The invention relates to a refillable plastic container—in particular, made of polyethylene terephthalate or polyethylene furanoate—according to the independent claims.
The containers, which were customary in the past, made of tinplate or non-ferrous sheet metal, of glass or also of ceramic, are increasingly being replaced by containers made of plastic. Of late, it is predominantly plastic containers that are used in particular for the packaging of fluid substances, e.g., for applications in the household, in agriculture, in industry and commerce, etc. Low weight and lower costs certainly play a not inconsiderable role in this substitution. The use of recyclable plastic materials and the overall more favorable total energy balance in their production also contribute to promoting the acceptance of plastic containers amongst users.
Plastic containers—in particular, plastic bottles—made of polyethylene terephthalate (PET) and similar materials are usually produced in a so-called stretch blow-molding process. In this case, a preform is first produced by an injection-molding process in an injection mold. Recently, even flow-molding or even extrusion blow-molding have been proposed for the production of preforms. The preform has an essentially elongate body and is formed to be closed at one longitudinal end. A gate mark originating from the injection-molding process is usually also found there. Adjoining the other end of the preform body is a neck section which is provided with a dispensing opening. The neck section already has the later shape of the container neck. In many known preforms, the preform body and the neck section are separated from one another by a so-called support ring. The support ring protrudes radially from the neck wall and serves for transporting the preform or the plastic container produced therefrom and for supporting the preform on the blow mold or for supporting the plastic container when the latter is being closed with a closure cap.
The preform is demolded after its production and can be further processed immediately while still hot in a single-stage, stretch blow-molding process. In a two-stage, stretch blow-molding process, the preform is cooled and temporarily stored for spatially—and/or temporally—separated further processing on a stretch blow-molding device. Before further processing in the stretch blow-molding device, the preform is then conditioned if necessary, i.e., a temperature profile is applied to the preform. It is then introduced into a blow mold of a stretch blow-molding device. In the blow mold, the preform is finally inflated by a gas injected at overpressure-usually air-in accordance with the mold cavity, and in this case is additionally stretched axially by means of a stretching mandrel.
An injection blow-molding method is also already known in which the stretch blow-molding process is carried out directly after the injection molding of the preform. Here, the preform remains on the injection core, which at the same time forms a kind of stretching mandrel. The preform is in turn inflated by overpressure in accordance with the mold cavity of a blow mold which is brought into position on the injection core or vice versa, and is thereby stretched by the stretching mandrel. The finished plastic container is then demolded. Stretch blow-molded or injection blow-molded plastic containers can be recognized by the gate mark usually found in the region of the container base and which originates in the preform. At this gate mark, the plastic material is only slightly or not at all stretched.
In addition to plastic containers produced from stretched preforms, there are also plastic containers which are formed by the unstretched preform itself. Examples thereof are pressure vessels for aerosols and similar filling materials. The most frequently used plastic for the plastic containers described is polyethylene terephthalate (PET). PET has been tried and tested, its chemical, physical, and mechanical properties are well-known, and it is easy to process on known installations. The recycling circuits which have been introduced and are being constantly expanded ensure that a high proportion of PET containers can be collected again after use and can be fed into renewed processing. Recently, plastic containers made of polyethylene furanoate (PEF) are also being produced, which, in particular, stand out from PET in having better barrier properties. With regard to mechanical loading capacities, plastic containers made of PET and of PEF have very similar properties.
Recently, efforts have also been made to use plastic containers several times before they are recycled. For this purpose, the collected used plastic containers must first be cleaned before they can be refilled. Since many plastic containers, e.g., containers made of PET, can soften and deform even at relatively low temperatures of, for example, 80 ° C., cleaning with boiling water is ruled out. Plastic containers are therefore often cleaned at lower temperatures with the aid of alkalis—for example, sodium hydroxide solution (NaOH) or potassium hydroxide solution (KOH). The use of a 1.5% to 2.5% NaOH lye at temperatures of 50 ° C. to 70 ° C. proves to be practicable.
However, the behavior of polyesters—in particular, PET and PEF—in conjunction with lyes is not without problems. Stress cracks in the plastic container can form points of attack for the lye, where, in time, degradation of the plastic can occur. In particular, a reaction between ester and lye can lead to saponification. On the plastic container, this can lead to discoloration and ultimately even to failure. The unstretched regions of plastic containers—in particular, the neck of a plastic container—are particularly susceptible to such stress-induced problems. In the case of stretch blow-molding of a PET or PEF preform, which is usually produced by an injection-molding method, the neck of the preform lies outside the blow mold and is not stretched during stretch blow-molding, and thus not stretch-solidified either. Stresses in the neck of the plastic container can lead to microscopically small cracks which can enlarge when the container is cleaned with lyes. This can lead to the neck of the plastic container developing leaks over time or no longer being able to withstand an internal pressure in the plastic container-for example, caused by carbonized beverages. The stresses in the neck of the plastic container can be of many kinds. For example, these include thermal stresses which can occur due to the different expansions of the inner wall and the outer wall of the neck of the container. During production of the plastic container from the preform, further stresses can be induced by the blowing nozzle and by the stretching mandrel with which the preform is stretched axially. Stresses in the neck can also be induced by the transport grippers or similar transport means with which the preform and the plastic containers produced therefrom are held and transported to the various system components. Finally, even axial and radial pressures from the closure cap and the torque on the neck of the container when the closure cap is fitted can lead to stresses in the neck of the plastic container.
It is therefore an aim of the present invention to remedy one or more disadvantages of plastic containers of the prior art. In particular, the prerequisites for a refillable plastic container are to be created which permit a greater number of cleanings and refillings.
This aim is achieved by the plastic container defined in the independent claim. Preferred and advantageous embodiment variants of the invention are the subject matter of the respective dependent claims.
A refillable plastic container according to the invention—in particular, a refillable plastic container made of PET or PEF—has a neck having a neck opening and a container body enclosing a filling volume which are separated from one another by an essentially radially—protruding support ring. The neck of the plastic container has an axial length, measured from an underside of the support ring up to a mouth rim bordering the neck opening, which is equal to or less than 17.25 mm. Here, the neck, at least in a section between the underside of the support ring up to the mouth rim bordering the neck opening, has a minimum wall thickness which does not fall below 1.9 mm.
In contrast to known refillable plastic containers—in particular, PET bottles—which are formed overall with relatively large wall thicknesses and a correspondingly high weight, the invention proposes optimizations of the neck of the plastic container, in order to minimize the stresses occurring during production in the unstretched region of the container. By forming the neck with a total shorter axial length as compared to known necks of disposable containers made of PET or PEF, thermal stresses resulting from different contractions of the inner wall and outer wall of the neck during production in, for example, an injection-molding process can be reduced. Due to the overall thicker-walled formation of the neck, the neck cools even more slowly and more uniformly during production, whereby the formation of stresses can be significantly reduced. Lower stresses during production of the preform lead to a significantly smaller number of microscopic cracks in the neck of the plastic container. As a result, a larger number of cycles of filling, cleaning, and refilling of the plastic containers is made possible.
For fitting a closure cap, the neck can be formed with interlocking engagement elements—in particular, threaded sections—which protrude as radial protrusions from an outer wall of the neck in a neck section which is situated between the mouth rim and the support ring.
These protrusions preferably extend over at least 85% of a circumference of the neck.
An associated closure cap can be designed, for example, as a screw cap or as a bayonet cap which has essentially complementary engagement elements. Such a closure cap is fitted by pressure and application of a torque. In order to minimize possibly resulting stresses in the neck, it is advantageous if the interlocking engagement elements extend over at least 85% of a circumference of the neck.
In order to provide the user with a visual first-opening guarantee, caps—in particular, screw caps—are provided with a tear-off guarantee strip. For this purpose, an abutment, extending circumferentially at least in sections and extending substantially radially from the outer wall of the neck, is formed on a section of the neck which is located between the support ring and an end of the interlocking engagement elements closer to the support ring. In the production of the container, a region of the neck lying between the abutment and the support ring is usually used for the engagement of transport elements, such as transport grippers. In order to thereby reduce stresses occurring in the neck, it proves expedient if this region—in particular, this region alone—has a minimum wall thickness which does not fall below 1.9.
In known necks of plastic containers, a region immediately adjacent to the mouth rim is formed as a sealing surface. A sealing cone protruding from a closure cap presses against this sealing surface when the closure cap is fitted. In order to minimize stresses thereby occurring in the neck, in a further exemplary embodiment of the invention, it proves advantageous for the neck, in a region between the interlocking engagement elements and the support ring, to have an inner wall in the form of a conical sealing surface. The sealing surface is thereby displaced axially away from the mouth rim in the direction of the interior of the plastic container and is formed in a region of the neck which is designed with a greater wall thickness. In interaction with a closure cap with a correspondingly elongated sealing cone, this leads to a reduction in the stresses in the container neck.
A further aspect of the invention therefore relates to a closure cap—in particular, a closure cap for use with a plastic container as described in the present case—which has a cover plate and, formed thereon, a substantially cylindrical barrel with interlocking engagement elements—in particular, threaded elements—which interact with correspondingly-designed, interlocking engagement elements—in particular, threaded sections—on the neck of the plastic container. Within a space enclosed by the barrel, a ring-shaped, peripheral spacer arranged concentrically to the barrel is arranged, which protrudes from the cover plate and on the free end of which a sealing lip is arranged. The spacer and the sealing lip have a maximum axial extension which is equal to or greater than the height of the cylindrical barrel. Further details and aspects of the closure cap are described below particularly in connection with the present plastic container.
In a further embodiment variant of the refillable plastic container, an inner diameter, measured at the neck opening, of the neck is less than 21.6 mm. In this case, the inner diameter in the region of the neck opening is larger than the inner diameter of the neck in the region of the support ring. This also leads to a reduction in stresses during production of the preform—in particular, in the injection-molding process.
In order to further reduce the stresses that may possibly occur, it can prove expedient for the support ring on the neck of the plastic container to have, measured over its largest radial extension, an external diameter which is equal to or less than 35 mm.
In a further embodiment variant of the invention, the design of the support ring with an axial thickness of 1.9 mm to 2.5 mm measured at the transition to an outer wall of the neck contributes to reducing the stresses.
The neck can have a wall thickness, measured at the mouth rim, of 1.4 mm to 1.8 mm.
During the blowing process, the blowing nozzle is pressed with a constant pressure against the mouth rim of the neck of the container. Since the neck has a wall thickness, measured at the mouth rim, of 1.4 mm to 1.8 mm—in particular, in conjunction with an inner diameter smaller than known necks of disposable plastic containers—the force acting on the neck can be reduced or better absorbed. In this way, stresses and microcracks in the material resulting thereby can be prevented.
In a further embodiment variant of the invention, geometric optimizations of the container neck for reducing the stresses occurring during production and assembly can also be supported by the addition of suitable additives to the plastic material. At least in the region of the neck, an addition of additives from the group consisting of terephthalic acid (PTA), isophthalic acid (IPA), monoethylene glycol (MEG), diethylene glycol (DEG), isosorbide, spiroglycol, and naphthalene dicarboxylic acid dimethyl ester (NDC) is found to be useful here.
In one embodiment of the invention, the refillable plastic container can be designed as a preform, which is produced in an injection-molding process or in a flow-molding process.
In a further embodiment of the invention, the refillable plastic container is designed as a container which is manufactured in a blow-molding process from a preform produced in an injection-molding process or in a flow-molding process. It is preferably designed as a stretch blow-molded container.
A further variant of the invention provides for a refillable plastic container, the neck of which is designed for fitting a closure cap formed in one or more parts. The closure cap can here be designed as a screw cap or as a bayonet cap. In conjunction with refillable plastic containers, caps are found to be advantageous which are made of a plastic from the group consisting of polyethylene (PE), polypropylene (PP), polyethylene terephthalate (PET), polyamide (PA), copolymers thereof, and thermoplastic elastomers (TPE). The pairing of the PET container material with the described cap materials can also contribute to reducing the occurrence of stresses in the neck of the plastic container.
A closure cap designed accordingly for use with a refillable plastic container designed according to the invention has a cover plate and, formed thereon, a substantially cylindrical barrel with interlocking engagement elements—in particular, threaded elements—which interact with correspondingly-formed, interlocking engagement elements—in particular, threaded sections—on the neck of the plastic container. Within a space enclosed by the barrel, a ring-shaped, peripheral spacer arranged concentrically to the barrel is arranged, which protrudes from the cover plate. A sealing lip is arranged on the free end of the spacer.
In a first embodiment, the spacer and the sealing lip have a maximum axial extent which is equal to or greater than a maximum distance of the interlocking engagement elements from the cover plate. The closure cap is designed for interacting with a conical sealing surface installed in the direction of the support ring into the interior of the neck of the refillable plastic container and therefore has a sealing lip arranged on a spacer. In some embodiment variants of the invention, the maximum axial extent of the spacer and the sealing lip can even be greater than an axial length of the barrel of the closure cap.
In a further embodiment, the sealing lip is designed to be circumferential and has an axial cross-section extending approximately in the shape of a trumpet. The free end of the sealing lip pointing outwards and in the direction of the cover plate of the closure cap rests on the inner wall of the neck of the plastic container in the fitted state of the closure cap. In this case, a spring-loaded elasticity of the sealing lip ensures venting when the closure cap is screwed on and a reliable sealing closure when it is fully screwed on.
In a further embodiment, the sealing lip has on its free end a circumferential, approximately olive-shaped sealing bead, which extends in the direction of an inner wall of the barrel. In the fitted state of the closure cap, the sealing bead interacts in a sealing manner with a sealing cone in a thickened region of the neck of the plastic container, said region being shifted in the direction of the support ring.
In a further embodiment, the sealing lip is designed as a sealing lip extending counter to the direction in which the spacer protrudes from the cover plate. When the closure cap is being screwed onto the plastic container, this sealing lip is thus pulled over a corresponding sealing surface arranged in the interior of the neck of the plastic container.
In a further embodiment, the closure cap can have one or more concentric sealing lips in an annular space delimited by the spacer and the barrel, said sealing lips protruding from the cover plate and resting in a sealing manner on the mouth rim bordering the neck opening in the fitted state. In this case, the additional sealing lips can rest on the mouth rim or surround it on the inner wall and on the outer wall of the neck of the plastic container.
In order to provide the consumer with a visual first-opening guarantee, in a further embodiment variant of the invention, the closure cap at the free end of the barrel can have a guarantee ring which is connected to the barrel via a number of breakable webs.
Further advantages and features become apparent from the following description with reference to the schematic drawings. Shown, in a representation not true-to-scale, are:
Number | Date | Country | Kind |
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01248/19 | Oct 2019 | CH | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2020/076600 | 9/23/2020 | WO |