1. Field of Invention
The invention relates to apparel, and in particular, to trousers and boots that may be used to protect the wearer from exposure to liquids, aerosols and/or vapors.
2. Discussion of Related Art
The field of the emergency response has become broader and of greater importance in the past several years. Emergency responders, such as firefighters, EMTs, policemen, civil defense workers and defense workers now need to be prepared for hazards beyond fires, floods, and conventional warfare. Firefighters can be well protected against flame, heat and water by firefighter apparel that includes waterproof and thermal layers, such as those described in U.S. Pat. No. 5,884,332 to Snedeker, which is incorporated by reference herein. Responders may now need to respond to incidents where it is important to be protected not only against flame, heat and water, but against toxic chemicals, chemical warfare agents and biological pathogens. These hazardous substances may be present in the form of solids, liquids, aerosols, vapors or gases and therefore may bypass the protection provided by conventional firefighter apparel that is typically designed to protect against flame, heat, and water.
Exposure to hazardous substances, such as chemical, biological or radiological agents, even minimal exposure, can be fatal or cause permanent injury. Apparel and equipment currently exist that are capable or partially capable of protecting a responder against these hazards, but in many cases, the apparel, which may be an impermeable full body suit may be uncomfortable and difficult or impossible to work in under some conditions. Furthermore, these protective suits may be of limited utility in responding to conventional fires or medical emergencies as their durability may be limited. Such garments are described, for example, in U.S. Pat. No. 5,948,708 to Langley.
These hazardous materials suits may limit mobility and may hamper a responder's ability to operate under emergency conditions. They typically do not provide protection from flame and/or heat. In addition, the lack of comfort that is typically experienced in using these types of protective suits means that responders are unlikely to don this protection until they are specifically called to respond to an unconventional event. Consequently, the emergency responder's ability to quickly rescue ambulatory victims or to escape from such an event with appropriate protection is compromised. Apparel that would provide comprehensive protection against chemical and biological hazards and would be more comfortable and user-friendly than hazmat suits would give the responder greater protection and confidence in performing his or her duties and would find widespread acceptance among responders of all types and, in particular, among firefighters.
The subject matter of this application may involve, in some cases, interrelated products, alternative solutions to a particular problem, and/or a plurality of different uses of a single system or article.
In one aspect, a protective boot for use with resistant barrier trousers is provided, the boot comprising an upper having an interior and an exterior, a sole affixed to the upper, and a flange around a portion of the exterior of the upper, the flange including a shoulder constructed and arranged to retain a resistant barrier liner cuff of the resistant barrier trousers.
In another aspect, a method of manufacturing a protective boot is provided, the method comprising attaching an upper to a sole, surrounding a portion of the upper with a flange, and securing the flange to the upper to produce a boot capable of interfacing with a cuff of a resistant barrier liner in a pair of trousers.
In the drawings,
b provides a perspective view of another embodiment of a boot and flange of the invention;
a provides a plan view of a strip of material prior to being formed into a flange;
b provides an end view of the flange of
a provides a view of a thermal liner removed from the trousers of
b provides a view of the liner of
In one aspect, the invention relates to boots including a flange for forming a vapor/liquid resistant seal when used in conjunction with vapor/liquid resistant trousers.
In another aspect, the invention relates to vapor/liquid resistant trousers for protecting the wearer against chemical and/or biological contamination.
In another aspect, the invention relates to a boot and trouser combination designed to protect the wearer against chemical and/or biological contamination.
In another aspect, the invention relates to trousers that may include a liner wherein the liner includes a gusset for protecting the torso of the wearer from contamination with chemical and/or biological hazards.
“Selectively Permeable” describes a material that allows the passage of some substances while preventing the passage of others.
“Vapor/liquid Resistant” means that a material with this property can prevent entry of undesirable vapors and/or liquids as well as aerosols. It may be permeable to some substances such as water vapor.
“Resistant barrier layer” means a layer that prevents the passage of a hazardous substance such as a chemical agent or a biological pathogen.
“Water Vapor Permeable” describes a material that is substantially impervious to liquid water but can allow the passage of water vapor at a rate of at least 100 g/m2/day.
The invention is directed, in part, to a system of apparel that provides a protective interface between trousers and boots worn by a responder. Whereas previously designed interfaces between pant cuff and boot may have been ineffective at preventing materials such as chemical agents and biological pathogens from contacting the wearer, the apparel system described herein may be used to effectively reduce or prevent the breach of dangerous substances through this interface. In one aspect, an apparel system includes trousers comprising, in part, a resistant barrier layer that may be effective at repelling dangerous vapors, aerosols and liquids. In some embodiments, the barrier layer is permeable to water vapor, allowing the garment to breathe while protecting the responder from dangerous vapors and/or liquids. The barrier layer may include a cuff in the ankle area that is designed to form a vapor/liquid resistant interface with a boot as described below.
In another aspect, a boot is provided that allows the boot to be joined to the trousers in a manner that can prevent the entry of vapors, aerosols and/or liquids. The boot may include a flange that surrounds the upper of the boot, and this flange may be used to interface with the cuff of a pair of trousers, thus allowing the trousers and boots to be donned independently while providing a continuous safety barrier from waist to toe. The flange may aid in preventing the trouser cuff from pulling off of the boot. The flange may include a shoulder, groove or cavity that provides a secure surface for retaining the cuff of the trousers even during the strenuous activities that a responder may experience during a response event. The boots may be used with or without the trousers and the barrier layer cuff may be engaged or disengaged with the boot by the responder. In addition to protecting against chemical and biological hazards, the boots may be worn by a responder, such as a firefighter, prior to or after an event or during a conventional emergency where protection against chemical agents and biological pathogens may not be necessary.
Similarly, the trousers may be used under a variety of conditions as they may include a resistant barrier liner that can either be removable or may be permanently attached. In addition, the trousers may optionally be worn with boots not specifically designed for interfacing with the trousers. The boot may include a resistant barrier layer made of similar material to that used in the trousers, or may be made of a different material or combination of materials. For example, the boot may include a non-permeable barrier that need not be breathable while the trousers may include a breathable barrier layer. This breathable layer can provide for the expulsion of moisture from a significant portion of the responder's skin surface, providing a greater degree of comfort. In a preferred embodiment, both the boots and the trousers include a water vapor permeable layer providing comfort to the wearer for extended periods of time.
A resistant barrier layer can function by preventing or retarding hazardous substances such as toxic chemicals, chemical warfare agents and biological pathogens from reaching the skin of the responder. The barrier layer may typically be one of two different types. A first type of barrier layer functions by repelling substances such as liquids and vapors. For example, the barrier layer may prevent the passage of a particular compound by exhibiting pore sizes that exclude a compound from passing through. A second type of barrier layer functions by adsorbing a substance rather than excluding it. For example, the barrier layer may include an adsorbent, such as activated carbon, that prevents the passage of undesirable substances by causing the substances to adhere to the adsorbent. In this manner, the substance may not be repelled by the barrier but is prevented from reaching the skin of the responder.
The resistant barrier liner may be made of any material that prevents or inhibits liquids and/or vapors from penetrating the liner. The barrier liner may be formed from woven and/or non-woven materials such as membrane films and in some embodiments is permeable to water vapor. The barrier layer may include one or more layers, for example, the barrier layer may be a laminate comprising a backing material or support layer laminated to a layer of semi-permeable membrane material and may also include an abrasion resistant material. The different layers may be affixed together by an adhesive. Some examples of polymers that may be useful as adhesives include polyurethane, natural latex rubber, nitrile rubber, silicone rubber, butyl rubber, fluorinated rubber, copolyether polyester, polyester, ethylene vinyl acetate or polyamide.
The resistant barrier layer or liner may include selectively permeable materials such as semi-permeable or “breathable” membranes that are water vapor permeable. Selectively permeable materials can include, for example, polyurethane, polytetrafluoroethylene (PTFE), polyester, polyether, polyamide, polyacrylate, copolyether ester and copolyether amides. Some preferred breathable membranes include expanded PTFE such as described in U.S. Pat. No. 4,187,390, incorporated by reference herein. Other materials that may be used in one or more layers of a resistant barrier liner include aramids such as NOMEX™ and para-aramids such as poly para-phenyleneterephthalamide. Additional materials that can be used in resistant barrier layers are described in U.S. Pat. No. 7,022,632, titled COMPOSITE NONWOVEN FABRIC FOR PROTECTIVE CLOTHING AND PRODUCTION METHOD THEREOF, and in U.S. patent application Ser. No. 10/513,738, titled BREATHABLE ARTICLES, published as 2005/0176331; both of these applications are incorporated by reference herein.
When worn together, the trousers and boots of the invention can provide an ensemble that may protect the wearer from waist to toe from exposure to harmful chemicals and biological pathogens that are typically in the form of (or carried in) vapors or liquids. The trousers may be combined with additional garments, for example, a coat, hood, breathing apparatus and/or gloves to provide full body protection. The trousers and/or boots may include one or more layers in addition to a barrier liner. For example, the trousers and/or boots may include an abrasion-resistant layer, a thermal layer and/or a flame resistant layer. Choice of layers may be determined in part by the type of emergency or situation that the responder is most likely to be called to. The amount of time the responder is expected to wear the garment may also help to determine the composition of the trousers and/or boots. Firefighters' apparel, for example, may include flame resistant and thermal layers. A soldier's apparel, however, might not include a thermal layer but may include a camouflage abrasion resistant layer.
Materials may be chosen so that the ensemble or apparel complies with one or more of NFPA Standards 1951, 1971, 1992, 1999, and 1994. Specifically, in some embodiments, the combination trousers and boots may form part of an ensemble that pass the “Man In Simulant Test” to meet the CBRN option of NFPA 1971. Some compounds and biological pathogens that may be specifically protected against include, for example, nerve agents, mustard gas, phosgene, sarin, pathogenic bacteria such as anthrax, and viruses. The apparel may also prevent the transmission of radioactive particulates or aerosols.
In some embodiments the boots may be used with or without trousers that include a barrier layer. A boot that can optionally be used with other types of trousers may be preferred by some users because this feature can allow the user to retain a single pair of boots that can be used under a variety of conditions. For instance, a firefighter may use the boots in combination with conventional firefighter's garments such as trousers that include an abrasion-resistant layer, a water proof layer, and a thermal layer, but that may not include a resistant barrier liner with an interlocking ankle cuff. However, preferably without modification, the same boots may be also be worn with the resistant barrier layer trousers described herein.
One aspect of the invention is depicted in
As shown in
Flange 130 may be produced in a number of ways. For example, flange 130 may be formed, or molded, in a single, substantially ring-shaped piece or may be linearly extruded and cut into lengths equal to the circumference of the final flange. For some embodiments, the flange may be subjected to machining. In the case of extrusion, the ends may be subsequently connected end-to-end to form a substantially circular flange. Ends may be joined by connectors made out of, for example, leather, plastic, or rubber. The connectors may be joined to flange 130 using, for example, an adhesive or rivets. In other embodiments, adhesives or mechanical connectors, such as shrink-tubing for example, may be used to directly join the ends of the flange. Alternatively, some materials, such as thermoplastics, may be joined end-to-end by softening or melting the ends and adhering them together. The flange may vary in width and can be size-optimized to securely retain the trouser cuff when engaged while also minimizing interference with activity when used with other trousers or when not engaged with the cuff. In cases where flange 130 is formed integrally as part of the upper there need not be a step of attaching the flange to the upper. If flange 130 is a separate component as shown in
Other methods of attachment include, for example, stitching and ultrasonic welding. In some cases it may be advantageous to include a gasket between the flange and the upper in order to prevent leakage into the boot and/or into the trouser area. In some embodiments, a linear flange may be joined end-to-end concurrently with attachment of the flange to the upper. In other cases, the attachment to upper 120 may force the ends of the linear flange together when wrapped around upper 120, resulting in a circular flange. Although the ends may not be adhered together, they may be in contact and under compression to prevent any significant leakage between the surfaces. Under these conditions there may not be a need to adhere the ends together.
In
In
It has been found that dangerous leakage through conventional boot-trouser interfaces is most prevalent when the responder (wearer) bends the boot upper during vigorous activity, such as when walking, running or climbing. For instance, see the position of the boot shown in
The use of a flange of substantial rigidity (in comparison to the upper material) in contact with the exterior of the upper may result in the elimination of these crevices with only a minimal decrease in the flexibility of the upper. Therefore, a trouser cuff can form a vapor/liquid tight seal that is not subject to crevice formation during movement. Any crevices that do form in the upper may be terminated at the flange due to, for example, the flange's thickness and/or higher rigidity. When a trouser barrier cuff is mated to the flange, the cuff may be in consistent surface contact around the entire flange because crevice formation is prevented even during vigorous activity. This can provide for the consistent maintenance of a vapor/liquid tight seal between the cuff and the flange which can help protect the responder from intrusion of vapors/liquids through the boot/cuff interface, particularly while running, climbing, crawling, etc.
In some embodiments, e.g.,
b illustrate an embodiment wherein the flange may be formed of leather and provides an integral shoulder 132 to retain the cuff. This embodiment does not include a cavity as does the embodiment of
As the flange exhibits a greater circumference in a central portion (shoulder 132) than along edges 142 and 144, if the flange is formed from a substantially flat strip, sections such as triangular portions 146 and 148 may be removed from the strip to help form a proper shape when wrapped around the upper and secured. The resulting seams may be sealed, for example, with an adhesive. An additional treatment such as a wax or temporary adhesive may be used on the flange in order to increase the friction between the flange and a trouser cuff (as described herein).
In another aspect, vapor/liquid resistant barrier trousers are provided. The trousers may include an abrasion resistant outer layer 280 and a resistant barrier liner or layer 240 that can substantially prevent the intrusion of hazardous substances such as toxic chemicals and biological pathogens. Such trousers may be referred to as C/B or CBRN trousers. Substantially preventing the intrusion of a substance means that the substance is excluded at an efficiency whereby the garment satisfies the standard defined by NFPA 1971. Typically, this also means that the trousers (in combination with other apparel when appropriate) are in compliance with one or more of NFPA Standards 1951, 1971, 1992, 1999, and 1994, which are incorporated by reference herein.
A resistant barrier liner may be integral to other trouser layers or it may be an independent layer. If an independent layer, the liner may be removable from the trousers. Trousers with a removable liner may be used with or without the liner and this feature may also facilitate servicing of the trousers, the liner, or both. A removable barrier liner may be temporarily attached to the trousers by fasteners such as, for example, buttons, snaps, zippers or hook and loop.
Preferably, the trousers form a releasable seal with a boot providing for separate pieces of apparel (boot and trousers) to be temporarily joined to form a vapor/liquid barrier to protect the responder. The trousers may include cuff 230 and optional second cuff 250. Second cuff 250 may be comprised of the same materials as cuff 230. Cuff 230 is constructed and arranged to interface with a flange of a boot such as flange 130 as illustrated in
Elastic material 234 may be hemmed into the cuff using conventional sewing techniques. Stitching, however, may be backed up with a non-permeable or selectively permeable tape to prevent leakage through the stitching. The elasticity is typically supplied by a polymer, a metal, a natural rubber, or a synthetic rubber. Different types of elastic include, for example, elastic tape, elastic cord and polymeric or metallic springs. In addition to placing an elastic band or cord in the cuff, there are other methods of forming a seal with the boot flange. Additional methods of temporarily securing the cuff to the boot flange include, for example, drawstring, hook and loop fasteners, flaps, snaps, clips, magnets, tape and pressure sensitive adhesive.
In another embodiment, the resistant barrier liner itself may be a resilient, stretchable fabric that exhibits enough tension itself to form a secure seal around the flange. Preferably, the fabric will stretch to an extent that allows the user to expand the circumference of the cuff opening by 2 cm or more. This may allow the wearer to pull the cuff over the boot flange and allow it to contract and seal against or below the shoulder of the flange. In this case, no additional elastic or closure may be required.
When a responder wearing trousers bends at the knee, for example when walking or climbing, the liner may be contracted in an upward direction and as a result applies an upward force to the cuff. In conventional trousers this movement is not a hindrance as the trouser cuff can freely slide up and down the boot. However, when a trouser liner is fixed to the boot, any resulting movement may either be restricted or may forcefully remove the cuff from the flange. In one set of embodiments, the trouser leg may be asymmetrical with the front portion of the leg longer than the rear portion. One, two or more layers of the trouser may be cut in this fashion. For example, the abrasion layer and/or the thermal layer and/or the resistant barrier layer may include a series of pleats and/or darts to add length in the area over the knee. For examples of this fitting technique, see co-owned U.S. Pat. No. 7,065,796, titled FIRE PROTECTIVE TROUSERS EXHIBITING REDUCED BINDING which is incorporated by reference herein.
In another set of embodiments this effect may be reduced or prevented by forming and shaping the liner, including the cuff(s), to be longer than the exterior layers of the trousers. This extra length is shown in, for example,
An optional second cuff 250 may also be formed from the resistant barrier liner. The cuff may be of the same or different material than primary cuff 230 and may be of similar design. Second cuff 250 may be of slightly smaller circumference than primary cuff 230 because it typically forms a vapor/liquid seal directly with the outer surface of the upper of the boot, above the flange. Secondary cuff 250 can supply an additional defense against breach of the trouser/boot interface. Should the first cuff leak for any reason, an optional second cuff may help to maintain the integrity of the ensemble.
In another aspect of the invention, a trouser is provided that includes a resistant barrier liner having a gusset portion to protect the mid-section of the responder.
The front portion of conventional firefighter's trousers include a fly typically closeable by a zipper or snaps and partially sealed by overlapping flaps of outer material. This design is often adequate for keeping the firefighter dry under most firefighting conditions. The fly also facilitates the donning and removal of the trousers, but it may not provide adequate protection against intrusion of hazardous vapors and/or liquids. Thus, to protect a responder under conditions that may include chemical agents and biological pathogens, a different design is desired.
While several embodiments of the present invention have been described and illustrated herein, those of ordinary skill in the art will readily envision a variety of other means and/or structures for performing the functions and/or obtaining the results and/or one or more of the advantages described herein, and each of such variations and/or modifications is deemed to be within the scope of the present invention. More generally, those skilled in the art will readily appreciate that all parameters, dimensions, materials, and configurations described herein are meant to be exemplary and that the actual parameters, dimensions, materials, and/or configurations will depend upon the specific application or applications for which the teachings of the present invention is/are used. Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, many equivalents to the specific embodiments of the invention described herein. It is, therefore, to be understood that the foregoing embodiments are presented by way of example only and that, within the scope of the appended claims and equivalents thereto, the invention may be practiced otherwise than as specifically described and claimed. The present invention is directed to each individual feature, system, article, material, kit, and/or method described herein. In addition, any combination of two or more such features, systems, articles, materials, kits, and/or methods, if such features, systems, articles, materials, kits, and/or methods are not mutually inconsistent, is included within the scope of the present invention.
All definitions, as defined and used herein, should be understood to control over dictionary definitions, definitions in documents incorporated by reference, and/or ordinary meanings of the defined terms.
The indefinite articles “a” and “an,” as used herein in the specification and in the claims, unless clearly indicated to the contrary, should be understood to mean “at least one.”
The phrase “and/or,” as used herein in the specification and in the claims, should be understood to mean “either or both” of the elements so conjoined. Other elements may optionally be present other than the elements specifically identified by the “and/or” clause, whether related or unrelated to those elements specifically identified unless clearly indicated to the contrary.
All references, patents and patent applications and publications that are cited or referred to in this application are incorporated in their entirety herein by reference.
This application claims benefit of U.S. Provisional Patent Application Ser. No. 60/753,966, filed Dec. 23, 2005, titled PROTECTIVE APPAREL FOR FIREFIGHTERS AND EMERGENCY RESPONDERS and which is incorporated by reference in its entirety herein.
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