This invention relates to heat exchangers in general and in more particular applications, to recuperative heat exchangers which find many uses in industry, including in fuel cell systems.
A recuperative heat exchanger, or recuperator, is used to optimize the overall system efficiency of a high temperature application, such as a gas turbine or a high temperature fuel cell system, by heating a low temperature incoming air stream to a temperature closer to the desired process operating temperature via the transfer of thermal energy from a high temperature process waste stream of exhaust gas or air. Such a heat exchanger allows for the efficient transfer of heat from the hot stream to the cold stream while maintaining isolation of the two streams from each other. In order to simplify the packaging of the recuperator into the system, and in order to reduce the material costs of the device, it is usually desirable to minimize the physical size and weight of the recuperative heat exchanger. It is also typically a principal object of such a heat exchanger to provide for high heat exchanger effectiveness in order to maximize the degree to which the heat is recuperated.
Heat exchanger effectiveness is defined as the ratio between the actual rate at which heat is transferred between the two fluids in a heat exchanger and the maximum possible heat transfer rate. The maximum possible heat transfer rate is achieved when the exit temperature of the fluid with the lower heat capacity is made to be equal to the entering temperature of the other fluid, and can theoretically be achieved in a heat exchanger of infinite length with the fluids passing through it in a counter-flow orientation. For most practical heat exchangers the effectiveness will be less than one.
A cathode recuperator for high temperature fuel cell systems such as, for example, solid oxide fuel cell (SOFC) systems, has some unique performance requirements as compared to recuperators in better-known applications such as, for example, gas turbines. SOFC's are solid-state devices that use an oxide-conducting ceramic electrolyte to produce electrical current by transferring oxygen ions from an oxidizing gas stream at the cathode of the fuel cell to a reducing gas stream at the anode of the fuel cell. This type of fuel cell is seen as especially promising in the area of distributed stationary power generation. SOFC's require an operating temperature range which is the highest of any fuel cell technology, giving it several advantages over other types of fuel cells for these types of applications. The rate at which a fuel cell's electrochemical reactions proceed increases with increasing temperature, resulting in lower activation voltage losses for the SOFC. The SOFC's high operating temperature precludes the need for precious metal catalysts, resulting in substantial material cost reductions. The elevated exit temperature of the flow streams allow for high overall system efficiencies in combined heat and power applications, which are well suited to distributed stationary power generation.
The traditional method of constructing solid oxide fuel cells has been as a large bundle of individual tubular fuel cells. Systems of several hundred kilowatts of power have been successfully constructed using this methodology. However, there are several known disadvantages to the tubular design which severely limit the practicality of its use in the area of 25 kW-100 kW distributed stationary power generation. For example, producing the tubes can require expensive fabrication methods, resulting in achievable costs per kW that are not competitive with currently available alternatives. As another example, the electrical interconnects between tubes can suffer from large ohmic losses, resulting in low volumetric power densities. These disadvantages to the tubular designs have led to the development of planar SOFC designs. The planar designs have been demonstrated to be capable of high volumetric power densities, and their capability of being mass produced using inexpensive fabrication techniques is promising.
As is known in the art, a single planar solid oxide fuel cell (SOFC) consists of a solid electrolyte that has high oxygen ion conductivity, such as yttria stabilized zirconia (YSZ); a cathode material such as strontium-doped lanthanum manganite on one side of the electrolyte, which is in contact with an oxidizing flow stream such as air; an anode material such as a cermet of nickel and YSZ on the opposing side of the electrolyte, which is in contact with a fuel flow stream containing hydrogen, carbon monoxide, a gaseous hydrocarbon, or a combination thereof such as a reformed hydrocarbon fuel; and an electrically conductive interconnect material on the other sides of the anode and cathode. A number of these cells are assembled into a fuel cell stack, with the electrically conductive interconnect material providing both the electrical connection between adjacent cells and the flow paths for the reactant flow streams to contact the anode and cathode. Such cells can be produced by well-established production methodologies such as screen-printing and ceramic tape casting.
It is critical in operation to prevent the anode flow from mixing with the cathode flow, since the cathode flow will act as an oxidizer to combust the fuel in the anode flow, leading to potentially damaging combustion occurring within the fuel cell system. High temperature gas-tight seals are therefore required between the individual fuel cells and the interconnect material in order to prevent such mixing from occurring. In order to meet the requirements of operating at high temperatures, remaining stable in both oxidizing and reducing environments, and other considerations necessary for usage with SOFCs, these seals are typically constructed of cements, glasses, or glass-ceramics.
As is known to those in the art, these types of sealing materials are not capable of withstanding large differential pressures. As a consequence, planar SOFC systems are typically not capable of operation at elevated pressures, as are gas turbines. This has resulted in the need for very low pressure drop, high thermal efficiency recuperative heat exchangers to recover the waste heat from the cathode exhaust in order to preheat the cathode air feed. The power required to pressurize the cathode air is quite often the largest single parasitic power draw of a SOFC system, so minimizing the pressure drop in such a recuperator can provide substantial gains in the overall electrical efficiency of the system, thus potentially providing a critical commercial advantage.
In some embodiments, the invention provides a primary surface annular heat exchanger suitable for use as a recuperator in solid oxide fuel cell systems.
In some embodiments, the invention provides a heat exchanger having a corrugated separator, a barrier and a plurality of flow channels. The corrugated separator has a surface positioned along a heat exchange fluid flow path, opposite ends of the separator having flattened corrugations. The barrier is positioned adjacent the surface. The plurality of flow channels are in the heat exchange fluid flow path and are at least partially defined by the surface and the barrier. The flattened corrugations are secured to the barrier.
The invention also provides a method of making a heat exchanger. The method includes the acts of providing a corrugated separator sheet having corrugations extending in a longitudinal direction, flattening the corrugations into flattened portions positioned at first and second longitudinal ends of the corrugated separator sheet, positioning the corrugated separator sheet adjacent a non-corrugated barrier to create a heat exchange flow path between the corrugated separator sheet and the non-corrugated barrier, and securing the flattened portions to a surface of the non-corrugated barrier.
The invention provides a corrugated separator sheet for a heat exchanger. The corrugated separator sheet can include a plurality of corrugations and a flattened region. The plurality of corrugations extend parallel to one another in a longitudinal direction, and have a plurality of peaks and a plurality of troughs opposite the plurality of peaks. The flattened region is proximate a longitudinal end of the separator sheet and is adjacent the plurality of peaks.
The invention can also provide a primary surface annular heat exchanger that is capable of achieving a high degree of heat exchanger effectiveness with minimal pressure drop and minimal size and weight impact on a system making use of such a heat exchanger.
In some embodiments, the invention provides a method of constructing a primary surface annular heat exchanger to exchange heat between two flowstreams, the method providing reliable sealing of the flowstreams from one another with a minimum number of parts and low overall cost.
In one aspect of the invention, a primary surface annular heat exchanger comprises a corrugated separator sheet with a first surface exposed to a first heat exchanging fluid and a second surface exposed to a second heat exchanging fluid. The first fluid flows through a plurality of flow channels bounded by the first surface of the corrugated separator sheet and a radially inwardly located cylinder. The second fluid flows through a plurality of flow channels bounded by the second surface of the corrugated separator sheet and a radially outwardly located cylinder. Each of the ends of the corrugated separator sheet has the corrugations flattened and bonded to the radially inwardly located cylinder.
In another aspect of the invention, a method is provided for constructing a primary surface annular heat exchanger. The method of making the heat exchanger includes the steps of corrugating a separator sheet and forming it into a corrugated cylinder by joining a first corrugation located at a first edge oriented parallel to the corrugations and a second corrugation located at a second edge oriented parallel to the corrugations. The method of making the heat exchanger may further include the steps of flattening the corrugations at either end of the corrugated cylinder, and bonding the flattened portions of the corrugations to the surface of a non-corrugated cylinder.
Other aspects of the invention will become apparent by consideration of the detailed description and accompanying drawings.
Before any embodiments of the invention are explained in detail, it is to be understood that the invention is not limited in its application to the details of construction and the arrangement of components set forth in the following description or illustrated in the following drawings. The invention is capable of other embodiments and of being practiced or of being carried out in various ways. Also, it is to be understood that the phraseology and terminology used herein is for the purpose of description and should not be regarded as limiting. The use of “including,” “comprising,” or “having” and variations thereof herein is meant to encompass the items listed thereafter and equivalents thereof as well as additional items. Unless specified or limited otherwise, the terms “mounted,” “connected,” “supported,” and “coupled” and variations thereof are used broadly and encompass both direct and indirect mountings, connections, supports, and couplings. Further, “connected” and “coupled” are not restricted to physical or mechanical connections or couplings.
As can be better seen in
A single convolution 7, or corrugation, of the corrugated separator sheet 2 is shown in greater detail in
In some embodiments, the crests 8 are joined to the cylinder 3 by a method such as brazing, welding, gluing, or other methods of joining known to those skilled in the art. In some embodiments, the crests 9 are joined to the cylinder 4 by a method such as brazing, welding, gluing, or other methods of joining known to those skilled in the art. In some embodiments, it may be preferable to have a bond between the crests 8 and the cylinder 3 in only certain limited areas. In some embodiments, it may be preferable to have a bond between the crests 9 and the cylinder 4 in only certain limited areas.
Methods of corrugating a sheet to take such a form are well-known to those skilled in the art of heat exchangers. It should be understood that the shape of the corrugations shown in the figures is meant to be illustrative of the overall concept, and is not meant to be limiting with regard to the specific shape of the corrugations. In other embodiments, the corrugated separator sheet may have other geometrical configurations, such as triangular corrugations (i.e., straight sections joining at crests of sharp points), rectangular corrugations (i.e., straight sections joining at flat crests) or curved corrugations (i.e., a sinusoidal pattern), amongst others. Other types of corrugations commonly used in heat exchangers, such as for example a corrugated separator sheet having flat-crested convolutions, would be equally valid substitutes for the geometry shown.
As is best seen in the elevation view of
The flow paths through an embodiment of the heat exchanger 1 can be seen in
Referring again to the embodiment of the heat exchanger 1 shown in
An alternative embodiment, illustrated in
In one embodiment, the shape of the convolutions in the zones D1 and D2 is as shown in the section view of
The flattened portion 32 is positioned adjacent a crest of the corrugated separator sheet 2. As can be seen, with reference to
A process for forming a primary surface annular heat exchanger according to the embodiments shown in
In some embodiments of the invention, the corrugated separarator sheet is next slid over a cylinder 24, the cylinder 24 having an outer diameter that is approximately equal to the outer diameter of the inner cylinder 4 of the primary surface annular heat exchanger. In a prefereable embodiment the width of the corrugated separator sheet is selected such that after engagement of the convolutions 9a and 9b, the corrugated separator sheet will not fit over the cylinder 24 in a free state. Since the nature of the convolutions allow for relatively easy expansion of the corrugated separator sheet, a most preferable embodiment would size the width of the corrugated separator sheet so that a slight stretching of the convolutions of the corrugated separator sheet occurs as it is placed over the cylinder 24, thereby ensuring uniform contact between the plurality of crests 9 and the cylinder 24.
In some embodiments of the invention, the corrugations in the zones D1 and D2 of the corrugated separator sheet 2 are flattened in a process illustrated in
In some embodiments, it may be preferable for the cylinder 24 to make multiple complete revolutions about its axis 25 and to successively decrease the spacing H1 while the cylinder 24 is revolving in order to flatten the convolutions in a more controlled manner.
In some embodiments of the invention multiple pairs of the wheels 22 and 23 are used to flatten the convolutions at both ends of the corrugated separator 2 in the same operation.
In some embodiments of the invention the corrugated separator is removed from the cylinder 24 and is assembled over the cylinder 4. In some other embodiments the cylinder 24 may actually be the cylinder 4.
In some embodiments of the invention the flattened zones D1 and D2 are bonded to the cylinder 4 by welding, brazing, gluing, or other bonding processes known to those skilled in the art.
It should be understood that the embodiments described above and illustrated in the figures are presented by way of example only and are not intended as a limitation upon the concepts and principles of the present invention. As such, it will be appreciated by one having ordinary skill in the art that various changes are possible.
The present application claims priority to U.S. Provisional Patent Application Ser. No. 61/095,818, filed Sep. 10, 2008, the entire contents of which is hereby incorporated by reference.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US2009/056432 | 9/10/2009 | WO | 00 | 5/12/2011 |
Number | Date | Country | |
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61095818 | Sep 2008 | US |