This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No. 2017-052296 filed in Japan on Mar. 17, 2017; the entire contents of which are incorporated herein by reference.
Embodiments described herein relate generally to a radiation detection element and a radiation detection apparatus.
In recent years, as a detection apparatus used detect a radioactive ray, an apparatus provided with a semiconductor detection element has been proposed. The semiconductor detection element has a smaller size, a lower driving voltage, and better responsiveness, compared to a Geiger-Muller tube (GM tube) of the prior art. The semiconductor detection element has, for example, a scintillator that converts a radioactive ray into light and a semiconductor layer that generates an electric charge in response to the light from the scintillator.
In this type of the semiconductor detection element, an effective area for detecting radioactive rays increases as its size increases. Therefore, a radioactive ray can be detected across a wide range. However, as the size of the element increases, a signal-to-noise (SN) ratio of the semiconductor detection element is degraded disadvantageously.
A radiation detection element according to an embodiment includes an organic layer that generates an electric charge by receiving an incident radioactive ray, a first electrode layer arranged in one side of the organic layer, and a second electrode layer arranged in the other side of the organic layer to face the first electrode layer, the second electrode layer having a first electrode pattern and a second electrode pattern spaced from the first electrode pattern.
Embodiments of a present disclosure will now be described with reference to the accompanying drawings. In the following description, an XYZ coordinate system consisting of X, Y, and Z axes perpendicular to each other is employed as appropriate. In addition, thicknesses or sizes of substrates or each layer stacked on the substrate illustrated in the reference drawings are illustrated schematically or exaggeratingly, and they may not necessarily match real thicknesses or sizes.
The substrate 20 is a rigid substrate formed of, for example, transparent resin. The electrode layer 22, the organic layer 23, and the electrode layer 24 are stacked on the upper surface of the substrate 20 in this order. The scintillator layer 21 is formed on the lower surface of the substrate 20.
The scintillator layer 21 is a layer that emits light in response to an incident radioactive ray. The organic layer 23 is excited by light from the scintillator layer 21. For this reason, a composition of the scintillator layer 21 is determined on the basis of compatibility with the organic layer 23. For example, the scintillator layer 21 is formed of a material including cesium iodide CsI, iodine I, cesium Cs, and thallium Tl. The scintillator layer 21 is excited in response to an incident radioactive ray and emits green light. The scintillator layer 21 is formed, for example, through vapor deposition.
The electrode layer 22 is formed of, for example, metal such as copper (Cu).
The electrode pattern 221 includes a plurality of line patterns 221a extending in parallel with the Y-axis and line patterns 221b that extend in parallel with the X-axis and are connected to an +Y-side end portion of the line pattern 221a. In addition, the electrode pattern 222 includes a plurality of line patterns 222a extending in parallel with the Y-axis and line patterns 222b that extend in parallel with the X-axis and are connected to an −Y-side end portion of the line pattern 221a. The line pattern 221a of the electrode pattern 221 and the line pattern 222a of the electrode pattern 222 are arranged along the X-axis in an alternating manner at equal intervals. The line patterns 221a and 222a have a line width of approximately 1 μm, and an arrangement pitch of the line patterns 221a and 222a is set to approximately 8 μm.
The electrode patterns 221 and 222 may be formed, for example, by providing a copper foil on the upper surface of the substrate 20 and etching the copper foil.
Returning to
The organic semiconductor region 23b is formed of a first compound and a second compound. The first compound contains a first subphthalocyanine derivative (SubPc), and the second compound contains a second subphthalocyanine derivative (F5-SubPc). The first compound forms an n-type semiconductor layer, and the second compound forms a p-type semiconductor layer. A boundary between the p-type semiconductor layer and the n-type semiconductor layer has a bulk heterojunction structure in which the first compound of the p-type semiconductor layer and the second compound of the n-type semiconductor layer are mixed with each other.
The amount of the first compound of the organic semiconductor region 23b is substantially equal to the amount of the second compound. In addition, a concentration of the first compound is 0.5 to 1.5 times of the concentration of the second compound. The concentration is a value expressed as a volume concentration or a volume ratio. For example, the volume ratio of the first compound may be set to be equal to or higher than 0.45 and equal to or lower than 0.55, and the volume ratio of the second compound may be set to be equal to or higher than 0.45 and equal to or lower than 0.55.
At least a part of the organic semiconductor region 23b preferably has an amorphous structure. If at least a part of the organic semiconductor region 23b has an amorphous structure, homogeneity of the organic semiconductor region 23b is improved.
The organic semiconductor region 23b configured as described above contains a subphthalocyanine derivative. For this reason, absorptance of the organic semiconductor region 23b for green light is improved. A wavelength (peak wavelength) of the light in the high absorptance depends on a material of the organic semiconductor region 23b. For this reason, a composition of the organic semiconductor region 23b is preferably determined considering compatibility with the composition of the scintillator layer 21. In the radiation detection element 10, the scintillator layer 21 contains cesium iodide CsI, and the organic semiconductor region 23b contains a subphthalocyanine derivative.
The organic intermediate layer 23a has a thickness of approximately 5 to 50 nm and is placed between the organic semiconductor region 23b and the electrode layer 22. The organic intermediate layer 23a suppresses inactivation of electric charges generated from the organic semiconductor region 23b. For this reason, it is possible to improve detection sensitivity of the pulse current caused by electric charges generated from the organic intermediate layer 23a. In addition, the thickness of the organic intermediate layer 23a is smaller than that of the organic semiconductor region 23b. For this reason, even when the organic intermediate layer 23a is provided in the organic layer 23, it is not necessary to excessively increase a bias voltage applied to the organic layer 23.
The organic intermediate layer 23a and the organic semiconductor region 23b may be formed, for example, through vapor deposition.
The electrode layer 24 is formed of metal such as copper (Cu).
In the radiation detection element 10 configured as described above, a stable sealing material such as glass is coated on the upper and lower surfaces of the substrate 20 to cover each layer of the element portion 20a.
As illustrated in
The bias power circuit 32 is connected to the electrode layer 24 and the electrode patterns 221 and 222 of the electrode layer 22. The bias power circuit 32 applies a voltage to the electrode layers 24 and 22 such that the electrode layer 24 has an electric potential of 0 V, the electrode pattern 221 has an electric potential of 0.4 V, and the electrode pattern 222 has an electric potential of 1 V.
The output circuit 31 is, for example, a differential circuit consisting of an operational amplifier, a resistor, a capacitor, and the like. The output circuit 31 outputs a detection signal having a voltage corresponding to electric charges arriving at the electrode layer 24.
The control circuit 30 provided with the output circuit 31 and the bias power circuit 32 is installed, for example, in the substrate 20 of
Next, operations of the radiation detection element 10 configured as described above will be described. For example, as a radioactive ray is incident to the scintillator layer 21 as indicated by the white arrow of
As the voltage of the electrode layer 24 increases, the control circuit 30 outputs a detection signal having a value corresponding to an increase of the voltage. The detection signal is a pulse signal having a value that steeply increases in synchronization with the incidence timing of the radioactive ray. Therefore, it is possible to measure an intensity of the radioactive ray incident to the radiation detection element 10 by counting the number of pulses of the detection signal.
For example, a radiation detection element of the prior art has a size of approximately 2 mm. With respect to this size, if the size of the radiation detection element has 10 mm, the SN ratio decreases to 1/10 or smaller. The SN ratio depends on a capacity of the radiation detection element (element capacity). As the element capacity increases, the SN ratio decreases accordingly.
Therefore, it can be said that the radiation detection element has a tradeoff relationship between enlargement of the effective area and improvement of the SN ratio. Using the radiation detection element 10 according to this embodiment, it is possible to achieve both enlargement of the effective area of the radiation detection element and improvement of the SN ratio. A principle thereof will now be described.
The element capacity of the radiation detection element is determined by an electrostatic capacity between the electrode layers 22 and 24. For example,
For example, in the radiation detection element 10 according to this embodiment illustrated in
As recognized from
By forming the electrode layer 22 provided with the line patterns 221a and 222a having a line width of 1 μm and an arrangement pitch of 8 μm as described above, it is possible to reduce the element capacity. However, in a case where a bias voltage is applied between the electrode layers 22 and 24 such that the line patterns 221a and 222a have the same electric potential, only the area where the line patterns 221a and 222a overlap with the electrode layer 24 predominantly contributes to detection of radioactive rays.
In this regard, according to this embodiment, as illustrated in
This is apparently equivalent to an increase of the effective area of the electrode layer 22. For this reason, it is possible to increase the effective area of the radiation detection element 10.
It is difficult to say that the larger difference of the electric potential between the line patterns 221a and 222a, the better. For example, it is assumed that a bias voltage is applied to the electrode layers 22 and 24 such that the line pattern 221a of the electrode layer 22 has an electric potential of 0 V, the line pattern 222a has an electric potential of 1 V, and the electrode layer 24 has an electric potential of 0 V as illustrated in
As described above, the electrode layer 22 of the radiation detection element 10 according to this embodiment has the line patterns 221a and 221b. For this reason, even when the size of the radiation detection element 10 increases, the element capacity is maintained in a small value. As a result, it is possible to suppress a decrease of the SN ratio. In addition, the bias voltage is applied to the electrode layers 22 and 24 such that a difference of the electric potential is generated between the line patterns 221a and 221b of the electrode layer 22. For this reason, it is possible to obtain an effect of apparently increasing the effective area of the radiation detection element 10. Therefore, it is possible to increase the size of the semiconductor element without decreasing the SN ratio of the radiation detection element.
In the radiation detection element 10 according to this embodiment, the line patterns 221a and 221b are formed in most of the electrode layer 22 as illustrated in FIG. 3. For this reason, a material that does not have transparency for the light from the scintillator layer 21 may be employed as a material of the electrode layer 22. Therefore, it is not necessary to form the electrode layer 22 using a transparent conductive material such as indium tin oxide (ITO). For this reason, it is possible to reduce a manufacturing cost of the radiation detection element. Furthermore, various conductive materials such as copper or aluminum may be employed as a material of the electrode layer 22. Therefore, it is possible to improve freedom of the element design.
Transmittance of the electrode layer 22 for the light from the scintillator layer 21 is preferably set to 60% or higher. According to this embodiment, the arrangement pitch of the line patterns 221a and 222a is set to 8 μm, and the line width is set to 1 μm. For this reason, the transmittance of the electrode layer 22 becomes 60% or higher.
The radiation detection element 10 according to this embodiment has been described by assuming that the electrode layer 24 is formed of copper. Without limiting thereto, the electrode layer 24 may be formed of a conductive material having excellent reflectivity for the light from the scintillator layer 21. In this case, the light passing through the organic layer 23 is reflected on the electrode layer 24 and is incident to the organic layer 23 again. For this reason, photoelectric conversion efficiency of the organic layer 23 is improved. Furthermore, a reflection film may also be formed between the electrode layer 24 and the organic layer 23.
Next, a second embodiment will be described with reference to the accompanying drawings. Like reference numerals denote like elements as in the first embodiment, and they will not be described repeatedly.
As illustrated in
The base 61 is a square plate member, for example, having a length of one side of 30 to 50 cm and a thickness of 2 to 5 mm. The base 61 is provided with a frame 61a formed along an outer periphery. The base 61 is formed of resin such as polyethylene, polyethyleneterephthalate, or polycarbonate. The cover 62 is a member shaped to match the base 61 in size and shape. The cover 62 is also formed of the same material as that of the base 61.
The base 61, the cover 62, the radiation detection element 10 configured as described above can be integrated to each other by placing the radiation detection element 10 inside of the frame 61a of the base 61 and fixing the outer periphery of the cover 62 to the frame 61a of the base 61. If the base 61 and the cover 62 are integrated to each other, the internal space of the frame 61a becomes a closed space where the radiation detection elements 10 are arranged. The cover 62 may be installed in the base 61, for example, using an adhesive, a bolt-nut set, and the like. In addition, after integration between the cover 62 and the base 61, it is preferable to perform light-shielding treatment in order to prevent visible light from reaching the radiation detection element 10.
After integration between the base 61 and the cover 62, handles 70 are installed in both end portions of the Y-direction of the detection unit 60 as illustrated in
The radiation detection apparatus 50 configured as described above has, for example, handles 70 used to press the detection unit 60 toward a target object serving as a radioactive ray source. As a radioactive ray is incident to the radiation detection apparatus 50, the detection signal is output to the outside through the interface 40 of
As described above, it is possible to increase the size of the radiation detection element 10 used in the radiation detection apparatus 50 according to this embodiment without decreasing the SN ratio. Therefore, it is possible to reduce the number of radiation detection elements 10 per detection area while maintaining the radioactive ray detection accuracy. Therefore, it is possible to simplify the apparatus configuration and reduce the manufacturing cost of the apparatus.
If the base 61, the cover 62, and the substrate 20 of the radiation detection element 10 are formed of a flexible material in the radiation detection apparatus 50 according to the aforementioned embodiment, it is possible to use the radiation detection apparatus 50 by curving it as illustrated in
While the embodiments of the disclosure have been described hereinbefore, the disclosure is not limited to such embodiments. For example, in the aforementioned embodiments, the electrode patterns 221 and 222 of the electrode layer 22 are the line patterns 221a and 222a as illustrated in
In addition, as illustrated in
In the aforementioned embodiment, the electrode layer 22 has eleven line patterns 221a and 222a extending in parallel to the Y-axis as illustrated in
In the aforementioned embodiment, one side of the radiation detection element 10 has a length of approximately 10 mm. Alternatively, without limiting thereto, one side of the radiation detection element 10 may have a length longer than 10 mm.
In the aforementioned embodiment, the radiation detection element 10 used in the radiation detection apparatus 50 has thirty six element portions 20a. Alternatively, without limiting thereto, thirty seven or more radiation detection elements 10 may also be provided. In addition, thirty five or less element portions 20a may also be provided.
In the aforementioned embodiment, the radiation detection element 10 having the scintillator layer 21 is provided on the lower surface of the substrate 20 as illustrated in
In the radiation detection element 10A, the scintillator layer 21 is formed on the upper surface of the electrode layer 24 by interposing an insulation film 25. The insulation film 25 may include, for example, a silicon oxynitride film (SiON), a silicon nitride film (SiN), a silicon oxide film (SiO), or the like. In the radiation detection element 10A, the electrode layer 24 has a pattern (solid pattern). For this reason, the electrode layer 24 may be formed of a transparent conductive material such as ITO.
In the radiation detection element 10A, for example, if a radioactive ray is incident to the scintillator layer 21 from the top as indicated by the white arrow of
As the voltage of the electrode layer 24 increases, a detection signal having a value corresponding to an increase of the voltage is output from the control circuit 30. The detection signal becomes a pulse signal having a value steeply increasing in synchronization with the incidence timing of the radioactive ray. Therefore, it is possible to measure an intensity of the radioactive ray incident to the radiation detection element 10 by counting the number of pulses of the detection signal.
Using the radiation detection element 10A according to the modification, it is possible to detect a radioactive ray incident from the top of the substrate 20 with high accuracy. Note that the electrode layer 24 of the radiation detection element 10A is provided on the upper surface of the organic layer 23, and the electrode layer 22 having a line pattern is provided on the lower surface of the organic layer 23. Alternatively, without limiting thereto, the electrode layer 22 may be provided on the upper surface of the organic layer 23, and the electrode layer 24 may be provided on the lower surface of the organic layer 23.
In the embodiments and the modifications described above, the radiation detection element 10 is an indirect conversion type radiation detection element provided with the scintillator layer 21. Alternatively, without limiting thereto, the radiation detection element 10 or 10A may be a direct conversion type radiation detection element having no scintillator layer 21. In the indirect conversion type radiation detection element, the organic layer is excited by the light from the scintillator as described above. In contrast, in the indirect conversion type radiation detection element, the organic layer is excited directly by an incident radioactive ray. For this reason, the direct conversion type radiation detection element typically has higher radioactive ray detection efficiency.
While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.
Number | Date | Country | Kind |
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2017-052296 | Mar 2017 | JP | national |