Claims
- 1. An article of a heat-recoverable material having coated on at least a part of the surface thereof an adhesive composition comprising an adhesive component and, in an amount sufficient to impart improved resistance to cathodic disbondment to the adhesive composition, a hydrazine derivative of the formula ##STR18## wherein n is 0 or 1; A is a radical selected from the group consisting of alkyl, aryl, aralkyl, hydrazido, radicals of the formula ##STR19## wherein m is 0-20, Y is alkyl, aryl or heterocyclic and Z is alkyl, aryl or heterocyclic, and substituted derivatives thereof wherein the substitutents are lower alkyl, halogen or hydroxyl;
- when n is 1, B is selected from the group consisting of alkyl, aryl, aralkyl, radicals of the formula ##STR20## where Y, Z and m are as defined above, and substituted derivatives thereof, wherein the substituents are lower alkyl, halogen or hydroxyl; and
- when n is 0, B is a divalent radical of the formula .dbd.CH--(CH.sub.2).sub.q --W wherein q is 0-20 and W is alkyl, aryl or heterocyclic, and substituted derivatives thereof, wherein the substituents are lower alkyl, halogen or hydroxyl.
- 2. An article in accordance with claim 1, wherein said article is a sheet.
- 3. An article in accordance with claim 1, wherein said article is a tape.
- 4. An article in accordance with claim 1, wherein said article is a sleeve.
- 5. An article in accordance with claim 1, wherein said heat-shrinkable material is a polymeric material.
- 6. An article in accordance with claim 5, wherein said polymeric material is polyethylene.
- 7. An article in accordance with claim 5, wherein said polymeric material is cross-linked polyethylene.
- 8. An article in accordance with claim 1, wherein said adhesive component is a hot melt adhesive.
- 9. An article in accordance with claim 1, wherein said hydrazine derivative is N,N'-bis(3,5-di-t-butyl-4-hydroxycinnamoyl) hydrazine.
- 10. An article in accordance with claim 1, wherein said hydrazine derivative is N-salicylidene-N'-salicylhydrazide.
- 11. An article in accordance with claim 1, wherein said hydrazine derivative is oxalyl bis(benzylidene hydrazide).
- 12. A pipe having bonded to the surface thereof a polymeric coating, said coating being bonded to said pipe with an adhesive composition comprising an adhesive component and from about 0.01 to about 30% by weight, based on the total weight of the adhesive composition of a hydrazine derivative of the formula ##STR21## wherein n is 0 or 1; A is a radical selected from the group consisting of alkyl, aryl, aralkyl, hydrazido, radicals of the formula ##STR22## wherein m is 0-20, Y is alkyl, aryl or heterocyclic and Z is alkyl, aryl or heterocyclic, and substituted derivatives thereof wherein the substitutents are lower alkyl, halogen or hydroxyl;
- when n is 1, B is selected from the group consisting of alkyl, aryl, aralkyl, radicals of the formula ##STR23## where Y, Z and m are as defined above, and substituted derivatives thereof, wherein the substituents are lower alkyl, halogen or hydroxyl; and
- when n is 0, B is a divalent radical of the formula .dbd.CH--(CH.sub.2).sub.q --W wherein q is 0-20 and W is alkyl, aryl or heterocyclic, and substituted derivatives thereof, wherein the substituents are lower alkyl, halogen or hydroxyl.
- 13. A pipe in accordance with claim 12, wherein said pipe is of steel.
- 14. A pipe in accordance with claim 12, wherein said polymeric coating is polyethylene.
- 15. A pipe in accordance with claim 12, wherein said polymeric coating is cross-linked polyethylene.
- 16. A pipe in accordance with claim 12, wherein said adhesive component is a hot melt adhesive.
- 17. A pipe in accordance with claim 12, wherein said hydrazine derivative is N,N'-bis(3,5-di-t-butyl-4-hydroxycinnamoyl) hydrazine.
- 18. A pipe in accordance with claim 12, wherein said hydrazine derivative is N-salicylidene-N'-salicylhydrazide.
- 19. A pipe in accordance with claim 12, wherein said hydrazine derivative is oxalyl bis(benzylidene hydrazide).
- 20. A metal pipe which is connected to an electric circuit such that the pipe forms a cathode; said pipe having bonded to the surface thereof a polymeric coating, said coating being bonded to said pipe with an adhesive composition comprising an adhesive component and from about 0.01 to about 30% by weight, based on the total weight of the adhesive composition of a hydrazine derivative of the formula ##STR24## wherein n is 0 or 1; A is a radical selected from the group consisting of alkyl, aryl, aralkyl, hydrazido, radicals of the formula ##STR25## wherein m is 0-20, Y is alkyl, aryl or heterocyclic and Z is alkyl, aryl or heterocyclic, and substituted derivatives thereof wherein the substitutents are lower alkyl, halogen or hydroxyl;
- when n is 1, B is selected from the group consisting of alkyl, aryl, aralkyl, radicals of the formula ##STR26## where Y, Z and m are as defined above, and substituted derivatives thereof, wherein the substituents are lower alkyl, halogen or hydroxyl; and
- when n is 0, B is a divalent radical of the formula .dbd.CH--(CH.sub.2).sub.q --W wherein q is 0-20 and W is alkyl, aryl or heterocyclic, and substituted derivatives thereof, wherein the substituents are lower alkyl, halogen or hydroxyl.
- 21. A pipe in accordance with claim 20, wherein said pipe is of steel.
- 22. A pipe in accordance with claim 20, wherein said polymeric coating is polyethylene.
- 23. A pipe in accordance with claim 20, wherein said polymeric coating is cross-linked polyethylene.
- 24. A pipe in accordance with claim 20, wherein said adhesive component is a hot melt adhesive.
- 25. A pipe in accordance with claim 20, wherein said hydrazine derivative is N,N'-bis(3,5-di-t-butyl-4-hydroxycinnamoyl) hydrazine.
- 26. A pipe in accordance with claim 20, wherein said hydrazine derivative is N-salicylidene-N'-salicylhydrazide.
- 27. A pipe in accordance with claim 20, wherein said hydrazine derivative is oxalyl bis(benzylidene hydrazide).
- 28. A method of protecting a metal substrate from corrosion which comprises bonding a protective coating to said pipe with an adhesive composition comprising an adhesive component and, in an amount sufficient to impart improved resistance to cathodic disbondment to the adhesive composition, hydrazine derivative of the formula ##STR27## wherein n is 0 or 1; A is a radical selected from the group consisting of alkyl, aryl, aralkyl, hydrazido, radicals of the formula ##STR28## wherein m is 0-20, Y is alkyl, aryl or heterocyclic and Z is alkyl, aryl or heterocyclic, and substituted derivatives thereof wherein the substitutents are lower alkyl, halogen or hydroxyl;
- when n is 1, B is selected from the group consisting of alkyl, aryl, aralkyl, radicals of the formula ##STR29## where Y, Z and m are as defined above, and substituted derivatives thereof, wherein the substituents are lower alkyl, halogen or hydroxyl; and
- when n is 0, B is a divalent radical of the formula .dbd.CH--(CH.sub.2).sub.q --W wherein q is 0-20 and W is alkyl, aryl or heterocyclic, and substituted derivatives thereof, wherein the substituents are lower alkyl, halogen or hydroxyl;
- applying a negative electrical potential to said substrate, thereby impressing an electric current through said substrate.
- 29. A method in accordance with claim 28, wherein said substrate is of steel.
- 30. A method in accordance with claim 28, wherein said polymeric coating is polyethylene.
- 31. A method in accordance with claim 28, wherein said polymeric coating is cross-linked polyethylene.
- 32. A method in accordance with claim 28, wherein said adhesive component is a hot melt adhesive.
- 33. A method in accordance with claim 28, wherein said hydrazine derivative is N,N'-bis(3,5-di-t-butyl-4-hydroxycinnamoyl) hydrazine.
- 34. A method in accordance with claim 28, wherein said hydrazine derivative is N-salicylidene-N'-salicylhydrazide.
- 35. A method in accordance with claim 28, wherein said hydrazine derivative is oxalyl bis(benzylidene hydrazide).
Parent Case Info
This is a continuation of application Ser. No. 282,354, filed July 13, 1981.
US Referenced Citations (14)
Non-Patent Literature Citations (3)
Entry |
Eastman Industrial Chemicals, Publication D-137 entitled "Eastman Inhibitor.RTM. OABH Oxalyl bis(benzylidenehydrazide)". |
Ciba Geigy Polymer Additives Department Product Data Sheet on "CHEL.RTM. 180 Metal Deactivator for Polymers and Coatings". |
Ciba Geigy Polymer Additives Department preliminary technical bulletin on Irganox MD-1024 Metal Deactivator/Antioxidant. |
Continuations (1)
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Number |
Date |
Country |
Parent |
282354 |
Jul 1981 |
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