This application claims priority to and the benefit of Korean Patent Application No. 10-2022-0187881, filed in the Korean Intellectual Property Office on Dec. 28, 2022, the entire contents of which are incorporated herein by reference.
The present disclosure relates to a rechargeable battery and a device for forming a pouch of the rechargeable battery. More specifically, the present disclosure relates to a rechargeable battery and a device for forming a pouch of the rechargeable battery that stably secures a thickness of a side wall corner portion of the pouch and a thickness of a bottom of the pouch connected to the side wall corner portion.
A rechargeable battery is a battery that repeatedly performs charging and discharging, unlike a primary battery. A small-capacity rechargeable battery may be used in a portable small electronic device, e.g., a mobile phone, a laptop computer, or a camcorder, and a large-capacity rechargeable battery may be used as a power source for driving motors of, e.g., a hybrid vehicle and an electric vehicle.
For example, the rechargeable battery may include an electrode assembly for charging and discharging, a pouch for accommodating the electrode assembly, and an electrode terminal electrically connected to the electrode assembly to draw the electrode assembly out to the outside of the pouch. For example, the electrode assembly may be a winding type, in which a negative electrode plate and a positive electrode plate are wound on both sides of a separator interposed therebetween, and a stacking type, in which a negative electrode plate and a positive electrode plate are stacked on both sides of a separator interposed therebetween.
A device for forming a pouch of a rechargeable battery according to an embodiment of the present disclosure may include a die that supports a first surface of a substrate of the pouch for the rechargeable battery and forms a first opening so that the substrate of the pouch is formed after the substrate of the pouch is reversely formed; a stripper that holds a second surface of the substrate of the pouch supported by the die and forms a second opening larger than the first opening; a reverse punch that ascends through the first opening at a side of the first surface of the substrate of the pouch to reversely form the substrate of the pouch and performs primary stretching for a side wall corner portion of the pouch and a portion corresponding to a bottom connected to the side wall corner portion; and a punch that descends through the second opening at a side of the second surface of the substrate of the pouch from an opposite side of the reverse punch to form the substrate of the pouch and supplements a thickness of the side wall corner portion of the pouch and a thickness of the bottom connected to the side wall corner portion when secondary stretching is performed by absorbing the primary stretching.
In a diagonal cross-section of the substrate of the pouch corresponding to the side wall corner portion of the pouch and the bottom connected to the side wall corner portion, a length of the reverse punch may be 70 to 90% of a length of the punch.
A depth of reverse forming of the substrate of the pouch may be 3.5 mm to 5.5 mm.
The reverse punch may primarily form a reverse forming portion of the substrate of the pouch having a reverse direction depth within the second opening.
The punch may secondarily form a forming portion of the substrate of the pouch having a forward direction depth within the first opening while absorbing the reverse forming portion.
The reverse punch may form a reverse forming portion at the side wall corner portion of the pouch and the portion corresponding to the bottom connected to the side wall corner portion in the substrate of the pouch, and the reverse forming portion may include an outer flange region provided at an outer periphery of the substrate of the pouch, a central region minimally stretched from a center of the substrate of the pouch, an outer bending region bent and stretched due to reverse forming of the substrate of the pouch in the outer flange region, and a first reverse stretching region, a second reverse stretching region, and a third reverse stretching region sequentially stretched in a reverse direction between the outer bending region and the central region.
The reverse punch may reversely form a reverse direction depth of the reverse forming portion to 3.5 mm to 5.5 mm with respect to the outer flange region as a reference plane, and may stretch the first reverse stretching region, the second reverse stretching region, and the third reverse stretching region by 4 μm to 5 μm.
The reverse punch may maximally stretch the first reverse stretching region, the second reverse stretching region, and the third reverse stretching region at the reverse forming portion.
The reverse punch may form the reverse forming portion, and a thickness of a section between the outer bending region and the first reverse stretching region may decrease at a first change rate, a thickness of a section between the first reverse stretching region and the second reverse stretching region may decrease at a second change rate smaller than the first change rate, a thickness of a section between the second reverse stretching region and the third reverse stretching region may increase inversely to the second change rate, and a thickness of a section between the third reverse stretching region and the central region may increase at a third change rate.
A rechargeable battery according to an embodiment of the present disclosure includes: a pouch that includes an outer flange disposed at an outer periphery thereof and a forming portion formed by forming with respect to a reverse forming portion; and a stacking type of electrode assembly included in the pouch, and the forming portion includes a side wall corner portion connected to the outer flange and a bottom connected to the side wall corner portion, while the bottom includes a round portion connected to the side wall corner portion and a main bottom formed by absorbing the reverse forming portion formed during reverse forming of the pouch.
In a diagonal direction of the main bottom, a forming length of the forming portion formed during the forming may be longer than a reverse forming length of the reverse forming portion.
The reverse forming length may be 70 to 90% of the forming length.
The reverse forming portion may include an outer flange region, an outer bending region, a first reverse stretching region, a second reverse stretching region, a third reverse stretching region, and a central region sequentially formed from outer peripheries of the side wall corner portion of the pouch and a portion corresponding to the bottom connected to the side wall corner portion in a substrate of the pouch to centers of the side wall corner portion of the pouch and the portion corresponding to the bottom connected to the side wall corner portion, and the side wall corner portion of the forming portion may be formed of a portion excluding the outer flange at the outer flange region.
The round portion may be formed by stretching the outer bending region to be connected to the side wall corner portion, and the main bottom may be formed by absorbing the first reverse stretching region, the second reverse stretching region, the third reverse stretching region, and the central region.
A height of the side wall corner portion may be 3.5 mm to 5.5 mm, and a thickness of the pouch may be 76 μm to 85 μm.
A height of the side wall corner portion may be 3.5 mm to 4.5 mm, and when a thickness of the pouch is 76 μm, a thickness of the round portion may be 15.82 μm to 16.92 μm.
A height of the side wall corner portion may be 4.0 mm to 5.0 mm, and when a thickness of the pouch is 85 μm, a thickness of the round portion may be 16.13 μm to 18.01 μm.
A thickness of the main bottom may gradually increase as the main bottom goes from the round portion to a center of the bottom.
When a thickness of the pouch is 85 μm and a thickness of the side wall corner portion is 21.04 μm to 21.54 μm, a thickness of the round portion may be 20.48 μm to 20.79 μm.
A thickness of the main bottom may be 21.43 μm to 27.62 μm.
Features will become apparent to those of skill in the art by describing in detail exemplary embodiments with reference to the attached drawings, in which:
Example embodiments will now be described more fully hereinafter with reference to the accompanying drawings; however, they may be embodied in different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey exemplary implementations to those skilled in the art.
In the drawing figures, the dimensions of layers and regions may be exaggerated for clarity of illustration. It will also be understood that when a layer or element is referred to as being “on” another layer or substrate, it can be directly on the other layer or substrate, or intervening layers may also be present. In addition, it will also be understood that when a layer is referred to as being “between” two layers, it can be the only layer between the two layers, or one or more intervening layers may also be present. Like reference numerals refer to like elements throughout.
As illustrated in
The die 10 may support a first surface S1 (i.e., first face) of a pouch substrate S (i.e., a basic material or a material) of the pouch for the rechargeable battery, and may form the first opening 11 so that the pouch is formed (or shaped) by reversely forming the pouch substrate S and then forming (or forwardly forming) the pouch. For example, as illustrated in
As illustrated in
As further illustrated in
When the length L1 of the reverse punch 30 is less than 70% of the length L2 of the punch 40, a distance between the reverse punch 30 and an inner surface of the second opening 21 of the stripper 20 is too large, so that an effect of reverse forming is lowered. When the length L1 of the reverse punch 30 exceeds 90% of the length L2 of the punch 40, the distance between the reverse punch 30 and the inner surface of the second opening 21 of the stripper 20 may be too small, so a distance between the reverse punch and a stretching object for the reverse forming may be too short, thereby increasing a potential for damaging the pouch substrate S during the reverse forming.
A depth D of the reverse forming formed by the reverse forming portion 50, i.e., a vertical distance that the reverse punch 30 protrudes into the second opening 21 plus a thickness of the pouch substrate S, may be about 3.5 mm to 5.5 mm. In addition, when the depth D of the reverse forming is less than 3.5 mm, the effect of the reverse forming is reduced. When the depth D of the reverse forming is greater than 5.5 mm, the pouch substrate S may be damaged due to excessive reverse forming.
For example, a thickness of the pouch substrate S is about 76 μm to 85 μm, and a height of a side wall of the pouch is 3.5 mm to 5.5 mm. The depth of the reverse forming may be changed according to the height of the sidewall of the pouch by the forming and the thickness of the pouch substrate S.
As described above, the reverse punch 30 may primarily form (or shape) the reverse forming portion 50 of the pouch substrate S having a reverse direction depth within the second opening 21. The reverse direction depth means the depth D of the reverse forming.
The reverse punch 30 forms the reverse forming portion 50 at portion to be a side wall corner portion 62 of the pouch 100 of
The reverse forming portion 50 is formed at a portion other than a portion corresponding to the corner portion 62 and the bottom 63 connected to the corner portion 62, but a first corner {circle around (1)}, a second corner {circle around (2)}, a third corner {circle around (3)}, and a fourth corner {circle around (4)} forming the corner portion 62 of the pouch and the round portion 631 of the pouch connected to the corner portion 62 that are portions where it is substantially most difficult to secure a thickness, will be mainly described.
In the second corner {circle around (2)}, the reverse forming portion 50 includes an outer flange region {circle around (a)} provided at an outer periphery of the pouch substrate S, a central region {circle around (f)} minimally stretched from a center of the pouch substrate S, an outer bending region {circle around (b)} bent and stretched due to the reverse forming in the outer flange region {circle around (a)}, and a first reverse stretching region {circle around (c)}, a second reverse stretching region {circle around (d)}, and a third reverse stretching region {circle around (e)} sequentially stretched in a reverse direction between the outer bending region {circle around (b)} and the central region {circle around (f)}. Primary stretching of the first corner {circle around (1)}, the second corner {circle around (2)}, the third corner {circle around (3)}, and the fourth corner {circle around (4)} mainly occurs at the first reverse stretching region {circle around (c)}, the second reverse stretching region {circle around (d)}, and the third reverse stretching region {circle around (e)}. For example, as illustrated in
The reverse punch 30 reversely forms the reverse direction depth D of the reverse forming portion 50 to 3.5 mm to 5.5 mm with respect to the outer flange region {circle around (a)} as a reference plane, and may stretch the first reverse stretching region {circle around (c)}, the second reverse stretching region {circle around (d)}, and the third reverse stretching region {circle around (e)} by about 4 μm to 5 μm. The reverse punch 30 maximally stretches the first reverse stretching region {circle around (c)}, the second reverse stretching region {circle around (d)}, and the third reverse stretching region {circle around (e)} at the reverse forming portion 50.
The reverse punch 30 forms the reverse forming portion 50. A thickness of a section between the outer bending region {circle around (b)} and the first reverse stretching region {circle around (c)} decreases at a first change rate. A thickness of a section between the first reverse stretching region {circle around (c)} and the second reverse stretching region {circle around (d)} decreases at a second change rate smaller than the first change rate. A thickness of a section between the second reverse stretching region {circle around (d)} and the third reverse stretching region {circle around (e)} generally increases inversely to the second change rate. A thickness of a section between the third reverse stretching region {circle around (e)} and the central region {circle around (f)} increases at a third change rate. The first reverse stretching region {circle around (c)}, the second reverse stretching region {circle around (d)}, and the third reverse stretching region {circle around (e)} by the primary stretching have generally similar thicknesses.
The forming portion 60 includes the side wall corner portion 62 connected to an outer flange 61 and the bottom 63 connected to the side wall corner portion 62, e.g., so the side wall corner portion 62 may be connected between the outer flange 61 and the bottom 63. The bottom 63 includes the round portion 631 ({circle around (b)}) connected to the side wall corner portion 62, and the main bottom portion 632 formed by absorbing the reverse forming portion 50 formed during the reverse forming.
In a diagonal direction of the main bottom portion 632, a forming length (L2) of the forming portion 60 formed during the forming is longer than a reverse forming length (L1) of the reverse forming portion 50 (L2>L1). The reverse forming length (L1) may be about 70% to 90% of the forming length (L2) (i.e., L1=(0.7 to 0.9)*L2), as discussed previously. The reverse forming length L1 is the ‘diagonal length’ of the reverse forming portion 50, and the forming length L2 is the ‘diagonal length’ of the forming portion 60.
The reverse forming portion 50 includes the outer flange region @, the outer bending region {circle around (b)}, the first reverse stretching region {circle around (c)}, the second reverse stretching region {circle around (d)}, the third reverse stretching region {circle around (e)}, and the central region {circle around (f)} sequentially formed from outer peripheries of the side wall corner portion 62 of the pouch 100 and the portion corresponding to the bottom 63 connected to the side wall corner portion 62 in the pouch substrate S to centers of the side wall corner portion 62 of the pouch 100 and the portion corresponding to the bottom 63 connected to the side wall corner portion 62.
The side wall corner portion 62 of the forming portion 60 is formed of a portion excluding the outer flange 61 at the outer flange region {circle around (a)}. The round portion 631({circle around (b)}) of the pouch 100 is formed by stretching the outer bending region {circle around (b)} to be connected to the side wall corner portion 62. The main bottom portion 632 of the pouch 100 is formed by absorbing the first reverse stretching region {circle around (c)}, the second reverse stretching region {circle around (d)}, the third reverse stretching region {circle around (e)}, and the central region {circle around (f)}. In the bottom 63, a thickness of the main bottom portion 632 gradually increases as the main bottom portion 632 goes from the round portion 631 to a center of the bottom 63.
As an example, a height of the side wall corner portion 62 ({circle around (a)}) may be about 3.5 mm to 5.5 mm, and a thickness of the pouch 100 may be about 76 μm to 85 μm.
As shown in Table 2, when a thickness of the pouch 100 is 76 μm, a height of the side wall corner portion 62 ({circle around (a)}), i.e., a forming depth, is 3.5 mm to 4.5 mm, and a thickness of the round portion 631 ({circle around (b)}), in structures according to example embodiments, is 15.82 μm to 16.92 μm. It is seen in Table 2 that a thickness of the round portion 631 ({circle around (b)}), in structures according to example embodiments to which the reverse forming is applied, is secured to be thicker as compared with comparative examples, i.e., structures to which the reverse forming is not applied.
As shown in Table 3, when a thickness of the pouch 100 is 85 μm, a height of the side wall corner portion 62 ({circle around (a)}), i.e., a forming depth, may be 4.0 mm to 5.0 mm, and a thickness of the round portion 631 ({circle around (b)}), in structures according to example embodiments, may be about 16 μm to 19 μm, e.g., 16.13 μm to 18.01 μm. It is seen in Table 3 that a thickness of the round portion 631 ({circle around (b)}), in structures according to example embodiments to which the reverse forming is applied, is secured to be thicker, as compared with the comparative examples (to which the reverse forming is not applied) and in which a thickness of the round portion 631 ({circle around (b)}) is 15 μm to 18 μm, e.g., 15.34 μm to 17.39 μm.
As shown in Table 4, when a thickness of the pouch 100 in Example Embodiments 1 and 2 is 85 μm, a thickness of the side wall corner portion 62 ({circle around (a)}), i.e., a forming depth, may be 21 μm to 22 μm, e.g., 21.04 μm to 21.54 μm, and a thickness of the round portion 631({circle around (b)}) may be 20 μm to 21 μm, e.g., 20.48 μm to 20.79 μm. In contrast, in Comparative Examples 1 and 2, to which the reverse forming is not applied, a thickness of the side wall corner portion may be 19 μm to 20 μm, e.g., 19.48 μm to 19.89 μm, and a thickness of the round portion may be 18 μm to 19 μm, e.g., 18.04 μm to 18.41 μm.
Therefore, it may be seen that a thickness of the side wall corner portion 62 ({circle around (a)}) and a thickness of the round portion 631 ({circle around (b)}) are secured to be thicker in Embodiments 1 and 2 to (which the reverse forming is applied), as compared with Comparative Examples 1 and 2. It may be seen that a thickness of the main bottom portion 632 is secured to be thinner in Embodiments 1 and 2 compared with Comparative Examples 1 and 2.
The pouch 100 is manufactured through the reverse forming and the forming of the pouch substrate S, as shown in
The electrode assembly 200 may include a separator 103, and a first electrode plate 101 and a second electrode plate 102 formed of sheets at opposite, e.g., both, surfaces of the separator 103. That is, the electrode assembly 200 has a structure in which the first electrode plate 101 and the second electrode plate 102 are disposed at both surfaces of the separator 103 that is repeatedly disposed.
As an example, the first electrode plate 101 may be a positive electrode plate, and may include a positive electrode active material layer 112 at both surfaces of an electrode current collecting plate 111. The electrode current collecting plate 111 may include an electrode tab 113 with an uncoated portion protruding to one side. The electrode tab 113 may be directly drawn out of the pouch 100 or may be connected to a lead tab to be drawn out of the pouch 100.
The second electrode plate 102 may be a negative electrode plate, and may include a negative electrode active material layer 122 at opposite, e.g., both, surfaces of an electrode current collecting plate 121. The electrode current collecting plate 121 may include an electrode tab 123 with an uncoated portion protruding to one side. The electrode tab 123 may be directly drawn out of the pouch 100 or may be connected to a lead tab to be drawn out of the pouch 100.
In the rechargeable battery according to the embodiment, even when the stacking type of electrode assembly 200 is embedded in the pouch 100 formed by the reverse forming and the forming, a thickness of the side wall corner portion 62 and a thickness of the round portion 631 are stably secured.
For example, the pouch substrate S forming the pouch 100 and the cover 110 may be formed including a polymer sheet 201 forming an inner surface and acting as electrical insulation and thermal bonding, a nylon sheet 202 that forms an outer surface and acts as protection, and an aluminum sheet 203 providing mechanical strength. The aluminum sheet 203 may be a portion that contributes to securing thicknesses of the side wall corner portion 62 and the round portion 631 by the forming after the reverse forming of the pouch substrate S.
By way of summation and review, the pouch of the rechargeable battery accommodating the winding type electrode assembly may accommodate the electrode assembly even if a corner portion of the pouch is shaped (or formed) into a relatively large round shape. However, the pouch of the rechargeable battery accommodating the stacking type electrode assembly may require that a corner portion of the pouch be shaped into a smaller round shape than that of the pouch accommodating the winding type electrode assembly.
Implementation of the stacking type electrode assembly may be desirable due to an increase in a capacity of the rechargeable battery and a decrease in a thickness of a smartphone. However, when a pouch is formed for the stacking type electrode assembly, e.g., by deep drawing with a punch, securing a thickness at the corner portion of the pouch may be insufficient, thereby increasing a structural weakness of the pouch and reducing safety of the electrode assembly.
In contrast, the present disclosure provides a rechargeable battery that stably secures a thickness of a side wall corner portion of a pouch and a thickness of a bottom of the pouch connected to the side wall corner portion, even when a stack type of electrode assembly is implemented. That is, the pouch for the electrode assembly may be formed by deep drawing in which a substrate of the pouch is reversely formed with a reverse punch and then is formed with a punch (i.e., by a two-step process requiring a reverse punch prior to the punch).
In other words, as described above, an embodiment of the present disclosure may secure a sufficient thickness of a side wall corner portion of a pouch and a sufficient thickness of a (main) bottom of the pouch connected to the (round) side wall corner portion, even when a stack type of electrode assembly is implemented, since the pouch is formed (i.e., shaped) by deep drawing in which a substrate of the pouch is reversely formed with a reverse punch, followed by a punch.
Example embodiments have been disclosed herein, and although specific terms are employed, they are used and are to be interpreted in a generic and descriptive sense only and not for purpose of limitation. In some instances, as would be apparent to one of ordinary skill in the art as of the filing of the present application, features, characteristics, and/or elements described in connection with a particular embodiment may be used singly or in combination with features, characteristics, and/or elements described in connection with other embodiments unless otherwise specifically indicated. Accordingly, it will be understood by those of skill in the art that various changes in form and details may be made without departing from the spirit and scope of the present invention as set forth in the following claims.
Number | Date | Country | Kind |
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10-2022-0187881 | Dec 2022 | KR | national |