Claims
- 1. A colored or colorless nail varnish comprising, in a nail varnish solvent consisting of a mixture of organic solvents:
- (a) 5 to 20% by weight of a film-forming substance;
- (b) 0.5 to 15% by weight of a resin;
- (c) 2 to 10% by weight of a plasticizer; and
- (d) a mixture of:
- (i) 0.05 to 5% by weight of an aminofunctional silicone having an amine index of between 0.05 and 2.3 or 0.05 to 5% by weight of a thiofunctional silicone having an amount of thiol groups between 0.1 to 15% by weight, said aminofunctional silicone and thiofunctional silicone having a molecular weight between 500 and 100,000; and
- (ii) 0.05% to 5% by weight of an organofluorinated hydrocarbon compound having a fluorine substitution rate of between 0.5 and 95% and a boiling point greater than 30.degree. C.;
- wherein the total weight of (i) and (ii) is less than or equal to 5% by weight based on the total weight of the varnish.
- 2. A method of applying a nail varnish to nails comprising:
- applying to said nails a composition comprising, in a nail varnish solvent consisting of a mixture of organic solvents:
- (a) 5 to 20% by weight of a film-forming substance;
- (b) 0.5 to 15% by weight of a resin;
- (c) 2 to 10% by weight of a plasticizer; and
- (d) a mixture of:
- (i) 0.05 to 5% by weight of an aminofunctional silicone having an amine index of between 0.05 and 2.3 or 0.05 to 5% by weight of a thiofunctional silicone having an amount of thiol groups between 0.1 to 15% by weight, said aminofunctional silicone and thiofunctional silicone having a molecular weight between 500 and 100,000; and
- (ii) 0.05% to 5% by weight of an organofluorinated hydrocarbon compound having a fluorine substitution rate of between 0.5 and 95% and a boiling point greater than 30.degree. C.;
- wherein the total weight of (i) and (ii) is less than or equal to 5% by weight based on the total weight of the varnish.
- 3. The nail varnish according to claim 1, wherein the organofluorinated hydrocarbon compound has a fluorine substitution rate greater than 10% and less than 80%.
- 4. The nail varnish according to claim 1, wherein the aminosilicone corresponds to the following general formula: ##STR18## in which: R.sub.1 represents CH.sub.3, OCH.sub.3, OCH.sub.2 CH.sub.3 or --(CH.sub.2).sub.d --NH.sub.2
- R.sub.2 represents CH.sub.3, OCH.sub.3 or OCH.sub.2 CH.sub.3,
- R.sub.3 represents CH.sub.3, OCH.sub.3, OCH.sub.2 CH.sub.3 or OSi(CH.sub.3).sub.3,
- R.sub.4 represents CH.sub.3 or ##STR19## R.sub.5 represents CH.sub.3, OCH.sub.3, OCH.sub.2 CH.sub.3 or ##STR20## a is 0 to 6 b is 0 to 2
- c is 0 or 1
- d is 1 to 6
- with the proviso that:
- (i) when R.sub.1 represents the --(CH.sub.2).sub.d --NH.sub.2 radical, R.sub.4 represents CH.sub.3 and R.sub.5 represents CH.sub.3, OCH.sub.3 or OCH.sub.2 CH.sub.3,
- (ii) when R.sub.4 represents CH.sub.3, R.sub.5 represents: ##STR21## and (iii) when R.sub.4 represents ##STR22## R.sub.5 represents CH.sub.3, OCH.sub.3 or OCH.sub.2 CH.sub.3, m is 1 to 1,000
- n is 0 to 50 and
- p is 0 to 50
- n and p being not simultaneously 0,
- the molecular weight of the said aminosilicone being between 500 and 100,000.
- 5. The nail varnish according to claim 1, wherein the thiosilicone is a polydiorganosiloxane containing, in the molecule, at least one unit of formula: ##STR23## in which: R denotes a divalent aliphatic radical having from 2 to 26 carbon atoms which is optionally interrupted by an ester functional group and which can carry ethylene oxide or propylene oxide units or their mixture,
- R' denotes a monovalent hydrocarbon radical having 1 to 6 carbon atoms, an alkoxy radical having 1 to 4 carbon atoms or a trimethylsilyloxy radical,
- a denotes an integer equal to 0, 1 or 2, the remaining units having the formula:
- 1) ##STR24## in which: R" represents a C.sub.1 -C.sub.18 alkyl, phenyl(C.sub.1 -C.sub.6)alkyl or phenyl group,
- b is an integer denoting 1, 2 or 3,
- at least 50% of the R' and R" groups representing a methyl group, and
- 2) optionally units of formula: ##STR25## in which R" is as defined above and n is an integer from 1 to 18.
- 6. The nail varnish according to claim 5, wherein in the unit of formula (II), the R radical represents --(CH.sub.2).sub.n --, where n is between 3 and 8, or a group of formula:
- --C.sub.n H.sub.2n O(C.sub.x H.sub.2x O).sub.p --COC.sub.m H.sub.2m --
- in which:
- n represents an integer between 1 and 18, m represents an integer between 1 and 8, x=2 or 3 and when x=3, the C.sub.3 H.sub.6 radical is branched and p is 0 to 40, and
- R' represents a C.sub.1 -C.sub.6 alkyl radical.
- 7. The nail varnish according to claim 1, wherein the organofluorinated hydrocarbon compound corresponds to the following general formula:
- R.sub.1 --(CH.sub.2).sub.n --X--�C.sub.3 H.sub.5 (OH)!--(Y).sub.x --(CH.sub.2).sub.m --R.sub.2 (VI)
- in which:
- the divalent radical C.sub.3 H.sub.5 (OH) represents at least one of the following divalent radicals: ##STR26## R.sub.1 represents a linear or branched C.sub.4 -C.sub.20 perfluoroalkyl radical or a mixture of such linear or branched C.sub.4 -C.sub.20 perfluoroalkyl radicals,
- R.sub.2 represents R.sub.1 or a linear or branched C.sub.1 -C.sub.22 alkyl radical or a mixture of such linear or branched C.sub.1 -C.sub.22 alkyl radicals or a C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.15 aralkyl radical, with the proviso that:
- (i) when R.sub.2 is different from R.sub.1,
- X and Y represent --O--, ##STR27## or --S--, X and Y being not simultaneously ##STR28## and
- (ii) when R.sub.2 represents R.sub.1, X and Y are identical to one another and represent --O-- or --S-- m and n, identical or different, are between 0 and 4 and
- x represents 0 or 1.
- 8. The nail varnish according to claim 1, wherein the organofluorinated compound is selected from the group consisting of:
- 1-(2'-(F-hexyl)ethylthio)-3-(2"-ethylhexyloxy)-2-propanol,
- 1-(2'-(F-octyl)ethylthio)-3-(2"-ethylhexyloxy)-2-propanol,
- 1-(2'-(F-octyl)ethylthio)-3-butyloxy-2-propanol,
- 1-(2'-(F-octyl)ethylthio)-3-phenoxy-2-propanol,
- 1-(2'-(F-hexyl)ethylthio)-3-dodecyloxy-2-propanol,
- 1-(2'-(F-hexyl)ethylthio)-2-decanol,
- 1-(2'-(F-hexyl)ethylthio)-2-hexanol,
- 1-(2'-(F-octyl)ethylthio)-2-hexanol,
- 1-(2'-(F-hexyl)ethyloxy)-3-(2"-ethylhexyloxy)-2-propanol,
- 1-(2'-(F-hexyl)ethylthio)-3-octylthio-2-propanol,
- 1-(2'-(F-octyl)ethylthio)-3-octadecylthio-2-propanol,
- 1,3-bis(2'-(F-hexyl)ethylthio)-2-propanol, and
- 1,3-bis(2'-(F-octyl)ethylthio)-2-propanol.
- 9. The nail varnish according to claim 1, wherein the organofluorinated compound corresponds to the following general formula: ##STR29## in which: R.sub.1 represents a linear or branched C.sub.4 -C.sub.20 perfluoroalkyl radical or a mixture of such linear or branched C.sub.4 -C.sub.20 perfluoroalkyl radicals,
- Y represents OH or --CH.sub.2 OH
- when Y is OH, Z represents --CH.sub.3, --CH.sub.2 OH, --CH.sub.2 OCOCH.sub.3 or --C.sub.6 H.sub.5,
- and when Y is --CH.sub.2 OH Z represents --OCOCH.sub.3, and
- X represents --O--, --S--, ##STR30##
- 10. The nail varnish according to claim 9, wherein the organofluorinated compound is selected from the group consisting of:
- 2-(2'-(F-hexyl)ethylthio)-1-phenylethanol, and
- 2-(2'-(F-hexyl)ethylsulphonyl)-1-phenylethanol.
- 11. The nail varnish according to claim 1, wherein the organofluorinated compound corresponds to the following general formula:
- R.sub.1 --CH.dbd.CH--CH.sub.2 --O--�C.sub.3 H.sub.5 (OH)!--W(XI)
- in which:
- the divalent radical C.sub.3 H.sub.5 (OH) represents at least one of the following divalent radicals: ##STR31## R.sub.1 represents a linear or branched C.sub.4 -C.sub.20 perfluoroalkyl radical or a mixture of such linear or branched C.sub.4 -C.sub.20 perfluoroalkyl radicals,
- W represents --OR, --SR, --COOR, --O--C.sub.6 H.sub.5, ortho- or para-O--C.sub.6 H.sub.4 (CH.sub.3) or ortho- or para-O--C.sub.6 H.sub.4 (OH), R representing a linear or branched C.sub.1 -C.sub.18 alkyl radical.
- 12. The nail varnish according to claim 11, wherein the organofluorinated compound is selected from the group consisting of:
- 1-(3'-(F-hexyl)-2'-propenoxy)-3-octylthio-2-propanol,
- 1-(3'-(F-hexyl)-2'-propenoxy)-3-butyloxy-2-propanol, and
- 1-(3'-(F-octyl)-2'-propenoxy)-3-octadecylthio-2-propanol.
- 13. Nail varnish according to claim 1, characterized in that the organofluorinated hydrocarbon compound corresponds to the following formula: ##STR32## in which: n is an integer equal to 6 or 8 and p is 1 or 2.
- 14. The nail varnish according to claim 1, said varnish comprises an organic or inorganic pigment.
- 15. Nail varnish according to claim 1, wherein the pigment is present at a concentration of between 0.01 and 2% with respect to the total weight of the varnish.
Priority Claims (1)
Number |
Date |
Country |
Kind |
93 00692 |
Jan 1993 |
FRX |
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Parent Case Info
This is a Continuation of application Ser. No. 08/302,877 filed Oct. 28, 1994, now abandoned.
US Referenced Citations (13)
Foreign Referenced Citations (25)
Number |
Date |
Country |
1166696 |
Jan 1986 |
EPX |
0295780 |
Dec 1988 |
EPX |
0370470 |
May 1990 |
EPX |
0432572 |
Jun 1991 |
EPX |
0558423 |
Sep 1993 |
EPX |
1356552 |
Jun 1964 |
FRX |
1378794 |
Feb 1965 |
FRX |
2379280 |
Sep 1978 |
FRX |
2397186 |
Feb 1979 |
FRX |
2478998 |
Oct 1981 |
FRX |
2499851 |
Aug 1982 |
FRX |
2611730 |
Sep 1988 |
FRX |
2617043 |
Dec 1988 |
FRX |
2679445 |
Jan 1993 |
FRX |
2684668 |
Jun 1993 |
FRX |
2052579 |
Apr 1972 |
DEX |
2702607 |
Jul 1977 |
DEX |
55-138316 |
Oct 1980 |
JPX |
59-199621 |
Nov 1984 |
JPX |
63-2916 |
Jan 1988 |
JPX |
63-183508 |
Jul 1988 |
JPX |
1-193236 |
Aug 1989 |
JPX |
4-275268 |
Sep 1992 |
JPX |
1182939 |
Mar 1970 |
GBX |
1199776 |
Jul 1970 |
GBX |
Continuations (1)
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Number |
Date |
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Parent |
302877 |
Oct 1994 |
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