The present invention relates in general to apparatus for the extrusion formation of polymeric webs and in particular to an external land extrusion die, patterned roller and gimbaled mounting arrangement, that directly forms a patterned web in a manner that eliminates a free surface draw down region.
Literature clearly describes the extrusion of a molten material on to a moving surface. An extrusion die is typically used to create a melt curtain of desired width and thickness, which upon attachment to the roller surface, is drawn from the exit of the extrusion die.
Various means are employed to assure uniform contact of the molten material with the roller surface, such as but not limited to, a nip formed between two rollers, vacuum chambers, air knife jet, and electrostatic attraction with the intention of removing air from the interface and to create sufficient pressure to replicate the roller surface.
A die lip to roller surface gap is a consequence of all these techniques. The fluidic nature, of the molten material entering the free surface region between the die lip and the roller surface, results in a non-uniform redistribution of material. The desired thickness profile and replication of the roller surface is negatively affected by the redistribution of material which can result in thickness non-uniformities and regions of poor surface replication due to such problems as air entrainment and non-uniform contact pressure.
In conventional extrusion die to roller applications, physical constraints prevent eliminating the curtain of molten material between die lip exit and the roller surface. Mechanical requirements for extrusion die and roller construction prevent the placement of the components in a way that could eliminate a melt curtain.
A recent U.S. Patent Application Publication No. 2003/0175430 A1 (Tomaru) for a coating method and apparatus describes a concept in which a solution coating die supplies a coating solution to the interface between the exit of the coating die and the surface of a moving web. The primary intention of application is to create a uniform layer of a solution on a moving web material without intention of creating a melt extruded web with specific surface feature requirements.
An apparatus which eliminates the free surface gap between the exit of the extrusion die and the roller surface would be desirable.
Briefly, according to one aspect of the present invention an apparatus produces a patterned material which comprises an external land die for extruding a material. A patterned roller is in close proximity to the external land die.
This apparatus eliminates the melt curtain neck-in and roller nip interface. Die lip length, converging angle, and gap between the roller surface are variables that can be optimized as a function of extrusion rate, roller surface speed, material properties, and desired final web thickness to develop a uniform pressure of sufficient level to form a continuous web with a smooth external surface on one side and replicated roller surface on the other side. This apparatus has been designed, fabricated, and tested. The die lips have extended surfaces to create a flow chamber between the die lip surface and the roller surface. Polymer is extruded into the chamber to completely fill it with resin. The roller is loaded into the die and supported by the fluid film developed within this chamber. Rotation of the patterned roller develops a shear force induced hydrodynamic pressure of sufficient level to prevent contact between the die lips and roller surface and to create a uniform, high-pressure environment to facilitate flow of the polymer into the pattern features.
The invention and its objects and advantages will become more apparent in the detailed description of the preferred embodiment presented below.
The present invention will be directed in particular to elements forming part of, or in cooperation more directly with the apparatus in accordance with the present invention. It is to be understood that elements not specifically shown or described may take various forms well known to those skilled in the art.
Referring to
A uniform gap is maintained between the rotating patterned roller surface and the edge of the first external land and the second external land. This is accomplished under dynamic conditions through the unique gimbaled mounting of the driven patterned roller 140 to the external land extrusion die 120. Typically, the extrusion die is held rigidly with respect to the roller surface. The geometric tolerances and thermal deformation of components result in a non-uniform gap. This apparatus utilizes a two axis gimbaled mounting arrangement 100, 105, 130 that enables the driven roller to seek a uniform alignment with respect to the fixed extrusion die. The patterned roller is mounted in bearing housings that have features to provide a skewing adjustment of the roller with respect to the gimbaled frame.
The external land die 120 is fixed to the machine frame and the patterned roller 140 is mounted in a gimbaled fixture attached to the die. This arrangement allows the roller surface to align with the die surface based on the pressure developed within the flow chamber. This design compensates for mechanical tolerances to maintain adequate alignment between the roller cylindrical surface and the die lip surfaces. This concept is not limited to cast web formation but could also be applied to extrusion coating of substrates. The apparatus provides a means of extrusion coating polymeric materials that have very low melt strength. Typically low melt strength polymers are prohibited from use in an extrusion process because of melt curtain instabilities. A single stream of molten polymer has been described to this point but co-extruded, (multiple layer), molten polymer flows can be processed with this apparatus.
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The interface region, shown shaded, represents the molten material delivered through the extrusion die into a trapezoidal region created by the first external land die land 220, the second external land die land 230, and the patterned roller surface 140. The patterned roller rotates about its primary axis of symmetry. This motion is with respect to the fixed extrusion die.
Delay in contact results in cooling of the molten material on the patterned roller before sufficient pressure is created to effectively replicate the surface. As the molten material cools the pressure required for efficient replication increases at a very high rate. Conventional approaches are to create a higher nip force to improve replication of the patterned roller surface. Higher nip loading requires a patterned roller design of high structural stiffness and strength to apply the load. The combination of higher nip loads and larger patterned roller diameter further increase the distance from extrusion die lip to the nip point. Therefore, increased neck-in of the molten material occurs along with further cooling which results in a non-uniform layer of molten material at the nip point. Even if the geometry of the nip interface is as desired, the non-uniform distribution of molten material will result in non-uniform contact pressure.
A significant feature of this apparatus is to provide a uniformly distributed molten material that is subject to a rapid pressure rise within a short dwell time to enable the molten material to fully replicate the patterned roller surface before excessive cooling of the molten material occurs thereby completing the replication process at a much lower overall nip load. The high pressure is applied over a small-localized area and at a point in which the temperature of the molten material is ideal for replication of the patterned surface. The mechanical requirements of the components are much less demanding. Therefore, a small roller can be used for an equivalent patterning process. This concept extends the range of width capability because roller deformation is proportional to the third power of roller face width. Typical wide extrusion lines, greater than 1 meter, will require larger diameter rollers. This apparatus allows more flexibility in choice of roller construction, for example roller diameter can be increased to allow increased cooling dwell time but without affecting the extrusion die to roller surface interface. Vacuum and electrostatic methods are limited to the maximum pressure that can be developed at the interface between the molten material and the patterned roller surface.
In one experiment, a polymeric material with a zero shear viscosity of 880 poise at 300° C. has been directly extruded to form a patterned web of approximately 0.150 m width by 2.5×10−4 m thick at a line speed of 0.05 m/s. The patterned surface roughness was approximately 6 micron Ra (6.0×10−6 m Ra). It is estimated that the localized pressure on the molten material was increased by a factor of thirty for a very short time. This resulted in a rapid pressure change on the order of 1.5×107 Pa/s.
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The external land extrusion die 120 features a unique two-piece construction consisting of the rear die body 200 and the lower die body 190. Typically in practice an extrusion die is split on a plane bisecting the die slot and parallel to the width direction. A bolted joint is created along this interface to seal both halves together. This design is subject to leaks at the interface point near the exit extrusion slot which causes poor edge formation on the extruded web. This external land extrusion die 120 is cut with a plane that is parallel to the back surface of the die and which does not cut through the die slot, resulting in a homogeneous lower die body free from potential leakage points near the web formation region.
The invention has been described in detail with particular reference to certain preferred embodiments thereof, but it will be understood that variations and modifications can be effected within the scope of the invention.