This application claims priority from U.S. Provisional Application Ser. No. 62/675,452 filed on May 23, 2018, the entire disclosure of which is incorporated herein by reference in its entirety.
The present disclosure relates to catalytic olefins conversion. More particularly, the present disclosure relates to regenerator bed temperature control of a catalytic conversion unit.
Olefins are a class of chemicals such as ethylene, propylene, and butylene. The olefins are building blocks for a wide variety of products such as plastics, rubbers, and solvents. Further, the olefins are produced from natural gas liquids and refinery products such as naphtha, kerosene, and gas oil. A wide variety of processes may be used to produce, recover, and convert the olefins. Olefins may be produced using Olefin producing technologies such as, but not limited to, steam cracking, Fluid Catalytic Cracking (FCC) and catalytic dehydrogenation (CATOFIN®). Further, olefins may be recovered using light olefins recovery technology. Olefins are converted to higher valued products such as, but not limited to, polyethylene, polypropylene, and alkylate. Olefins may be converted using Olefins conversion technology (OCT), ethylene dimerization, and comonomer production technology (CPT).
One factor that plays an important role during an operation of the catalytic olefins technology is converter/regenerator bed temperature. The present disclosure is directed to effective control of regenerator bed temperature.
For detailed understanding of the present disclosure, references should be made to the following detailed description of the preferred embodiment, taken in conjunction with the accompanying drawings, in which like elements have been given like numerals and wherein:
In aspects, in the present disclosure an advanced regulatory controller for a converter of a catalytic olefins unit is described. A catalytic olefins technology, described henceforth, may provide a method for converting low value olefins streams to valuable propylene and ethylene products. In one case, the low value olefins streams may comprise mixed butenes, pentenes, Fluid Catalytic Cracking (FCC) light gasoline, and coker gasoline. In a current design of the catalytic olefins technology, an FCC type converter (i.e., reactor-regenerator) may be combined with an ethylene style cold-end for recovery of a product. Further, in the current design, the catalytic olefins technology may include innovative heat integration features and may be designed for a regenerator bed temperature control.
In certain arrangements, when the converter/regenerator bed temperature is 703° C., then the catalytic olefins technology works appropriately. However, when the converter/regenerator bed temperature falls below a design operating point of 703° C., then excessive afterburn may be experienced in a regenerator part of the converter and a flue gas system during initial operations. Therefore, the converter/regenerator bed temperature of 720° C. or even 730° C. may be needed to reduce the afterburning.
Further, the converter/regenerator bed temperature may swing significantly from disturbances in one or more variables such as feed rate, feed temperature, disengage overhead temperature, and stripper level. In some traditional Fluid Catalytic Converters (FCC), the feed rate, feed temperature, reactor temperature or stripper level changes at times, and coke make automatically moves in a correct direction to minimize the impact on the converter/regenerator bed temperature. However, in other FCC processes, very little fuel is provided by the coke on a catalyst, thus intrinsic balancing mechanisms is missing. Embodiments of the present disclosure provide system and method to control regenerator bed temperature.
In an APC/ARC mode, the flow controller 104 of the fuel oil 106 or the tail gas 108 may receive a setpoint from an Advanced Process Control (APC) application controller 114. It should be noted that an operator may switch an operation from a basic TIC control to the APC application controller 114 using a selector (i.e., a DCS selector) or a local/remote switch on the TIC controller 102. Hereinafter, the terms APC application and ARC application may be used interchangeably. The controller 114 may be a general purpose computer having processors, memory, and algorithms.
The APC application may include selectors 116 for controlling a manipulated variable, such as flow of the tail gas (WTG) 108 or the fuel oil 106 (WFO). For example, in one case, an initial setting of the manipulated variable may be used for controlling flow of the fuel oil 106. Further, the APC application may include a controller variable such as a regenerator bed temperature (T) and disturbance variables such as feed rate 118 (i.e., feed flow) to a unit (WF), feed temperature (TF), disengager overhead temperature (TDT), stripper level (SL), and combustion air rate (AF). The APC application may further include associated variables such as a flue gas excess oxygen composition (OPV).
It should be noted that a basic design of the ARC application may be equivalent to a model predictive controller. The model predictive controller may be used to provide a feed forward element to the TIC controller 102, and thus may allow the TIC controller 102 to be more aggressive while retaining robustness of control. In the model predictive controller, a control action may be represented using below provided control equation 1:
In above mentioned equation 1, “ε” denotes model predictive error, i.e., SP−PV*, where PV* represents a model predicted steady state value of a Process Variable (PV).
Further, the above mentioned equation 1 may correspond to a Proportional Integral (P-I) controller. It should be noted that such form of APC/ARC controller may fall in a general class of controllers, i.e., a Generalized Predictive Controller (GPC). Further, a strategy of the Generalized Predictive Controller (GPC) may be used for small applications and/or for cases where model prediction may be explicitly derived. Strategy of the Generalized Process Controller (GPC) may be further employed, where a basic control strategy may be represented using a below provided equation 2.
Further, the basic control strategy may be defined in a discrete form, using a below provided equation 3.
Thus, a new setpoint for the fuel oil, WFO, may be determined using a below provided equation 4.
WFO=WFO current+ΔWFO Equation 4
In above provided equation 3 and equation 4, “ΔWFO” indicates fuel oil setpoint change from the ARC application adjusted by flue gas excess oxygen composition. “WFO current” indicates a current value of the fuel oil or the fuel gas flow rate setpoint. “ΔT” indicates bed temperature difference between the setpoint (TSP) and the ARC calculated predicted value (Tcal), where ΔT=TSP−Tcal. “K1” indicates a move suppression parameter used for tuning size of change in the manipulated variable (ΔWFO). “T” denotes an integral time parameter of the controller, and 0 and 1 subscripts used with ΔT denotes values of a parameter at a previous period of time and at a current period of time.
“GFO” denotes estimated gain between the regenerator bed temperature and flow of the fuel oil (i.e., obtained by steady state step tests in a commercial unit), and is calculated using below provided equation 5.
GFO=∂T/∂WFO Equation 5
Similarly, “GTG” i.e. estimated gain between the regenerator bed temperature and the flow of the tail gas may be determined using below mentioned equation 6.
GTG=∂T/∂WTG Equation 6
Further, the predicted regenerator bed temperature may be determined as a sum of current measured temperature and a predicted change due to changes in any or all of the disturbance variables, using below mentioned equation 7
Tcal=TPV,0+ΔTcal Equation 7
In above mentioned equation 7, “TPV” indicates a measured value of the regenerator bed temperature at the previous time period (or one time period before). In one case, when ARC execution time is fast, then the difference between TPV,1 and TPV,1 may be marginal; therefore, for the purposes of implementation, a current TPV,1 value may be used in place of a previous value, i.e., TPV,0.
ΔTcal, mentioned in above equation 7, denotes an expected future change in the regenerator bed temperature due to changes in the disturbance variables. Further, ΔTcal may be considered as a linear function of gains between the regenerator bed temperature and the disturbance variables, as defined below using equation 8.
ΔTcal=(∂T/∂WF)*ΔWF+(∂T/∂TF)*ΔTF+(∂T/∂TDT)*ΔTDT+(∂T/∂SL)*ΔSL+(∂T/∂WA)*ΔWA Equation 8
ΔTcal may be represented in a vector notation using below provided equation 9.
Further, ΔTcal may include additional constants that may allow an operator's selection of the disturbance variables to be included in the ARC application, as defined below using equation 10.
ΔTcal=C1*GF*ΔWF+C2*GTF*ΔTF+C3*GDT*ΔTDT+C4*GSL*ΔSL+C5*GA*ΔWA Equation 10
In above mentioned equation 10, values of constants C1, C2, C3, C4, and C5 may be ‘1’ while the disturbance variables are considered during calculation of “ΔTcal” and values of the constants C1, C2, C3, C4, and C5 may be ‘0’ while the disturbance variables are not used during calculation of ΔTcal. “ΔWF” denotes a change in feed flow to the unit i.e. WF1−WFO, from time to to the time t1, where t1>t0 and (t1−t0) define the ARC time period.
Further, GF may be calculated as ∂T/∂WF, where GF denotes estimated steady state gain between the regenerator bed temperature and the feed flow. ΔTF denotes a change in feed temperature to the unit, TF1−TFO, from time t0 to time t1. GTF may be calculated as ∂T/∂TF, where GTF denotes estimated steady state gain between the regenerator bed temperature and the feed temperature. ΔTTD denotes change on the disengager overhead temperature to the unit, TTD1−TTD0, from time t0 to time t1. Further, GDT denotes estimated steady state gain between the regenerator bed temperature and the disengager overhead temperature, and may be determined as ∂T/∂TDT. Further, ΔSL denotes a change on the stripper level in the unit, SL1−SL0, from time t0 to time t1. GSL denotes estimated steady state gain between the regenerator bed temperature and the stripper level, and may be determined as ∂T/∂SL. ΔWA denotes a change in the combustion air flow rate to the unit, WA1−WA0, from time t0 to time t1. GA denotes estimated steady state gain between the regenerator bed temperature and the combustion air flow rate, and may be determined as ∂T/∂WA.
Additionally, other disturbance variables such as, but not limited to, air temperature, gain, and constant may also be included in the equation 10 for calculating ΔTcal, without departing from the scope of the disclosure. As discussed above, the ARC application may include the associated variable. The associated variable may comprise flue gas excess oxygen composition (OPV) that may constrain change in the flue gas flow rate setpoint. It should be noted that a change in the flue gas excess oxygen composition may be linearly dependent on the combustion air flow rate change and the fuel flow rate change to the regenerator 110. Using the calculated value of the fuel oil 106 change (ΔWFO), change in the value of the flue gas excess oxygen composition may be determined using below mentioned equation 11 or equation 12.
ΔOcal=(∂O/∂WA)*ΔWA+(∂O/∂WFO)*ΔWFO Equation 11
ΔOcal=GOA*ΔWA+GFO*ΔWFO Equation 12
In above provided equation 11 and equation 12, “ΔOcal” denotes expected future change in the flue gas excess oxygen composition due to changes in the disturbance variables. GOA denotes estimated steady state gain between the flue gas excess oxygen composition and the combustion air flow rate, and may be determined using ∂O/∂WA. ΔWA denotes a change in the combustion air flow rate to the unit, WA1−WAO, from time t0 to time t1, where t1>t0 and (t1−t0) define the ARC time period. GFO denotes estimated steady state gain between the flue gas excess oxygen composition and the fuel gas flow rate, and may be determined as ∂O/∂WFO. ΔWFO denotes calculated value of the change in fuel gas flow rate from a previous calculation of the fuel gas flow rate.
The parameters such as GF, GTF, GDT, GSL, and GA, defined in the equation 9 and equation 10 and the parameters GOA and GFO defined in the equation 12 may be obtained by steady state step tests in the operating unit. The steady state step tests may be described later. Further, upper and lower limits on the flue gas excess oxygen composition may be defined and entered through a DCS field. It should be noted that the fuel supplied to the regenerator 110 may be limited when calculated change in flue gas excess oxygen composition forces the oxygen composition to be outside the limits. Thus, a limit checking may be performed using the below mentioned equation 13.
ΔOUP=OUP−OPV, and ΔOLO=OLO−OPV Equation 13
In above mentioned equation 13, ΔOUP denotes a difference between the flue gas excess oxygen composition value (OPV) and an upper limit for oxygen composition in the flue gas (OUP), and ΔOLO denotes a difference between the flue gas excess oxygen composition value (OPV) and a lower limit for oxygen composition in the flue gas (OLO). Further, OPV is a process value obtained from an analyzer or from a lab report.
In one case, while ΔOCAL≥ΔOUP, change in the fuel oil setpoint may be constrained using below mentioned equation 14.
ΔWFO=ΔWFO·(ΔOUP/ΔOCAL) Equation 14
Similarly, while ΔOCAL≤ΔOUP, change in the fuel oil setpoint may be constrained using below mentioned equation 15.
ΔWFO=ΔWFO·(ΔOLO/ΔOCAL) Equation 15
While the move limits are not violated, then a change in the fuel oil flow rate may not be constrained, i.e., the full move may be allowed, i.e., ΔWFO=ΔWFO. Additionally, two independent flags, UPO2 and LOO2 may be defined to indicate to the operator that the flue gas excess oxygen composition may be active. In one case, while OPV≥OUP, then UPO2=ON, otherwise UPO2=OFF. In another case, while OPV≥OLO, then LOO2=ON, otherwise LOO2=OFF.
It should be noted that a controller (i.e., TIC controller 102) may have high and low setpoint limits which may override the controller action, when the setpoint lies outside the limits. The change on the manipulated variable may have high and low limits, and may require a ramp function to adjust the setpoint smoothly and provide bumpless transfer from a regulatory action.
As discussed above, the parameters such as GF, GTF, GDT, GSL, and GA may be determined by the steady state step tests in the operating unit. For example, in a case, GF may be determined using the steady state step tests in the operating unit. Further, GF may be determined as the steady state gain value of ΔT/ΔWF, where delta values of the variables may be determined from the steady state step tests on the operating unit or from an operator training simulator system. The steady state step tests may include steady state gains that may be estimated as a ratio of a discrete steady state change in the control variables i.e. the regenerator bed temperature, to a step change in the disturbance variables or the manipulated variable. It should be noted that following method may be used for estimating the steady state gains for GF computed as ΔT/ΔWF.
At first, the operating unit may be running at a stable steady state. Further, a step change could be made on the feed flow controller. It should be noted that size of the change may be agreed with the operations before the test. Further, values of the variables may be recorded throughout the change in the feed flow 118 and at a steady state (T, WF). Thereafter, an operator may wait until the operating unit reaches a steady state or some stable operation. Successively, a value of new temperature (Tnew) may be recorded after the step change. Further, a value of change in the regenerator bed temperature (ΔT=Tnew−T) may be determined. It should be noted that the value of ΔWF may be the difference between value of the feed flow 118 after and before the step change i.e., ΔWF=WF,new−WF. Thereafter, the value of the steady step gain (GF) may be estimated as ratio of the difference values, i.e. GF=ΔT/ΔWF.
It will be apparent to one skilled in the art that the above-mentioned method for determining the gains may be applicable to other gains such as, but not limited to, gains of temperature with the flow rates of the fuel oil 106 and the tail gas 108 as well, without departing from the scope of the disclosure.
At first, the ARC application may receive one or more inputs (i.e., manual inputs) from an operator, at a step 202. The one or more inputs may include an ON/OFF activation of the ARC application, manipulated variable suppression factors K1 and K2, constants C1, C2, C3, C4, and C5 ON/OFF binary variables for inclusion of variables gains in the ARC application, and ON/OFF activation parameter of the flue gas excess oxygen composition calculation to adjusting fuel oil 106 flow rate. Based on the received inputs, steady state gains for GF, GTF, GDT, GSL, GFO, GTG, GDA, and GOF may be determined, at step 204. The steady state gains may be calculated using the steady state step tests in the operating unit.
Successively, the ARC application may receive one or more process inputs, at step 206. The process inputs may include, but not limited to, the feed rate 118 to the unit, feed temperature, disengager overhead temperature, stripper level, fuel oil flow, tail gas flow, regenerator bed temperature, flue gas excess oxygen composition, and combustion air rate. Further, data may be retrieved at T1, at step 208. The data at T1 may include WF1, TF1, TDT1, SL1, GF1, GT1, TSP, TPV,1, and WA1. Similarly, data may be retrieved at T0, at step 210. The data at T0 may include WF0, TF0, TDT0, SL0, GFO, GTG, TSP, TPV,0, and WA0.
Based on the received data at T1 and T0, change in values of variables i.e., ΔWF1, ΔTF1, ΔTDT1, and ΔSL1 may be calculated, at step 212. It should be noted that for each predefined period of time, t1−t0, the ARC application may calculate changes in the disturbance variables at the start of the time period (t0) and at the end of the time period (t1). Post calculation, the ARC application may load T0 from T1, at step 214. Further, the changes in the values of the variables along with the calculated steady state gains and the constants (i.e., C1, C2, C3, C4, and C5) may be used to determine ΔTcal, at step 216. It should be noted that values of the constants may be provided by the operator in order to determine the ΔTcal. Further, the operator may decide which of the disturbance variable gains may be used to calculate the regenerator bed temperature by setting the values of the constants C1, C2, C3, C4, and C5. Values of the constants may be set as ‘1’ while in use, otherwise may be set as ‘0’.
Successively, a manipulated variable unconstrained move may be calculated, at step 218. The manipulated variable unconstrained move may be calculated based on move suppression parameters (i.e., K1, K2) and integral time parameter (τ). The manipulated variable unconstrained move may be determined using below mentioned equation 16.
ΔWFO=K1*GFO*ΔT+1/τ(ΔT1−ΔT0) Equation 16
Based at least on the manipulated variable unconstrained move, flue gas excess oxygen composition value, and a process value, a manipulated variable move may be constrained, at step 220. Thereafter, setpoints (i.e., manipulated variable FIC setpoints) may be calculated, at step 222. The setpoints may be determined using below mentioned equation 17 and equation 18.
WFO−WFOcurr+ΔWF0 Equation 17
WTG=WTGcurr+ΔWTG Equation 18
It should be noted that flue gas excess oxygen composition constraint may be retrieved and used as a flag value, at step 224. The flue gas excess oxygen composition may be retrieved based on inputs such as OPV, OUP, and OLO. In a case, the flowrate change may be constrained by the flue gas excess oxygen composition calculation before the flowrate change may be applied to the FIC controller 104. Further, the ARC application may transmit the calculated setpoints to a controller 226. It should be noted that ARC selector and a manipulated variable selector may feed to the controller 226. Thereafter, the ARC application may change the flow rate of the fuel oil and the tail gas.
It should be noted that the predicted regenerator bed temperature may be compared with the setpoint (TSP) and the difference may be used as an error value to determine the change in the manipulated variable (WF). Further, the suggested ARC run frequency may be once per minute and may be easily tuned to run slower or faster depending on an observed quality of control. Further, in a case, the ARC setpoint may be applied to the flow controller 104 through a filter such as a ramp function, to ensure a smooth and bump less change in the manipulated variable value.
The DCS screen interface 300 may further display a target field 308 of the controlled variable 302 that the operator may use to set a target value or a desired value, and a mode field 310. It should be noted that the mode field 310 may indicate which of the variables may be used to control the regenerator bed temperature. It should also be noted that in embodiments, the disengager temperature may be replaced by the controller TIC10R01_1 set point.
As shown in
The high limits field 320 and the low limits field 322 may be changed by the operator and a flag constraint may be displayed to the operator as a change of color of the high limits field 320 and the low limits field 322. It should be noted that the flag constraint may be displayed when high limits and low limits may be reached and changed back when the high limits and the low limits are normal. The available field 326 may be changed by the operator i.e., ON/OFF to activate an adjustment of the fuel setpoint by the calculation of the flue gas excess oxygen composition. Further, the available field 326 may be used by the operator when the gain of the associated variable may be active in the ARC temperature calculation.
The DCS interface screen 300 may further display an application state field 328 that may be configured as a selector of the ARC application and the regulatory control. The application state field 328 may be used by the operator to set ON/OFF while the ARC application is active or inactive.
The DCS interface screen 400 may further display measured values field, lab input field 418, and a lab/analyzer field 420, of the associated variable. In a case, when the analyzer may not work, then a lab value may be entered by the operator in the lab input field 418. It should be noted that the lab input field 418, and the lab/analyzer field may allow the operator to set the value that may be used by the ARC application in the calculation. Further, a set of values may be selected as a default for gains, constants, and tuning values. The values may be replaced easily or restore with a use of a restore default values field 422.
The disclosed embodiments encompass numerous advantages. Various embodiments of an advanced regulatory controller for a converter of a catalytic olefins unit may be disclosed. The advanced regulatory model predictive feed forward Advanced Process Control (APC) or Advanced Regulatory Control (ARC) function may include feed-forward adjustments to the regenerator fuel in response to changes in the variables of the ARC application, and thus may result in minimizing swings in the regenerator bed temperature. Thus, functionality of the ARC application may allow the regenerator bed temperature to be maintained closer to the desired setpoint for low afterburning. Further, such system and method may include consideration of critical constraints to fuel combustion. Therefore, such operation of flue gas mechanical system will result in more stable operation and extended life of the flue gas mechanical systems.
From the above, it should be appreciated that what has been described includes a method of converting a olefin stream into a product stream. The method may include the step of feeding at least an olefin feed, a fuel oil, and a tail gas into a regenerator to produce an effluent stream; and operating the regenerator. Operating the generator may include the steps of determining at least one disturbance variable associated with the regenerator, the at least one disturbance variable being selected from one of: (i) an olefin feed rate, (ii) an olefin feed temperature, (iii) a disengager temperature, and (iv) a stripper level; predicting a change in the regenerator bed temperature based on the determined at least one disturbance variable; determining a setpoint for a flow rate of at least one input to a regenerator based on the predicted change in the regenerator bed temperature, wherein the at least one input is selected from one of: (i) a fuel oil, and (ii) a tail gas; feeding the effluent stream to generate the product stream.
In embodiments, a Distributed Control System (DCS) may be implemented to control the regenerator. As used herein, a DCS is a computer-based control system having control loops. Autonomous controllers are distributed throughout various components and devices making up the system. A central operator supervisory control oversees operation of the autonomous controllers. The autonomous controllers exchange data with the supervisory control using a suitable communication network.
From the above, it should be appreciated that what has been described also includes method of controlling the regenerator temperature in a general process of converting a olefin stream into a product stream. The method may include the steps of feeding at least an olefin feed, a fuel oil, and a tail gas into a regenerator to produce an effluent stream; operating the regenerator by: determining at least one disturbance variable associated with the regenerator, the at least one disturbance variable being selected from one of: (i) an olefin feed rate, (ii) an olefin feed temperature, (iii) a disengager temperature, and (iv) a stripper level; predicting a change in the regenerator bed temperature based on the determined at least one disturbance variable; and determining a setpoint for a flow rate of at least one input to a regenerator based on the predicted change in the regenerator bed temperature, wherein the at least one input is selected from one of: (i) a fuel oil, and (ii) a tail gas; and feeding the effluent stream to generate the product stream. Also, the controller may be implemented in a Distributed Control System.
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20200369967 A1 | Nov 2020 | US |