The following relates to the field of diode, in particular to a red phosphor, a white light emitting diode (LED) and a backlight module.
Wide color gamut has become a newly focused hot issue in the field of backlight, and there is rising commercial demand in color gamut for higher quality. As the full width at half maxima (FWHM) of conventional nitride red phosphor is relatively wide, the NTSC color gamut is normally limited to around 90%, which is hardly improved further.
Novel phosphor having a structure of M2AX6, activated by Mn4+, has a narrow FWHM of less than 10 nm and high color purity, and the NTSC color gamut of this novel phosphor can reach to over 98%, which is greatly improved comparing with the conventional phosphors, it therefore becomes a hot spot in recent research.
In a backlight module, different screens have different color filter (CF), leading to various changes of the colored points after the light, emitted from LED, passing through the screens. Because the emission wavelength and spectral shape of this novel phosphor cannot be adjusted, the “color” of those colored points are not freely adjustable, the specific “color” of some colored points may not be enabled, resulting in unqualified color temperature and deep-ultraviolet (DUV) energy parameter after the light, emitted from LED, passing through the screen in the backlight module. It is desired to achieve the adjustably colored points based on a novel phosphor having a structure of M2AX6 activated by Mn4+.
It is an objective of the invention to provide a red phosphor, which is used in a device to enable colored points of a novel phosphor having a structure of M2AX6, activated by Mn4+ to be adjustable.
It is also an objective of the invention to provide a white LED.
It is also an objective of the invention to provide a backlight module.
The objective is achieved by the following technical solutions:
A red phosphor comprising a first red phosphor and a second red phosphor having adjustable emission wavelength; the first red phosphor is made from a substance having structure formula M2AX6:Mn4+, wherein
the element M is selected from Li, Na, K, Rb or Cs,
the element A is selected from Ti, Si, Ge or Zr, and
the element X is selected from F, Cl or Br;
the ratio of the second red phosphor to the red phosphor ranges from 0.01% to 15%.
Preferably, the second red phosphor comprises one or more compound selected from CaAlSiN3:Eu, SrLiAl3N4:Eu or Quantum Dot (QD).
Preferably, the second red phosphor has an emission wavelength ranging from 630 nm to 670 nm.
Preferably, the second red phosphor is selected from the followings:
the second red phosphor having an emission wavelength of 630 nm, and a FWHM being no greater than 35 nm; or
the second red phosphor having an emission wavelength that is larger than 630 nm and less than or equal to 635 nm, and a FWHM being no greater than 40 nm; or
the second red phosphor having an emission wavelength that is larger than 635 nm and less than or equal to 640 nm, and a FWHM being no greater than 50 nm; or
the second red phosphor having an emission wavelength that is larger than 640 nm and less than or equal to 645 nm, and a FWHM being no greater than 60 nm; or
the second red phosphor having an emission wavelength that is larger than 645 nm and less than or equal to 650 nm, and a FWHM being no greater than 70 nm; or
the second red phosphor having an emission wavelength that is larger than 650 nm and less than or equal to 655 nm, and a FWHM being no greater than 90 nm; or
the second red phosphor having an emission wavelength that is larger than 655 nm and less than or equal to 660 nm, and a FWHM being no greater than 100 nm; or
the second red phosphor having an emission wavelength that is larger than 660 nm and less than or equal to 665 nm, and a FWHM being no greater than 105 nm; or
the second red phosphor having an emission wavelength that is larger than 665 nm and less than 670 nm, and a FWHM being no greater than 110 nm; or
the second red phosphor having an emission wavelength of 670 nm, and a FWHM being no greater than 110 nm.
Preferably, with the addition of the second red phosphor, an increasing light emission intensity from the red phosphor, compared with an light emission intensity from the first red phosphor before the second red phosphor added, at the emission wavelength ranging from 600 nm to 630 nm will be less than or equal to an increasing light emission intensity from the red phosphor, compared with an light emission intensity from the first red phosphor before the second red phosphor added, at the emission wavelength ranging from 630 nm to 670 nm.
Preferably, the second red phosphor has an emission wavelength ranging from 630 nm to 670 nm, and a FWHM ranging from 35 nm to 110 nm.
A white LED comprising the above-described red phosphor, wherein a red light, a blue light and a green light are mixed simultaneously to produce a white light. The red light is emitted by the red phosphor which absorbed the blue light or the green light.
Preferably, the white LED further comprises a green phosphor having an emission wavelength ranging from 510 nm to 550 nm and a FWHM being no greater than 70 nm, and/or a blue LED chip emitting blue light, wherein the green light is emitted by the green phosphor which absorbed the blue light.
Preferably, the white LED further comprises a leadframe, a thermoplastic or thermosetting transparent protective layer, and a fluorescence conversion layer provided on the leadframe; the blue LED chip is arranged on the leadframe and is covered by the fluorescence conversion layer; the green phosphor and the red phosphor are dispersed in the fluorescence conversion layer which is wrapped up by the thermoplastic or thermosetting transparent protective layer wherein the blue light, the green light and the red light are distributed.
The present invention further provides a backlight module comprising above-described white LED.
The present invention has following benefits as compared with the prior art:
As the emission wavelength and spectrum of the phosphor comprising M2AX6:Mn4+ are barely changed (shown in
The invention will be described in more details hereinafter with reference to the figures and embodiments.
The present invention provides a red phosphor comprising a first red phosphor and a second red phosphor having adjustable wavelength.
The first red phosphor is made from a substance having structure formula M2AX6:Mn4+, wherein
the element M is selected from Li, Na, K, Rb or Cs,
the element A is selected from Ti, Si, Ge or Zr, and
the element X is selected from F, Cl or Br.
The ratio of the second red phosphor to the red phosphor ranges from 0.01% to 15%. The second red phosphor comprises one or more compound selected from CaAlSiN3: Eu, SrLiAl3N4: Eu, or QD. The second red phosphor has an emission wavelength ranging from 630 nm to 670 nm and a FWHM ranging from 35 nm to 110 nm.
To improve the color purity of the red phosphor and the NTSC color gamut, the second red phosphor is added into the first red phosphor to form the red phosphor, whereby the increasing light emission intensity from the red phosphor, compared with the light emission intensity from the first red phosphor before the second red phosphor added, at the emission wavelength ranging from 600 nm to 630 nm will be less than or equal to the increasing light emission intensity from the red phosphor, compared with the light emission intensity from the first red phosphor before the second red phosphor added, at the emission wavelength ranging from 630 nm to 670 nm, as shown in
Preferably, the second red phosphor is selected from the followings:
the second red phosphor having an emission wavelength of 630 nm, and a FWHM being no greater than 35 nm; or
the second red phosphor having an emission wavelength that is larger than 630 nm and less than or equal to 635 nm, and a FWHM being no greater than 40 nm; or
the second red phosphor having an emission wavelength that is larger than 635 nm and less than or equal to 640 nm, and a FWHM being no greater than 50 nm; or
the second red phosphor having an emission wavelength that is larger than 640 nm and less than or equal to 645 nm, and a FWHM being no greater than 60 nm; or
the second red phosphor having an emission wavelength that is larger than 645 nm and less than or equal to 650 nm, and a FWHM being no greater than 70 nm; or
the second red phosphor having an emission wavelength that is larger than 650 nm and less than or equal to 655 nm, and a FWHM being no greater than 90 nm; or
the second red phosphor having an emission wavelength that is larger than 655 nm and less than or equal to 660 nm, and a FWHM being no greater than 100 nm; or
the second red phosphor having an emission wavelength that is larger than 660 nm and less than or equal to 665 nm, and a FWHM being no greater than 105 nm; or
the second red phosphor having an emission wavelength that is larger than 665 nm and less than 670 nm, and a FWHM being no greater than 110 nm; or
the second red phosphor having an emission wavelength of 670 nm, and a FWHM being no greater than 110 nm.
The appropriate second red phosphor is selected from those having the emission wavelength and FWHM as described above, in order to improve the color purity of the red phosphor mixed and improve the NTSC color gamut.
As shown in
This embodiment provides a red phosphor comprising a first red phosphor and a second red phosphor having adjustable wavelength. The first red phosphor is made from a substance having structure formula M2AX6:Mn4+, wherein the element M is selected from Li, Na, K, Rb or Cs, the element A is selected from Ti, Si, Ge or Zr, and the element X is selected from F, Cl or Br. The ratio of the second red phosphor to the red phosphor is 0.1%. The second red phosphor comprises CaAlSiN3: Eu. The second red phosphor has an emission wavelength of 660 nm and a FWHM of 90 nm.
This embodiment provides a white LED comprising the above-described red phosphor, green phosphor and blue LED chip, wherein a red light, a blue light and a green light are mixed simultaneously to produce a white light.
The red light is emitted by the red phosphor which absorbed the blue light or the green light.
The green light is emitted by the green phosphor which absorbed the blue light. The green phosphor comprises one or more compound selected from β-sialon, silicate, γ-alon or QD. The green phosphor has wavelength ranging from 510 nm to 550 nm and a FWHM being no greater than 70 nm.
This embodiment provides a white LED whose white light is produced by mixing blue light, green light and red light together. The red light is emitted by the red phosphor which absorbed blue light or green light.
The blue light emitted by the blue LED chip has an emission wavelength ranging from 430 nm to 460 nm.
The green light having an emission wavelength of 529 nm and a FWHM of 50 nm is emitted by the green phosphor which absorbed the blue light, wherein the green phosphor is comprised of β-sialon.
The red phosphor comprises a first red phosphor and a second red phosphor, wherein the first red phosphor is made from a substance having structure formula K2SiF6:Mn4+, and the second red phosphor is made from a substance having structure formula SrLiAl3N4:Eu whose light emission wavelength is 650 nm and FWHM is 45 nm; wherein the ratio of the second red phosphor to the red phosphor is 5%. With the addition of the second red phosphor to the first red phosphor, the increasing light emission intensity from the red phosphor, compared with the light emission intensity from the first red phosphor before the second red phosphor added, at the emission wavelength ranging from 600 nm to 630 nm will be less than or equal to the increasing light emission intensity from the red phosphor, compared with the light emission intensity from the first red phosphor before the second red phosphor added, at the emission wavelength ranging from 630 nm to 670 nm.
The blue light, the green light and the red light are distributed in the thermoplastic or thermosetting transparent protective layer.
The NTSC color gamut of the LED according to this embodiment is reduced by no more than 1% on the basis of the NTSC color gamut of pure K2SiF6:Mn4+.
This embodiment provides a white LED which is extremely similar to the one in the embodiment 2, except the following differences, while their identical parts will not be repeated here.
The green phosphor is comprised of γ-alon whose light emission wavelength is 520 nm and FWHM is 35 nm.
The red phosphor comprises a first red phosphor and a second red phosphor, wherein the first red phosphor is made from a substance having structure formula K2TiF6:Mn4+, and the second red phosphor is made from a substance having structure formula CaAlSiN3:Eu whose light emission wavelength is 670 nm and FWHM is 90 nm; wherein the ratio of the second red phosphor to the red phosphor is 2%.
The NTSC color gamut of the LED according to this embodiment is reduced by 1%-2% on the basis of the NTSC color gamut of pure K2TF6:Mn4+.
This embodiment provides a white LED which is extremely similar to the one in the embodiment 2, except the following differences, while their identical parts will not be repeated here.
The green phosphor is comprised of silicate whose light emission wavelength is 525 nm and FWHM is 70 nm.
The red phosphor comprises a first red phosphor and a second red phosphor, wherein the first red phosphor is made from a substance having structure formula K2GeF6:Mn4+, and the second red phosphor is made from QD whose light emission wavelength is 640 nm and FWHM is 30 nm; wherein the ratio of the second red phosphor to the red phosphor mixed is 8%.
The NTSC color gamut of the LED according to this embodiment is reduced by 1%-2% on the basis of the NTSC color gamut of pure K2GeF6:Mn4+.
This embodiment provides a white LED which is extremely similar to the one in the embodiment 2, except the following differences, while their identical parts will not be repeated here.
The green phosphor is comprised of silicate whose light emission wavelength is 525 nm and FWHM is 70 nm.
The red phosphor comprises a first red phosphor and a second red phosphor, wherein the first red phosphor is made from a substance having structure formula K2GeF6:Mn4+, and the second red phosphor is made from QD whose light emission wavelength is 640 nm and FWHM is 30 nm; wherein the ratio of the second red phosphor to the red phosphor mixed is 0.06%.
The NTSC color gamut of the LED according to this embodiment is reduced by %-2% on the basis of the NTSC color gamut of pure K2GeF6:Mn4+.
The following embodiments further provides a backlight module, including direct-lit backlight module and edge-lit backlight module.
This embodiment uses an existing LED direct-lit backlight module 200, wherein the LEDs are in accordance with the present invention.
As shown in
This embodiment uses an existing LED edge-lit backlight module 300, wherein the LEDs are in accordance with the present invention.
As shown in
The embodiment described hereinbefore is merely preferred embodiment of the present invention and not for purposes of any restrictions or limitations on the invention. It will be apparent that any non-substantive, obvious alterations or improvement by the technician of this technical field according to the present invention may be incorporated into ambit of claims of the present invention.
For the sake of clarity, it is to be understood that the use of ‘a’ or ‘an’ throughout this application does not exclude a plurality, and ‘comprise’ or ‘comprising’ do not exclude other steps or elements.
Number | Date | Country | Kind |
---|---|---|---|
201711207443.8 | Nov 2017 | CN | national |
This application is a continuation of PCT International Patent Application No. PCT/CN2018/096082, filed Jul. 18, 2018, which claims the benefit of Chinese Application No. 201711207443.8 filed Nov. 27, 2017, the disclosure of each of these applications are expressly incorporated herein by reference in their entireties.
Number | Date | Country | |
---|---|---|---|
Parent | PCT/CN2018/096082 | Jul 2018 | US |
Child | 16884098 | US |