The invention relates to a refractory tile for fixing to a wall of a reactor, in particular to protect that wall from heat.
Refractory tiles are used to line the walls of combustion chamber tubes in boilers for incinerating biomass or domestic refuse. The tubes are usually vertical and connected together by cross-bars. The tiles form a refractory lining, protecting the tubes from physical contact with materials during their combustion and with the fumes from that combustion. Thin tiles facilitate heat transfer from the reactor to a fluid flowing in the tubes of the boiler.
Water flows in the tubes to recover part of the heat released during incineration. Close contact between the tiles and the tubes is thus desirable. To this end, as described, for example, in European patent EP-1 032 790, the rear face of each tile conventionally has semi-cylindrical channels shaped so that each receives a tube of the wall of tubes. A thin layer of liquid mortar may also be disposed behind the tiles to limit the volume of the void between the tiles and the tubes, and thus improve heat exchange.
Using floating tiles hung on the wall provides the tiles with a certain degree of mobility relative to one another. To this end, the tiles may, for example, be freely hung on hooks fixed to the middles of bars, and the tiles may be spaced from each other by a few millimeters. The protective lining can thus adapt itself to dimensional variations in the tiles during thermal cycles. The reliability of the lining is thus improved.
The expansion space between two adjacent tiles is generally filled with a flexible mortar to guarantee a seal for the lining. Flexible mortar expansion joints are vulnerable zones and their length must thus be minimized. Conventionally, then, each tile extends over a plurality of tubes. To facilitate positioning of the lining, the dimensions of the tiles must, however, be limited. As an example, the tiles described in EP-1 032 790 extend over three tubes. They include two slots extending either side of a central channel and intended to receive fixing means.
Two types of assembly are possible with the system described in EP-1 032 790.
In a first type of assembly, the hooks are mounted to allow the tiles to be assembled in a pattern that is staggered in the vertical or horizontal direction. Depending on the selected configuration, such an assembly prevents the vertical or horizontal joints from aligning. In practice, that type of assembly proves to be complex and a source of problems. Further, it takes a long time to produce and thus costs are high.
In the second type of assembly, the hooks are disposed in vertical and horizontal lines. However, the configuration of the tiles implies that the spacing of the lines of hooks must vary, which results in an alignment of vertical and horizontal joints. The inventors have found that such an alignment reduces the durability of the joints and thus of the lining.
Further, there are occasional obstacles, for example those formed by passages for thermocouples, which require the assembly to be modified. In particular, it may be necessary to offset one or more rows of hooks, which is an expensive operation. It is also possible to cut one or more tiles. However, cutting inevitably weakens the cut part when in service.
Thus, there is a need for a refractory lining comprising refractory tiles, which lining is easy to use, in particular to accommodate the presence of obstacles, and has improved reliability.
The invention aims to satisfy that need.
In accordance with the invention, that aim is achieved by a refractory tile, notably for protecting the inner wall of a gasifier reactor, said tile having an alignment of at least two fixing points, any two adjacent fixing points of said alignment being spaced by a constant distance A, the first and last fixing points of said alignment being separated, in the direction of said alignment, by distances α1 and α2 from first and second edges of said tile extending in the proximity of said first and last fixing points respectively. The tile of the invention is characterized in that 0<A−(α1+α2).
When the distance D=A−(α1+α2) corresponds to the width el of the vertical expansion joints, the fixing means of a row of tiles are then regularly spaced by the length A. In other words, the horizontal distance between two fixing means side by side is identical, regardless of whether these means are intended to support one tile or two adjacent tiles. Thus, it is possible to offset a row of tiles horizontally by the distance A or by any multiple of that distance. Similarly, when the distance D corresponds to the width eh of the horizontal expansion joints, it is possible to offset a row of tiles vertically by the distance separating two superimposed fixing points of the tile, or by any multiple of that distance.
Adapting the tile assembly to accommodate the presence of an obstacle may then be the result of simply offsetting the tiles horizontally and/or vertically. Further, it is possible to offset the tiles of two superimposed rows and/or two adjacent columns to remove any continuous alignment of vertical and/or horizontal joints. The reliability of the joints and thus of the lining is advantageously improved thereby.
Preferably, the tile of the invention also exhibits one or more of the following optional characteristics:
The invention also provides a refractory lining, in particular for protecting the inner wall of a reactor of a gasifier, the lining comprising an assembly of refractory tiles attached to fixing means fixed to a wall, and being characterized in that said lining comprises at least one tile in accordance with the invention.
Preferably, the refractory lining of the invention also has one or more of the following optional characteristics:
The lining of the invention is particularly for the protection of a wall of a gasifier reactor.
Coal gasification is a process that has been known for about half a century and that is currently developing rapidly. It can produce synthesis gas (CO, H2), a clean energy source, and also base compounds for the chemicals industry starting from highly diverse hydrocarbon materials, for example coal, oil coke, or even heavy oils for recycling. That process can also eliminate unwanted components, for example NOx, sulfur or mercury, before being discharged into the atmosphere.
The principle of gasification consists in controlled partial combustion in steam and/or oxygen at a temperature in the range about 1150° C. to 1600° C., and under pressure.
Different types of gasifier exist, using a fixed, fluidized, or entrained bed. Such gasifiers differ in the way in which the reagents are introduced, the manner in which the fuel-oxidizer mixture is produced, the temperature and pressure conditions, and the method of evacuating ash or slurry, the liquid residue from the reaction.
In particular, a pressurized dry gasifier 5 is known, with a fluidized bed, of the “Lurgi fixed bed dry ash gasifier” type. As can be seen in
The dry coal gasifier reactor 14 comprises a water jacket 22 formed from steel. The jacket 22 comprises an outer wall 24 and an inner wall 26, the site of a great deal of corrosion, which at least partially defines the internal volume of the reactor 14. Said reactor has a limited service life due to thermal cycles and/or corrosion and/or abrasion by the dry ash and/or hot points where the temperature is typically about 1400° C.
The tiles of the invention are particularly suitable for protecting the wall of a gasifier reactor, said wall not being constituted by tubes. Preferably, the refractory tiles are fixed by hanging them on fixing means fixed to said wall. The protective lining obtained is advantageously compact, reliable, and easy to position, as appears in greater detail in the description below.
Finally, the invention provides a method of determining the overall thermal conductivity of a lining of a wall of a reactor, the lining comprising an assembly of refractory tiles, the method being characterized in that concrete with predetermined conductivity is cast between the assembly of tiles and said wall.
Other characteristics and advantages of the invention become apparent from the following description and the drawings in which:
In the various figures, identical or analogous reference numerals are used to designate identical or analogous parts or portions.
Since
The description below is made in the context of a lining for the gasifier described above. However, the invention is not limited to that application.
A tile 30 has the general shape of a cylindrical rectangle, having a small amount of curvature to follow the shape of the inner wall of the jacket 22 of the reactor 14.
Preferably, the tile 30 is made of a thermally insulating material. Preferably, that material comprises at least 60%, more preferably at least 90%, and still more preferably at least 99%, as a percentage by weight, of non-siliceous oxides. Preferably, said non-siliceous oxides are selected from alumina, zirconia, chromium oxide Cr2O3, or mixtures thereof. However, any other refractory material that can resist corrosion by ash (which may be molten), abrasion by dry ash, and by hot points could be used.
Preferably, the material of the tile of the invention contains no silicon carbide (SiC). Preferably again, it includes less than 1%, more preferably less than 0.5% by weight of silica (SiO2). Silicon carbide and silica have a deleterious effect on corrosion resistance. Further, silica may be unstable and evaporate in the form of SiO, or even SiH4.
The tile 30 has a front face 32 and a rear face 34 and an upper edge 36, lower edge 38, right edge 40 and left edge 42.
The rear face 34 or “cold face” of the floating tile 30 includes first 44 and second 46 slots extending substantially parallel to the side edges 40 and 42 along the right 40 and left 42 edges respectively. The slots 44 and 46 open via first 48 and second 50 lower openings respectively to the lower edge 38, and via first 52 and second 54 rear openings respectively to the rear face 34.
The face 32 or the “hot face” and the face 34 or the “cold face” of the floating tile 30, are curved substantially to follow the curvature of the reactor.
As can be seen in
As is described in more detail in the description below, the tile 30 can be hung on a fixing means having the general form of a nail and comprising a shank and a head. After hanging, the bottom of the slot rests under gravity on the head of the fixing means which then supports the weight of the tile.
Viewed from the rear of the tile as shown in
A rear opening also preferably has a wide lower portion 45i for introducing a head of a fixing means. Advantageously, this head may thus be introduced into the slot 45 via a lower opening or via a lower portion of a rear opening.
The rear face 34 of the tile 30 also has crosspieces or “spacers” 56 that are preferably shaped to maintain a distance in the range 2 mm to 5 mm between the rear face of the tile and the inner wall 26 of the cooling jacket. Advantageously, the distance of the tiles from the wall governs heat exchange.
The presence of a plurality of slots per tile, preferably two, advantageously guarantees that the tile stays in position if one of the fixing points fails.
As can be seen in
As can be seen below, it is preferable to provide a castable concrete behind the tiles, in particular to bond them to the cooling jacket 22. Blocking communication between the rear and front faces of the tiles also has the advantage of preventing the concrete from flowing into the expansion spaces 60 during installation. If it did flow therein, the tiles could no longer expand during operation of the gasifier without expansion generating high, unwanted thermomechanical stresses.
The disposition of the upper lip 53 in the extension of the front face of a tile allows an enlarged opening to be formed to access the rear of the tile. Advantageously, this facilitates casting of concrete behind that tile.
In a first variation (
The lower portion 45i of a slot that does not open onto the lower edge of the tile must necessarily be shaped to allow a head of a fixing means to be introduced; this head cannot be introduced via the lower edge.
In a second variation (
Preferably, the tile has as many tongues as it has slots, so that when assembling an upper tile immediately above a lower tile, all of the lower openings of the slots of the upper tile are hidden by the tongues of the lower tile. This characteristic may be obtained by assembling tongues on an existing tile, for example by adhesive bonding (
In a third variation (
Preferably, all of the slots of all of the tiles of the assembly are hidden by using at least one of the solutions illustrated in
As can be seen in
0<el=A−(α1+α2).
More generally, if the tile has “n” slots regularly spaced by a distance An, then in accordance with the invention:
0<el=An−(α1+α2).
Preferably, el is in the range 2 mm to 10 mm.
Since the edges of the tile 30 are not planar, α1 and α2 are measured on the rear face of the tile. This is also applies to the length L of the tile and to its height H.
Clearance is provided between the head 86 and the slot 45 so that the fixing means 80 do not interfere with expansion of the tile 30.
In the prior art, the fixing means 80 of the type shown in
When used in a gasifier reactor, installation of an irregular array of fixing means 80 as shown in
In contrast to the disposition of the fixing means shown in
The fixing means are also aligned in substantially horizontal lines regularly spaced by a distance B. Preferably, the distance B is greater than the height H of a tile, i.e. 0<eh=B−H.
The term “spacing” when applied to two tiles does not means that those two tiles do not touch, but that in the direction under consideration, relative displacement of one tile relative to the other is possible. Thus the spacing el of two tiles in the width direction means that one tile may expand laterally by a distance el before abutting against the tile to its side. The spacing eh in the height direction of two tiles means that one tile may expand upwards or downwards by a distance eh before abutting against the tile above or below it.
Preferably, the distance B is equal to the distance A. The same gauge can thus be used to provide the correct vertical and horizontal spacings.
Since el+(α1+α2)=A, the same gauge can be used to check the spacing of two fixing means 801 and 802 side by side and intended to receive the same tile, and to check the spacing of two fixing means 803, 804 side by side and intended to receive different tiles. A single gauge can thus advantageously be used to position all of the fixing means.
Further, the way the tiles are assembled is not “frozen” by the positioning of the fixing means; a row of tiles may, for example, be laterally offset by a length corresponding to the spacing between two slots of a tile if necessary. In contrast to the prior art, a half tile may thus readily be incorporated even after the fixing means have been welded into place.
It is thus possible to mount the tiles in a staggered pattern to reinforce the protection offered by the refractory lining, to readily incorporate a passage for a thermocouple embedded in a filler concrete 90, or to accommodate a damaged surface, having an opening or a hole 92, for example, with a great deal of flexibility.
A comparison of the tile assemblies of
Before hanging on the tiles, a grid, preferably a metal or non organic fiber grid, is preferably hung on the fixing means.
The tiles are then hung on the fixing means 80 by inserting the fixing means in the slots 45. Preferably, the tiles are of the type shown in
The heads 86 are dimensioned to allow the fixing means 80 to be inserted into the bottoms 55 of the slots, while preventing disengagement via the upper portions 45s of the rear openings of the slots, which are partially closed because of their omega, Ω, shape.
The fixing means 80 thus serve not only to support the weight of the tiles (acting as a bracket), but also to prevent the tiles from swinging by holding them substantially flat against the wall 26.
The order in which the tiles are hung up depends on the profiles of their edges. It is determined so that adjacent tiles overlap, as envisaged by the tile manufacturer.
In accordance with the invention, a castable concrete is preferably cast into the space separating the tiles and the inner wall of the cooling jacket. This space is guaranteed by the presence of spacers 56 bearing on the wall 26. Advantageously, the spacers 56 prevent direct contact between the rear faces of the tiles and the wall, and thus improve the thermal protection of the wall.
Since the spacers 56 extend over only part of the height of said tile, they do not impede the movement of concrete behind the tile.
Advantageously, the concrete can thus be distributed uniformly behind the tiles.
Preferably, the castable concrete is based on Al2O3 or Al2O3—Cr2O3 or has a nature similar to the tiles.
The castable concrete can advantageously regulate the overall conductivity of the lining by its nature and its thickness. Its composition can be modified as a consequence. As an example, a castable concrete based on SiC or enriched with metal or ceramic fibers, for example of the Dramix® or Unifrax type, may advantageously be used if necessary to increase the thermal conductivity of the lining, i.e. to increase the transfer of heat to the cooling jacket, in particular to produce the steam necessary for the gasifier system.
The castable concrete may also protect the inner wall 26 of the cooling jacket if a tile becomes unhooked.
It also helps the tiles to withstand the pressure of several tens of bars reigning inside the reactor in operation.
Finally, it blocks any direct access to the rear faces of the tiles and thus to the metal wall 26 of the cooling jacket.
In the event of a tile unhooking by being ripped off, the castable concrete is sometimes ripped off with the tile. It might be mechanically bonded to it, in particular by filling the slots receiving the heads 86 of the fixing means.
The metal or non organic fiber grid, disposed between the inner wall 26 of the cooling jacket and the rear face of the tiles, i.e. in the zone into which the castable concrete is then cast, advantageously improves cohesion of the layer of concrete and retains it locally if one or more tiles are ripped off or unhooked. Alternatively or in addition to the grid, the castable concrete may advantageously be reinforced with fibers, preferably metal fibers, mixed with its other constituents during preparation thereof.
After casting the concrete, a flexible mortar is disposed in the expansion spaces separating the tiles to form an expansion joint. The expansion joint thus has a width eh on its horizontal portions and a width el on its vertical portions. Flexible mortars conventionally include ceramic fibers. An example that may be mentioned is Fiberfax® produced by Unifrax.
When the gasifier 5 is operational, variations in heat in the reactor 14 provoke expansion of the tiles. The spacing of the tiles relative to each other, however, allows them to expand without generating high mechanical stresses.
The expansion joint compresses under the effect of the expansion, then regains its initial form when the tiles contract again. At any time during a thermal cycle, the inner wall of the cooling jacket of the reactor thus remains effectively protected.
If the expansion joint is damaged, the shape of the tiles or the presence of plugs 74 (
Finally, if a tile unhooks, the castable concrete still maintains a protective barrier for the jacket 22. This barrier is safer if a grid has been provided between the wall 26 of said jacket and the tiles, and if the concrete is reinforced with fibers.
All of the tiles of the assemblies shown in
As can clearly be seen here, in the preferred implementation, the invention provides a refractory thermally insulating lining that is resistant to corrosive gas, that is of low bulk, that is easy to dismantle, and that has increased reliability. This lining is particularly suitable for protecting the jacket of a gasifier reactor.
Clearly, the present invention is not limited to the above-described and shown implementations that are provided by way of non limiting illustration.
In particular, it is possible to provide a plurality of superimposed slots in a single tile so as to be able to vertically offset two side-by-side tiles and thus avoid a continuous alignment of the horizontal joints. The tiles are preferably mounted in a vertical staggered pattern, all of the tiles of one column being offset relative to the tiles of the two columns that are adjacent to it.
Further, the tiles of the invention are not limited to lining the water jackets of gasifiers.
Further, the tongues 72, the plugs 74, the hiding of the slots on the lower edge of the tiles, the grid, the castable concrete, and the arrangement of the fixing means shown in
Finally, the slots that form the suspension points do not constitute the only possible fixing points. Any point of the tile of the invention serving as a point for supporting fixing means may be considered to be a fixing point.
Number | Date | Country | Kind |
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05 02272 | Mar 2005 | FR | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/FR2006/000501 | 3/6/2006 | WO | 00 | 11/27/2007 |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2006/095081 | 9/14/2006 | WO | A |
Number | Name | Date | Kind |
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4453475 | Ploger | Jun 1984 | A |
4768447 | Roumeguere | Sep 1988 | A |
5966886 | Di Loreto | Oct 1999 | A |
6267066 | Schickling et al. | Jul 2001 | B1 |
6487980 | Wilhelmi et al. | Dec 2002 | B2 |
Number | Date | Country |
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2234051 | Jan 1991 | GB |
2234051 | Jan 1991 | GB |
Number | Date | Country | |
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20080163806 A1 | Jul 2008 | US |