Claims
- 1. A composition selected from the group consisting of: ##STR33## and isomers thereof, wherein X is selected from the group consisting of Cl and Br.
- 2. The composition of claim 1 of the formula: ##STR34## wherein X is selected from the group consisting of Cl and Br.
- 3. The composition of claim 1 of the formula: ##STR35## wherein X is selected from the group consisting of Cl and Br.
- 4. The composition of claim 1 of the formula: ##STR36## and isomers, wherein X is selected from the group consisting of Cl and Br.
- 5. The composition of claim 1 of the formula: ##STR37## wherein X is selected from the group consisting of Cl and Br.
- 6. The composition of claim 1 of the formula: ##STR38## wherein X is selected from the group consisting of Cl and Br.
- 7. The composition of claim 1 of the formula: ##STR39## and isomers, wherein X is selected from the group consisting of Cl and Br.
- 8. A composition selected from the group consisting of:
- X.sub.2 P(S)CH.sub.2 --CH.dbd.CH--P(S)X.sub.2 and
- (OH).sub.2 P(O)CH.sub.2 --CH.dbd.CH+13 P(O)(OH).sub.2
- and isomers thereof, wherein X is selected from the group consisting of Cl and Br.
- 9. The composition of claim 8 of the formula: ##STR40## wherein X is selected from the group consisting of Cl and Br.
- 10. The composition of claim 8 of the formula: ##STR41##
- 11. A composition selected from the group consisting of: ##STR42## and isomers thereof.
- 12. The composition of claim 11 of the formula: ##STR43##
- 13. The composition of claim 11 of the formula: ##STR44##
- 14. The composition of claim 11 of the formula: ##STR45##
- 15. A method of preparing reaction products of unsaturated hydrocarbons, P.sub.4 S.sub.10 and PSX.sub.3 wherein X is selected from the group consisting of Cl and Br comprising contacting an unsaturated hydrocarbon reactant of the general formula:
- R.sub.1 R.sub.2 C.dbd.CR.sub.3 R.sub.4 I
- wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 can be the same or different and are selected from the group consisting of hydrogen, C.sub.1 -C.sub.10 alkyl and C.sub.1 -C.sub.10 alkylene with the proviso that said reactant can be cyclic; and with the further proviso that said reactant is not ethylene; with reactants having the general formulas:
- P.sub.4 S.sub.10 ; and II
- PSX.sub.3 III
- wherein X is as defined above, at a temperature from about 90.degree. C. to about 250.degree. C. and under autogenous pressure.
- 16. The method of claim 1 wherein the unsaturated hydrocarbon reactant is selected from the group consisting of propylene, 1-butene, 2-butene, 1-pentene, cyclohexane, 1,3 butadiene and isoprene.
- 17. The method of claim 1 wherein the reaction products are selected from the group consisting of: ##STR46## wherein X is selected from the group consisting of Cl and Br.
Parent Case Info
This is a continuation of application Ser. No. 252,114, filed Apr. 8, 1983, now abandoned.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
4231970 |
Uhing |
Nov 1980 |
|
Continuations (1)
|
Number |
Date |
Country |
Parent |
252114 |
Apr 1981 |
|