Patent Grant
10392753
The invention relates to soft-magnetic microwires for use in a recording medium, which enables the presence of the recording medium to be detected in an EAS (Electronic Article Surveillance) system.
Heretofore, various kinds of paper containing soft-magnetic microwires (tag) have been studied for the prevention of forgery, security for highly confidential information, and other purposes.
The related-art technology for the paper mentioned is overviewed. U.S. Pat. No. 7,301,324 describes a recording medium detecting system including a magnetic field-generating unit that generates an alternating magnetic field in a predetermined particular region, a detecting unit provided close to the particular region for detecting a change in magnetic flux, and a recording medium, that is detectable by the detecting unit when placed in the particular region. The recording medium may be a two-layered or three-layered structure containing magnetic wires. In the two-layer structure, the magnetic wires are placed on one face of a substrate previously prepared and laminating another substrate hereon. In the three-layered structure a single-layered substrate (or wet paper) containing dispersed wires is sandwiched between two substrates (or wet paper) containing no wires. According to this technique, a plurality (eighteen) of 25 mm-long magnetic wires are dispersed uniformly over a whole sheet of wet paper. The wire has a diameter of 30 μm and a coercive force of less than 70 A/m.
Further, WO14185686 and KR101341164 describe a recording medium for security, including a detection base layer containing a material for detection and having a printable base integrated with the material for detection; and a shielding layer formed on both sides of the detection base layer so as to shield the material for detection. Here, the material for detection can be a soft magnetic material having a residual magnetic flux density of 0.1 T or more, a coercive force of 1 to 50 A/m and a magnetic permeability of 500 to 100,000H/m, when the frequency is 10 kHz.
There is a need in the art for a novel recording medium utilizing soft magnetic microwires for use in EAS systems. The term “recording medium” used herein refers to a structure/substrate to be printed on (e.g. a sheet of paper) by any suitable printing process such ink-jet printing, digital printing, etc.
For the EAS detection of an object carrying magnetic wires, the number and the distribution of the magnetic wires are important factors to provide sufficiently strong detection signals. Considering the use of magnetic wires to protect a recording medium, in order to enable better printing on the recording medium, the number and the distribution of microwires are important factors to provide a flat surface of the recording medium to be printed thereon. Furthermore, the number and the distribution of microwires in are closely connected with the medium (paper) production process.
The present invention is aimed at providing a security recording medium enabling successful detection by commercially available EM (Electromagnetic) gate systems. More specifically, the present invention is aimed at providing a security paper (exemplifying a recording medium) and is therefore described below with respect to this specific application.
Thus, according to one aspect of the invention, it provides a recording medium, comprising: a pulp structure formed by pulp fibers, said pulp structure carrying glass-coated microwires; at least one coating layer on at least one side of said pulp structure; wherein said pulp structure is a single-layer structure with said glass-coated microwires fully embedded in said single layer, the microwires having cross-sectional dimensions approximately equal to cross-sectional dimensions of the pulp fibers.
The microwire is configured as a soft-magnetic element, having a metal core of a predetermined material composition, and an insulating (e.g. glass) coating on said metal core. The magnetic microwire has a magnetic coercive force of 60 A/m or less (even preferably less than 20 A/m, or even less than 15 A/m), and has a large Barkhausen jump (discontinuity). The material composition of the metal core has nearly zero or negative magnetostriction.
Preferably, the material composition of the metal core is Co—Fe—Si—B—Cr alloy. Preferably, the Co—Fe—Si—B—Cr alloy contains 67.7% Co, 4.3% Fe, 11% Si, 14% B, and 3% Cr by atomic percentage.
Preferably, the length of microwire does not exceed or even preferably is less than 10 mm, being preferably 4-7.5 mm. The diameter of metal core is preferably in a range of 5-15 μm. The thickness of insulating coating preferably does not exceed and even preferably is less than 3 μm, is preferably in a range of 1-1.5 μm.
The microwires with the above dimensions can be properly distributed over the entire pulp layer (entire recording medium), i.e. uniformly distributed within a plane defined by the pulp layer being entirely embedded thereinside (i.e. without projecting from or exposed to the outside of the pulp layer). Also, the above microwires provide for proper orientation thereof, i.e. quazi-random orientation with respect to the longitudinal axis of the recording medium. Such distribution and orientation of the microwires of given dimensions allow for increasing the density of microwires in the pulp layer. These features provides for improving of the detectability of the microwires.
For example, the microwires fully embedded in the single-layer pulp structure are arranged with a density of microwires higher than 1.0 per square centimeter, or higher than 2.0 per square centimeter, or even higher than 3.0 per square centimeter.
As indicated above, the microwires fully embedded in said single-layer pulp structure are arranged with quazi-random orientation. Preferably, they are arranged with about 10 degrees variation of an angle of orientation of the microwires (their longitudinal axis).
The recording medium may be a paper configured for printing data thereon.
According to another broad aspect of the invention, it provides a soft-magnetic microwire having a metal core of a predetermined material composition, and an insulating coating on said metal core, wherein the metal core is Co—Fe—Si—B—Cr alloy having a magnetic coercive force less than 60 A/m, a large Barkhausen jump, and nearly zero or negative magnetostriction.
Preferably, the length of microwire does not exceed, or even preferably is less than 10 mm, being preferably 4-7.5 mm. The diameter of metal core is preferably in a range of 5-15 μm. The thickness of insulating coating preferably does not exceed and even preferably is less than 3 μm, is preferably in a range of 1-1.5 μm.
According to yet another aspect of the invention, it provides a method of manufacturing the above-described paper serving as recording medium, the method comprising:
proving a plurality of microwires, each microwire having a metal core of a predetermined material composition, and a glass coating on said metal core, wherein a diameter of the metal core substantially does not exceed 15 μm and a thickness of the glass coating substantially does not exceed 3 μm, and the material composition of the metal core is a soft-magnetic amorphous metal alloy with large Barkhausen effect, a magnetic coercive force of less than 20 A/m, and nearly zero or negative magnetostriction;
preparing a paper web on top of a fiber mesh, and distributing the microwires in the paper web;
applying water reduction treatment to said paper web, causing a water flow through and out of the paper web, thereby dispersing the microwires and forming a single-layer pulp structure with the microwires fully embedded therein such that the microwires are arranged with substantially uniform distribution within the pulp layer, and quazi-random orientation with about 10 degrees variation of an angle of orientation of the microwires.
In order to better understand the subject matter that is disclosed herein and to exemplify how it may be carried out in practice, embodiments will now be described, by way of non-limiting example only, with reference to the accompanying drawings, in which:
As described above, the present invention provides a novel configuration of a recording medium (paper) secured by an arrangement (tag) of magnetic microwires, as well as the microwire structure, and a method of mass production of such recording medium.
Referring to
The recording medium 10 may be used for electro-photographic printing. Electro-photographic printing is completed by fusing a toner image on a surface 15 of the recoding medium by a rubber roll. Therefore, the printing surface 15 of the recording medium should preferably be sufficiently smooth; otherwise, i.e. if the microwires partially project from the printing surface, this will damage a surface of fuser roll. Thus, the microwires 14 should preferably be fully embedded in the pulp layer 12.
As further shown in
Referring to
In the structure of
Such thicker medium unavoidably causes defusing due to an increase of heat mass because the pulp layer mostly contributes to the heat mass. Further, in the area/region where the microwires are exposed, the toner is hardly fused because the melted toner fails to diffuse between the pulp fibers. Also, in the structure of
In the configuration of
As indicated above, partial embedding of the microwires in the recording medium impedes and practically makes it impossible to obtain high-quality printing on the surface of the recoding medium.
As also shown in the figures, the recording medium 10 of the present invention (
It should be understood that, generally, the simpler the structure of a recording medium (paper), the simpler and cheaper the paper fabrication is.
To make two-layer structure of an active part of the recording medium of the kind described above, a lower pulp layer (12B) is first prepared, then microwires are dispersed on it, and covered by an upper pulp layer (12A). Such process is described for example in JP4529420.
Further, the known recording mediums described above utilize microwires with larger diameters (about 40 μm versus 5-15 μm in the medium of the present invention). Each such larger-diameter piece of microwire is relatively heavy, and accordingly dispersion is difficult to proceed. Most of such relatively heavy microwires are sunk at the bottom of a wire-dispersion tank. The yield of the microwire inclusion into the medium is very low. Furthermore, longer microwires tangle in a wire-dispersion tank, which makes the dispersion difficult. Due to relatively large mass of microwires, the wire is buried at the lower part of lower pulp layer. Sometimes, some of microwires are exposed at the surface of medium after size press.
The above-described recording medium 10 of the invention shown in
The improvement of security is in that it is harder to see the microwires, i.e. microwires are practically not exposed to viewer at all. This means people are less likely to pull and/or the microwires out from the medium.
The following is the description of the possible configuration of the soft-magnetic microwire 14 of the invention. The soft-magnetic microwire 14 of an exemplary embodiment of the invention for use in a recording medium is capable of emitting large Barkhausen signals, which are caused by magnetization reversal, detectable with an EAS detector (typically, incorporated in a gate assembly). The microwire structure includes a soft-magnetic metal core coated with an insulating material, like a glass.
Glass coated microwires with amorphous metal cores have been developed and are described disclosed with a U.S. Pat. No. 6,441,737, incorporated herein by reference. The inventor of the present application is a co-inventor in U.S. Pat. No. 6,441,737. The material for the metal core is a cobalt-base alloy. For example, Co—Fe—Si—B alloy (e.g., containing 77.5% Co, 4.5% Fe, 12% Si, and 6% B by atomic percentage), Co—Fe—Si—B—Cr alloy (e.g., containing 68.7% Co, 3.8% Fe, 12.3% Si, 11.4% B, and 3.8% Cr by atomic percentage), or Co—Fe—Si—B—Cr—Mo alloy (e.g., containing 68.6% Co, 4.2% Fe, 12.6% Si, 11% B, 3.52% Cr and 0.08% Mo by atomic percentage) may be used.
As described below, it is desired that the soft-magnetic metal core has nearly zero or negative magnetostriction. The inventors of the present invention have found that, for the purposes of paper-like recording medium production, if the metal core in soft-magnetic microwires has positive magnetostriction, the large Barkhausen signal will be reduced or at worst diminished by the mechanical stress induced by the paper production process. The stress is typically applied after the paper production. For example, the pulp fiber elongates due to moisture and shrinks due to drying. The microwires are under such a stress in the pulp layer. On the other hand, when the soft-magnetic metal core has nearly zero or negative magnetostriction, the large Barkhausen signal will be more stable under stress applied on the microwires.
By controlling the alloy component, nearly zero or negative magnetostriction can be achieved. For example, while Co—Fe—Si—B—Cr alloy containing 67% Co, 5% Fe, 11% Si, 14% B, and 3% Cr by atomic percentage shows positive magnetostriction, Co—Fe—Si—B—Cr alloy containing 67.7% Co, 4.3% Fe, 11% Si, 14% B, and 3% Cr by atomic percentage shows nearly zero magnetostriction.
The diameter of the metal core in microwires of the current invention, which is especially useful for security paper, can be in a range of 5-15 μm. The thickness of insulating material (e.g. glass) substantially does not exceed and is preferably less than 2 μm, preferably about 1.5 μm. This is because thicker (more than 3 μm thick) glass coating is practically fragile to mechanical stress applied during paper production and also paper handling in the printing and/or copying machine like an electro-photographic printer. When glass is broken in the paper production machine and/or the printing machine, glass particles contaminate inside the parts of the machine, which may increase machine maintenance cost due to the shortened cleaning cycle. The present invention provides for using thinner glass coating which makes the microwire more flexible, and thus preventing the glass breaking effects.
The glass-coated microwire may be fabricated using the continuous Taylor-Ulitovsky method, which is disclosed in U.S. Pat. No. 8,978,415, and then cut into pieces with the lengths of about 10 mm or less, preferably 4 mm to 7.5 mm.
The following is the description of an example of the manufacturing process for manufacturing the recording medium of the present invention.
The manufacturing process utilizes well-known paper making techniques used for paper production for making graphic paper (i. e., paper suitable for office and printing) today. The main stages of such process are known per se and do not form part of the invention, and therefore need not be specifically described.
The microwires of desired dimensions (metal core diameter and length) are prepared using the above-mentioned Taylor-Ulitovsky continuous method and cutting into pieces (step 102). The paper web is separately prepared (step 104) using the known technique. Briefly, pulpwood arrives at a paper mill in the form of very thick sheets and recovered paper normally arrives in the form of large, compressed bales. Both these materials have to be broken down so that the individual fibers they contain are completely separated from each other. This process is performed in large vessels, known as ‘pulpers’, where the raw materials are diluted with water and then subjected to violent mechanical action using steel rotor blades. The resulting papermaking stock is then passed to holding tanks. During this preliminary stage, auxiliary chemicals and additives may be added. The auxiliary chemicals are usually combined with the fibrous raw materials and can be sizing agents, which reduce ink and water penetration, and process anti-foaming agents. The stock is then pumped through various types of mechanical cleaning equipment to the paper machine. On the paper machine, more water is added to produce a fiber suspension and the resulting mixture is passed into a head-box which squirts it through a thin, horizontal slit across the full machine width on to a moving, endless wire mesh.
Then, a water reduction treatment is applied (sheet formation process), during which the microwires are dispersed in the pulp layer (step 106). During the water removal, the fibers start to spread and consolidate into a thin mat, forming a layer of paper on top of the wire mesh. This web of wet paper is then lifted from the wire mesh and squeezed between a series of presses where its water content is lowered to about 50%. It then passes around a series of cast-iron cylinders, heated to temperatures in excess of 100° C., where drying takes place. Here, the water content is lowered to its final level (to between 5% and 8%). Throughout its passage from the wire mesh to the drying operation, the paper web is supported by various types of endless fabric belts moving at the same speed. After drying, some papers may also undergo surface treatments, e.g. sizing and calendaring—smoothing the surface of the paper by passing it between a series of rotating, polished, metal rollers to produce a glazed or glossy appearance. The paper may then be wound into a reel.
According to the invention, during the above water reduction treatment, the microwires (configured as described above) are distributed uniformly with proper orientation and density in the paper web (step 108). This will be described more specifically further below. The paper web provides a base which fixes the microwires on its smooth and soft surface. When it is size pressed, the microwires are buried (fully embedded) inside the pulp fibers.
Then, coating is applied on both sides of the paper layer (pulp layer) containing microwires (step 110). The pulp layer, when contains microwires embedded therein, presents an active securing layer detectable by a magnetic reader/detector (gate).
The coating has several functions, as follows. It prevents the microwires from being exposed at the surface, from leaving the pulp layer (escaping therefrom), from being identified easily. Also, the coating enables toner or ink to diffuse easily inside during fusing or drying, and enables to provide friction force for paper handling in a copy machine and printer.
Thus, the coating materials are properly selected to provide the above functions. The following is the description of an example of the candidates for coating material composition is described below.
Coating takes place on size press after the paper web is created and partially dried. A coating bath contains mixture of natural binder (starch, PVOH, carboxymethylcellulose) and synthetic latex (styrenebutadien, styreneacrylic, vinylacetate). The ratio of these two compounds may be about (approximately) 10 to 80 parts of natural binder (depending on binder used) and approximately 40 to 70 parts of synthetic latex (expressed as dry weight). The coating bath may also contain other materials, like mineral filler, antistatic agent, whitening agent, dye and other functional chemicals usually used for surface treatment of paper. Total solids content of the coating bath is in a range of about 4 to 20%. Pickup of solids on size press is about 1.5 to 4 gsm per one side of paper.
A final form is paper roll which winds a paper sheet composed of one pulp layer (12 in
For comparison, let us consider the prior art techniques of the kind specified. In the prior art techniques, the blade is deteriorated fast because of thick metal core and thick glass coating of the wires. A resulting short life of blade make the paper production process more expensive, and causes the cutting failure which left the microwires out from the surface of cut cross-section. This is illustrated schematically in
Turning back to
As indicated above, for the proper detection of the microwires embedded in the recording medium, such factors as number of microwires and their distribution in the recording medium. With regard to the number of microwires, it is evident that for a given paper size, the present invention provides for embedding a larger number of microwires since they are thinner than the known ones, thus, for a given thickness of a recording medium, providing a stronger detection signal. The technique of the present invention also provides distribution of the microwires improving the security performance.
In this connection, reference is made to
In this connection, the following should be noted. The microwires are actually dispersed by water flow. In the conventional techniques, most of the microwires, being relatively large and heavy become almost homogeneously oriented. In some cases they are oriented approximately along the X-axis, being that of the water flow direction, or along the axis tilted against the water flow axis but such that the central value is just shifted and the variation in tilt angle is almost the same (i.e. the microwires are almost equally tilted resulting in substantially homogeneous orientation).
The inventors have found that from the security point of view, the directionality of detecting the existence of the microwire should be reduced. This is because large Barkhausen jump happens when the effective magnetic field coincides with the wire direction. Hence, if the directionality is high (homogeneous orientation of microwires), the detection is hardly done for some zones of EAS gates; and if the randomness in the wire orientation (i.e. non-directionality) is high, large Barkhausen jump happens for any zone of EAS gate.
Therefore, the use of the above-described lighter-mass microwires of the present invention provides for increasing the randomness in the microwires orientation (i.e. orientation of their long axes). This results in the higher security performances of the recording medium carrying such microwires. Moreover, the randomness in the microwires orientation also provides for increasing the number of microwires that can be embedded in the paper.
Thus, the present invention provides the microwires of lighter mass (caused by smaller core diameters and shorter lengths), which provides for better dispersion of microwires in water, which results in both, uniform distribution of the microwires and randomness (or quazi-randomness) of their orientation (while with narrower distribution of the tilt angle). The microwire of the present invention, being of about 5-10 μm diameter and about 10 mm length (compared to the prior art one of 30 μm diameter and 25 mm length), has a mass of one order of magnitude smaller than that of the prior art.
The present invention thus advantageously provides improved microwires dispersion which leads to an increase of the number of uniformly distributed and randomly oriented microwires in the recording medium, which causes large Barkhausen signals to be higher. In the case of A4 sheet, more than 1000 pieces of magnetic wires, which equals to the density of more than 1.6 per square centimeter, provide sufficient detection in a commercial EAS electromagnetic gate. If the number of microwires is less than 700, which equals to the density of less than 1.1 per square centimeter, the inventors found that detection failed in some zones of the gate in several detection tests. For a paper sheet larger than A4-size, the density of more than 1.6 per square centimeter should preferably be kept to provide sufficient detection in a commercial EAS electromagnetic gate.
The following are some practical examples for the fabrication of paper with microwires and detection of microwires.
Fabrication of Paper with Microwires
The inventors have manufactured the A4-sized (210 mm×297 mm) test paper samples with the above-described microwires (previously prepared by the above-described method). The samples have the same structure of the paper shown in
The characteristics of 45 types of the test paper are summarized in the following Table 1:
Detection Test
The inventors ran the detection test using two types of a commercial EAS electromagnetic gate. One is Tagit EM (Electromagnetic) System, whose detection mechanism is disclosed in U.S. Pat. No. 6,836,216 assigned to the assignee of the present application and incorporated herein by reference. The configuration and operation of the Gate System (as well as any other suitable detection system) do not form part of the present invention, and therefore need not be described in details. Briefly, the Tagit EM System operates such that in the interrogation zone, an oscillating magnetic field is generated in orthogonal directions like ORTHOGONAL, FLAT, and FRONT direction. When the soft-magnetic material (used in the present invention) passes through the interrogation zone, it interacts with the oscillating magnetic field of the detection system and transmits large-Barkhousen signal to a receiving coil of the detection system.
The other Gate System used in the detection test is Meto EM System, whose detection mechanism is disclosed in U.S. Pat. No. 5,414,410. Generally, in such Gate System, transmitting antennas generate magnetic fields of two or three different frequencies, and the nonlinear response of soft-magnetic marker results in intermodulation products of these frequencies that are detected by the signal processing unit. The magnetic markers are relatively small markers (0.7 mm width and 35 mm typical length). The test paper of Koreit has this type of the marker, so it is easily detected by Meto system.
In the detection tests, the same distance of 75 cm between the gate panels (as used in Tagit EM system) was used for both detection systems.
The paper samples used in the test are the above listed 45 types of paper (Table 1). These paper samples are fabricated by changing the average number of microwires embedded in the pulp layer. The numbers chosen are 2000, 1300, 1100, 850, and 700. The corresponding densities of microwires are 3.2, 2.1, 1.8, 1.4, 1.1 in unit of per square centimeter, respectively. The diameter of soft-magnetic core varied from 7.5 μm to 15 μm, and the length of microwires varied from 5 mm to 10 mm. The thickness of glass coating was 0.5 μm to 2 μm. The magnetic coercive force was 5 to 15 A/m.
For reference, Koreit paper, which is commercially available, was used for the test. The Koreit paper has a two-layered structure, with 2 or 3 amorphous soft magnetic strips of amorphous soft-magnetic metal located between layers, which can be easily detected by Meto EM system. The width of slip is 0.7 mm, the length is 35 mm, and the magnetic coercive force is 5 to 30 A/m.
The test is aimed at checking the detection ability of the gate in the Tagit 2-antenna and Meto 2-antenna EM Systems for the paper being moved with a certain orientation through a certain cell inside the gate. Taking into account the practical use, the moving speed is about the walking speed of an individual.
Before the test, the practical positions which are most frequently-used positions are defined, as shown in
As can be seen, detectability of the secured paper of the present invention (Tagit paper) configured as described above increases with an increase of the density of microwires. The Tagit 1100, whose density of microwires is about 1.8 per square centimeter, has better performance than the prior-art (Koreit paper). On the other hand, Tagit 700 and Tagit 850 paper samples are inferior in detection. A similar behavior was observed for other paper samples containing microwire sets with different diameters of metal core (10 μm, 5 μm) and different lengths of microwire (10 mm, 7.5 mm).
Summarizing the results, the detectability decreases with a decrease of microwire diameter and length D, L and the density of microwires. For example, as shown in
Print Test
The print test was performed for the test paper samples listed in Table 1 and Koreit paper. The used printers were an electro-photographic printer and an ink-jet printer. Printing was made on the both sides. The Tagit paper showed almost the same printing quality as Koreit paper. No curling was observed after optimization of the design of the coating layer.
From the above results, it is evident that the density of microwire should preferably be greater than 1.6 per square centimeter to achieve better detection as compared to the known technique. Furthermore, it is shown that the technique of the present invention provides high quality recording medium with single-layer pulp structure that can be fabricated by the conventional paper production process described before.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/IL2016/050403 | 4/18/2016 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2016/170527 | 10/27/2016 | WO | A |
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| Number | Date | Country | |
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| 20180142423 A1 | May 2018 | US |
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|---|---|---|---|
| 62149845 | Apr 2015 | US |
