics, hrs. 5.0 7.5 26.5 31.5 49.7 54.0 74.0 77.5 80.0Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.81 3.85 3.23 4.01 3.93 4.12 3.71 3.87 3.79DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.935 2.148 4.938 0.907 1.895 0.879 4.006 2.166 1.951MEA 18.750 21.318 20.112 30.534 28.213 31.731 24.388 29.089 28.221PIP 0.553 0.373 0.726 0.053 0.150 0.043 0.410 0.190 0.179DETA 59.396 52.368 51.336 60.802 57.134 60.506 53.455 57.017 58.930AEEA 0.561 0.915 0.707 0.796 1.023 0.782 0.908 1.152 1.167AEP 0.744 0.572 0.748 0.309 0.383 0.307 0.625 0.384 0.410HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.214 1.199 0.429 0.429 0.192 0.365 0.366 0.265 0.2661-TETA 9.307 8.213 5.708 1.341 2.861 1.182 4.049 2.751 2.937DAEP 0.134 0.098 0.388 0.083 0.164 0.000 0.099 0.107 0.177PEEDA 0.113 0.091 0.487 0.000 0.168 0.097 0.310 0.113 0.134DPE 0.111 0.074 0.489 0.000 0.145 0.000 0.313 0.141 0.126AE-TAEA 0.592 0.135 0.282 0.140 0.151 0.000 0.279 0.118 0.1521-TEPA 2.145 1.256 0.907 0.000 0.116 0.111 0.000AE-DAEP 0.105 0.097 0.165 0.000 0.000 0.000 0.000 0.000 0.000AE-PEEDA 0.221 0.227 0.312 0.000 0.000 0.000 0.129 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 7.869 5.765 6.160 1.656 2.354 1.509 5.848 2.786 2.669MEA Conversion, % 49.20 41.78 44.57 16.55 21.53 13.41 32.99 20.19 23.49DETA Conversion, % 18.85 15.01 15.92 1.24 5.56 1.86 12.71 7.03 5.05Acyclic(N4), % 96.71 97.29 81.81 95.55 86.50 94.12 85.94 89.31 88.02Acyclic(N5), % 89.37 81.10 67.94 100.00 100.00 0.00 75.42 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.28 0.18 0.23 0.08 0.08 0.00 0.10 0.07 0.04weight ratioAcyclic(N4)/cyclic 6.36 7.80 2.16 3.98 3.03 3.47 2.51 3.23 3.12(<=N4), weight ratio__________________________________________________________________________ TABLE XXXII__________________________________________________________________________Example No. 295 296 297 298 299 300 301 302 303__________________________________________________________________________Catalyst Type NN NN NN NN NN NN NN NN NNCatalyst weight, gm 81.2 81.2 81.2 81.2 81.2 81.2 81.2 81.2 81.2Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.9 272.7 279.9 260.3 268.3 261.4 278.9 270.6 271.7Time on organics, hrs. 7.5 26.0 31.0 47.0 53.0 58.5 73.0 78.0 80.0Duration of run, hrs. 2 2 2 2 2 2.5 2 2 2MEA SV, gmol/hr/kgcat 3.80 3.43 3.59 3.68 3.75 4.01 3.56 3.87 3.87DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.775 2.809 2.208 1.431 2.058 0.987 4.151 1.948 1.942MEA 28.020 25.978 11.404 32.207 28.431 31.510 25.905 30.029 29.693PIP 0.108 0.150 0.000 0.069 0.120 0.040 0.254 0.118 0.112DETA 59.798 58.058 46.899 58.424 57.923 59.289 52.433 57.883 58.062AEEA 0.541 0.675 1.138 0.696 0.890 0.677 0.840 0.882 0.858AEP 0.313 0.348 1.766 0.248 0.320 0.252 0.449 0.311 0.322HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.092 0.169 1.615 0.393 0.129 0.398 0.234 0.129 0.1281-TETA 3.144 3.193 10.766 1.341 2.981 1.076 3.031 2.141 2.296DAEP 0.168 0.096 0.685 0.064 0.076 0.099 0.109 0.146 0.166PEEDA 0.243 0.153 0.635 0.058 0.167 0.147 0.177 0.113 0.141DPE 0.184 0.207 0.122 0.098 0.172 0.095 0.253 0.136 0.160AE-TAEA 0.203 0.120 2.095 0.000 0.159 0.000 0.298 0.115 0.1421-TEPA 0.216 0.000 5.688 0.179 0.000 0.121 0.099 0.000 0.000AE-DAEP 0.000 0.000 0.571 0.000 0.000 0.000 0.000 0.000 0.000AE-PEEDA 0.000 0.000 0.651 0.000 0.000 0.000 0.098 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.469 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.532 0.000 0.000 0.000 0.000 0.000 0.000Others 2.095 3.752 4.778 2.591 3.333 2.170 6.088 2.749 2.847MEA Conversion, % 23.74 28.57 68.94 12.45 22.42 13.61 27.80 17.72 18.86DETA Conversion, % 3.28 5.12 24.09 5.62 6.07 3.39 13.14 5.74 5.71Acyclic(N4), % 84.47 88.05 89.57 88.73 88.23 81.18 85.84 85.16 83.84Acyclic(N5), % 100.00 100.00 77.78 100.00 100.00 100.00 80.24 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.11 0.03 0.72 0.09 0.05 0.07 0.13 0.04 0.05weight ratioAcyclic(N4)/cyclic 3.19 3.52 3.86 3.23 3.64 2.33 2.63 2.75 2.69(<=N4), weight ratio__________________________________________________________________________ TABLE XXXIII__________________________________________________________________________Example No. 304 305 306 307 308 309 310 311 312__________________________________________________________________________Catalyst Type OO OO OO OO OO OO OO OO OOCatalyst weight, gm 76.3 76.3 76.3 76.3 76.3 76.3 76.3 76.3 76.3Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.9 272.7 279.9 260.3 268.3 261.4 278.9 270.6 271.7Time on organics, hrs. 7.5 26.0 31.0 47.0 53.0 58.5 73.0 78.0 80.0Duration of run, hrs. 2 2 2 2 2 2.5 2 2 2MEA SV, gmol/hr/kgcat 3.99 3.68 4.09 2.65 1.23 0.96 3.38 3.80 3.31DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.574 1.791 4.858 0.968 2.024 2.100 2.080 0.921 0.937MEA 18.061 16.725 23.777 24.322 13.187 16.037 16.072 23.937 22.805PIP 1.056 0.060 0.323 0.500 1.357 1.136 1.291 0.528 0.587DETA 52.716 51.336 50.891 55.597 51.804 51.667 51.643 57.189 56.650AEEA 1.515 1.794 0.774 3.457 3.008 2.269 1.717 2.377 3.256AEP 1.413 1.302 0.469 0.517 1.435 1.300 1.360 0.518 0.660HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.676 1.719 0.290 0.781 1.672 1.529 1.523 0.820 0.8791-TETA 11.477 11.388 3.548 6.608 11.810 11.030 10.185 6.667 7.190DAEP 0.280 0.282 0.141 0.080 0.263 0.294 0.263 0.097 0.107PEEDA 0.193 0.215 0.257 0.000 0.192 0.203 0.206 0.000 0.067DPE 0.000 0.000 0.366 0.000 0.000 0.072 0.000 0.000 0.000AE-TAEA 0.773 0.861 0.327 0.406 0.810 0.775 0.789 0.456 0.5131-TEPA 3.017 3.327 0.123 0.963 3.541 3.449 2.992 1.036 1.135AE-DAEP 0.088 0.115 0.110 0.000 0.227 0.177 0.222 0.000 0.000AE-PEEDA 0.000 0.000 0.176 0.000 0.115 0.135 0.110 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.094 0.000 0.000 0.072 0.098 0.058 0.000 0.000Others 0.509 0.841 7.550 0.461 1.103 0.677 1.461 0.555 0.534MEA Conversion, % 50.94 53.95 33.72 32.83 63.87 55.94 55.35 34.29 37.73DETA Conversion, % 14.90 15.99 15.70 8.75 15.64 15.63 14.74 6.69 8.06Acyclic(N4), % 96.53 96.35 83.41 98.93 96.73 95.66 96.15 98.72 97.88Acyclic(N5), % 97.72 95.24 61.11 100.00 91.31 91.12 90.64 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.28 0.32 0.16 0.18 0.34 0.35 0.34 0.20 0.20weight ratioAcyclic(N4)/cyclic 4.47 4.59 2.47 6.74 4.15 4.18 3.75 6.55 5.67(<=N4), weight ratio__________________________________________________________________________ TABLE XXXIV__________________________________________________________________________Example No. 313 314 315 316 317 318 319 320 321__________________________________________________________________________Catalyst Type PP PP PP PP PP PP PP PP PPCatalyst weight, gm 76.1 76.1 76.1 76.1 76.1 76.1 76.1 76.1 76.1Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270 270 280 260 270 260 280 270 269.4Time on organics, hrs. 5.5 24.0 29.5 48.5 53.5 72.0 77.5 93.0 94.0Duration of run, hrs. 2 2 2 2 2 2 2 1 1MEA SV, gmol/hr/kgcat 4.03 3.42 4.57 5.42 4.80 4.26 4.14 4.21 1.91DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 2.718 0.000 3.456 1.014 1.450 0.805 3.050 1.886 1.860MEA 13.198 13.705 10.445 24.724 21.688 32.394 18.370 26.238 25.429PIP 1.176 1.217 1.276 0.318 0.501 0.279 1.161 0.667 0.651DETA 44.099 47.849 45.082 54.434 53.648 46.319 42.468 43.338 42.572AEEA 1.298 1.149 0.783 1.841 1.512 2.946 1.159 2.722 2.762AEP 1.774 1.847 1.906 0.410 0.649 0.391 1.624 0.861 0.848HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.744 1.923 1.704 1.507 1.720 1.323 1.037 1.629 1.6561-TETA 12.612 12.764 11.841 8.466 10.127 7.262 9.928 9.641 10.039DAEP 0.762 0.661 0.856 0.081 0.169 0.072 0.671 0.224 0.201PEEDA 0.511 0.477 0.625 0.000 0.110 0.000 0.510 0.153 0.129DPE 0.135 0.166 0.089 0.000 0.000 0.000 0.101 0.076 0.000AE-TAEA 2.518 1.883 2.119 0.797 1.392 0.705 1.873 1.397 1.5071-TEPA 6.017 4.679 5.227 1.495 2.798 1.149 4.035 2.862 3.120AE-DAEP 0.397 0.354 0.577 0.000 0.000 0.000 0.486 0.102 0.214AE-PEEDA 0.098 0.000 0.207 0.000 0.000 0.000 0.102 0.000 0.103iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.180 0.219 0.363 0.000 0.000 0.000 0.246 0.303 0.151BPEA 0.182 0.198 0.325 0.000 0.000 0.000 0.200 0.174 0.113Others 1.581 2.529 4.320 0.513 0.856 0.383 4.070 1.426 1.246MEA Conversion, % 63.48 62.41 71.33 32.51 41.96 8.72 48.56 27.14 28.62DETA Conversion, % 27.47 22.01 26.47 11.69 14.67 22.43 29.33 28.48 28.98Acyclic(N4), % 91.07 91.84 89.61 99.19 97.70 99.17 89.54 96.14 97.25Acyclic(N5), % 90.88 89.49 83.31 100.00 100.00 100.00 85.10 88.03 88.85.SIGMA.(N5)/.SIGMA.(N4), 0.60 0.46 0.58 0.23 0.35 0.21 0.57 0.41 0.43weight ratioAcyclic(N4)/cyclic 3.29 3.36 2.85 12.33 8.29 11.56 2.70 5.69 6.40(< = N4), weight ratio__________________________________________________________________________ TABLE XXXV__________________________________________________________________________Example No. 322 323 324 325 326 327 328 329 330__________________________________________________________________________Catalyst Type QQ QQ QQ QQ QQ QQ QQ QQ QQCatalyst weight, gm 78.5 78.5 78.5 78.5 78.5 78.5 78.5 78.5 78.5Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.3 270.8 280.9 259.5 270.8 261.4 282.6 273.4 270.8Time on organics, hrs. 4.0 7.0 26.0 31.0 50.0 55.0 74.0 79.0 99.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.42 3.32 3.47 3.50 3.64 3.76 3.58 3.51 3.64DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 2.064 1.889 2.436 0.860 0.798 0.344 1.077 0.453 0.663MEA 14.084 15.810 12.462 36.060 25.744 30.392 15.607 22.241 25.522PIP 1.454 1.307 1.613 0.473 0.583 0.199 0.827 0.380 0.467DETA 51.792 51.235 52.756 54.948 56.753 59.500 53.106 59.354 60.415AEEA 0.857 1.123 0.758 1.393 0.172 1.675 1.251 1.785 0.264AEP 2.286 1.884 2.151 0.372 0.645 0.390 1.366 0.626 0.647HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.116 0.989 1.006 0.279 0.629 0.401 1.612 0.804 0.6291-TETA 12.082 10.881 10.297 2.687 6.508 4.381 11.880 6.933 5.481DAEP 0.742 0.738 0.685 0.000 0.135 0.000 0.271 0.099 0.151PEEDA 0.468 0.513 0.507 0.000 0.071 0.000 0.256 0.087 0.127DPE 0.000 0.133 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 1.823 1.579 1.601 0.000 0.441 0.000 0.202 0.000 0.3801-TEPA 5.194 4.155 4.031 0.000 0.624 0.000 3.427 0.617 0.349AE-DAEP 0.472 0.373 0.373 0.000 0.000 0.000 0.230 0.000 0.000AE-PEEDA 0.179 0.155 0.159 0.000 0.000 0.000 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.109 0.154 0.117 0.000 0.000 0.000 0.186 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 0.428 0.801 1.358 0.429 2.397 0.417 2.141 1.419 2.054MEA Conversion, % 62.62 57.18 65.91 1.08 29.53 17.71 57.46 38.96 31.32DETA Conversion, % 18.31 17.53 14.23 10.42 7.67 4.25 13.98 3.19 3.37Acyclic(N4), % 91.61 89.56 90.46 100.00 97.20 100.00 96.24 97.65 95.65Acyclic(N5), % 90.22 89.36 89.68 0.00 100.00 0.00 89.72 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.54 0.48 0.50 0.00 0.14 0.00 0.29 0.08 0.11weight ratioAcyclic(N4)/cyclic 2.67 2.59 2.28 3.51 4.98 8.11 4.96 6.49 4.39(< = N4), weight ratio__________________________________________________________________________ TABLE XXXVI__________________________________________________________________________Example No. 331 332 333 334 335 336 337 338 339__________________________________________________________________________Catalyst Type RR RR RR RR RR RR RR RR RRCatalyst weight, gm 74.5 74.5 74.5 74.5 74.5 74.5 74.5 74.5 74.5Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 267.3 271.6 280.4 260.3 269.1 261.9 278.4 268.9 268.5Time on organics, hrs. 6.5 25.5 30.5 49.5 54.5 73.5 78.5 97.0 99.2Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.48 4.16 4.21 3.93 3.96 3.98 4.08 3.40 3.96DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.181 1.202 2.220 0.541 0.922 0.455 1.851 1.236 0.863MEA 24.149 27.125 24.297 32.485 29.621 31.003 24.872 30.577 28.781PIP 0.405 0.291 0.859 0.101 0.203 0.079 0.464 0.261 0.228DETA 57.182 59.913 55.802 60.897 60.714 62.348 54.893 58.708 61.316AEEA 0.929 1.479 1.151 1.074 1.180 0.920 1.384 1.342 1.371AEP 0.649 0.503 0.740 0.341 0.427 0.349 0.703 0.474 0.446HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.720 0.473 0.644 0.321 0.303 0.320 0.553 0.276 0.2911-TETA 7.014 4.341 6.500 1.844 3.136 1.875 6.108 2.942 3.059DAEP 0.113 0.000 0.109 0.000 0.098 0.000 0.348 0.090 0.090PEEDA 0.098 0.000 0.111 0.000 0.000 0.000 0.583 0.000 0.000DPE 0.000 0.000 0.083 0.000 0.000 0.000 0.182 0.000 0.000AE-TAEA 0.438 0.224 0.288 0.000 0.000 0.000 0.826 0.000 0.0001-TEPA 1.158 0.139 0.695 0.000 0.000 0.000 1.081 0.000 0.000AE-DAEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-PEEDA 0.105 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 1.839 1.060 2.010 0.836 1.046 0.930 2.604 0.915 0.887MEA Conversion, % 34.39 26.20 33.56 12.26 19.77 16.34 32.77 16.26 21.89DETA Conversion, % 7.68 3.12 9.31 2.25 2.27 0.01 11.81 4.45 1.10Acyclic(N4), % 97.35 100.00 95.92 100.00 97.24 100.00 85.69 97.27 97.40Acyclic(N5), % 93.82 100.00 100.00 0.00 0.00 0.00 100.00 0.00 0.00.SIGMA.(N5)/.SIGMA.(N4), 0.21 0.08 0.13 0.00 0.00 0.00 0.25 0.00 0.00weight ratioAcyclic(N4)/cyclic 6.12 6.06 3.75 4.89 4.73 5.13 2.92 3.90 4.39(< = N4), weight ratio__________________________________________________________________________ TABLE XXXVII__________________________________________________________________________Example No. 340 341 342 343 344 345 346 347 348__________________________________________________________________________Catalyst Type SS SS SS SS SS SS SS SS SSCatalyst weight, gm 84 84 84 84 84 84 84 84 84Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270 270 280 260 270 260 280 270 270Time on organics, hrs. 6.5 24.0 29.5 48.0 53.7 71.0 74.0 98.0 99.0Duration of run, hrs. 2 2 2 2 2 2 1 2 1MEA SV, gmol/hr/kgcat 2.92 2.94 2.91 3.00 3.21 2.85 3.69 3.28 3.38DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 3.143 3.522 6.151 1.751 3.148 1.874 5.153 2.734 2.608MEA 30.100 29.982 26.771 32.968 30.586 32.904 26.314 31.293 31.488PIP 0.084 0.091 0.154 0.000 0.064 0.042 0.115 0.055 0.064DETA 55.305 54.533 48.236 58.522 54.943 55.103 47.403 53.775 53.754AEEA 0.153 0.233 0.160 0.091 0.000 0.090 0.176 0.171 0.152AEP 0.295 0.276 0.352 0.223 0.245 0.200 0.308 0.227 0.225HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.380 0.387 0.555 0.226 1.227 0.630 0.434 0.277 0.2901-TETA 1.422 1.462 1.967 0.594 0.634 0.365 1.619 0.287 0.240DAEP 0.097 0.089 0.101 0.117 0.081 0.068 0.090 0.088 0.095PEEDA 0.084 0.081 0.215 0.150 0.109 0.121 0.166 0.158 0.167DPE 0.181 0.185 0.356 0.110 0.150 0.062 0.241 0.134 0.129AE-TAEA 0.000 0.000 0.184 0.000 0.000 0.000 0.122 0.000 0.0001-TEPA 0.133 0.000 0.123 0.000 0.148 0.103 0.000 0.000 0.000AE-DAEP 0.000 0.000 0.000 0.000 0.132 0.000 0.000 0.000 0.000AE-PEEDA 0.000 0.000 0.104 0.000 0.000 0.000 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 4.933 5.408 9.890 3.207 4.813 2.118 8.097 5.003 4.889MEA Conversion, % 17.10 17.35 25.92 10.37 15.66 6.14 22.88 11.56 10.89DETA Conversion, % 9.47 10.66 20.67 5.44 9.96 6.58 17.43 9.67 9.59Acyclic(N4), % 83.24 83.89 78.95 68.51 84.54 79.89 80.51 59.78 57.54Acyclic(N5), % 100.00 0.00 74.66 0.00 52.87 100.00 100.00 0.00 0.00.SIGMA.(N5)/.SIGMA.(N4), 0.06 0.00 0.13 0.00 0.13 0.08 0.05 0.00 0.00weight ratioAcyclic(N4)/cyclic 2.43 2.56 2.14 1.37 2.87 2.02 2.23 0.85 0.78(< = N4), weight ratio__________________________________________________________________________ TABLE XXXVIII__________________________________________________________________________Example No. 349 350 351 352 353 354 355 356 357__________________________________________________________________________Catalyst Type TT TT TT TT TT TT TT TT TTCatalyst weight, gm 80.7 80.7 80.7 80.7 80.7 80.7 80.7 80.7 80.7Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.6 269.6 279.5 260.0 269.8 259.2 280.0 271.4 269.4Time on organics, hrs. 20.5 24.5 44.0 49.0 68.0 73.0 92.0 97.0 116.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.55 3.63 3.60 3.78 3.52 3.53 3.01 3.34 3.20DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.354 1.094 2.246 0.648 1.032 0.457 2.918 1.351 1.546MEA 18.152 18.204 13.314 28.101 23.557 28.629 14.287 21.618 21.329PIP 0.850 0.723 1.703 0.353 0.902 0.303 2.036 0.844 1.106DETA 49.396 53.187 48.982 57.642 58.104 58.959 49.804 54.426 52.827AEEA 1.115 1.255 0.534 1.459 0.788 1.073 0.483 0.249 0.256AEP 1.250 0.946 2.103 0.528 0.967 0.526 2.138 1.089 1.122HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.869 1.413 1.083 0.729 0.404 0.462 0.770 1.319 1.2581-TETA 12.723 11.602 11.826 6.274 7.800 5.369 10.228 9.582 9.770DAEP 0.209 0.196 0.731 0.061 0.485 0.286 0.654 0.151 0.165PEEDA 0.152 0.141 0.630 0.000 0.281 0.137 0.454 0.114 0.115DPE 0.000 0.000 0.064 0.000 0.000 0.000 0.062 0.000 0.000AE-TAEA 0.956 1.039 2.383 0.000 0.000 0.000 1.590 0.000 0.0001-TEPA 3.937 3.244 5.190 0.326 0.168 0.000 3.399 0.708 0.786AE-DAEP 0.509 0.284 0.454 0.000 0.000 0.000 0.085 0.000 0.000AE-PEEDA 0.534 0.100 0.131 0.000 0.000 0.000 0.201 0.087 0.108iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 1.412 0.293 0.271 0.000 0.000 0.000 0.168 0.099 0.371BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 1.363 1.228 2.694 1.129 0.741 0.607 2.400 3.254 3.290MEA Conversion, % 51.28 50.92 64.50 24.02 35.62 22.13 60.51 41.07 41.44DETA Conversion, % 21.21 14.77 22.37 7.37 5.63 4.69 18.19 11.82 13.80Acyclic(N4), % 97.41 97.47 90.05 99.13 91.45 93.23 90.38 97.63 97.53Acyclic(N5), % 66.59 86.35 89.84 100.00 100.00 0.00 91.65 79.22 62.13.SIGMA.(N5)/.SIGMA.(N4), 0.53 0.37 0.59 0.05 0.02 0.00 0.45 0.08 0.11weight ratioAcyclic(N4)/cyclic 5.52 6.49 2.47 7.44 3.11 4.66 2.06 4.96 4.40(< = N4), weight ratio__________________________________________________________________________ TABLE XXXIX__________________________________________________________________________Example No. 358 359 360 361 362 363 364 365 366__________________________________________________________________________Catalyst Type UU UU UU UU UU UU UU UU UUCatalyst weight, gm 89 89 89 89 89 89 89 89 89Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270 270 280 260 270 260 270 270 270Time on organics, hrs. 6.5 24.0 29.5 48.0 53.7 71.0 24.0 98.0 99.0Duration of run, hrs. 2 2 2 2 2 2 2 2 1MEA SV, gmol/hr/kgcat 2.91 2.74 2.97 2.84 3.12 2.66 2.76 2.88 3.02DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.718 0.645 1.457 0.333 0.542 0.310 1.234 0.585 0.539MEA 27.595 26.525 25.356 30.520 27.336 29.634 25.529 26.745 28.074PIP 1.107 1.105 2.119 0.588 1.024 0.549 1.947 0.000 0.917DETA 57.184 57.402 53.992 60.160 55.509 55.391 54.113 54.836 55.562AEEA 1.254 1.122 0.744 1.059 0.901 0.959 0.906 1.108 1.108AEP 0.828 0.865 1.760 0.408 0.730 0.375 1.646 0.736 0.672HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.643 0.674 0.525 0.429 0.414 0.344 0.605 0.489 0.5121-TETA 5.227 5.572 5.376 3.427 4.632 2.912 6.015 5.284 4.209DAEP 0.127 0.144 0.312 0.000 0.117 0.000 0.350 0.115 0.094PEEDA 0.140 0.173 0.363 0.000 0.128 0.000 0.428 0.126 0.099DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 0.366 0.492 0.490 0.169 0.040 0.124 0.669 0.166 0.2741-TEPA 1.413 1.833 1.908 0.515 1.633 0.351 2.473 1.458 1.032AE-DAEP 0.000 0.000 0.150 0.000 0.000 0.000 0.136 0.098 0.000AE-PEEDA 0.000 0.000 0.131 0.000 0.000 0.000 0.136 0.079 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.112 0.000 0.000Others 0.277 0.238 0.707 0.082 0.575 0.000 0.491 0.374 0.208MEA Conversion, % 25.36 28.39 30.94 17.40 23.34 13.63 31.57 23.79 20.82DETA Conversion, % 8.07 7.90 12.61 3.24 7.49 4.05 13.80 7.13 6.87Acyclic(N4), % 95.65 95.17 89.74 100.00 95.38 100.00 89.49 95.99 96.08Acyclic(N5), % 100.00 100.00 89.50 100.00 100.00 100.00 89.11 90.17 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.29 0.35 0.41 0.18 0.32 0.15 0.48 0.30 0.27weight ratioAcyclic(N4)/cyclic 2.67 2.73 1.30 3.87 2.52 3.52 1.51 5.90 2.65(< = N4), weight ratio__________________________________________________________________________ TABLE XL__________________________________________________________________________Example No. 367 368 369 370 371 372 373 374__________________________________________________________________________Catalyst Type VV VV VV VV VV VV VV VVCatalyst weight, gm 89 89 89 89 89 89 89 89Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 270 280 260 270 260 260 270 270Time on organics, hrs. 6.5 29.5 48.0 53.7 71.0 74.0 98.0 99.0Duration of run, hrs. 2 2 2 2 2 1 2 1MEA SV, gmol/hr/kgcat 3.60 4.04 3.87 3.77 3.63 3.82 3.80 4.14DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.213 0.589 0.063 0.237 0.132 0.597 0.268 0.221MEA 28.924 28.276 32.679 29.051 31.767 26.401 29.867 31.406PIP 0.577 1.302 0.331 0.637 0.305 1.250 0.636 0.606DETA 60.693 59.604 61.967 55.284 57.693 54.502 57.225 57.491AEEA 1.337 0.873 0.904 0.882 0.873 1.072 1.112 1.076AEP 0.468 1.015 0.268 0.432 0.237 0.913 0.463 0.406HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.446 0.369 0.216 0.202 0.171 0.391 0.328 0.2871-TETA 3.783 3.779 1.991 2.687 1.723 4.061 2.922 2.612DAEP 0.000 0.182 0.000 0.064 0.000 0.133 0.000 0.000PEEDA 0.000 0.236 0.000 0.000 0.000 0.175 0.000 0.000DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 0.194 0.224 0.000 0.000 0.000 0.289 0.138 0.0001-TEPA 0.663 0.879 0.000 0.296 0.000 1.049 0.455 0.350AE-DAEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 0.102 0.321 0.081 0.079 0.000 0.307 0.187 0.194MEA Conversion, % 21.74 24.03 11.82 14.35 8.93 24.03 15.55 11.95DETA Conversion, % 2.40 4.83 0.62 3.13 1.70 6.80 3.84 4.21Acyclic(N4), % 100.00 90.85 100.00 97.82 100.00 93.54 100.00 100.00Acyclic(N5), % 100.00 100.00 0.00 100.00 0.00 100.00 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.20 0.24 0.00 0.10 0.00 0.28 0.18 0.12weight ratioAcyclic(N4)/cyclic 4.04 1.52 3.69 2.55 3.50 1.80 2.96 2.86(< = N4), weight ratio__________________________________________________________________________ TABLE XLI__________________________________________________________________________Example No. 375 376 377 378 379 380 381 382 383__________________________________________________________________________Catalyst Type WW WW WW WW WW WW WW WW WWCatalyst weight, gm 109.3 109.3 109.3 109.3 109.3 109.3 109.3 109.3 109.3Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 272.8 272.4 281.4 261.6 271.6 261.2 281.1 271.8 271.8Time on organics, hrs. 4.5 25.5 30.5 49.5 54.5 73.5 78.5 96.5 98.0Duration of run, hrs. 2 2 2 2 2 2 2 1 1MEA SV, gmol/hr/kgcat 2.41 2.58 2.54 2.56 2.62 2.46 2.37 2.35 2.01DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 2.497 6.772 12.561 3.271 5.650 3.027 8.398 6.989 6.342MEA 11.926 3.136 0.306 9.052 3.533 8.556 0.344 2.253 2.052PIP 1.508 3.617 5.688 2.203 3.219 2.114 3.924 3.679 3.432DETA 43.663 34.939 27.007 40.944 37.212 42.204 28.868 34.736 33.388AEEA 0.175 0.056 0.056 0.424 0.046 0.430 0.068 0.054 0.052AEP 2.674 6.800 10.087 3.163 5.751 2.837 8.269 5.679 5.546HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 5.276 2.471 0.713 3.624 2.701 3.372 1.567 2.339 2.3871-TETA 13.602 13.192 7.877 15.395 13.650 14.959 10.350 13.399 13.817DAEP 0.031 3.410 4.966 0.050 2.804 1.167 5.005 2.753 2.852PEEDA 0.402 1.586 3.460 0.670 1.378 0.689 3.719 1.712 1.642DPE 0.164 0.126 0.173 0.124 0.130 0.189 0.296 0.208 0.214AE-TAEA 4.114 2.399 0.888 3.396 2.480 3.259 1.667 2.421 2.6841-TEPA 4.558 5.996 3.503 6.285 6.269 6.192 5.083 6.762 7.401AE-DAEP 0.056 1.150 2.203 0.395 0.981 0.321 2.619 1.146 1.196AE-PEEDA 0.000 0.368 0.656 0.172 0.301 0.143 0.777 0.355 0.371iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.202 0.000 0.000 0.000 0.230 0.000 0.049BPEA 0.019 0.170 0.043 0.198 0.142 0.105 0.056 0.133 0.249Others 2.325 4.721 8.340 3.395 3.331 1.197 7.221 4.133 4.304MEA Conversion, % 67.86 91.64 99.18 75.79 90.41 76.63 99.08 93.85 94.36DETA Conversion, % 30.07 44.67 56.74 34.91 39.97 31.48 53.83 43.61 45.49Acyclic(N4), % 96.93 75.36 49.97 95.75 79.13 89.96 56.92 77.11 77.49Acyclic(N5), % 99.14 83.26 58.59 92.68 86.00 94.33 64.70 84.90 84.39.SIGMA.(N5)/.SIGMA.(N4), 0.45 0.49 0.44 0.53 0.49 0.49 0.50 0.53 0.57weight ratioAcyclic(N4)/cyclic 3.95 1.01 0.35 3.06 1.23 2.62 0.56 1.12 1.18(< = N4), weight ratio__________________________________________________________________________ TABLE XLII__________________________________________________________________________Example No. 384 385 386 387 388 389 390 391 392__________________________________________________________________________Catalyst Type XX XX XX XX XX XX XX XX XXCatalyst weight, gm 117 117 117 117 117 117 117 117 117Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.3 269.2 279.4 258.8 269.2 259.4 279.2 268.9 269.6Time on organics, hrs. 23.5 27.5 47.0 52.0 71.0 76.0 95.0 100.0 120.0Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.58 2.36 2.57 2.67 2.50 2.45 1.13 0.81 1.98DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 3.709 3.837 8.600 2.804 3.721 0.488 9.601 7.741 3.411MEA 9.936 9.370 5.731 16.450 9.968 25.695 3.708 7.550 16.344PIP 2.708 2.524 4.204 1.433 2.717 0.842 4.962 3.887 2.182DETA 38.446 38.390 33.775 45.291 38.571 55.220 34.097 37.900 43.567AEEA 0.291 0.324 0.317 0.339 0.292 0.367 0.388 0.526 0.391AEP 4.686 4.502 7.284 1.974 4.702 0.717 8.582 5.708 2.836HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 3.835 4.377 2.941 4.188 3.848 1.310 2.846 3.803 3.7471-TETA 8.969 9.950 7.471 9.662 8.998 6.251 8.150 9.402 9.633DAEP 1.874 1.752 2.889 0.521 1.880 0.065 2.947 1.720 0.876PEEDA 0.861 0.698 1.317 0.180 0.864 0.000 1.373 0.837 0.409DPE 0.078 0.000 0.059 0.000 0.078 0.000 0.000 0.000 0.000AE-TAEA 0.228 0.307 0.306 0.270 0.229 0.199 0.000 0.000 0.0001-TEPA 4.090 4.452 0.103 3.018 4.103 0.000 2.329 3.192 2.764AE-DAEP 0.690 0.464 0.318 0.583 0.692 0.000 0.787 0.451 0.000AE-PEEDA 0.231 0.161 0.259 0.301 0.232 0.000 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.068 0.115 0.462 1.425 0.068 0.000 0.359 0.000 0.257BPEA 0.160 0.349 0.515 0.765 0.161 0.000 0.358 0.278 0.000Others 8.818 8.017 13.158 2.876 8.846 1.176 7.923 4.755 2.383MEA Conversion, % 72.57 74.10 84.35 54.81 72.57 27.13 89.78 78.65 53.20DETA Conversion, % 36.91 36.95 45.17 26.06 36.91 6.93 44.14 36.31 25.86Acyclic(N4), % 81.99 85.39 70.94 95.19 81.99 99.14 71.79 83.78 91.24Acyclic(N5), % 78.98 81.38 20.83 51.69 78.98 100.00 60.77 81.41 91.50.SIGMA.(N5)/.SIGMA.(N4), 0.35 0.35 0.13 0.44 0.35 0.03 0.25 0.25 0.21weight ratioAcyclic(N4)/cyclic 1.25 1.51 0.66 3.37 1.25 4.66 0.62 1.09 2.12(< = N4), weight ratio__________________________________________________________________________ TABLE XLIII__________________________________________________________________________Example No. 393 394 395 396 397 398 399 400 401__________________________________________________________________________Catalyst Type YY YY YY YY YY YY YY YY YYCatalyst weight, gm 109.7 109.7 109.7 109.7 109.7 109.7 109.7 109.7 109.7Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 272.8 272.4 281.4 261.6 271.6 261.2 281.1 271.8 271.8Time on organics, hrs. 4.5 25.5 30.5 49.5 54.5 73.5 78.5 96.5 98.0Duration of run, hrs. 2 2 2 2 2 2 2 1 1MEA SV, gmol/hr/kgcat 2.30 2.46 2.44 2.27 2.30 2.79 2.53 3.81 2.50DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 2.261 1.959 2.786 1.241 1.755 1.003 1.824 1.913 1.114MEA 11.820 15.971 11.138 22.601 18.976 22.986 18.586 22.750 22.718PIP 1.520 1.200 1.593 0.719 1.121 0.694 1.109 1.280 0.748DETA 45.153 45.959 41.322 50.852 47.133 52.385 47.720 47.166 49.655AEEA 0.011 0.410 0.153 0.999 0.569 0.740 0.269 0.266 0.465AEP 2.740 1.799 2.738 1.065 1.366 0.830 1.702 2.957 1.051HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 4.881 4.991 5.095 4.056 4.454 3.564 3.729 2.475 3.4041-TETA 14.240 13.568 13.497 10.800 11.889 10.434 10.309 7.038 9.572DAEP 0.016 0.382 1.089 0.163 0.254 0.130 0.690 1.198 0.295PEEDA 0.211 0.138 0.463 0.071 0.110 0.061 0.347 0.648 0.149DPE 0.149 0.000 0.194 0.034 0.000 0.066 0.208 0.175 0.058AE-TAEA 3.624 3.300 4.229 1.833 2.595 1.438 2.605 1.218 2.1631-TEPA 4.655 3.616 5.175 2.182 2.918 1.629 3.169 1.628 2.578AE-DAEP 0.025 0.000 0.194 0.047 0.000 0.000 0.138 0.331 0.250AE-PEEDA 0.000 0.000 0.091 0.000 0.000 0.000 0.071 0.087 0.071iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.044 0.000 0.126 0.000 0.000 0.000 0.000 0.000 0.000Others 1.451 0.368 1.796 0.219 0.402 0.081 0.814 2.102 0.506MEA Conversion, % 68.07 57.17 69.70 39.78 48.09 38.05 49.16 37.30 38.16DETA Conversion, % 27.50 25.91 33.19 19.47 23.36 16.10 22.42 22.74 19.67Acyclic(N4), % 98.07 97.27 91.41 98.23 97.82 98.20 91.85 82.48 96.27Acyclic(N5), % 99.18 100.00 95.81 98.83 100.00 100.00 96.51 87.21 93.66.SIGMA.(N5)/.SIGMA.(N4), 0.43 0.36 0.48 0.27 0.33 0.22 0.39 0.28 0.38weight ratioAcyclic(N4)/cyclic 4.12 5.27 3.06 7.24 5.73 7.86 3.46 1.52 5.64(< = N4), weight ratio__________________________________________________________________________ TABLE XLIV______________________________________Example No. 402 403 404 405______________________________________Catalyst Type ZZ ZZ ZZ ZZCatalyst weight, gm 91.33 91.33 91.33 91.33Pressure, psig 597 597 596 596Temperature, .degree.C. 270 284 258 272Time on organics, hrs. 20.5 25.5 44.5 49.5Duration of run, hrs. 2 2 2 2MEA SV, gmol/hr/kgcat 2.39 2.58 2.52 2.54DETA/MEA mole ratio 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 4.834 8.303 4.455 3.149MEA 5.992 2.084 9.647 10.990PIP 2.283 3.699 1.702 1.505DETA 24.621 19.876 30.406 33.928AEEA 1.216 0.261 1.338 2.268AEP 3.659 6.379 2.728 2.013HEP 0.000 0.000 0.000 0.000TAEA 1.286 0.698 1.273 1.595TETA 12.156 7.714 10.112 12.504DAEP 2.494 4.084 1.904 1.055PEEDA 1.717 3.007 0.160 0.699DPE 0.254 0.161 0.302 0.234AE-TAEA 2.896 1.747 2.455 2.9141-TEPA 10.186 6.866 8.071 8.571AE-DAEP 1.858 3.439 1.934 0.777AE-PEEDA 0.718 0.938 0.748 0.439iAE-PEEDA 0.000 0.000 0.000 0.000AE-DPE 0.091 0.255 0.169 0.039BPEA 0.403 0.377 0.505 0.558Others 14.617 19.011 15.441 9.062MEA Conversion, % 84.09 94.41 74.56 70.46DETA Conversion, % 61.16 68.33 52.34 45.81Acyclic(N4), % 75.07 53.70 82.79 87.64Acyclic(N5), % 80.99 63.23 75.82 86.37.SIGMA.(N5)/.SIGMA.(N4), 0.90 0.87 1.01 0.83weight ratioAcyclic(N4)/cyclic 1.29 0.49 1.68 2.56(<=N4), weight ratio______________________________________ TABLE XLV__________________________________________________________________________Example No. 406 407 408 409 410 411__________________________________________________________________________Catalyst Type AAA AAA AAA AAA AAA AAACatalyst weight, gm 107 107 107 107 107 107Pressure, psig 600 600 600 600 600 600Temperature, .degree.C. 277 277 277 313 314 314Time on organics, hrs. 3.0 18.7 20.7 26.0 42.7 44.7Duration of run, hrs. 1 16 2 2 16 2MEA SV, gmol/hr/kgcat 2.26 2.24 2.27 2.10 2.08 2.11NH.sub.3 feedrate, gm/hr 59 59 56 59 59 59Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84EDA -- -- -- -- -- --Liquid product composition,wt. %EDA 1.69 1.53 1.11 5.98 5.97 6.14MeEDA 0.00 0.00 0.00 0.00 0.00 0.00MEA 10.19 7.13 8.50 1.44 1.75 1.70EtEDA 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.17 1.29 1.08 4.26 4.38 4.67DETA 63.75 67.41 69.62 56.36 56.78 56.34AEEA 1.16 0.51 0.78 0.78 0.78 0.78AEP 1.48 1.64 1.20 5.91 5.77 5.86HEP 0.00 0.00 0.00 0.07 0.09 0.07TETA's 13.90 13.58 11.94 14.21 13.22 13.20TEPA's 4.76 4.63 3.90 5.29 3.76 3.77ROH Conversion % 56.11 69.33 63.43 93.70 92.18 92.41Acyclic (N4)/cyclic 16.2 13.3 20.9 2.2 2.0 2.0(<=N4),weight ratioAcyclic (N5)/cyclic 11.6 10.9 16.1 1.2 2.2 2.4(<=N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- --weight ratio__________________________________________________________________________ TABLE XLVI__________________________________________________________________________Example No. 412 413 414 415 416 417 418 419 420 421__________________________________________________________________________Catalyst Type BBB BBB BBB BBB BBB BBB BBB BBB BBB BBBCatalyst weight, gm 123.7 123.7 123.7 123.7 123.7 123.7 123.7 123.7 123.7 123.7Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 266 272 271 270 298 300 300 299 303 302Time on organics, hrs. 10.5 15.5 32.5 34.5 40.5 55.5 57.5 63.0 81.5 129.5Duration of run, hrs. 10 2 16 2 2 15 15 2 2 2MEA SV, gmol/hr/kgcat 1.94 1.72 1.97 1.97 2.02 1.94 0.26 1.88 1.97 1.89NH.sub.3 feedrate, gm/hr 38.4 56.0 57.0 63.0 59.0 60.2 57.5 57.0 58.5 46.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 77.16 77.16 77.16 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 22.84 22.84 22.84 22.84Liquid product composition,wt. %EDA 0.97 1.21 1.01 0.94 3.46 2.86 2.63 2.72 2.46 2.44MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 13.53 11.37 11.57 12.57 4.80 6.56 7.31 7.23 8.08 7.91EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.63 0.72 0.58 0.58 2.14 1.81 1.37 1.78 1.56 1.61DETA 74.34 73.54 74.39 75.32 69.81 71.72 73.83 72.52 73.94 73.16AEEA 0.91 0.72 0.86 0.86 0.34 0.32 0.28 0.39 0.52 0.47AEP 0.59 0.81 0.71 0.63 2.42 1.93 1.74 1.74 1.55 1.59HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 7.74 9.46 8.96 7.68 12.10 10.11 8.91 9.43 8.16 7.76TEPA's 1.07 1.81 1.48 1.17 2.94 2.34 1.88 2.12 1.79 1.93ROH Conversion % 41.89 51.36 50.41 46.08 79.45 71.67 68.42 68.80 65.08 65.40Acyclic (N4)/cyclic 100.0 73.1 38.5 74.8 8.1 8.9 10.6 9.9 10.1 9.4(<=N4),weight ratioAcyclic (N5)/cyclic -- -- -- -- -- 5.1 5.5 8.0 8.2 5.2(<=N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- -- -- -- --weight ratio__________________________________________________________________________ TABLE XLVII__________________________________________________________________________Example No. 422 423 424 425 426 427 428 429 430__________________________________________________________________________Catalyst Type CCC CCC CCC CCC CCC CCC CCC CCC CCCCatalyst weight, gm 105.7 105.7 105.7 105.7 105.7 105.7 105.7 105.7 105.7Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 268 281 275 302 304 304 303 302 302Time on organics, hrs. 4.7 19.7 21.7 26.7 43.7 45.7 51.2 66.7 68.7Duration of run, hrs. 2 15 2 2 17 2 2 14 2MEA SV, gmol/hr/kgcat 2.09 2.13 2.20 2.06 2.14 2.09 1.90 2.02 1.91NH.sub.3 feedrate, gm/hr 49.5 42.8 54.5 47.5 51.0 41.5 54.5 58.8 53.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- --AEEA -- -- -- -- -- -- 33.54 33.54 33.54Liquid product composition,wt. %EDA 2.25 1.42 1.17 4.33 4.33 4.06 2.41 2.32 2.62MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 8.59 11.37 12.86 5.60 6.05 5.73 0.00 0.00 0.00EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.36 0.68 0.49 1.69 1.70 1.69 9.19 9.15 9.13DETA 70.30 74.76 76.82 71.05 71.22 71.97 68.27 68.90 70.40AEEA 0.80 0.97 0.85 0.31 0.40 0.00 1.15 1.10 0.53AEP 1.27 0.69 0.53 1.68 1.67 1.61 1.32 1.33 1.51HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 10.97 8.09 5.52 9.47 8.65 7.79 6.49 6.41 6.60TEPA's 2.93 1.60 0.93 2.07 1.87 1.65 7.25 7.27 5.87ROH Conversion % 63.07 51.25 44.36 75.40 73.30 74.34 96.50 96.70 98.40Acyclic (N4)/cyclic (<=N4), 9.09 72.20 100.00 8.90 8.70 7.90 0.30 0.30 0.30weight ratioAcyclic (N5)/cyclic (<=N5), 28.90 100.00 100.00 15.10 10.60 9.60 13.10 13.60 9.50weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- 1.10 1.10 0.90weight ratio__________________________________________________________________________ TABLE XLVIII__________________________________________________________________________Example No. 431 432 433 434 435 436 437 438 439 440 441__________________________________________________________________________Catalyst Type DDD DDD DDD DDD DDD DDD DDD DDD DDD DDD DDDCatalyst weight, gm 121 121 121 121 121 121 121 121 121 121 121Pressure, psig 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 279 270 270 269 269 275 270 272 274 272 258Time on organics, hrs. 4.5 18.5 35.5 37.5 43.5 54.5 62.5 66.0 82.0 84.0 90.7Duration of run, hrs. 2 2 16 2 2 2 2 2 15 2 2MEA SV, gmol/hr/kgcat 2.00 1.98 1.98 2.03 2.03 2.01 1.97 1.68 1.70 1.69 1.33NH.sub.3 feedrate, gm/hr 67.2 72.0 48.1 46.0 44.5 41.1 47.5 48.0 45.1 49.0 86.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- --AEEA -- -- -- -- -- -- -- 33.54 33.54 33.54 33.54Liquid product composition,wt. %EDA 5.79 1.61 1.48 1.43 1.18 1.34 1.37 1.05 1.04 1.08 0.48MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 2.74 6.67 7.72 7.67 7.39 6.27 6.43 0.31 0.11 0.12 0.15EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 4.65 1.25 1.17 1.16 0.99 1.15 1.21 10.37 10.57 10.55 7.06DETA 61.98 71.25 73.17 73.07 69.92 68.69 68.71 58.64 58.83 59.53 67.06AEEA 0.00 0.16 0.22 0.24 0.45 0.42 0.37 5.96 6.64 6.72 15.36AEP 5.74 1.29 0.94 0.93 0.97 1.13 1.18 1.35 1.26 1.20 0.59HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 13.80 14.03 12.81 12.89 14.92 16.23 15.76 8.51 8.04 7.49 3.04TEPA's 3.53 2.45 1.96 2.10 3.18 3.62 3.71 10.70 11.09 10.99 6.08ROH Conversion % 88.45 71.55 67.20 67.43 68.55 73.37 72.65 82.40 80.50 80.30 55.20Acyclic (N4)/cyclic 3.69 8.70 46.60 49.50 44.30 38.60 34.50 0.25 0.17 0.18 0.12(<=N4),weight ratioAcyclic (N5)/cyclic 2.70 100.00 100.00 100.00 100.00 100.00 100.00 34.00 38.70 44.00 100.00(<=N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- -- 1.30 1.40 1.50 2.00weight ratio__________________________________________________________________________ TABLE XLIX__________________________________________________________________________Example No. 442 443 444 445 446 447 448 449 450__________________________________________________________________________Catalyst Type EEE EEE EEE EEE EEE EEE EEE EEE EEECatalyst weight, gm 118.7 118.7 118.7 118.7 118.7 118.7 118.7 118.7 118.7Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 267 268 267 289 284 301 291 298 260Time on organics, hrs. 8.5 19.0 21.0 25.0 28.0 32.0 35.0 39.0 43.0Duration of run, hrs. 2 10 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.01 2.04 2.11 2.00 1.94 1.58 1.65 1.57 1.68NH.sub.3 feedrate, gm/hr 45.2 47.4 47.5 54.0 51.0 46.0 43.0 30.0 46.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 -- -- -- --AEEA -- -- -- -- -- 33.54 33.54 33.54 33.54Liquid product composition,wt. %EDA 1.12 0.95 0.83 2.89 2.86 2.46 1.69 2.41 0.31MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 11.83 12.17 12.64 6.50 6.93 0.45 0.52 0.34 0.45EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.94 0.63 0.49 1.87 1.84 11.04 10.33 11.22 3.39DETA 76.42 79.20 76.28 68.84 71.08 57.52 61.86 67.91 75.51AEEA 0.36 0.28 0.54 0.17 0.17 0.90 2.98 0.97 17.00AEP 0.63 0.39 0.41 1.88 1.71 2.52 1.37 1.71 0.27HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 7.47 5.50 7.52 11.98 10.95 11.25 8.74 6.93 1.01TEPA's 1.02 0.54 0.97 3.35 2.49 8.61 9.41 5.34 2.07ROH Conversion % 49.35 47.67 45.70 71.94 70.17 97.30 91.10 97.10 49.80Acyclic (N4)/cyclic (<=N4), 100.00 100.00 100.00 10.60 13.70 0.30 0.20 0.20 0.20weight ratioAcyclic (N5)/cyclic (<=N5), 100.00 100.00 100.00 5.78 8.20 4.40 22.80 100.00 100.00weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- 0.80 1.10 0.80 2.00weight ratio__________________________________________________________________________ TABLE L__________________________________________________________________________Example No. 451 452 453 454 455 456 457 458 459 460 461 462__________________________________________________________________________Catalyst Type FFF FFF FFF FFF FFF FFF FFF FFF FFF FFF FFF FFFCatalyst weight, gm 123.6 123.6 123.6 123.6 123.6 123.6 123.6 123.6 123.6 123.6 123.6 123.6Pressure, psig 600 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 279 277 276 260 263 264 261 262 263 274 277 276Time on organics, hrs. 4.7 22.0 24.0 29.0 45.0 47.0 52.5 69.0 71.0 76.5 93.5 95.0Duration of run, hrs. 2 17 2 2 16 2 2 16 2 2 16 1MEA SV, gmol/hr/kgcat 1.92 1.96 1.93 1.96 1.97 1.99 1.73 1.70 1.74 1.65 1.66 1.73NH.sub.3 feedrate, gm/hr 53.0 48.4 55.0 52.0 49.3 49.5 47.0 47.3 46.5 49.0 49.9 54.6Liquid feed composition, wt. %PIP -- -- -- -- -- -- -- -- -- -- -- --DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- -- -- --AEEA -- -- -- -- -- -- 33.54 33.54 33.54 33.54 33.54 33.54Liquid product composition,wt. %EDA 3.96 3.55 3.17 1.21 1.14 1.30 0.77 0.77 0.67 1.58 1.88 1.60MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 2.91 2.56 2.50 7.40 7.44 7.38 0.18 0.00 0.00 0.00 0.00 0.00EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 3.12 2.46 2.21 1.06 1.05 1.15 8.23 8.70 8.57 10.86 10.76 10.60DETA 61.14 63.82 60.32 71.24 72.08 68.84 65.43 66.94 69.33 65.27 62.85 65.63AEEA 0.00 0.00 0.00 0.00 0.00 0.29 3.28 3.21 3.00 0.42 0.35 0.00AEP 4.38 3.42 3.06 1.06 0.99 1.07 0.00 0.91 0.88 1.66 1.77 1.70HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 17.74 18.49 18.86 15.11 14.78 15.71 6.46 5.73 5.20 7.71 8.60 7.54TEPA's 4.05 4.67 5.70 2.73 2.32 3.70 14.12 13.23 12.12 11.71 11.80 11.62ROH Conversion % 87.61 89.27 89.19 68.76 68.57 68.77 90.40 90.70 91.30 99.80 99.00 100.00Acyclic (N4)/cyclic 7.20 11.20 11.20 80.70 100.00 46.90 0.30 0.20 0.10 0.20 0.30 0.20(<=N4),weight ratioAcyclic (N5)/cyclic 100.00 18.00 17.30 100.00 100.00 100.00 85.10 94.20 100.00 35.10 26.40 30.80(<=N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- 2.20 2.30 2.30 1.50 1.40 1.50weight ratio__________________________________________________________________________ TABLE LI__________________________________________________________________________Example No. 463 464 465 466 467 468 469 470 471 472 473__________________________________________________________________________Catalyst Type GGG GGG GGG GGG GGG GGG GGG GGG GGG GGG GGGCatalyst weight, gm 116.6 116.6 116.6 116.6 116.6 116.6 116.6 116.6 116.6 116.6 116.6Pressure, psig 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 277 284 272 272 277 266 267 266 282 282 281Time on organics, hrs. 4.5 20.0 22.0 27.5 44.5 52.5 69.5 71.5 76.5 94.5 96.5Duration of run, hrs. 2 15 2 2 15 2 15 2 2 16 2MEA SV, gmol/hr/kgcat 2.02 2.05 2.13 2.03 2.02 1.76 1.80 1.79 1.72 2.04 2.06NH.sub.3 feedrate, gm/hr 60.5 54.7 57.0 54.5 43.5 68.5 53.1 45.5 66.0 60.6 56.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46 77.16 77.16MEA 22.84 22.84 22.84 22.84 22.84 -- -- -- -- 22.84 22.84AEEA -- -- -- -- -- 33.54 33.54 33.54 33.54 -- --Liquid product composition,wt. %EDA 2.05 2.24 1.23 0.78 0.73 0.38 0.32 0.39 1.58 2.16 2.07MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 5.90 3.75 6.68 8.22 8.34 0.26 0.00 0.19 0.00 4.77 4.91EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 2.21 2.48 1.56 1.14 1.10 6.66 6.97 6.77 9.99 2.49 2.37DETA 74.52 75.33 75.56 79.77 81.46 72.66 76.76 73.28 65.22 73.27 75.76AEEA 0.00 0.00 0.00 0.00 0.00 6.14 5.08 6.32 0.00 0.00 0.00AEP 2.09 2.54 1.56 1.05 1.06 0.64 0.61 0.59 1.90 2.48 2.38HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 11.24 11.94 11.23 8.09 6.69 5.09 4.22 4.81 9.47 10.79 10.14TEPA's 1.89 1.67 2.03 0.92 0.62 7.62 5.92 7.17 9.26 3.34 2.36ROH Conversion % 75.18 84.30 71.82 65.14 64.60 82.00 85.20 81.60 100.00 79.85 79.41Acyclic (N4)/cyclic 15.00 12.40 17.20 100.00 100.00 0.11 0.00 0.10 0.20 7.30 8.40(<=N4),weight ratioAcyclic (N5)/cyclic 100.00 100.00 100.00 100.00 100.00 62.00 100.00 70.20 7.21 2.50 7.40(<=N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- 1.30 1.40 1.50 1.00 -- --weight ratio__________________________________________________________________________ TABLE LII__________________________________________________________________________Example No. 474 475 476 477 478 479 480 481 482 483 484 485__________________________________________________________________________Catalyst Type HHH HHH HHH HHH HHH HHH HHH HHH HHH HHH HHH HHHCatalyst weight, gm 118.4 118.4 118.4 118.4 118.4 118.4 118.4 118.4 118.4 118.4 118.4 118.4Pressure, psig 600 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 267 276 276 295 296 296 298 270 271 266 267 268Time on organics, hrs. 8.0 21.0 23.0 29.0 45.0 47.0 53.0 69.0 71.0 77.0 93.0 95.0Duration of run, hrs. 2 13 2 2 16 2 2 16 2 2 16 2MEA SV, gmol/hr/kgcat 1.96 2.00 2.06 2.01 1.99 2.01 1.68 1.72 1.71 1.98 2.00 2.01NH.sub.3 feedrate, gm/hr 65.5 57.4 53.5 59.0 46.6 36.0 64.0 49.5 51.5 51.0 49.3 49.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 77.16 77.16 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- 22.84 22.84 22.84AEEA -- -- -- -- -- -- 33.54 33.54 33.54 -- -- --Liquid product composition,wt. %EDA 0.81 0.99 1.00 3.45 3.60 3.29 2.33 0.00 0.37 0.27 0.48 0.51MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 8.16 6.51 7.10 1.45 2.25 2.43 0.00 0.00 0.00 10.27 10.50 10.46EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.03 1.41 1.44 3.95 4.17 4.13 12.33 6.69 6.85 0.80 0.75 0.77DETA 77.87 78.14 74.65 76.12 72.14 74.46 69.31 82.62 77.14 84.56 84.28 84.63AEEA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 4.62 6.65 0.00 0.00 0.00AEP 1.04 1.43 1.38 4.56 4.28 4.25 3.27 0.72 0.61 0.74 0.72 0.71HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 9.61 9.93 11.80 9.39 10.88 9.44 8.73 2.75 3.71 2.87 2.89 2.61TEPA's 1.49 1.59 2.63 1.08 2.34 1.86 3.29 2.60 4.50 0.49 0.39 0.00ROH Conversion % 65.45 72.55 70.09 93.97 90.62 89.88 100.00 86.50 80.60 56.14 55.12 55.13Acyclic (N4)/cyclic 53.30 37.90 23.80 4.10 4.40 4.10 0.20 0.00 0.00 100.00 100.00 100.00(<=N4),weight ratioAcyclic (N5)/cyclic 100.00 100.00 100.00 1.90 2.10 2.00 5.40 100.00 100.00 100.00 100.00 100.00(<=N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- 0.40 1.00 1.20 -- -- --weight ratio__________________________________________________________________________ TABLE LIII__________________________________________________________________________Example No. 486 487 488 489 490 491 492 493 494 495 496 497__________________________________________________________________________Catalyst Type III III III III III III III III III III III IIICatalyst weight, gm 118.2 118.2 118.2 118.2 118.2 118.2 118.2 118.2 118.2 118.2 118.2 118.2Pressure, psig 600 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 272 271 273 299 301 300 302 302 273 270 272 272Time on organics, hrs. 4.0 17.0 19.0 25.0 42.5 44.5 50.5 59.0 62.0 72.7 82.0 84.0Duration of run, hrs. 2 13 2 2 17 2 2 8 2 2 9 2MEA SV, gmol/hr/kgcat 1.98 1.99 1.98 1.98 1.96 2.02 1.69 1.68 1.67 1.99 2.08 2.01NH.sub.3 feedrate, gm/hr 69.0 70.7 59.0 55.5 49.9 65.5 48.0 47.8 57.5 45.0 44.0 41.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 77.16 77.16 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- 22.84 22.84 22.84AEEA -- -- -- -- -- -- 33.54 33.54 33.54 -- -- --Liquid product composition,wt. %EDA 0.74 0.72 0.58 2.88 2.15 2.01 1.65 1.44 0.00 0.21 0.22 0.00MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 7.89 7.63 8.40 1.99 3.10 3.86 0.00 0.00 0.19 11.14 11.57 11.60EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.28 1.11 0.93 3.30 3.03 2.79 12.61 12.29 7.23 0.82 0.77 0.77DETA 79.77 73.47 73.54 76.57 79.28 79.79 71.48 70.87 78.08 84.83 84.22 85.08AEEA 0.23 0.50 0.70 0.00 0.00 0.00 0.00 0.00 7.36 0.00 0.00 0.00AEP 0.78 1.01 0.88 2.61 2.05 1.80 1.93 1.71 0.19 0.29 0.25 0.21HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 7.63 11.54 11.52 8.85 6.88 7.59 5.61 6.10 2.44 1.85 2.29 1.69TEPA's 1.03 2.90 2.71 1.72 1.36 1.22 3.11 4.22 3.46 0.37 0.26 0.19ROH Conversion % 66.33 67.44 64.22 91.52 86.72 83.64 100.00 100.00 78.20 52.05 50.20 50.04Acyclic (N4)/cyclic 22.50 26.60 14.70 14.70 5.70 2.30 0.20 0.20 0.10 100.00 100.00 100.00(<=N4),weight ratioAcyclic (N5)/cyclic 100.00 33.50 100.00 100.00 4.50 1.90 1.90 2.90 14.00 100.00 100.00 100.00(<=N5),weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- 0.60 0.70 1.40 -- -- --weight ratio__________________________________________________________________________ TABLE LIV__________________________________________________________________________Example No. 498 499 500 501 502 503 504 505 506 507 508 509__________________________________________________________________________Catalyst Type JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJ JJJCatalyst weight, gm 118.3 118.3 118.3 118.3 118.3 118.3 118.3 118.3 118.3 118.3 118.3 118.3Pressure, psig 600 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 272 271 272 300 302 302 301 274 275 275 276 276Time on organics, hrs. 4.0 17.5 19.5 25.0 41.0 43.0 48.0 65.0 67.0 72.0 85.0 87.0Duration of run, hrs. 2 13 2 2 16 2 2 16 2 2 15 2MEA SV, gmol/hr/kgcat 1.94 1.98 1.91 1.92 1.90 1.89 3.34 3.38 3.37 2.03 1.96 1.97NH.sub.3 feedrate, gm/hr 45.0 45.9 48.5 46.0 58.4 55.0 55.5 53.0 50.5 52.5 51.0 49.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 77.16 77.16 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- 22.84 22.84 22.84AEEA -- -- -- -- -- -- 33.54 33.54 33.54 -- -- --Liquid product composition,wt. %EDA 0.48 0.50 0.45 2.70 2.96 2.83 2.44 0.36 0.40 0.51 0.50 0.59MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 9.18 9.77 9.84 2.44 2.92 2.93 0.00 0.30 0.29 10.04 10.18 10.47EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.10 1.10 1.07 3.88 3.86 3.85 11.79 7.03 7.40 1.33 1.23 1.21DETA 77.40 77.67 78.15 68.03 67.03 66.76 61.93 69.26 69.84 76.33 78.33 77.59AEEA 0.64 0.63 0.64 0.00 0.07 0.08 0.00 7.10 6.01 0.69 0.48 0.51AEP 0.85 0.84 0.82 3.78 3.70 3.69 2.60 0.76 0.77 0.99 0.91 0.90HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.10 0.00 0.00 0.00TETA's 7.04 6.84 6.47 11.12 10.94 11.03 9.81 5.55 5.66 7.02 6.22 6.15TEPA's 60.31 57.98 57.64 89.42 87.25 87.18 100.00 78.90 82.20 56.92 56.32 54.87ROH Conversion %Acyclic (N4)/cyclic (<=N4), 22.40 22.90 21.20 4.00 4.10 4.00 0.30 0.10 0.10 13.50 21.40 20.40weight ratioAcyclic (N5)/cyclic (<=N5), 100.00 100.00 100.00 2.30 2.30 2.20 2.10 19.10 20.10 9.40 100.00 100.00weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- 0.70 1.30 1.30 -- -- --weight ratio__________________________________________________________________________ TABLE LV__________________________________________________________________________Example No. 510 511 512 513 514 515 516 517 518__________________________________________________________________________Catalys Type KKK KKK KKK KKK KKK KKK KKK KKK KKKCatalyst weight, gm 116.2 116.2 116.2 116.2 116.2 11.62 116.2 116.2 116.2Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 281 289 255 253 308 300 297 272 268Time on organics, hrs. 8.5 17.5 65.0 67.0 73.0 88.5 90.5 96.7 114.5Duration of run, hrs. 2 9 10 2 2 15 2 2 2MEA SV, gmol/hr/kgcat 1.95 1.92 1.68 1.73 1.62 1.74 1.71 1.68 1.72NH.sub.3 feedrate, gm/hr 47.2 45.6 46.8 45.0 44.0 43.3 47.0 43.0 46.5Liquid feed composition, wt. %DETA 77.16 77.16 66.46 66.46 77.16 77.16 77.16 66.46 66.46MEA 22.84 22.84 -- -- 22.84 22.84 22.84 -- --AEEA -- -- 33.54 33.54 -- -- -- 33.54 33.54Liquid product composition,wt. %EDA 2.23 1.99 0.37 0.35 9.13 5.71 5.98 1.22 1.22MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 9.36 10.47 0.39 0.36 4.75 8.86 8.41 0.45 0.45EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.65 0.44 1.26 1.29 1.40 0.90 0.92 3.43 3.43DETA 75.37 77.92 74.89 76.09 63.34 69.29 67.65 74.85 84.85AEEA 0.45 0.44 20.42 19.29 0.21 0.22 0.32 11.31 11.31AEP 0.71 0.52 0.00 0.00 1.52 1.00 1.05 0.45 0.45HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 6.89 4.55 0.22 0.21 6.49 5.50 6.02 2.05 2.05TEPA's 1.28 0.49 0.96 0.89 0.99 0.57 0.79 3.05 3.05ROH Conversion % 58.81 53.66 38.40 41.80 76.90 58.71 60.45 65.60 65.60Acyclic (N4)/cyclic (<=N4), 20.00 41.60 0.00 0.00 4.70 7.80 8.10 0.30 0.20weight ratioAcyclic (N5)/cyclic (<=N5), 100.00 100.00 100.00 100.00 2.50 100.00 100.00 100.00 100.00weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- 4.40 4.20 -- -- -- 1.50 1.50weight ratio__________________________________________________________________________ TABLE LVI__________________________________________________________________________Example No. 519 520 521 522 523 524 525 526 527 528 529__________________________________________________________________________Catalyst Type LLL LLL LLL LLL LLL LLL LLL LLL LLL LLL LLLCatalyst weight, gm 131.5 131.5 131.5 131.5 131.5 131.5 131.5 131.5 131.5 131.5 131.5Pressure, psig 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 273 277 277 305 300 300 300 303 301 278 276Time on organics, hrs. 5.0 21.7 23.7 29.0 45.0 47.0 53.0 70.0 72.0 76.0 80.0Duration of run, hrs. 2 15 2 1 16 2 2 16 2 2 2MEA SV, gmol/hr/kgcat 1.86 1.78 1.86 1.39 1.71 1.52 1.54 1.50 1.57 1.54 1.75NH.sub.3 feedrate, gm/hr 53.0 48.6 45.0 49.0 45.0 50.5 54.5 48.0 53.0 50.0 47.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- -- 22.84AEEA -- -- -- -- -- -- 33.54 33.54 33.54 33.54 --Liquid product composition,wt. %EDA 0.39 0.41 0.44 4.14 1.93 1.70 1.17 1.32 1.32 0.35 0.48MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 12.44 11.40 11.03 1.91 5.20 5.43 0.00 0.00 0.00 0.00 10.23EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.04 1.00 0.97 4.80 2.81 2.65 9.73 9.94 10.69 7.37 1.48DETA 77.93 79.28 78.81 69.34 71.17 73.05 72.15 68.24 72.00 76.09 78.06AEEA 0.76 0.54 0.58 0.00 0.00 0.00 0.00 0.00 0.00 3.28 0.50AEP 0.86 0.88 0.85 5.19 2.82 2.57 2.10 2.26 2.37 0.74 1.14HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 5.36 5.49 5.87 10.35 10.83 10.10 7.69 8.66 7.72 5.03 5.65TEPA's 0.88 0.66 0.82 1.52 2.87 2.53 5.44 6.42 4.62 6.46 1.98ROH Conversion % 46.63 51.16 52.65 91.86 77.72 76.79 100.00 100.00 100.00 90.40 56.31Acyclic (N4)/cyclic (<=N4), 20.20 25.50 22.70 3.20 6.60 7.30 0.20 0.20 0.20 0.10 5.90weight ratioAcyclic (N5)/cyclic (<=N5), 100.00 100.00 100.00 1.70 6.80 8.20 11.40 7.50 8.30 52.40 18.50weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- 0.70 0.70 0.60 1.30 --weight ratio__________________________________________________________________________ TABLE LVII__________________________________________________________________________Example No. 530 531 532 533 534 535 536 537__________________________________________________________________________Catalyst Type MMM MMM MMM MMM MMM MMM MMM MMMCatalyst weight, gm 120.5 120.5 120.5 120.5 120.5 120.5 120.5 120.5Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 268 273 300 301 302 301 302 301Time on organics, hrs. 2 16 2 15 2 2 13 3Duration of run, hrs. 2 16 2 15 2 2 13 3MEA SV, gmol/hr/kgcat 1.93 2.17 1.86 1.93 1.92 1.65 1.68 1.72NH.sub.3 feedrate, gm/hr 77.0 57.7 51.5 53.0 51.5 51.5 46.4 48.7Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 -- -- --AEEA -- -- -- -- -- 33.54 33.54 33.54Liquid product composition,wt. %EDA 0.46 0.36 1.97 1.71 1.80 1.01 1.10 1.04MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 8.19 8.94 3.30 4.02 4.32 0.00 0.00 0.00EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.71 0.58 1.70 1.53 1.45 8.12 8.21 8.14DETA 81.58 82.37 80.61 82.51 85.17 78.02 81.61 78.10AEEA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00AEP 0.77 0.66 1.96 1.66 1.50 1.16 1.11 1.10HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 7.44 0.49 0.59 0.26 0.00 5.01 3.31 4.78ROH Conversion % 65.18 61.92 86.01 82.82 81.58 100.00 100.00 100.00Acyclic (N4)/cyclic (<=N4), 100.00 100.00 12.60 15.50 100.00 0.10 0.00 0.10weight ratioAcyclic (N5)/cyclic (<=N5), 100.00 100.00 100.00 100.00 -- 25.20 100.00 20.90weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- 0.90 0.80 0.86weight ratio__________________________________________________________________________ TABLE LVIII__________________________________________________________________________Example No. 538 539 540 541 542 543 544 545 546 547 548 549__________________________________________________________________________Catalyst Type NNN NNN NNN NNN NNN NNN NNN NNN NNN NNN NNN NNNCatalyst weight, gm 119.6 119.6 119.6 119.6 119.6 119.6 119.6 119.6 119.6 119.6 119.6 119.6Pressure, psig 600 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 272 274 273 299 301 300 273 300 298 299 272 275Time on organics, hrs. 4.0 20.0 22.0 27.0 44.0 46.0 49.0 66.0 68.0 70.0 74.0 86.0Duration of run, hrs. 2 16 2 2 16 2 2 16 2 2 3 3MEA SV, gmol/hr/kgcat 2.01 2.16 2.02 1.93 1.94 2.01 1.99 1.71 1.73 1.65 1.71 1.15NH.sub.3 feedrate, gm/hr 47.0 46.5 53.5 44.0 60.8 50.5 59.0 45.2 56.5 56.5 64.0 59.4Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- -- 22.84AEEA -- -- -- -- -- -- -- 33.54 33.54 33.54 33.54 --Liquid product composition,wt. %EDA 0.00 0.00 0.00 2.00 1.82 1.80 0.00 1.63 1.66 1.44 0.00 0.00MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 6.84 7.07 7.00 2.75 2.63 2.57 8.52 0.00 0.00 0.00 0.00 9.35EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.21 0.85 0.69 1.96 2.02 2.11 0.58 9.79 10.05 10.16 6.52 0.72DETA 83.64 87.98 88.48 83.40 82.22 81.77 87.13 75.36 72.92 72.45 80.94 83.87AEEA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 3.47 0.00AEP 1.32 0.82 0.72 2.56 2.51 2.55 0.69 1.93 1.98 1.88 0.57 0.69HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 6.59 3.27 3.11 6.33 7.56 7.85 3.08 7.07 7.66 7.60 3.57 4.14TEPA's 0.41 0.00 0.00 0.00 0.56 0.71 0.00 3.95 4.60 5.08 4.74 0.51ROH Conversion % 71.08 69.97 70.25 88.33 88.90 89.16 63.70 100.00 100.00 100.00 89.80 59.87Acyclic (N4)/cyclic (<=N4), 100.00 100.00 100.00 14.10 7.74 7.62 100.00 0.00 0.18 0.17 0.00 0.00weight ratioAcyclic (N5)/cyclic (<=N5), 100.00 0.00 00.00 0.00 0.00 0.00 0.00 11.00 9.80 11.09 100.00 100.00weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- -- 0.60 0.60 0.70 1.30 --weight ratio__________________________________________________________________________ TABLE LIX__________________________________________________________________________Example No. 550 551 552 553 554 555 556 557 558 559 560__________________________________________________________________________Catalyst Type OOO OOO OOO OOO OOO OOO OOO OOO OOO OOO OOOCatalyst weight, gm 119.0 119.0 119.0 119.0 119.0 119.0 119.0 119.0 119.0 119.0 119.0Pressure, psig 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 272 271 272 293 293 293 293 290 292 270 270Time on organics, hrs. 6.0 22.0 24.0 29.0 46.0 48.0 53.0 69.5 71.5 76.5 93.0Duration of run, hrs. 2 16 2 2 16 2 2 15 2 2 16MEA SV, gmol/hr/kgcat 1.91 1.91 1.92 1.87 1.87 1.92 1.56 1.58 1.50 1.66 1.69NH.sub.3 feedrate, gm/hr 50.0 45.0 51.0 61.0 52.0 63.5 65.0 47.8 50.5 45.0 68.6Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- -- 22.84AEEA -- -- -- -- -- -- 33.54 33.54 33.54 33.54 --Liquid product composition,wt. %EDA 0.63 0.69 0.72 2.72 3.02 2.99 2.68 3.21 3.67 0.60 0.78MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 15.06 14.67 14.70 7.20 6.66 6.83 0.37 0.24 0.24 0.45 14.81EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.51 0.58 0.59 1.88 2.08 2.11 6.78 7.42 7.73 4.42 1.25DETA 76.49 75.73 75.87 69.26 69.03 67.89 61.99 60.81 59.19 65.18 71.26AEEA 0.75 0.79 0.78 0.17 0.00 0.21 0.24 0.16 0.00 10.62 1.89AEP 0.53 0.59 0.60 2.19 2.37 2.41 2.12 2.49 2.81 0.51 0.71HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 4.07 4.50 4.48 9.01 9.15 8.99 8.99 9.15 9.40 4.16 5.02TEPA's 1.66 1.99 1.94 5.81 5.97 6.10 12.71 11.71 12.96 12.13 3.62ROH Conversion % 35.01 36.68 36.63 69.16 71.53 70.57 99.30 99.50 100.00 68.50 36.13Acyclic (N4)/cyclic (<=N4), 100.00 40.70 32.30 4.40 4.00 4.20 0.67 0.30 0.30 0.10 5.00weight ratioAcyclic (N5)/cyclic (<=N5), 100.00 100.00 100.00 2.90 2.40 2.50 2.50 1.90 1.10 21.70 100.00weight ratio.SIGMA.(N4)/.SIGMA.(N5), -- -- -- -- -- -- 1.40 1.30 1.40 2.90 --weight ratio__________________________________________________________________________ TABLE LX__________________________________________________________________________Example No. 561 562 563 564 565 566 567 568__________________________________________________________________________Catalyst Type PPP PPP PPP PPP PPP PPP PPP PPPCatalyst weight, gm 113.7 113.7 113.7 113.7 113.7 113.7 113.7 113.7Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 274 274 299 29 303 294 297 293Time on organics, hrs. 18.0 20.0 25.0 41.7 43.4 49.0 65.5 67.4Duration of run, hrs. 16 2 2 16 2 2 16 2MEA SV, gmol/hr/kgcat 2.15 2.19 2.20 2.10 2.19 2.11 2.14 2.06NH.sub.3 feedrate, gm/hr 55.6 43.0 52.0 55.0 38.0 84.0 52.0 54.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 73.30 73.30 73.30MEA 22.84 22.84 22.84 22.84 22.84 21.70 21.70 21.70EDA -- -- -- -- -- -- -- --H.sub.2 O -- -- -- -- -- 5.00 5.00 5.00Liquid product composition,wt. %EDA 0.85 0.69 2.50 1.60 1.42 1.28 1.24 1.16MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 11.05 11.08 3.45 6.52 7.59 10.77 11.01 11.46EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.46 0.37 1.22 0.77 0.70 0.53 0.50 0.46DETA 71.01 72.32 65.63 70.92 72.86 73.67 73.65 74.18AEEA 1.08 1.21 0.25 0.59 0.78 0.94 1.06 1.07AEP 0.69 0.56 2.04 1.27 1.14 0.99 0.93 0.88HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 11.09 10.78 15.98 11.82 10.35 8.14 8.13 7.51TEPA's 2.74 2.32 5.41 3.35 2.60 1.92 1.81 1.57ROH Conversion % 52.50 52.51 85.08 71.61 67.04 53.28 52.25 50.21Acyclic (N4)/cyclic (<=N4), 30.30 100.00 9.50 13.90 13.00 17.80 19.80 21.10weight ratioAcyclic (N5)/cyclic (<=N5), 31.60 100.00 6.70 10.00 13.40 12.90 31.20 14.90weight ratio.SIGMA.(N5)/.SIGMA.(N4), 14.70 10.50 5.30 7.10 7.60 8.00 8.70 9.00weight ratio__________________________________________________________________________ Example No. 569 570 571 572 573 574__________________________________________________________________________ Cata;yst Type PPP PPP PPP PPP PPP PPP Catalyst weight, gm 113.7 113.7 113.7 113.7 113.7 113.7 Pressure, psig 600 600 600 600 600 600 Temperature, .degree.C. 299 298 297 300 298 298 Time on organics, hrs. 72.4 89.5 91.5 112.2 114.2 149.2 Duration of run, hrs. 2 16 2 15 2 2 MEA SV, gmol/hr/kgcat 2.09 2.07 2.08 3.06 3.17 11.03 NH.sub.3 feedrate, gm/hr 47.0 67.0 49.5 57.0 54.0 47.0 Liquid feed composition, wt. % DETA 77.16 77.16 77.16 -- -- -- MEA 22.84 22.84 22.84 33.70 33.70 100.00 EDA -- -- -- 66.30 66.30 -- H.sub.2 O -- -- -- -- -- -- Liquid product composition, wt. % EDA 1.17 1.09 1.06 69.42 67.49 1.37 MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 MEA 9.15 10.15 10.62 20.41 20.60 85.05 EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 PIP 0.52 0.44 0.40 0.54 0.53 0.51 DETA 72.91 74.49 75.62 4.65 6.35 1.42 AEEA 1.21 1.18 1.20 2.23 2.29 8.02 AEP 0.90 0.83 0.80 0.62 0.62 0.58 HEP 0.06 0.00 0.00 0.00 0.00 0.39 TETA's 8.79 7.76 6.81 1.00 1.04 0.51 TEPA's 2.10 1.50 1.19 0.11 0.82 0.00 ROH Conversion % Acyclic (N4)/cyclic (<=N4), 14.70 15.60 18.70 -- -- -- weight ratio Acyclic (N5)/cyclic (<=N5), 21.40 100.00 100.00 -- -- -- weight ratio .SIGMA.(N5)/.SIGMA.(N4), 7.60 8.10 8.70 -- -- -- weight ratio__________________________________________________________________________ TABLE LXI__________________________________________________________________________Example No. 575 576 577 578 579 580 581__________________________________________________________________________Catalyst Type QQQ QQQ QQQ QQQ QQQ QQQ QQQCatalyst weight, gm 123.1 123.1 123.1 123.1 123.1 123.1 123.1Pressure, psig 600 600 600 600 600 600 600Temperature, .degree.C. 278 280 279 308 306 305 305Time on organics, hrs. 31.2 19.5 21.5 26.2 32.2 49.2 51.2Duration of run, hrs. 1 16 2 2 2 16 2MEA SV, gmol/hr/kgcat 2.14 1.96 1.95 1.93 1.91 1.64 1.65NH.sub.3 feedrate, gm/hr 80.0 53.0 53.5 58.5 59.5 56.0 47.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 -- --AEEA -- -- -- -- -- 33.54 33.54Liquid product composition,wt. %EDA 0.93 0.49 0.46 1.74 1.34 1.17 1.12MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 15.52 14.20 14.55 7.82 10.95 0.58 0.25EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.08 0.13 0.11 0.66 0.36 4.33 4.26DETA 79.78 80.09 80.45 79.71 78.22 72.69 71.85AEEA 0.63 0.82 0.84 0.58 0.97 4.41 5.88AEP 0.38 0.42 0.39 1.19 0.85 0.97 0.80HEP 0.00 0.00 0.00 0.00 0.12 0.15 0.08TETA's 2.32 3.12 2.68 6.54 3.78 8.89 8.53TEPA's 0.00 0.22 0.16 1.09 0.55 4.30 4.08ROH Conversion % 32.65 38.51 37.03 65.50 51.72 86.80 82.30Acyclic (N4)/cyclic (<=N4), -- -- 100.00 11.57 12.90 7.79 10.00weight ratioAcyclic (N5)/cyclic (<=N5), -- -- -- -- -- 0.10 0.10weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- 0.50 0.50weight ratio__________________________________________________________________________ TABLE LXII__________________________________________________________________________Example No. 582 583 584 585 586 587 588 589__________________________________________________________________________Catalyst Type RRR RRR RRR RRR RRR RRR RRR RRRCatalyst weight, gm 116.4 116.4 116.4 116.4 116.4 116.4 116.4 116.4Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 274 274 274 303 301 303 301 301Time on organics, hrs. 3.0 18.8 20.8 26.5 43.0 45.0 50.4 55.1Duration of run, hrs. 1 16 2 2 16 2 2 2MEA SV, gmol/hr/kgcat 2.05 2.07 2.11 2.03 2.02 1.97 3.24 3.26NH.sub.3 feedrate, gm/hr 70.0 60.3 53.5 93.0 60.8 61.0 53.0 78.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 62.81 62.81MEA 22.84 22.84 22.84 22.84 22.84 22.84 37.19 37.19Liquid product composition,wt. %EDA 1.07 1.05 0.86 3.00 2.27 1.97 2.25 1.86MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 10.34 10.06 11.47 3.86 6.06 7.28 15.71 21.10EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.07 0.69 0.44 1.4 1.06 0.87 1.14 0.71DETA 71.40 71.74 74.72 68.70 70.45 72.29 62.19 63.50AEEA 2.14 1.02 1.02 0.29 0.47 0.62 1.27 1.68AEP 1.05 0.89 0.63 2.17 1.54 1.30 1.61 1.01HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 8.90 10.65 8.62 13.51 11.60 10.01 9.86 5.67TEPA's 3.00 2.71 1.52 3.58 2.99 2.10 2.09 1.32ROH Conversion % 55.63 56.77 50.69 83.26 73.52 68.05 57.95 43.18Acyclic (N4)/cyclic (<=N4), 14.20 26.00 40.00 7.30 9.40 11.10 8.40 13.00weight ratioAcyclic (N5)/cyclic (<=N5), 21.70 25.90 100.00 3.90 5.60 26.00 13.70 2.97weight ratio.SIGMA.(N5)/.SIGMA.(N4), 5.00 9.50 13.00 3.90 -- -- 4.00 4.70weight ratio__________________________________________________________________________ TABLE LXIII__________________________________________________________________________Example No. 590 591 592 593 594 595 596 597 598 599 600 601__________________________________________________________________________Catalyst Type SSS SSS SSS SSS SSS SSS SSS SSS SSS SSS SSS SSSCatalyst weight, gm 105.1 105.1 105.1 105.1 105.1 105.1 105.1 105.1 105.1 105.1 105.1 105.1Pressure, psig 600 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 284 286 284 304 303 276 276 280 306 311 311 311Time on organics, hrs. 3.0 19.0 20.0 41.6 43.6 49.0 65.0 67.0 71.0 78.0 92.0 94.0Duration of run, hrs. 1 16 2 16 2 2 15 2 2 2 16 2MEA SV, gmol/hr/kgcat 2.30 2.34 2.35 2.26 2.29 2.00 1.97 1.94 1.96 1.84 1.90 1.98NH.sub.3 feedrate, gm/hr 60.5 59.0 52.5 53.4 56.5 54.5 61.5 54.0 48.0 63.0 45.0 53.0Liquid feed composition, wt. %EDA -- -- -- -- -- -- -- -- -- 18.29 18.29 18.29DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46 31.41 31.41 31.41MEA 22.84 22.84 22.84 22.84 22.84 -- -- -- -- 18.59 18.59 18.59AEEA -- -- -- -- -- 33.54 33.54 33.54 33.54 31.71 31.71 31.71Liquid product composition,wt. %EDA 1.42 1.51 1.58 4.01 4.05 0.68 0.62 0.57 3.04 27.12 23.79 25.27MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 9.68 8.49 9.09 3.41 3.82 0.36 0.19 0.16 0.00 3.52 3.25 3.40EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.16 1.29 1.28 2.99 2.95 6.65 6.30 5.94 9.68 10.98 9.83 10.11DETA 71.42 70.10 71.52 65.54 64.54 71.47 69.54 69.17 57.76 28.16 27.11 27.67AEEA 0.59 0.59 0.55 0.23 0.18 8.21 9.71 10.06 0.27 0.42 0.37 0.33AEP 1.08 1.25 1.22 3.33 3.12 0.89 0.75 0.73 3.14 6.78 7.24 6.99HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 11.29 12.78 11.42 13.94 14.12 4.16 3.83 3.84 11.05 12.22 14.47 13.61TEPA's 2.65 3.21 2.53 3.96 4.53 6.84 8.00 8.60 10.52 6.38 7.75 7.53ROH Conversion % 58.68 63.87 61.20 85.42 83.62 75.90 71.50 70.50 99.20 81.42 82.82 81.99Acyclic (N4)/cyclic (<=N4), 28.50 26.30 26.00 6.70 6.80 0.40 0.30 0.30 0.50 0.90 0.90 0.90weight ratioAcyclic (N5)/cyclic (<=N5), -- -- 100.00 4.10 4.00 61.00 79.00 28.20 4.10 0.70 0.80 0.80weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- 1.64 2.10 2.20 1.00 -- -- --weight ratio__________________________________________________________________________ TABLE LXIV__________________________________________________________________________ Example No. 602 603 604 605 606 607 608 609 610 611 612__________________________________________________________________________Catalyst Type TTT TTT TTT TTT TTT TTT TTT TTT TTT TTT TTTCatalyst weight, gm 117.9 117.9 117.9 117.9 117.9 117.9 117.9 117.9 117.9 117.9 117.9Pressure, psig 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 278 277 301 302 301 300 300 303 301 302 302Time on organics, hrs. 18.0 20.0 25.0 40.0 42.0 47.5 65.5 87.0 88.5 109.0 111.0Duration of run, hrs. 16 2 2 14 2 2 2 19 2 20 2MEA SV, gmol/hr/kgcat 2.03 2.06 1.98 2.00 2.11 1.74 1.32 3.51 3.79 3.30 3.45NH.sub.3 feedrate, gm/hr 56.0 54.0 54.0 63.0 61.0 60.0 10.0 67.8 54.0 67.9 48.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 62.81 62.81 62.81 62.81MEA 22.84 22.84 22.84 22.84 22.84 -- -- 37.19 37.19 37.19 37.19AEEA -- -- -- -- -- 33.54 33.54 -- -- -- --Liquid product composition, wt. %EDA 1.02 0.88 3.46 2.84 2.51 1.46 2.23 2.44 2.31 2.15 2.01MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 12.18 11.85 5.47 5.76 6.66 0.35 0.15 15.93 16.51 17.85 18.61EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.50 0.49 1.74 1.49 1.27 5.41 5.82 1.39 1.23 1.13 1.02DETA 74.13 74.56 70.50 71.81 70.37 70.92 61.30 60.00 61.02 61.91 62.27AEEA 1.14 1.11 0.39 0.48 0.56 3.78 4.31 1.92 1.89 2.00 2.10AEP 0.64 0.64 2.16 1.91 1.65 1.24 2.04 1.64 1.58 1.42 1.26HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 7.19 7.69 10.84 10.30 10.16 6.34 7.31 9.54 9.36 8.29 8.01TEPA's 2.28 1.79 2.96 2.74 3.47 8.47 12.87 3.31 2.80 2.39 2.35ROH Conversion % 47.45 48.87 76.39 75.07 70.93 88.80 87.00 57.42 56.04 52.52 50.66Acyclic (N4)/cyclic (<= N4), 30.70 29.40 6.40 7.90 8.10 0.30 0.50 6.70 6.40 8.40 9.20weight ratioAcyclic (N5)/cyclic (<=N5), 2.70 100.00 3.50 4.40 5.20 11.70 12.20 4.70 3.90 4.80 5.10weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- 1.30 1.80 -- -- -- --weight ratio__________________________________________________________________________ TABLE LXV__________________________________________________________________________Example No. 613 614 615 616 617 618 619 620 621__________________________________________________________________________Catalyst Type UUU UUU UUU UUU UUU UUU UUU UUU UUUCatalyst weight, gm 116.4 116.4 116.4 116.4 116.4 116.4 116.4 116.4 116.4Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 278 291 278 304 307 306 301 302 302Time on organics, hrs. 18.0 20.2 22.2 28.0 44.5 46.5 55.5 68.5 70.5Duration of run, hrs. 16 16 2 2 16 2 2 13 2MEA SV, gmol/hr/kgcat 2.03 2.05 2.06 2.07 2.00 2.02 1.73 1.72 1.78NH.sub.3 feedrate, gm/hr 56.0 51.2 51.5 56.0 56.0 53.5 64.0 59.7 59.7Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- --AEEA -- -- -- -- -- -- 33.54 33.54 33.54 Liquid product composition, wt. %EDA 1.02 1.12 0.70 2.22 2.31 2.54 1.67 1.70 1.86MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 12.18 10.60 11.71 6.34 6.10 6.24 0.21 0.00 0.20EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.50 0.56 0.35 1.18 1.19 1.22 7.01 6.71 7.26DETA 74.13 76.35 76.18 74.45 74.51 74.81 73.57 73.53 73.22AEEA 1.14 0.90 1.00 0.49 0.42 0.43 1.39 1.52 1.41AEP 0.64 0.79 0.61 1.53 1.60 1.58 1.22 1.17 1.15HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.10 0.00 0.09TETA's 7.19 7.58 7.18 9.57 8.76 8.18 7.33 7.38 7.12TEPA's 2.28 1.36 1.47 1.86 3.57 1.80 4.61 5.25 4.68ROH Conversion % 47.45 54.45 49.55 72.57 73.87 72.74 95.90 95.50 95.80Acyclic (N4)/cyclic (<=N4), 30.70 24.30 30.50 11.20 10.20 8.90 0.20 0.10 0.10weight ratioAcyclic (N5)/cyclic (<=N5), 2.70 100.00 100.00 10.00 5.80 7.40 11.80 9.80 11.00weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- 0.60 0.70 0.70weight ratio__________________________________________________________________________ TABLE LXVI__________________________________________________________________________Example No. 622 623 624 625 626 627 628 629__________________________________________________________________________Catalyst Type VVV VV VVV VVV VVV VVV VVV VVVCatalyst weight, gm 117.2 117.2 117.2 117.2 117.2 117.2 117.2 117.2Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 276 277 275 299 290 302 300 308Time on organics, hrs. 4.0 11.0 20.0 26.0 36.0 40.0 45.0 57.0Duration of run, hrs. 2 2 2 2 10 2 2 2MEA SV, gmol/hr/kgcat 1.76 2.31 2.08 2.00 2.03 1.95 1.81 1.69NH.sub.3 feedrate, gm/hr 29.0 37.5 58.0 55.0 55.0 52.0 59.0 49.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- --AEEA -- -- -- -- -- -- 33.54 33.54Liquid product composition, wt. %EDA 1.54 1.38 1.38 2.84 2.73 3.56 1.85 2.20MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 8.33 7.66 13.37 5.58 5.61 6.07 0.33 0.00EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 1.26 1.16 0.29 1.49 1.48 1.46 7.47 6.84DETA 74.34 74.58 80.12 74.81 70.27 70.19 71.84 71.91AEEA 1.27 0.89 0.00 0.00 0.00 0.13 1.65 1.10AEP 0.64 1.29 0.54 1.97 1.90 1.84 1.31 1.68HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 10.00 10.98 4.25 10.18 11.99 10.45 5.91 6.40TEPA's 2.07 1.86 0.00 1.74 3.50 2.98 7.79 6.50ROH Conversion % 64.49 67.56 42.44 76.15 75.80 73.51 95.10 96.70Acyclic (N4)/cyclic (<=N4), 17.80 20.40 20.40 9.50 11.40 9.80 0.20 0.30weight ratioAcyclic (N5)/cyclic (<=N5), -- -- -- 5.30 7.30 -- 22.60 11.20weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- 1.30 1.00weight ratio__________________________________________________________________________ TABLE LXVII__________________________________________________________________________Example No. 630 631 632 633 634 635 636 637__________________________________________________________________________Catalyst Type WWW WWW WWW WWW WWW WWW WWW WWWCatalyst weight, gm 107.3 107.3 107.3 107.3 107.3 107.3 107.3 107.3Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 276 275 276 300 301 300 301 301Time on organics, hrs. 4.0 14.0 16.0 21.0 37.5 39.5 47.5 44.0Duration of run, hrs. 2 10 2 2 16 2 2 2MEA SV, gmol/hr/kgcat 2.22 2.22 2.28 2.18 2.06 1.92 1.90 1.82NH.sub.3 feedrate, gm/hr 49.0 53.7 51.0 49.0 52.3 60.0 61.0 49.5Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 -- -- --AEEA -- -- -- -- -- 33.54 33.54 33.54Liquid product composition, wt. %EDA 0.59 0.48 0.42 1.39 1.39 1.17 1.18 1.35MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 11.78 12.64 12.69 7.30 8.85 0.48 0.00 8.79EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.32 0.18 0.14 0.65 0.57 5.50 5.68 0.57DETA 81.41 81.70 81.91 81.16 82.83 79.81 81.98 84.88AEEA 1.12 0.89 0.89 0.00 0.00 2.01 1.94 1.08AEP 0.57 0.50 0.48 1.17 1.08 1.14 1.08 0.00HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 3.71 3.08 2.89 5.97 3.52 6.18 5.18 1.83TEPA's 0.00 0.00 0.00 0.65 0.00 1.97 1.34 0.00ROH Conversion % 49.22 45.39 45.13 68.46 61.55 94.00 94.20 96.70Acyclic (N4)/cyclic (<=N4), 100.00 100.00 100.00 25.40 18.40 100.00 100.00 100.00weight ratioAcyclic (N5)/cyclic (<=N5), -- -- -- 100.00 -- 0.00 0.00 --weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- 0.30 0.30 --weight ratio__________________________________________________________________________ TABLE LXVIII__________________________________________________________________________Example No. 638 639 640 641 642 643 644 645__________________________________________________________________________Catalyst Type XXX XXX XXX XXX XXX XXX XXX XXXCatalyst weight, gm 126.9 126.9 126.9 126.9 126.9 126.9 126.9 126.9Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 282 264 269 296 283 290 299 272Time on organics, hrs. 4.0 24.0 27.0 48.0 50.0 67.5 69.5 75.0Duration of run, hrs. 2 2 2 2 2 15 2 2MEA SV, gmol/hr/kgcat 1.87 1.84 1.86 1.71 1.87 1.63 1.67 1.64NH.sub.3 feedrate, gm/hr 53.5 54.0 51.0 55.0 50.0 45.0 41.0 51.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46MEA 22.84 22.84 22.84 22.84 22.84 -- -- --AEEA -- -- -- -- -- 33.54 33.54 33.54Liquid product composition, wt. %EDA 2.60 1.08 0.73 2.34 1.57 1.64 1.62 0.00MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 2.38 8.61 10.46 5.48 7.30 0.00 0.00 0.00EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 2.30 0.91 0.71 2.12 1.59 11.97 12.36 6.27DETA 72.97 78.50 79.50 76.30 78.68 68.16 71.0 77.31AEEA 0.00 0.00 0.00 0.00 0.00 1.42 1.38 14.18AEP 3.04 1.12 0.68 2.28 1.55 1.79 1.72 0.47HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 13.55 7.63 6.79 7.81 7.22 8.73 7.12 1.57TEPA's 3.04 1.60 0.92 1.88 1.11 4.32 3.21 0.00ROH Conversion % 90.08 63.26 55.30 76.51 68.80 95.90 96.00 58.30Acyclic (N4)/cyclic (<=N4), 7.10 10.50 100.00 5.40 9.90 0.10 0.00 0.00weight ratioAcyclic (N5)/cyclic (<=N5), 7.80 100.00 100.00 2.90 100.00 10.50 100.00 100.00weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- 0.50 0.50 --weight ratio__________________________________________________________________________ TABLE LXIX__________________________________________________________________________Example No. 646 647 648 649 650 651 652 653 654 655 656__________________________________________________________________________Catalyst Type YYY YYY YYY YYY YYY YYY YYY YYY YYY YYY YYYCatalyst weight, gm 120.2 120.2 120.2 120.2 120.2 120.2 120.2 120.2 120.2 120.2 120.2Pressure, psig 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 272 273 273 289 300 299 297 300 299 272 272Time on organics, hrs. 3.5 19.5 21.5 27.5 43.5 45.5 50.5 66.5 68.5 70.5 73.5Duration of run, hrs. 2 16 2 2 16 2 2 16 2 2 1MEA SV, gmol/hr/kgcat 1.92 1.95 2.06 2.09 1.94 1.99 1.56 1.58 1.55 1.66 2.03NH.sub.3 feedrate, gm/hr 111.0 50.9 66.0 80.0 58.0 55.0 68.0 64.5 84.8 67.0 49.0Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- -- 22.84AEEA -- -- -- -- -- -- 33.54 33.54 33.54 33.54 --Liquid product composition, wt. %EDA 0.00 0.00 0.00 0.00 1.08 0.00 0.00 0.00 0.00 0.00 0.00MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 8.22 8.33 7.82 2.98 3.36 3.69 1.08 1.14 0.00 0.00 9.79EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.00 0.00 0.00 0.91 0.73 0.71 5.156 4.86 4.64 3.87 0.43DETA 88.30 87.01 88.01 84.49 81.52 83.00 83.96 79.07 83.12 84.96 87.16AEEA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.65 0.73 5.72 0.00AEP 0.37 0.38 0.38 1.42 1.30 1.22 1.35 1.06 1.01 0.43 0.49HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 3.10 4.29 3.79 8.95 10.19 8.57 4.93 6.53 5.81 2.15 2.13TEPA's 0.00 0.00 0.00 0.75 1.14 0.79 2.69 5.45 4.13 2.87 0.00ROH Conversion % 64.92 64.48 66.67 87.43 85.77 84.16 99.30 99.50 100.00 68.50 58.15Acyclic (N4)/cyclic (<=N4), 100.00 100.00 100.00 26.20 17.50 17.80 0.31 0.10 0.06 0.00 100.00weight ratioAcyclic (N5)/cyclic (<=N5), -- -- -- 100.00 100.00 100.00 100.00 22.20 100.00 100.00 --weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- -- -- -- -- --weight ratio__________________________________________________________________________ TABLE LXX__________________________________________________________________________Example No. 657 658 659 660 661 662 663 664 665 666 667__________________________________________________________________________Catalyst Type ZZZ ZZZ ZZZ ZZZ ZZZ ZZZ ZZZ ZZZ ZZZ ZZZ ZZZCatalyst weight, gm 116.3 116.3 116.3 116.3 116.3 116.3 116.3 116.3 116.3 116.3 116.3Pressure, psig 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 275 275 275 300 303 300 299 299 300 274 275Time on organics, hrs. 6.0 23.0 25.0 29.0 47.0 49.0 54.0 71.0 73.0 78.0 95.0Duration of run, hrs. 2 16 2 2 16 2 2 17 2 2 16MEA SV, gmol/hr/kgcat 1.92 2.00 2.03 1.96 1.96 1.95 1.74 1.51 1.60 1.78 1.99NH.sub.3 feedrate, gm/hr 70.0 61.1 57.5 49.5 51.3 52.0 55.5 48.8 50.5 55.0 48.3Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 66.46 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- -- 22.84AEEA -- -- -- -- -- -- 33.54 33.54 33.54 33.54 --Liquid feed composition, wt. %EDA 1.09 0.80 0.74 1.86 1.69 1.60 1.45 1.55 1.62 0.58 0.58MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 13.57 15.03 15.47 8.52 10.49 11.24 0.62 0.38 0.38 0.46 16.94EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.34 0.20 0.18 0.56 0.47 0.42 3.49 3.53 3.46 1.39 0.14DETA 71.01 74.43 74.82 71.47 73.78 74.30 72.62 70.62 71.21 69.66 76.98AEEA 1.11 1.21 1.24 0.65 0.87 0.99 4.29 4.09 4.36 20.93 2.65AEP 0.51 0.33 0.31 0.91 0.77 0.73 0.76 0.68 0.67 0.22 0.25HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 7.40 5.81 5.25 8.79 6.82 5.83 6.63 6.99 6.60 1.40 1.67TEPA's 3.76 1.88 1.60 4.50 2.87 2.23 8.06 8.11 7.70 4.25 0.37ROH Conversion % 41.20 35.13 33.09 62.86 54.23 50.62 87.20 87.50 86.70 37.40 26.29Acyclic (N4)/cyclic (<=N4), 24.50 100.00 100.00 12.00 12.80 11.60 0.12 0.10 0.10 0.10 100.00weight ratioAcyclic (N5)/cyclic (<=N5), 96.0 100.00 100.00 5.90 8.70 17.10 10.20 11.50 12.70 100.00 100.00weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- 1.20 1.20 1.20 3.00 --weight ratio__________________________________________________________________________ TABLE LXXI__________________________________________________________________________Example No. 668 669 670 671 672 673 674 675 676 677 678__________________________________________________________________________Catalyst Type AAAA AAAA AAAA AAAA AAAA AAAA AAAA AAAA AAAA AAAA AAAACatalyst weight, gm 117.7 117.7 117.7 117.7 117.7 117.7 117.7 117.7 117.7 117.7 117.7Pressure, psig 600 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 275 275 277 303 302 302 273 301 301 274 274Time on organics, hrs. 6.0 22.0 24.0 29.0 45.6 47.6 52.6 69.7 71.7 76.7 93.7Duration of run, hrs. 2 16 2 2 16 2 2 16 2 2 16MEA SV, gmol/hr/kgcat 1.98 1.99 2.03 1.99 1.99 2.03 2.00 1.58 1.70 1.75 1.98NH.sub.3 feedrate, gm/hr 68.0 54.3 50.5 5.5 47.8 48.5 79.0 68.3 72.5 79.5 68.1Liquid feed composition, wt. %DETA 77.16 77.16 77.16 77.16 77.16 77.16 77.16 66.46 66.46 66.46 77.16MEA 22.84 22.84 22.84 22.84 22.84 22.84 22.84 -- -- -- 22.84AEEA -- -- -- -- -- -- -- 33.54 33.54 33.54 --Liquid product composition, wt. %EDA 0.97 0.91 0.90 2.63 2.07 1.73 0.53 1.35 1.32 0.42 0.48MeEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00MEA 11.59 11.42 11.61 3.72 5.41 7.22 15.50 0.39 0.26 0.39 15.13EtEDA 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00PIP 0.35 0.33 0.31 0.84 0.64 0.53 0.12 3.59 3.54 1.45 0.22DETA 71.40 70.89 71.27 67.56 69.33 71.24 76.04 68.79 68.37 66.67 74.89AEEA 1.15 1.26 1.28 0.23 0.44 0.85 1.39 2.48 3.15 20.08 3.01AEP 0.52 0.49 0.47 1.53 1.12 0.91 0.30 0.81 0.69 0.23 0.29HEP 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00TETA's 9.08 9.52 9.30 12.67 11.55 9.77 4.68 6.58 6.06 1.62 3.65TEPA's 4.20 4.41 4.17 7.89 6.69 5.30 1.17 13.35 12.33 7.56 1.63ROH Conversion % 50.26 51.01 50.20 83.98 76.63 68.73 33.00 92.60 90.40 39.90 34.34Acyclic (N4)/cyclic (<=N4), 38.80 46.80 50.10 9.60 13.90 17.20 100.00 0.30 0.20 0.20 15.70weight ratioAcyclic (N5)/cyclic (<=N5), 21.00 24.40 22.90 4.10 6.10 8.90 100.00 13.50 16.00 100.00 8.20weight ratio.SIGMA.(N5)/.SIGMA.(N4), -- -- -- -- -- -- -- 2.00 12.00 4.70 --weight ratio__________________________________________________________________________ TABLE LXXII__________________________________________________________________________Example No. 679 680 681 682 683 684 685 686 687__________________________________________________________________________Catalyst Type BBBB BBBB BBBB BBBB BBBB BBBB BBBB BBBB BBBBCatalyst weight, gm 78.74 78.74 78.74 78.74 78.74 78.74 78.74 78.74 78.74Pressure, psig 606 603 603 602 603 603 603 598 603Temperature, .degree.C. 270 270 280 269 259 280 280 270.1 270Time on organics, hrs. 4.5 4.5 28.5 51.5 71.5 76.5 100.5 120 167.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.46 3.84 3.94 3.87 3.77 3.63 3.78 3.83 3.81DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.874 1.232 1.585 0.847 0.433 1.400 1.565 0.773 0.551MEA 12.473 11.945 7.517 13.370 17.877 6.436 7.199 12.823 16.111PIP 0.965 1.116 1.414 1.070 0.651 1.400 1.451 1.028 0.807DETA 39.228 39.867 35.453 41.854 47.014 35.668 35.534 41.213 44.005AEEA 1.227 1.108 0.479 1.371 2.399 0.486 0.502 1.388 1.922AEP 1.183 1.533 1.814 1.158 0.708 1.977 1.886 1.126 0.824HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.760 2.694 2.611 2.646 2.564 2.683 2.567 2.662 2.5601-TETA 12.867 13.297 13.364 12.613 12.062 14.170 13.658 12.943 12.257DAEP 0.519 0.744 0.968 0.425 0.180 1.018 0.985 0.432 0.232PEEDA 0.110 0.111 0.154 0.082 0.152 0.059 0.710 0.336 0.206DPE 0.118 0.120 0.127 0.085 0.097 0.087 0.322 0.227 0.120AE-TAEA 4.110 3.926 4.516 3.704 2.640 4.497 4.572 3.788 3.0141-TEAP 7.436 7.679 8.979 7.093 5.411 8.403 9.298 7.467 6.239AE-DAEP 0.140 0.117 0.182 0.100 0.097 0.000 0.808 0.390 0.275AE-PEEDA 0.099 0.100 0.129 0.096 0.000 0.720 0.173 0.127 0.099iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.304 0.169 0.301 0.160 0.065 0.160 1.020 0.739 0.467BPEA 0.639 0.578 0.844 0.573 0.045 0.211 1.060 0.835 0.435Others 8.068 6.841 11.264 5.414 2.775 11.735 8.190 6.222 3.695MEA Conversion, % 66.60 68.06 79.87 63.84 52.17 82.68 80.79 66.20 56.64DETA Conversion, % 37.56 36.64 43.59 32.72 25.25 42.94 43.64 35.44 29.62Acyclic(N4), wt. % 95.43 94.25 92.75 96.27 97.15 93.54 88.94 94.00 96.37Acyclic(N5), wt. % 90.71 92.25 90.26 92.08 97.50 92.20 81.92 84.33 87.88.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.78 0.74 0.87 0.74 0.55 0.78 0.93 0.80 0.68Acyclic(N4)/cyclic(<=N4), 5.40 4.41 3.57 5.41 8.18 3.71 3.03 4.96 6.77weight ratio__________________________________________________________________________Example No. 688 689 690 691 692 693 694 695 696__________________________________________________________________________Catalyst Type BBBB BBBB BBBB BBBB BBBB BBBB BBBB BBBB BBBBCatalyst weight, gm 78.74 78.74 78.74 78.74 78.74 78.74 78.74 78.74 78.74Pressure, psig 603 604 603 604 603 603 603 604 604Temperature, .degree.C. 280 259 269 260 280 270 280 270 270Time on organics, hrs. 172.5 191.5 196.5 214.5 219.5 238.5 243.5 262.5 266Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.71 3.89 3.89 3.81 3.78 3.79 3.51 3.51 3.71DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.445 0.461 0.791 0.658 1.456 0.910 1.122 1.072 1.017MEA 5.976 18.787 12.858 18.141 6.956 13.064 13.239 11.990 12.608PIP 1.387 0.691 1.023 0.811 1.416 1.148 1.024 1.234 1.186DETA 33.430 47.586 40.957 45.580 35.955 41.603 42.624 40.482 40.928AEEA 0.443 2.282 1.404 1.879 0.493 1.322 1.350 1.216 1.269AEP 1.827 0.682 1.103 0.881 1.832 1.184 1.192 1.267 1.191HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.553 2.310 2.681 2.359 2.571 2.654 2.361 2.647 2.6271-TETA 13.506 10.647 12.732 10.997 13.341 12.720 11.438 12.833 12.755DAEP 1.004 0.173 0.386 0.275 0.888 0.410 0.490 0.472 0.422EEDA 0.710 0.146 0.310 0.222 0.654 0.36 0.382 0.369 0.339DPE 0.335 0.085 0.184 0.086 0.309 0.196 0.271 0.070 0.135AE-TAEA 4.645 2.372 3.629 2.706 4.368 3.735 3.951 3.951 3.7511-TEPA 9.538 4.500 6.990 5.378 8.945 7.412 6.576 7.610 7.246AE-DAEP 0.848 0.213 0.276 0.183 0.700 0.300 0.385 0.331 0.291AE-PEEDA 0.185 0.000 0.057 0.056 0.084 0.065 0.085 0.035 0.028iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 1.089 0.315 0.667 0.434 1.016 0.698 0.091 0.064 0.062BPEA 1.026 0.247 0.634 0.403 0.932 0.638 0.093 0.594 0.053Others 9.232 1.904 3.598 2.311 6.162 3.686 6.348 5.045 5.231MEA conversion, % 83.70 48.64 64.40 50.59 80.69 64.55 64.31 67.22 65.36DETA conversion, % 45.82 22.68 32.60 26.22 40.67 32.91 31.71 34.22 33.16Acyclic(N4), wt. % 88.68 96.98 94.60 95.81 89.58 94.23 92.35 94.45 94.49Acyclic(N5), wt. % 81.83 89.87 86.66 88.25 82.97 86.76 94.15 91.86 96.21Acyclic(N4)/cyclic(<=N4), 3.05 7.29 5.13 5.86 3.12 4.70 4.11 4.54 4.70weight ratio__________________________________________________________________________ TABLE LXXIII__________________________________________________________________________Example No. 697 698 699 700 701 702 703 704 705__________________________________________________________________________Catalyst Type CCCC CCCC CCCC CCCC CCCC CCCC CCCC CCCC CCCCCatalyst weight, gm 84.66 84.66 84.66 84.66 84.66 84.66 84.66 84.66 84.66Pressure, psig 598 598 598 598 598 599 599 598 603Temperature, .degree.C. 270 270 280 259 269 259 280 280 270.1Time on organics, hrs. 4.5 23.5 28.5 47.5 51.5 71.5 76.5 100.5 120Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.95 2.82 2.91 2.90 2.89 2.81 2.72 2.85 2.92DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.387 0.451 0.942 0.263 0.472 0.251 0.768 0.805 0.481MEA 18.211 18.550 12.561 24.117 18.908 22.270 11.181 11.851 17.815PIP 0.711 0.768 1.105 0.411 0.731 0.450 1.013 1.082 0.763DETA 45.762 47.529 39.025 52.023 46.902 51.519 38.122 38.925 46.516AEEA 1.902 2.077 1.192 2.582 2.111 2.804 1.247 1.088 2.005AEP 0.846 0.787 1.214 0.446 0.718 0.519 1.229 1.254 0.767HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.031 2.252 2.423 1.674 2.273 2.036 2.764 2.429 2.3451-TETA 10.921 11.106 12.012 8.125 11.140 9.812 13.613 12.691 11.657DAEP 0.186 0.202 0.477 0.080 0.175 0.097 0.523 0.523 0.191PEEDA 0.159 0.178 0.147 0.057 0.157 0.084 0.424 0.443 0.174DPE 0.084 0.096 0.095 0.052 0.114 0.086 0.094 0.303 0.105AE-TAEA 2.341 2.390 3.575 1.205 2.444 1.558 4.042 3.853 2.6501-TEPA 3.918 5.171 7.286 2.186 6.082 3.822 8.123 8.109 6.868AE-DAEP 0.366 0.189 0.131 0.129 0.081 0.000 0.417 0.508 0.093AE-PEEDA 0.080 0.079 0.101 0.068 0.000 0.000 0.113 0.139 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.403 0.061 0.264 0.051 0.078 0.066 0.220 0.797 0.055BPEA 0.328 0.276 0.649 0.076 0.291 0.128 0.215 0.930 0.371Others 6.126 2.669 9.532 1.845 2.513 1.388 8.524 7.390 2.594MEA conversion, % 51.16 50.15 66.20 34.36 49.36 40.71 70.01 68.44 52.59DETA conversion, % 27.06 24.09 37.59 15.85 25.35 18.49 39.22 38.40 26.43Acyclic(N4), wt. % 96.80 96.56 95.26 98.11 96.78 97.79 94.03 92.26 96.75Acyclic(N5), wt. % 84.17 92.59 90.47 91.27 94.99 96.53 92.65 83.44 94.83.SIGMA.(N5)/.SIGMA. (N4), weight ratio 0.56 0.59 0.79 0.37 0.65 0.46 0.75 0.87 0.69Acyclic(N4)/cyclic(<=N4), 6.52 6.58 4.75 9.37 7.08 9.58 4.99 4.20 7.00weight ratio__________________________________________________________________________Example No. 706 707 708 709 710 711 712 713 714 715__________________________________________________________________________Catalyst Type CCCC CCCC CCCC CCCC CCCC CCCC CCCC CCCC CCCC CCCCCatalyst weight, gm 84.66 84.66 84.66 84.66 84.66 84.66 84.66 84.66 84.66 84.66Pressure, psig 598 598 598 598 598 599 599 604 604 604Temperature, .degree.C. 270 280 259 269 260 280 270 280 270 270Time on organics, hrs. 167.5 172.5 191.5 196.5 214.5 219.5 238.5 243.5 262.5 266Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.92 2.51 2.94 2.91 3.37 2.82 2.90 2.83 2.69 2.83DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.768 0.935 0.259 0.554 0.303 0.984 0.731 1.166 0.772 0.727MEA 11.617 9.895 22.5045 16.654 25.518 10.278 15.594 9.688 14.486 15.223PIP 1.012 1.112 0.501 0.801 0.351 1.163 0.969 1.258 0.984 0.967DETA 38.660 37.291 50.906 4.882 53.431 38.532 43.211 37.652 42.240 43.621AEEA 1.321 0.909 2.608 1.955 2.502 0.852 1.707 0.755 1.601 1.652AEP 1.097 1.308 0.480 0.827 0.406 1.361 1.004 1.440 1.010 0.980HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.638 2.623 2.028 2.607 1.424 2.641 2.659 2.671 2.744 2.6661-TETA 12.643 12.534 9.067 11.734 6.423 12.393 11.936 12.701 12.439 12.081DAEP 0.461 0.560 0.119 0.241 0.079 0.538 0.298 0.622 0.320 0.282PEEDA 0.353 0.455 0.081 0.211 0.068 0.431 0.263 0.498 0.276 0.248DPE 0.353 0.332 0.103 0.133 0.127 0.308 0.161 0.109 0.118 0.100AE-TAEA 3.971 4.248 1.719 2.992 1.105 4.215 3.423 4.647 3.605 3.4111-TEPA 8.051 8.471 3.147 5.870 1.995 8.144 6.726 8.696 6.609 6.249AE-DAEP 0.479 0.536 0.073 0.161 0.074 0.499 0.236 0.581 0.204 0.181AE-PEEDA 0.163 0.150 0.064 0.000 0.053 0.132 0.054 0.123 0.034 0.030iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.793 0.918 0.151 0.456 0.092 0.892 0.536 0.306 0.061 0.063BPEA 0.949 1.033 0.115 0.459 0.108 0.885 0.576 0.724 0.059 0.402Others 7.450 7.630 1.713 2.553 2.042 6.020 3.491 7.953 4.671 3.839MEA conversion, % 68.95 73.17 39.26 54.71 30.82 71.85 58.06 73.87 60.45 58.58DETA conversion, % 38.60 39.91 18.34 27.46 13.91 37.28 30.93 39.64 31.46 29.46Acyclic(N4), wt. % 92.90 91.84 97.34 96.08 96.64 92.17 95.29 92.60 95.51 95.90Acyclic(N5), wt. % 83.45 82.83 92.34 89.17 90.46 83.69 87.90 88.50 96.63 93.47.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.88 0.93 0.46 0.67 0.42 0.91 0.76 0.91 0.67 0.67Acyclic(N4)/cyclic(<=N4), 4.66 4.02 8.64 6.48 7.62 3.95 5.42 3.91 5.61 5.72weight ratio__________________________________________________________________________ TABLE LXXIV__________________________________________________________________________ Example No. 716 717 718 719 720 721 722 723 724__________________________________________________________________________Catalyst Type DDDD DDDD DDDD DDDD DDDD DDDD DDDD DDDD DDDDCatalyst weight, gm 75 75 75 75 75 75 75 75 75Pressure, psig 607.5 600 600 600 600 600 600 600 600Temperature, .degree.C. 267.9 267.8 277.8 259.9 270.1 259.9 280.1 269.6 269Time on organics, hrs. 5 7.5 26 31.5 50 55.5 74 78 80Duration of run, hrs. 1 1 2 2 2 2 2 2 1.5MEA SV, gmol/hr/kgcat 8.48 8.57 4.17 3.96 3.90 4.22 4.15 4.01 3.97DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.673 0.822 1.742 0.612 1.367 0.688 2.430 1.370 1.341MEA 33.641 24.246 13.234 26.804 16.396 24.443 8.046 15.672 15.462PIP 0.585 1.113 0.000 0.823 1.584 0.886 1.994 1.506 1.484DETA 51.838 49.325 40.936 52.117 49.168 51.098 40.046 47.408 47.941AEEA 2.205 0.926 0.312 1.512 0.754 1.506 0.202 0.925 0.850AEP 0.502 0.953 1.969 0.613 1.431 0.666 2.287 1.330 1.326HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.488 2.104 2.220 1.660 2.270 1.751 2.342 2.219 2.1951-TETA 4.586 9.252 11.293 7.569 10.817 7.792 12.031 10.555 10.356DAEP 0.000 0.167 0.922 0.114 0.307 0.112 1.101 0.290 0.271PEEDA 0.000 0.113 0.678 0.000 0.217 0.075 0.791 0.209 0.196DPE 0.000 0.000 0.205 0.000 0.000 0.000 0.096 0.000 0.000AE-TAEA 0.234 1.259 3.575 0.885 2.431 1.011 3.561 2.057 2.0191-TEPA 0.541 2.471 6.977 1.667 5.274 1.895 7.683 4.176 3.991AE-DAEP 0.000 0.000 0.676 0.000 0.134 0.000 0.783 0.149 0.124AE-PEEDA 0.000 0.000 0.710 0.000 0.089 0.000 0.718 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.882 0.000 0.270 0.091 1.072 0.423 0.395BPEA 0.000 0.000 0.729 0.000 0.340 0.077 0.874 0.385 0.362Others 0.455 0.399 3.890 0.125 1.112 0.488 5.301 1.685 1.506MEA conversion, % 6.59 32.47 63.69 25.82 54.29 31.29 78.37 56.01 56.32DETA conversion, % 14.45 18.36 33.25 14.28 23.51 14.64 36.03 20.92 19.52Acyclic(N4), wt. % 100.00 97.59 88.22 98.78 96.15 98.08 87.85 96.23 96.41Acyclic(N5), wt. % 100.00 100.00 77.88 100.00 90.24 94.53 76.53 86.69 87.22.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.15 0.32 0.88 0.27 0.63 0.32 0.90 0.54 0.53Acyclic(N4)/cyclic(<=N4), 4.67 4.84 3.58 5.96 3.70 5.49 2.29 3.83 3.83weight ratio__________________________________________________________________________ TABLE LXXV__________________________________________________________________________ Example No. 725 726 727 728 729 730 731 732 733__________________________________________________________________________Catalyst Type EEEE EEEE EEEE EEEE EEEE EEEE EEEE EEEE EEEECatalyst weight, gm 68.38 68.38 68.38 68.38 68.38 68.38 68.38 68.38 68.38Pressure, psig 602 602 602 602 602 603 603 602 602Temperature, .degree.C. 270 270 280 259 269 259 280 280 270.1Time on organics, hrs. 4.5 23.5 28.5 47.5 51.5 71.5 76.5 100.5 120Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.96 3.87 4.09 3.96 3.90 3.87 3.92 3.90 4.03DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 0.223 0.361 0.675 0.212 0.396 0.180 0.730 0.795 0.461MEA 24.445 22.069 16.449 26.799 21.362 24.727 13.740 14.037 20.260PIP 0.470 0.526 0.892 0.297 0.553 0.298 0.888 0.897 0.585DETA 53.878 51.806 46.950 56.278 50.889 55.710 44.046 42.839 49.907AEEA 2.281 2.479 1.818 2.578 2.565 2.914 1.871 1.449 2.318AEP 0.515 0.624 1.064 0.387 0.663 0.447 1.193 1.137 0.672HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.420 1.640 2.118 1.210 1.747 1.411 2.465 2.237 1.9311-TETA 7.238 7.768 10.879 5.638 8.217 6.704 12.235 11.091 9.032DAEP 0.092 0.160 0.324 0.058 0.188 0.079 0.480 0.476 0.204PEEDA 0.097 0.137 0.289 0.053 0.154 0.073 0.398 0.393 0.166DPE 0.075 0.095 0.046 0.052 0.063 0.100 0.355 0.333 0.191AE-TAEA 1.219 1.522 2.583 0.752 1.679 0.945 3.598 3.115 2.0031-TEPA 2.039 2.628 5.427 1.366 3.512 1.934 6.530 6.472 4.096AE-DAEP 0.173 0.187 0.318 0.000 0.179 0.087 0.390 0.491 0.208AE-PEEDA 0.066 0.063 0.068 0.000 0.071 0.080 0.096 0.129 0.079iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.141 0.121 0.160 0.073 0.175 0.115 0.175 0.301 0.139BPEA 0.101 0.141 0.381 0.047 0.197 0.060 0.186 0.732 0.292Others 2.821 3.594 4.790 1.260 3.582 1.974 6.576 7.895 3.856MEA conversion, % 34.76 40.66 56.27 27.73 42.89 34.28 64.11 62.93 46.18DETA conversion, % 14.55 17.21 25.83 9.80 19.14 12.00 31.61 32.77 21.21Acyclic(N4), wt. % 97.05 96.00 95.18 97.67 96.10 96.98 92.27 91.72 95.13Acyclic(N5), wt. % 87.14 89.01 89.63 94.66 89.31 89.37 92.28 85.30 89.48.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.42 0.48 0.65 0.32 0.56 0.38 0.69 0.77 0.59Acyclic(N4)/cyclic(<=N4), 7.31 6.11 4.97 8.08 6.15 8.14 4.44 4.12 6.03weight ratio__________________________________________________________________________ Example No. 734 735 736 737 738 739 740 741 742 743__________________________________________________________________________Catalyst Type EEEE EEEE EEEE EEEE EEEE EEEE EEEE EEEE EEEE EEEECatalyst weight, gm 68.38 68.38 68.38 68.38 68.38 68.38 68.38 68.38 68.38 68.38Pressure, psig 602 602 603 602 603 603 602 603 603 603Temperature, .degree.C. 270 280 259 269 260 280 270 280 270 270Time on organics, hrs. 167.5 172.5 191.5 196.5 214.5 219.5 238.5 243.5 262.5 266Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.92 3.98 4.05 4.06 3.59 4.00 3.95 4.40 3.76 3.89DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 0.516 0.878 0.251 0.489 0.337 0.945 0.600 1.593 0.706 0.676MEA 18.745 12.739 24.769 19.980 21.647 14.371 19.473 6.716 18.311 19.235PIP 0.611 0.931 0.340 0.589 0.483 0.985 0.679 1.480 0.743 0.731DETA 47.493 41.921 53.539 49.348 49.438 44.879 48.790 36.170 47.421 48.217AEEA 2.331 1.424 2.555 2.352 2.505 1.539 2.260 0.475 2.170 2.155AEP 0.691 1.141 0.402 0.686 0.479 1.175 0.770 1.905 0.803 0.752HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.040 2.361 1.480 1.962 2.037 2.311 2.070 2.556 2.174 1.9901-TETA 9.416 11.410 6.735 8.956 8.928 10.980 9.466 13.448 10.036 9.225DAEP 0.223 0.454 0.082 0.179 0.113 0.411 0.216 0.992 0.260 0.214PEEDA 0.181 0.371 0.072 0.153 0.087 0.337 0.181 0.685 0.205 0.176DPE 0.211 0.323 0.103 0.188 0.090 0.336 0.229 0.084 0.151 0.130AE-TAEA 2.229 3.445 1.148 1.988 1.704 3.208 2.190 4.698 2.609 2.2551-TEPA 4.517 6.679 2.110 3.632 3.226 6.048 4.274 8.949 4.512 4.130AE-DAEP 0.250 0.419 0.072 0.068 0.065 0.302 0.149 0.729 0.156 0.129AE-PEEDA 0.091 0.113 0.055 0.000 0.051 0.055 0.000 0.083 0.027 0.026iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.100 0.642 0.059 0.074 0.169 0.596 0.296 0.104 0.073 0.070BPEA 0.316 0.649 0.081 0.221 0.152 0.558 0.257 0.781 0.053 0.056Others 4.550 5.879 1.898 3.066 1.779 4.582 3.140 7.552 4.192 3.803MEA conversion, % 49.40 65.33 32.69 45.43 40.15 61.44 47.63 81.50 50.64 47.61DETA conversion, % 23.81 32.19 13.53 19.90 18.77 28.43 22.01 40.80 24.03 21.95Acyclic(N4), wt. % 94.90 92.30 96.97 95.46 97.43 92.46 94.85 90.08 95.20 95.57Acyclic(N5), wt. % 89.91 84.74 92.45 93.93 91.87 85.96 90.20 88.94 95.85 95.78.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.62 0.80 0.42 0.52 0.48 0.75 0.59 0.86 0.58 0.57Acyclic(N4)/cyclic(<=N4), 5.98 4.28 8.23 6.09 8.76 4.10 5.56 3.11 5.65 5.60weight ratio__________________________________________________________________________ TABLE LXXVI__________________________________________________________________________ Example No. 744 745 746 747 748 749 750 751 752__________________________________________________________________________Catalyst Type FFFF FFFF FFFF FFFF FFFF FFFF FFFF FFFF FFFFCatalyst weight, gm 73.5 73.5 73.5 73.5 73.5 73.5 73.5 73.5 73.5Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 271.8 270 280.2 260.9 270.6 261.2 281.5 270 270Time on organics, hrs. 5 8.5 25 30 34 49 55 76 78Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.58 4.68 4.69 4.82 4.64 4.33 4.30 4.25 4.63DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product compositionwt. %EDA 1.589 2.650 2.164 0.505 0.958 0.544 2.028 0.834 1.373MEA 12.185 10.223 10.619 22.868 16.851 21.648 7.865 11.872 15.153PIP 1.766 1.979 2.007 0.826 1.277 0.872 2.020 1.302 1.673DETA 50.183 46.166 46.617 54.246 49.991 54.106 39.033 47.518 46.832AEEA 0.119 0.000 0.000 0.956 0.608 1.198 0.102 0.526 0.540AEP 2.179 2.940 2.249 0.787 1.410 0.884 2.331 1.655 1.577HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.287 2.018 2.378 1.970 2.298 2.027 2.600 2.786 2.0921-TETA 11.888 11.231 12.228 9.216 11.514 9.474 13.657 14.189 11.667DAEP 0.650 1.480 0.908 0.125 0.263 0.142 0.136 0.460 0.271PEEDA 0.395 0.990 0.562 0.087 0.186 0.092 0.793 0.320 0.185DPE 0.000 0.079 0.082 0.000 0.000 0.000 0.063 0.000 0.000AE-TAEA 2.483 2.485 2.951 1.171 2.213 1.284 3.723 3.229 2.1781-TEPA 5.189 5.996 6.225 2.266 4.333 2.454 8.413 6.752 4.536AE-DAEP 0.456 1.010 0.453 0.000 0.214 0.000 0.650 0.175 0.435AE-PEEDA 0.128 0.369 0.129 0.000 0.181 0.000 0.200 0.000 0.419iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.131 0.143 0.206 0.000 0.132 0.000 0.735 0.194 0.412BPEA 0.097 0.158 0.137 0.000 0.160 0.000 0.654 0.211 0.541Others 0.955 2.634 1.884 0.416 0.810 0.314 3.399 0.747 2.735MEA conversion, % 67.00 72.55 71.14 37.96 54.14 41.18 78.38 67.95 58.74DETA conversion, % 19.21 26.33 24.71 12.54 19.15 12.63 36.23 23.77 24.21Acyclic(N4), wt. % 93.14 83.87 90.40 98.14 96.85 98.00 89.08 95.60 96.79Acyclic(N5), wt. % 90.43 83.47 90.84 100.00 90.50 100.00 84.43 94.51 78.79.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.56 0.64 0.63 0.30 0.51 0.32 0.79 0.59 0.60Acyclic(N4)/cyclic(<=N4), 2.84 1.77 2.51 6.13 4.40 5.78 2.57 4.54 3.71weight ratio__________________________________________________________________________ TABLE LXXVII__________________________________________________________________________ Example No. 753 754 755 756 757 758 759 760 761__________________________________________________________________________Catalyst Type GGGG GGGG GGGG GGGG GGGG GGGG GGGG GGGG GGGGCatalyst weight, gm 76.8 76.8 76.8 76.8 76.8 76.8 76.8 76.8 76.8Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 271.8 270 280.2 260.9 270.6 261.2 281.5 270 270Time on organics, hrs. 5 8.5 25 30 34 49 55 76 78Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.12 4.24 4.01 4.36 4.32 4.20 4.12 4.07 4.24DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.668 1.225 4.618 0.557 0.985 0.575 1.947 0.795 1.103MEA 20.080 14.935 10.851 24.320 17.690 22.023 6.480 10.724 12.429PIP 0.842 1.211 3.467 0.742 1.218 0.827 1.830 1.251 1.391DETA 54.453 48.042 42.353 55.896 51.741 52.738 44.334 45.995 43.281AFEA 0.451 0.313 0.139 1.169 0.760 1.449 0.113 0.560 0.651AEP 0.974 1.563 4.537 0.688 1.325 0.757 2.402 1.604 1.454HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.048 2.361 1.079 1.584 2.048 1.917 2.309 2.717 2.2721-TETA 10.507 12.537 9.182 8.077 10.742 9.822 13.034 15.283 13.463DAEP 0.193 0.511 1.628 0.101 0.256 0.153 0.989 0.531 0.365PEEDA 0.122 0.327 1.082 0.000 0.173 0.087 0.592 0.336 0.226DPE 0.000 0.000 0.152 0.000 0.000 0.000 0.071 0.000 0.000AE-TAEA 1.448 2.895 1.930 0.722 1.679 1.331 3.231 3.219 2.9961-TEPA 2.807 6.158 3.803 1.591 3.499 2.971 7.631 7.644 6.601AE-DAEP 0.000 0.383 1.217 0.000 0.082 0.000 0.605 0.208 0.516AE-PEEDA 0.000 0.091 0.346 0.000 0.000 0.000 0.174 0.000 0.418iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.211 0.255 0.000 0.095 0.000 0.622 0.212 0.696BPEA 0.000 0.119 0.152 0.000 0.089 0.000 0.573 0.168 0.136Others 0.356 1.079 3.709 0.353 0.618 0.261 2.961 0.934 4.252MEA conversion, % 45.60 59.89 70.22 33.93 51.41 40.05 82.26 70.97 66.33DETA conversion, % 12.33 23.33 30.92 9.75 15.54 14.68 27.88 26.01 30.31Acyclic(N4), wt. % 97.56 94.68 78.19 98.96 96.75 97.99 90.27 95.40 96.38Acyclic(N5), wt. % 100.00 91.84 74.42 100.00 95.12 100.00 84.62 94.86 84.46.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.33 0.63 0.59 0.24 0.41 0.36 0.76 0.61 0.70Acyclic(N4)/cyclic(<=N4), 5.89 4.12 0.94 6.31 4.30 6.43 2.61 4.84 4.58weight ratio__________________________________________________________________________ TABLE LXXVIII__________________________________________________________________________ Example No. 762 763 764 765 766 767 768 769__________________________________________________________________________Catalyst Type HHHH HHHH HHHH HHHH HHHH HHHH HHHH HHHHCatalyst weight, gm 76.9 76.9 76.9 76.9 76.9 76.9 76.9 76.9Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 274.4 274.4 280.9 259.8 270.6 259.9 281.6 270.4Time on organics, hrs. 22 26 45.5 50.5 69 74.5 95 119Duration of run, hrs. 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.43 3.31 2.85 3.38 3.41 3.28 3.10 3.37DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.637 1.752 6.215 1.030 1.705 0.900 2.931 2.193MEA 11.346 11.171 3.117 18.167 8.987 15.534 1.812 8.349PIP 0.000 1.648 4.753 1.076 1.772 1.117 2.704 1.830DETA 46.167 45.574 31.042 48.855 44.146 47.263 56.512 40.724AEEA 0.707 0.779 0.145 2.493 0.622 2.337 0.000 0.571AEP 1.861 1.810 7.515 1.125 2.031 1.205 4.394 2.315HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.681 2.785 1.354 2.334 2.745 2.609 1.349 2.5591-TETA 14.827 14.769 9.178 13.329 15.519 14.514 14.115 14.634DAEP 0.707 0.684 3.204 0.266 0.862 0.288 1.482 1.224PEEDA 0.445 0.480 2.063 0.161 0.535 0.170 0.741 0.805DPE 0.104 0.070 0.140 0.000 0.097 0.000 0.000 0.048AE-TAEA 2.754 2.700 1.519 1.536 2.882 1.909 0.548 2.6241-TEPA 6.335 6.366 3.932 3.904 7.086 4.851 1.430 7.214AE-DAEP 0.241 0.242 1.881 0.138 0.283 0.068 0.260 0.638AE-PEEDA 0.079 0.075 0.401 0.000 0.087 0.000 0.000 0.188iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.420 0.000 0.205 0.042 0.000 0.216BPEA 0.223 0.231 0.079 0.000 0.239 0.045 0.000 0.261Others 1.726 1.594 11.423 0.487 1.637 0.517 0.425 2.538MEA conversion, % 69.01 69.88 91.52 51.10 75.61 57.80 94.97 76.78DETA conversion, % 25.06 26.98 49.81 21.84 28.79 23.70 6.73 32.70Acyclic(N4), wt. % 93.31 93.43 66.08 97.35 92.43 97.40 87.43 89.22Acyclic(N5), wt. % 94.36 94.30 66.22 97.52 92.46 97.75 88.40 88.31.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.51 0.51 0.52 0.35 0.55 0.39 0.13 0.58Acyclic(N4)/cyclic(<=N4), 5.62 3.74 0.60 5.96 3.45 6.16 1.66 2.76weight ratio__________________________________________________________________________ TABLE LXXIX__________________________________________________________________________ Example No. 770 771 772 773 774 775 776__________________________________________________________________________Catalyst Type IIII IIII IIII IIII IIII IIII IIIICatalyst weight, gm 79.56 79.56 79.56 79.56 79.56 79.56 79.56Pressure, psig 602 602 603 602 602 603 603Temperature, .degree.C. 268.2 270 280 258 270 279.6 269.3Time on organics, hrs. 24 4.5 29 48 72 77 96.25Duration of run, hrs. 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 1.40 2.14 0.94 0.90 2.37 1.20 0.78DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.357 2.006 4.277 2.306 1.090 3.199 2.846MEA 3.284 1.883 0.923 5.261 9.399 1.511 0.959PIP 1.251 1.346 2.162 1.382 0.869 1.861 1.707DETA 35.076 34.162 23.951 32.591 36.463 29.869 26.799AEEA 0.000 0.000 0.254 1.603 1.807 0.455 0.394AEP 2.193 2.794 3.951 1.914 1.135 3.122 2.893HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.772 3.324 1.853 2.782 2.789 2.443 2.4341-TETA 17.464 21.229 13.658 16.596 14.933 15.761 14.689DAEP 1.240 1.560 2.447 0.995 0.521 1.740 1.700PEEDA 0.891 1.074 0.289 0.699 0.388 0.125 0.247DPE 0.000 0.000 0.355 0.262 0.143 0.157 0.291AE-TAEA 4.199 5.092 0.220 4.454 4.587 4.487 4.7431-TEPA 9.456 11.417 10.338 9.746 8.931 11.169 10.912AE-DAEP 0.765 0.809 0.324 0.167 0.134 0.189 0.259AE-PEEDA 0.060 0.064 0.193 0.141 0.097 0.112 0.175iAE-PEEDA 0.278 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.242 0.496 0.187 0.158 0.174 0.433BPEA 0.000 0.000 0.734 0.667 0.692 0.754 0.232Others 6.124 6.280 20.326 8.645 7.394 10.911 15.928MEA conversion, % 90.76 95.12 97.45 85.78 74.59 95.86 97.37DETA conversion, % 41.33 47.41 60.62 47.66 41.42 51.33 56.29Acyclic(N4), wt. % 90.47 90.31 83.39 90.83 94.39 90.00 88.44Acyclic(N5), wt. % 92.53 93.67 85.81 92.43 92.59 92.72 93.44.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.66 0.65 0.66 0.72 0.78 0.83 0.87Acyclic(N4)/cyclic(<=N4), 3.63 3.62 1.69 3.69 5.80 2.60 2.50weight ratio__________________________________________________________________________ TABLE LXXX__________________________________________________________________________ Example No. 777 778 779 780 781 782 783 784__________________________________________________________________________Catalyst Type JJJJ JJJJ JJJJ JJJJ JJJJ JJJJ JJJJ JJJJCatalyst weight, gm 78.44 78.44 78.44 78.44 78.44 78.44 78.44 78.44Pressure, psig 598 598 598 598 598 598 598 598Temperature, .degree.C. 268.2 270 280 258 268 270 279.6 269.3Time on organics, hrs. 24 4 29 48 53 72 77 96.25Duration of run, hrs. 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.38 3.12 3.09 3.01 3.06 2.97 2.39 3.07DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.113 0.976 1.860 0.782 1.043 1.302 1.824 0.980MEA 10.615 12.327 5.220 14.139 10.320 9.098 6.092 8.653PIP 1.129 1.005 1.496 0.859 1.132 1.320 1.611 1.111DETA 36.799 37.931 31.746 39.773 37.334 36.528 34.990 34.182AEEA 1.033 1.258 0.344 1.844 1.311 1.136 0.541 1.124AEP 1.305 1.132 2.067 0.979 1.353 1.472 2.104 1.379HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.615 2.470 2.365 2.433 2.657 2.733 2.577 2.6121-TETA 14.292 13.515 14.587 14.440 14.597 14.582 14.930 13.465DAEP 0.594 0.489 1.269 0.296 0.595 0.603 1.041 0.647PEEDA 0.435 0.400 0.866 0.242 0.463 0.496 0.064 0.168DPE 0.131 0.135 0.159 0.052 0.133 0.092 0.091 0.150AE-TAEA 3.929 3.799 4.211 3.918 4.621 4.393 4.377 4.3571-TEPA 8.291 7.823 9.865 6.776 8.516 8.862 9.611 8.767AE-DAEP 0.503 0.527 1.032 0.400 0.502 0.089 0.121 0.177AE-PEEDA 0.099 0.115 0.175 0.082 0.088 0.060 0.083 0.122iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.163 0.228 0.356 0.253 0.153 0.091 0.117 0.297BPEA 0.610 0.599 0.845 0.412 0.618 0.748 0.798 0.729Others 7.223 7.030 12.137 4.048 6.784 6.715 8.479 10.461MEA conversion, % 71.04 66.53 86.00 61.31 72.29 75.11 83.32 76.14DETA conversion, % 40.33 38.80 49.40 35.32 40.42 40.60 43.06 43.99Acyclic(N4), wt. % 93.58 93.98 88.08 96.62 93.54 93.56 93.61 94.34Acyclic(N5), wt. % 89.89 88.77 85.39 90.32 90.62 93.07 92.60 90.83.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.75 0.77 0.86 0.68 0.79 0.77 0.81 0.85Acyclic(N4)/cyclic(<=N4), 4.70 5.06 2.89 6.95 4.69 4.35 3.57 4.66weight ratio__________________________________________________________________________ TABLE LXXXI__________________________________________________________________________ Example No. 785 786 787 788 789 790 791 792 793__________________________________________________________________________Catalyst Type KKKK KKKK KKKK KKKK KKKK KKKK KKKK KKKK KKKKCatalyst weight, gm 73.3 73.3 73.3 73.3 73.3 73.3 73.3 73.3 73.3Pressure, psig 598 603 603 605 604 604.9 604 604 604Temperature, .degree.C. 274.8 274.2 280.3 261.2 271.4 261.8 180.2 269.7 269.6Time on organics, hrs. 6 8 26 33 50 54.5 74 98.5 100Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.27 4.14 3.79 3.77 3.97 3.92 3.80 4.20 4.17DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.429 1.424 3.172 0.868 1.570 0.800 3.025 0.882 1.051MEA 14.429 13.943 9.322 21.725 13.285 20.998 6.949 13.400 14.889PIP 1.355 1.300 2.261 0.868 1.478 0.814 2.234 1.030 1.176DETA 47.230 42.295 39.568 53.087 43.212 52.672 42.607 43.225 47.069AEEA 0.550 0.512 0.197 1.245 0.559 1.274 0.098 0.676 0.823AEP 1.672 1.513 2.379 0.784 1.629 0.825 2.731 1.328 1.396HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.605 2.279 2.424 2.158 2.317 2.279 2.342 2.467 2.7391-TETA 13.001 12.670 12.814 9.683 12.889 10.389 12.621 13.828 13.069DAEP 0.431 0.360 0.995 0.154 0.368 0.187 1.128 0.319 0.360PEEDA 0.302 0.232 0.710 0.092 0.242 0.106 0.753 0.216 0.238DPE 0.000 0.000 0.075 0.000 0.000 0.000 0.089 0.000 0.000AE-TAEA 2.986 2.963 3.398 1.553 2.893 1.804 3.351 3.239 3.0921-TEPA 5.571 5.909 7.347 2.674 5.827 3.180 7.449 6.276 6.252AE-DAEP 0.181 0.442 0.599 0.000 0.449 0.000 0.673 0.454 0.145AE-PEEDA 0.000 0.529 0.187 0.000 0.476 0.000 0.202 0.384 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.352 0.757 0.645 0.089 0.811 0.084 0.585 0.601 0.363BPEA 0.223 0.550 0.560 0.093 0.574 0.076 0.109 0.674 0.300Others 1.202 3.012 3.419 0.547 3.170 0.521 3.655 3.060 1.300MEA conversion, % 61.11 61.45 74.39 41.37 63.75 43.71 81.09 63.56 60.17DETA conversion, % 24.34 30.49 35.40 14.85 29.93 16.08 31.11 30.14 25.17Acyclic(N4), wt. % 95.51 96.19 89.54 97.97 96.15 97.74 88.37 96.82 96.36Acyclic(N5), wt. % 91.88 79.57 84.37 95.88 79.06 96.89 87.32 81.83 92.04.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.57 0.72 0.75 0.36 0.70 0.40 0.73 0.69 0.62Acyclic(N4)/cyclic(<=N4), 4.15 4.39 2.37 6.24 4.09 6.56 2.16 5.63 4.99weight ratio__________________________________________________________________________ TABLE LXXXII__________________________________________________________________________ Example No. 794 795 796 797 798 799 800 801 802__________________________________________________________________________Catalyst Type LLLL LLLL LLLL LLLL LLLL LLLL LLLL LLLL LLLLCatalyst weight, gm 78.4 78.4 78.4 78.4 78.4 78.4 78.4 78.4 78.4Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.3 269.2 279.4 258.8 269.2 259.4 279.2 268.9 269.6Time on organics, hrs. 23.5 27.5 47 52 71 76 95 100 120Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.21 3.22 3.15 3.26 3.16 3.28 2.60 3.20 2.85DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 2.011 1.726 3.400 1.045 1.704 2.927 2.694 1.875 2.016MEA 19.645 19.830 10.922 24.936 17.747 13.549 6.399 19.549 17.740PIP 1.597 1.489 2.412 0.797 1.531 2.082 2.206 1.710 1.570DETA 49.999 49.815 44.929 54.559 49.660 43.523 37.413 49.063 49.599AEEA 0.269 0.305 0.156 0.448 0.288 0.213 0.000 0.288 0.481AEP 1.525 1.493 2.688 0.754 1.573 3.273 2.897 1.565 1.777HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.104 2.144 2.134 1.661 2.231 4.370 1.861 2.034 2.0611-TETA 9.952 10.859 11.222 7.684 10.454 11.481 11.542 9.840 10.021DAEP 0.081 0.238 1.038 0.095 0.470 1.096 1.664 0.680 0.442PEEDA 0.215 0.153 0.603 0.062 0.241 0.388 1.166 0.368 0.000DPE 0.000 0.000 0.051 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 0.000 0.000 0.000 0.000 0.000 4.286 4.233 0.000 1.8831-TEPA 1.592 1.629 2.342 0.742 1.760 4.935 8.341 1.975 2.969AE-DAEP 0.000 0.168 0.443 0.077 0.178 0.160 1.448 0.296 0.000AE-PEEDA 0.160 0.000 0.095 0.000 0.069 0.000 0.614 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.066 0.073 0.204 0.051 0.268 0.089 0.503 0.000 0.000BPEA 0.000 0.000 0.076 0.000 0.000 0.000 0.496 0.000 0.000Others 3.564 3.489 6.276 2.170 3.688 1.449 6.241 2.737 0.000MEA conversion, % 45.57 45.47 69.23 31.62 50.63 63.79 82.59 45.48 49.85DETA conversion, % 17.68 18.59 24.77 11.08 17.90 30.86 39.50 18.68 16.68Acyclic(N4), wt. % 97.60 97.08 88.75 98.34 94.69 91.44 82.57 91.89 96.47Acyclic(N5), wt. % 87.57 87.12 74.10 85.31 77.39 97.37 80.42 86.95 100.00.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.15 0.14 0.21 0.09 0.17 0.55 0.96 0.18 0.39Acyclic(N4)/cyclic(<=N4), 3.53 3.86 1.97 5.47 3.33 2.32 1.69 2.75 3.19weight ratio__________________________________________________________________________ TABLE LXXXIII__________________________________________________________________________ Example No. 803 804 805 806 807 808 809 810 811__________________________________________________________________________Catalyst Type MMMM MMMM MMMM MMMM MMMM MMMM MMMM MMMM MMMMCatalyst weight, gm 73.2 73.2 73.2 73.2 73.2 73.2 73.2 73.2 73.2Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.1 270 280.2 259.7 270.1 259.6 280 270 270Time on organics, hrs. 5 7.5 26.5 31.5 49.75 54 74 77.5 80Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.58 4.67 4.05 4.77 4.61 4.82 4.51 4.47 4.60DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.979 1.000 2.216 0.524 0.877 0.472 2.124 1.229 1.025MEA 17.990 19.335 10.087 24.701 17.662 24.119 9.596 17.400 17.389PIP 0.989 0.964 1.718 0.593 0.993 0.590 1.696 1.203 1.145DETA 50.172 53.162 45.219 55.645 50.697 55.944 45.259 49.313 51.748AEEA 0.000 0.433 0.000 1.012 0.642 1.026 0.126 0.667 0.713AEP 1.134 1.062 2.216 0.613 1.091 0.648 2.172 1.229 1.334TAEA 2.208 2.198 2.406 1.617 2.175 1.619 2.323 2.162 2.3071-TETA 9.955 10.785 12.776 7.737 10.803 7.844 12.734 10.465 11.340DAEP 0.232 0.218 0.936 0.103 0.249 0.110 0.896 0.273 0.300PEEDA 0.124 0.143 0.603 0.062 0.166 0.000 0.576 0.174 0.184DPE 0.000 0.075 0.075 0.000 0.000 0.000 0.085 0.000 0.000AE-TAEA 1.588 1.180 3.177 0.735 2.054 0.826 3.277 1.942 2.2551-TEPA 2.656 2.775 6.758 1.190 3.841 1.534 6.807 4.191 4.651AE-DAEP 0.114 0.097 0.606 0.000 0.000 0.000 0.525 0.086 0.106AE-PEEDA 0.000 0.000 0.149 0.000 0.000 0.000 0.136 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.235 0.000 0.000 0.000 0.222 0.121 0.135BPEA 0.000 0.000 0.112 0.000 0.000 0.000 0.109 0.000 0.128Others 6.460 0.646 1.993 0.269 0.439 0.218 1.489 0.694 0.701MEA conversion, % 51.45 47.17 72.49 32.06 50.75 33.87 73.52 51.33 53.62DETA conversion, % 19.53 13.67 26.69 9.04 15.98 8.83 25.77 18.02 17.97Acyclic(N4), wt. % 97.15 97.30 90.39 98.27 96.90 98.85 90.62 96.58 96.57Acyclic(N5), wt. % 97.38 97.61 90.01 100.00 100.00 100.00 91.03 95.24 94.93.SIGMA. (N5)/.SIGMA.(N4), weight ratio 0.35 0.30 0.66 0.20 0.44 0.25 0.67 0.49 0.51Acyclic(N4)/cyclic(<=N4), 4.91 5.44 2.74 6.83 5.19 7.02 2.78 4.39 4.61weight ratio__________________________________________________________________________ TABLE LXXXIV__________________________________________________________________________Example No. 812 813 814 815 816 817 818 819 820__________________________________________________________________________Catalyst Type NNNN NNNN NNNN NNNN NNNN NNNN NNNN NNNN NNNNCatalyst weight, gm 76.6 76.6 76.6 76.6 76.6 76.6 76.6 76.6 76.6Pressure, psig 597 599 594 596 597 598 598 578 592Temperature, .degree.C. 274.8 274.2 280.3 261.2 271.4 261.8 280.2 269.7 269.6Time on organics, hrs. 6 8 26 33 50 54.5 74 98.5 100Duration of run, hrs. 2 2 2 2 2 2 2 1.5 1.5MEA SV, gmol/hr/kgcat 3.47 3.41 3.15 3.08 3.28 3.12 3.05 3.41 3.47DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 2.061 2.011 3.148 1.184 2.307 1.307 3.298 4.426 1.702MEA 11.521 11.310 6.396 20.282 13.265 20.615 5.659 11.296 14.677PIP 1.527 1.470 2.157 0.932 1.702 0.989 2.146 3.452 1.419DETA 42.334 40.741 38.310 49.435 42.179 50.484 37.713 34.699 46.940AEEA 0.171 0.229 0.345 1.161 0.498 1.159 0.000 0.094 0.619AEP 2.239 2.094 3.230 0.922 1.874 0.956 3.141 5.456 1.744HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.485 2.769 2.228 2.289 2.411 2.243 1.952 1.031 2.4731-TETA 13.469 14.759 13.494 11.956 12.180 10.324 11.730 8.626 13.276DAEP 0.942 0.959 1.643 0.249 0.703 0.219 1.537 2.523 0.455PEEDA 0.758 0.783 1.241 0.150 0.500 0.132 1.082 1.975 0.332DPE 0.099 0.097 0.135 0.000 0.076 0.000 0.130 0.128 0.000AE-TAEA 3.476 3.863 3.743 2.042 3.220 1.844 3.286 1.977 3.0251-TEPA 6.876 7.762 8.263 3.497 6.138 3.258 7.403 4.058 5.508AE-DAEP 0.571 0.509 1.049 0.000 0.355 0.000 1.086 2.356 0.367AE-PEEDA 0.150 0.159 0.419 0.000 0.107 0.000 0.878 0.928 0.121iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.410 0.460 0.567 0.176 0.433 0.123 0.974 0.089 0.242BPEA 0.370 0.402 0.445 0.148 0.335 0.123 0.797 0.129 0.142Others 3.222 3.202 4.458 0.022 2.377 0.934 5.999 8.878 1.378MEA conversion, % 69.06 69.99 82.87 44.85 63.31 44.03 84.47 69.87 60.81DETA conversion, % 32.44 35.75 39.01 20.11 30.67 18.54 38.47 45.00 25.51Acyclic(N4), wt. % 89.87 90.50 83.90 97.28 91.94 97.28 83.27 67.62 95.24Acyclic(N5), wt. % 87.34 88.37 82.89 94.47 88.39 95.40 74.10 63.28 90.73.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.67 0.68 0.77 0.40 0.67 0.41 0.88 0.67 0.57Acyclic(N4)/cyclic (< = N4), 2.87 3.24 1.87 6.32 3.01 5.47 1.70 0.71 3.99weight ratio__________________________________________________________________________ TABLE LXXXV__________________________________________________________________________Example No. 821 822 823 824 825 826 827 828 829__________________________________________________________________________Catalyst Type OOOO OOOO OOOO OOOO OOOO OOOO OOOO OOOO OOOOCatalyst weight, gm 77.2 77.2 77.2 77.2 77.2 77.2 77.2 77.2 77.2Pressure, psig 606 602 603 599 605 601.3 604 605 602Temperature, .degree.C. 274.8 274.2 280.3 261.2 271.4 261.8 280.2 269.7 269.6Time on organics, hrs. 6 8 26 33 50 54.5 74 98.5 100Duration of run, hrs. 2 2 2 2 2 2 2 1.5 1.5MEA SV, gmol/hr/kgcat 3.66 3.28 3.32 3.12 3.38 3.23 3.28 3.68 3.71DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 4.605 3.886 5.431 1.582 3.133 1.518 5.888 2.090 2.159MEA 14.165 13.840 8.988 20.796 15.163 22.247 9.341 16.165 15.935PIP 2.743 2.486 3.003 1.044 1.960 1.001 3.051 1.333 1.433DETA 39.645 39.381 34.406 46.873 40.571 50.785 37.693 42.241 45.956AEEA 0.101 0.264 0.101 0.891 0.476 0.962 0.000 0.631 0.594AEP 3.421 3.180 4.196 1.218 2.294 1.114 3.834 1.851 1.880HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.671 1.753 1.198 1.910 2.183 2.023 1.193 2.292 2.4591-TETA 10.517 11.090 10.855 9.315 11.704 9.626 10.401 11.963 12.528DAEP 1.223 1.224 1.875 0.287 0.898 0.251 1.503 0.631 0.765PEEDA 1.151 1.136 1.743 0.206 0.759 0.177 1.167 0.451 0.617DPE 0.130 0.119 0.213 0.000 0.080 0.000 0.109 0.000 0.105AE-TAEA 2.230 2.468 2.555 1.718 2.775 1.629 2.507 2.873 3.1831-TEPA 5.038 5.654 6.324 3.175 5.413 2.702 5.290 5.112 5.477AE-DAEP 0.832 0.808 1.544 0.156 0.488 0.107 1.070 0.396 0.424AE-PEEDA 0.403 0.315 0.858 0.000 0.160 0.000 0.446 0.111 0.106iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.130 0.259 0.457 0.096 0.092 0.000 0.307 0.366 0.235BPEA 0.134 0.409 0.354 0.122 0.279 0.000 0.451 0.213 0.175Others 4.461 4.200 9.270 1.000 3.341 0.756 6.468 2.101 1.798MEA conversion, % 61.68 62.60 76.38 40.76 58.41 39.45 75.52 57.13 58.04DETA conversion, % 36.26 36.76 46.26 20.64 33.86 17.85 38.88 26.66 28.09Acyclic(N4), wt. % 82.96 83.82 75.88 95.80 88.88 96.46 80.67 92.94 90.97Acyclic(N5), wt. % 82.90 81.94 73.43 92.89 88.93 97.60 77.42 88.03 90.21.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.60 0.65 0.76 0.45 0.59 0.37 0.70 0.59 0.58Acyclic(N4)/cyclic (< = N4), 1.41 1.58 1.09 4.07 2.32 4.58 1.20 3.34 3.12weight ratio__________________________________________________________________________ TABLE LXXXVI__________________________________________________________________________Example No. 830 831 832 833 834 835 836 837 838__________________________________________________________________________Catalyst Type PPPP PPPP PPPP PPPP PPPP PPPP PPPP PPPP PPPPCatalyst weight, gm 74.1 74.1 74.1 74.1 74.1 74.1 74.1 74.1 74.1Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.1 270 280.2 259.7 270.1 259.6 280 270 270Time on organics, hrs. 5 7.5 26.5 31.5 49.75 54 74 77.5 80Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.32 4.45 3.86 4.75 4.55 4.76 4.72 4.88 4.68DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 0.799 0.893 2.371 0.614 1.122 0.619 1.998 0.866 1.017MEA 16.923 18.142 8.959 23.814 16.116 25.054 10.110 16.161 17.198PIP 1.117 1.135 0.000 0.764 1.371 0.835 1.977 1.209 1.356DETA 50.969 52.494 43.962 55.309 48.689 54.390 47.265 50.840 51.369AEEA 0.000 0.655 0.113 1.240 0.695 1.219 0.126 0.812 0.802AEP 1.445 1.273 2.405 0.656 1.488 0.655 2.444 1.326 1.362HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.361 2.414 2.424 1.705 2.211 1.553 2.474 2.443 2.3191-TETA 10.806 11.071 12.003 8.100 10.604 7.390 12.128 11.857 11.027DAEP 0.223 0.211 1.034 0.102 0.328 0.101 0.788 0.287 0.268PEEDA 0.000 0.150 0.742 0.000 0.209 0.000 0.537 0.199 0.180DPE 0.000 0.000 0.122 0.000 0.000 0.000 0.109 0.000 0.000AE-TAEA 1.975 1.711 2.755 0.748 2.130 0.714 2.508 2.424 1.8701-TEPA 3.599 3.260 6.223 1.444 4.940 1.373 5.742 5.006 3.901AE-DAEP 0.249 0.000 0.609 0.000 0.099 0.000 0.378 0.000 0.000AE-PEEDA 0.508 0.000 0.659 0.000 0.000 0.000 0.116 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.236 0.000 0.800 0.000 0.118 0.000 0.334 0.140 0.099BPEA 0.164 0.000 0.533 0.000 0.126 0.000 0.204 0.121 0.116Others 2.605 0.440 4.535 0.205 0.635 0.218 1.962 0.607 0.694MEA conversion, % 54.25 50.54 75.37 34.57 54.94 30.55 72.30 56.49 53.15DETA conversion, % 18.10 14.95 28.17 9.69 19.10 10.39 23.03 18.65 16.84Acyclic(N4), wt. % 98.33 97.39 88.38 98.97 95.98 98.88 91.06 96.71 96.75Acyclic(N5), wt. % 82.81 100.00 77.54 100.00 95.38 100.00 88.88 96.60 96.42.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.50 0.36 0.71 0.22 0.56 0.23 0.58 0.52 0.43Acyclic(N4)/cyclic (< = N4), 4.73 4.87 3.35 6.44 3.77 5.62 2.58 4.73 4.21weight ratio__________________________________________________________________________ TABLE LXXXVII__________________________________________________________________________Example No. 839 840 841 842 843 844 845 846 847__________________________________________________________________________Catalyst Type QQQQ QQQQ QQQQ QQQQ QQQQ QQQQ QQQQ QQQQ QQQQCatalyst weight, gm 78.9 78.9 78.9 78.9 78.9 78.9 78.9 78.9 78.9Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.3 270.8 280.9 259.5 270.8 261.4 282.6 273.4 270.8Time on organics, hrs. 4 7 26 31 50 55 74 79 99.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.12 3.22 3.28 3.33 3.43 3.59 3.37 3.31 3.46DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 1.169 1.189 2.230 1.402 1.099 0.671 1.752 0.918 1.448MEA 15.817 15.231 6.402 28.485 16.384 22.977 5.783 12.331 15.301PIP 1.664 1.609 2.315 1.465 1.764 1.139 2.015 1.420 1.843DETA 52.256 51.487 43.212 53.634 51.751 53.055 43.336 47.964 50.154AEEA 0.283 0.283 0.000 1.094 0.153 0.886 0.000 0.400 0.339AEP 1.915 1.855 2.978 0.777 1.978 1.094 2.884 1.762 2.059HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.062 2.339 1.830 0.884 2.131 1.899 2.473 2.651 2.2591-TETA 11.022 11.780 12.001 6.150 11.397 9.186 13.960 13.405 11.464DAEP 0.337 0.328 1.290 0.078 0.299 0.126 1.238 0.389 0.381PEEDA 0.207 0.217 0.927 0.046 0.186 0.076 0.763 0.288 0.260DPE 0.000 0.000 0.251 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 1.815 1.985 2.926 0.503 1.572 1.100 3.768 3.096 1.8801-TEPA 3.691 3.831 7.181 0.912 3.369 2.347 8.080 6.384 3.990AE-DAEP 0.243 0.116 1.511 0.121 0.213 0.276 0.809 0.295 0.138AE-PEEDA 0.000 0.000 0.928 0.000 0.000 0.000 0.238 0.136 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 1.302 0.000 0.106 0.156 0.212 0.000 0.537BPEA 0.000 0.000 0.709 0.000 0.000 0.000 0.505 0.127 0.377Others 0.459 0.872 2.746 0.399 0.607 0.361 2.423 0.974 1.252MEA conversion, % 56.77 58.52 82.77 22.06 55.23 37.72 84.29 66.57 58.72DETA conversion, % 15.12 16.67 30.89 12.79 15.96 14.53 30.04 22.72 19.59Acyclic(N4), wt. % 96.01 96.29 84.86 98.26 96.54 98.20 89.14 95.95 95.54Acyclic(N5), wt. % 95.76 98.04 69.43 92.12 93.94 88.86 87.04 94.45 84.81.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.42 0.40 0.89 0.21 0.38 0.34 0.74 0.60 0.48Acyclic(N4)/cyclic (< = N4), 3.17 3.52 1.78 2.97 3.20 4.55 2.38 4.16 3.02weight ratio__________________________________________________________________________ TABLE LXXXVIII__________________________________________________________________________Example No. 848 849 850 851 852 853 854 855 856__________________________________________________________________________Catalyst Type RRRR RRRR RRRR RRRR RRRR RRRR RRRR RRRR RRRRCatalyst weight, gm 75 75 75 75 75 75 75 75 75Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 271.8 270 280.2 260.9 270.6 261.2 281.5 270 270Time on organics, hrs. 5 8.5 25 30 34 49 55 76 78Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.47 4.56 4.56 4.83 4.82 4.39 4.36 4.29 4.45DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 0.810 0.695 1.728 0.496 1.051 0.606 2.250 1.081 1.235MEA 17.286 19.405 12.726 23.941 20.602 23.930 10.050 16.058 17.476PIP 0.000 0.893 1.726 0.691 1.246 0.771 1.912 1.336 1.440DETA 49.596 50.668 47.269 55.529 51.649 54.615 43.590 49.568 50.015AEEA 0.486 0.691 0.138 1.063 0.715 1.234 0.241 0.655 0.684AEP 1.371 0.938 1.974 0.669 1.231 0.731 2.221 1.449 1.413HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.260 2.121 2.389 1.786 2.157 1.878 2.470 2.355 2.1871-TETA 12.072 9.647 11.834 8.149 10.098 8.642 12.086 11.364 11.254DAEP 0.252 0.179 0.649 0.097 0.211 0.112 0.851 0.313 0.251PEEDA 0.179 0.124 0.372 0.070 0.144 0.071 0.630 0.209 0.172DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.068 0.000 0.000AE-TAEA 2.502 1.504 2.751 0.826 1.555 0.937 2.780 2.257 2.0151-TEPA 4.580 2.966 5.577 1.450 2.954 1.689 6.099 4.795 4.114AE-DAEP 0.259 0.000 0.387 0.000 0.084 0.000 0.395 0.000 0.231AE-PEEDA 0.105 0.000 0.100 0.000 0.000 0.000 0.111 0.000 0.177iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.166 0.000 0.181 0.000 0.077 0.000 0.451 0.115 0.108BPEA 0.000 0.068 0.138 0.000 0.100 0.000 0.352 0.164 0.105Others 0.756 0.599 1.252 0.294 0.726 0.304 2.563 0.790 0.884MEA conversion, % 52.45 44.86 64.94 34.49 44.04 34.90 71.93 55.92 52.53DETA conversion, % 18.91 14.44 22.61 9.70 16.62 11.71 27.65 19.14 19.26Acyclic(N4), wt. % 97.08 97.48 93.30 98.35 97.19 98.29 90.39 96.33 96.95Acyclic(N5), wt. % 93.03 98.50 91.18 100.00 94.52 100.00 87.15 96.19 90.81.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.52 0.38 0.60 0.23 0.38 0.25 0.63 0.51 0.49Acyclic(N4)/cyclic (< = N4), 7.95 5.51 3.01 6.51 4.33 6.24 2.56 4.15 4.10weight ratio__________________________________________________________________________ TABLE LXXXIX__________________________________________________________________________Example No. 857 858 859 860 861 862 863 864 865__________________________________________________________________________Catalyst Type SSSS SSSS SSSS SSSS SSSS SSSS SSSS SSSS SSSSCatalyst weight, gm 74.9 74.9 74.9 74.9 74.9 74.9 74.9 74.9 74.9Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 269.3 269.2 279.4 258.8 269.2 259.4 279.2 268.9 269.6Time on organics, hrs. 23.5 27.5 47 52 71 76 95 100 120Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.93 3.73 3.63 3.84 3.64 3.67 3.53 3.56 3.35DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 0.980 0.906 2.141 0.568 1.040 0.888 2.069 1.289 1.356MEA 20.085 19.419 12.916 27.282 20.217 25.518 12.998 22.393 20.330PIP 1.509 1.448 2.211 0.850 1.624 0.922 2.027 1.573 1.718DETA 52.434 51.557 46.545 55.689 52.087 54.254 47.895 52.707 52.473AEEA 0.262 0.255 0.178 0.429 0.220 0.421 0.000 0.268 0.263AEP 1.402 1.413 2.106 0.696 1.428 0.823 2.307 1.348 1.537HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.988 2.084 2.094 1.374 1.867 1.680 1.920 1.733 1.9441-TETA 9.493 9.950 10.311 6.413 8.947 7.890 9.728 7.823 8.760DAEP 0.173 0.198 0.645 0.058 0.382 0.275 0.714 0.279 0.373PEEDA 0.127 0.146 0.460 0.052 0.150 0.192 0.328 0.000 0.000DPE 0.000 0.000 0.056 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.0001-TEPA 1.257 1.371 2.257 0.448 1.195 0.801 2.316 0.979 1.375AE-DAEP 0.000 0.292 0.334 0.000 0.091 0.104 0.624 0.000 0.000AE-PEEDA 0.084 0.135 0.070 0.000 0.000 0.000 0.485 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.208 0.779 1.181 0.000 0.365 0.281 0.490 0.000 0.365BPEA 0.000 0.000 0.287 0.000 0.000 0.000 0.631 0.000 0.000Others 2.920 3.097 5.689 1.582 2.587 1.652 6.070 1.507 2.305MEA conversion, % 44.42 46.57 63.21 25.08 43.62 30.56 63.95 36.84 43.63DETA conversion, % 13.76 15.69 21.21 9.11 13.68 12.26 21.06 11.65 13.54Acyclic(N4), wt. % 97.46 97.22 91.45 98.61 95.31 95.35 91.79 97.16 96.64Acyclic(N5), wt. % 81.13 53.17 72.13 100.00 72.41 67.51 50.94 100.00 79.03.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.13 0.21 0.23 0.06 0.15 0.12 0.36 0.10 0.16Acyclic(N4)/cyclic (< = N4), 3.58 3.76 2.26 4.70 3.02 4.33 2.17 2.99 2.95weight ratio__________________________________________________________________________ TABLE XC__________________________________________________________________________Example No. 866 867 868 869 870 871 872 873 874__________________________________________________________________________Catalyst Type TTTT TTTT TTTT TTTT TTTT TTTT TTTT TTTT TTTTCatalyst weight, gm 77.1 77.1 77.1 77.1 77.1 77.1 77.1 77.1 77.1Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 270.3 270.8 280.9 259.5 270.8 261.4 282.6 272.4 270.8Time on organics, hrs. 4 7 26 31 50 55 74 79 99.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.57 3.84 3.80 3.90 4.07 4.29 4.00 4.02 4.09DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 1.064 1.067 2.949 1.044 1.126 0.634 1.319 0.655 0.856MEA 19.737 20.664 15.833 33.488 22.772 28.669 10.428 16.261 18.470PIP 1.010 1.060 2.508 1.029 1.433 0.868 1.591 0.964 1.166DETA 52.528 52.478 47.832 54.061 52.460 55.001 46.963 50.475 53.782AEEA 0.618 0.649 0.219 0.981 0.066 1.055 0.134 0.751 0.219AEP 1.111 1.092 2.117 0.537 1.255 0.600 2.045 1.283 1.400HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.982 1.964 1.306 0.527 1.836 1.309 2.590 2.505 2.0821-TETA 10.911 10.012 8.857 4.302 9.388 6.368 13.545 12.661 10.355DAEP 0.183 0.172 0.652 0.031 0.165 0.065 0.739 0.233 0.193PEEDA 0.134 0.122 0.487 0.000 0.108 0.000 0.478 0.186 0.154DPE 0.000 0.000 0.321 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 1.065 1.592 1.529 0.149 0.830 0.433 3.290 2.387 1.4781-TEPA 2.728 3.034 2.962 0.125 2.166 0.748 6.467 4.760 2.918AE-DAEP 0.123 0.000 0.376 0.000 0.049 0.125 0.366 0.110 0.086AE-PEEDA 0.000 0.000 0.218 0.000 0.000 0.000 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.142 0.198 0.600 0.000 0.000 0.000 0.151 0.105 0.000BPEA 0.000 0.000 0.310 0.000 0.000 0.000 0.157 0.065 0.000Others 0.983 0.675 2.785 0.347 1.245 0.414 1.358 0.510 1.052MEA conversion, % 46.25 43.91 56.39 7.91 37.98 21.73 71.61 56.02 49.81DETA conversion, % 14.98 15.34 21.70 11.65 15.09 10.85 24.02 18.86 13.13Acyclic(N4), wt. % 97.60 97.60 87.44 99.35 97.63 99.16 92.99 97.31 97.29Acyclic(N5), wt. % 93.48 95.89 74.91 100.00 98.39 90.46 93.53 96.24 98.09.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.31 0.39 0.52 0.06 0.26 0.17 0.60 0.48 0.35Acyclic(N4)/cyclic (< = N4), 5.29 4.89 1.67 3.02 3.79 5.01 3.32 5.69 4.27weight ratio__________________________________________________________________________ TABLE XCI__________________________________________________________________________Example No. 875 876 877 878 879 880 881 882 883__________________________________________________________________________Catalyst Type UUUU UUUU UUUU UUUU UUUU UUUU UUUU UUUU UUUUCatalyst weight, gm 89.1 89.1 89.1 89.1 89.1 89.1 89.1 89.1 89.1Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 274.4 274.4 280.9 259.8 270.6 259.9 281.6 270.4 270.4Time on organics, hrs. 22 26 45.5 50.5 69 74.5 95 119 120Duration of run, hrs. 2 2 2 2 2 2 2 1 1MEA SV, gmol/hr/kgcat 3.54 3.49 3.26 3.62 3.67 3.54 3.50 7.34 3.64DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 2.720 2.147 6.050 1.506 2.063 0.510 4.522 1.700 1.717MEA 17.172 17.646 11.090 24.376 18.880 23.711 12.670 19.091 19.532PIP 3.605 3.285 6.865 1.922 2.983 1.500 5.411 2.536 2.650DETA 45.019 47.846 36.936 51.126 46.069 60.718 38.319 46.051 46.810AEEA 1.105 0.896 0.266 2.671 1.310 1.103 0.484 1.774 1.241AEP 2.925 2.891 6.159 1.195 2.402 1.058 4.968 2.089 2.120HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.209 0.424 0.376 0.813 1.233 0.599 0.517 1.195 0.7821-TETA 10.239 10.478 8.946 8.826 10.269 6.805 9.581 9.683 9.534DAEP 0.772 0.760 1.868 0.178 0.640 0.127 1.531 0.559 0.548PEEDA 0.840 0.880 2.576 0.170 0.724 0.140 2.159 0.624 0.603DPE 0.041 0.054 0.072 0.000 0.086 0.000 0.101 0.052 0.032AE-TAEA 0.934 0.596 0.549 0.231 0.979 0.000 0.711 0.904 0.7881-TEPA 4.738 4.381 4.535 2.107 4.687 0.000 5.357 4.353 4.151AE-DAEP 0.398 0.278 1.152 0.049 0.262 0.000 0.969 0.257 0.237AE-PEEDA 0.126 0.129 0.254 0.000 0.115 0.000 0.235 0.109 0.104iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.047 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 1.657 1.439 3.878 0.448 1.598 0.000 3.154 1.704 1.370MEA conversion, % 53.55 52.50 70.19 33.82 49.12 35.88 65.36 47.50 45.94DETA conversion, % 27.63 23.46 41.00 17.51 26.21 2.41 37.74 24.74 23.00Acyclic(N4), % 87.38 86.56 67.36 96.51 88.80 96.51 72.70 89.80 89.71Acyclic(N5), % 91.53 92.44 77.77 97.93 93.75 0.00 83.44 93.50 93.54.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.47 0.43 0.47 0.24 0.47 0.00 0.52 0.46 0.46Acyclic(N4)/cyclic (< = N4), 1.40 1.39 0.53 2.78 1.68 2.61 0.71 1.86 1.73weight ratio__________________________________________________________________________ TABLE XCII__________________________________________________________________________Example No. 884 885 886 887 888 889 890 891 892__________________________________________________________________________Catalyst Type VVVV VVVV VVVV VVVV VVVV VVVV VVVV VVVV VVVVCatalyst weight, gm 91.7 91.7 91.7 91.7 91.7 91.7 91.7 91.7 91.7Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 268.6 268.9 278.6 259.1 268.3 258.2 278.9 269 269.6Time on organics, hrs. 3 22 27 51 69.5 74 93 99 116.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 1.87 2.59 2.79 2.74 2.82 2.85 2.58 2.74 2.59DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 2.183 2.188 1.770 0.548 1.020 0.597 1.940 1.065 1.184MEA 27.641 27.702 4.345 16.309 9.520 16.119 3.529 9.960 7.884PIP 0.359 0.359 1.724 0.781 1.295 0.831 1.768 1.334 1.404DETA 50.123 50.233 32.473 45.537 37.563 44.839 30.507 38.688 35.307AEEA 1.469 1.473 0.272 2.441 0.835 2.461 0.259 0.891 0.693AEP 0.425 0.425 2.604 0.939 1.587 0.990 2.516 1.641 1.764HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.540 0.541 1.884 1.758 2.057 1.894 1.864 1.979 2.0251-TETA 5.907 5.920 14.212 13.575 13.856 13.962 13.839 13.903 13.810DAEP 0.000 0.000 1.323 0.221 0.725 0.221 1.371 0.816 0.894PEEDA 0.077 0.077 1.066 0.195 0.561 0.189 1.056 0.588 0.667DPE 0.000 0.000 0.212 0.073 0.453 0.073 0.204 0.194 0.226AE-TAEA 0.243 0.243 3.128 1.661 2.763 1.921 3.001 2.711 2.9541-TEPA 0.585 0.586 9.266 4.428 7.937 4.979 9.181 7.693 8.505AE-DAEP 0.000 0.000 1.117 0.186 0.635 0.255 1.174 0.589 0.748AE-PEEDA 0.151 0.152 0.266 0.147 0.165 0.151 0.247 0.180 0.234iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.400 0.000 0.339 0.241 0.370 0.292 0.377BPEA 0.000 0.000 0.692 0.194 0.581 0.058 0.692 0.473 0.620Others 1.677 1.680 14.327 2.888 11.047 4.339 13.830 8.942 12.375MEA conversion, % 20.18 20.18 88.44 54.92 74.73 56.63 90.23 73.20 78.90DETA conversion, % 13.97 13.97 48.67 25.19 40.75 28.30 49.82 38.12 43.84Acyclic(N4), % 98.82 98.82 86.09 96.91 90.15 97.10 85.65 90.86 89.86Acyclic(N5), % 84.54 84.54 83.35 92.03 86.19 90.74 83.07 87.15 85.28.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.15 0.15 0.80 0.42 0.70 0.47 0.80 0.68 0.76Acyclic(N4)/cyclic (< = N4), 7.50 7.50 2.32 6.94 3.44 6.91 2.27 3.47 3.20weight ratio__________________________________________________________________________ TABLE XCIII__________________________________________________________________________Example No. 893 894 895 896 897 898 899 900 901__________________________________________________________________________Catalyst Type WWWW WWWW WWWW WWWW WWWW WWWW WWWW WWWW WWWWCatalyst weight, gm 79.6 79.6 79.6 79.6 79.6 79.6 79.6 79.6 79.6Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 268.6 268.9 278.6 259.1 268.3 258.2 278.9 269 269.6Time on organics, hrs. 3 22 27 51 69.5 74 93 99 116.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.34 2.66 2.48 3.46 3.32 3.85 2.73 2.84 2.42DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 0.402 0.984 1.667 0.394 0.739 0.489 1.751 1.291 1.139MEA 15.275 9.355 3.835 17.705 9.833 17.982 3.544 9.828 6.948PIP 1.023 1.416 1.735 0.823 1.192 0.874 1.765 1.556 1.504DETA 46.636 38.050 30.559 46.962 37.022 46.771 30.103 39.458 33.830AEEA 0.563 0.635 0.229 2.288 0.818 2.437 0.237 0.909 0.647AEP 1.146 1.654 2.572 0.964 1.493 0.918 2.432 1.661 1.837HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.055 1.701 1.742 1.714 1.968 1.798 1.727 1.992 1.9651-TETA 14.353 14.398 14.401 12.742 14.026 12.801 13.949 14.704 14.368DAEP 0.249 0.654 1.412 0.204 0.702 0.176 1.305 0.678 0.917PEEDA 0.325 0.561 0.102 0.191 0.551 0.167 1.053 0.549 0.702DPE 0.121 0.297 0.229 0.068 0.281 0.065 0.214 0.195 0.339AE-TAEA 1.394 2.685 2.896 1.785 2.857 2.350 2.894 2.684 2.9501-TEPA 5.057 7.739 9.422 4.753 8.218 4.811 9.500 7.913 9.201AE-DAEP 0.509 0.622 1.153 0.165 0.574 0.183 1.120 0.446 0.733AE-PEEDA 0.114 0.112 0.260 0.085 0.186 0.082 0.318 0.112 0.220iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.157 0.184 0.396 0.088 0.450 0.068 0.417 0.000 0.374BPEA 0.332 0.572 0.676 0.225 0.581 0.214 0.673 0.443 0.631Others 4.749 7.940 13.943 2.415 10.748 2.214 13.837 6.329 12.335MEA conversion, % 58.32 74.19 89.50 51.84 73.69 51.51 90.14 73.15 81.27DETA conversion, % 26.00 37.61 50.21 24.08 41.13 25.04 50.22 35.93 45.79Acyclic(N4), % 95.68 91.41 85.48 96.90 91.24 97.28 85.90 92.15 89.29Acyclic(N5), % 85.30 87.49 83.21 92.07 86.08 92.90 83.07 91.37 86.12.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.47 0.68 0.78 0.48 0.73 0.51 0.82 0.64 0.77Acyclic(N4)/cyclic (< = N4), 5.38 3.51 2.29 6.43 3.79 6.63 2.32 3.60 3.08weight ratio__________________________________________________________________________ TABLE XCIV__________________________________________________________________________Example No. 902 903 904 905 906 907 908 909 910 911__________________________________________________________________________Catalyst Type XXXX XXXX XXXX XXXX XXXX XXXX XXXX XXXX XXXX XXXXCatalyst weight, gm 87.7 87.7 87.7 87.7 87.7 87.7 87.7 87.7 87.7 87.7Pressure, psig 603 596 606 600 600 600 607 600 590 600Temperature, .degree.C. 269 279 260 270 270 259.6 279 270 280 270Time on organics, hrs. 21 28 49 54 73.5 97.5 116 121 139 144Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 0.91 0.59 2.75 1.43 2.59 2.77 2.41 2.60 2.29 2.43DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 2.350 1.919 0.622 0.752 0.640 0.391 1.122 0.738 1.310 1.032MEA 23.993 22.805 29.044 27.951 26.940 30.561 23.577 28.244 22.626 14.670PIP 0.625 0.683 0.215 0.276 0.295 0.203 0.700 0.146 0.834 1.073DETA 52.709 52.718 55.792 52.407 51.421 56.953 49.965 55.022 49.613 43.078AEEA 0.839 0.906 0.676 0.848 0.865 0.965 0.936 1.077 0.953 1.870AEP 0.670 0.712 0.316 0.322 0.328 0.257 0.586 0.387 0.639 1.002HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.188 1.399 0.875 0.858 0.973 0.696 1.543 1.161 1.716 2.4081-TETA 5.320 6.386 4.275 4.119 4.573 3.717 7.655 5.591 8.550 11.687DAEP 0.347 0.266 0.123 0.104 0.092 0.061 0.191 0.106 0.224 0.280PEEDA 0.057 0.170 0.083 0.060 0.058 0.038 0.023 0.067 0.028 0.239DPE 0.083 0.083 0.030 0.034 0.035 0.027 0.067 0.045 0.075 0.094AE-TAEA 0.899 0.988 0.607 0.509 0.572 0.374 0.052 0.789 1.664 3.0611-TEPA 1.485 1.792 1.076 0.867 0.939 0.666 2.604 1.419 3.031 5.965AE-DAEP 0.280 0.202 0.116 0.085 0.000 0.035 0.142 0.084 0.162 0.312AE-PEEDA 0.108 0.080 0.000 0.033 0.069 0.000 0.000 0.035 0.042 0.048iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.043 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.146BPEA 0.107 0.106 0.059 0.022 0.081 0.000 0.175 0.080 0.210 0.374Others 2.935 3.026 0.992 0.725 0.939 0.685 3.151 0.949 2.575 3.282MEA Conversion, % 33.53 37.20 19.34 18.02 20.14 15.44 33.80 22.92 37.97 59.15DETA Conversion, % 13.21 13.72 7.91 8.64 9.40 6.34 16.63 10.76 19.16 28.71Acyclic(N4), % 93.03 93.76 95.63 96.18 96.79 97.22 97.03 96.87 96.92 95.83Acyclic(N5), % 81.55 87.74 90.59 90.79 90.93 96.73 89.33 91.76 91.91 91.11.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.42 0.38 0.34 0.29 0.29 0.24 0.31 0.35 0.48 0.67Acyclic(N4)/cyclic 3.65 4.07 6.72 6.26 6.87 7.52 5.87 6.61 5.71 5.24__________________________________________________________________________ TABLE XCV__________________________________________________________________________Example No. 912 913 914 915 916 917 918 919 920 921__________________________________________________________________________Catalyst Type YYYY YYYY YYYY YYYY YYYY YYYY YYYY YYYY YYYY YYYYCatalyst weight, gm 83.01 83.01 83.01 83.01 83.01 83.01 83.01 83.01 83.01 83.01Pressure, psig 603 596 599 599 601 597 603 603 602 603Temperature, .degree.C. 271 278 260 271 260 280 270 280 270 270Time on organics, hrs. 99 104 123 128 147 152 171 176 195 206.75MEA SV, gmol/hr/kgcat 3.13 3.33 3.26 3.20 3.18 3.07 2.34 2.47 2.21 2.35DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.984 2.995 1.212 1.766 1.149 2.885 1.710 2.748 1.423 1.500MEA 6.383 3.073 13.003 5.647 11.598 3.611 10.193 5.664 10.816 11.721PIP 1.434 1.763 1.183 1.449 1.142 1.861 1.330 1.727 1.168 1.186DETA 32.000 30.373 38.190 32.197 37.489 30.866 31.155 29.136 31.286 32.092AEEA 0.501 0.186 1.296 0.439 1.265 0.220 0.847 0.403 0.987 1.078AEP 1.636 2.525 1.050 1.785 1.133 2.307 1.524 2.483 1.278 1.244HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.376 1.934 2.312 2.434 2.613 2.044 2.151 1.797 2.071 2.1401-TETA 12.940 12.003 11.840 13.576 13.452 12.217 10.663 10.795 10.563 10.796DAEP 0.920 1.655 0.439 1.079 0.545 1.534 0.822 1.573 0.617 0.608PEEDA 0.665 1.233 0.355 0.842 0.415 1.110 0.628 1.133 0.479 0.498DPE 0.287 0.120 0.230 0.316 0.181 0.104 0.063 0.089 0.229 0.044AE-TAEA 4.489 3.831 3.705 4.743 4.293 4.176 3.815 3.271 3.526 3.5751-TEPA 9.472 9.488 7.999 10.201 8.828 9.980 8.349 8.770 7.873 7.613AE-DAEP 0.811 1.698 0.463 0.927 0.392 1.458 0.759 1.596 0.624 0.664AE-PEEDA 0.148 0.223 0.123 0.165 0.067 0.216 0.150 0.128 0.081 0.078iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.151 0.482 0.201 0.162 0.057 0.283 0.193 0.229 0.390 0.325BPEA 0.149 0.853 0.178 0.215 0.057 0.232 0.082 0.655 0.601 0.569Others 9.595 14.536 7.200 10.480 6.385 12.915 9.485 10.732 7.587 7.371MEA Conversion, % 81.81 91.66 64.27 84.42 68.27 90.05 69.91 83.37 67.11 64.89DETA Conversion, % 45.79 51.02 37.63 47.22 39.06 49.48 45.34 49.17 43.45 42.86Acyclic(N4), % 89.11 82.25 93.25 87.74 93.37 83.84 89.43 81.83 90.51 91.84Acyclic(N5), % 91.73 80.36 92.38 91.05 95.82 86.60 91.13 82.19 87.05 87.25.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.89 0.98 0.83 0.90 0.80 0.96 0.93 0.95 0.94 0.91Acyclic(N4)/cyclic 3.10 1.91 4.34 2.93 4.70 2.06 2.93 1.80 3.35 3.61(< = N4), weight ratio__________________________________________________________________________ TABLE XCVI__________________________________________________________________________Example No. 922 923 924 925 926 927 928 929 930 931 932__________________________________________________________________________Catalyst Type ZZZZ ZZZZ ZZZZ ZZZZ ZZZZ ZZZZ ZZZZ ZZZZ ZZZZ ZZZZ ZZZZCatalyst weight, gm 84.9 84.9 84.9 84.9 82.11 84.9 84.9 84.9 84.9 84.9 84.9Pressure, psig 604 604 604 604 602 604 602 603 600 600 600Temperature, .degree.C. 268 279 258 270 259 278 269 278 279 270 270Time on organics, hrs. 24.5 27.75 47 52 71 76 95 99 118.5 139.8 141.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2 1 1MEA SV, gmol/hr/kgcat 2.66 2.74 2.85 3.15 3.30 3.27 3.01 3.14 2.91 2.26 3.32DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.261 0.356 0.244 0.282 0.226 0.267 0.193 0.300 0.276 0.137 0.175MEA 32.096 31.884 33.649 33.262 34.748 33.604 35.331 34.218 33.615 33.551 33.298PIP 0.012 0.017 0.009 0.013 0.000 0.013 0.000 0.014 0.015 0.021 0.015DETA 53.034 52.823 55.550 57.167 58.160 57.340 58.631 55.561 55.690 57.452 57.445AEEA 0.039 0.072 0.023 0.200 0.054 0.089 0.039 0.073 0.075 0.063 0.067AEP 0.256 0.295 0.218 0.287 0.233 0.349 0.288 0.358 0.393 0.340 0.313HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.091 0.098 0.112 0.187 0.094 0.150 0.077 0.475 0.111 0.137 0.1711-TETA 0.144 0.122 0.087 0.577 0.076 0.434 0.092 0.000 0.343 0.416 0.498DAEP 0.024 0.031 0.016 0.056 0.000 0.021 0.000 0.067 0.044 0.030 0.027PEEDA 0.194 0.074 0.183 0.037 0.211 0.152 0.077 0.082 0.052 0.036 0.034DPE 0.069 0.085 0.053 0.027 0.094 0.065 0.061 0.044 0.047 0.082 0.055AE-TAEA 0.000 0.037 0.000 0.045 0.000 0.085 0.052 0.000 0.000 0.000 0.0001-TEPA 0.147 0.062 0.000 0.047 0.000 0.068 0.000 0.036 0.061 0.000 0.071AE-DAEP 0.000 0.000 0.000 0.000 0.024 0.060 0.027 0.091 0.114 0.028 0.000AE-PEEDA 0.000 0.168 0.000 0.000 0.000 0.000 0.000 0.041 0.000 0.129 0.332iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.039 0.000 0.053 0.035 0.162 0.044 0.031 0.092 0.099 0.097BPEA 0.344 0.000 0.000 0.000 0.000 0.038 0.000 0.000 0.000 0.000 0.066Others 1.659 2.389 1.815 2.931 1.866 3.482 2.698 3.109 3.712 2.859 2.756MEA Conversion, % 3.06 3.91 2.16 6.89 3.11 7.25 3.34 3.38 5.38 6.32 7.15DETA Conversion, % 4.80 5.39 4.00 4.90 3.62 5.94 4.67 6.76 6.84 4.67 4.80Acyclic(N4), % 44.95 53.51 44.02 86.49 35.80 71.03 54.99 71.17 76.09 78.86 85.22Acyclic(N5), % 30.60 32.37 0.00 63.66 0.00 37.00 42.32 18.14 22.79 0.00 12.61.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.92 0.75 0.00 0.16 0.13 0.50 0.40 0.30 0.45 0.36 0.72Acyclic(N4)/cyclic 0.42 0.44 0.41 1.82 0.32 0.97 0.40 0.84 0.82 1.09 1.51(< = N4), weight ratio__________________________________________________________________________ TABLE XCVII__________________________________________________________________________Example No. 933 934 935 936 937 938 939 940 941__________________________________________________________________________Catalyst Type AAAAA AAAAA AAAAA AAAAA AAAAA AAAAA AAAAA AAAAA AAAAACatalyst weight, gm 45.68 45.68 45.68 45.68 45.68 45.68 45.68 45.68 45.68Pressure, psig 600 599 607 596 600 600 600 600 604Temperature, .degree.C. 269 279 260 270 270 259.6 279 270 280Time on organics, hrs. 21 28 49 54 73.5 97.5 116 121 139Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.74 5.87 5.23 6.08 3.67 3.99 2.29 4.68 5.77DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 4.265 6.176 3.433 3.075 3.788 3.313 4.920 3.283 4.944MEA 5.796 3.354 10.079 7.161 8.233 12.638 5.859 8.995 7.083PIP 2.117 2.992 1.443 1.595 1.901 1.711 3.037 1.662 2.421DETA 28.085 21.574 33.585 28.671 28.468 35.387 22.837 31.649 26.907AEEA 0.099 0.063 0.399 0.132 0.103 0.381 0.025 0.197 0.067AEP 4.039 6.092 2.608 3.219 3.601 3.484 6.074 3.491 5.328HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 3.229 1.766 3.587 3.434 2.819 2.812 1.936 3.537 2.2411-TETA 11.677 6.932 11.244 11.553 10.261 9.480 6.501 11.947 9.241DAEP 2.387 3.807 1.767 1.907 1.991 1.653 4.685 2.133 3.545PEEDA 1.116 1.889 0.855 0.890 0.958 0.844 2.020 0.989 1.785DPE 0.174 0.405 0.101 0.132 0.139 0.113 0.580 0.315 0.262AE-TAEA 5.681 3.174 5.080 5.634 4.681 3.953 2.940 5.597 3.6771-TEPA 8.664 6.535 6.720 7.856 6.920 5.613 3.566 7.833 6.809AE-DAEP 0.935 0.738 0.803 0.708 0.722 0.579 0.757 0.823 1.937AE-PEEDA 0.258 1.129 0.214 0.198 0.223 0.219 0.904 0.272 0.737iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.055 0.256 0.050 0.037 0.048 0.047 0.237 0.050 0.057BPEA 0.975 0.822 0.665 0.847 0.688 0.813 0.350 0.801 0.858Others 8.808 15.412 6.548 7.053 6.595 5.262 19.371 7.036 12.602MEA Conversion, % 84.08 90.34 72.07 79.20 75.41 64.40 83.73 75.68 81.06DETA Conversion, % 54.16 63.06 44.68 50.52 49.47 40.75 62.31 49.14 57.23Acyclic(N4), % 80.21 58.78 84.49 83.65 80.90 82.49 53.67 81.83 67.25Acyclic(N5), % 86.58 76.69 87.20 88.29 87.35 85.23 74.32 87.34 74.50.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.89 0.86 0.77 0.85 0.82 0.75 0.56 0.81 0.82Acyclic(N4)/cyclic 1.52 0.57 2.19 1.94 1.52 1.58 0.51 1.80 0.86(< = N4), weight ratio__________________________________________________________________________ TABLE XCVIII__________________________________________________________________________Example No. 942 943 944 945 946 947 948 949 950__________________________________________________________________________Catalyst Type BBBBB BBBBB BBBBB BBBBB BBBBB BBBBB BBBBB BBBBB BBBBBCatalyst weight, gm 71.9 71.9 71.9 71.9 71.9 71.9 71.9 71.9 71.9Pressure, psig 604 604 609 606 600 600 603 602 602Temperature, .degree.C. 270 282 258 272 260 280 273 281 272Time on organics, hrs. 20.5 25.5 44.5 49.5 69.3 93.3 116.5 121.5 138.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.36 3.46 3.43 3.50 3.55 3.41 3.50 3.67 3.49DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.654 1.188 0.880 0.700 0.372 1.659 0.860 1.397 0.841MEA 26.367 22.170 24.384 27.194 29.909 21.016 27.518 23.168 26.560PIP 0.812 1.365 0.882 0.772 0.000 1.711 0.812 1.473 0.833DETA 51.269 45.690 48.835 51.840 55.476 43.224 51.818 46.089 52.002AEEA 2.016 1.702 1.570 1.900 1.779 1.481 1.827 1.619 1.976AEP 0.692 1.168 0.882 0.598 0.374 1.439 0.624 1.193 0.678HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.323 1.418 1.256 1.217 0.943 1.295 1.188 1.308 1.2161-TETA 7.359 8.836 7.770 6.793 5.048 8.777 6.824 8.418 7.095DAEP 0.163 0.347 0.300 0.112 0.071 0.485 0.130 0.370 0.143PEEDA 0.160 0.417 0.373 0.120 0.076 0.528 0.145 0.432 0.153DPE 0.046 0.069 0.061 0.042 0.025 0.114 0.046 0.034 0.050AE-TAEA 1.015 1.431 1.257 0.863 0.494 1.551 0.865 1.450 0.9231-TEPA 2.990 4.899 4.463 2.563 1.436 5.428 2.725 4.968 2.853AE-DAEP 0.242 0.305 0.326 0.045 0.074 0.345 0.060 0.264 0.065AE-PEEDA 0.106 0.077 0.079 0.000 0.000 0.094 0.062 0.187 0.038iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000BPEA 0.031 0.052 0.046 0.123 0.080 0.273 0.127 0.070 0.049Others 1.656 3.848 3.595 1.579 0.943 4.584 1.700 3.838 1.946MEA Conversion, % 29.19 48.08 35.05 26.39 18.82 42.93 26.19 38.13 28.97DETA Conversion, % 18.17 26.61 22.69 16.60 10.51 30.24 17.39 26.86 17.35Acyclic(N4), % 95.92 92.50 92.49 96.69 97.20 89.50 96.15 92.08 96.01Acyclic(N5), % 91.34 93.59 92.70 95.32 92.60 90.73 93.52 92.49 96.12.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.48 0.61 0.63 0.43 0.34 0.68 0.46 0.66 0.45Acyclic(N4)/cyclic 4.64 3.05 3.61 4.87 10.96 2.33 4.56 2.78 4.48(< = N4), weight ratio__________________________________________________________________________ TABLE XCIX__________________________________________________________________________Example No. 951 952 953 954 955 956 957 958 959__________________________________________________________________________Catalyst Type CCCCC CCCCC CCCCC CCCCC CCCCC CCCCC CCCCC CCCCC CCCCCCatalyst weight, gm 47.15 47.15 47.15 47.15 47.15 47.15 47.15 47.15 47.15Pressure, psig 603 604 597 593 600 609 600 601 601Temperature, .degree.C. 270 281 258 272 280 273 281 272 272Time on organics, hrs. 20.5 25.5 44.5 49.5 93.3 116.5 121.5 138.5 143.25Duration of run, hrs. 2 2 2 2 1 2 2 2 2MEA SV, gmol/hr/kgcat 5.62 5.50 6.38 5.77 5.23 4.89 6.12 5.90 6.45DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 4.112 6.049 3.022 3.411 5.550 3.212 4.820 3.441 2.793MEA 3.993 1.805 8.392 5.992 2.263 7.178 3.892 6.533 8.131PIP 2.090 2.764 1.493 1.835 2.928 1.697 2.331 1.856 1.521DETA 26.200 19.797 30.716 29.072 19.595 30.928 25.883 27.399 32.697AEEA 0.105 0.029 0.466 0.193 0.059 0.257 0.082 0.253 0.337AEP 3.816 5.459 2.748 3.098 5.455 2.783 4.440 3.792 2.683HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 3.246 1.816 3.371 3.690 1.636 3.637 1.211 3.154 3.6571-TETA 12.248 7.991 11.446 12.890 7.985 12.535 9.944 11.428 12.152DAEP 2.327 3.836 1.908 1.821 3.625 1.607 2.852 2.506 1.457PEEDA 1.147 2.001 1.029 0.933 1.998 0.854 1.534 1.473 0.870DPE 0.205 0.259 0.072 0.159 0.343 0.212 0.287 0.292 0.199AE-TAEA 5.841 3.653 5.224 6.189 3.051 6.144 4.652 4.999 5.5661-TEPA 9.617 6.279 8.218 9.146 4.846 8.976 8.411 7.886 8.254AE-DAEP 1.138 2.226 1.270 0.744 0.976 0.196 0.637 0.703 0.282AE-PEEDA 0.133 0.798 0.566 0.032 1.236 0.237 0.789 0.817 0.091iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.198 0.335 0.262 0.062 0.124 0.064 0.176 0.106 0.138BPEA 0.494 1.127 0.826 0.441 0.203 1.316 1.347 1.252 1.167Others 13.100 17.605 11.271 10.063 19.810 9.418 16.332 12.551 9.604MEA Conversion, % 89.29 94.88 77.77 83.74 93.38 80.79 89.55 82.50 78.25DETA Conversion, % 58.24 66.61 51.64 53.13 65.93 50.81 58.69 56.38 48.01Acyclic(N4), % 80.81 61.67 83.12 85.06 61.73 85.82 70.48 77.35 86.22Acyclic(N5), % 88.73 68.89 82.14 92.30 75.68 89.29 81.59 81.74 89.16.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.91 0.91 0.92 0.85 0.67 0.90 1.01 0.84 0.85Acyclic(N4)/cyclic 1.62 0.68 2.04 2.11 0.67 2.26 0.97 1.47 2.35(< = N4), weight ratio__________________________________________________________________________Example No. 960 961 962 963 964 965 966 967 968__________________________________________________________________________Catalyst Type CCCCC CCCCC CCCCC CCCCC CCCCC CCCCC CCCCC CCCCC CCCCCCatalyst weight, gm 47.15 47.15 47.15 47.15 47.15 47.15 47.15 47.15 47.15Pressure, psig 603 602 601 602 596 599 600 600 600Temperature, .degree.C. 270 280 260 269 259 269 269 279.6 268Time on organics, hrs. 22.5 27.5 46.5 51.5 70.5 99.5 120 143 169.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.97 4.30 3.85 2.94 0.75 5.31 5.03 4.80 3.32DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 2.967 4.366 4.440 2.967 4.460 1.952 3.142 4.055 2.453MEA 9.344 4.942 4.115 7.299 4.769 11.879 10.054 6.454 12.691PIP 1.511 2.037 2.043 1.452 2.132 1.272 1.700 2.182 1.366DETA 31.637 26.975 25.016 30.734 25.564 38.106 32.444 26.800 38.319AEEA 0.424 0.162 0.130 0.465 0.229 0.767 0.506 0.183 0.649AEP 2.464 3.612 3.730 2.436 3.835 1.957 3.105 4.023 2.028HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 3.232 3.170 3.039 4.030 3.514 3.588 2.814 2.467 3.5441-TETA 11.069 12.118 12.039 13.420 13.075 11.521 10.058 9.825 12.044DAEP 1.231 2.138 2.332 1.243 2.045 0.861 1.515 2.269 0.889PEEDA 0.679 1.195 1.326 0.704 1.131 0.508 0.922 1.458 0.524DPE 0.187 0.300 0.338 0.255 0.476 0.141 0.254 0.309 0.124AE-TAEA 5.103 5.422 5.331 6.126 5.933 4.797 4.017 4.146 4.6101-TEPA 7.681 9.105 9.262 8.935 9.548 6.845 6.630 7.426 6.884AE-DAEP 0.028 0.438 0.477 0.260 0.377 0.367 0.846 1.348 0.370AE-PEEDA 0.645 0.119 0.143 0.119 0.141 0.096 0.119 0.616 0.106iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.437 0.190 0.276 0.126 0.050 0.048 0.028 0.092 0.029BPEA 0.997 0.316 0.321 0.381 0.328 0.593 0.605 0.273 0.533Others 6.554 13.105 14.254 9.326 11.795 5.441 9.162 13.636 4.287MEA Conversion, % 73.30 86.63 88.77 80.18 87.07 67.40 71.78 82.09 65.35DETA Conversion, % 46.27 56.62 59.43 50.41 58.82 37.84 45.87 55.81 37.82Acyclic(N4), % 87.21 80.80 79.05 88.79 81.96 90.91 82.71 75.29 91.03Acyclic(N5), % 85.85 93.18 92.31 94.44 94.53 91.34 86.95 83.25 91.71.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.91 0.82 0.83 0.81 0.81 0.77 0.79 0.85 0.73Acyclic(N4)/cyclic 2.36 1.65 1.54 2.87 1.72 3.19 1.72 1.20 3.16(< = N4), weight ratio__________________________________________________________________________ TABLE C__________________________________________________________________________Example No. 969 970 971 972 973__________________________________________________________________________Catalyst Type DDDDD DDDDD DDDDD DDDDD DDDDDCatalyst weight, gm 76.68 76.68 76.68 76.68 76.68Pressure, psig 603 603 604 604 604Temperature, .degree.C. 270 260 269 259 280Time on organics, hrs. 22.5 46.5 51.5 70.5 75.5Duration of run, hrs. 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.56 3.18 3.05 2.39 2.57DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.048 1.891 1.635 0.886 2.023MEA 15.586 7.180 13.602 16.846 6.993PIP 0.813 1.493 1.323 0.749 1.617DETA 41.901 34.342 39.594 43.641 34.966AEEA 1.865 0.611 1.010 2.381 0.717AEP 0.823 1.517 1.156 0.704 1.562HEP 0.000 0.000 0.000 0.000 0.000TAEA 2.659 2.739 2.487 2.206 2.5761-TETA 11.989 13.676 12.245 10.267 13.010DAEP 0.232 0.654 0.419 0.182 0.622PEEDA 0.217 0.518 0.333 0.166 0.508DPE 0.109 0.083 0.058 0.039 0.100AE-TAEA 3.022 4.382 3.620 1.989 4.3141-TEPA 5.378 8.807 6.947 3.856 8.743AE-DAEP 0.000 0.169 0.298 0.077 0.555AE-PEEDA 0.213 0.106 0.056 0.030 0.119iAE-PEEDA 0.000 0.000 0.000 0.000 0.000AE-DPE 0.429 0.057 0.000 0.000 0.079BPEA 0.423 0.255 0.529 0.212 0.715Others 2.432 7.971 4.837 2.430 8.651MEA Conversion, % 55.76 79.54 62.13 50.35 80.43DETA Conversion, % 29.31 41.82 34.48 23.55 41.85Acyclic(N4), % 96.35 92.90 94.78 96.99 92.69Acyclic(N5), % 88.75 95.74 92.28 94.82 89.89.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.62 0.78 0.74 0.48 0.86Acyclic(N4)/cyclic 6.67 3.85 4.48 6.78 3.54(< = N4), weight ratio__________________________________________________________________________Example No. 974 975 976 977 978__________________________________________________________________________Catalyst Type DDDDD DDDDD DDDDD DDDDD DDDDDCatalyst weight, gm 76.68 76.68 76.68 76.68 76.68Pressure, psig 604 602 600 600 603Temperature, .degree.C. 280 269 269 279.6 268Time on organics, hrs. 94.5 99.5 120 143 169.5Duration of run, hrs. 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.86 3.10 2.58 2.14 2.10DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 1.862 0.964 1.307 2.134 1.598MEA 5.180 14.419 11.949 4.391 10.047PIP 1.560 1.056 1.181 1.690 1.287DETA 31.278 43.144 40.674 33.084 40.233AEEA 0.512 2.061 1.865 0.489 1.972AEP 1.651 0.963 1.108 1.845 1.344HEP 0.000 0.000 0.000 0.000 0.000TAEA 2.486 2.470 2.584 2.664 2.7781-TETA 12.812 11.950 12.589 14.102 14.021DAEP 0.734 0.275 0.343 0.814 0.472PEEDA 0.588 0.265 0.328 0.634 0.384DPE 0.095 0.052 0.061 0.132 0.148AE-TAEA 4.182 3.097 3.397 4.800 3.5281-TEPA 8.887 6.071 6.875 10.097 7.285AE-DAEP 0.161 0.332 0.223 0.191 0.386AE-PEEDA 0.104 0.049 0.039 0.121 0.860iAE-PEEDA 0.000 0.000 0.000 0.000 0.000AE-DPE 0.078 0.045 0.000 0.109 0.086BPEA 0.986 0.407 0.447 1.153 0.657Others 8.353 4.000 4.471 9.150 4.134MEA Conversion, % 84.46 60.32 66.53 87.79 72.35DETA Conversion, % 44.25 29.45 32.30 45.34 34.20Acyclic(N4), % 91.52 96.06 95.40 91.39 94.36Acyclic(N5), % 90.77 91.66 93.55 90.44 90.10.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.86 0.67 0.69 0.90 0.67Acyclic(N4)/cyclic 3.31 5.53 5.02 3.28 4.62(< = N4), weight ratio__________________________________________________________________________ TABLE CI__________________________________________________________________________Example No. 979 980 981 982 983 984 985 986 987 988__________________________________________________________________________Catalyst Type EEEEE EEEEE EEEEE EEEEE EEEEE EEEEE EEEEE EEEEE EEEEE EEEEECatalyst weight, gm 78.75 78.75 78.75 78.75 78.75 78.75 78.75 78.75 78.75 78.75Pressure, psig 598 598 599 598 600 600 598 600 598 600Temperature, .degree.C. 269 279 260 270 270 259.6 279 270 280 270Time on organics, hrs. 21 28 49 54 73.5 97.5 116 121 139 144Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.92 2.87 3.06 2.85 2.60 2.98 2.80 2.99 2.81 2.96DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product compo-sition, wt. %EDA 1.555 1.668 1.004 0.978 0.998 0.533 2.192 1.116 1.691 0.974MEA 15.132 10.654 18.325 16.432 15.110 22.024 8.483 16.234 7.965 14.943PIP 0.978 1.343 0.749 0.856 0.926 0.581 1.662 1.112 1.577 1.057DETA 41.054 38.593 44.607 43.072 41.241 51.032 35.320 45.272 36.976 44.374AEEA 1.683 0.873 1.751 1.997 1.834 2.629 0.512 1.883 0.650 1.955AEP 1.101 1.347 0.771 0.821 0.835 0.570 1.905 0.982 1.561 1.000HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.712 2.489 2.232 2.241 2.226 1.861 2.166 2.390 2.589 2.5111-TETA 11.777 11.906 10.383 10.387 10.429 8.845 11.724 11.589 13.232 12.136DAEP 0.423 0.486 0.280 0.215 0.235 0.126 0.995 0.266 0.649 0.285PEEDA 0.327 0.415 0.253 0.183 0.199 0.101 0.736 0.226 0.512 0.249DPE 0.088 0.183 0.098 0.092 0.091 0.057 0.262 0.089 0.219 0.098AE-TAEA 3.411 3.691 2.918 2.501 2.621 1.429 3.662 3.017 4.503 3.1211-TEPA 6.041 0.960 5.789 4.661 4.999 2.823 8.129 5.730 9.114 6.079AE-DAEP 0.397 0.339 0.351 0.199 0.231 0.053 1.154 0.242 0.570 0.278AE-PEEDA 0.058 0.077 0.059 0.052 0.032 0.000 0.223 0.032 0.163 0.042iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.052 0.153 0.049 0.072 0.067 0.000 0.208 0.077 0.070 0.097BPEA 0.695 0.772 0.603 0.425 0.457 0.177 0.094 0.547 0.803 0.556Others 4.145 4.991 3.687 2.354 2.636 1.310 9.047 2.757 7.406 3.016MEA Conversion, % 58.37 69.49 50.38 52.25 55.02 39.54 76.37 56.07 78.27 59.37DETA Conversion, % 32.88 34.31 28.22 25.62 27.04 16.74 41.52 27.19 40.06 28.29Acyclic(N4), % 94.53 92.99 95.23 96.26 96.01 97.42 87.46 96.01 91.98 95.86Acyclic(N5), % 88.72 88.82 89.13 90.54 90.63 94.86 87.54 90.69 89.45 90.43.SIGMA.(N5)/.SIGMA. (N4), weight ratio 0.70 0.77 0.74 0.60 0.64 0.41 0.85 0.66 0.88 0.67Acyclic(N4)/cyclic 4.97 3.81 5.86 5.83 5.53 7.46 2.50 5.23 3.50 5.45(< = N4), weight ratio__________________________________________________________________________ TABLE CII__________________________________________________________________________Example No. 989 990 991 992 993 994 995 996 997 998__________________________________________________________________________Catalyst Type FFFFF FFFFF FFFFF FFFFF FFFFF FFFFF FFFFF FFFFF FFFFF FFFFFCatalyst weight, gm 76.67 76.67 76.67 76.67 76.67 76.67 76.67 76.67 76.67 76.67Pressure, psig 599 599 609 599 600 598 596 598 600 599Temperature, .degree.C. 270 280 260 269 259 280 280 269 269 268Time on organics, hrs. 22.5 27.5 46.5 51.5 70.5 75.5 94.5 99.5 120 169.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.05 3.06 2.79 3.10 3.07 3.13 3.03 3.01 3.05 3.15DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product compo-sition, wt. %EDA 1.520 2.437 2.447 1.228 1.029 2.414 2.547 1.320 1.437 1.242MEA 14.652 8.505 6.424 13.718 18.262 7.632 6.416 14.174 12.516 13.988PIP 1.110 1.615 1.625 1.089 0.811 1.685 1.788 1.154 1.228 1.100DETA 39.856 33.953 30.620 42.604 44.433 34.076 32.533 40.980 39.040 42.773AEEA 1.060 0.447 0.314 1.855 1.945 0.437 0.334 1.170 1.071 1.048AEP 1.075 1.737 1.834 1.025 0.733 1.846 2.086 1.119 1.173 1.187HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.436 2.526 2.311 2.830 2.495 2.424 2.285 2.594 2.614 2.5921-TETA 11.953 13.615 12.962 13.423 11.709 13.253 12.977 12.761 12.998 14.044DAEP 0.316 0.845 0.960 0.297 0.197 0.863 1.049 0.408 0.461 0.325PEEDA 0.271 0.647 0.738 0.284 0.177 0.663 0.796 0.337 0.392 0.267DPE 0.114 0.099 0.099 0.049 0.040 0.099 0.102 0.071 0.074 0.052AE-TAEA 3.524 4.505 4.333 3.359 2.704 4.359 4.387 3.710 3.897 3.4011-TEPA 6.384 9.138 9.198 6.628 5.017 9.080 9.494 6.780 7.415 6.586AE-DAEP 0.000 0.248 0.279 0.314 0.207 0.679 0.267 0.307 0.269 0.300AE-PEEDA 0.229 0.135 0.140 0.042 0.063 0.126 0.123 0.032 0.057 0.054iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.553 0.191 0.210 0.000 0.000 0.052 0.093 0.000 0.033 0.000BPEA 0.522 0.338 0.365 0.442 0.300 0.794 0.831 0.530 0.577 0.532Others 3.075 9.229 10.383 4.003 2.618 9.258 10.540 4.653 5.267 2.788MEA Conversion, % 58.39 76.75 81.53 63.00 49.80 79.10 82.29 61.34 65.43 61.89DETA Conversion, % 32.73 44.85 47.68 31.70 27.42 44.55 46.62 33.56 35.92 30.74Acyclic(N4), % 95.36 91.03 89.48 96.26 97.17 90.61 88.68 94.65 94.40 96.27Acyclic(N5), % 88.37 93.73 93.16 92.61 93.12 89.06 91.35 92.35 92.35 91.85.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.74 0.82 0.85 0.64 0.57 0.87 0.88 0.70 0.74 0.63Acyclic(N4)/cyclic 4.99 3.27 2.91 5.92 7.25 3.04 2.62 4.97 4.69 5.68(< = N4), weight ratio__________________________________________________________________________ TABLE CIII__________________________________________________________________________Example No. 999 1000 1001 1002 1003 1004 1005 1006 1007__________________________________________________________________________Catalyst Type GGGGG GGGGG GGGGG GGGGG GGGGG GGGGG GGGGG GGGGG GGGGGCatalyst weight, 81.02 81.02 81.02 81.02 81.02 81.02 81.02 81.02 81.02gmPressure, psig 598 598 598 598 598 598 600 600 600Temperature, .degree.C. 258 270 259 278 269 278 279 270 270Time on organics, 47 52 71 76 95 99 118.5 139.8 141.5hrs.Duration of run, 2 2 2 2 2 2 2 1 1hrs.MEA SV, gmol/ 2.59 2.69 2.76 2.69 2.62 2.89 2.50 2.61 2.85hr/kgcatDETA/MEA 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00mole ratioNH.sub.3 /MEA 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97mole ratioCrude productcomposition,wt. %EDA 1.431 1.466 0.836 2.026 1.389 1.898 3.937 1.319 1.270MEA 20.803 15.928 21.573 8.455 13.153 5.684 3.430 11.218 12.033PIP 0.619 0.793 0.421 1.275 0.987 1.265 2.108 1.046 0.955DETA 41.470 40.511 47.612 36.072 40.931 31.699 26.932 37.630 37.696AEEA 1.655 2.044 2.654 0.991 1.869 0.695 0.297 1.784 1.787AEP 1.227 0.888 0.525 1.430 1.026 1.530 3.019 1.099 0.994HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.792 2.202 1.893 2.343 2.432 2.392 1.670 2.598 2.3081-TETA 9.207 11.790 9.627 13.461 13.115 13.772 11.582 14.083 12.425DAEP 0.616 0.258 0.103 0.671 0.399 0.778 1.863 0.456 0.383PEEDA 0.451 0.211 0.071 0.519 0.296 0.575 1.351 0.364 0.034DPE 0.029 0.076 0.066 0.203 0.107 0.217 0.107 0.049 0.059AE-TAEA 2.172 3.076 1.560 4.364 3.434 4.598 0.163 3.800 3.5881-TEPA 4.520 5.662 2.989 9.213 7.036 9.871 9.389 7.945 7.481AE-DAEP 0.421 0.185 0.102 0.530 0.226 6.503 0.543 0.066 0.134AE-PEEDA 0.029 0.036 0.030 0.116 0.035 0.100 0.907 0.030 0.098iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.023 0.000 0.000 0.223 0.050 0.264 0.161 0.068 0.138BPEA 0.388 0.045 0.026 0.807 0.056 1.316 1.078 0.184 0.220Others 3.269 3.950 1.862 7.511 4.907 4.583 16.344 5.932 7.028MEA Conver- 40.86 54.65 39.37 76.88 63.86 84.34 90.23 68.77 66.03sion, %DETA Conver- 29.93 31.45 20.47 41.38 33.16 48.10 54.39 37.75 36.75sion, %Acyclic(N4), % 90.94 96.25 97.95 91.90 95.09 91.15 79.97 95.05 96.87Acyclic(N5), % 88.61 97.05 96.63 89.01 96.62 63.88 78.03 97.13 94.95.SIGMA.(N5)/.SIGMA.(N4), 0.62 0.62 0.40 0.89 0.66 1.28 0.74 0.69 0.77weight ratioAcyclic(N4)/ 3.74 6.29 9.71 3.86 5.52 3.70 1.57 5.53 5.98cyclic(< = N4),weight ratio__________________________________________________________________________ TABLE CIV__________________________________________________________________________Example No. 1008 1009 1010 1011 1012 1013 1014 1015 1016__________________________________________________________________________Catalyst Type HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHHCatalyst weight, gm 68 68 68 68 68 68 68 68 68Pressure, psig 606 599 602 606 593 593 601 600 600Temperature, .degree.C. 270 270 280 260 270 260 280 280 270Time on organics, hrs. 7 26 30.5 50 55 74 79 98.8 123Duration of run, hrs. 2 2 1 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.97 3.90 3.93 3.98 3.96 3.94 3.97 3.93 3.85DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.750 0.869 1.269 0.502 0.696 1.589 1.188 1.273 0.810MEA 14.139 13.058 7.841 19.884 13.962 19.078 8.661 6.995 13.582PIP 0.946 1.041 1.264 0.614 0.883 0.667 1.206 1.218 0.953DETA 42.338 40.333 34.679 47.727 41.491 46.874 37.218 33.635 40.430AEEA 1.641 1.480 0.679 2.213 1.609 2.241 0.609 0.617 1.541AEP 0.987 1.041 1.527 0.599 0.913 0.603 1.467 1.500 0.961HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.657 2.786 2.699 2.233 2.513 2.246 2.703 2.625 2.5551-TETA 12.825 13.469 13.932 10.488 12.891 10.468 13.856 13.911 12.446DAEP 0.340 0.387 0.763 0.170 0.305 0.165 0.693 0.770 0.335PEEDA 0.302 0.336 0.601 0.150 0.227 0.146 0.549 0.605 0.284DPE 0.132 0.150 0.301 0.094 0.099 0.099 0.088 0.118 0.077AE-TAEA 3.574 3.998 4.830 2.253 3.538 2.309 4.432 4.606 3.5001-TEPA 7.216 7.943 9.991 4.612 7.184 4.724 9.147 9.831 7.304AE-DAEP 0.088 0.082 0.204 0.154 0.134 0.064 0.601 0.879 0.328AE-PEEDA 0.155 0.158 0.380 0.028 0.223 0.074 0.067 0.125 0.039iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.038 0.067 0.403 0.056 0.248 0.075 0.078 0.313 0.048BPEA 0.508 0.179 1.040 0.229 0.611 0.231 0.804 0.839 0.472Others 5.025 5.875 9.178 2.946 5.812 3.348 7.734 8.939 4.826MEA conversion, % 62.09 64.96 79.02 46.40 62.51 48.13 76.57 80.72 62.33DETA conversion, % 32.54 35.67 44.85 23.54 33.79 24.26 40.15 44.90 33.36Acyclic(N4), wt. % 95.24 94.91 90.90 96.85 95.77 96.87 92.56 91.71 95.57Acyclic(N5), wt. % 93.19 96.09 87.98 93.64 89.81 94.07 89.76 87.00 92.42.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.71 0.73 0.92 0.56 0.74 0.57 0.85 0.92 0.74Acyclic(N4)/cyclic(< = N4), 5.72 5.50 3.73 7.82 6.22 7.57 4.14 3.93 5.75weight ratio__________________________________________________________________________Example No. 1017 1018 1019 1020 1021 1022 1023 1024 1025 1026__________________________________________________________________________Catalyst Type HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHHCatalyst weight, gm 68 68 68 68 68 68 68 68 68 68Pressure, psig 596 598 602 603 602 602 603 603 603 603Temperature, .degree.C. 271 282 260 270 260 281 272 280 272 271Time on organics, hrs. 158 163 182 187 206 211 272 235 254 257.5Duration of run, hrs. 2 2 2 2 83.7 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.92 3.89 3.99 3.83 0.09 3.85 3.80 3.88 3.86 4.03DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composi-tion, wt. %EDA 1.086 1.518 0.564 0.960 0.630 1.769 1.921 2.220 1.641 1.650MEA 13.203 6.960 18.056 12.558 17.829 6.838 12.002 5.827 11.663 13.072PIP 1.186 1.446 0.765 1.101 0.770 1.362 1.263 1.380 1.178 1.205DETA 40.181 35.494 45.781 40.874 44.267 34.368 39.115 30.652 38.907 40.441AEEA 1.261 0.505 2.117 1.385 2.108 0.517 1.158 0.441 1.197 1.308AEP 1.136 1.798 0.738 1.161 0.699 1.725 1.205 1.595 1.179 1.119HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.661 2.671 2.384 2.732 2.320 2.531 2.548 2.402 2.575 2.5131-TETA 13.232 14.206 11.386 13.549 11.117 13.437 12.752 13.162 12.893 12.524DAEP 0.452 0.939 0.225 0.438 0.196 0.889 0.485 0.981 0.469 0.410PEEDA 0.372 0.692 0.187 0.361 0.175 0.670 0.383 0.728 0.375 0.335DPE 0.076 0.107 0.056 0.091 0.033 0.111 0.077 0.133 0.082 0.076AE-TAEA 4.013 4.667 2.669 3.990 2.705 4.603 4.023 4.890 3.878 3.7701-TEPA 8.152 9.680 5.588 8.225 5.696 9.840 8.145 10.433 8.054 7.706AE-DAEP 0.401 0.783 0.156 0.382 0.201 0.171 0.377 0.235 0.379 0.324AE-PEEDA 0.047 0.080 0.028 0.051 0.028 0.114 0.042 0.161 0.048 0.037iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.057 0.105 0.046 0.043 0.036 0.053 0.049 0.706 0.047 0.046BPEA 0.607 0.902 0.324 0.630 0.311 0.897 0.644 1.020 0.619 0.582Others 5.537 8.116 3.310 5.711 3.339 10.005 5.502 13.484 5.564 5.184MEA conversion, % 64.77 81.20 51.33 66.74 50.94 81.35 67.32 84.30 67.93 64.52DETA conversion, % 36.28 43.03 26.65 35.67 27.60 44.30 36.70 50.93 36.43 34.77Acyclic(N4), wt. % 94.64 90.67 96.72 94.81 97.08 90.53 94.19 89.41 94.35 94.83Acyclic(N5), wt. % 91.63 88.47 93.7 91.70 93.58 92.12 91.63 87.84 91.61 92.07.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.79 0.87 0.62 0.78 0.65 0.89 0.82 1.00 0.79 0.79Acyclic(N4)/cyclic 4.93 3.39 6.99 5.16 7.17 3.36 4.48 3.23 4.71 4.78(<=N4), weight ratio__________________________________________________________________________Example No. 1027 1028 1029 1030 1031 1032 1033 1034 1035__________________________________________________________________________Catalyst Type HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHH HHHHHCatalyst weight, gm 67.2 67.2 67.2 67.2 67.2 67.2 67.2 67.2 67.2Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 267.7 267.9 278 257.8 269.6 259.3 279.3 269.8 270.1Time on organics, hrs. 4 6.5 28.5 47.5 52.5 71 76.5 96.5 99Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.59 4.81 4.66 4.74 4.80 4.79 4.46 4.63 4.60DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.515 0.541 1.593 0.567 0.832 0.445 1.675 0.932 0.995MEA 23.588 25.727 18.012 26.580 21.992 27.189 13.854 20.859 20.291PIP 0.888 1.118 1.953 1.009 1.390 0.957 1.810 1.493 1.486DETA 54.811 54.100 50.845 55.433 53.042 56.685 51.796 53.039 51.623AEEA 0.344 0.802 0.233 0.360 0.208 0.377 0.150 0.478 0.210AEP 0.883 0.858 1.884 0.856 1.352 0.775 2.177 1.423 1.423HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.618 1.490 1.878 1.474 1.695 1.397 1.977 1.858 1.9551-TETA 7.964 7.269 9.198 6.586 8.327 6.490 9.962 8.880 10.270DAEP 0.114 0.093 0.645 0.301 0.154 0.207 0.692 0.412 0.178PEEDA 0.081 0.064 0.387 0.144 0.104 0.117 0.359 0.162 0.125DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 0.000 0.088 0.246 0.000 0.102 0.000 1.894 0.109 0.0001-TEPA 0.664 0.704 1.555 0.500 0.975 0.246 3.556 1.157 1.321AE-DAEP 0.000 0.223 0.372 0.000 0.000 0.000 0.114 0.133 0.326AE-PEEDA 0.000 0.000 0.099 0.000 0.175 0.000 0.075 0.000 0.069iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.168 0.000 0.059 0.000 0.423 0.000 0.000 0.083 0.512BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 1.532 0.963 2.990 1.492 2.047 0.994 0.880 1.861 2.579MEA conversion, % 34.18 28.60 49.97 27.10 38.81 25.75 61.46 42.13 44.20DETA conversion, % 9.11 10.77 16.06 9.64 12.29 7.99 14.37 12.55 15.64Acyclic(N4), wt. % 98.01 98.23 91.48 94.77 97.49 96.05 91.91 94.93 97.59Acyclic(N5), wt. % 79.79 78.07 77.26 100.00 64.30 100.00 96.64 85.40 59.30.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.09 0.11 0.19 0.06 0.16 0.03 0.43 0.13 0.18Acyclic(N4)/cyclic(<=N4), 4.87 4.11 2.27 3.49 3.34 3.83 2.37 3.08 3.81weight ratio__________________________________________________________________________ TABLE CV__________________________________________________________________________Example No. 1036 1037 1038 1039 1040 1041 1042 1043 1044 1045 1046 1047__________________________________________________________________________Catalyst Type IIIII IIIII IIIII IIIII IIIII IIIII IIIII IIIII IIIII IIIII IIIII IIIIICatalyst weight, gm 69.34 69.34 69.34 69.34 69.34 69.34 69.34 69.34 69.34 69.34 69.34 69.34Pressure, psig 604 603 603 604 604 603 603 600 600 603 604 603Temperature, .degree.C. 270 270 280 260 270 260 280 280 270 271 282 260Time on organics, hrs. 7 26 30.5 50 55 74 79 98.8 123 158 163 182Duration of run, hrs. 2 2 1 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.33 4.26 4.21 4.20 4.33 4.20 4.17 4.26 4.16 4.01 4.31 4.28DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition,wt. %EDA 0.805 1.034 1.662 0.510 0.908 0.544 1.363 2.077 0.963 1.212 1.778 0.757MEA 14.316 13.747 10.093 20.646 15.418 19.410 8.991 9.550 15.047 12.554 9.298 20.034PIP 0.832 0.927 1.260 0.542 0.841 0.555 1.085 1.325 0.906 1.009 1.387 0.734DETA 41.647 40.641 36.709 48.819 43.537 47.902 35.150 32.997 41.105 37.117 36.552 46.016AEEA 1.392 1.332 0.661 2.056 1.526 2.142 0.718 0.580 1.445 1.046 0.554 1.888AEP 0.990 1.057 1.455 0.554 0.915 0.588 1.336 1.810 0.927 1.212 1.598 0.679HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 2.980 2.906 2.683 2.272 2.709 2.329 2.593 1.994 2.443 2.311 2.549 2.2231-TETA 13.276 13.074 12.859 9.750 12.028 10.013 12.850 10.946 11.547 11.703 13.076 10.211DAEP 0.416 0.470 0.726 0.152 0.358 0.171 0.754 1.270 0.373 0.669 0.839 0.209PEEDA 0.321 0.347 0.527 0.130 0.270 0.147 0.531 0.858 0.292 0.476 0.594 0.174DPE 0.151 0.167 0.208 0.055 0.159 0.073 0.126 0.164 0.196 0.112 0.468 0.072AE-TAEA 4.148 4.074 4.997 2.219 3.441 2.254 4.357 3.447 3.193 3.397 4.484 2.5801-TEPA 7.057 7.074 8.378 3.718 6.209 3.871 8.283 7.231 6.092 7.003 8.450 5.015AE-DAEP 0.081 0.074 0.124 0.145 0.075 0.247 1.053 1.912 0.489 0.928 0.694 0.198AE-PEEDA 0.148 0.141 0.238 0.027 0.117 0.067 0.154 0.294 0.065 0.153 0.085 0.045iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.051 0.069 0.286 0.266 0.175 0.261 0.309 0.130 0.070 0.287 0.093 0.051BPEA 0.582 0.570 0.800 0.207 0.479 0.205 0.737 0.613 0.415 0.510 0.761 0.054Others 5.099 5.415 7.215 2.423 4.615 2.781 8.931 12.620 4.609 7.302 7.358 3.390MEA conversion, % 61.90 63.00 72.52 43.91 58.43 46.90 75.19 73.83 57.94 64.82 74.69 45.65DETA conversion, % 34.13 35.00 40.60 21.18 30.42 22.12 42.36 46.26 31.71 38.19 40.86 25.81Acyclic(N4), wt. % 94.82 94.20 91.41 97.28 94.93 96.93 91.63 84.95 94.20 91.77 89.15 96.47Acyclic(N5), wt. % 92.86 92.88 90.23 90.21 91.94 88.71 84.88 78.36 89.93 84.70 88.79 95.62.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.70 0.71 0.87 0.53 0.68 0.54 0.88 0.89 0.70 0.80 0.83 0.62Acyclic(N4)/cyclic(< = N4), 6.00 5.38 3.72 8.39 5.80 8.05 4.03 2.38 5.19 4.03 3.20 6.65weight ratio__________________________________________________________________________ Example No. 1048 1049 1050 1051 1052 1053 1054__________________________________________________________________________ Catalyst Type IIIII IIIII IIIII IIIII IIIII IIIII IIIII Catalyst weight, gm 69.34 69.34 69.34 69.34 69.34 69.34 69.34 Pressure, psig 604 603 604 604 604 603 604 Temperature, .degree.C. 270 260 281 272 280 272 271 Time on organics, hrs. 187 206 211 272 235 254 257.5 Duration of run, hrs. 2 2 2 2 2 2 2 MEA SV, gmol/hr/kgcat 4.05 4.11 4.41 4.13 4.11 4.22 4.43 DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 Crude product composition, wt. % EDA 0.980 0.861 2.156 1.946 2.350 1.794 1.594 MEA 13.105 18.882 8.720 12.941 7.170 13.118 13.362 PIP 0.962 0.794 1.385 1.150 1.343 1.147 1.045 DETA 38.892 44.565 34.824 39.610 33.663 39.912 39.851 AEEA 1.280 1.745 0.521 1.185 0.478 1.195 1.279 AEP 0.976 0.784 1.518 1.109 1.669 1.094 1.015 HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 TAEA 2.513 2.187 2.296 2.546 2.452 2.458 2.496 1-TETA 11.973 10.178 12.160 12.466 13.106 12.081 12.149 DAEP 0.394 0.335 0.916 0.518 1.012 0.454 0.423 PEEDA 0.318 0.240 0.634 0.377 0.766 0.348 0.321 DPE 0.186 0.150 0.127 0.092 0.123 0.079 0.072 AE-TAEA 3.922 2.727 4.290 3.863 4.417 3.624 3.540 1-TEPA 7.390 5.407 8.840 7.583 9.218 7.097 6.990 AE-DAEP 0.427 0.351 0.189 0.411 0.892 0.342 0.038 AE-PEEDA 0.079 0.059 0.132 0.052 0.135 0.036 0.038 iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 AE-DPE 0.166 0.042 0.411 0.073 0.390 0.091 0.061 BPEA 0.563 0.330 0.822 0.597 0.843 0.577 0.535 Others 6.493 3.912 10.339 5.881 9.704 5.473 5.321 MEA conversion, % 63.83 48.59 76.20 64.94 80.41 63.82 62.91 DETA conversion, % 36.20 27.88 43.50 36.22 45.35 34.58 34.25 Acyclic(N4), wt. % 94.16 94.46 89.61 93.83 89.12 94.28 94.72 Acyclic(N5), wt. % 90.16 91.23 89.42 91.00 85.78 91.11 91.63 .SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.82 0.68 0.91 0.79 0.91 0.76 0.74 Acyclic(N4)/cyclic(< = N4), 5.11 5.37 3.16 4.63 3.17 4.66 5.00 weight ratio__________________________________________________________________________ TABLE CVI__________________________________________________________________________Example No. 1055 1056 1057 1058 1059 1060 1061 1062 1063__________________________________________________________________________Catalyst Type JJJJJ JJJJJ JJJJJ JJJJJ JJJJJ JJJJJ JJJJJ JJJJJ JJJJJCatalyst weight, gm 70.6 70.6 70.6 70.6 70.6 70.6 70.6 70.6 70.6Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 267.7 267.9 278 257.8 269.6 259.3 279.3 269.8 270.1Time on organics, hrs. 4 6.5 30.5 49.5 54.5 73 78.5 98 101Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.23 4.29 4.10 4.04 4.14 4.15 3.89 3.94 3.95DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.162 0.169 0.783 0.192 0.397 0.176 1.073 0.529 0.553MEA 29.144 31.908 24.483 32.053 27.952 31.487 22.456 25.861 26.009PIP 0.349 0.340 1.209 0.251 0.651 0.248 1.406 0.768 0.760DETA 59.742 58.534 56.565 58.955 59.279 59.506 54.811 57.648 57.364AEEA 0.310 0.929 0.200 0.321 0.342 0.351 0.776 0.366 0.370AEP 0.544 0.498 1.287 0.436 0.711 0.471 1.454 0.793 0.801HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.578 0.706 0.873 0.618 0.733 0.669 1.573 0.874 1.3101-TETA 4.153 2.968 6.200 2.623 4.926 2.835 6.907 5.628 5.841DAEP 0.177 0.175 0.342 0.144 0.238 0.180 0.520 0.239 0.184PEEDA 0.076 0.000 0.220 0.000 0.135 0.000 0.347 0.085 0.125DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-TAEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.0001-TEPA 0.000 0.000 0.463 0.000 0.000 0.000 0.848 0.318 0.401AE-DAEP 0.000 0.000 0.000 0.000 0.000 0.000 0.181 0.000 0.000AE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.279 0.000 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 0.976 0.215 1.483 1.078 1.416 1.247 1.734 1.491 2.212MEA conversion, % 20.13 12.23 32.26 12.02 24.15 14.16 38.70 28.47 29.14DETA conversion, % 2.69 4.31 6.99 3.83 4.40 3.59 11.07 5.24 7.12Acyclic(N4), wt. % 94.94 95.46 92.64 95.76 93.82 95.11 90.14 95.25 95.85Acyclic(N5), wt. % -- -- 100.00 -- -- -- 70.20 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.00 0.00 0.00 0.00 0.00 0.00 0.16 0.05 0.05Acyclic(N4)/cyclic(< = N4), 4.13 3.63 2.31 3.90 3.26 3.90 2.24 3.45 3.82weight ratio__________________________________________________________________________ TABLE CVII__________________________________________________________________________Example No. 1064 1065 1066 1067 1068 1069 1070 1071 1072__________________________________________________________________________Catalyst Type KKKKK KKKKK KKKKK KKKKK KKKKK KKKKK KKKKK KKKKK KKKKKCatalyst weight, gm 67.5 67.5 67.5 67.5 67.5 67.5 67.5 67.5 67.5Pressure, psig 598 597 597 598 598 598 598 600 600Temperature, .degree.C. 270 270 280 260 270 260 280 280 270Time on organics, hrs. 7 26 30.5 50 55 74 79 98.8 123Duration of run, hrs. 2 2 1 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.62 3.73 3.53 3.46 3.70 3.56 3.47 3.46 3.40DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composition, wt. %EDA 0.294 0.424 0.706 0.273 0.506 0.342 0.979 1.001 0.624MEA 25.314 22.475 18.589 26.092 22.747 25.743 18.317 16.142 21.635PIP 0.421 0.496 0.707 0.266 0.485 0.297 0.712 0.692 0.469DETA 54.036 51.203 48.723 54.115 52.329 54.167 48.580 42.653 47.745AEEA 1.899 2.033 1.670 2.115 2.193 2.258 1.799 1.403 1.963AEP 0.488 0.616 0.869 0.374 0.614 0.438 0.855 0.848 0.588HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.340 1.728 1.888 1.215 1.590 1.290 1.768 1.764 1.5511-TETA 6.203 8.239 9.101 5.680 7.515 6.023 8.740 9.202 7.737DAEP 0.091 0.205 0.282 0.096 0.157 0.110 0.267 0.415 0.216PEEDA 0.093 0.162 0.229 0.076 0.133 0.090 0.209 0.313 0.172DPE 0.048 0.111 0.178 0.076 0.126 0.084 0.220 0.387 0.232AE-TAEA 1.230 1.884 2.347 1.338 1.704 1.006 1.902 2.806 1.8321-TEPA 2.363 3.385 4.197 1.841 2.798 1.882 3.504 5.099 3.159AE-DAEP 0.139 0.145 0.257 0.143 0.273 0.114 0.392 0.812 0.539AE-PEEDA 0.066 0.034 0.101 0.042 0.061 0.024 0.100 0.168 0.078iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.043 0.117 0.077 0.157 0.090 0.062 0.343 0.035BPEA 0.110 0.211 0.290 0.056 0.110 0.069 0.063 0.209 0.048Others 2.415 3.286 4.610 2.509 3.660 2.432 4.633 8.202 4.835MEA conversion, % 31.77 40.08 50.03 29.37 39.57 30.42 49.72 55.92 40.42DETA conversion, % 13.44 18.87 22.15 12.94 17.39 12.99 20.75 30.77 21.85Acyclic(N4), wt. % 97.01 95.43 94.10 96.54 95.63 96.27 93.80 90.77 93.73Acyclic(N5), wt. % 91.93 92.41 89.53 90.91 88.22 90.67 89.75 83.77 87.68.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.50 0.55 0.63 0.49 0.54 0.42 0.54 0.78 0.57Acyclic(N4)/cyclic(< = N4), 6.61 6.27 4.85 7.78 6.01 7.18 4.65 4.13 5.53weight ratio__________________________________________________________________________Example No. 1073 1074 1075 1076 1077 1078 1079 1080 1081 1082__________________________________________________________________________Catalyst Type KKKKK KKKKK KKKKK KKKKK KKKKK KKKKK KKKKK KKKKK KKKKK KKKKKCatalyst weight, gm 67.5 67.5 67.5 67.5 67.5 67.5 67.5 67.5 67.5 67.5Pressure, psig 585 598 598 598 598 598 598 598 598 598Temperature, .degree.C. 271 282 260 270 260 281 272 280 272 271Time on organics, hrs. 158 163 182 187 206 211 272 235 254 257.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.97 3.69 3.58 3.41 3.41 3.54 3.99 3.53 3.50 3.70DETA/MEA mole ratio 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00NH.sub.3 /MEA mole ratio 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97 5.97Crude product composi-tion, wt. %EDA 0.764 1.129 0.479 0.786 0.509 1.756 1.803 1.993 1.749 1.597MEA 20.571 16.885 25.262 21.504 25.342 18.397 20.631 15.100 20.996 22.350PIP 0.531 0.826 0.351 0.538 0.352 0.865 0.634 0.781 0.638 0.567DETA 47.941 46.768 52.656 48.687 51.138 47.357 46.647 42.162 46.440 48.370AEEA 1.707 1.530 2.132 1.979 2.129 1.620 1.739 1.446 1.730 1.824AEP 0.697 1.034 0.470 0.636 0.432 0.927 0.707 0.935 0.676 0.626HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.641 1.964 1.408 1.541 1.337 1.743 1.648 1.942 1.596 1.5301-TETA 8.006 9.717 6.641 7.305 6.278 8.432 8.037 9.595 7.922 7.422DAEP 0.239 0.408 0.135 0.174 0.125 0.291 0.359 0.442 0.295 0.232PEEDA 0.186 0.297 0.101 0.138 0.094 0.224 0.234 0.314 0.215 0.169DPE 0.211 0.069 0.110 0.183 0.114 0.089 0.099 0.103 0.182 0.107AE-TAEA 1.858 2.661 1.266 1.659 1.462 2.013 2.165 2.975 2.063 1.9051-TEPA 3.247 5.154 2.314 2.935 2.396 3.688 3.984 5.395 3.860 3.394AE-DAEP 0.401 0.342 0.130 0.223 0.173 0.261 0.335 0.507 0.256 0.234AE-PEEDA 0.057 0.062 0.025 0.068 0.063 0.045 0.076 0.117 0.056 0.042iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.053 0.067 0.086 0.211 0.083 0.034 0.229 0.080 0.055 0.040BPEA 0.051 0.390 0.040 0.087 0.037 0.225 0.294 0.465 0.272 0.231Others 4.459 5.997 2.874 5.176 3.565 5.035 6.480 8.307 5.107 4.381MEA conversion, % 42.93 55.07 31.89 40.98 31.07 49.41 44.79 58.84 42.66 39.29DETA conversion, % 20.95 26.04 15.63 20.58 17.33 22.60 25.81 31.71 24.63 31.91Acyclic(N4), wt. % 93.81 93.79 95.88 94.70 95.80 94.40 93.33 93.06 93.21 94.64Acyclic(N5), wt. % 90.08 90.08 92.72 88.64 91.56 90.98 86.82 87.74 90.25 90.67.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.55 0.70 0.46 0.55 0.53 0.58 0.68 0.77 0.64 0.62Acyclic(N4)/cyclic 5.17 4.43 6.90 5.30 6.82 4.25 4.76 4.48 4.74 5.26(<=N4), weight ratio__________________________________________________________________________ TABLE CVIII__________________________________________________________________________Example No. 1083 1084 1085 1086 1087 1088 1089 1090 1091 1092 1093__________________________________________________________________________Catalyst Type LLLLL LLLLL LLLLL LLLLL LLLLL LLLLL LLLLL LLLLL LLLLL LLLLL LLLLLCatalyst weight, 89.3 89.3 89.3 89.3 89.3 89.3 89.3 89.3 89.3 89.3 89.3gmPressure, psig 600 600 600 600 600 600 600 600 600 600 600Temperature, 270.4 271 280.8 260.7 270.6 260 280 251.2 260.9 246 256.degree.C.Time on or- 6 25 30 49 54 75 98 122 126 146 150ganics, hrs.Duration of 2 2 2 2 2 2 2 2 2 2 2run, hrs.MEA SV, 2.58 3.38 3.44 3.51 3.60 3.57 3.24 3.36 3.38 3.39 3.40gmol/hr/kgcatDETA/MEA 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99mole ratioNH.sub.3 /MEA 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98mole ratioCrude productcomposition,wt. %EDA 7.581 5.561 8.937 2.704 3.955 2.560 6.744 1.365 2.123 1.102 1.555MEA 5.649 4.652 1.477 12.445 6.771 14.307 1.922 20.539 13.637 23.785 17.583PIP 2.611 2.188 3.634 1.038 1.673 1.040 2.760 0.505 0.844 0.316 0.605DETA 20.830 22.594 17.418 33.381 27.328 37.933 21.040 44.901 35.026 47.146 40.284AEEA 0.277 0.720 0.119 1.862 1.082 2.151 0.214 2.495 2.047 2.268 2.300AEP 4.086 3.847 6.035 1.539 2.846 1.511 4.978 0.671 1.240 0.438 0.841HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.417 1.005 0.410 1.722 1.235 1.843 0.687 1.801 1.866 1.600 1.9131-TETA 6.468 10.968 6.099 13.376 11.500 13.551 8.038 12.034 13.031 10.358 13.283DAEP 0.214 2.647 3.666 0.817 1.651 0.668 3.053 0.199 0.603 0.134 0.303PEEDA 1.910 2.007 3.593 0.689 1.305 0.551 2.822 0.149 0.453 0.084 0.234DPE 0.511 0.786 0.396 0.496 0.519 0.388 0.407 0.158 0.444 0.132 0.278AE-TAEA 1.200 2.252 1.072 2.980 2.621 3.187 1.564 2.189 3.092 1.688 2.7801-TEPA 4.021 8.850 3.847 8.247 8.806 7.806 6.952 4.035 7.515 3.427 5.980AE-DAEP 2.544 2.479 3.363 0.847 1.622 0.596 2.586 0.217 0.561 0.186 0.310AE-PEEDA 1.209 1.148 1.857 0.301 0.275 0.127 0.657 0.082 0.144 0.229 0.085iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.400 0.546 0.786 0.214 0.327 0.203 0.511 0.072 0.356 0.213 0.271BPEA 0.426 0.441 0.406 0.579 0.417 0.504 0.538 0.049 0.256 0.087 0.212Others 28.967 19.631 26.356 9.863 15.860 3.864 21.819 3.947 10.343 2.978 6.374MEA conver- 84.58 87.85 96.06 66.71 81.58 61.26 94.72 44.71 63.52 35.97 53.12sion, %DETA conver- 68.31 65.04 72.53 47.07 55.94 39.12 65.80 28.35 44.46 24.76 36.33sion, %Acyclic(N4), 72.31 68.75 45.95 88.28 78.55 90.54 58.43 96.46 90.84 97.14 94.89Acyclic(N5), 53.27 70.63 43.41 85.24 81.21 88.47 66.48 93.63 88.94 87.72 90.87%.SIGMA.(N5)/.SIGMA.(N4), 1.02 0.90 0.80 0.77 0.86 0.73 0.85 0.46 0.72 0.47 0.60weight ratioAcyclic(N4)/ 0.73 1.04 0.37 3.29 1.59 3.70 0.62 8.20 4.15 10.80 6.71cyclic(<=N4),weight ratio__________________________________________________________________________ TABLE CIX__________________________________________________________________________Example No. 1094 1095 1096 1097 1098 1099 1100 1101__________________________________________________________________________Catalyst Type MMMMM MMMMM MMMMM MMMMM MMMMM MMMMM MMMMM MMMMMCatalyst weight, gm 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 249.9 259.9 270 265 275 280.7 245.4 255.6Time on organics, hrs. 23 27 48 53 71 96 119 143Duration of run, hrs. 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.68 3.83 3.55 3.76 3.33 3.79 3.95 3.85DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition,wt. %EDA 1.576 2.613 3.978 3.156 5.524 6.509 0.996 1.499MEA 17.638 11.313 5.763 9.706 3.516 3.037 24.706 19.664PIP 0.661 1.130 1.710 1.360 2.341 2.601 0.354 0.600DETA 39.776 31.481 24.483 30.274 23.630 21.989 47.915 42.143AEEA 2.240 1.704 1.039 1.469 0.510 0.312 1.910 2.051AEP 0.977 1.950 3.062 2.204 4.152 4.514 0.487 0.818HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.670 1.413 1.130 1.389 0.831 0.617 1.418 1.6341-TETA 13.251 13.353 12.483 13.317 11.047 9.109 9.280 11.618DAEP 0.478 1.311 2.314 1.454 2.807 3.039 0.151 0.330PEEDA 0.351 0.887 1.565 0.988 2.444 2.697 0.112 0.237DPE 0.312 0.494 0.685 0.566 0.162 0.218 0.143 0.272AE-TAEA 2.637 2.967 2.606 2.999 0.260 0.286 1.553 2.3281-TEPA 6.180 8.339 9.381 8.829 8.372 6.929 2.536 4.917AE-DAEP 0.385 1.116 1.890 1.178 2.735 0.320 0.103 0.269AE-PEEDA 0.094 0.460 0.627 0.505 0.663 0.684 0.051 0.063iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.203 0.336 0.071 0.097 0.053 0.192 0.186 0.135BPEA 0.099 0.280 0.687 0.358 0.583 0.477 0.063 0.072Others 6.086 11.972 16.987 14.062 19.743 24.147 2.010 4.512MEA conversion, % 52.70 69.92 84.56 74.53 90.51 91.63 31.61 45.99DETA conversion, % 36.77 50.39 61.12 52.92 62.23 64.10 21.37 31.38Acyclic(N4), % 92.89 84.57 74.88 83.01 68.69 62.02 96.33 94.03Acyclic(N5), % 91.85 83.74 78.54 84.68 68.15 81.17 91.02 93.05.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.59 0.77 0.84 0.78 0.73 0.56 0.40 0.55Acyclic(N4)/cyclic(< = N4), 5.36 2.55 1.45 2.23 0.99 0.74 8.56 5.86weight ratio__________________________________________________________________________ TABLE CX__________________________________________________________________________Example No. 1102 1103 1104 1105 1106 1107 1108 1109__________________________________________________________________________Catalyst Type NNNNN NNNNN NNNNN NNNNN NNNNN NNNNN NNNNN NNNNNCatalyst weight, gm 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 249.9 259.9 270 265 275 280.7 245.4 255.6Time on organics, hrs. 23 27 48 53 71 96 119 143Duration of run, hrs. 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.13 4.06 3.61 3.95 3.59 3.73 3.92 3.85DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 1.549 2.657 3.816 2.918 4.945 5.969 0.647 1.041MEA 26.153 22.877 17.520 20.205 16.087 14.680 30.721 27.460PIP 1.065 1.698 3.017 2.402 3.952 4.620 0.575 0.919DETA 45.023 38.851 29.155 34.030 27.311 23.227 52.572 47.799AEEA 1.218 0.982 0.837 1.081 0.676 0.509 1.117 1.247AEP 1.053 1.832 3.443 2.575 4.691 5.337 0.059 0.880HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.900 0.792 0.594 0.766 0.491 0.319 0.738 0.8401-TETA 5.944 6.306 6.128 6.849 5.723 4.369 4.214 5.237DAEP 0.360 0.709 1.430 1.052 2.070 2.354 0.120 0.254PEEDA 0.397 0.866 2.099 1.325 2.733 3.018 0.131 0.289DPE 0.253 0.301 0.310 0.288 0.386 0.613 0.086 0.156AE-TAEA 0.991 0.999 0.917 1.079 0.819 0.226 0.604 0.9151-TEPA 4.013 4.927 5.460 5.824 4.414 3.018 2.018 2.952AE-DAEP 0.401 0.835 1.545 1.161 2.224 2.681 0.112 0.278AE-PEEDA 0.400 0.554 0.512 0.489 0.511 0.542 0.121 0.220iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.324 0.318 0.392 0.318 0.632 0.239 0.000 0.089BPEA 0.176 0.309 0.369 0.281 0.202 0.202 0.054 0.073Others 7.341 11.517 13.927 12.910 15.843 20.589 2.521 3.702MEA conversion, % 30.67 40.03 52.14 46.63 57.49 60.93 15.90 24.03DETA conversion, % 29.24 39.62 52.78 46.72 57.22 63.35 14.68 21.60Acyclic(N4), % 87.11 79.08 63.63 74.06 54.49 43.92 93.59 89.67Acyclic(N5), % 79.35 74.60 69.34 75.42 59.44 46.96 90.10 85.38.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.80 0.88 0.87 0.89 0.77 0.64 0.55 0.66Acyclic(N4)/cyclic(< = N4), 2.19 1.31 0.65 0.99 0.44 0.29 5.08 2.43weight ratio__________________________________________________________________________ TABLE CXI__________________________________________________________________________Example No. 1110 1111 1112 1113 1114 1115 1116 1117 1118 1119__________________________________________________________________________Catalyst Type OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOOCatalyst weight, gm 50 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 249.9 259.9 270 265 275 280.7 245.4 255.6 250.7 249.7Time on organics, hrs. 23 27 48 53 71 96 119 143 4 22.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.91 3.98 3.24 3.97 3.68 3.71 3.62 3.79 5.16 4.70DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composi-tion, wt. %EDA 0.813 1.260 2.398 1.598 2.314 2.549 0.484 0.749 1.094 0.827MEA 21.532 15.622 10.867 13.317 7.792 5.589 27.925 23.876 20.059 23.108PIP 0.251 0.421 0.882 0.590 0.731 0.778 0.097 0.183 0.327 0.225DETA 47.006 39.567 32.817 35.817 32.340 29.857 52.926 48.757 43.271 47.311AEEA 2.748 2.642 1.046 2.119 1.372 1.018 1.990 2.368 2.409 2.483AEP 0.401 0.686 1.551 0.829 1.174 1.246 0.252 0.319 0.548 0.347HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.801 1.987 1.375 1.958 2.017 1.874 1.232 1.615 1.501 1.5921-TETA 12.031 14.750 10.951 12.866 14.396 13.387 6.891 9.157 11.936 10.715DAEP 0.111 0.253 1.051 0.455 0.782 0.853 0.046 0.075 0.225 0.098PEEDA 0.080 0.230 0.708 0.335 0.543 0.599 0.043 0.066 0.181 0.076DPE 0.112 0.173 0.437 0.453 0.539 0.630 0.067 0.139 0.174 0.137AE-TAEA 1.968 2.920 2.711 3.016 4.316 4.170 0.874 1.511 2.199 1.9581-TEPA 4.549 6.175 7.240 6.904 8.891 9.110 1.270 2.338 4.246 3.296AE-DAEP 0.057 0.500 1.079 0.522 0.775 0.951 0.060 0.082 0.326 0.147AE-PEEDA 0.000 0.477 0.256 0.215 0.250 0.299 0.000 0.000 0.181 0.127iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.058 0.314 0.301 0.358 0.368 0.496 0.053 0.099 0.286 0.112BPEA 0.185 0.182 0.313 0.582 0.348 0.444 0.056 0.141 0.107 0.050Others 2.088 7.250 12.439 11.787 13.042 15.672 1.167 1.829 5.810 3.174MEA conversion, % 42.08 58.67 69.47 64.44 79.13 84.73 23.07 33.43 45.87 37.58DETA conversion, % 25.04 37.95 45.35 43.31 48.67 51.65 13.57 19.42 30.78 24.24Acyclic(N4), % 97.84 96.21 84.86 92.25 89.78 87.99 98.09 97.46 95.84 97.51Acyclic(N5), % 95.56 86.04 83.61 85.52 88.33 85.83 92.64 92.25 87.72 92.30.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.48 0.60 0.81 0.72 0.81 0.89 0.27 0.37 0.52 0.45Acyclic(N4)/cyclic 14.43 9.47 2.66 5.56 4.35 3.71 16.01 13.75 9.21 13.89(<=N4), weight ratio__________________________________________________________________________Example No. 1120 1121 1122 1123 1124 1125 1126 1127 1128 1129__________________________________________________________________________Catalyst Type OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOOCatalyst weight, gm 50 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 260 255.5 265.5 260.5 270.1 250.6 250 265.2 275.2 270.3Time on organics, hrs. 28 46.5 52 71.5 76 95.5 118 145 148 170Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.01 4.40 4.64 4.92 4.88 4.87 4.45 4.02 3.87 3.87DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composi-tion, wt. %EDA 1.292 1.045 1.658 1.287 1.756 0.653 0.658 1.445 2.153 1.729MEA 16.448 21.025 15.267 18.822 12.662 24.836 24.781 17.208 11.166 13.488PIP 0.399 0.287 0.516 0.337 0.537 0.161 0.156 0.414 0.698 0.492DETA 39.380 43.930 37.874 42.302 36.372 48.917 49.188 40.090 34.966 37.519AEEA 2.393 2.382 2.051 2.263 1.834 2.123 2.116 1.781 1.886 1.571AEP 0.583 0.411 0.711 0.476 0.801 0.303 0.298 0.559 0.957 0.762HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.770 1.662 1.767 1.798 1.909 1.483 1.480 1.667 1.789 1.6591-TETA 13.854 11.854 12.904 12.705 13.617 9.174 9.069 11.193 12.877 11.276DAEP 0.249 0.137 0.361 0.199 0.443 0.094 0.073 0.298 0.501 0.557PEEDA 0.183 0.102 0.256 0.143 0.304 0.067 0.057 0.210 0.366 0.360DPE 0.205 0.156 0.410 0.181 0.122 0.066 0.128 0.100 0.135 0.412AE-TAEA 3.040 2.393 3.401 2.775 3.772 1.512 1.451 2.977 3.693 3.1821-TEPA 5.724 4.313 6.650 4.894 6.982 2.416 2.266 5.519 7.108 5.762AE-DAEP 0.392 0.289 0.446 0.324 0.477 0.105 0.070 0.367 0.112 0.680AE-PEEDA 0.182 0.086 0.178 0.101 0.174 0.062 0.029 0.122 0.140 0.117iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.279 0.133 0.078 0.141 0.077 0.044 0.046 0.058 0.278 0.193BPEA 0.278 0.178 0.626 0.192 0.706 0.129 0.129 0.572 0.680 0.209Others 7.869 5.310 8.286 5.602 9.166 2.965 2.416 7.580 9.685 10.183MEA conversion, % 55.95 43.59 58.83 49.17 65.41 32.04 31.64 52.56 68.72 62.38DETA conversion, % 37.48 30.13 39.45 32.28 41.11 20.65 19.56 34.48 41.95 37.97Acyclic(N4), % 96.06 97.15 93.45 96.51 94.69 97.89 97.60 95.47 93.59 90.67Acyclic(N5), % 88.54 90.71 88.30 90.98 88.22 92.00 93.08 88.34 89.91 88.16.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.60 0.53 0.72 0.56 0.74 0.39 0.36 0.71 0.76 0.71Acyclic(N4)/cyclic 9.63 12.34 6.50 10.84 7.02 15.35 14.76 8.11 5.51 5.00(<=N4), weight ratio__________________________________________________________________________Example No. 1130 1131 1132 1133 1134 1135 1136 1137 1138__________________________________________________________________________Catalyst Type OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOO OOOOOCatalyst weight, gm 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 280.7 250.7 265.7 259.9 270 250.4 265.5 250 250Time on organics, hrs. 172 191 196 216 220 239 244 262 286Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.95 4.44 4.42 4.32 4.52 4.32 4.59 4.28 3.96DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 2.487 0.562 1.308 0.998 1.594 0.620 1.133 0.494 0.560MEA 8.016 26.365 19.043 21.551 14.399 26.157 17.426 24.474 23.986PIP 0.837 0.141 0.371 0.259 0.462 0.139 0.304 0.127 0.146DETA 31.719 51.019 41.915 45.886 37.620 49.403 39.117 47.899 48.509AEEA 1.511 2.181 2.319 2.375 1.945 2.052 2.033 1.815 1.816AEP 1.224 0.289 0.484 0.404 0.668 0.283 0.454 0.283 0.038HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.853 1.399 1.786 1.788 1.875 1.377 1.723 1.389 1.4541-TETA 13.608 8.273 11.292 10.921 12.338 7.973 10.608 7.992 8.498DAEP 0.762 0.078 0.234 0.143 0.335 0.095 0.209 0.102 0.104PEEDA 0.533 0.051 0.168 0.103 0.259 0.072 0.149 0.071 0.079DPE 0.509 0.144 0.321 0.215 0.438 0.171 0.354 0.160 0.170AE-TAEA 4.179 1.285 2.934 2.270 3.574 1.424 2.823 1.514 1.6141-TEPA 8.123 2.016 4.826 3.679 6.077 2.067 4.493 2.110 2.426AE-DAEP 0.938 0.067 0.268 0.108 0.461 0.171 0.264 0.267 0.166AE-PEEDA 0.201 0.060 0.086 0.066 0.101 0.061 0.134 0.107 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.098 0.084 0.239 0.087 0.138 0.112 0.246 0.120 0.053BPEA 0.850 0.042 0.137 0.075 0.193 0.046 0.175 0.053 0.056Others 12.032 2.444 6.821 4.133 9.534 2.987 7.006 3.146 3.176MEA conversion, % 77.91 28.64 48.59 41.59 60.59 28.29 49.91 30.83 33.03DETA conversion, % 48.20 18.14 32.92 26.27 38.96 19.71 33.35 19.75 19.71Acyclic(N4), % 89.54 97.24 94.75 96.48 93.21 96.49 94.53 96.56 96.56Acyclic(N5), % 85.48 92.81 91.37 94.61 91.34 89.90 89.90 86.86 93.58.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.83 0.35 0.61 0.47 0.69 0.40 0.62 0.42 0.41Acyclic(N4)/cyclic 3.99 13.72 8.28 11.28 6.56 12.25 8.37 12.60 12.29(< = N4), weight ratio 4.60 17.25 10.39 13.95 8.23 15.79 11.03 16.06 15.57__________________________________________________________________________ TABLE CXII__________________________________________________________________________Example No. 1139 1140 1141 1142 1143 1144 1145 1146 1147__________________________________________________________________________Catalyst Type PPPPP PPPPP PPPPP PPPPP PPPPP PPPPP PPPPP PPPPP PPPPPCatalyst weight, gm 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 249.2 249.8 259.9 264.9 269.9 254.8 244.9 269.2 274.5Time on organics, hrs. 3.5 22.5 27.5 46.5 51.6 70.6 95.5 118.5 122.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.05 3.45 3.71 3.37 3.66 4.11 3.75 3.37 3.61DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 1.701 1.330 2.175 2.857 3.642 1.575 0.790 2.998 4.045MEA 16.452 20.045 13.804 10.226 7.809 18.066 25.597 9.273 6.909PIP 0.640 0.536 0.952 1.209 1.520 0.606 0.260 1.165 1.515DETA 35.879 42.232 35.213 31.459 28.823 40.057 48.800 31.599 29.253AEEA 1.848 2.310 2.025 1.615 1.216 2.188 2.179 1.469 1.067AEP 0.845 0.661 1.314 1.822 2.394 0.806 0.375 1.797 2.395HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.322 1.559 1.518 1.409 1.216 1.638 1.501 1.434 1.2401-TETA 11.392 12.975 14.107 14.075 13.354 13.401 10.153 13.748 13.019DAEP 0.426 0.224 0.652 1.052 1.477 0.312 0.097 1.047 1.571PEEDA 0.338 0.171 0.491 0.777 1.119 0.227 0.067 0.783 1.163DPE 0.378 0.162 0.370 0.148 0.166 0.178 0.103 0.153 0.172AE-TAEA 2.369 2.370 3.157 3.316 3.106 2.829 1.535 3.212 3.2511-TEPA 5.829 5.299 8.162 9.154 9.766 5.998 2.509 8.811 9.487AE-DAEP 0.502 0.250 0.590 0.924 1.403 0.326 0.060 0.968 1.481AE-PEEDA 0.347 0.087 0.124 0.292 0.486 0.090 0.044 0.282 0.455iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.232 0.275 0.287 0.246 0.088 0.181 0.082 0.038 0.044BPEA 0.378 0.316 0.172 0.212 0.728 0.108 0.026 0.237 0.689Others 6.553 3.689 8.018 10.689 12.800 5.245 2.365 11.008 12.985MEA conversion, % 52.34 45.74 62.87 72.31 78.98 51.01 30.96 74.50 81.34DETA conversion, % 38.38 32.23 43.85 49.50 54.02 35.61 21.97 48.49 53.19Acyclic(N4), % 91.74 96.30 91.16 88.66 84.05 95.43 97.74 88.44 83.06Acyclic(N5), % 84.87 89.18 90.60 88.15 82.62 92.58 94.97 88.74 82.66.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.69 0.56 0.72 0.80 0.89 0.60 0.35 0.78 0.89Acyclic(N4)/cyclic(< = N4), 4.83 8.27 4.13 3.09 2.18 7.05 12.88 3.06 2.09weight ratio__________________________________________________________________________ TABLE CXIII__________________________________________________________________________Example No. 1148 1149 1150 1151 1152 1153 1154 1155 1156__________________________________________________________________________Catalyst Type QQQQQ QQQQQ QQQQQ QQQQQ QQQQQ QQQQQ QQQQQ QQQQQ QQQQQCatalyst weight, gm 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 249.2 249.8 259.9 264.9 269.9 254.8 244.9 269.2 274.5Time on organics, hrs. 3.5 22.5 27.5 46.5 51.6 70.6 95.5 118.5 122.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.81 3.68 3.89 3.54 3.97 4.37 3.98 3.57 3.82DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 1.087 0.784 1.159 1.518 1.787 0.898 0.427 1.694 2.168MEA 18.000 23.201 17.032 13.812 11.331 21.539 28.009 12.798 9.998PIP 0.304 0.215 0.374 0.499 0.603 0.261 0.099 0.550 0.705DETA 38.387 48.461 41.116 37.786 35.688 46.385 52.406 37.936 35.454AEEA 1.924 2.613 2.539 2.224 1.893 2.489 2.034 2.026 1.642AEP 0.449 0.342 0.517 0.696 0.879 0.393 0.244 0.797 1.019HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.318 1.639 1.852 1.906 1.859 1.711 1.190 1.917 1.8861-TETA 10.672 10.861 13.747 14.589 13.661 10.892 7.078 13.335 13.840DAEP 0.198 0.087 0.200 0.337 0.533 0.121 0.037 0.403 0.653PEEDA 0.174 0.066 0.178 0.212 0.342 0.087 0.032 0.284 0.424DPE 0.179 0.118 0.179 0.221 0.417 0.120 0.055 0.352 0.139AE-TAEA 2.140 1.768 3.096 3.996 4.461 2.295 1.015 3.949 4.5571-TEPA 4.234 2.982 5.888 7.317 8.157 3.420 1.361 7.182 8.348AE-DAEP 0.296 0.057 0.409 0.400 0.522 0.133 0.088 0.409 0.588AE-PEEDA 0.088 0.000 0.334 0.106 0.146 0.036 0.000 0.096 0.134iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.160 0.104 0.269 0.268 0.263 0.116 0.063 0.216 0.185BPEA 0.267 0.172 0.142 0.179 0.194 0.048 0.026 0.155 0.204Others 4.394 1.773 5.061 7.143 9.034 3.187 4.556 7.761 10.098MEA conversion, % 45.31 36.86 54.05 62.75 69.21 40.96 23.12 65.04 72.98DETA conversion, % 30.85 21.83 34.25 39.59 42.51 24.63 14.72 38.57 43.21Acyclic(N4), % 95.59 97.86 96.54 95.52 92.30 97.45 98.50 93.60 92.81Acyclic(N5), % 88.69 93.42 88.59 92.21 91.80 94.45 93.00 92.68 92.06.SIGMA.(N5)/.SIGMA.(N4), weight ratio 0.57 0.39 0.62 0.71 0.81 0.46 0.30 0.73 0.82Acyclic(N4)/cyclic(< = N4), 9.17 15.04 10.75 8.38 5.58 12.79 17.59 6.38 5.34weight ratio__________________________________________________________________________ TABLE CXIV__________________________________________________________________________Example No. 1157 1158 1159 1160 1161 1162 1163 1164 1165__________________________________________________________________________Catalyst Type RRRRR RRRRR RRRRR RRRRR RRRRR RRRRR RRRRR RRRRR RRRRRCatalyst weight, gm 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 248.2 249.8 259.9 264.9 269.9 254.8 244.8 269.2 274.5Time on organics, hrs. 3.5 22.5 27.5 46.5 51.6 70.6 95.5 118.5 122.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 2.81 3.53 3.71 3.46 3.59 3.87 2.57 2.86 3.23DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 1.256 0.898 1.478 1.884 2.373 1.036 0.465 1.816 2.297MEA 25.808 27.657 23.849 20.875 18.992 27.163 30.642 19.820 18.074PIP 0.741 0.635 1.097 1.449 1.776 0.782 0.318 1.333 1.650DETA 46.166 50.830 44.501 41.541 37.635 48.978 54.604 40.543 39.246AEEA 1.262 1.412 1.399 1.264 1.114 1.392 1.370 1.307 1.228AEP 0.698 0.614 1.115 1.609 2.034 0.761 0.370 1.447 1.897HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.061 1.182 1.300 1.247 1.133 1.126 0.903 1.223 1.2881-TETA 6.765 6.611 7.971 8.544 8.553 6.512 4.641 8.127 8.926DAEP 0.208 0.157 0.077 0.663 0.883 0.231 0.068 0.527 0.791PEEDA 0.205 0.143 0.366 0.645 0.886 0.213 0.055 0.541 0.782DPE 0.113 0.071 0.219 0.258 0.341 0.119 0.033 0.233 0.284AE-TAEA 1.055 1.082 1.616 1.535 1.657 1.234 0.646 1.783 1.9291-TEPA 2.631 2.675 4.495 5.280 5.850 2.897 0.093 4.793 5.840AE-DAEP 0.282 0.121 0.395 0.609 0.911 0.196 0.144 0.532 0.763AE-PEEDA 0.292 0.151 0.092 0.119 0.165 0.038 0.053 0.122 0.135iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.145 0.056 0.248 0.182 0.222 0.075 0.051 0.226 0.172BPEA 0.092 0.102 0.103 0.126 0.256 0.045 0.017 0.125 0.148Others 4.080 2.114 6.330 7.633 9.871 3.590 2.398 7.053 7.859MEA Conversion, % 27.62 25.05 36.44 44.22 49.24 26.50 16.41 44.75 50.95DETA Conversion, % 23.25 18.34 29.70 34.20 40.37 21.43 11.69 33.00 36.86Acyclic(N4), % 93.68 95.43 93.13 86.19 82.11 93.10 97.23 87.77 84.60Acyclic(N5), % 81.93 89.70 87.91 86.79 82.82 92.02 73.46 86.72 86.42.SIGMA. (N5)/.SIGMA.(N4), 0.53 0.51 0.69 0.69 0.76 0.54 0.17 0.71 0.74weight ratioAcyclic(N4)/cyclic 3.97 4.80 3.20 2.11 1.63 3.62 6.55 2.28 1.88(<=N4), weight ratio__________________________________________________________________________ TABLE CXV__________________________________________________________________________Example No. 1166 1167 1168 1169 1170 1171 1172 1173 1174 1175__________________________________________________________________________Catalyst Type SSSSS SSSSS SSSSS SSSSS SSSSS SSSSS SSSSS SSSSS SSSSS SSSSSCatalyst weight, gm 50 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 249.5 259.7 254.4 264.4 269.3 279.6 249.3 259.5 260 250Time on organics, hrs. 19.5 24.5 43.5 48.5 69 73 92 97 116.3 138Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.34 5.65 6.24 6.38 8.47 6.90 6.07 5.74 6.46 5.51DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.699 0.991 0.581 0.845 0.904 1.637 0.332 0.557 0.575 0.259MEA 30.881 26.979 30.239 25.449 23.586 17.207 30.424 27.661 28.796 31.430PIP 0.175 0.376 0.190 0.382 0.461 0.971 0.111 0.252 0.248 0.099DETA 54.402 53.966 56.223 52.550 52.679 47.929 58.899 56.255 55.809 58.323AEEA 2.275 3.020 2.563 2.952 3.082 2.508 2.232 2.891 2.746 2.097AEP 0.295 0.411 0.323 0.398 0.511 0.939 0.287 0.368 0.336 0.287HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.544 0.915 0.601 0.901 1.106 1.536 0.566 0.803 0.731 0.4441-TETA 3.185 5.582 3.529 5.218 6.542 9.101 3.328 4.694 4.368 2.706DAEP 0.103 0.030 0.056 0.111 0.131 0.332 0.046 0.086 0.060 0.023PEEDA 0.033 0.040 0.046 0.025 0.026 0.319 0.036 0.039 0.032 0.026DPE 0.079 0.078 0.059 0.071 0.094 0.191 0.047 0.059 0.058 0.000AE-TAEA 0.120 0.479 0.160 0.566 0.782 1.819 0.164 0.345 0.340 0.1101-TEPA 0.223 1.046 0.335 1.448 1.933 4.344 0.305 0.748 0.777 0.175AE-DAEP 0.054 0.000 0.000 0.035 0.058 0.101 0.000 0.000 0.000 0.000AE-PEEDA 0.000 0.043 0.000 0.037 0.000 0.047 0.062 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.085 0.000 0.053 0.000 0.000 0.108 0.000 0.000 0.000 0.098BPEA 0.000 0.060 0.000 0.078 0.052 0.141 0.000 0.000 0.000 0.000Others 1.439 1.936 1.433 2.104 2.736 5.251 1.312 1.757 1.538 0.936MEA Conversion, % 13.32 26.12 16.89 28.40 35.09 53.51 17.91 24.54 21.17 13.94DETA Conversion, % 9.48 12.39 8.40 12.35 14.06 23.24 5.79 9.02 9.43 5.33Acyclic(N4), % 94.50 97.75 96.19 96.70 96.80 92.65 96.76 96.72 97.11 98.43Acyclic(N5), % 71.06 93.57 90.33 92.98 96.07 93.91 88.20 100 100 74.27.SIGMA.(N5)/.SIGMA.(N4), 0.12 0.24 0.12 0.34 0.35 0.57 0.13 0.19 0.21 0.12weight ratioAcyclic(N4)/cyclic 5.42 6.93 6.10 6.18 6.23 3.86 7.36 6.81 6.91 7.21(<=N4), weight ratio__________________________________________________________________________Example No. 1176 1177 1178 1179 1180 1181 1182 1183 1184 1185__________________________________________________________________________Catalyst Type SSSSS SSSSS SSSSS SSSSS SSSSS SSSSS SSSSS SSSSS SSSSS SSSSCatalyst weight, gm 50 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 249.9 259.7 254.4 264.4 269.3 279.6 249.3 259.5 260 250Time on organics, hrs. 19.5 24.5 43.5 48.5 69 73 92 97 116.3 138Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.31 5.47 5.77 6.00 6.06 6.55 5.78 5.50 5.21 5.66DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.745 0.944 0.594 0.847 1.030 1.615 0.327 0.590 0.591 0.329MEA 30.660 27.781 30.325 25.425 24.014 17.349 31.104 27.787 28.697 31.814PIP 0.148 0.317 0.168 0.346 0.455 0.912 0.099 0.228 0.218 0.088DETA 56.688 54.036 55.722 53.130 52.088 48.017 59.117 56.024 55.945 58.205AEEA 2.475 3.096 2.580 3.089 3.100 2.630 2.204 2.899 2.826 2.086AEP 0.299 0.420 0.298 0.379 0.470 0.914 0.261 0.367 0.346 0.274HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.588 0.879 0.588 0.969 1.022 1.530 0.489 0.798 0.714 0.4101-TETA 3.553 5.158 3.445 5.562 5.935 8.838 2.904 4.702 4.162 2.520DAEP 0.105 0.125 0.051 0.095 0.114 0.319 0.031 0.066 0.065 0.018PEEDA 0.026 0.043 0.060 0.030 0.042 0.332 0.042 0.036 0.027 0.022DPE 0.055 0.072 0.073 0.088 0.099 0.211 0.040 0.071 0.055 0.000AE-TAEA 0.066 0.361 0.137 0.513 0.679 1.746 0.102 0.299 0.261 0.0781-TEPA 0.144 0.806 0.322 1.126 1.742 3.970 0.183 0.650 0.621 0.101AE-DAEP 0.068 0.000 0.000 0.030 0.037 0.180 0.000 0.000 0.000 0.000AE-PEEDA 0.000 0.000 0.000 0.000 0.056 0.080 0.164 0.030 0.092 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.058 0.000 0.000 0.000 0.000 0.000 0.000 0.154BPEA 0.000 0.000 0.000 0.056 0.046 0.093 0.000 0.000 0.000 0.000Others 1.371 1.735 1.521 2.443 2.782 5.517 1.044 1.685 1.503 0.926MEA Conversion, % 16.17 23.60 16.23 29.21 33.10 52.96 15.90 23.93 21.18 12.82DETA Conversion, % 8.12 11.91 8.75 12.31 13.98 22.83 5.25 9.08 8.91 5.45Acyclic(N4), % 95.65 96.13 95.62 96.81 96.43 92.31 96.73 96.92 97.05 98.63Acyclic(N5), % 75.52 100.00 88.65 94.91 94.51 94.17 63.39 96.93 90.51 53.84.SIGMA.(N5)/.SIGMA.(N4), 0.06 0.18 0.12 0.25 0.35 0.54 0.12 0.17 0.19 0.11weight ratioAcyclic(N4)/cyclic 6.50 6.15 6.19 6.93 5.88 3.85 7.13 7.13 6.83 7.26(<=N4), weight ratio__________________________________________________________________________ TABLE CXVI__________________________________________________________________________Example No. 1186 1187 1188 1189 1190 1191 1192 1193 1194__________________________________________________________________________Catalyst Type TTTTT TTTTT TTTTT TTTTT TTTTT TTTTT TTTTT TTTTT TTTTTCatalyst weight, gm 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 250.1 259.9 270.4 250 250 265.4 274.9 270.4 280.5Time on organics, hrs. 49 69 73 92 117 141 145 164 168Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 6.27 5.79 6.32 6.13 5.94 5.89 5.95 6.07 6.15DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.646 0.996 1.453 0.520 0.455 1.300 2.007 1.580 2.469MEA 26.654 23.680 16.639 28.140 28.547 22.094 15.810 19.303 11.900PIP 0.159 0.228 0.386 0.099 0.087 0.283 0.468 0.350 0.631DETA 51.837 47.809 41.131 53.445 54.624 47.199 40.533 44.569 38.430AEEA 2.147 2.219 2.091 1.899 1.991 2.285 1.858 2.050 1.358AEP 0.366 0.391 0.584 0.286 0.291 0.441 0.652 0.586 1.003HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.404 1.960 2.022 1.297 1.245 1.889 1.973 1.833 2.1021-TETA 9.038 10.383 12.919 7.486 7.272 11.110 12.264 11.044 12.373DAEP 0.091 0.136 0.267 0.047 0.050 0.144 0.296 0.227 0.594PEEDA 0.049 0.069 0.074 0.030 0.025 0.066 0.089 0.070 0.162DPE 0.102 0.194 0.327 0.078 0.085 0.208 0.379 0.309 0.460AE-TAEA 1.004 1.822 3.107 0.781 0.689 1.905 3.070 2.472 3.4351-TEPA 1.515 2.906 5.194 1.189 1.007 2.936 5.147 4.012 5.957AE-DAEP 0.043 0.106 0.253 0.000 0.000 0.051 0.422 0.311 0.280AE-PEEDA 0.000 0.000 0.112 0.000 0.000 0.000 0.118 0.082 0.131iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.240 0.000 0.000 0.000 0.343 0.373 0.088BPEA 0.085 0.242 0.492 0.078 0.000 0.281 0.275 0.212 0.296Others 1.551 4.275 6.422 1.397 1.017 3.348 7.308 5.745 11.413MEA Conversion, % 27.88 35.83 54.96 23.58 22.81 40.26 56.94 48.09 67.96DETA Conversion, % 16.85 23.20 34.01 13.96 12.53 24.35 34.55 28.95 38.66Acyclic(N4), % 97.71 96.35 95.71 98.25 98.13 96.87 94.89 95.49 92.24Acyclic(N5), % 95.12 93.12 88.30 96.16 100.00 93.55 87.63 86.86 92.18.SIGMA.(N5)/.SIGMA.(N4), 0.24 0.46 0.60 0.22 0.19 0.38 0.62 0.55 0.64weight ratioAcyclic(N4)/cyclic 13.55 10.36 9.11 16.20 15.74 11.35 7.54 8.33 5.07(<=N4), weight ratio__________________________________________________________________________ Example No. 1195 1196 1197 1198 1199 1200__________________________________________________________________________ Catalyst Type TTTTT TTTTT TTTTT TTTTT TTTTT TTTTT Catalyst weight, gm 50 50 50 50 50 50 Pressure, psig 600 600 600 600 600 600 Temperature, .degree.C. 250.3 255.6 260.5 270.5 250.4 260.4 Time on organics, hrs. 187 192 212 216 235 240 Duration of run, hrs. 2 2 2 2 2 2 MEA SV, gmol/hr/kgcat 5.94 6.33 5.99 6.27 5.90 6.53 DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 Crude product composition, wt. % EDA 0.514 0.593 0.846 1.480 0.481 0.783 MEA 26.000 26.235 23.790 20.254 28.197 23.941 PIP 0.090 0.105 0.152 0.302 0.082 0.131 DETA 54.672 54.260 52.317 46.643 55.162 53.334 AEEA 1.820 1.991 2.249 2.223 1.878 2.190 AEP 0.502 0.388 0.389 0.514 0.325 0.363 HEP 0.000 0.000 0.000 0.000 0.000 0.000 TAEA 1.571 1.456 1.611 1.878 1.195 1.609 1-TETA 7.704 7.909 9.027 10.859 6.705 8.957 DAEP 0.245 0.133 0.114 0.191 0.060 0.105 PEEDA 0.053 0.083 0.108 0.084 0.049 0.099 DPE 0.106 0.143 0.171 0.268 0.122 0.180 AE-TAEA 0.748 0.777 1.110 2.057 0.628 1.062 1-TEPA 0.976 1.117 1.577 3.217 0.791 1.486 AE-DAEP 0.045 0.028 0.041 0.083 0.000 0.032 AE-PEEDA 0.151 0.102 0.121 0.043 0.195 0.055 iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 AE-DPE 0.000 0.000 0.034 0.272 0.000 0.000 BPEA 0.000 0.000 0.052 0.156 0.000 0.047 Others 2.165 1.873 2.601 4.845 1.692 2.559 MEA Conversion, % 30.21 29.38 35.76 45.44 24.03 35.94 DETA Conversion, % 13.00 13.42 16.25 25.48 11.90 15.05 Acyclic(N4), % 95.80 96.29 96.42 95.89 97.14 96.48 Acyclic(N5), % 89.71 93.54 91.50 90.44 87.86 94.96 .SIGMA.(N5)/.SIGMA.(N4), 0.19 0.20 0.26 0.43 0.19 0.24 weight ratio Acyclic(N4)/cyclic 9.28 10.96 11.35 9.35 12.35 12.00 (<=N4), weight ratio__________________________________________________________________________ TABLE CXVII__________________________________________________________________________Example No. 1201 1202 1203 1204 1205 1206 1207 1208 1209__________________________________________________________________________Catalyst Type UUUUU UUUUU UUUUU UUUUU UUUUU UUUUU UUUUU UUUUU UUUUUCatalyst weight, gm 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 250.1 259.9 270.4 250 250 285.4 274.9 270.4 280.5Time on organics, hrs. 4 24 28 47 72 96 100 120 124Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 6.18 2.34 5.82 5.84 5.69 5.51 5.75 5.84 5.73DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.917 1.897 2.108 0.590 0.434 1.245 2.140 1.671 2.735MEA 25.662 20.472 16.778 28.012 27.367 22.431 16.450 20.118 12.411PIP 0.380 0.881 1.077 0.268 0.212 0.674 1.189 0.858 1.490DETA 50.521 43.321 39.423 52.720 54.768 47.275 40.189 45.395 37.922AEEA 2.344 2.643 1.892 2.035 2.217 2.374 1.773 2.194 1.405AEP 0.461 0.807 1.116 0.369 0.357 0.675 1.147 0.885 1.698HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.220 1.437 1.468 1.065 1.114 1.421 1.395 1.422 1.5421-TETA 9.448 11.215 12.082 7.243 7.568 10.105 11.100 10.492 11.616DAEP 0.115 0.274 0.481 0.069 0.062 0.210 0.438 0.310 0.808PEEDA 0.063 0.175 0.071 0.039 0.033 0.056 0.067 0.060 0.135DPE 0.116 0.171 0.245 0.071 0.076 0.182 0.299 0.250 0.107AE-TAEA 1.057 1.803 2.308 0.672 0.602 1.534 2.154 1.795 2.3491-TEPA 2.317 4.207 5.775 1.422 1.227 3.460 5.412 4.306 6.191AE-DAEP 0.039 0.195 0.407 0.000 0.029 0.142 0.610 0.314 0.399AE-PEEDA 0.000 0.037 0.039 0.000 0.000 0.000 0.119 0.043 0.254iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.042 0.000 0.000 0.000 0.184 0.112 0.044BPEA 0.141 0.281 0.355 0.082 0.065 0.187 0.205 0.132 0.238Others 1.669 3.555 5.886 1.375 1.291 3.662 7.822 4.954 11.756MEA Conversion, % 30.62 43.66 53.48 23.36 26.31 39.42 55.00 45.87 66.59DETA Conversion, % 19.04 29.32 35.21 14.49 12.58 24.32 34.91 27.60 39.49Acyclic(N4), % 97.30 95.31 94.43 97.87 98.05 96.24 93.94 95.04 92.59Acyclic(N5), % 94.89 92.10 90.54 96.19 95.07 93.80 87.10 90.99 90.10.SIGMA.(N5)/.SIGMA.(N4), 0.32 0.49 0.62 0.25 0.21 0.44 0.65 0.53 0.66weight ratioAcyclic(N4)/cyclic 9.37 5.47 4.52 10.14 11.70 6.40 3.97 5.03 3.10(<=N4), weight ratio__________________________________________________________________________ Example No. 1210 1211 1212 1213 1214 1215__________________________________________________________________________ Catalyst Type UUUUU UUUUU UUUUU UUUUU UUUUU UUUUU Catalyst weight, gm 50 50 50 50 50 50 Pressure, psig 600 600 600 600 600 600 Temperature, .degree.C. 250.3 255.6 260.5 270.5 250.4 260.4 Time on organics, hrs. 143 148 168 172 191 196 Duration of run, hrs. 2 2 2 2 2 2 MEA SV, gmol/hr/kgcat 5.72 6.20 5.68 6.10 5.61 6.22 DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 Crude product composition, wt. % EDA 0.568 0.601 0.717 1.279 0.432 0.659 MEA 27.232 27.065 22.943 20.079 28.096 24.621 PIP 0.215 0.248 0.334 0.685 0.190 0.305 DETA 54.809 54.903 54.289 45.849 56.154 54.216 AEEA 1.865 2.067 2.397 2.218 1.939 2.262 AEP 0.495 0.410 0.506 0.739 0.377 0.454 HEP 0.000 0.000 0.000 0.000 0.000 0.000 TAEA 1.241 1.085 1.426 1.382 0.995 1.248 1-TETA 7.018 6.914 8.559 9.775 6.269 7.933 DAEP 0.201 0.100 0.168 0.247 0.071 0.112 PEEDA 0.041 0.070 0.067 0.081 0.058 0.082 DPE 0.098 0.111 0.138 0.256 0.116 0.155 AE-TAEA 0.572 0.555 0.788 1.643 0.476 0.783 1-TEPA 0.960 1.063 1.605 3.662 0.771 1.561 AE-DAEP 0.051 0.032 0.048 0.231 0.000 0.049 AE-PEEDA 0.060 0.172 0.043 0.121 0.267 0.041 iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 AE-DPE 0.000 0.000 0.000 0.398 0.000 0.000 BPEA 0.000 0.000 0.093 0.146 0.000 0.100 Others 2.205 1.668 2.622 6.639 1.610 2.481 MEA Conversion, % 26.89 26.88 38.41 46.08 24.52 33.90 DETA Conversion, % 12.77 12.07 13.61 27.01 10.57 13.72 Acyclic(N4), % 96.03 96.59 96.39 95.01 96.71 96.32 Acyclic(N5), % 93.16 88.76 92.80 85.52 82.30 92.41 .SIGMA.(N5)/.SIGMA.(N4), 0.19 0.22 0.24 0.52 0.20 0.26 weight ratio Acyclic(N4)/cyclic 7.85 8.50 8.21 5.55 8.91 8.26 (<=N4), weight ratio__________________________________________________________________________ TABLE CXVIII__________________________________________________________________________Example No. 1216 1217 1218 1219 1220 1221 1222 1223 1224__________________________________________________________________________Catalyst Type VVVVV VVVVV VVVVV VVVVV VVVVV VVVVV VVVVV VVVVV VVVVVCatalyst weight, gm 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 250.1 259.9 270.4 250 250 285.4 274.9 270.4 280.5Time on organics, hrs. 4 24 28 47 72 96 100 120 124Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.91 5.22 5.79 5.68 5.01 4.83 3.20 4.69 4.67DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 1.242 1.425 2.314 0.692 0.693 1.556 2.532 2.046 2.610MEA 24.360 19.503 13.469 26.303 26.975 19.666 10.987 15.532 8.187PIP 0.265 0.346 0.627 0.143 0.124 0.340 0.644 0.486 0.714DETA 47.368 41.906 36.625 50.994 52.751 43.552 35.351 40.568 37.477AEEA 2.338 2.228 1.775 2.093 2.109 2.236 1.595 2.030 1.250AEP 0.444 0.513 0.933 0.336 0.320 0.511 0.884 0.729 1.333HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.585 1.779 1.946 1.465 1.421 1.853 1.907 1.979 2.2171-TETA 10.818 11.971 13.853 8.981 8.541 11.616 12.837 13.039 13.746DAEP 0.137 0.201 0.508 0.073 0.066 0.184 0.434 0.315 0.805PEEDA 0.048 0.063 0.083 0.041 0.045 0.070 0.105 0.089 0.181DPE 0.147 0.053 0.357 0.113 0.106 0.275 0.379 0.354 0.142AE-TAEA 1.536 2.197 3.601 1.105 0.931 2.462 3.448 3.044 3.4871-TEPA 2.585 3.750 6.842 1.710 1.407 4.084 6.236 5.278 6.468AE-DAEP 0.039 0.075 0.609 0.000 0.000 0.281 0.507 0.443 0.547AE-PEEDA 0.000 0.041 0.143 0.000 0.040 0.099 0.122 0.116 0.102iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.108 0.388 0.000 0.000 0.319 0.127 0.215 0.099BPEA 0.201 0.347 0.305 0.127 0.079 0.340 0.272 0.259 0.272Others 2.750 3.474 9.064 1.636 1.564 5.577 8.946 7.208 12.055MEA Conversion, % 33.99 44.31 63.83 28.21 27.29 47.03 68.48 58.05 77.82DETA Conversion, % 23.91 29.07 41.70 17.49 15.71 30.46 39.88 35.04 39.81Acyclic(N4), % 97.38 97.73 94.33 97.86 97.84 96.20 94.12 95.18 93.39Acyclic(N5), % 94.47 91.20 87.83 95.68 95.12 86.28 90.39 88.94 90.68.SIGMA.(N5)/.SIGMA.(N4), 0.34 0.46 0.70 0.27 0.24 0.54 0.68 0.59 0.64weight ratioAcyclic(N4)/cyclic 11.89 11.66 6.29 14.74 15.00 9.73 6.02 7.59 5.02(<=N4), weight ratio__________________________________________________________________________ Example No. 1225 1226 1227 1228 1229 1230__________________________________________________________________________ Catalyst Type VVVVV VVVVV VVVVV VVVVV VVVVV VVVVV Catalyst weight, gm 50 50 50 50 50 50 Pressure, psig 600 600 600 600 600 600 Temperature, .degree.C. 250.3 255.6 260.5 270.5 250.4 260.4 Time on organics, hrs. 143 148 168 172 191 196 Duration of run, hrs. 2 2 2 2 2 2 MEA SV, gmol/hr/kgcat 4.55 4.85 5.47 5.78 5.58 5.91 DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 Crude product composition, wt. % EDA 0.781 0.770 0.851 1.497 0.588 1.026 MEA 25.538 22.350 20.873 16.503 25.282 24.673 PIP 0.126 0.140 0.170 0.328 0.089 0.177 DETA 52.133 52.645 51.089 44.349 55.299 51.223 AEEA 2.040 2.312 2.326 2.193 2.078 2.224 AEP 0.426 0.428 0.436 0.591 0.356 0.443 HEP 0.000 0.000 0.000 0.000 0.000 0.000 TAEA 1.593 1.735 1.861 1.981 1.469 1.571 1-TETA 8.770 9.724 10.271 11.974 8.218 9.145 DAEP 0.153 0.159 0.161 0.253 0.106 0.115 PEEDA 0.049 0.112 0.117 0.133 0.097 0.112 DPE 0.140 0.171 0.192 0.320 0.142 0.165 AE-TAEA 1.025 1.128 1.380 2.468 0.743 1.139 1-TEPA 1.452 1.623 2.028 4.244 0.949 1.722 AE-DAEP 0.053 0.044 0.047 0.312 0.000 0.000 AE-PEEDA 0.079 0.041 0.037 0.094 0.106 0.000 iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 AE-DPE 0.000 0.000 0.000 0.050 0.000 0.000 BPEA 0.000 0.100 0.106 0.197 0.000 0.030 Others 2.433 2.776 3.266 6.788 1.812 2.887 MEA Conversion, % 31.14 39.18 43.37 55.46 32.14 33.50 DETA Conversion, % 16.67 15.95 17.84 29.04 12.01 18.16 Acyclic(N4), % 96.78 96.26 96.26 95.17 96.54 96.46 Acyclic(N5), % 94.89 93.64 94.69 91.17 94.09 98.95 .SIGMA.(N5)/.SIGMA.(N4), 0.24 0.24 0.28 0.50 0.17 0.26 weight ratio Acyclic(N4)/cyclic 11.55 11.30 11.24 8.57 12.22 10.56 (<=N4), weight ratio__________________________________________________________________________ TABLE CXIX__________________________________________________________________________Example No. 1231 1232 1233 1234 1235 1236 1237__________________________________________________________________________Catalyst Type WWWWW WWWWW WWWWW WWWWW WWWWW WWWWW WWWWWCatalyst weight, gm 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600Temperature, .degree.C. 249.3 259.6 270.3 264.7 274.8 280.3 285.1Time on organics, hrs. 4 24 28 48 52 72 76Duration of run, hrs. 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 6.40 6.33 6.28 5.72 6.02 5.58 5.65DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.770 0.980 1.583 1.111 1.832 2.142 3.301MEA 25.827 23.440 17.219 22.571 16.310 16.564 10.045PIP 0.276 0.393 0.662 0.422 0.751 0.950 1.442DETA 51.636 48.836 42.304 48.278 40.898 42.099 35.503AEEA 2.334 2.504 2.372 2.475 2.126 1.936 1.055AEP 0.412 0.494 0.383 0.522 0.865 0.963 1.612HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.110 1.332 1.599 1.416 1.525 1.379 1.3081-TETA 8.696 10.460 12.736 10.690 12.202 11.061 11.624DAEP 0.101 0.165 0.378 0.173 0.369 0.370 0.792PEEDA 0.489 0.055 0.252 0.693 0.263 0.286 0.651DPE 0.112 0.134 0.073 0.039 0.086 0.085 0.110AE-TAEA 0.841 1.303 2.375 1.359 2.466 2.153 2.7711-TEPA 1.854 3.003 5.582 3.165 5.909 5.377 7.397AE-DAEP 0.000 0.051 0.359 0.070 0.646 0.658 0.827AE-PEEDA 0.000 0.000 0.040 0.031 0.109 0.115 0.423iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.112 0.049 0.000 0.057 0.476 0.079BPEA 0.093 0.263 0.619 0.150 0.427 0.359 0.296Others 1.692 2.457 4.961 2.959 6.639 6.450 12.385MEA Conversion, % 29.54 36.72 53.44 38.82 55.78 55.02 72.73DETA Conversion, % 16.50 21.84 32.20 22.43 34.26 32.23 42.86Acyclic(N4), % 97.38 97.07 95.31 97.77 95.01 94.37 89.26Acyclic(N5), % 96.65 90.95 88.16 94.71 87.09 82.38 86.19.SIGMA.(N5)/.SIGMA.(N4), 0.27 0.38 0.60 0.38 0.66 0.69 0.81weight ratioAcyclic(N4)/cyclic 10.30 9.49 6.49 9.91 5.87 4.68 2.80(<=N4), weight ratio__________________________________________________________________________ Example No. 1238 1239 1240 1241__________________________________________________________________________ Catalyst Type WWWWW WWWWW WWWWW WWWWW Catalyst weight, gm 50 50 50 50 Pressure, psig 600 600 600 600 Temperature, .degree.C. 260.4 270.3 250.7 250.8 Time on organics, hrs. 86 100 119.7 144.5 Duration of run, hrs. 2 2 2 2 MEA SV, gmol/hr/kgcat 6.24 6.17 6.94 5.93 DETA/MEA mole ratio 0.99 0.99 0.99 0.99 NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 Crude product composition, wt. % EDA 0.774 1.198 0.345 0.350 MEA 27.643 21.820 30.552 30.853 PIP 0.265 0.454 0.111 0.096 DETA 52.572 47.132 55.797 55.617 AEEA 2.172 2.317 1.696 1.611 AEP 0.359 0.551 0.258 0.247 HEP 0.000 0.000 0.000 0.000 TAEA 1.011 1.348 0.717 0.639 1-TETA 7.027 9.767 4.893 4.363 DAEP 0.081 0.178 0.044 0.039 PEEDA 0.025 0.122 0.023 0.032 DPE 0.079 0.180 0.004 0.052 AE-TAEA 0.689 1.489 0.308 0.099 1-TEPA 1.584 3.350 0.591 0.239 AE-DAEP 0.000 0.171 0.000 0.342 AE-PEEDA 0.032 0.042 0.000 0.000 iAE-PEEDA 0.000 0.000 0.000 0.000 AE-DPE 0.000 0.000 0.000 0.045 BPEA 0.036 0.063 0.000 0.000 Others 2.004 3.510 1.034 0.830 MEA Conversion, % 24.68 39.81 16.04 14.31 DETA Conversion, % 15.08 22.93 9.10 8.43 Acyclic(N4), % 97.73 95.84 98.71 97.58 Acyclic(N5), % 97.08 94.57 100.00 46.54 .SIGMA.(N5)/.SIGMA.(N4), 0.28 0.44 0.15 0.14 weight ratio Acyclic(N4)/cyclic 9.90 7.47 12.67 10.70 (<=N4), weight ratio__________________________________________________________________________ TABLE CXX__________________________________________________________________________Example No. 1242 1243 1244 1245 1246 1247 1248 1249 1250 1251__________________________________________________________________________Catalyst Type XXXXX XXXXX XXXXX XXXXX XXXXX XXXXX XXXXX XXXXX XXXXX XXXXXCatalyst weight, gm 50 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 400 600 600 600 600 600 600Temperature, .degree.C. 249.3 259.6 270.3 264.7 274.8 280.3 285.1 270.3 250.7 250.8Time on organics, hrs. 4 24 28 48 52 72 76 100 119.7 144.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 6.17 5.95 5.82 5.54 5.88 4.57 6.15 6.07 7.05 5.82DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composi-tion, wt. %EDA 0.893 1.185 1.874 1.443 2.387 2.639 3.678 1.556 0.481 0.515MEA 23.997 21.165 15.053 20.703 14.059 13.349 8.387 18.730 28.844 29.482PIP 0.250 0.368 0.597 0.409 0.727 0.812 1.108 0.435 0.112 0.093DETA 50.182 46.524 39.414 45.397 38.993 39.116 35.238 42.781 53.913 53.627AEEA 2.411 2.498 2.085 2.340 1.699 1.499 0.681 2.101 1.876 1.810AEP 0.422 0.510 0.810 0.527 0.904 1.012 1.488 0.535 0.274 0.244HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.425 1.775 1.846 1.795 1.800 1.721 1.514 1.777 1.179 1.0181-TETA 10.191 11.986 13.100 11.628 12.524 12.091 11.574 10.990 6.600 5.769DAEP 0.109 0.185 0.375 0.187 0.419 0.473 0.929 0.206 0.053 0.044PEEDA 0.063 0.051 0.228 0.118 0.266 0.306 0.601 0.128 0.026 0.066DPE 0.125 0.171 0.107 0.060 0.110 0.107 0.462 0.286 0.080 0.066AE-TAEA 1.294 2.017 3.232 2.258 3.432 3.203 3.391 2.731 0.694 0.4901-TEPA 2.267 3.609 6.173 3.897 6.441 6.147 7.234 4.636 1.042 0.691AE-DAEP 0.031 0.048 0.524 0.080 0.621 0.625 0.927 0.399 0.000 0.000AE-PEEDA 0.000 0.033 0.108 0.047 0.094 0.111 0.467 0.157 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.236 0.000 0.224 0.275 0.049 0.299 0.000 0.000BPEA 0.045 0.106 0.552 0.282 0.617 0.594 0.195 0.235 0.000 0.000Others 1.906 3.042 6.857 3.249 7.904 8.181 13.108 5.468 1.100 0.978MEA Conversion, % 34.77 42.76 59.22 43.57 62.03 63.61 77.16 48.81 21.06 17.89DETA Conversion, % 19.07 25.41 36.70 26.65 37.57 36.79 43.13 30.69 12.53 11.46Acyclic(N4), % 97.49 97.11 95.45 97.33 94.73 93.96 86.78 95.35 97.98 97.44Acyclic(N5), % 97.89 96.76 86.87 93.75 86.37 85.33 86.62 87.08 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.30 0.41 0.69 0.47 0.75 0.74 0.81 0.63 0.21 0.16weight ratioAcyclic(N4)/cyclic 11.96 10.68 7.04 10.28 5.89 5.09 2.85 8.01 14.23 13.14(<=N4), weight ratio__________________________________________________________________________ TABLE CXXI__________________________________________________________________________ComparativeExample No. 1252 1253 1254 1255 1256 1257 1258 1259 1260__________________________________________________________________________Catalyst Type YYYYY YYYYY YYYYY YYYYY YYYYY YYYYY YYYYY YYYYY YYYYYCatalyst weight, gm 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 251 250.5 260.7 265.6 270.4 275.8 280.5 255.8 245.6Time on organics, hrs. 4 23.5 27.5 46.5 51.5 70.5 75.5 95.5 119.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 3.47 3.80 3.91 3.78 4.01 3.87 4.12 3.34 3.15DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 2.846 1.526 2.032 1.886 2.080 2.055 2.349 0.725 0.430MEA 20.117 22.677 18.757 16.307 13.974 13.175 11.612 25.948 29.403PIP 0.388 0.256 0.499 0.640 0.773 0.847 0.969 0.218 0.102DETA 38.752 46.030 41.118 41.094 35.948 37.509 34.665 52.792 56.722AEEA 2.423 3.036 3.076 3.058 2.464 2.253 1.745 3.079 2.412AEP 0.532 0.351 0.611 0.804 0.961 1.106 1.326 0.327 0.250HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.913 0.960 1.193 1.429 1.379 1.405 1.366 0.793 0.4801-TETA 6.883 7.323 9.136 10.360 9.961 9.612 9.046 5.680 3.493DAEP 0.130 0.038 0.254 0.343 0.479 0.517 0.769 0.100 0.049PEEDA 0.188 0.076 0.217 0.124 0.154 0.084 0.662 0.074 0.036DPE 0.150 0.132 0.325 0.319 0.397 0.361 0.120 0.153 0.089AE-TAEA 0.216 0.137 1.821 0.185 0.244 0.207 2.472 0.625 0.3491-TEPA 0.296 2.808 4.728 6.414 7.260 6.994 7.086 2.162 0.887AE-DAEP 0.731 0.413 0.156 0.157 0.197 0.176 1.016 0.226 0.078AE-PEEDA 0.175 0.237 0.215 0.263 0.406 0.407 0.313 0.082 0.031iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.291 0.147 0.259 0.254 0.453 0.383 0.175 0.036 0.138BPEA 0.199 0.113 0.345 0.433 0.745 0.091 0.611 0.033 0.000Others 16.400 7.123 10.349 11.322 15.766 15.360 16.327 3.878 2.051MEA Conversion, % 43.51 37.03 49.65 56.66 62.55 64.22 68.78 30.04 19.95DETA Conversion, % 35.49 24.23 34.57 35.26 42.89 39.62 44.75 15.62 8.46Acyclic(N4), % 94.31 97.10 92.83 93.73 91.66 91.95 87.02 95.16 95.77Acyclic(N5), % 26.85 76.39 87.03 85.62 80.62 87.19 81.87 88.03 83.29.SIGMA.(N5)/.SIGMA.(N4), 0.23 0.45 0.67 0.61 0.75 0.68 0.97 0.46 0.35weight ratioAcyclic(N4)/cyclic 5.60 9.69 5.41 5.27 4.09 3.77 2.70 7.39 7.51(<=N4), weight ratio__________________________________________________________________________ TABLE CXXII__________________________________________________________________________Example No. 1261 1262 1263 1264 1265 1266 1267 1268 1269 1270__________________________________________________________________________Catalyst Type ZZZZZ ZZZZZ ZZZZZ ZZZZZ ZZZZZ ZZZZZ ZZZZZ ZZZZZ ZZZZZ ZZZZZCatalyst weight, gm 50 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 249.5 259.7 254.4 264.4 269.3 279.6 249.3 259.5 260 250Time on organics, hrs. 19.5 24.5 43.5 48.5 69 73 72 97 116.3 138Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.54 5.44 6.26 6.35 6.68 6.95 6.07 5.74 6.22 5.52DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composi-tion, wt. %EDA 0.557 0.797 0.461 0.645 0.777 1.221 0.258 0.400 0.408 0.214MEA 32.336 29.295 31.431 27.011 27.058 20.206 31.252 29.183 29.037 32.707PIP 0.147 0.336 0.159 0.315 0.434 0.832 0.093 0.216 0.197 0.088DETA 56.556 55.334 57.257 55.289 54.631 50.585 59.566 57.321 57.294 59.411AEEA 2.101 2.829 2.340 2.851 2.944 2.743 2.003 2.673 2.620 1.871AEP 0.307 0.366 0.271 0.435 0.440 0.778 0.285 0.332 0.318 0.272HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.432 0.692 0.443 0.736 0.748 1.212 0.436 0.516 0.547 0.2801-TETA 2.629 4.380 2.617 4.340 4.427 7.328 2.476 3.221 3.344 1.831DAEP 0.162 0.122 0.053 0.087 0.088 0.243 0.039 0.054 0.055 0.074PEEDA 0.052 0.024 0.046 0.028 0.021 0.247 0.029 0.027 0.030 0.025DPE 0.000 0.064 0.078 0.068 0.075 0.145 0.031 0.045 0.039 0.000AE-TAEA 0.082 0.270 0.095 0.335 0.461 1.255 0.092 0.152 0.245 0.0601-TEPA 0.033 0.668 0.303 0.856 1.340 3.408 0.229 0.413 0.661 0.085AE-DAEP 0.083 0.027 0.000 0.020 0.058 0.215 0.000 0.000 0.000 0.000AE-PEEDA 0.055 0.000 0.000 0.000 0.000 0.025 0.075 0.161 0.184 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.106 0.000 0.000 0.000 0.000 0.087 0.000 0.000 0.000 0.118BPEA 0.000 0.000 0.000 0.000 0.036 0.100 0.000 0.000 0.000 0.000Others 1.554 1.558 1.509 1.685 2.059 3.632 1.368 1.728 1.572 0.679MEA Conversion, % 11.54 20.03 14.00 24.93 25.58 44.77 15.58 20.02 20.56 10.86DETA Conversion, % 8.29 10.46 7.13 8.91 10.93 18.03 4.61 6.87 7.07 4.01Acyclic(N4), % 93.44 95.99 94.48 96.48 96.52 93.06 96.66 96.71 96.87 95.47Acyclic(N5), % 32.06 97.13 100.00 98.26 94.89 91.56 80.95 77.80 83.06 55.28.SIGMA.(N5)/.SIGMA.(N4), 0.11 0.18 0.12 0.23 0.34 0.55 0.13 0.18 0.27 0.11weight ratioAcyclic(N4)/cyclic 4.57 5.54 5.02 5.42 4.87 3.80 6.08 5.53 6.06 4.58(<=N4), weight ratio__________________________________________________________________________ TABLE CXXIII__________________________________________________________________________ComparativeExample No. 1271 1272 1273 1274 1275 1276 1277 1278 1279__________________________________________________________________________Catalyst Type AAAAAA AAAAAA AAAAAA AAAAAA AAAAAA AAAAAA AAAAAA AAAAAA AAAAAACatalyst weight, 50 50 50 50 50 50 50 50 50gmPressure, psig 600 600 600 400 600 600 600 600 600Temperature, .degree.C. 251 250.5 260.7 265.6 270.4 275.8 280.5 255.8 245.5Time on organics, 4 23.5 27.5 46.5 51.5 70.5 75.5 95.5 119.5hrs.Duration of run, 2 2 2 2 2 2 2 2 2hrs.MEA SV, gmol/ 3.46 3.96 3.89 3.66 3.88 3.96 4.00 3.97 4.04hr/kgcatDETA/MEA 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99mole ratioNH.sub.3 /MEA 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98mole ratioCrude productcomposition,wt. %EDA 0.569 0.369 0.606 0.790 0.904 1.370 1.436 0.353 0.165MEA 22.906 25.594 20.285 17.926 14.593 14.303 12.427 26.475 30.271PIP 0.366 0.218 0.401 0.561 0.667 1.037 1.090 0.220 0.079DETA 50.355 54.133 48.370 47.753 41.854 42.262 40.213 53.453 59.022AEEA 2.955 3.393 3.649 3.648 2.988 2.426 1.989 2.794 2.193AEP 0.473 0.305 0.456 0.607 0.722 1.086 1.211 0.306 0.236HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.254 1.114 1.436 1.582 1.518 1.586 1.556 0.732 0.4471-TETA 7.783 6.913 9.002 9.975 9.612 10.518 10.362 4.586 2.655DAEP 0.122 0.065 0.137 0.196 0.312 0.449 0.543 0.081 0.040PEEDA 0.065 0.039 0.117 0.171 0.130 0.064 0.515 0.067 0.029DPE 0.063 0.049 0.181 0.170 0.302 0.281 0.115 0.161 0.062AE-TAEA 0.161 0.112 1.712 1.846 2.488 0.152 2.426 0.607 0.1791-TEPA 2.457 1.842 3.712 4.439 5.404 6.285 6.578 1.410 0.198AE-DAEP 0.059 0.063 0.165 0.212 0.623 0.154 0.685 0.248 0.065AE-PEEDA 0.059 0.025 0.138 0.103 0.359 0.325 0.207 0.152 0.036iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.044 0.028 0.236 0.276 0.341 0.169 0.351 0.184 0.138BPEA 0.025 0.049 0.166 0.271 0.792 0.439 0.423 0.121 0.000Others 3.746 2.581 5.592 4.546 10.542 10.867 9.666 4.479 1.866MEA Conver- 36.31 30.93 45.92 51.83 60.98 61.53 66.10 28.20 17.97sion, %DETA Conver- 17.00 13.40 23.56 23.94 33.65 32.63 34.97 14.06 5.18sion, %Acyclic(N4), % 97.29 98.10 95.97 95.54 93.72 93.83 91.02 94.48 95.88Acyclic(N5), % 93.26 92.16 88.46 87.92 78.84 85.42 84.36 74.04 61.21.SIGMA.(N5)/.SIGMA.(N4), 0.30 0.25 0.56 0.59 0.84 0.58 0.81 0.48 0.19weight ratioAcyclic(N4)/ 8.28 11.82 8.06 6.76 5.21 4.14 3.42 6.35 6.89cyclic(<=N4),weight ratio__________________________________________________________________________ TABLE CXXIV__________________________________________________________________________Comparative Example No. 1280 1281 1282 1283 1284 1285 1286 1287 1288__________________________________________________________________________Catalyst Type BBBBBB BBBBBB BBBBBB BBBBBB BBBBBB BBBBBB BBBBBB BBBBBB BBBBBBCatalyst weight, gm 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 400 600 600 600 600 600Temperature, .degree.C. 251 250.5 260.7 265.6 270.4 275.8 280.5 255.8 245.5Time on organics, hrs. 4 23.5 27.5 46.5 51.5 70.5 75.5 95.5 119.5Duration of run, hrs. 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.35 4.44 4.56 3.97 4.31 4.29 4.42 3.99 4.38DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.129 0.034 0.081 0.130 0.184 0.319 0.432 0.086 0.044MEA 31.011 33.961 32.995 30.431 29.013 27.475 26.166 30.793 34.503PIP 0.136 0.085 0.172 0.302 0.423 0.645 0.863 0.155 0.069DETA 59.305 59.998 58.455 58.206 56.825 54.579 51.202 55.790 59.775AEEA 1.084 1.095 1.515 1.846 1.989 2.043 1.872 1.338 0.780AEP 0.308 0.219 0.266 0.335 0.419 0.580 0.708 0.282 0.209HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.432 0.292 0.389 0.566 0.673 0.798 0.785 0.390 0.2231-TETA 2.508 1.580 1.972 2.905 3.532 4.375 4.754 2.170 1.109DAEP 0.065 0.025 0.043 0.060 0.080 0.127 0.290 0.149 0.046PEEDA 0.047 0.029 0.037 0.051 0.085 0.146 0.239 0.084 0.027DPE 0.022 0.038 0.057 0.072 0.080 0.101 0.100 0.221 0.018AE-TAEA 0.305 0.284 0.525 0.127 0.137 1.094 0.823 0.664 0.1071-TEPA 0.579 0.428 0.478 1.062 1.431 1.985 2.525 1.037 0.075AE-DAEP 0.063 0.194 0.053 0.066 0.116 0.232 0.666 0.600 0.000AE-PEEDA 0.000 0.000 0.050 0.039 0.034 0.106 0.169 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.053 0.078 0.027 0.063 0.028 0.045 0.037 0.417 0.201BPEA 0.035 0.000 0.000 0.021 0.040 0.046 0.045 0.037 0.000Others 1.348 0.783 1.767 2.309 2.800 3.375 4.038 3.468 0.757MEA Conversion, % 15.65 8.73 11.34 18.47 22.00 26.74 28.82 16.92 5.92DETA Conversion, % 4.38 4.41 6.89 7.56 9.44 13.72 17.43 10.77 3.38Acyclic(N4), % 95.58 95.25 94.45 94.94 94.46 93.24 89.79 84.87 93.55Acyclic(N5), % 85.28 72.27 88.43 86.18 87.68 87.70 78.48 61.69 47.55.SIGMA.(N5)/.SIGMA.(N4), 0.33 0.50 0.45 0.37 0.40 0.63 0.69 0.91 0.26weight ratioAcyclic(N4)/cyclic 5.06 4.70 4.08 4.22 3.85 3.23 2.51 2.86 3.60(< = N4), weight ratio__________________________________________________________________________ TABLE CXXV__________________________________________________________________________Example No. 1289 1290 1291 1292 1293 1294 1295__________________________________________________________________________Catalyst Type CCCCCC CCCCCC CCCCCC CCCCCC CCCCCC CCCCCC CCCCCCCatalyst weight, gm 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600Temperature, .degree.C. 249.4 250.2 260.0 264.8 274.3 269.7 279.6Time on organics, hrs. 3.5 22.5 27.0 46.5 50.5 70.5 74.5Duration of run, hrs. 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.87 5.72 6.05 6.00 6.02 5.98 5.04DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 1.519 0.694 1.216 1.280 2.428 1.153 2.115MEA 31.506 32.042 30.354 30.605 27.717 30.601 23.296PIP 0.817 0.572 1.053 1.075 1.986 0.958 1.628DETA 49.429 53.921 50.152 49.725 43.594 50.450 38.887AEEA 0.896 0.966 1.015 0.991 0.957 1.013 0.855AEP 0.642 0.422 0.770 0.803 1.591 0.760 1.481HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.734 0.732 0.884 0.820 0.779 0.837 0.7581-TETA 4.465 4.271 5.695 5.262 5.911 5.274 5.499DAEP 0.173 0.090 0.194 0.193 0.476 0.176 0.452PEEDA 0.153 0.064 0.187 0.199 0.589 0.178 0.544DPE 0.059 0.026 0.052 0.062 0.131 0.056 0.168AE-TAEA 0.538 0.468 0.781 0.769 0.931 0.682 0.9871-TEPA 1.798 1.534 2.851 2.784 3.990 2.531 3.812AE-DAEP 0.111 0.079 0.177 0.165 0.389 0.088 0.463AE-PEEDA 0.165 0.051 0.105 0.092 0.193 0.074 0.275iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.105BPEA 0.000 0.000 0.090 0.098 0.188 0.085 0.308Others 2.487 1.092 2.264 2.409 4.492 2.276 5.439MEA Conversion, % 12.79 12.53 18.53 17.36 25.28 17.17 30.93DETA Conversion, % 18.89 12.74 20.21 20.40 30.33 19.05 31.65Acyclic(N4), % 93.08 96.49 93.79 93.03 84.81 93.68 84.30Acyclic(N5), % 89.40 93.87 90.65 90.87 86.46 92.82 80.64.SIGMA.(N5)/.SIGMA.(N4), 0.46 0.41 0.57 0.59 0.72 0.53 0.80weight ratioAcyclic(N4)/cyclic 2.81 4.25 2.91 2.60 1.40 2.86 1.46(< = N4), weight ratio__________________________________________________________________________ Example No. 1296 1297 1298 1299__________________________________________________________________________ Catalyst Type CCCCCC CCCCCC CCCCCC CCCCCC Catalyst weight, gm 50 50 50 50 Pressure, psig 600 600 600 600 Temperature, .degree.C. 254.9 265.5 250.0 250.0 Time on organics, hrs. 94.5 98.5 118.0 142.0 Duration of run, hrs. 2 2 2 2 MEA SV, gmol/hr/kgcat 5.89 5.99 5.66 5.83 DETA/MEA mole ratio 0.99 0.99 0.99 0.99 NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 Crude product composition, wt. % EDA 0.252 0.488 0.120 0.078 MEA 33.872 32.164 35.051 35.546 PIP 0.224 0.444 0.105 0.071 DETA 57.536 55.374 59.521 60.251 AEEA 0.774 1.009 0.339 0.338 AEP 0.293 0.430 0.243 0.206 HEP 0.000 0.000 0.000 0.000 TAEA 0.520 0.767 0.322 0.235 1-TETA 2.760 4.241 1.727 1.284 DAEP 0.039 0.095 0.000 0.000 PEEDA 0.025 0.099 0.000 0.000 DPE 0.000 0.044 0.000 0.000 AE-TAEA 0.185 0.411 0.000 0.000 1-TEPA 0.440 1.232 0.000 0.000 AE-DAEP 0.000 0.000 0.000 0.000 AE-PEEDA 0.000 0.000 0.000 0.000 iAE-PEEDA 0.000 0.000 0.000 0.000 AE-DPE 0.000 0.000 0.000 0.000 BPEA 0.000 0.000 0.000 0.000 Others 0.924 1.213 0.418 0.337 MEA Conversion, % 7.75 13.08 4.17 3.21 DETA Conversion, % 7.11 11.29 3.53 2.74 Acyclic(N4), % 98.06 95.42 100.00 100.00 Acyclic(N5), % 100.00 100.00 0.00 0.00 .SIGMA.(N5)/.SIGMA.(N4), 0.18 0.31 0.00 0.00 weight ratio Acyclic(N4)/cyclic 5.63 4.49 5.88 5.47 (< = N4), weight ratio__________________________________________________________________________ TABLE CXXVI__________________________________________________________________________Example No. 1300 1301 1302 1303 1304__________________________________________________________________________Catalyst Type DDDDDD DDDDDD DDDDDD DDDDDD DDDDDDCatalyst weight, gm 50 50 50 50 50Pressure, psig 600 600 600 600 600Temperature, .degree.C. 249.4 260.0 264.8 274.3 269.7Time on organics, hrs. 3.5 27.0 46.5 50.5 70.5Duration of run, hrs. 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.19 6.09 7.07 6.15 6.06DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 2.846 2.162 2.521 3.371 2.410MEA 28.451 28.405 27.689 22.373 26.870PIP 0.292 0.311 0.356 0.675 0.375DETA 47.215 49.052 48.027 42.085 47.503AEEA 1.527 1.477 1.552 1.306 1.542AEP 0.394 0.489 0.563 0.836 0.604HEP 0.000 0.000 0.000 0.000 0.000TAEA 0.805 0.950 0.969 1.115 1.0321-TETA 6.223 6.861 7.071 8.458 7.313DAEP 0.139 0.130 0.150 0.290 0.155PEEDA 0.054 0.065 0.083 0.181 0.089DPE 0.186 0.172 0.213 0.359 0.226AE-TAEA 0.595 0.826 0.906 1.543 0.9421-TEPA 1.190 1.632 1.751 3.174 1.795AE-DAEP 0.075 0.104 0.098 0.253 0.091AE-PEEDA 0.356 0.187 0.182 0.431 0.151iAE-PEEDA 0.000 0.000 0.000 0.000 0.000AE-DPE 0.079 0.083 0.070 0.063 0.065BPEA 0.000 0.062 0.081 0.053 0.103Others 4.635 4.013 4.427 8.254 4.444MEA Conversion, % 21.20 23.10 24.95 39.09 26.53DETA Conversion, % 22.48 21.28 22.83 32.08 23.00Acyclic(N4), % 94.87 95.49 94.72 92.01 94.64Acyclic(N5), % 77.74 84.86 85.97 85.46 86.94.SIGMA.(N5)/.SIGMA.(N4), 0.31 0.35 0.36 0.53 0.35weight ratioAcyclic(N4)/cyclic 6.58 6.67 5.87 4.08 5.74(< = N4), weight ratio__________________________________________________________________________Example No. 1305 1306 1307 1308 1309__________________________________________________________________________Catalyst Type DDDDDD DDDDDD DDDDDD DDDDDD DDDDDDCatalyst weight, gm 50 50 50 50 50Pressure, psig 600 600 600 600 600Temperature, .degree.C. 279.6 250.0 265.5 250.0 250.0Time on organics, hrs. 74.5 94.5 98.5 118.0 142.0Duration of run, hrs. 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.36 5.94 6.02 5.71 6.05DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 3.708 0.958 1.667 0.727 0.656MEA 19.491 30.997 27.854 33.177 33.332PIP 0.711 0.117 0.226 0.073 0.061DETA 38.192 54.844 50.639 55.737 56.938AEEA 1.289 1.199 1.503 0.934 0.936AEP 0.971 0.390 0.530 0.340 0.348HEP 0.000 0.000 0.000 0.000 0.000TAEA 1.206 0.726 1.030 0.478 0.4611-TETA 8.977 4.883 6.759 3.252 3.068DAEP 0.368 0.054 0.112 0.000 0.000PEEDA 0.248 0.048 0.059 0.046 0.037DPE 0.502 0.080 0.180 0.036 0.025AE-TAEA 1.789 0.306 0.113 0.129 0.0721-TEPA 3.752 0.447 1.274 0.082 0.419AE-DAEP 0.309 0.000 0.036 0.000 0.000AE-PEEDA 0.490 0.000 0.085 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000AE-DPE 0.158 0.101 0.121 0.309 0.000BPEA 0.135 0.034 0.144 0.000 0.000Others 10.424 2.167 4.231 1.493 1.571MEA Conversion, % 46.19 15.71 24.30 8.77 9.35DETA Conversion, % 37.50 11.59 18.42 9.14 8.20Acyclic(N4), % 90.09 96.84 95.68 97.81 98.24Acyclic(N5), % 83.49 84.65 78.19 40.69 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.58 0.15 0.21 0.13 0.13weight ratioAcyclic(N4)/cyclic 3.63 8.11 7.02 7.50 7.46(< = N4), weight ratio__________________________________________________________________________ TABLE CXXVII__________________________________________________________________________Example No. 1310 1311 1312 1313 1314 1315 1316__________________________________________________________________________Catalyst Type EEEEEE EEEEEE EEEEEE EEEEEE EEEEEE EEEEEE EEEEEECatalyst weight, gm 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600Temperature, .degree.C. 249.4 250.2 260.0 264.8 274.3 269.7 279.6Time on organics, hrs. 3.5 22.5 27.0 46.5 50.5 70.5 74.5Duration of run, hrs. 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 4.96 5.31 5.56 5.64 5.56 5.51 5.09DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.654 0.449 0.757 0.960 1.686 1.190 2.015MEA 27.386 29.344 25.472 23.704 17.028 22.148 12.850PIP 0.229 0.158 0.318 0.417 0.765 0.526 0.925DETA 53.639 55.586 52.752 50.945 45.979 49.847 40.504AEEA 2.419 2.339 2.764 2.728 2.360 2.672 1.772AEP 0.319 0.268 0.391 0.468 0.851 0.568 1.059HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.067 0.826 1.226 1.323 1.677 1.416 1.7281-TETA 6.467 4.920 7.114 7.589 9.995 8.115 10.503DAEP 0.088 0.062 0.117 0.137 0.317 0.176 0.437PEEDA 0.054 0.044 0.081 0.083 0.227 0.154 0.396DPE 0.045 0.029 0.068 0.096 0.188 0.128 0.297AE-TAEA 0.685 0.395 1.040 1.239 2.283 1.495 2.7741-TEPA 1.252 0.683 2.067 2.357 4.522 2.895 5.506AE-DAEP 0.000 0.000 0.099 0.104 0.276 0.134 0.596AE-PEEDA 0.031 0.000 0.000 0.034 0.087 0.038 0.220iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.089 0.000 0.165BPEA 0.098 0.000 0.136 0.132 0.363 0.186 0.107Others 1.308 1.020 1.910 2.415 4.738 3.325 7.889MEA Conversion, % 24.85 19.33 30.93 34.91 53.54 39.67 63.95DETA Conversion, % 12.74 9.41 15.20 17.07 25.63 19.50 32.65Acyclic(N4), % 97.56 97.67 96.88 96.55 94.09 95.39 91.54Acyclic(N5), % 93.71 100.00 92.95 92.97 89.29 92.45 88.36.SIGMA.(N5)/.SIGMA.(N4), 0.26 0.18 0.38 0.41 0.61 0.47 0.70weight ratioAcyclic(N4)/cyclic 10.21 10.19 8.53 7.40 4.96 6.13 3.92(< = N4), weight ratio__________________________________________________________________________ Example No. 1317 1318 1319 1320__________________________________________________________________________ Catalyst Type EEEEEE EEEEEE EEEEEE EEEEEE Catalyst weight, gm 50 50 50 50 Pressure, psig 600 600 600 600 Temperature, .degree.C. 254.9 265.5 250.0 250.0 Time on organics, hrs. 94.5 98.5 118.0 142.0 Duration of run, hrs. 2 2 2 2 MEA SV, gmol/hr/kgcat 5.43 5.54 5.23 5.37 DETA/MEA mole ratio 0.99 0.99 0.99 0.99 NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 Crude product composition, wt. % EDA 0.476 0.898 0.343 0.351 MEA 28.641 23.935 30.296 30.702 PIP 0.165 0.377 0.111 0.109 DETA 56.024 51.376 57.092 57.637 AEEA 2.377 2.731 2.066 2.049 AEP 0.297 0.452 0.262 0.268 HEP 0.000 0.000 0.000 0.000 TAEA 0.900 1.406 0.710 0.675 1-TETA 4.990 7.814 3.954 3.695 DAEP 0.057 0.137 0.044 0.052 PEEDA 0.040 0.081 0.029 0.052 DPE 0.045 0.106 0.037 0.032 AE-TAEA 0.419 1.182 0.238 0.195 1-TEPA 0.703 2.253 0.393 0.295 AE-DAEP 0.000 0.079 0.000 0.000 AE-PEEDA 0.000 0.000 0.000 0.000 iAE-PEEDA 0.000 0.000 0.000 0.000 AE-DPE 0.000 0.000 0.525 0.202 BPEA 0.000 0.130 0.000 0.000 Others 1.257 2.793 1.201 1.290 MEA Conversion, % 21.61 34.98 17.69 16.70 DETA Conversion, % 9.10 17.26 8.05 7.29 Acyclic(N4), % 97.62 96.58 97.64 96.94 Acyclic(N5), % 100.00 94.22 54.59 70.75 .SIGMA.(N5)/.SIGMA.(N4), 0.18 0.38 0.24 0.15 weight ratio Acyclic(N4)/cyclic 9.70 7.96 9.58 8.47 (< = N4), weight ratio__________________________________________________________________________ TABLE CXXVIII__________________________________________________________________________Example No. 1321 1322 1323 1324 1325 1326 1327 1328 1329 1330__________________________________________________________________________Catalyst Type FFFFFF FFFFFF FFFFFF FFFFFF FFFFFF FFFFFF FFFFFF FFFFFF FFFFFF FFFFFFCatalyst weight, gm 50 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 250.7 260.9 265.9 275.6 270.7 280.7 255.9 266.0 250.0 250.0Time on organics, hrs. 24 28 48 52 72 76 96 100 119 143Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.63 5.74 3.32 5.65 5.42 5.49 5.53 5.57 5.89 5.93DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composi-tion, wt. %EDA 0.903 1.402 1.768 2.544 1.835 3.073 0.888 1.294 0.515 0.506MEA 25.752 20.894 16.605 12.576 17.830 10.281 26.167 20.923 27.453 29.003PIP 0.219 0.362 0.507 0.711 0.498 0.901 0.187 0.353 0.106 0.103DETA 50.036 46.155 42.553 38.126 43.798 37.053 51.456 47.042 54.880 54.395AEEA 1.893 2.170 2.124 1.446 1.873 1.003 2.038 2.036 1.893 1.661AEP 0.352 0.501 0.668 0.969 0.662 1.189 0.334 0.490 0.278 0.267HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.345 1.686 1.782 1.715 1.776 1.699 1.361 1.719 1.214 1.0391-TETA 9.150 11.543 12.441 12.696 11.873 12.762 8.128 10.831 7.041 5.981DAEP 0.123 0.212 0.297 0.536 0.298 0.703 0.088 0.187 0.057 0.051PEEDA 0.063 0.115 0.173 0.315 0.175 0.078 0.051 0.100 0.035 0.035DPE 0.076 0.135 0.211 0.313 0.079 0.133 0.082 0.072 0.048 0.060AE-TAEA 1.447 2.123 2.635 3.323 2.723 3.556 1.164 2.237 0.691 0.5651-TEPA 2.439 3.738 4.737 6.407 4.814 6.968 1.786 3.880 0.956 0.711AE-DAEP 0.033 0.115 0.343 0.446 0.192 0.758 0.000 0.081 0.000 0.000AE-PEEDA 0.000 0.048 0.132 0.326 0.068 0.357 0.000 0.045 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.062 0.077 0.106 0.119 0.091 0.112 0.000 0.000 0.000 0.000BPEA 0.198 0.376 0.163 0.712 0.593 0.257 0.112 0.102 0.000 0.000Others 1.859 3.207 5.566 8.060 4.576 10.826 1.993 3.228 1.156 1.187MEA Conversion, % 30.00 43.32 54.48 65.46 51.49 72.02 28.58 43.01 25.09 19.91DETA Conversion, % 19.37 25.78 30.84 37.92 29.36 40.22 16.74 24.04 11.23 10.95Acyclic(N4), % 97.54 96.61 95.41 92.51 96.10 94.03 97.71 97.19 98.32 97.94Acyclic(N5), % 92.96 90.47 90.82 85.91 88.84 87.63 96.33 96.38 100.00 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.38 0.47 0.54 0.72 0.59 0.78 0.31 0.49 0.19 0.17weight ratioAcyclic(N4)/cyclic 12.56 9.96 7.65 5.06 7.95 4.80 12.76 10.41 15.69 13.56(< = N4), weight ratio__________________________________________________________________________ TABLE CXXIX__________________________________________________________________________Example No. 1331 1332 1333 1334 1335__________________________________________________________________________Catalyst Type GGGGGG GGGGGG GGGGGG GGGGGG GGGGGGCatalyst weight, gm 50 50 50 50 50Pressure, psig 600 600 600 600 600Temperature, .degree.C. 250.9 260.9 265.9 275.6 270.7Time on organics, hrs. 24 28 48 52 72Duration of run, hrs. 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.32 5.25 5.18 5.19 5.09DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.592 1.050 1.170 2.045 1.486MEA 27.184 23.113 22.344 15.162 21.294PIP 0.127 0.270 0.291 0.551 0.372DETA 53.615 49.172 48.478 41.150 47.716AEEA 2.106 2.326 2.191 1.866 2.144AEP 0.280 0.388 0.415 0.715 0.489HEP 0.000 0.000 0.000 0.000 0.000TAEA 1.264 1.608 1.571 1.888 1.6861-TETA 7.794 10.144 9.823 12.185 10.176DAEP 0.076 0.137 0.147 0.347 0.166PEEDA 0.034 0.074 0.089 0.211 0.099DPE 0.045 0.094 0.134 0.118 0.156AE-TAEA 0.814 0.589 1.649 2.952 1.9651-TEPA 1.274 2.726 2.848 5.423 3.349AE-DAEP 0.000 0.000 0.086 0.479 0.108AE-PEEDA 0.000 0.000 0.029 0.188 0.035iAE-PEEDA 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.073 0.100 0.119 0.079BPEA 0.000 0.199 0.189 0.565 0.277Others 1.237 2.368 2.867 7.018 3.114MEA Conversion, % 26.02 37.12 38.74 58.74 41.99DETA Conversion, % 13.50 20.70 21.21 33.62 22.94Acyclic(N4), % 98.30 97.45 96.84 95.40 96.55Acyclic(N5), % 100.00 94.05 91.70 86.09 91.37.SIGMA.(N5)/.SIGMA.(N4), 0.22 0.38 0.41 0.65 0.47weight ratioAcyclic(N4)/cyclic 16.04 12.16 10.56 7.23 9.23(< = N4), weight ratio__________________________________________________________________________Example No. 1336 1337 1338 1339 1340__________________________________________________________________________Catalyst Type GGGGGG GGGGGG GGGGGG GGGGGG GGGGGGCatalyst weight, gm 50 50 50 50 50Pressure, psig 600 600 600 600 600Temperature, .degree.C. 280.7 255.9 266.0 250.0 250.0Time on organics, hrs. 76 96 100 119 143Duration of run, hrs. 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.20 5.18 5.12 5.39 5.47DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 2.547 0.696 1.188 0.456 0.452MEA 13.368 28.286 24.782 31.286 31.867PIP 0.660 0.135 0.269 0.080 0.076DETA 39.980 54.059 50.590 55.663 57.022AEEA 1.559 1.968 2.123 1.530 1.495AEP 0.840 0.283 0.381 0.235 0.239HEP 0.000 0.000 0.000 0.000 0.000TAEA 1.837 1.171 1.430 0.801 0.7571-TETA 11.968 6.606 8.234 4.501 4.245DAEP 0.413 0.062 0.105 0.035 0.000PEEDA 0.086 0.039 0.063 0.029 0.000DPE 0.130 0.066 0.108 0.000 0.000AE-TAEA 3.233 0.758 1.349 0.372 0.0001-TEPA 5.930 1.123 2.132 0.504 0.000AE-DAEP 0.545 0.000 0.031 0.000 0.000AE-PEEDA 0.201 0.000 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000AE-DPE 0.126 0.000 0.070 0.000 0.000BPEA 0.243 0.000 0.169 0.000 0.000Others 8.624 1.140 2.109 1.021 1.114MEA Conversion, % 63.48 22.75 32.08 14.00 12.93DETA Conversion, % 35.25 12.48 17.80 9.30 7.64Acyclic(N4), % 95.63 97.87 97.21 98.79 100.00Acyclic(N5), % 89.13 100.00 92.76 100.00 0.000.SIGMA.(N5)/.SIGMA.(N4), 0.71 0.23 0.37 0.16 0.000weight ratioAcyclic(N4)/cyclic 6.47 13.22 10.42 12.02 15.87(< = N4), weight ratio__________________________________________________________________________ TABLE CXXX__________________________________________________________________________Example No. 1341 1342 1343 1344 1345__________________________________________________________________________Catalyst Type HHHHHH HHHHHH HHHHHH HHHHHH HHHHHHCatalyst weight, gm 50 50 50 50 50Pressure, psig 600 600 600 600 600Temperature, .degree.C. 249.8 249.5 259.9 264.3 274.1Time on organics, hrs. 4 24 28 48 52Duration of run, hrs. 2 2 2 2 2MEA SV, gmol/hr/kgcat 6.01 5.76 6.31 6.08 6.51DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.761 0.624 1.038 1.221 1.948MEA 25.622 26.514 24.098 23.576 16.694PIP 0.313 0.180 0.319 0.354 0.596DETA 51.757 52.135 49.333 49.050 42.503AEEA 2.271 2.049 2.327 2.321 1.938AEP 0.469 0.304 0.391 0.428 0.713HEP 0.000 0.000 0.000 0.000 0.000TAEA 1.249 1.216 1.449 1.478 1.7061-TETA 8.948 8.159 9.767 9.512 11.779DAEP 0.121 0.097 0.148 0.142 0.316PEEDA 0.067 0.063 0.086 0.097 0.232DPE 0.039 0.054 0.073 0.086 0.203AE-TAEA 1.082 1.193 1.621 1.608 2.8381-TEPA 2.014 2.188 2.900 2.766 5.279AE-DAEP 0.000 0.000 0.066 0.041 0.429AE-PEEDA 0.000 0.000 0.000 0.000 0.162iAE-PEEDA 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.083 0.071 0.078 0.546BPEA 0.000 0.140 0.190 0.225 0.601Others 1.401 1.373 1.963 2.198 5.197MEA Conversion, % 30.38 28.05 34.69 35.69 54.79DETA Conversion, % 16.63 16.13 20.74 20.69 31.77Acyclic(N4), % 97.81 97.75 97.31 97.11 94.71Acyclic(N5), % 100.00 93.80 93.22 92.68 82.34.SIGMA.(N5)/.SIGMA.(N4), 0.29 0.37 0.42 0.41 0.69weight ratioAcyclic(N4)/cyclic 10.08 13.38 10.99 9.89 6.53(< = N4), weight ratio__________________________________________________________________________Example No. 1346 1347 1348 1349 1350__________________________________________________________________________Catalyst Type HHHHHH HHHHHH HHHHHH HHHHHH HHHHHHCatalyst weight, gm 50 50 50 50 50Pressure, psig 600 600 600 600 600Temperature, .degree.C. 270.2 279.2 254.5 264.3 251.7Time on organics, hrs. 72 72 96 100 120Duration of run, hrs. 2 2 2 2 2MEA SV, gmol/hr/kgcat 6.27 6.51 6.20 6.03 6.22DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 1.583 2.362 0.611 1.025 0.465MEA 20.651 13.560 28.634 23.574 29.808PIP 0.466 0.712 0.136 0.289 0.092DETA 46.442 40.240 54.507 48.715 53.735AEEA 2.152 1.499 1.953 2.175 1.635AEP 0.549 0.914 0.271 0.386 0.235HEP 0.000 0.000 0.000 0.000 0.000TAEA 1.601 1.752 1.109 1.439 0.7761-TETA 10.430 12.550 6.599 9.395 4.640DAEP 0.196 0.455 0.057 0.152 0.074PEEDA 0.028 0.325 0.033 0.091 0.000DPE 0.141 0.249 0.054 0.069 0.000AE-TAEA 2.237 3.225 0.711 1.419 0.3101-TEPA 3.962 6.363 1.162 2.409 0.421AE-DAEP 0.137 0.501 0.000 0.000 0.000AE-PEEDA 0.052 0.290 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000AE-DPE 0.099 0.570 0.264 0.111 0.000BPEA 0.329 0.696 0.000 0.132 0.000Others 3.367 6.347 1.172 1.892 0.943MEA Conversion, % 43.71 63.20 22.55 34.28 15.16DETA Conversion, % 24.95 35.27 12.60 19.49 9.33Acyclic(N4), % 97.04 93.27 98.14 97.18 98.64Acyclic(N5), % 90.92 82.32 87.61 93.99 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.54 0.75 0.27 0.36 0.13weight ratioAcyclic(N4)/cyclic 8.70 5.38 13.91 10.95 13.46(< = N4), weight ratio__________________________________________________________________________ TABLE CXXXI______________________________________Example No. 1351 1352 1353 1354______________________________________Catalyst Type IIIIII IIIIII IIIIII IIIIIICatalyst weight, gm 50 50 50 50Pressure, psig 600 600 600 600Temperature, .degree.C. 249.8 264.3 274.1 270.2Time on organics, hrs. 4 37 40 61Duration of run, hrs. 2 2 2 2MEA SV, gmol/hr/kgcat 5.86 5.73 5.94 5.40DETA/MEA mole ratio 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98Crude product composi-tion, wt. %EDA 1.024 1.195 2.071 1.604MEA 26.663 25.244 19.405 22.346PIP 0.296 0.293 0.530 0.392DETA 50.089 49.881 43.746 46.459AEEA 1.810 1.985 1.764 1.910AEP 0.383 0.382 0.629 0.466HEP 0.000 0.000 0.000 0.000TAEA 1.335 1.526 1.657 1.5671-TETA 7.810 8.794 10.168 9.213DAEP 0.119 0.111 0.244 0.145PEEDA 0.083 0.063 0.147 0.090DPE 0.049 0.091 0.211 0.141AE-TAEA 1.264 1.525 2.605 1.9431-TEPA 2.012 2.274 4.356 3.093AE-DAEP 0.000 0.000 0.377 0.094AE-PEEDA 0.057 0.000 0.155 0.035iAE-PEEDA 0.000 0.000 0.000 0.000AE-DPE 0.076 0.077 0.546 0.097BPEA 0.038 0.166 0.533 0.257Others 1.245 2.056 5.068 3.030MEA Conversion, % 25.98 31.20 47.33 37.71DETA Conversion, % 17.56 19.41 29.62 23.22Acyclic(N4), % 97.31 97.48 95.14 96.61Acyclic(N5), % 95.00 93.96 81.20 91.22.SIGMA.(N5)/.SIGMA.(N4), 0.36 0.38 0.68 0.49weight ratioAcyclic(N4)/cyclic 9.81 10.94 6.70 8.72(< = N4), weight ratio______________________________________ TABLE CXXXII__________________________________________________________________________Example No. 1355 1356 1357 1358 1359 1360 1361 1362 1363 1364__________________________________________________________________________Catalyst Type JJJJJJ JJJJJJ JJJJJJ JJJJJJ JJJJJJ JJJJJJ JJJJJJ JJJJJJ JJJJJJ JJJJJJCatalyst weight, gm 50 50 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600 600 600Temperature, .degree.C. 249.8 249.5 259.9 264.3 274.1 270.2 279.2 254.5 264.3 251.7Time on organics, hrs. 4 24 28 48 52 72 72 96 100 120Duration of run, hrs. 2 2 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.10 4.90 5.23 5.17 5.39 5.13 5.44 5.16 5.11 5.35DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 0.960 0.781 1.286 1.404 2.490 1.935 2.792 0.714 1.281 0.493MEA 25.276 26.501 22.272 21.316 14.838 19.716 11.330 27.403 22.785 27.477PIP 0.268 0.204 0.383 0.358 0.742 0.540 0.837 0.168 0.348 0.103DETA 50.594 51.409 47.463 45.857 40.344 44.583 37.401 53.232 47.558 54.912AEEA 2.227 2.171 2.322 2.246 1.783 2.068 1.362 2.040 2.125 1.779AEP 0.365 0.314 0.469 0.481 0.878 0.612 1.085 0.294 0.441 0.273HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.233 1.224 1.587 1.506 1.615 1.578 1.689 1.266 1.424 1.0951-TETA 9.272 8.238 10.975 10.156 11.821 10.601 12.728 7.741 9.232 6.746DAEP 0.116 0.088 0.175 0.175 0.394 0.229 0.599 0.075 0.153 0.071PEEDA 0.072 0.059 0.117 0.170 0.031 0.173 0.376 0.041 0.100 0.028DPE 0.061 0.053 0.092 0.124 0.233 0.160 0.305 0.047 0.090 0.000AE-TAEA 1.263 1.061 1.872 2.256 3.087 2.494 3.494 0.922 1.714 0.4351-TEPA 2.381 1.850 3.306 4.088 5.984 4.457 6.930 1.552 2.925 0.540AE-DAEP 0.000 0.000 0.049 0.183 0.533 0.160 0.701 0.000 0.039 0.000AE-PEEDA 0.000 0.000 0.000 0.202 0.312 0.063 0.374 0.000 0.000 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.076 0.000 0.077 0.648 0.544 0.112 0.581 0.000 0.112 0.000BPEA 0.118 0.075 0.262 0.540 0.639 0.399 0.995 0.049 0.240 0.000Others 1.481 1.265 2.484 2.761 6.684 3.550 7.622 1.247 2.245 1.490MEA Conversion, % 31.15 27.16 39.53 42.00 59.71 45.84 69.02 25.71 36.32 24.24DETA Conversion, % 18.31 16.23 23.60 26.03 35.07 27.41 39.37 14.45 21.21 10.25Acyclic(N4), % 97.67 97.91 97.01 96.12 95.31 95.57 91.83 98.20 96.87 98.74Acyclic(N5), % 94.93 97.48 93.01 80.11 81.72 90.42 79.71 98.02 92.20 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.35 0.30 0.43 0.65 0.78 0.60 0.83 0.27 0.45 0.12weight ratioAcyclic(N4)/cyclic 11.88 13.13 10.13 8.90 5.89 7.09 4.49 14.33 9.39 16.44(< = N4), weight ratio__________________________________________________________________________ TABLE CXXXIII__________________________________________________________________________Example No. 1365 1366 1367 1368 1369 1370 1371 1372__________________________________________________________________________Catalyst Type KKKKKK KKKKKK KKKKKK KKKKKK KKKKKK KKKKKK KKKKKK KKKKKKCatalyst weight, gm 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 250.9 251.1 261.2 265.8 275.6 270.6 280.1 286.3Time on organics, hrs. 4 23 28 48 52 72 76 96Duration of run, hrs. 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 5.47 5.89 6.03 6.26 6.37 6.13 6.30 5.74DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composi-tion, wt. %EDA 0.720 0.471 0.905 1.039 1.480 1.147 1.920 2.426MEA 22.009 25.260 20.953 20.030 12.865 18.327 11.062 10.395PIP 0.236 0.148 0.320 0.360 0.596 0.411 0.716 0.888DETA 49.471 53.904 50.021 50.155 43.606 48.889 42.722 43.690AEEA 2.596 2.713 2.960 3.007 2.400 2.930 1.997 1.666AEP 0.369 0.293 0.450 0.511 0.832 0.592 1.018 1.209HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 1.431 1.225 1.593 1.658 1.845 1.669 1.892 1.7451-TETA 9.494 7.564 9.777 9.875 11.583 9.862 11.226 10.431DAEP 0.148 0.096 0.184 0.198 0.402 0.207 0.439 0.480PEEDA 0.122 0.090 0.106 0.123 0.320 0.113 0.034 0.294DPE 0.066 0.055 0.069 0.086 0.155 0.046 0.133 0.167AE-TAEA 1.452 0.810 1.783 1.741 3.025 1.768 3.034 2.8231-TEPA 2.655 1.402 3.149 3.152 5.660 3.141 5.502 5.191AE-DAEP 0.000 0.000 0.000 0.048 0.304 0.056 0.503 0.535AE-PEEDA 0.000 0.000 0.000 0.000 0.217 0.036 0.192 0.219iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.085 0.000 0.106 0.088 0.532 0.055 0.161 0.144BPEA 0.089 0.000 0.224 0.200 0.722 0.287 0.763 0.720Others 1.049 1.041 2.233 2.823 5.516 3.315 7.516 7.487MEA Conversion, % 37.93 30.47 42.95 45.73 64.84 49.30 69.45 71.21DETA Conversion, % 17.29 12.04 19.27 19.45 29.37 19.83 30.06 28.28Acyclic(N4), % 97.00 97.30 96.93 96.58 93.85 96.91 95.57 92.81Acyclic(N5), % 95.91 100.00 93.70 93.55 83.01 91.86 84.03 83.18.SIGMA.(N5)/.SIGMA.(N4), 0.38 0.24 0.44 0.43 0.73 0.44 0.74 0.73weight ratioAcyclic(N4)/cyclic 11.57 12.82 10.05 9.01 5.82 8.40 5.59 4.00(< = N4), weight ratio__________________________________________________________________________ TABLE CXXXIV__________________________________________________________________________Example No. 1373 1374 1375 1376 1377 1378 1379 1380__________________________________________________________________________Catalyst Type LLLLLL LLLLLL LLLLLL LLLLLL LLLLLL LLLLLL LLLLLL LLLLLLCatalyst weight, gm 50 50 50 50 50 50 50 50Pressure, psig 600 600 600 600 600 600 600 600Temperature, .degree.C. 250.9 251.1 261.2 265.8 275.6 270.6 280.1 286.3Time on organics, hrs. 4 23 28 48 52 72 76 96Duration of run, hrs. 2 2 2 2 2 2 2 2MEA SV, gmol/hr/kgcat 6.04 5.42 5.91 6.40 6.54 6.13 6.74 5.98DETA/MEA mole ratio 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99NH.sub.3 /MEA mole ratio 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98Crude product composition, wt. %EDA 1.243 0.400 0.619 0.453 0.613 0.354 0.525 0.580MEA 29.356 33.017 31.776 32.605 30.780 32.217 30.493 31.003PIP 0.484 0.185 0.304 0.266 0.441 0.244 0.428 0.540DETA 54.083 59.592 58.373 59.235 57.284 58.765 57.084 56.943AEEA 1.249 0.742 1.272 1.184 1.363 1.159 1.500 1.300AEP 0.395 0.262 0.352 0.330 0.422 0.301 0.428 0.482HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.704 0.276 0.427 0.390 0.510 0.276 0.503 0.4801-TETA 3.680 1.530 2.245 1.887 2.609 1.462 2.595 2.425DAEP 0.102 0.032 0.065 0.120 0.082 0.000 0.088 0.070PEEDA 0.057 0.000 0.034 0.066 0.054 0.000 0.087 0.097DPE 0.044 0.000 0.026 0.000 0.026 0.000 0.035 0.000AE-TAEA 0.259 0.000 0.096 0.057 0.153 0.000 0.230 0.1821-TEPA 0.507 0.000 0.236 0.106 0.469 0.000 0.673 0.501AE-DAEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-PEEDA 0.133 0.000 0.000 0.000 0.000 0.000 0.067 0.000iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.000 0.000 0.000 0.000 0.299 0.000BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000Others 2.796 1.200 1.868 1.546 1.758 1.067 1.606 1.461MEA Conversion, % 18.40 9.46 13.61 11.72 15.52 8.49 16.54 14.42DETA Conversion, % 10.89 3.12 5.92 4.92 6.79 4.03 7.37 6.82Acyclic(N4), % 95.54 98.24 95.49 92.41 95.03 100.00 93.59 94.56Acyclic(N5), % 85.20 0.00 100.00 100.00 100.00 0.00 71.12 100.00.SIGMA.(N5)/.SIGMA.(N4), 0.19 0.00 0.11 0.06 0.18 0.00 0.38 0.22weight ratioAcyclic(N4)/cyclic 4.04 3.76 3.41 2.90 3.03 3.18 2.89 2.44(< = N4), weight ratio__________________________________________________________________________ TABLE CXXXV__________________________________________________________________________Example No. 1381 1382 1383 1384 1385 1386 1387 1388__________________________________________________________________________Catalyst Type MMMMMM MMMMMM MMMMMM MMMMMM MMMMMM MMMMMM MMMMMM MMMMMMCatalyst 50 50 50 50 50 50 50 50weight, gmPressure, psig 600 600 600 600 600 600 600 600Temperature, 250.9 251.1 261.2 265.8 275.6 270.6 280.1 286.3.degree.C.Time on or- 4 23 28 48 52 72 76 96ganics, hrs.Duration of 2 2 2 2 2 2 2 2run, hrs.MEA SV, 4.89 4.52 5.00 4.97 5.03 4.67 5.18 4.59gmol/hr/kgcatDETA/MEA 0.99 0.99 0.99 0.99 0.99 0.99 0.99 0.99mole ratioNH.sub.3 /MEA 5.98 5.98 5.98 5.98 5.98 5.98 5.98 5.98mole ratioCrude pro-duct composi-tion, wt. %EDA 0.361 0.219 0.411 0.545 0.946 0.691 1.268 1.591MEA 30.065 31.539 30.198 28.886 25.101 27.183 22.856 21.265PIP 0.191 0.101 0.235 0.344 0.686 0.468 0.951 1.183DETA 57.915 60.816 59.141 58.453 55.105 56.245 52.509 52.661AEEA 1.844 1.669 2.173 2.351 2.319 2.307 2.115 1.849AEP 0.299 0.245 0.312 0.391 0.627 0.461 0.842 1.032HEP 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000TAEA 0.476 0.214 0.406 0.515 0.745 0.564 0.870 0.8941-TETA 2.817 1.483 2.555 3.157 4.703 3.517 5.428 5.629DAEP 0.066 0.000 0.066 0.077 0.144 0.104 0.191 0.220PEEDA 0.077 0.000 0.030 0.063 0.138 0.033 0.212 0.248DPE 0.000 0.000 0.000 0.033 0.039 0.000 0.060 0.066AE-TAEA 0.102 0.000 0.108 0.157 0.411 0.199 0.708 0.5821-TEPA 0.142 0.000 0.113 0.379 1.210 0.590 2.108 1.711AE-DAEP 0.000 0.000 0.000 0.000 0.041 0.000 0.126 0.089AE-PEEDA 0.000 0.000 0.000 0.000 0.037 0.000 0.098 0.085iAE-PEEDA 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000AE-DPE 0.000 0.000 0.311 0.284 0.170 0.250 0.050 0.078BPEA 0.000 0.000 0.000 0.000 0.000 0.000 0.101 0.096Others 0.939 0.839 1.295 1.748 2.458 1.973 3.578 3.552MEA Con- 16.32 13.59 17.86 21.73 30.80 24.34 36.90 40.66version, %DETA Con- 4.44 1.22 4.64 6.11 9.94 7.19 14.06 12.88version, %Acyclic(N4), 95.83 100.00 96.82 95.45 94.40 96.74 93.13 92.40Acyclic(N5), 100.00 0.00 41.61 65.36 86.70 75.90 88.18 86.75%.SIGMA.(N5)/.SIGMA. 0.07 0.00 0.17 0.21 0.32 0.24 0.47 0.37(N4), weightratioAcyclic(N4)/ 5.19 4.88 4.59 4.03 3.32 3.82 2.78 2.37cyclic(< = N4),weight ratio__________________________________________________________________________

Although the invention has been illustrated by certain of the preceding examples, it is not to be construed as being limited thereby; but rather, the invention encompasses the generic area as hereinbefore disclosed. Various modifications and embodiments can be made without departing from the spirit and scope thereof.

Claims

1. A process of making polyalkylene polyamines which comprises condensing, in the absence of hydrogen as a reactant,

(i) an alkanolamine with an alkyleneamine,

(ii) an alkanolamine with itself or another alkanolamine, or

(iii) an alkylene glycol with an alkyleneamine,

optionally in the presence of ammonia, under condensation conditions including the presence of a condensation catalyst consisting essentially of a metatungstate and a condensation catalyst promoter free of phosphorus-containing compounds, wherein said condensation catalyst promoter differs from said condensation catalyst and is present in an amount sufficient to promote the condensation catalyst.

2. The process of claim 1 wherein the condensation catalyst has a surface area greater than about 70 m.sup.2 /gm.

3. The process of claim 1 wherein the condensation catalyst promoter comprises one or more metal oxides.

4. The process of claim 3 wherein the condensation catalyst promoter comprises one or more Group IA metal oxides, Group IIA metal oxides, Group IIB metal oxides, Group VB metal oxides, Group VIB metal oxides, Group VIIB metal oxides, Group VIII metal oxides, Group IB metal oxides, Group IIB metal oxides, Group IIIA metal oxides, Group IVA metal oxides, Group VA metal oxides, Group VIA metal oxides, Group IVB metal oxides or mixtures thereof.

5. The process of claim 4 wherein the condensation catalyst promoter comprises one or more oxides of scandium, yttrium, lanthanum, cerium, gadolinium, lutetium, ytterbium, niobium, tantalum, chromium, molybdenum, tungsten, titanium, zirconium, ion, cobalt, nickel, zinc, cadmium, boron, aluminum, gallium, indium, silicon, germanium, tin, lead, arsenic, antimony and bismuth.

6. The process of claim 1 wherein the condensation catalyst promoter comprises a Group VIB metal-containing substance.

7. The process of claim 6 wherein the condensation catalyst promoter comprises one or more oxides of tungsten, chromium and/or molybdenum.

8. The process of claim 1 wherein the condensation catalyst is associated with a support material.

9. The process of claim 8 wherein the support comprises an alumina material or an alumina-silica material.

10. The process of claim 8 wherein the support comprises a silica material or a silica-alumina material.

11. The process of claim 8 wherein the support comprises from about 2 to about 50 percent by weight of the condensation catalyst.

12. The process of claim 1 wherein the amines product has a TETA+TAEA to PIP+AEP+PEEDA+DAEP+DPE weight ratio of greater than about 0.5 and a TETA to TAEA weight ratio of greater than about 2.0.

13. The process of claim 1 in which the amines product comprises, based on 100 percent of the weight of the product and exclusive of any water and/or ammonia present,

a) greater than about 3.0 weight percent of the combination of TETA and TEPA,

b) greater than about 0.1 weight percent of TEPA,

c) greater than about 3.0 weight percent of TETA,

d) less than about 90.0 weight percent of DETA and/or EDA,

e) less than about 90.0 weight percent of MEA and/or AEEA,

f) less than about 12.5 weight percent of the combination of PIP and AEP,

g) less than about 15.0 weight percent of other polyalkylene polyamines,

h) a TETA+TAEA to PIP+AEP+PEEDA+DAEP+DPE weight ratio of greater than about 0.5,

i) a TEPA+AETAEA to PIP+AEP+PEEDA+DAEP+DPE+AEPEEDA+iAEPEEDA+AEDAEP+AEDPE+BPEA weight ratio of greater than about 0.5,

j) a TETA to TAEA weight ratio of greater than about 2.0, and

k) a TEPA to AETAEA weight ratio of greater than about 1.0.

14. The process of claim 1 which is effected in the liquid phase, vapor phase, supercritical liquid phase or mixtures thereof.

15. The process of claim 1 wherein the metatungstate is associated with a Group IVB metal oxide.

16. The process of claim 15 wherein the Group IVB metal oxide comprises a high surface area titanium oxide.

17. A process of making alkylamines which comprises condensing, in the absence of hydrogen as a reactant, an alcohol and at least one of a primary amine, a secondary amine or a tertiary amine in the presence of a condensation catalyst consisting essentially of a metatungstate and a condensation catalyst promoter free of phosphorus-containing compounds, wherein said condensation catalyst promoter differs from said condensation catalyst and is present in an amount sufficient to promote the condensation catalyst.

18. The process of claim 1 wherein the condensation reaction is of said alkanolamine and alkyleneamine reactants (i).

19. The process of claim 18 wherein the alkanolamine is monoethanolamine.

20. The process of claim 18 wherein the alkanolamine is aminoethylethanolamine.

21. The process of claim 18 wherein the alkyleneamine is ethylenediamine.

22. The process of claim 187 wherein the alkyleneamine is diethylenetriamine.

23. The process of claim 18 wherein the alkanolamine is monoethanolamine and the alkyleneamine is ethylenediamine.

24. The process of claim 23 wherein the process is effected in the presence of ammonia.

25. The process of claim 18 wherein the alkanolamine is monoethanolamine and the alkyleneamine is diethylenetriamine.

26. The process of claim 25 wherein the process is effected in the presence of ammonia.

27. The process of claim 18 wherein the alkanolamine is aminoethylenethanolamine and the alkyleneamine is ethylenediamine.

28. The process of claim 27 wherein the process is effected in the presence of ammonia.

29. The process of claim 18 wherein the alkanolamine is aminoethylenethanolamine and the alkyleneamine is diethylenetriamine.

30. The process of claim 29 wherein the process is effected in the presence of ammonia.

31. The process of claim 18 wherein the alkanolamine is diethanolamine and the alkyleneamine is ethylenediamine or diethylenetriamine.

32. The process of claim 19 wherein the alkanolamine is dihydroxyethylenethylenediamine and the alkyleneamine is ethylenediamine or diethylenetriamine.

33. The process of claim 18 wherein the alkanolamine is hydroxyethyldiethylenetriamine and the alkyleneamine is ethylenediamine or diethylenetriamine.

34. The process of claim 18 wherein the alkanolamine is hydroxyethyltriethylenetetramine and the alkyleneamine is ethylenediamine or diethylenetriamine.

35. The process of claim 1 wherein the condensation reaction is of said alkanolamine reactant (ii) with itself.

36. The process of claim 35 wherein said alkanolamine is monoethanolamine.

37. The process of claim 1 wherein the condensation reaction is of said alkylene glycol and alkyleneamine reactants (iii).

38. The process of claim 37 wherein the alkylene glycol is ethylene glycol and the alkyleneamine is ethylenediamine or diethylenetriamine.

39. The process of claim 17 further comprising ammonia as a reactant.