Ready to use combined skin marking stain compound and applicator requiring only the addition of water

Information

  • Patent Application
  • 20080022888
  • Publication Number
    20080022888
  • Date Filed
    July 27, 2006
    18 years ago
  • Date Published
    January 31, 2008
    17 years ago
Abstract
A ready to use skin marking stain/applicator for use in inhibiting voter fraud requiring only the addition of water, includes a open top container with a measured quantity of dry water soluble stain producing compound disposed therein. The compound, when dissolved in water, filling the container, is capable of reacting with the organic materials on the person's finger, to produce within a relatively short time, a semipermanent, highly visible, stain, on the finger. A substantially impermeable removable cover is secured over the open top of the container to inhibit the ingress of moisture into the container prior to its use.
Description

BRIEF DESCRIPTION OF THE DRAWINGS


FIGS. 1 and 2 are perspective and side elevational views of an applicator which includes a dehydrated water-soluble stain producing compound therein in accordance with the present invention with an installed cover in FIG. 1;



FIG. 3 is a cross-sectional view of the applicator of claim 1 illustrating the compound disposed therein in packet, tablet and capsule form; and



FIG. 4 is a perspective view of the applicators of FIG. 1 filled with water and a fill line designated thereon.





DESCRIPTION OF THE PREFERRED EMBODIMENT

Referring to the drawing a container 10 made of a suitable plastic, for example, has a bottom wall 12 and a peripheral side wall 14 terminating in a rim 16 defining an open top through which a voter's digit, e.g., finger or thumb, maybe inserted to be stained. Alternatively, the stain may be applied via a brush or the like. A measured quantity of a skin staining compound 18 is disposed in the container within a water-soluble pouch 20. The compound(s) is in its dry or dehydrated state so that when the container is filled with water to approximately the rim or to a designated fill line, the dry or dehydrated compound is dissolved in the water forming a staining solution capable of reacting with the organic materials on an individual's finger, thumb and/or nail to produce a semipermanent, highly visible stain on the exposed digit which is visible under ambient and/or UV light. The resulting stain will remain on the individual's body, e.g, finger or thumb, for a reasonable period of time, e.g., 2-3 days to accommodate the voting process and be substantially nonremovable through the use of common available household products such as soap and bleach during said time frame. The term “measured quantity” as used herein to describe the staining compound shall mean a quantity of the compound which is sufficient to provide the semipermanent stain on the exposed digit when dissolved in the quantity of water 28 filling the container to its top or designated fill line 26. Where two or more compounds are used the term “measured quantity” can refer to the stoichiometric quantity between the two or more ingredients. The term “completely soluble” as used herein to describe the staining compound shall mean a compound or compounds which will directly pass into solution. The term “soluble” as used herein to describe a staining compound shall mean a compound which will pass directly into solution with water, i.e, completely soluble or one, i.e., partially soluble that requires the aid of solubilizer to dissolve in sufficient quantities in water to form the desired staining solution.


Instead of placing the staining compound 18 in a pouch it may be in the form of a tablet or small briquette 18a or capsule 18b disposed within the container. Where a two component staining compound, to be described (or to separate single component compounds), is to be used, one-component may be encapsulated in pouch 20 and the other component 22 may be encapsulated in a separate pouch 24, although such physical separation may not be required. A substantially impermable removable cover, such as a conventional thermoplastic sheet or metallic foil 30, may be placed over the container mouth to inhibit the ingress of moisture into the container interior prior to its use.


The size of container may vary, but I have found that containers holding (or having a fill line designation of 60 ml (2 oz) or 120 ml (4 oz) are readily acceptable in the industry. The size of the container determines the amount of the staining compound required with the caveat that the strength of the resulting solution and the quantity of the staining compound will vary depending upon the desired staining formulation.


Examples of Suitable Staining Compounds

Single-component dehydrated dyes, suitable for use in the invention, may be either highly colorant (Gentian violet, FD&C Blue #1), invisible but fluorescent (stilbene, naphthalene, and coumarin derivatives) both colorant and fluorescent (Rhodamine-G6), invisible and essentially non-fluorescent until bound with proteins (dansylated compounds) or essentially colorless until bound with proteins (ninhydrin and its analogs).


A two-component dry dye based compound may consist of a fluorescent coumarin derivative generally hydophilic dye, such as Savannah Yellow, and a solubilizer such as caprolactam and dimethyl sulfone. The high molecular weight polyethylene powders may also be used as solubilizer. Single-component reagent stains include ninhydrin, silver sutrate in a water-soluble polyvinyl alcohol structure.


Two-component staining reagents (coated or placed in separated pouches to prevent a reaction prior to the addition of water) may be in the form of a color former, i.e, chromogenic or fluorogenic combination of an intermediate mono-or poly-functional benzene, naphthalene, acridine compound and a developer such as a polyvalent metal ion, mineral or organic acid, oxidizer or an electron-receiving substance. Some examples of such two component staining reagents are listed below:















Color Former   Developer









pyrocatechol + vanadium oxysulfate



8-hydroxyquinoline sulfate + ferric sulfate



aminophenol + peroxide



diphenylamine hydrochloride + potassium nitrate



naphthalenediamine dihydrochloride + sodium nitrite



tannic acid + ferric salt



fluorescin + peroxide



acridine hydrochloride + zinc sulfate










A third component in the form of a dye capable of providing an immediate, though less permanent stain, may be added to the single-or double-component compound. Such a dye may be rhodamine (added to ninhydrin).


Quantative Examples of Staining Compounds and Water Need to Produce the Staining Solution

Single Component Dyes:

    • a) 1.2 grams Gentian Violet in water-soluble structure
    • Fill 120-ml container to capacity with tap water
    • b) 1.8 grams of Basic Violet 10, 500% conc., in water-soluble structure
    • c) 1.2 grams of DayGlo Color Corp. UV Blue D-282 in water-soluble structure


Fill 120-ml container to capacity with tap water

    • d) Single-component reagent stains:
    • e) 1.2 grams ninhydrin in water-soluble structure
    • Fill 120-ml container to capacity with purified water
    • f) 6 grams of silver nitrate in water-soluble, opaque, polyvinyl alcohol structure
    • Fill 60-ml container to capacity using distilled water


Two-component reagents:

    • a) 2.7 grams ferric chloride hexahydrate in water-soluble structure 1.66 grams of pyrocatechol in another water-soluble structure Fill 60-ml container to capacity using tap water
    • b) 2.7 grams ferric chloride hexahydrate in water-soluble structure 17 grams of tannic acid in another water-soluble structure Fill 60-ml container to capacity using tap water


Combined Slow and Fast Acting Dyes:

    • 1 gram ninhydrin in water-soluble structure dissolvable in 3-5 seconds
    • 1.8 grams of Basic Violet 10 in water-soluble structure dissolvable in 10-20 seconds
    • 1 gram of Victoria Pure Blue Base in another water-soluble structure dissolvable in 10-20 seconds


Fill 120-ml container to capacity using purified water


There has been described a ready-to-use skin marking stain and applicator requiring only the addition of water. The dry, stain-producing compound carried by the applicator prior to the addition of water has a long shelf-life and is lightweight for shipping purposes. The resulting stain on a person's digit is not readily removable for several days enabling those monitoring the election to readily identify those that have previously participated in the event, thereby inhibiting voter fraud.

Claims
  • 1. A ready-to-use skin marking stain and applicator for inhibiting voter fraud, requiring only the addition of water comprising: a) a container of a selected volumetric size with an open top adapted to be filled with water; andb) a measured quantity of a dry water-soluble stain producing compound, capable, when in an aqueous solution, of reacting with the organic material(s) existing on the surface of a person's skin/nails to produce within a selected time frame a semipermanent, highly visible stain under ambient and/or ultraviolet light on a selected portion of the person's body, disposed in the container.
  • 2. The invention of claim 1 wherein the selected time frame is within the range of 0 to 20 minutes.
  • 3. The invention of claim 1 further including a substantially impermeable removable cover secured over the open top of the container to inhibit the ingress of moisture into the container prior to its use.
  • 4. The invention of claim 1 wherein the stain producing compound is contained within a water-soluble pouch.
  • 5. The invention of claim 1 wherein the stain producing compound is in tablet form.
  • 6. The invention of claim 1 wherein the stain producing compound is in capsule form.
  • 7. The invention of claim 1 wherein the stain producing compound is a completely soluble dye.
  • 8. The invention of claim 1 wherein the stain producing compound is a two-component dye in the form of a partially soluble dye and a solublizing agent.
  • 9. The invention of claim 1 wherein the stain producing compound is a single-component reagent.
  • 10. The invention of claim 1 wherein the stain producing compound is a two-component reagent.
  • 11. The invention of claim 1 further including a second dehydrated stain producing compound which, in an aqueous solution, produces a highly visible stain on the selected body portion substantially immediately.
  • 12. The invention of claim 7 wherein the dye is selected from the group consisting of one or more of the following compounds: Gentian violet, FD&C Blue #1, Basic Violet, UV Blue D-282, stilbene, naphthalene, coumarin derivatives, Rhodamine-G6, dansylated compounds and ninhydrin and its analogs.
  • 13. The invention of claim 9 wherein the reagent selected from the group consisting of ninhydrin and silver nitrate.
  • 14. The invention of claim 10 wherein the coupled reagent is selected from one or more of the group consisting of: Color Former Developerpyrocatechol+vanadium oxysulfate8-hydroxyquinoline sulfate+ferric sulfateaminophenol+peroxidediphenylamine hydrochloride+potassium nitratenaphthalenediamine dihydrochloride+sodium nitritetannic acid+ferric saltfluorescin+peroxideacridine hydrochloride+zinc sulfate
  • 15. A ready to use skin staining compound and applicator requiring only the addition of water for identifying an individual participating in or attending an event through placing a stain on a portion of the individual's body comprising: a) a container capable of holding a selected volume of water, the container having a bottom and peripheral wall terminating in a rim surrounding an open top;b) a measured quantity of a dry water-soluble stain producing compound disposed in the container, the compound, when dissolved in water filling the container, being capable of reacting with the organic material(s) present on an individual's skin to produce a highly visible stain under ambient and/or UV light on the selected individual's skin portion exposed to the solution.
  • 16. The invention of claim 15 further including a substantially impermeable, removable cover secured to the container rim to inhibit the ingress of moisture into the container.
  • 17. The invention of claim 16 wherein the stain producing compound is a completely soluble reagent.
  • 18. The invention of claim 16 wherein the staining compound is a two-component reagent.
  • 19. The invention of claim 16 wherein the staining compound comprises a partially soluble dye and a hydrophilic solublizing agent.
  • 20. The invention of claim 17 further including a completely soluble dye disposed in the container which when passed into the solution is capable of producing a stain of the selected body portion substantially immediately.
  • 21. The invention of claim 18 further including a completely soluble dye disposed in the container which when passed into the solution is capable of producing a stain of the selected body portion substantially immediately.
  • 22. The invention of claim 19 further including a completely soluble dye disposed in the container which when passed into the solution is capable of producing a stain of the selected body portion substantially immediately.