The present invention relates to a protective element which interrupts a current path when an abnormality such as over-charging or over-discharging occurs. This application claims priority to Japanese Patent Application No. 2013-92328 filed on Apr. 25, 2013, the entire content of which is hereby incorporated by reference.
Secondary batteries are often provided to users in the form of rechargeable battery packs which can be repeatedly used. In particular, in order to protect users and electronic appliances, lithium ion secondary batteries having a high volumetric energy density typically include several protective circuits incorporated in battery packs for over-charging protection and over-discharging protection to interrupt the output of the battery pack under predetermined conditions.
Some of these protective elements use an FET switch incorporated in a battery pack to turn ON/OFF the output, for over-charging protection or over-discharging protection of the battery pack. However, even in the cases of the FET switch being short-circuited and damaged for some reason, a large current caused by a surge such as lighting momentarily flows, and an abnormally decreased output voltage or an excessively high voltage occurs in an aged battery cell, the battery pack or the electronic appliance should prevent accidents including fire, among others. For this reason, a protective element is used having a fuse which interrupts a current path in accordance with an external signal so as to safely interrupt the output of the battery cell under these possible abnormalities.
As shown in
Additionally, in such a protective element 80 as illustrated in
PLT 1: Japanese Unexamined Patent Application Publication No. 2010-003665
PLT 2: Japanese Unexamined Patent Application Publication No. 2004-185960
PLT 3: Japanese Unexamined Patent Application Publication No. 2012-003878
Along with increases in capacity and output in lithium ion secondary batteries in recent years, improved ratings are also desired in a protective element 80 of a protective circuit for lithium ion secondary batteries. In addition, along with miniaturization and slimming of electronic appliances, the protective element 80 is also desired to be smaller and thinner.
In order to improve ratings and allow larger currents, it is desirable to reduce the conductor resistance of the meltable conductor 83. The resistance of the meltable conductor 83 can be reduced by (1) increasing conductor cross-sectional area or (2) reducing the conductor length between the first and second electrodes 81, 82 between which the meltable conductor 83 is arranged. In addition, because contact resistance between the meltable conductor 83 and the first and second electrodes 81, 82 also affects the rating of the protective element 80, (3) increasing contact area between the meltable conductor 83 and first and second electrodes 81, 82 is also effective.
Because the protective element 80 is desired to be smaller and thinner, (1) increasing conductor cross-sectional area has a limit; therefore, effective solutions for improving ratings are (2) decreasing the conductor length and (3) increasing the contact area between the meltable conductor 83 and the first and second electrodes 81, 82. For this reason, the shape of the meltable conductor 83, as shown in
Furthermore, a flux body 85 is provided above the meltable conductor 83 to prevent oxidation and improve wettability and is desirably held in an elliptical shape in accordance with the shape of the meltable conductor 83. However, in an elliptically shaped flux body, tension is stronger on both ends of the major axis leading to a tendency to deviate towards one end of the major axis with even a small inclination; the elliptically shaped flux body is thus held deviating from the center of the heat-generating resistor 84 and consequently does not spread across the entire meltable conductor 83 thereby adversely increasing melting time.
Therefore, the flux body provided on the meltable conductor 83 is preferably held in a circular shape in view of holding the flux body on the center of the heat-generating resistor 84. However, in the meltable conductor 83 which has a rectangular shape in order to improve ratings, the diameter of such a circular flux body is determined by the length of the short dimension of the meltable conductor 83, leading to held amount being insufficient to cover the entire surface area of the meltable conductor 83, thus precluding improvements in oxidation resistance and wettability.
Therefore, an object of the present invention is to provide a protective element in which flux can be spread evenly to the entire surface of the meltable conductor even in the case of a rectangular meltable conductor.
To solve the aforementioned problem, a protective element according to the present invention includes: an insulating substrate; a heat-generating resistor disposed on the insulating substrate; a first and a second electrodes laminated onto the insulating substrate; a heat-generating element extracting electrode overlapping the heat-generating resistor in a state electrically insulated therefrom and electrically connected to the heat-generating resistor on a current path between the first and the second electrodes; a rectangular meltable conductor laminated between the heat-generating element extracting electrode and the first and second electrodes for interrupting a current path between the first electrode and the second electrodes by being melted by heat; and a plurality of flux bodies disposed on the meltable conductor; wherein the plurality of flux bodies are disposed along the heat-generating resistor.
According to the present invention, because a plurality of flux bodies are provided along the heat-generating resistor, the plurality of flux bodies can cover a wide area of the surface of the rectangular meltable conductor, and heat generated by the heat-generating resistor can spread flux evenly across the entire surface of the meltable conductor. Accordingly, a protective element according to the present invention suppresses oxidation and improves wettability in the meltable conductor thus enabling rapid interruption of a current path between the first and second electrodes.
Embodiments of protective element according to the present invention will now be more particularly described with reference to the accompanying drawings. It should be noted that the present invention is not limited to the embodiments described below and various modifications can be added to the embodiment without departing from the scope of the present invention. The features shown in the drawings are illustrated schematically and are not intended to be drawn to scale. Actual dimensions should be determined in consideration of the following description. Moreover, those skilled in the art will appreciate that dimensional relations and proportions may be different among the drawings in some parts.
Protective Element Configuration
As illustrated in
The insulating substrate 11 is formed in an approximately rectangular shape by using an insulating material such as alumina, glass ceramics, mullite and zirconia. Other materials used for printed circuit boards such as glass epoxy substrate or phenol substrate may be used as the insulating substrate 11; in these cases, however, the temperature at which the fuses are blown should be considered.
The heat-generating resistor 14 is made of a conductive material such as W, Mo and Ru, having a relatively high resistance and generates a heat when a current flows therethrough. A powdered alloy, composition or compound of these materials is mixed with a resin binder to obtain a paste, which is screen-printed as a pattern on the insulating substrate 11 and baked to form the heat-generating resistor 14.
The insulating member 15 is arranged such that it covers the heat-generating resistor 14, and the heat-generating element extracting electrode 16 is arranged to face the heat-generating resistor 14 with the insulating member 15 interposing therebetween. The insulating member 15 may be laminated between the heat-generating resistor 14 and the insulating substrate 11 in order to efficiently conduct the heat of the heat-generating resistor 14 to the meltable conductor 13. A glass, for example, can be used as the insulating member 15.
The heat-generating element extracting electrode 16 is continuous with one end of the heat-generating resistor 14 and one end is connected to the heat-generating element extracting electrode 18 (P1) and the other end is connected to the heat-generating element extracting electrode 18 (P2) via the heat-generating resistor 14.
The meltable conductor 13 is formed from a low melting point metal, such as a Pb free solder having Sn as a primary constituent, capable of being promptly melted by the heat of the heat-generating resistor 14. In addition, the meltable conductor 13 may be formed by using a high melting point metal including In, Pb, Ag and/or Cu alloys or may have a laminated structure of a low melting point metal and a high melting point metal of Ag, Cu or an alloy consisting essentially of these.
It should be noted that the meltable conductor 13 is connected to the heat-generating element extracting electrode 16 and the electrodes 12 (A1), 12 (A2) by, for example, soldering. The meltable conductor 13 can be easily connected by reflow solder bonding.
For internal protection, the protective element 10 may include a covering member 19 disposed on the insulating substrate 11.
In the protective element 10, the meltable conductor 13 overlaps the heat-generating resistor 14, with the insulating member 15 and the heat-generating element extracting electrode 16 interposing therebetween, enabling efficient conveyance of heat generated by the heat-generating resistor 14 to the meltable conductor 13 which facilitates rapid blowout.
In order to improve ratings and allow larger currents in the protective element 10, reductions are desired in conductor resistance of the meltable conductor 13. Therefore, in the protective element 10, it is possible to reduce conductor length of the electrodes 12 (A1), (A2) and increase connection surface area between the meltable conductor 13 and the electrodes (A1), (A2); as shown in the plan view of
In addition, with the meltable conductor 13 being rectangular, the heat-generating resistor 14, the insulating member 15 and the heat-generating element extracting electrode 16 are also accordingly short between the electrodes 12 (A1), (A2) and long along the long edge of the electrodes (A1), (A2) thus also forming a rectangle.
Positioning of the Flux Bodies 17
A plurality of flux bodies 17 are provided on the surface of the meltable conductor 13. Each of the flux bodies is approximately circular and tension acts evenly throughout the entirety of each thereof so that holding is well balanced and without lateral bias.
Furthermore, the plurality of flux bodies 17 are arranged along the heat-generating resistor 14. Thus, in the protective element 10, the plurality of flux bodies can widely cover the surface of the rectangular meltable conductor 13, and heat generated by the heat-generating resistor 14 causes the flux bodies 17 to spread evenly across the entire surface of the meltable conductor 13. Consequently, by preventing oxidation and improving wettability of the meltable conductor 13, the current path between the electrodes 12 (A1), (A2) can be rapidly blown in the protective element 10.
For example, the plurality of flux bodies 17 are, as illustrated in
As shown in
In the protective element 10, by arranging the flux bodies 17 on the heat-generation center 14a, the flux bodies 17 spread radially from the heat-generation center 14a towards peripheral portions in accordance with the heat distribution of the heat-generating resistor 14. In the case of not providing the flux bodies 17 on the heat-generation center 14a, it is difficult to spread the flux bodies 17 towards the heat-generation center 14a, which has the highest temperature, and the flux bodies 17 might not spread to the vicinity above the heat-generation center 14a.
Therefore, in the protective element 10, by providing the flux bodies 17 on this difficult to reach area of the heat-generation center 14a of the heat-generating resistor 14, spreading of the flux bodies 17 to the entire surface of the meltable conductor 13 can be assured.
Melting Portions
The plurality of the flux bodies 17, as illustrated in
In the protective element 10, aligning the flux bodies along the heat-generating resistor 14 on the melting portions 13a of the meltable conductor 13 prevents oxidation of the meltable conductor 13, which is between the heat-generating element extracting electrode 16 and the electrodes 12 (A1), 12 (A2), and enables rapid blowout of the melting portions 13a which interrupts the current path between the electrodes 12 (A1), 12 (A2).
In addition, the plurality of flux bodies 17, as illustrated in
Each of the flux bodies 17 spreads radially toward peripheral portions from the heat-generation center 14a, which has the highest temperature and is the most difficult location for spreading to reach, ensuring that the flux bodies 17 can spread to the entire surface of the meltable conductor 13. Furthermore, reliable blowout is required in the melting portions 13a of the meltable conductor 13, which is arranged between the heat-generating element extracting electrode 16 and the electrodes 12 (A1), 12 (A2), and oxidation thereof is suppressed by the flux bodies 17 thus enabling rapid blowout.
Symmetric Arrangement
Furthermore, the plurality of flux bodies 17 are preferably arranged symmetrically about the heat-generation center 14a of the heat-generating resistor 14. The flux bodies 17 can thus spread evenly across the entire surface of the meltable conductor 13 preventing variances in blowout properties among individual products and enabling reliable and rapid blowout.
As illustrated in
It should be noted that the plurality of flux bodies 17 may be arranged asymmetrically in relation to the heat-generation center 14a of the heat-generating resistor 14. In this case, as illustrated in
Holding Mechanism
The protective element 10 includes a holding mechanism to hold the flux bodies 17 at predetermined positions on the above-mentioned meltable conductor 13. The holding mechanism, for example as illustrated in
Furthermore, as the diameter of the flux bodies 17 are determined by the diameter of the rib 21, the rib 21 has a size according to the size of each of the flux bodies 17. Still further, in the rib 21, a slit in the height direction may be formed on a portion of a side wall.
Additionally, in the protective element 10, as illustrated in
Openings of the holding holes 22 on the surface of the meltable conductor 13 are preferably circular in order to hold the flux bodies 17 in a well-balanced manner.
Furthermore, as the diameter of the flux bodies 17 are determined by the diameter of the holding holes 22, the holding holes 22 have a size according to the size of each of the flux bodies 17.
As illustrated in
Furthermore, as the diameter of the flux bodies 17 are determined by the diameter of the convex 23, the convex 23 has a size according to the size of each of the flux bodies 17.
As illustrated in
The holding member 24 is provided above the meltable conductor 13 by, for example, a side wall 24b being supported by the insulating substrate 11. It should be noted that the top surface 19a or a sidewall 19b of the covering member 19 may provide support for arranging the holding member 24 above the meltable conductor 13.
In this case, the holding hole 22 (not illustrated), as described above, may be provided on the meltable conductor 13 in a position opposing the rib 24a.
As illustrated in
By providing the holding member 24, the top surface 19a of the covering member 19 and the convex 23 formed on the surface of the meltable conductor 13 are separated and, even in the case that the flux bodies 17 cannot be held, the height of the holding member 24 above the meltable conductor 13 can be freely selected and the flux bodies 17 can be reliably held at predetermined positions on the surface of the meltable conductor 13 by tensile forces occurring between the convex member 23 and the holding member 24.
Method of Using the Protective Element
As illustrated in
The battery pack 30 includes a battery stack 35, a charging/discharging controlling circuit 40 for controlling charging/discharging of the battery stack 35, a protective element 10 according to the present invention for interrupting electricity to the battery stack 35 in the event of an abnormality, a detecting circuit 36 for detecting voltage in each of the battery cells 31 to 34, and a current controlling element 37 for controlling operation of the protective element 10 in accordance with detection results of the detection circuit 36.
The battery stack 35, comprising battery cells 31 to 34 connected in series and requiring a control for protection from over-charging or over-discharging state, is removably connected to a charging device 45 via an anode terminal 30a and a cathode terminal 30b of the battery pack 30, and the charging device 45 applies charging voltage to the battery stack 35. The battery pack 30 charged by the charging device 45 can be connected to a battery-driven electronic appliance via the anode terminal 30a and the cathode terminal 30b and supply electric power to the electronic appliance.
The charging/discharging controlling circuit 40 includes the two current controlling elements 41, 42 connected to the current path from the battery stack 35 to the charging device 45 in series, and the controlling component 43 for controlling the operation of these current controlling elements 41, 42. The current controlling elements 41, 42 are formed of a field effect transistor (hereinafter referred to as FET) and the controlling component 43 controls the gate voltage to switch the current path of the battery stack 35 between conducting state and interrupted state. The controlling component 43 is powered by the charging device 45 and, in accordance with the detection signal from the detecting circuit 36, controls the operation of the current controlling elements 41, 42 to interrupt the current path when over-discharging or over-charging occurs in the battery stack 35.
The protective element 10 is connected in a charging/discharging current path between the battery stack 35 and the charging/discharging controlling circuit 40, for example, and the operation thereof is controlled by the current controlling element 37.
The detecting circuit 36 is connected to each battery cell 31 to 34 to detect voltage value of each battery cell 31 to 34 and supplies the detected voltage value to a controlling component 43 of the charging/discharging controlling circuit 40. Furthermore, when an over-changing voltage or over-discharging voltage is detected in one of the battery cells 31 to 34, the detecting circuit 36 outputs a control signal for controlling the current controlling elements 37.
When the detection signal output from the detection circuit 36 indicates a voltage exceeding the predetermined threshold value corresponding to over-discharging or over-charging of the battery cells 31 to 34, the current controlling element 37, which is formed of an FET, for example, controls protective element 10 to interrupt the charging/discharging current path of the battery stack 35 without the switching operation of the current controlling element 41, 42.
In the protective element 10 having such a circuit configuration, the current path can be reliably interrupted by blowout of the meltable conductor 13 caused by heat generated by the heat-generating resistor 14.
Those skilled in the art will appreciate that the protective element according to the present invention is not limited to usage in battery packs of lithium ion secondary batteries but may be applied to any other application requiring interruption of a current path by an electric signal.
10 protective element, 11 insulating substrate, 12 electrodes, 13 meltable conductor, 13a melting portion, 14 heat-generating resistor, 15 insulating member, 16 heat-generating element extracting electrode, 18 heat-generating element electrode, 19 covering member, 21 rib, 22 holding hole, 23 convex, 24 holding member, 24a rib, 24b side wall, 30 battery pack, 31 to 34 battery cell, 36 detection circuit, 37 current controlling element, 40 charging/discharging controlling circuit, 41, 42 current controlling element, 43 controlling unit, 45 charging device
Number | Date | Country | Kind |
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2013-092328 | Apr 2013 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2014/061566 | 4/24/2014 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2014/175379 | 10/30/2014 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
6452475 | Kawazu | Sep 2002 | B1 |
20100206621 | Wada | Aug 2010 | A1 |
20110012704 | Kimura | Jan 2011 | A1 |
20120024491 | Kinney | Feb 2012 | A1 |
20120249283 | Kimura | Oct 2012 | A1 |
Number | Date | Country |
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2004-185960 | Jul 2004 | JP |
2010-003665 | Jan 2010 | JP |
2012-003878 | Jan 2012 | JP |
2012-256569 | Dec 2012 | JP |
Entry |
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Jun. 10, 2014 International Search Report received in International Patent Application No. PCT/JP2014/061566. |
Number | Date | Country | |
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20160049272 A1 | Feb 2016 | US |