This application is a U.S. national stage application of International Application No. PCT/JP2015/062418, filed on Apr. 23, 2015, the contents of which are incorporated herein by reference.
The present invention relates to a refrigeration cycle apparatus, and specifically, relates to a refrigeration cycle apparatus having a function of calculating a refrigerant amount in a refrigerant circuit.
In a conventional refrigeration cycle apparatus, when a period of use is extended in a state where clamping of connecting portions of pipes or others is insufficient, refrigerant leakage occurs little by little from a gap in clamped pipes or others in some cases. Moreover, due to damage or the like of pipes, sometimes the refrigerant leakage unexpectedly occurs. Such refrigerant leakage causes a decline in air-conditioning ability or damage to constituting equipment. Moreover, when the refrigerant circuit is excessively filled with refrigerant, pressure transfer of liquid refrigerant is performed for an extended period in a compressor, and thereby failure is caused.
Therefore, from the viewpoint of improving the quality and the maintenance easiness, it is desired that a function of calculating a refrigerant amount charged in the refrigerant circuit to determine excess or shortage of the refrigerant amount is to be provided. In Patent Literature 1, there is suggested a method of measuring operation state amounts at multiple positions in a refrigerant circuit, calculating a refrigerant amount from the measured operation state amounts and comparing thereof with an appropriate refrigerant amount to determine excess or shortage of refrigerant amount.
Patent Literature 1: Japanese Patent No. 4975052
To improve calculation accuracy of the refrigerant amount, it is necessary to improve estimation accuracy of the refrigerant amount in a condenser in which an existing amount of refrigerant is large. Here, in the method suggested in Patent Literature 1, a volumetric proportion of each of a liquid phase, a two-phase gas-liquid and a gas phase in a heat exchanger is indirectly obtained from a heat exchange amount, and thereby the refrigerant amount is calculated. In this case, since there is a need to regulate errors due to installation environment of an actual device or the like, calculation is performed by using coefficients or assuming conditions. Therefore, these become error causes and make it difficult to obtain sufficient accuracy in calculation of the refrigerant amount.
The present invention has been made to solve the above problem, and has an object to provide a refrigeration cycle apparatus capable of improving calculation accuracy of a refrigerant amount.
A refrigeration cycle apparatus according to one embodiment of the present invention includes a refrigerant circuit that includes a condenser; multiple temperature sensors that are disposed in line in a direction in which refrigerant flows in the condenser and detect refrigerant temperature of the condense, a memory unit that stores positional information of the multiple temperature sensors, and a refrigerant amount calculation unit that calculates a refrigerant amount of the condenser based on the positional information of the multiple temperature sensors, detected temperatures of the multiple temperature sensors and a saturated liquid temperature of the refrigerant.
According to a refrigeration cycle apparatus related to one embodiment of the present invention, by calculating a refrigerant amount from positional information and detected temperatures of multiple temperature sensors disposed in a direction in which refrigerant of a condenser flows, this eliminates necessity for error regulation by coefficients, and improves calculation accuracy of the refrigerant amount.
Hereinafter, embodiments of the refrigeration cycle apparatus in the present invention will be described in detail with reference to the drawings.
The compressor 11 is configured with, for example, an inverter compressor or other devices capable of performing capacity control, and sucks in gas refrigerant and discharges thereof upon compressing and bringing into a state of high temperature and pressure. The condenser 12 is, for example, a fin-and-tube heat exchanger of a cross-fin type configured with a heat transfer pipe and many fins. The condenser 12 causes the refrigerant of high temperature and pressure discharged from the compressor 11 to exchange heat with air to condense thereof. The pressure-reducing device 13 is configured with, for example, an expansion valve or a capillary tube, and reduces the pressure of the refrigerant condensed by the condenser 12 to expand thereof. Similar to the condenser 12, the evaporator 14 is, for example, a fin-and-tube heat exchanger of a cross-fin type configured with a heat transfer pipe and many fins. The evaporator 14 allows the refrigerant expanded by the pressure-reducing device 13 to exchange heat with air to evaporate thereof.
On a discharge side of the compressor 11, a discharge pressure sensor 16 that detects the discharge pressure of the refrigerant in the compressor 11 is provided. Moreover, temperature sensors 1 for detecting temperature of refrigerant flowing through the condenser 12 are provided to the condenser 12. The temperature sensors 1 includes: a first liquid-phase temperature sensor 1a disposed at an outlet of the condenser 12; a second liquid-phase temperature sensor 1b disposed upstream of the first liquid-phase temperature sensor 1a; a first gas-phase temperature sensor 1c disposed at an inlet of the condenser 12; and a second gas-phase temperature sensor 1d disposed downstream of the first gas-phase temperature sensor 1c. The temperature sensors 1 are disposed in line along a direction in which the refrigerant flows in the condenser 12. The information detected by the discharge pressure sensor 16 and the temperature sensors 1 is output to the controller 20.
Next, operations of the refrigeration cycle apparatus 100 will be described. In the refrigeration cycle apparatus 100, refrigerant in a form of low temperature and pressure gas is compressed by the compressor 11, to be a gas refrigerant of high temperature and pressure and discharged. The gas refrigerant of high temperature and pressure discharged from the compressor 11 flows into the condenser 12. The refrigerant of high temperature and pressure flowed into the condenser 12 radiates heat to outdoor air or the like, and is condensed to be a liquid refrigerant of high pressure. The liquid refrigerant of high pressure flowed from the condenser 12 flows into the pressure-reducing device 13, and is expanded and depressurized to become a two-phase gas-liquid refrigerant of low temperature and pressure. The two-phase gas-liquid refrigerant flowed from the pressure-reducing device 13 flows into the evaporator 14. The two-phase gas-liquid refrigerant flowed into the evaporator 14 exchanges heat with air or water to evaporate, to thereby become a gas refrigerant of low temperature and pressure. The gas refrigerant flowed from the evaporator 14 is sucked into the compressor 11 to be compressed again.
Note that the refrigerant usable for the refrigeration cycle apparatus 100 includes single refrigerant, near-azeotropic refrigerant mixture, zeotropic refrigerant mixture and so forth. The near-azeotropic refrigerant mixture includes R410A and R404A, which are HFC refrigerant, and so forth. Other than properties similar to those of zeotropic refrigerant mixture, the near-azeotropic refrigerant mixture has a property of operating pressure about 1.6 times the operating pressure of R22. The zeotropic refrigerant mixture includes R4070 and R1123+R32, which are HFC (hydrofluorocarbon) refrigerant, and so forth. Since the zeotropic refrigerant mixture is a refrigerant mixture having different boiling points, provided with a property of different composition ratio between the liquid-phase refrigerant and the gas-phase refrigerant.
Next, calculation of a refrigerant amount in the refrigerant amount calculation unit 23 will be described. The refrigerant amount Mr [kg] in the refrigeration cycle apparatus 100 is, as shown in Expression (1), expressed as a sum total of products of an internal cubic volume V [m3] and an average refrigeration cycle apparatus density ρ [kg/m3] of each factor.
[Expression 1]
Mr=ΣV×ρ (1)
Here, in general, most of the refrigerant stays in the condenser 12 having a high internal cubic volume V and an average refrigerant density p. Therefore, in this embodiment, calculation of the refrigerant amount of the condenser 12 in the refrigerant amount calculation unit 23 will be described. Note that a factor having a high average refrigerant density ρ described here refers to a factor of high pressure or a factor with which refrigerant of two-phase gas-liquid or liquid phase passes. The refrigerant amount Mr,c[kg] of the condenser 12 is expressed by the following expression.
[Expression 2]
Mr,c=Vc×ρc (2)
Since being device specifications, the internal cubic volume Vc [m3] of the condenser 12 is already known. The average refrigerant density ρc [kg/m3] of the condenser 12 is shown by the following expression.
[Expression 3]
ρ0=Rcg×ρcg+Rcs×ρcs+Rcf×ρcf (3)
Here, Rcg [−], Rcs [−] and Rcl [−] represent volumetric proportions of the gas phase, the two-phase gas-liquid and the liquid phase in the condenser 12, respectively, and ρcg [kg/m3], ρcs [kg/m3] and ρcl[kg/m3] represent average refrigerant densities of the gas phase, the two-phase gas-liquid and the liquid phase, respectively. In other words, to calculate the average refrigerant density in the condenser 12, it is necessary to calculate a volumetric proportion and an average refrigerant density of each phase.
First, a calculation method of the average refrigerant density in each phase will be described. The gas-phase average refrigerant density ρcg in the condenser 12 is obtained by, for example, an average value of an inlet density ρd [kg/m3] of the condenser 12 and a saturated vapor density ρcsg [kg/m3] in the condenser 12.
The inlet density ρd of the condenser 12 can be calculated from the inlet temperature of the condenser 12 (the detected temperature of the first gas-phase temperature sensor 1c) and the pressure (the detected pressure of the discharge pressure sensor 16). Moreover, the saturated vapor density ρcsg in the condenser 12 can be calculated from a condensing pressure (the detected pressure of the discharge pressure sensor 16). Moreover, the liquid-phase average refrigerant density ρcl in the condenser 12 is obtained by, for example, an average value of an outlet density ρsco [kg/m3] of the condenser 12 and a saturated liquid density ρcsl [kg/m3] in the condenser 12.
The outlet density ρsco of the condenser 12 can be calculated from the outlet temperature of the condenser 12 (the detected temperature of the first liquid-phase temperature sensor 1a) and the pressure (the detected pressure of the discharge pressure sensor 16). Moreover, the saturated liquid density ρcsl in the condenser 12 can be calculated from the condensing pressure (the detected pressure of the discharge pressure sensor 16).
Assuming that the heat flux is constant in the two-phase gas-liquid part, the two-phase average refrigerant density ρcs in the condenser 12 is expressed by the following expression.
[Expression 6]
ρcs=∫01[fcg×ρcsg+(1−fcg)×ρcsl]dz (6)
Here, z [−] refers to quality of refrigerant and fcg [−] refers to a void content in the condenser 12, and are expressed by the following expression.
Here, s [−] represents a slip ratio. Up to now, many experimental expressions have been suggested as the calculation expression of the slip ratio s, and the calculation expression of the slip ratio s is expressed as a function of a mass flux Gmr [kg/(m2s)], the condensing pressure (the detected pressure of the discharge pressure sensor 16) and the quality z.
[Expression 8]
s=f(Gmr,Pd,Z) (8)
Since the mass flux Gmr varies in accordance with the operating frequency of the compressor 11, detection of variation in the refrigerant amount Mr with respect to the operating frequency of the compressor 11 by calculating the slip ratio s by the method is conducted. The mass flux Gmr can be obtained from the refrigerant flow rate of the condenser 12. The refrigerant flow rate can be estimated by formulating the properties of the compressor 11 (relationship between the refrigerant flow rate and the operating frequency, high pressure, low pressure and so forth) into a function form or a table form.
Next, the calculation method of the volumetric proportions Rcg, Rcs and Rcl of the phases will be described.
Moreover, as shown in
Subsequently, the temperature glide dTL/dxL in the liquid phase part is calculated (S2). Here, dTL is a difference between detected temperatures of the first liquid-phase temperature sensor 1a and the second liquid-phase temperature sensor 1b, and dxL is a distance between the first liquid-phase temperature sensor 1a and the second liquid-phase temperature sensor 1b. The distance is obtained from the positional information of the first liquid-phase temperature sensor 1a and the second liquid-phase temperature sensor 1b stored in the memory unit 22. Next, the temperature glide dTG/dxG in the gas phase part is calculated (S3). Here, dTG is a difference between detected temperatures of the first gas-phase temperature sensor 1c and the second gas-phase temperature sensor 1d, and dxG is a distance between the first gas-phase temperature sensor 1c and the second gas-phase temperature sensor 1d. The distance is obtained from the positional information of the first gas-phase temperature sensor 1c and the second gas-phase temperature sensor 1d stored in the memory unit 22.
Subsequently, from the saturated liquid temperature TL1 and the saturated gas temperature TG1 estimated in S1 and the temperature glides dTL/dxL and dTG/dxG that are estimated in S2 and S3, each of the length LL of the liquid phase part, the length LS of the two phase part and the length LG of the gas phase part is estimated (S4). Specifically, a start position of the liquid phase part can be obtained by obtaining a position where an extended line of the temperature glide dTL/dxL in the liquid phase part and the saturated liquid temperature TL1 intersect with each other. From the relationship between the start position of the liquid phase part and an outlet position of the condenser 12, the length LL of the liquid phase part is estimated. Similarly, an end position of the gas phase part is obtained by obtaining a position where an extended line of the temperature glide dTG/dxG in the gas phase part and the saturated gas temperature TG1 intersect with each other. From the relationship between the end position of the gas phase part and an inlet position of the condenser 12, the length LG of the gas phase part is estimated. Further, by assuming that a part between the liquid phase part and the gas phase part is the two phase part, the length LS of the two phase part is obtained. Then, from the length of each part, the volumetric proportion of each phase is obtained (S5). Specifically, when the condenser 12 is a circular pipe and has a constant cross section, proportions of length of the phase parts to the known length of the condenser 12 are the volumetric proportions Rcg, Rcs and Rcl of the respective phases.
Then, the average refrigerant density ρc of the condenser 12 is obtained by substituting the volumetric proportions Rcg, Rcs and Rcl of the phases obtained by the volumetric proportion calculation process and the average refrigerant densities ρcg, ρcs and ρcl into Expression (3). From the average refrigerant density ρc and the known volumetric capacity Vc of the condenser 12, the refrigerant amount Mr,c of the condenser 12 is calculated. Further, by calculating the refrigerant amounts in the evaporator 14 and the connection pipe 15 by a known method and adding the refrigerant amounts in the parts together, the refrigerant amount in the refrigerant circuit of the refrigeration cycle apparatus 100 can be estimated.
As described above, in this embodiment, the volumetric proportion of each phase of the condenser 12 can be directly obtained from the detected temperatures and positional information of the multiple temperature sensors 1 disposed in the direction in which the refrigerant flows in the condenser 12. Therefore, it is possible to perform highly accurate estimation of the refrigerant amount without conducting error regulation by coefficients or the like.
Subsequently, Embodiment 2 according to the present invention will be described. Embodiment 2 is different from Embodiment 1 in the disposition of the temperature sensors 1 in a condenser 12A and the volumetric proportion calculation process. The configuration of the refrigeration cycle apparatus 100 other than these is similar to Embodiment 1.
In this case, the refrigerant amount calculation unit 23 estimates the length LL of the liquid phase part from the temperature glide dTL/dxL in the liquid phase part and the saturated liquid temperature TL1, and estimates the remaining length as the length LS of the two phase part, to calculate the volumetric proportion and the refrigerant amount. In a general refrigeration cycle apparatus, the first liquid-phase temperature sensor 1a that detects the outlet temperature of the condenser 12A is normally provided in many cases. Therefore, by employing the configuration as in this embodiment, the volumetric proportion calculation process can be performed by only adding the second liquid-phase temperature sensor 1b. Consequently, in addition to the effects of Embodiment 1, Embodiment 2 ensures the reduction of the number of parts and product costs.
Subsequently, Embodiment 3 according to the present invention will be described. In the above-described Embodiment 1 and Embodiment 2, descriptions were given by taking the case in which the single refrigerant and the azeotropic refrigerant mixture are used; however, Embodiment 3 is applied to a case in which zeotropic refrigerant is used as the refrigerant. This embodiment is different from Embodiment 1 in the disposition of the temperature sensors 2 in a condenser 12B and the volumetric proportion calculation process. The configuration of the refrigeration cycle apparatus 100 other than these is similar to Embodiment 1.
Therefore, the temperature sensors 2 disposed in the condenser 12B include a first two-phase temperature sensor 2a and a second two-phase temperature sensor 2b that detect the temperatures of the two phase part in the condenser 12B. The first two-phase temperature sensor 2a and the second two-phase temperature sensor 2b are disposed in line in the direction of refrigerant flow at the center portion of the condenser 12B. Consequently, the refrigerant amount calculation unit 23 is able to obtain the temperature glide in the direction of refrigerant flow in the two phase part (dTS/dx) from the detected temperatures and positional information of the first two-phase temperature sensor 2a and the second two-phase temperature sensor 2b. Then, by using the temperature glide and the saturated temperatures (TL1 and TG1), the length and the volumetric proportion in each phase part can be estimated.
Here, by changing the ratio of the mixed components (mixed refrigerants) of the zeotropic refrigerant mixture, the p-h diagram becomes a different one and the temperature glide of the two phase part is changed. Therefore, the distance between the first two-phase temperature sensor 2a and the second two-phase temperature sensor 2b is set so that a sufficient temperature glide (dTS/dx) corresponding to (the temperature glide of) the used refrigerant can be obtained. Specifically, for example, when the temperature glide of the used refrigerant is small, as compared to the case of the large temperature glide, the distance between the first two-phase temperature sensor 2a and the second two-phase temperature sensor 2b is set longer.
Subsequently, from the saturated liquid temperature TL1 and the saturated gas temperature TG1 estimated in S1 and the temperature glide dTS/dx calculated in S21, each of the length LL of the liquid phase part, the length LS of the two phase part and the length LG of the gas phase part is estimated (S22). Specifically, an end position of the two phase part is obtained by obtaining a position where an extended line of the temperature glide dTS/dx and the saturated liquid temperature TL1 intersect with each other. From the relationship between the end position of the two phase part and an outlet position of the condenser 12, the length LL of the liquid phase part is estimated. Moreover, similarly, the length LG of the gas phase part is estimated from the temperature glide dTS/dx and the saturated gas temperature TG1. Specifically, a start position of the two phase part is obtained from a position where an extended line of the temperature glide dTS/dx and the saturated gas temperature TG1 intersect with each other. From the relationship between the start position of the two phase part and an inlet position of the condenser 12, the length LG of the gas phase part is estimated. Further, by assuming that a part between the liquid phase part and the gas phase part is the two phase part, the length LS of the two phase part is estimated.
Then, similar to Embodiment 1, from the length of each part, the volumetric proportion of each phase is calculated (S5). Then, from the volumetric proportions and the average refrigerant densities of the liquid phase, the two phase and the gas phase, the refrigerant amount of the condenser 12B is calculated.
In this manner, in this embodiment, the length of each phase part can be estimated based on the temperature glide of the two phase part in the zeotropic refrigerant mixture. Since the range of the two phase part is relatively wide in the condenser 12B, there is a high degree of freedom in disposing the first two-phase temperature sensor 2a and the second two-phase temperature sensor 2b; therefore, it is possible to estimate the length of each phase part more reliably. Particularly, even in a condition of less subcooling, it is possible to estimate the length of each phase part accurately.
Moreover, when the zeotropic refrigerant mixture is used as in this embodiment, it is possible to estimate a quality distribution of the refrigerant in the two phase part from the position in the flow direction and the temperature of the refrigerant. Then, from the quality distribution, it is possible to calculate the two-phase average refrigerant density ρcs in each quality section by using the above-described expression (6). This makes it possible to increase the accuracy in density estimation.
Subsequently, Embodiment 4 according to the present invention will be described. Embodiment 4 is different from Embodiment 3 in the point that a correction in consideration of pressure loss in the two phase part is performed in the volumetric proportion calculation process. The configuration of the refrigeration cycle apparatus 100 other than this is similar to Embodiment 3.
For instance, in the example shown in
Here, it is possible to estimate the correction amount dTL by studying correlation between the refrigerant flow rate flowing through the condenser 12B and the dTL in advance and formulating the correlation into a table form or a function form. The estimated dTL is stored in the memory unit 22, and is retrieved when the volumetric proportion calculation process is performed. Note that the refrigerant flow rate can be estimated by formulating the properties of the compressor 11 (relationship between the refrigerant flow rate and the operating frequency, high pressure, low pressure and so forth) into a function form or a table form.
Subsequently, Embodiment 5 according to the present invention will be described. Embodiment 5 is different from Embodiment 1 in the disposition of the temperature sensors 3 in a condenser 12C and the volumetric proportion calculation process. The configuration of the refrigeration cycle apparatus 100 other than these is similar to Embodiment 1.
Then, it is determined whether or not the detected temperature Tn is lower than the saturated liquid temperature TL1 (S32). Here, it is assumed that the temperature detected by the temperature sensor 3a is T1, the temperature detected by the temperature sensor 3b is T2, and in the same manner, the temperatures detected by the temperature sensors 3c to 3f are T3 to T6, respectively. Then, in S32, when n=1, it is determined whether or not the temperature T1 detected by the temperature sensor 3a is lower than the saturated liquid temperature TL1. When the detected temperature Tn is lower than the saturated liquid temperature TL1 (S32: YES), it is determined that the temperature sensor corresponding to the detected temperature Tn (for example, the temperature sensor 3a when the detected temperature is T1) is disposed in the liquid phase part (S33).
Then, it is determined whether or not n is not more than N (S34). N refers to the number of temperature sensors, and N is 6 in the case of this embodiment. When n is not more than N (S34: YES), 1 is added to n (S35), and the process returns to S32. Then, in S32, when the detected temperature Tn is not less than the saturated liquid temperature TL1 (S32: NO), it is determined whether or not the detected temperature Tn is not more than the saturated gas temperature TG1 (S36). When the detected temperature Tn is not more than the saturated gas temperature TG1 (S36: YES), it is determined that the temperature sensor corresponding to the detected temperature Tn (for example, the temperature sensor 3c when the detected temperature is T3) is disposed in the two phase part (S37).
On the other hand, when the detected temperature Tn is more than the saturated gas temperature TG1 (S36: NO), it is determined that the temperature sensor corresponding to the detected temperature Tn (for example, the temperature sensor 3e when the detected temperature is T5) is disposed in the gas phase part (S38). Then, when it is determined in S34 that n is larger than N (S34: NO), based on the determination results in S33, S37 and S38, each of the length LL of the liquid phase part, the length LS of the two phase part and the length LG of the gas phase part is estimated (S39). Specifically, for example, when it is determined that the temperature sensor 3a is disposed in the liquid phase and the temperature sensor 3b is disposed in the two phase, it is assumed that the liquid phase part exists between the outlet of the condenser 12C and the temperature sensor 3b, and the length LL of the liquid phase part is estimated based on the positional information of the temperature sensor 3b. Similarly, when it is determined that the temperature sensor 3d is disposed in the two phase part and the temperature sensor 3e is disposed in the gas phase part, it is assumed that the two phase part exists between the temperature sensor 3b and the temperature sensor 3e, and the length LS of the two phase part is estimated based on the positional information of the temperature sensor 3e. Then, from the length of each part, the volumetric proportion of each phase is obtained (S5). Then, from the volumetric proportions and the average refrigerant densities of the liquid phase, the two phase and the gas phase, the refrigerant amount of the condenser 12C is calculated.
In this manner, also in this embodiment, effects similar to those in Embodiment 1 can be obtained. Note that, in this embodiment, the configuration was employed in which six temperature sensors 3 were disposed in the condenser 12C; however, it may be possible to employ a configuration in which the temperature sensors 3 not less than seven or not more than five are disposed in the condenser 12C. Moreover, in the example in
The embodiments of the present invention have been described above; however, the present invention is not limited to the configurations of the above-described embodiments, and various modifications or combinations within the scope of the technical idea of the present invention are available. For example, in the embodiments, as shown in
Moreover, in the above-described Embodiments 3 and 5, the configuration was employed in which the volumetric proportion in each of the liquid phase, the two phase and the gas phase was obtained; however, similar to Embodiment 2, it may be possible to employ the configuration in which the gas phase is assumed to be the two phase and the volumetric proportions of the liquid phase and the two phase are calculated. With the configuration like this, it is possible to reduce the number of temperature sensors to further reduce the costs. Moreover, in the above-described Embodiments 1, 2 and 5, description was given by taking the cases in which a single refrigerant or an azeotropic refrigerant mixture is used as examples; however, the present invention can be similarly applied to a case in which a zeotropic refrigerant mixture is used.
Moreover, the calculation method of the refrigerant amount is not limited to those described in the above embodiments. For example, the volumetric capacity of each phase can be obtained from the length of each phase and the known specifications of the condenser 12. For example, when the condenser 12 is a circular pipe, the following holds true: cross-sectional area in pipe×length of each phase part=volumetric capacity of each phase. Then, the refrigerant amount of each phase can be calculated by multiplying the volumetric capacity of each phase by the average refrigerant density.
Further, in the above-described embodiments, description was given by taking a case of the pipe configuration with no branches or merges inside the condenser 12 as an example; however, the present invention can be applied, as seen in
Moreover, it may be possible to assume any one of the branched routes 1205, 1203 as a representative route and provide the temperature sensors 12a, 12b or 12c, 12d only to the representative route, to obtain the length of each phase part in the representative route. Then, it is possible to assume the length of each phase part in the other branched routes to be similar to the length of each phase part in the representative route, to thereby calculate the refrigerant amount in each of the branched routes 1205, 1203. This makes it possible to reduce the number of temperature sensors, and to reduce the number of parts and the product cost.
Filing Document | Filing Date | Country | Kind |
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PCT/JP2015/062418 | 4/23/2015 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2016/170650 | 10/27/2016 | WO | A |
Number | Name | Date | Kind |
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7000415 | Daddis, Jr. | Feb 2006 | B2 |
8806877 | Tamaki | Aug 2014 | B2 |
20090019879 | Kasahara | Jan 2009 | A1 |
20110308267 | Tamaki et al. | Dec 2011 | A1 |
Number | Date | Country |
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102378884 | Mar 2012 | CN |
1 970 651 | Sep 2008 | EP |
07260264 | Oct 1995 | JP |
H07-260264 | Oct 1995 | JP |
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Number | Date | Country | |
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20180038621 A1 | Feb 2018 | US |