RECORDING MEDIUM AND METHOD FOR PRODUCING RECORDED MATTER HAVING THREE-DIMENSIONAL IMAGE

Information

  • Patent Application
  • 20230294129
  • Publication Number
    20230294129
  • Date Filed
    March 13, 2023
    a year ago
  • Date Published
    September 21, 2023
    a year ago
Abstract
A recording medium for producing a recorded matter having a three-dimensional image comprises: a substrate; and a foaming layer being provided on the substrate and containing a foaming material which foams with heat and a binder resin. A contact angle of water to a surface of the foaming layer 30 seconds after the water is brought into contact with the surface of the foaming layer is 30° or more and 80° or less, and a ratio of a diameter of a water droplet 30 seconds after the water is brought into contact with the surface of the foaming layer to a diameter of the water droplet 0.01 seconds after the water is brought into contact with the surface of the foaming layer is 1.3 times or less.
Description
Claims
  • 1. A recording medium comprising: a substrate; anda foaming layer being provided on the substrate and containing a foaming material which foams with heat and a binder resin, whereina contact angle of water to a surface of the foaming layer 30 seconds after the water is brought into contact with the surface of the foaming layer is 30° or more and 80° or less, anda ratio of a diameter of a water droplet 30 seconds after the water is brought into contact with the surface of the foaming layer to a diameter of the water droplet 0.01 seconds after the water is brought into contact with the surface of the foaming layer is 1.3 times or less.
  • 2. The recording medium according to claim 1, wherein the foaming material is a foaming particle including: a shell layer containing a thermoplastic resin; and a volatile material encapsulated in the shell layer.
  • 3. The recording medium according to claim 2, wherein the thermoplastic resin is polyacrylonitrile, andthe volatile material is isobutane.
  • 4. The recording medium according to claim 1, wherein the binder resin is at least one selected from the group consisting of acrylic resins, urethane resins, and polyacrylonitrile resins.
  • 5. The recording medium according to claim 1, wherein a glass transition temperature of the binder resin is lower than a foaming start temperature of the foaming material by 70° C. or more.
  • 6. The recording medium according to claim 1, wherein a foaming start temperature of the foaming material is 80° C. or more and 100° C. or less.
  • 7. The recording medium according to claim 1, wherein a glass transition temperature of the binder resin is -10° C. or more and 10° C. or less.
  • 8. The recording medium according to claim 1, wherein an arithmetic average roughness Ra of the surface of the foaming layer is 1.0 µm or more.
  • 9. The recording medium according to claim 1, wherein a Martens hardness of the foaming layer is 15 N/mm2 or less.
  • 10. The recording medium according to claim 1, wherein a creep CIT1 of the foaming layer after an increase in load as measured under the following conditions is 25 or more and 70 or less.Indentation force F: 3.0 µm/20 sCreep time C: 20.0 s.
  • 11. The recording medium according to claim 1, wherein the contact angle of water to a surface of the foaming layer 30 seconds after the water is brought into contact with the surface of the foaming layer is 30° or more and 75° or less.
  • 12. A method for producing a recorded matter having a three-dimensional image, comprising the steps of: adding, to a recording medium including a substrate and a foaming layer being provided on the substrate and containing a foaming material which foams with heat and a binder resin, a foam-promoting liquid containing a foam-promoting component which reduces a foaming start temperature of the foaming material and water; andheating the foaming layer of the recording medium to which the foam-promoting liquid is added to cause the foaming material to foam, forming a three-dimensional image, whereina contact angle of water to a surface of the foaming layer 30 seconds after the water is brought into contact with the surface of the foaming layer is 30° or more and 80° or less, anda ratio of a diameter of a water droplet 30 seconds after the water is brought into contact with the surface of the foaming layer to a diameter of the water droplet 0.01 seconds after the water is brought into contact with the surface of the foaming layer is 1.3 times or less.
  • 13. The method for producing a recorded matter having a three-dimensional image according to claim 12, wherein the foam-promoting component is at least one selected from the group consisting of 2-pyrrolidone, dimethyl sulfoxide, N,N-dimethylformamide, and N-methyl-2-pyrrolidone.
  • 14. The method for producing a recorded matter having a three-dimensional image according to claim 12, wherein the foam-promoting liquid is an aqueous foam-promoting liquid containing water.
  • 15. The method for producing a recorded matter having a three-dimensional image according to claim 12, wherein the contact angle of water to a surface of the foaming layer 30 seconds after the water is brought into contact with the surface of the foaming layer is 30° or more and 75° or less.
Priority Claims (2)
Number Date Country Kind
2022-041599 Mar 2022 JP national
2023-037212 Mar 2023 JP national