All rights, including copyrights, in the material included herein are vested in and the property of the Applicant. The Applicant retains and reserves all rights in the material included herein, and grants permission to reproduce the material only in connection with reproduction of the granted patent and for no other purpose.
Extrusion is a process used to create objects of a fixed cross-sectional profile. A material is pushed or drawn through a die of a desired cross-section. Because a material only encounters compressive and shear stresses, extrusion provides the ability to create objects having complex cross-sections.
This Summary is provided to introduce a selection of concepts in a simplified form that are further described below in the Detailed Description. This Summary is not intended to identify key features or essential features of the claimed subject matter. Nor is this Summary intended to be used to limit the claimed subject matter's scope.
Plastic zone extrusion may be provided. First, stock may be placed in a chamber. Then frictional heat may be generated within the stock to heat the stock to a plastic zone of the stock in the chamber. The stock may then be extruded through an orifice in the chamber after the stock is at the plastic zone.
Both the foregoing general description and the following detailed description provide examples and are explanatory only. Accordingly, the foregoing general description and the following detailed description should not be considered to be restrictive. Further, features or variations may be provided in addition to those set forth herein. For example, embodiments may be directed to various feature combinations and sub-combinations described in the detailed description.
The accompanying drawings, which are incorporated in and constitute a part of this disclosure, illustrate various embodiments of the present invention. In the drawings:
The following detailed description refers to the accompanying drawings. Wherever possible, the same reference numbers are used in the drawings and the following description to refer to the same or similar elements. While embodiments of the invention may be described, modifications, adaptations, and other implementations are possible. For example, substitutions, additions, or modifications may be made to the elements illustrated in the drawings, and the methods described herein may be modified by substituting, reordering, or adding stages to the disclosed methods. Accordingly, the following detailed description does not limit the invention.
For the U.S. domestic metal producers (steels, Al alloys, Ti alloys, for example), recycling scraped materials is of prominent importance for a number of reasons. First, there are great concerns on the environmental issues related to disposing the scraped metals as industrial wastes. There is also an issue of diminishing domestic natural mineral resources, in contrast to the abundance and continuing pileups of scraped metals produced over the years of industrialization. The primary driver may be in the economics. It may be far cheaper, faster, and more energy-efficient to recycle than to manufacture from ores. In addition, capital equipment costs may be low for recycling. For example, recycling aluminum may require only about 10% of the capital equipment costs of these for production from ore. Mini steel mills with EAF furnaces that mainly use scraps as feedstock may also be less expensive to construct than the large BOF based integrated mills.
The U.S. Department of Energy's Industrial Technology Program (ITP) conducted a series of studies looking into the energy consumptions in the most energy-intensive industry sectors. For both steel industry and aluminum industry—the two largest metal making industries in the U.S.—converting scraps into usable products have become the major source of production.
Since the 1960's, recycling aluminum scraps in the U.S. has steadily grown, both in terms of the tonnage, and the percentage of total production. In 2000, nearly half (48.5%) of the aluminum metal produced in the U.S. was from recycled material. Similar trend exists in steelmaking. Steel has become the most recycled material, with two-third of U.S. steel now produced from scrap. Over ten million cars are shredded annually and the shredder scrap from these cars is returned to the melt shops.
Melting the feedstock may be a major energy efficiency barrier in metal recycling. In general, melting and melt processing operations may be the most energy intense of all post-smelting processes. Thermal energy may be used to heat the scrap from ambient temperature to well above the melting point. A considerable portion of the thermal energy may be consumed to overcome the latent heat of fusion associated with melting. The thermal efficiency of today's melting process may be also low. For steel, the best-practice energy usage of EAF steelmaking using 100% scrap charge is about 6.7 MBtu/cast ton, about five times of the theoretical minimum energy. For aluminum, the ratio is 2.50 kWh/kg to 0.33 kWh/kg—the actual usage is about 7.6 times of the theoretical minimum value.
Recycling of scrap materials has become a major source and will play an even more important role in future production and manufacturing of industrial metals in the U.S. The shift to a recycling dominant metal-making market represents a fundamental change in the feedstock materials in the US. This shift also presents a window-of-opportunity to re-think how metals should be produced from recyclables with even greater energy efficiency, environmental benefits, and product quality.
The stock may comprise any material that may be placed in the stock's plastic zone by plastic zone extrusion system 100. For example, the stock may comprise aluminum, copper, or a combination. The stock, for example, may comprise shavings or swarf. Swarf may comprise metal shavings or chippings, for example, debris or waste resulting from metalworking operations. Swarf may be recycled, for example, due to the environmental concerns regarding potential contamination with liquids such as cutting fluid or tramp oil. These liquids may be separated from the metal using a centrifuge, thus allowing both to be reclaimed and prepared for further treatment.
Moreover, consistent with embodiments of the invention, the stock may comprise one metal, a plurality of any metals, or a combination of a metal or metals with another non-metal substance or substances. For example, the stock may comprise both copper and aluminum. With conventional systems, there may be a limit to the amount of molten copper that can mix homogeneously with molten aluminum. Consistent with embodiments of the present invention, the stock may include copper and aluminum in any percentage. Consequently, a wire may be constructed balancing aluminum's strength and light weigh with copper's conductivity. In other words, copper may be added to aluminum stock to increase the stocks conductivity.
The stock may also comprise any recycled or recyclable substance such as shredded aluminum cans. With conventional systems, recycled material, such as aluminum cans, must go through a “de-lacquering” process to remove substances from the recycled material. Consistent with embodiments of the invention, wire may be constructed using shredded aluminum cans that have not been de-lacquered thus avoiding costs associated with de-lacquering. While such wire may not have as high conductivity as stock that has been de-lacquered, this wire may be used in situations in which this is not an issue (e.g. fence wire).
Furthermore, consistent with embodiments of the invention, nano-particles may be added to the stock. For example, nano-particles of aluminum oxide may be added to aluminum stock to increase strength and conductivity of wire made with this stock. Notwithstanding, added nano-particles may add to the strength, conductivity, thermal expansion, or any physical or chemical property of wire made from stock with nano-particles added. With conventional systems, because material used to make wire has to be heated at least until it melts, any nano-particles added in conventional systems my not be stable (e.g. may lose their desired properties) at the temperature of molten metals.
A highly energy-efficient solid-state material synthesis process—a direct solid-state metal conversion (DSSMC) technology may be provided. Specifically, nano-particle dispersion strengthened bulk materials may be provided. Nano-composite materials from powders, chips, or other recyclable feedstock metals or scraps through mechanical alloying and thermo-mechanical processing may be provided in a single-step. Producing nano-engineered bulk materials with unique functional properties (e.g. thermal or electrical) may also be provided. Nano-engineered wires may be used in long-distance electric power delivery infrastructure.
Embodiments of the present invention may comprise a DSSMC system and method. These systems and methods may eliminate the need of melting (the most energy extensive step) during scrap-to-metal conversion/recycling process, thereby reducing the energy consumption and the cost of the metal making. Furthermore, since melting and solidification may be avoided, embodiments of the invention may open new pathways toward producing new classes of materials such as nano-engineered structural and functional materials by using, for example, mechanical alloying and processing. Embodiments of the present invention may use friction extrusion of metal recycling and friction stir processing of nano-particle strengthened surfaces.
Friction extrusion may be a direct solid-state metal conversion process. Friction extrusion is shown in
As shown in
Consistent with embodiments of the invention, the extensive thermo-mechanical deformation may be to produce mechanically alloyed materials. Aluminum powder 2618 and 40% micron-sized silicon carbides may be used as the feedstock. Consistent with embodiments of the invention, most processed materials may be produced with reasonable appearance, consequently at least partial consolidation and conversion of the feedstock materials may be achieved.
Consistent with embodiments of the invention, the product from the friction extrusion may be a round wire/bar. However, other forms or shapes of products could be made through use of different die and plunger designs. Also, there may be no barrier limiting the size of the final products, if the process consistent with embodiments of the invention is scale up, for example, through additional hot extrusion/forming/rolling of the billet produced from multiple friction extrusion stations.
Consistent with embodiments of the invention, friction stir processing (FSP) may incorporate nano-sized oxide particles into Al matrix to form a mechanically alloyed hard and strong nanocomposite surface layer. FSP may comprise a variant of friction stir welding. In FSP (e.g.,
Consistent with embodiments of the invention, up to 20% volume fraction of nano-sized Al2O3 particles may be uniformly dispersed and mechanically alloyed with the Al matrix to form a nano-composite material with greatly increased strength. The Al—Al2O3 nano-composite may have over an order of magnitude higher compressive strength than that of baseline comparison metal. The wear resistance may be several orders of magnitude higher.
Embodiments of the invention may provide a direct solid-state metal conversion process that includes: (1) metal recycling with greatly improved energy efficiency; and (2) synthesis of nano-engineered bulk materials with enhanced mechanical strength and other unique functional properties.
DSSMC consistent with embodiments of the invention may provide high energy efficiency including an over 80% energy reductions in DSSMC over conventional metal conversion/synthesis processes that involve metal melting. Actual energy savings in production could be even higher, due to, for example, the energy efficiency of the mechanical system over the thermal/melting system. DSSMC may be environmentally friendly due to recycling scraps and low energy consumption.
Since melting and solidification may be eliminated, DSSMC may be suitable for synthesis of high-performance structural materials and functional materials that relies on mechanical alloying principles. DSSMC may produce lightweight metal matrix composites for transportation systems, nano-engineered (nano-composite, and/or nano-crystalline) bulk materials for electricity infrastructure, and oxide dispersion strengthened (ODS) alloys for nuclear energy systems. It may also be used in the low-cost Ti process, as well as Ti based composite materials such as TiAl intermetallics and/or SiC-reinforced Ti alloys.
DSSMC may be a continuous process that may be much easier to scale-up for high-volume production of bulk nano-engineered materials, in comparison with the powder metallurgic (PM)+hot isostatic pressing (HIP) and other mechanically alloying or nano material synthesis processes.
Consistent with embodiments of the invention, engineering materials strengthened with nano-sized oxides and other ceramic particulate dispersoids may have some unique properties. For the same volume fraction, nano-sized particles may be much more effective than micron-sized particles in strengthening the material due to reduced inter-particle spacing and the Orowan hardening effect. Because the oxides and ceramic particles may be thermally stable and insoluble in the matrix, dispersion strengthened materials may retain their strength up to temperatures near the matrix melting point. Further, dispersion strengthening may not have the same limitation of precipitation strengthening that requires high solubility of solute atoms at high temperatures and specific nano phase forming thermodynamics and kinetics. Therefore, dispersion strengthening may lessen the compositional restrictions in alloy design—an important aspect in metal recycling as it may ease the requirement for metal sorting.
Dispersion strengthened materials may be produced in small quantity through mechanical-alloying power-metallurgy route that may be involved in HIP and multi-step hot rolling and annealing. Examples may include oxide dispersion strengthened (ODS) ferrous and non-ferrous alloys intended for next generation nuclear reactors and ultra high-temperature boiler applications. However, the PM+HIP process may be highly energy intensive and very costly to scale-up. Nano ceramic dispersion particles may be added to cast Al alloys and Mg alloys with considerable improvement in mechanical properties, especially high-temperature creep strength.
Although casting can produce large quantity of bulk materials, achieving uniform dispersion of nano-sized particles in the molten metal and subsequent solidified metal matrix may be difficult. Due to the low density and the van der Waals force effect, the nano-sized oxide particles may tend to agglomerate and float to the surface during metal casting. Attempts to apply external energy field such as ultrasonic energy to breakdown the agglomerates and mix the nano-particles uniformly in the molten metal have been experimented in laboratory with limited success.
DSSMC consistent with embodiments of the invention may provide an approach to produce nano-engineered materials. Uniform dispersion may be provided with much higher volume fraction (up to 20%) of nano-particles in a metal matrix. Friction extrusion shares the same deformation and metallurgical bonding principles with FSP and other widely used friction based solid-state joining processes. They all may rely on frictional heating and extreme thermo-mechanical process deformation to stir, mix, mechanically alloy, and metallurgically consolidate and synthesize the material together. Friction extrusion may offer a practical means to produce bulk materials utilizing the principle of friction stir consolidation.
Embodiments of the invention may provide:
Although DSSMC may recycle and convert a variety of industrial metals, the analysis in this section will be limited to two type of metals: aluminum alloys and steels for which the widespread applications of the transformational DSSMC technology is expected to have highest energy, economic, environmental impacts. DSSMC may be applied to steel products especially on tool materials used for the dies and the plungers.
The analysis on the energy, economic, and environmental impacts from the application of the DSSMC technology may be divided into two parts. The first part describes the procedure, references and assumptions used in the analysis. The second part summarizes the analysis results.
Secondary aluminum production—aluminum produced entirely from recycled aluminum scrap—is an example of as the current baseline technology (e.g. conventional.) Secondary aluminum production may comprise a number of major operations. The scraps are first melted in a furnace, cast into large ingot, billets, T-bar, slab or strip, and finally rolled, extruded or otherwise formed into the components and useful products. The secondary aluminum industry is a large market—currently, over 50% of the domestically produced Al products are made from aluminum scraps.
A mini steel mill may comprise a conventional system for steel production. The mini steel mill may comprise an electric arc furnace, billet continuous caster and rolling mill capable of making long products (bars, rod, sections, etc). The mini steel mill takes 100% scrap charge and makes bar and rod stocks as the final product. Therefore, both the input and output are the same in the direct conversion and the mini-mill steel converting processes.
The DSSMC process consistent with embodiments of the invention may produce near net-shape products from recyclable scraps in a single step, for the products described above by the current baseline technologies.
Energy analysis may comprise two major steps. The first step may comprise determining the unit energy consumption for both the current baseline technology (conventional) and embodiments consistent with the invention. This included determination of the theoretical minimum energy requirements for both current and embodiments consistent with the invention, the actual average energy usage by U.S. industry for the current baseline technology, and the estimated energy usage for embodiments consistent with the invention. To ensure proper energy and environmental calculations, the “process energy”—the energy used at a process facility (the onsite energy)—may be determined. It does not include the energy losses incurred at offsite utilities (such as power generation and transmission loss).
In the second step, appropriate U.S. domestic Al and steel production figures may be obtained from available market survey. The unit energy usage data from the first step, together with the statistic annual production data from the second step, may be used as input to, for example, Energy Savings Calculation Tool (GPRA2004 Excel spreadsheet) from DOE ITP to determine the overall energy, economic and environmental benefits of the new technology.
The energy usage of the current baseline technology can be found from DOE reports. In general, a variety of fuels are used in different stages of Al or steel making. Choate and Green's study provides a detailed account of the energy used in aluminum recycling. According to this study, the energy usage for making final near net-shape product is:
In this equation, it is assumed that percentages of ingots used for rolling and extrusion are proportional to the annual rolling and extrusion production rates: 2.75 million metric tons for hot rolling, 2.75 million metric tons for cold rolling, and 1.72 million metric tons for extrusion. The actual energy consumptions for steel recycling (EAF furnaces in mini steel mills) are estimated in the similar fashion according to the study by Stubbles.
The average actual unit energy consumption figures are presented in Table 1, together with the theoretical minimum energy requirement for both current (conventional) and new technology (embodiments of the invention), and estimated energy usage for embodiments of the present invention. The theoretical minimum energy requirements were obtained from Choate and Green for aluminum, and Fruehan's study for steel.
The unit energy consumption of embodiments of the invention, for example, is estimated below. In DSSMC process, friction may be used to drive the localized deformation and heating. Both the frictional heating and high-strain rate plastic deformation result in an increase in temperature of the processed region. Therefore, the energy input can be estimated from the temperature increase in the processing region. The minimum theoretical energy may be determined from adiabatic heating by plastic work:
where Cp is the specific heat capacity of the material processed, and T2 is the processing temperature. The processing temperature is assumed to be 450° C. for aluminum alloys and 1300° C. for steels, based on the typical hot forging temperatures of the materials. The average specific heat is 0.9 and 0.45 respectively for Al and Fe.
The energy efficiency of the new technology is assumed to be 50%. This figure is based on the fact that the new technology is primarily a mechanical deformation process. According to Choate and Green, the efficiency of electrical/hydraulic system for rolling and extrusion is 75%. A lower efficiency may be assumed to account for other uncounted energy loses of the new technology.
As shown in
While certain embodiments of the invention have been described, other embodiments may exist. Further, the disclosed methods' stages may be modified in any manner, including by reordering stages and/or inserting or deleting stages, without departing from the invention. While the specification includes examples, the invention's scope is indicated by the following claims. Furthermore, while the specification has been described in language specific to structural features and/or methodological acts, the claims are not limited to the features or acts described above. Rather, the specific features and acts described above are disclosed as example for embodiments of the invention.
The present application claims priority to U.S. Provisional Application No. 61/362,726 filed on Jul. 9, 2010, which is hereby incorporated by reference in its entirety.
Number | Date | Country | |
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61362726 | Jul 2010 | US |