Claims
- 1. A method for removing radioactive contaminants from a surface comprising the steps of:a) applying to the surface an aqueous solution wherein the aqueous solution comprises a wetting agent and an active agent, said wetting agent being selected from the group consisting of methanol, ethanol, propanol, isopropanot, butanol, propargyl alcohol, tertiary butyl alcohol, pentanol, propylene glycol, polypropylene glycol, ethylene glycol, and mixtures thereof and said active agent being a complex substituted keto-amine having the formula wherein R is selected from the group consisting of abietyl, hydroabietyl, and dehydroabietyl; wherein R″ is an alpha ketonyl having fewer than 10 carbon atoms; and wherein R′ is either H or CH2R″;b) retaining the aqueous solution on the surface for a period of time to allow radioactive contaminants to migrate into the aqueous solution; and c) removing the aqueous solution containing the radioactive contaminants from the surface.
- 2. The method of claim 1, wherein the complex substituted keto-amine has the molecular formula C33H45NO2ClH.
- 3. The method of claim 1, wherein the alpha ketonyl group is derived from a ketone selected from the group consisting of acetone, methyl ethyl ketone, diacetone alcohol, isophorone, mesityl oxide, pentane dione, acetonyl acetone, cyclopentanone, cyclohexanone, and acetophenone.
- 4. The method of claim 1, wherein the wetting agent is a mixture of isopropanol and propargyl alcohol.
- 5. The method of claim 1, wherein the wetting agent comprises between 0.1 and 1.0% by weight of the aqueous solution and the active agent is a complex substituted keto-amine comprising between 0.1 and 2% by weight of the aqueous solution.
- 6. The method of claim 1, wherein the aqueous solution further comprises an acid selected from the group consisting of hydrochloric acid, hydrofluoric acid, sulfuric acid, phosphoric acid, sulfurous acid, bromic acid, iodic acid, nitric acid, perchloric acid, oxalic acid, aqua regia, citric acid, sulfamic acid, glycolic acid, ascorbic acid, and mixtures thereof.
- 7. The method of claim 1, wherein the radioactive contaminant is a member of the lanthanide group.
- 8. The method of claim 1 wherein the radioactive contaminant is a member of the actinide group.
- 9. The method of claim 1 wherein the radio active contaminant is a member selected from the group consisting of Actinium-227, Americium-241, Americium-243, Antimony-124, Antimony-125, Barium-133, Beryllium-7, Bismuth-207, Cadmium-109, Calcium-45, Carbon-14, Cerium-139, Cerium-141, Cerium-144, Cesium-134, Cesium-135, Cesium-137, Chromium-51, Cobalt-56, Cobalt-57, Cobalt-58, Cobalt-60, Copper-67, Curium-242, Curium-243, Curium-244, Curium-247, Europium-152, Europium-154, Europium-155, Gadolinium-153, Germanium-68, Gold-195, Hafnium-181, Hydrogen-3(Tritium), Iodine-125, Iodine-126, Iodine-129, Iodine-131, Iodine-133, Iridium-192, Iron-55, Iron-59, Lead-210, Manganese-54, Mercury-203, Neptunium-237, Nickel-59, Nickel-63, Niobium-94, Plutonium-236, Plutonium-238, Plutonium-239, Plutonium-240, Plutonium-241, Plutonium-242, Plutonium-243, Plutonium-244, Polonium-210, Potassium-40, Promethium-147, Protactinium-231, Radium-223, Radium-224, Radium-226, Radium-228, Ruthenium-106, Samarium-151, Scandium-46, Selenium-75, Silver-108m, Silver-110m, Sodium-22, Strontium-85, Strontium-89, Strontium-90, Sulfur-35, Tantalum-182, Technetium-99, Thallium-204, Thorium-natural, Thorium-228, Thorium-230, Thorium-232, Tin-113, Uranium-232, Uranium-233, Uranium-234, Uranium-235, Uranium-236, Uranium-238, Uranium-natural, Uranium-depleted, Yttrium-88, Yttrium-91, Zinc-65, Zirconium-95 and associated decay products thereof.
- 10. The method of claim 1, wherein steps (a), (b) and (c) are repeated to optimize decontamination.
- 11. The method of claim 1, wherein the aqueous solution is applied to the surface by spraying.
- 12. The method of claim 1, wherein the aqueous solution is retained on the surface for a period of less than ten minutes.
- 13. The method of claim 1, wherein the surface is a member selected from the group consisting of metal, plastic, glass, concrete, wood, fiberglass, fabric, soil and combinations thereof.
- 14. The method of claim 1, wherein the aqueous solution contains approximately 0% by weight of an acid.
- 15. The method of claim 1, further comprising the steps of:a) applying to the surface a second aqueous treatment solution wherein the second aqueous treatment solution comprises a second wetting agent and a second active agent, the second active agent being a member selected from the group consisting of linear alcohol alkoxylates, ethoxylated alkyl amines, and fixtures thereof; b) retaining the second aqueous treatment solution on the surface for a period of time to allow radioactive contaminants to migrate into the second aqueous treatment solution; and c) removing the second aqueous treatment solution containing the radioactive contaminants from the surface.
- 16. The method of claim 6, wherein the acid is selected from the group consisting of hydrochloric acid, hydrofluoric acid, sulfuric acid, phosphoric acid, sulfurous acid, bromic acid, iodic acid, nitric acid, and mixtures thereof.
- 17. The method of claim 6, wherein the aqueous solution has a pH of less than about 1.5.
- 18. The method of claim 6, wherein the aqueous solution containing radioactive contaminants removed in step (c) is neutralized with an alkaline agent to a pH of between 5.5 and 9.0.
- 19. The method of claim 6, wherein the acid comprises between about 1% and about 10% by weight of the aqueous solution.
- 20. The method of claim 11, wherein the step of retaining the solution on the surface is accompanied by brushing the treated surface with an ultrasonic brush to decrease the period of time required to allow radioactive contaminants to migrate into the aqueous solution.
- 21. The method of claim 13, wherein the surface is metal.
- 22. The method of claim 13, wherein the surface is a vehicle used for transportation of materials.
- 23. The method of claim 15, wherein the second active agent is an ethoxylated alkyl amine, said ethoxylated alkyl amine being ethoxylated coco alkyl amine.
- 24. The method of claim 15, wherein the second active agent is a linear alcohol alkoxylate.
- 25. The method of claim 15, wherein the second aqueous treatment solution further comprises an acid.
- 26. The method of claim 17, wherein said acid is hydrochloric acid.
- 27. The method of claim 18, wherein said alkaline agent is a member selected from the group consisting of sodium hydroxide and potassium hydroxide.
PRIORITY INFORMATION
This application is a continuation-in-part of co-pending U.S. patent application Ser. No. 09/976,467, filed Oct. 12, 2001, issued as U.S. Pat. No. 6,497,769 on Dec. 24, 2002, which is hereby incorporated by reference.
US Referenced Citations (24)
Foreign Referenced Citations (4)
Number |
Date |
Country |
2065092 |
Dec 1979 |
GB |
357111244 |
Jul 1982 |
JP |
59174800A |
Oct 1984 |
JP |
11202086 |
Jul 1999 |
JP |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
09/976467 |
Oct 2001 |
US |
Child |
10/283039 |
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US |