The present invention relates to a pump having an elasticity at least in a part of an operation chamber wall.
A tube pump configured such that a flexible tube is disposed in a ring-shape along a cylindrical inner wall surface formed on a housing and fluid in the tube is transported by rotating a roller along the inner wall surface while letting the roller press the tube between the roller and the inner wall surface of the housing is known (see Japanese Patent Provisional Publication No. 2011-102574A (hereafter, referred to as patent document 1)).
Since, in the tube pump of this type, a particular portion of the tube is bent by 180 degrees repeatedly, a large degree of deformation is caused locally at the particular portion of the tube, and thereby fatigue rapidly progresses. Therefore, life of the tube is relatively short in comparison with other components, such as a pump, and the tube needs to be replaced periodically as a consumable article.
Furthermore, in the tube pump, a sucking process (i.e., a process transferring from a state where a hollow part of the tube serving as an operation chamber is pressed and an cross sectional area of the hollow part becomes the minimum to a natural state where the cross sectional area of the hollow part of the tube becomes the maximum) is performed by an elastic restoring force of the tube itself. Therefore, the speed of the sucking process is low, which causes limiting the rotational speed of the pump.
U.S. Patent Application Publication No. 2012/0020822 A1 (hereafter, referred to as patent document 2) describes a pump including: a cylindrical inner wall, a cylindrical diaphragm forming a ring-shaped operation chamber between the diaphragm and the inner wall surface, a presser roller deposed to rotate along the inner wall surface while pressing the operation chamber, a ring-shaped actuator disposed between the diaphragm and the presser roller, and a support member restricting the distance between the actuator and the inner wall surface within a predetermined value.
Since, in the pump described in the patent document 2, an elastic member (diaphragm) is not pressed in a state where the elastic member is bend by 180 degrees as in the case of the above described tube pump, the local deterioration of the elastic member is suppressed. Furthermore, in the pump described in the patent document 2, the actuator which is thicker than the diaphragm is disposed between the diaphragm and the presser roller, deterioration of the diaphragm is suppressed.
However, since, in the pump described in the patent document 2, a thin diaphragm having a low mechanical strength is used as an elastic member, a large degree of enhancement of life of the elastic member cannot be expected.
The present invention is made in view of the above described circumstances. That is, the object of the present invention is to provide a pump whose elastic member has long life.
According an embodiment of the invention, there is provided a pump, comprising: an inner wall surface having a cylindrical shape; an elastic ring disposed along the inner wall surface and forming an operation chamber extending in a circumferential direction of the elastic ring with respect to the inner wall surface; and a plurality of pressing members pressing a part of the elastic ring in the circumferential direction against the inner wall surface and thereby forming a blocking part in the operation chamber, the plurality of pressing members causing fluid in the operation chamber to move by rotating along the inner wall surface and thereby moving the blocking part. The elastic ring is disposed to maintain a circumference in a natural state of the elastic ring.
In the above described pump, a diameter of the inner wall surface may be slightly larger than an outer diameter of the elastic ring in the natural state. A difference between the diameter of the inner wall surface and the outer diameter of the elastic ring in the natural state may be defined to achieve a relationship that, when the elastic ring deforms due to a pumping motion, the elastic ring contacts the inner wall surface while causing almost no change with respect to the circumference of the elastic ring.
In the above described pump, an inner diameter of the elastic ring in the natural state may be smaller than a diameter of a circumscribed circle of the plurality of pressing members. The elastic ring may be configured not to expand the circumference of the elastic ring by deforming, at a part of the elastic ring not contacting the plurality of pressing members, such that curvature in the circumferential direction becomes smaller than curvature in the natural state.
In the above described pump, the inner wall surface may be formed with a sucking port through which the fluid to be transported is sucked from an outside into the operation chamber, and may be formed with a discharging port through which the fluid is discharged from an inside of the operation chamber to the outside. The elastic ring may include a division wall partitioning the operation chamber between the sucking port and the discharging port. The division wall may be an elastic plate-like member projecting from an outer circumferential surface of the elastic ring.
In the above described pump, a barycenter of the plurality of pressing members may lie on a center axis of rotation of the plurality of pressing members.
In the above described pump, the plurality of pressing members may be disposed around a center axis of the inner wall surface at constant intervals.
The pump may further comprise a rotor rotating the plurality of pressing members along an inner circumferential surface of the elastic ring while holding the plurality of pressing members to maintain a predetermined positional relationship of the plurality of pressing members.
In the pump may further comprise a sun roller disposed coaxially with a center axis of rotation of the plurality of pressing members. Each of the plurality of pressing members may be a pressing roller rotatably supported by the rotor. When the sun roller rotates, the plurality of pressing members being sandwiched between the sun roller and the inner circumferential surface of the elastic ring may rotate in the circumferential direction along an outer circumferential surface of the sun roller and the inner circumferential surface of the elastic ring. The elastic ring may be configured such that the plurality of pressing members and the sun roller can be inserted into a hollow part of the elastic ring from one side in an axis direction of the hollow part for assembling. The inner wall surface may be formed in one of a barrel shape and a conical shape in which a diameter of the inner wall surface expands toward the one side. The sun roller may have an outer circumferential surface formed in one of a barrel shape and a conical shape to be parallel with the inner wall surface.
In the above described pump, pressing forces applied from the plurality of pressing members to the sun roller may be cancelled out.
According to the embodiment of the invention, since the circumference (the length in the circumferential direction) of the elastic member is kept substantially at the natural length, it becomes possible to provide a pump whose elastic member has long life.
In the following, an embodiment according to the invention is described with reference to the accompanying drawings.
A pump device 1 according to the embodiment of the invention described below is a pump suitable for transporting, by a constant amount, organic solvent or liquid containing a substance having a high degree of chemical activity (hereafter, referred to as “active liquid”) (e.g., supplying liquid resin material for laminate shaping to a 3D printer). Needless to say, the pump device 1 is also suitable for transporting water or liquid having a low degree of chemical activity.
A conventional pump (e.g., a tube pump) used for a constant amount transporting of liquid is configured such that at least a part of an operation chamber containing liquid to be transported is formed of elastic material, such as synthetic rubber. Furthermore, when active liquid is transported, it becomes necessary to form components constituting the operation chamber with material having solvent resistance or chemical resistance. However, in general, elastic material having solvent resistance or chemical resistance has a low degree of durability (fatigue strength). In particular, regarding the configuration of the tube pump where a large degree of stress is intensively and repeatedly applied to the elastic member (the tube) during operation, it was difficult to achieve both of practical durability and solvent resistance or chemical resistance.
Furthermore, even in the case of a tube pump in which a tube formed of a general elastic member not having a high degree of solvent resistance (e.g., silicone rubber), life of the tube is relatively short in comparison with other components. For this reason, it was the object for the conventional tube pump to reduce frequency of maintenance while enhancing life of the tube.
The pump device 1 according to the embodiment provided advantageous effects in that life of an elastic member can be enhanced.
The pump device 1 includes a pump unit 3, a drive unit 2 which drives the pump unit 3, and a casing (not shown) which accommodates and holes the pump unit 3 in an assembled state. The drive unit 2 includes a motor (not shown), a control circuit (not shown) which drives and controls the drive unit 2, and a power supply (not shown) which supplies electric power to the motor and the control circuit. As described later, in this embodiment, the drive unit 2 is not provided with a reduction gear because the pump unit 3 has the function of reducing the rotational output of the drive unit 2 and amplifying torque. The torque required for driving the pump unit 3 varies depending on design (size, material, viscosity of liquid to be transported, etc.) of the pump unit 3. Therefore, when a large degree of torque is required, the drive unit 2 may be provided with a reduction gear. Furthermore, a housing of the drive unit 2 is attached to a rear surface of the pump unit 3, and a drive shaft 2a of the drive unit 2 is inserted into and connected to the inside of the pump unit 3.
The drive unit 2 includes an input terminal (not shown) which receives an external control signal, and an operation switch (not shown) which receives a user operation. The drive unit 2 controls driving of the built-in motor based on the control signal inputted to an input port or a user operation to the operation switch, and outputs a rotational driving force via the drive shaft 2a. The driving may be controlled by ON/OFF of an external power source (e.g., power supplied from a 3D printer) inputted to the power supply.
The pump unit 3 includes a rigid ring 20, an elastic ring 30, the sun roller 40, the pair of planetary roller 50 and a rotor 60. The rotor 60 is illustrated only in
As shown
As shown in
As shown in
As shown in
As shown
The both surfaces of the cylindrical part 31 of the elastic ring 30 are also formed to be inclined with respect to the center axis AX by the same angle as that of the inner wall surface 21a of the rigid ring 20. The cylindrical part 31 has a uniform thickness so that the pressure applied to the cylindrical apart 31 by the planetary roller 50 becomes uniform.
In the hollow part 31h of the elastic ring 30, the rotor 60, and the sun roller 40 and the pair of planetary rollers 50 held by the rotor 60 are accommodated.
As shown in
As shown in
Further, the rotor 60 is held to be freely rotatable about the center axis AX with respect to the rigid ring 20 and the elastic ring 30. Further, in the rear rotor member 64, a through hole is formed on the center axis AX to allow the drive shaft 2a to penetrate therethrough.
An axis hole is formed in the rear part of the sun roller 40 to extend on the center axis AX, and the drive shaft 2a of the drive unit 2 is fitted into the axis hole. Therefore, the sun roller 40 is driven and rotated directly by the drive unit 2.
The pair of planetary rollers 50 rolls on the outer circumferential surface of the sun roller 40 (and on the inner circumferential surface 31b of the elastic ring 30) in a state where the planetary rollers 50 are sandwiched between the sun roller 40 and the elastic ring 30. At this time, a relative positional relationship between the sun roller 40 and the pair of planetary rollers 50 is kept constant by the rotor 60.
Hereafter, behavior of the elastic ring 30 during operation of the pump device 1 is explained.
In a natural state, the inner diameter of the cylindrical par 31 is narrower than the outer width W (the diameter of a circle circumscribing the pair of planetary rollers 50). Therefore, as shown by arrows E, positions at which the cylindrical part 31 contacts the planetary rollers 50 are pressed and expanded outward in the radial direction. That is, the diameter of the cylindrical part 31 is expanded in the Y-axis direction along which the pair of planetary rollers 50 are arranged. On the other hand, in the X-axis direction perpendicularly intersecting with the arranging direction of the planetary rollers 50, the diameter of the cylindrical par 31 contracts as shown by arrows S. Since the pair of planetary roller 50 rotate at a constant speed around the center axis AX, every part of the cylindrical part 31 periodically repeats diameter-expanding and diameter-contracting. Since in a natural state the diameter of the outer circumferential surface 31a of the cylindrical part 31 is smaller than the diameter of the inner wall surface 21a of the rigid ring 20, a ring-shaped space (the operation chamber C) is formed between the inner wall surface 21a and the outer circumferential surface 31a before the components, such as the planetary rollers 50, are accommodated in the hollow part 31h of the elastic ring 30. When the pair of planetary rollers 50 are accommodated in the hollow part 31h and the cylindrical part 31 is pressed from the inner side by the pair of planetary rollers 50, the cylindrical part 31 deforms in an elliptical shape as shown by the solid line and concurrently is pressed against the inner wall surface 21a. As a result, at the portions pressed by the pair of planetary rollers 50, the elastic ring 30 contacts locally and closely a part of the inner wall surface 21a of the rigid ring 20 in the circumferential direction, and forms a blocking part in the operation chamber C extending in the circumferential direction, so that the operation chamber is divided in the circumferential direction.
In this embodiment, the length (the circumference) of the elastic ring 30 in the circumferential direction is set to be a predetermined length. Specifically, the circumference of the elastic ring 30 is set such that, when the elastic ring 30 is pressed from the inner side by the pair of planetary roller 50 in the radial direction and is deformed in an elliptical shape, the elastic ring 30 forms the blocking part in the operation chamber C while closely contacting the inner wall surface 21a of the rigid ring 20 in a state where the circumference of the elastic ring 30 does not substantially change, and divides the operation chamber C in an airtight manner. That is, when the sun roller 40 and the pair of planetary rollers 50 are inserted into the hollow part 31h of the elastic ring 30, the elastic ring 30 is expanded from the inner side by the pair of planetary rollers 50 and deforms in an elliptical shape. Then, the outer circumferential surface 31a of the elastic ring 30 closely contacts the inner wall surface 21a of the rigid ring 20 at the both ends in the major axis direction, and forms the two blocking parts in the operation chamber C, so that the operation chamber C is divided into two portions. At this time, the diameter of the elastic ring 30 in the minor axis direction becomes shorter than that in a natural state, and thereby increase of the circumference caused by expansion of the diameter of the elastic ring 30 in the major axis direction is absorbed, and as a result change of the total length of the circumference of the elastic ring 30 is adequately suppressed. Specifically, the elastic ring 30 deforms (i.e., the bending shape is stretched) such that, at the portion (the portion extending between the planetary rollers 50) not contacting the plurality of planetary rollers 50, the curvature in the circumferential direction becomes smaller than a natural state by the tension applied to the elastic ring 30, so that the circumference does not increase. The thickness of the cylindrical part 31 of the elastic ring 30 is set to the extent that the thickness of the cylindrical part 30 is not substantially changed by the tension in the circumferential direction applied to the cylindrical part 31. The term circumference of the elastic ring 30 means the circumference at the central position in the thickness direction of the elastic ring 30. When the elastic ring 30 is elastically deformed in an elliptical shape and the curvature of the elastic ring 30 in the circumferential direction is changed, the inner circumferential surface 31b and the outer circumferential surface 31a elastically deform and the circumferences of the inner circumferential surface 31b and the outer circumferential surface 31a slightly change, but the circumference at the central position in the thickness direction hardly expands and contracts because the change of the circumference is absorbed by deformation at the inner and outer circumferential surfaces. As a result, it becomes possible to reduce aging variation such as fatigue by expansion and contraction of the cylindrical part 31 and thereby it becomes possible to enhance durability.
As described above, the length of the circumference of the elastic ring 30 is defined such that the circumference of the elastic ring 30 does not substantially expand and contract at least in the circumferential direction during the pumping operation. In other words, the elastic ring 30 elastically deforms in an elliptical shape when the elastic ring 30 is pressed from the inner side by the planetary rollers 50; however, by setting the circumference of the elastic ring 30 to be the predetermined length, even when the elastic ring 30 deforms in this way, the outer circumferential surface 31a of the cylindrical part 31 and the inner circumferential surface 21a of the rigid ring 20 closely contact with each other and thereby form the blocking part in the state where the length of the elastic ring 30 in the circumferential direction hardly changes, and the operation chamber C is divided in an airtight manner. The fact that the length of the elastic ring 30 does not substantially expand and contract means that the elastic ring 30 hardly expands and contracts in the circumferential direction by the pressure from the planetary rollers 50 and the inner pressure applied to the operation chamber C. By thus configuring the elastic ring 30 so that the circumference of the elastic ring 30 does not substantially expand and contract, it becomes possible to reduce the aging variation such as fatigue by expansion and contraction of the elastic ring 30 and to enhance the durability. Since the elastic ring 30 has an adequate thickness, the elastic ring 30 has reasonable rigidity. As a result, it becomes possible to adequately decrease change of volume by the inner pressure of the operation chamber C. The fact that the change of volume is adequately decreased means, for example, that the change of volume of the operation chamber C defined when the maximum discharging pressure is applied to the operation chamber C is smaller than or equal to 10% (preferably smaller than or equal to 5%, and more preferably smaller than or equal to 1%). Since the circumference of the elastic ring 30 is defined such that the elastic ring 30 does not substantially expand and contract in the circumferential direction during operation, it becomes possible to reduce fatigue by expansion and contraction and to enhance durability. Furthermore, even when the inner pressure of the operation chamber C increases, it is possible to avoid occurrence of a situation where the elastic ring 30 expands and the volume of the operation chamber C expands and as a result efficiency for transporting fluid is decreased. Furthermore, with this configuration, it becomes possible to achieve an extremely high degree of durability or discharging pressure and sacking pressure in comparison with the case where a diaphragm which expands and contracts during the pumping operation is used.
The periodic deformation (the diameter-expanding and the diameter-contracting) of the cylindrical part 31 is not caused by a relatively weak elastic restoring force, but is forcibly caused by a strong external force applied by the pair of planetary rollers 50. Therefore, required time for the periodic deformation is short. Accordingly, even when the planetary roller 50 is rotated at a high speed, deformation of the cylindrical part 31 is able to follow motion of the planetary roller 50.
In the meantime, in a tube pump, a discharging process is performed by forcibly pressing a tube by a roller, while a sucking process is performed by a relatively weak elastic restoring force of an elastic tube (a self-restoration force). Therefore, time required for the discharging process is short, but time required for the sucking process is long. For this reason, there was a case where, when the tube pump is driven at a high speed (a roller is rotated at a high speed), restoration of the elastic tube cannot follow the cycle of rotation of the roller and thereby the transporting efficiency of liquid decreases because a next discharging process starts before the current sucking process is finished. According to the configuration of the pump unit 3 of the embodiment, higher motion than that of the tube pump can be achieved.
In
In the diameter-contracted state (a diameter-contracted direction) in
In the diameter-expanded state (a diameter-expanded direction) in
Furthermore, as shown in
Furthermore, as described above, the cylindrical part 31 of the elastic ring 30 has the uniform thickness, and, as shown in
In the expanded state, the operation chamber C is pressed by the planetary rollers 50, and is divided into two parts. When each planetary roller 50 rotates around the sun roller 40, the blocking part of the operation chamber C also moves in the circumferential direction along the inner wall surface 21a of the rigid ring 20 together with the planetary roller 50, and thus the liquid stored in the operation chamber C is transported.
As described above, in the pump unit 3 according to the embodiment, the rotation motion of the sun roller 40 is converted to the rotating motion (orbital revolution) of the planetary roller 50 along the inner wall surface 21a of the rigid ring 20, and the liquid in the operation chamber C is moved along the inner wall surface 21a of the rigid ring 20 by rotation of the planetary rollers 50. Since the inner circumferential length of the elastic ring 30 is longer than the outer circumferential length of the sun roller 40, the speed of the rotation motion of the sun roller 40 is reduced, and thereby the planetary roller 50 rotates at a speed slower than that of the sun roller 40. That is, a rotational driving force transmitting mechanism constituted by the sun roller 40, the planetary rollers 50 and the elastic ring 30 provided in the pump unit 3 has the speed reduction function like a planetary gear mechanism. Therefore, it is not necessary to provide a speed reduction device in the drive unit 2 side, and, as a result, a simple and compact configuration is achieved.
Furthermore, the pump unit 3 according to the embodiment is provided with the two planetary rollers 50. Therefore, each time the rotor 60 makes one revolution, every part on the circumference of the elastic ring 30 alternately repeats, two times, the diameter-expanded state of being pressed by the planetary roller 50 and closely contacting the rigid ring 20 and the diameter-contracted state of being separated from the rigid ring 20 and forming the operation chamber C. That is, each time the rotor makes one revolution, sucking and discharging are performed by two cycles. Therefore, since the number of cycles per one revolution of the rotor is larger in comparison with the pump formed to use a single planetary roller or an eccentric rotor as described in the patent document 2 (U.S. Patent Application Publication No. 2012/0020822), pulsation motion is smoothed and thereby smooth pumping can be achieved. Furthermore, the transporting amount of liquid per one revolution of the rotor is increased, and thereby the transporting efficiency can be enhanced.
Hereafter, operation of the pump device 1 is explained. For example, when a control signal for instructing activation of the pump device 1 is externally inputted, the drive unit 2 drives and rotates the drive shaft 2a based on the control signal. Since, as described above, the sun roller 40 (a body part) is coaxially fixed to the tip part of the drive shaft 2a, the sun roller 40 is rotated together with the drive shaft 2a.
When the sun roller 40 is rotated in a direction of an arrow A1 as shown in
Around the grove 22a, the operation chamber C is divided into operation chambers C1 and C2 by the division wall 22a. The operation chamber C1 communicates with the sucking port 23, and the operation chamber C2 communicates with the discharging port 24. When the operation chamber C communicates with the groove 22a, the operation chamber C1 gradually expands (concurrently the operation chamber C2 gradually contracts) as the operation chamber C moves in the clockwise direction in
In the pump unit 3 according to the embodiment, the width of the groove 22a of the rigid ring 20 is sufficiently small relative to (e.g., smaller than or equal to ⅓ of) the diameter of the planetary roller 50, and the elastic ring 30 has the thickness substantially equal to the width of the groove 22a. Therefore, when the planetary roller 50 passes through the groove 22a of the rigid ring 20, a force which the planetary roller 50 receives from the rigid ring 20 does not change largely. Therefore, since the sun roller 40 constantly receives balanced forces from the pair of planetary rollers 50, the sun roller 40 does not vibrate largely in the radial direction. As a result, the sun roller 40 does not produce a large degree of noise, and life of the sun roller 40 is also enhanced.
Since, in the pump unit 3 according to the embodiment, the sun roller 40, the pair of planetary rollers 50 and the rotor 60 rotate about the barycenter (a point on the center axis AX), vibration and noise are not caused by fluctuation of the barycenter during operation of the pump unit 3. Furthermore, since the sucking and discharging are performed at constant time intervals (pulsation motion is produced at a constant cycle), fluctuation of the discharging amount of the liquid can be reduced.
In this embodiment, the configuration where the pair of planetary rollers 50 are disposed to sandwich the center axis AX and to have the same distances with respect to the center axis AX is used. Specifically, the pair of planetary rollers 50 are disposed, for example, in a rotationally-symmetrical manner with respect to the center axis AX or in a plane symmetrical manner with respect to a plane including the center axis AX. As a result, pressing forces applied from the planetary rollers 50 to the sun roller 40 are cancelled out, and balance during rotation of the sun roller 40 is enhanced and the noise and vibration can be reduced.
It is not necessarily required to have a pair of (two) planetary rollers 50, but three or more planetary rollers 50 may be used. In such a case, a plurality of planetary rollers 50 may be symmetrically disposed with respect to the center axis AX and/or may be disposed around the center axis AX at constant intervals along the circumferential direction around the center axis AX. With this configuration, it becomes possible to prevent the barycenter position of the entire of the plurality of planetary rollers 50 and the elastic ring 30 from moving, and thereby it becomes possible to reduce the vibration and noise during operation. Furthermore, fluctuation of the discharging amount of liquid can be reduced.
The above described embodiment is configured such that the barycenter of the cylindrical part 31 of the elastic ring 30 does not move or the cylindrical part 31 of the elastic ring 30 deforms (expands and contracts) in a symmetrical manner with respect to the barycenter. Therefore, the cylindrical part 31 of the elastic ring 30 does not move, at the diameter-expanded part thereof (at positions indicated by reference symbols S in
The rotational driving force transmitting mechanism including the sun roller 40, the planetary rollers 50 and the elastic ring 30 according to the embodiment may be used for another type of rotational pump, such as, a tube pump in which an elastic tube is used as an operation chamber.
The forgoing is the explanation about the embodiment of the invention; however, the invention is not limited to the above described configuration according to the embodiment but may be varied in various ways within the scope of the invention.
The above described embodiment is an example in which the elastic ring 30 is formed of a single material; however, the elastic ring 30 may be formed of a combination of material having elasticity and material not having a large degree of elasticity (expansion/contraction suppressing material). For example, as shown
In the above described embodiment, the sun roller 40 having a conical outer circumferential surface inclined with respect to the center axis by the same angle as that of the inner wall surface 21a of the rigid ring 20 is used, and the center axis of the planetary roller (presser roller) 50 is inclined with respect to the center axis of the rigid ring 20 by the same angle as that of the inner wall surface 21a. However, the present invention is not limited to such a configuration. For example, the outer circumferential surface of the sun roller 40 may not be formed as the taper surface, but the planetary roller 50 having a conical outer circumferential surface inclined with respect to the center axis by the same angle as that of the inner wall surface 21a of the rigid ring 20 may be used.
In the above described embodiment, a planetary roller mechanism in which the sun roller 40 and the planetary rollers 50 are used and the driving force is transmitted by the frictional force between the rollers is used. However, the present invention is not limited to such a configuration. For example, a sun gear and a planetary gear (a planetary gear mechanism) may be used in place of the sun roller 40 and the planetary rollers 50. In such a case, an inner gear may be provided on the inner circumferential surface of the elastic ring 30 to engage with the planetary roller 50. Furthermore, the planetary gear mechanism may not be provided, but the rotor 60 may be directly driven by the drive unit 2. In such a case, it becomes necessary to provide a reduction gear for amplifying torque in the drive unit 2.
When liquid having a low degree of light resistance property is transported, the casing 5 and/or the elastic ring 30 may be formed of material having a light shielding property (or an ultraviolet shielding property).
The above described embodiment is an example in which the present invention is applied to a liquid transporting pump which transports liquid; however, the present invention may be applied to an air transporting pump which transports air. Further, the present invention can be used in a wide range of technical fields, such as, medical care, water treatment, water supply, agriculture, shipping and construction, as well as a whole industrial field including the food industry and the chemical industry.
This is a Continuation-in-Part of International Application No. PCT/JP2013/077472 filed Oct. 9, 2013. The entire disclosure of the prior application is hereby incorporated by reference herein its entirety.
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Number | Date | Country | |
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20160215768 A1 | Jul 2016 | US |
Number | Date | Country | |
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Parent | PCT/JP2013/077472 | Oct 2013 | US |
Child | 15092872 | US |