This application is based upon and claims the benefit of priority from prior Japanese Patent Application No. 2013-195677 filed on Sep. 20, 2013 in Japan, the entire contents of which are incorporated herein by reference.
Embodiments described herein relate generally to radiation detectors and radiation detection apparatuses.
In a radiation imaging system such as a radiography apparatus or a computerized tomography (CT) system, X-ray beams from an X-ray source are emitted to a test subject or an object such as a patient or baggage. An X-ray beam attenuates as passing through a test subject, and then enters a radiation detector. As detecting pixels are arranged in an array in a radiation detector, an X-ray that has entered the radiation detector enters the detecting pixels arranged in an array. The intensity of radiation to be detected by each detecting pixel normally depends on X-ray attenuance. The respective detecting elements of the detecting pixels arranged in an array generate electrical signals corresponding to attenuated X-ray beams sensed by the respective detecting elements independently of one another. These signals are transmitted to a data processing system for analysis, and an image is eventually formed by the data processing system.
a) through 6(c) are cross-sectional views showing the process of manufacturing the radiation detector of the first embodiment;
a) through 7(c) are cross-sectional views showing the process of manufacturing the radiation detector of the first embodiment;
a) through 8(c) are cross-sectional views showing the process of manufacturing the radiation detector of the first embodiment;
a) and 11(b) are cross-sectional views showing the process of manufacturing the radiation detector of the third embodiment; and
a) through 12(c) are diagrams for explaining a radiation detection apparatus according to a fourth embodiment.
A radiation detector according to an embodiment includes: a semiconductor substrate having a first surface and a second surface located on the opposite side from the first surface; a light detecting unit provided on a side of the first surface of the semiconductor substrate; a first insulating film provided on the first surface to cover the light detecting unit; a second insulating film covering the first insulating film; a scintillator provided on the second insulating film, and converting radiation into visible light; a first opening penetrating through the semiconductor substrate and the first insulating film; an interconnection provided between the first insulating film and the second insulating film, and connected to the light detecting unit; a first electrode connected to the interconnection through a bottom portion of the first opening, the first electrode being provided on a bottom surface and a side surface of the first opening and on part of the second surface; a second electrode provided on a region in the second surface of the semiconductor substrate, the region opposing at least a part of the light detecting unit; a second opening provided in the semiconductor substrate, the second opening being located in a region, the region surrounding the first electrode and not surrounding the second electrode; and an insulating resin layer covering the first electrode, the second electrode, the first opening, and the second opening, the insulating resin layer having a third opening and a fourth opening provided therein, the third opening leading to the first electrode, the fourth opening leading to the second electrode.
Before embodiments of the present invention are described, how the embodiments have been developed is explained.
In a radiation detector of indirect conversion type, visible light that is generated from radiation entering a scintillator is detected by light detecting units such as photodiodes or photomultipliers.
Regarding a radiation detector that includes such a scintillator and pixels with light detecting units arranged in an array, there is a demand for formation of a large number of pixels at a high density so as to obtain high-quality CT images with arrayed pixels. However, it is difficult to extract electrical signals from pixels formed at a high density with interconnections connected by wire bonding. In view of this, through electrodes that are called TSV (Through Silicon Via) electrodes are normally required.
In a case where TSV electrodes are formed on light detecting units, the TSV electrodes are normally formed after the light detecting units are formed in a semiconductor substrate (“via-last”). In a case where the light detecting units are formed in a semiconductor substrate after the TSV electrodes are formed (“via-first”), the material of the TSV electrodes needs to be capable of tolerating various kinds of load (such as heat history) during the light detecting unit manufacturing process, and therefore, the material of the TSV electrodes is limited.
By a general method of manufacturing the TSV electrodes, through holes for forming the TSV electrodes are formed in the semiconductor substrate having the light detecting units formed therein, and insulating layers for insulating and isolating the TSV electrodes from the semiconductor substrate are formed. After that, the TSV electrodes are completed by using a plating technique or the like. At this point, the breakdown voltage of the insulating films (hereinafter also referred to as TSV insulating films) formed on the side walls of the through holes is important. Particularly, in the case of an avalanche photodiode (hereinafter also referred to as an APD) that operates in Geiger mode, a relatively high voltage of approximately 20 V to 80 V is applied between the cathode electrode and the anode electrode of the APD for driving. Therefore, the TSV insulating film for the APD needs to have a sufficiently high breakdown voltage. That is, in a case where TSV electrodes are formed on APDs, it is necessary to pay enough attention to the breakdown voltage of the TSV insulating films.
So as to improve the breakdown voltage of TSV insulating films, the inventors have considered the following aspects.
In a case where TSV electrodes are formed, it is difficult to form the openings for through holes if the semiconductor substrate is thick. Therefore, a supporting member is bonded to the substrate with an adhesive agent, and the substrate is thinned by polishing. After that, the openings for through holes are formed. Therefore, in a case where TSV insulating films are formed, it is necessary to pay attention to the heat resistance of the adhesive agent. For example, in a case where TSV insulating films are formed by plasma CVD (Chemical Vapor Deposition), by which insulating films can be formed at relatively low temperatures, film quality and breakdown voltage become lower than those of thermally-oxidized films or CVD films formed by high-temperature plasma, if SiO2 films are formed at a low temperature such as 200° C., for example, by taking into account the heat resistance of the adhesive agent. Particularly, the CVD gas flow becomes slower at the bottom portions of the through holes than in the substrate surface, and therefore, degradation in the insulating film quality is conspicuous at the bottom portions. In a case where the TSV insulating films are made of a resin material, contact plugs are formed at the bottom portions of the through holes after the insulating films made of resin are formed, and the TSV electrodes are then formed. In this case, the insulating films made of resin deteriorate during the process of forming the contact plugs and the TSV electrodes, and the breakdown voltage of the TSV insulating films becomes lower.
To improve the breakdown voltage of TSV insulating films, isolation trenches that penetrate through a silicon substrate and surround respective TSV electrodes are formed, and insulating films are formed in the isolation trenches before devices and the TSV electrodes are formed in the silicon substrate. By this manufacturing method, Si-based insulating films are formed in the isolation trenches in the following manner. That is, after the isolation trenches are formed, polysilicon films are formed on the inner walls of the isolation trenches, and the polysilicon films are modified into SiO2 films by thermal oxidation. In voids in the SiO2 films, SiO2 films are further formed by CVD. In this case, the type of the insulating films to be formed in the isolation trenches is selected by taking into account various kinds of load (such as heat history) of the device forming process and the through electrode forming process that follow the isolation trench forming process.
By using such a manufacturing method, the TSV insulating films still need to have sufficiently high heat resistance, and the options for the material of the insulating films are limited. Although the insulating films in the isolation trenches are Si-based insulating films, the width of each isolation trench needs to be made smaller to avoid voids, and therefore, processing the isolation trenches becomes difficult. Further, since the isolation trenches are filled with Si-based insulating films that are hard but fragile, there is a possibility that the isolation trench portions will crack when the thinned Si substrate is handled. Also, the process of forming the insulating films in the isolation trenches becomes complicated, resulting in higher manufacturing costs.
The inventors have made intensive studies, and have managed to develop radiation detectors and radiation detection apparatuses that are capable of improving the breakdown voltage of the TSV insulating films. Embodiments of the radiation detectors and the radiation detection apparatuses will be described below.
The following is a description of the embodiments, with reference to the accompanying drawings. However, it should be understood that the drawings are merely schematic, and the relationship between the thickness and the planar size of each component, and the width ratios between layers differ from those in reality. Therefore, specific thicknesses and sizes should be determined by taking into account the description below. Also, the relationships and ratios between components might vary among the drawings.
A radiation detector according to this embodiment includes: a semiconductor substrate that has a first surface and a second surface located on the opposite side from the first surface; a light detecting unit placed on the side of the first surface of the semiconductor substrate; a first insulating film formed on the first surface to cover the light detecting unit; a second insulating film covering the first insulating film; a scintillator that is placed on the second insulating film and converts radiation into visible light; a first opening penetrating through the semiconductor substrate and the first insulating film; an interconnection that is placed between the first insulating film and the second insulating film, and is connected to the light detecting unit; a first electrode that is placed on the bottom surface and the side surface of the first opening and on part of the second surface, and is connected to the interconnection through a bottom portion of the first opening; a second electrode that is placed on the second surface of the semiconductor substrate having the light detecting unit formed therein, with the semiconductor substrate being divided by the first opening; a second opening that is formed in the semiconductor substrate, and is located in a region that surrounds the first electrode and does not surround the second electrode; and an insulating resin layer that covers the first electrode, the second electrode, the first opening, and the second opening in the second surface of the semiconductor substrate, and has a third opening and a fourth opening formed therein, the third opening leading to the first electrode, the fourth opening leading to the second electrode.
Referring to
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Through holes 40 that lead to the interconnections 30 are formed in the surface (the bottom surface) of the semiconductor substrate 12 on the opposite side from the surface having the light detecting units 22 formed therein. The through holes 40 are provided for the respective pixels 20 in one-to-one correspondence. In each of the through holes 40, a seed layer 42a that has a stack structure formed with conductive materials such as a Ti layer and a Cu layer is provided to cover the bottom surface and the side surface of the through hole 40, and to extend onto the bottom surface of the semiconductor substrate 12. The Ti layer is a barrier metal. The electrodes 44a made of Cu, for example, are provided to cover the seed layers 42, so that the electrodes 44a serve as the TSV electrodes. Isolation trenches 46 are formed in the semiconductor substrate 12 so as to surround the respective through holes 40. The isolation trenches 46 are designed to penetrate through the semiconductor substrate 12, and reach the insulating film 24 in
In the radiation detector 10 having such a structure, when an X-ray enters the scintillator 70 from above in
In this embodiment, the pixels 20 each having cells 21 that include light detecting units 22 formed with APDs operating in Geiger mode and are arranged in parallel to the corresponding interconnection 30 are arranged in an array. An APD that operates in Geiger mode is a photodiode that generates a current pulse every time a photon enters the APD. In this embodiment, APDs 22 are arranged in parallel to the corresponding interconnection 30 in each pixel 20. Accordingly, the number of photons that each pixel 20 fails to detect can be reduced. As the pixels 20 each having APDs 22 arranged in parallel are arranged in an array, a current pulse having a wave height proportional to the number of APDs that photons have entered can be obtained. By measuring the wave height of this pulse, the number of phones that have entered the radiation detector 10, or the energy of the radiation that has entered the scintillator 70, can be measured.
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By the above described manufacturing method, the isolation trenches 46 are formed, so that the breakdown voltage of the TSV insulating film 50 or the breakdown voltage between the TSV electrodes 44a and the bottom-surface electrodes 44b can be dramatically improved. Also, as the through holes 40 and the isolation trenches 46 are filled with the insulating resin 50, wafer breakage can be prevented by virtue of the mechanical strength and the appropriate elastic effect of the resin when the thinned Si substrate 12 is handled. If the isolation trenches 46 are made wider to improve the processability of the isolation trenches 46, the isolation trenches 46 can be easily filled with the insulating resin 50. Accordingly, the isolation trenches 46 can be easily processed. Furthermore, as the insulating resin 50 to fill the through holes 40 and the isolation trenches 46 is integrally formed, the manufacturing process can be simplified, and the manufacturing costs can be lowered.
According to the first embodiment and the modifications thereof, a radiation detector that can improve the breakdown voltage of the TSV insulating film can be obtained.
This second embodiment can achieve the same effects as those of the first embodiment. The first modification or the second modification of the first embodiment may also be applied to the radiation detector of the second embodiment.
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The third embodiment can also achieve the same effects as those of the first embodiment. Furthermore, having the support glass 84, the radiation detector 10D of the third embodiment has a higher strength than that of the radiation detector 10 of the first embodiment. Accordingly, breakage can be more effectively prevented when the radiation detector is handled.
As described so far, according to the first through third embodiments and the modifications thereof, isolation trenches penetrating through the semiconductor substrate are formed so as to surround the TSVs. Accordingly, the breakdown voltage of the TSV insulating film (the breakdown voltage between the TSV electrodes and the bottom-surface electrodes) can be dramatically improved.
Also, as the through holes and the isolation trenches in the TSV electrode portions are filled integrally with insulating resin, wafer breakage can be prevented by virtue of the mechanical strength and the appropriate elastic effect of the resin when the thinned Si substrate is handled. If the isolation trenches are made wider to improve processability of the isolation trenches, the isolation trenches can be easily filled with insulating resin. Accordingly, the isolation trenches can be easily processed. Furthermore, as the insulating resin to fill the through holes and the isolation trenches is integrally formed, the manufacturing process can be simplified, and the manufacturing costs can be lowered.
The first modification or the second modification of the first embodiment may be applied to the radiation detector of the third embodiment. Also, the third embodiment may be applied to the second embodiment.
Referring to
As shown in
The radiation tube 520 is a device that emits a radiation beam 530 such as an X-ray in a fan-like shape toward the radiation detecting units 510 located on the opposite side. The radiation beam 530 emitted from the radiation tube 520 passes through a test subject 540 on a stand (not shown), and enters the radiation detecting units 510.
Each of the radiation detecting units 510 is a device that has an incident surface 221 to receive the radiation beam 530 that has been emitted from the radiation tube 520 and partially passed through the test subject 540, converts the radiation into visible light, and detects the visible light as an electrical signal. The radiation detection apparatus 500 includes the radiation detecting units 510 arranged in an arc-like shape, a collimator 550 placed on the side of the incident surfaces 221 of the radiation detecting units 510, and the signal processing unit 580 connected, by signal lines 150, to electrodes on the opposite side of the respective radiation detecting units 510 from the radiation tube 520.
The radiation detecting units 510 convert the radiation (the radiation beam 530) entering from the incident surfaces 221 into visible light, and converts (photoelectrically converts) the visible light into electrical signals (currents) with photoelectric conversion elements 114 described later.
The collimator 550 is an optical system that is placed on the side of the incident surfaces 221 of the radiation detecting units 510, and refracts radiation so as to enter the radiation detecting units 550 in a collimated manner.
The signal processing unit 580 receives the electrical signals (currents) photoelectrically converted by the respective radiation detecting units 510 via the signal lines 150, and calculates, from the current values, the energy of the radiation that has entered the respective radiation detecting units 510. From the energy of the radiation that has entered the respective radiation detecting units 510, the signal processing unit 580 generates a radiation image that is colored in accordance with the substances in the test subject 540.
The radiation tube 520 and the radiation detecting units 510 are designed to rotate about the test subject 540. With this arrangement, the radiation detection apparatus 500 can generate a cross-sectional image of the test subject 540.
The radiation detection apparatus 500 according to this embodiment can be used not only for generating cross-sectional images of human bodies, animals, or plants, but also as an inspection apparatus such as a security screening apparatus for fluoroscopically inspecting objects.
Referring now to
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The scintillator 210 includes light reflection layers 215 that are formed at predetermined pitch in two directions perpendicular to each other. The photoelectric conversion layer 110 and the scintillator 210 are divided, by the light reflection layers 215, into photoelectric conversion components 220 arranged in a matrix form. The photoelectric conversion components 220 include photoelectric conversion elements 114, and energy of incident radiation is detected by each photoelectric conversion component 220.
In the radiation detection apparatus 500 shown in
According to the fourth embodiment, a radiation detection apparatus that includes radiation detectors capable of improving the breakdown voltage of the TSV insulating films can be obtained.
The radiation detectors of the first through third embodiments and the modifications thereof, and the radiation detection apparatus of the fourth embodiment can be used not only for obtaining cross-sectional images of human bodies, animals, or plants, but also in various kinds of inspection apparatuses such as security screening apparatuses for fluoroscopically inspecting objects.
While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel methods and systems described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the methods and systems described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.
Number | Date | Country | Kind |
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2013-195677 | Sep 2013 | JP | national |