Patent Application
20140154509
The present disclosure relates to providing a sintered polycrystalline diamond (PCD) that is free of Co, W, or other metals. The PCD can be made entirely free of metals or can be free of metals on a top layer ranging in thickness from a few to several hundred microns. Furthermore, the catalyst free layer is made without the use of acids, which are often dangerous and costly to use.
This catalyst free layer may be produced during the high pressure and high temperature (HPHT) sintering process that is used to make the PCD itself. Benefits of this invention include providing a PCD that is thermally stable, that possesses improved abrasion resistance, and that may be produced more cheaply and safely than existing methods for providing catalyst free PCD.
PCD is formed by sintering diamond particles under high pressure and high temperature (HPHT) in the presence of a metal catalyst (such as cobalt, Co). Typical HPHT conditions include pressures at or above about 45 kBar and temperatures at or above about 1400° C. Carbon from the diamond particles is dissolved by, and then re-precipitated as diamond, from the metal catalyst. The presence of the metal catalyst facilitates formation of inter-particle diamond growth, which binds the diamond particles together as a sintered compact. However, the metal catalyst remains in the PCD compact after the HPHT sintering process, and the presence of the metal catalyst is detrimental to PCD performance when the compact is used in cutting and machining applications. In particular, the presence of the metal catalyst in the PCD compact may have detrimental effects on the PCD when used in intended applications.
This is because the frictional heat generated during the rock or metal cutting process promotes back conversion of the diamond to graphite, thereby leading to pre-mature wear. Also, because of differences in the coefficient of thermal expansion (CTE) between diamond and metal, the metal will expand more as the compact is heated and thereby may induce micro-cracking in the diamond compact and leading to pre-mature failure. Removing the metals from the sintered PCD is thought to be effective in mitigating these problems.
Other ways to provide a catalyst free PCD is by sintering at elevated pressure as described in Sumiya. (Sumiya, H., et al., Microstructure features of polycrystalline diamond synthesized directly from graphite under static high pressure. Journal of Materials Science, 2004. 39: p. 445-450). However, sintering conditions are so extreme (>15 GPa, >2300° C.) that this method is not economically feasible for industrial scale production. Still another way is to synthesize diamond by chemical vapor deposition (CVD). However, the rate of formation of diamond, the deposition rate, is at the order of 0.1 μm/hour, which renders this technology economically infeasible for industrial scale production.
Therefore, as can be seen, there is a need for a thermally stable, catalyst free, abrasion resistant, and strong PCD that may be produced economically and without the use of acid leaching.
In one exemplary embodiment, a cutting element for a tool may comprise a substrate; a polycrystalline diamond table bonded to the substrate; and a diamond volume substantially free of catalytic material attached to the polycrystalline diamond table, wherein the polycrystalline diamond table is sandwiched between the substrate and the diamond volume substantially free of catalytic material.
In another exemplary embodiment, a method of making a cutting element may comprise steps of positioning a diamond volume between a substrate and graphene; and sintering the graphene onto the diamond volume and the substrate. In the process of sintering, graphene is converted to diamond.
In further another exemplary embodiment, a method of making a cutting element may comprise steps of positioning a diamond volume onto a substrate; disposing a pill adjacent to the diamond volume distal from the substrate; sintering the pill to form a layer adhered to the diamond volume and secured to the substrate.
It is to be understood that both the foregoing general description and the following detailed description are exemplary and explanatory and are intended to provide further explanation of the invention as claimed.
Before the present methods, systems and materials are described, it is to be understood that this disclosure is not limited to the particular methodologies, systems and materials described, as these may vary. It is also to be understood that the terminology used in the description is for the purpose of describing the particular versions or embodiments only, and is not intended to limit the scope. For example, as used herein, the singular forms “a,” “an,” and “the” include plural references unless the context clearly dictates otherwise. In addition, the word “comprising” as used herein is intended to mean “including but not limited to.” Unless defined otherwise, all technical and scientific terms used herein have the same meanings as commonly understood by one of ordinary skill in the art.
Unless otherwise indicated, all numbers expressing quantities of ingredients, properties such as size, weight, reaction conditions and so forth used in the specification and claims are to be understood as being modified in all instances by the term “about”. Accordingly, unless indicated to the contrary, the numerical parameters set forth in the following specification and attached claims are approximations that may vary depending upon the desired properties sought to be obtained by the invention. At the very least, and not as an attempt to limit the application of the doctrine of equivalents to the scope of the claims, each numerical parameter should at least be construed in light of the number of reported significant digits and by applying ordinary rounding techniques.
As used herein, the term “about” means plus or minus 10% of the numerical value of the number with which it is being used. Therefore, about 50% means in the range of 45%-55%. When the term, “substantially free”, is used referring to catalyst in interstices, interstitial matrix, or in a volume of polycrystalline element body, such as polycrystalline diamond, it should be understood that many, if not all, of the surfaces of the adjacent diamond crystals may still have a coating of the catalyst. Likewise, when the term “substantially free” is used referring to catalyst on the surfaces of the diamond crystals, there may still be catalyst present in the adjacent interstices.
As used herein, the term “graphene” refers to a form of graphitic carbon, in which the carbon atoms are arranged in a 2-dimensional hexagonal lattice, that can be as thin as one atomic layer (<1 nm). These layers can also exist as multiple stacked sheets. The graphene particles have a very high aspect ratio such that, thickness (the z-axis) can be on the order of 100 nm (nanometers) whereas the ‘x’ and ‘y’ dimensions can be on the order of 100 μm (microns). The oxygen content of the material may be between about 1.0% to about 5.0%, in some embodiments about 1.2% to about 2.0% and in some embodiments, about 1.4%.
The sintered PDC cutters, representing a polycrystalline diamond volume bonded to a tungsten carbide cobalt substrate (WC—Co), were fabricated using the first HPHT process. After fabrication all PDC cutters were shaped by grinding and polishing to the cylindrical shape with diameter 13 mm and height 8 mm. The thickness of polycrystalline diamond table was about 2 mm. Finally, a chamfer (0.5 mm, 45°) was made on the top edge of polycrystalline diamond table of each cutter. After shaping completion, the cutter's surface was cleaned by sand blasting using SiC beads.
Raman spectroscopy was performed on a Horiba LabRAM HR instrument using 785 nm and 532 nm laser excitation with a 600 grating and an aperture size between 100 μm and 1000 μm. A 50× objective lens was used, and collection time was for 10 second each for 20 accumulations.
Scanning electron microscopy (SEM) and elemental analysis (EDS) were performed on a 4500 Hitachi SEM with 25 kV accelerating voltage. EDS was done with an Oxford XMAX with solid state detector.
Exemplary embodiments disclose a cutting element for a tool and a method of making the cutting element. In an exemplary embodiment, a pill made from graphene, or fullerene may be loaded into a tantalum cup. The fullerene may comprise C60, C70, carbon nanotubes, for example. Into this cup may be placed diamond powder or sintered diamond table and a tungsten carbide substrate. This assembly may be loaded into a HPHT cell and pressed at up to 75 kBar and up to 1600° C. The recovered part has a layer of diamond, the top of which is free of cobalt or other metal catalysts.
The polycrystalline diamond volume 33 substantially free of catalytic material may be converted from graphene, fullerene under high pressure high temperature. Without intending to be bound to any particular theory, it may appear that under high pressure high temperature, p-electrons on carbon atoms of graphene or fullerene may attract every other carbon atom on graphene to cause the carbon to pucker, thus forming a diamond material as sp3 carbon bond from sp2 carbon bond graphene or fullerene.
Still in
In one exemplary embodiment, the polycrystalline diamond table 34 may be a leached polycrystalline diamond table. Thus, in an exemplary embodiment described here, the surface of machined PDC cutter 12 was treated in a mixture of acids in order to remove a surface layer of a catalyst. The polycrystalline diamond table 34 may be depleted in cobalt to a necessary one or several depths from, correspondently: an outer peripheral upper surface 24, chamfer 25, or an outer peripheral side surface 26. The polycrystalline diamond table 34 rich in catalyst may extend along the side surface 26 but does not reach the interface 22 with the substrate 20; a working surface 23 that includes a planar upper surface 24 and a chamfer 25. In particular cases, a catalyst substantially leached area may extend away from an upper surface 24 to a first predetermined depth, from a chamfer 25 to a second predetermined depth, and from a side surface 26 to a third predetermined depth.
For example, each depletion depth, as it is described above, may be from about 10 μm to about 650 μm, or it could be from about 2 μm to about 60 μm, for example. Also, for example, a third depletion depth may constitute of at least half of the overall thickness of the polycrystalline diamond table 34, but stops short of the interface 22 by at least about 650 μm, for example.
These PDC cutting elements 12 may be made in a conventional very high pressure and high temperature pressing (or sintering) operation, and then finished and machined into the cylindrical shapes shown. One such process for making these PDC cutting elements 12 may involve combining mixtures of various sized diamond crystals into diamond powder layer 36 with a pill 38 which may include graphene, or fullerene, and diamond, and substrate 20 in a tantalum cup 31 as shown in
As shown in
In one exemplary embodiment, diamond volume may be a mixture of various sized diamond crystals as shown in
Forming these cutting elements 12 with more than one HPHT cycle may be called ‘double pressing’. But the process for manufacture may be difficult, costly and cause internal defects in the product. These defects may lead to limited wear life of the resulting product. In particular, HPHT sintering of round discs onto a PDC in a second press cycle may lead to cracking of the diamond layer due to stresses developed during the process.
An alternate process for double pressing PDC cutting elements as described herein may involve an HPHT sintered PDC which includes diamond table 52 and the substrate 20. Previously pressed PDC material may have substantially all metallic materials removed from its crystalline structure by, for example, acid leaching. The graphene or fullerene, such as a graphene or fullerene pill 38, may then be layered (or otherwise dispersed) and assembled with a sintered PDC cutting element, as shown in
In one exemplary embodiment, the double press onto the substrate may include a first press at higher temperature than catalyst melting point, to affect standard polycrystalline diamond sintering, and a second press at temperature lower than catalyst melting point. Under the second press at temperature lower than catalyst melting point, the catalyst, such as cobalt, does not melt and graphene or fullerene may convert to polycrystalline diamond without the aid of catalyst.
0.1 g of graphene was pressed into a 13 mm diameter pill which was placed in a Ta cup. Diamond powder (1.1 g) was then put into the Ta cup and then capped with a tungsten carbide (WC) cylinder to seal the cup. This assembly was loaded into a high pressure cell and pressed at 75 kBar and 1300˜1600° C. for a few minutes, then brought back to atmospheric pressure and recovered from the high pressure cell. The Ta layer was removed by grinding. Raman analysis on the sintered materials revealed the presence of both diamond and graphite. There were no graphene peaks (about 1600 cm−1 & 2700 cm−1) being detected. In
Ta cups were filled with loose graphene powder (0.1 to 0.22 g). Then, sintered PDC on a WC substrate, as shown in
In a third embodiment, Ta cups were loaded with graphene pill of approximate weight 0.9 to 0.95 g. A sintered PDC on a WC substrate was loaded and the assembly dried. Pressing was done at 75 kBar and 1300° C. for soak time of 8 minutes. Visually, these samples appeared different from standard PDC in that they appeared to have ‘wrinkles’ and some cracks, and did not appear to have reflective metal regions on the surface when observed in the optical microscope. SEM images (
The samples were OD ground to 16 mm and chamfered (0.016″) prior to testing their abrasion resistance. Diamond PDC cutters were subjected to abrasion test, representing a standard vertical turret lather test using flushing water as a coolant (VTL-c). The PDC cutter was oriented at a 15° back rake angle against the surface of Barre Gray Granite rock wheel having a 1.82 m diameter. Such rock materials may comprise a compressive strength of about 200 MPa. The tested cutter traveled on the surface of the granite wheel while the cutting element was held constant at a 0.36 cm depth of cut and the feed was 0.36 mm/revolution.
The wear curve (
The similar experiments as example 3 were done except that PDC cutters were chemically etched in acid solutions and then boiled in deionized water to clean from etching deposits. Different etching times provided PDC cutters with different Co depletion depths from the surface, such as from 10 to 200 μm deep. Co depletion depth was measured by SEM on sample cross-sections obtained after completion and subsequent abrasion tests. Several etched cutters were further used for diamond coating and others were used as the references in abrasion tests.
Although described in connection with preferred embodiments thereof, it will be appreciated by those skilled in the art that additions, deletions, modifications, and substitutions not specifically described may be made without departure from the spirit and scope of the invention as defined in the appended claims.
