The present invention relates to bulk high temperature superconductors and methods for their manufacture. Of particular interest are rare earth barium copper oxide bulk superconductors with fibre reinforcement.
High temperature superconducting oxides include rare-earth based barium copper oxides. For example, the composition YBa2Cu3O7-δ (referred to herein and in the academic literature as YBCO) is a superconductor at temperatures below a critical temperature Tc, which varies with the value of δ. Rare-earth based (RE)-Ba—Cu—O ((RE)BCO) bulk superconductors in single grain form and typically with engineered microstructures have great potential to trap large magnetic fields due to their tremendous ability to pin magnetic flux vortices thereby enabling large supercurrents to flow within the size of the sample [1-9]. When an external magnetic field is applied and the material is field cooled, superconducting persistent currents are set circulating within the single grain size of the superconducting material. This effect is observed as a trapped field profile with a peak at the center and an associated field gradient is observed towards the sample edge, the slope of which is proportional to the critical current density (Jc) of the superconducting material. Put simply, the trapped field in the material is proportional to Jc*d, where d is the size of the single grain.
Over the last 30 years, extensive research has been carried out on these materials which led to the development of potential fabrication methodologies such as Top Seeded Melt Growth (TSMG) [10-16] and Top Seeded Infiltration Growth (TSIG) [17-28] techniques that enable reliable production of single grains out of these materials with success rates in excess of about 80-90%. These materials with suitable properties are key candidates for several real scale applications such as trapped field magnets, rotating electrical machines, flywheel energy storage systems, magnetic separators, fault current limiters and magnetic bearings [1-4, 29, 30].
(RE)BCO materials are type-II superconductors and are ceramic in nature. In order to achieve (RE)BCO single grains, precursor powders comprising a mixture of (RE)Ba2Cu3O7-x (RE-123) and (RE)2BaCuO5 (RE-211), enriched with a grain refining agent such as Pt or CeO2 are used. The RE-123 phase when heated above its peritectic temperature Tp melts incongruently and decomposes into a solid RE-211 phase and a barium-rich liquid phase (comprising BaCuO2 and CuO). These RE-211 and liquid phases recombine to form RE-123 on subsequent cooling of the material below the Tp of the compound. This process would usually generate multiple grain nucleation sites, resulting in the formation of a multi-grained (RE)BCO. In this context, a seed crystal with Tp greater than that of the (RE)BCO material being grown, is arranged on the pressed powder sample (cold seeding method). On cooling of the sample, the seed crystal initiates heterogeneous nucleation and subsequent growth to form a single grain exhibiting characteristic growth-facet lines both in a-b plane and along c-axis.
Recent developments made in fabrication processes have enabled production of large single-grain bulk RE-Ba—Cu—O superconductors with enhanced Jc values. Some of the notable examples are the fabrication of 65 mm diameter GdBCO—Ag single grain bulk superconductor trapping a magnetic field of 3 T at 77 K [31], increasing the flux pinning strength of (RE)BCO with proper tuning of the microstructure to achieve optimum amounts of RE-211 phase in the matrix of RE-123 [5, 32, 33] and further with additional enhancement via suitable additives and/or dopants in (RE)BCO [34-36].
Operating the (RE)BCO materials described above in either large magnetic fields or intensely in rotating patterns, or both, may be required in some real applications. However, the present inventors appreciate that the mechanical stresses to which these materials are subjected during the magnetization and subsequent operation are immense. It is found that bulk superconductors will fail mechanically when put under extreme tensile loading such as the tensile loading that is applied due to maintaining a magnetic field. For example, a magnetic field of 15 tesla can give rise to a hoop stress greater than about 100 MPa [37]. These materials are typically not reinforced, and in bare form (i.e. without reinforcement) these materials cannot withstand magnetic fields of greater than 7-8 T [38-41] even at low temperatures due to the enormous tensile forces that are generated as a result of Lorentz forces.
The material failure method for the type of loading discussed above is often a rapid failure of the superconductor and destructive strain within the bulk material [42]. A bulk superconductor that has failed due to destructive strain and subsequent cracking will be incapable of maintaining the original magnetic field magnitude due to the reduction in effective current loop size. An example of the effect of such destructive strain is shown in
Further, when two single grains are stacked one on the other, the magnetic field experienced at the center of the sample stack is large. Some of the examples which illustrate the great potential of the (RE)BCO superconducting bulk materials in trapping large magnetic fields are: 16 Tat 24 K achieved in 2002 [43], 17.24 Tat 29 K achieved in 2003 [44] and the current record magnetic field of 17.6 Tat 26 K achieved in 2014 [2]. All these results were possible only because of the fact that these materials were reinforced in one way or another. Some of the reinforcement techniques followed are complex resin impregnation or pre-stressing via a shrink-fit technique or a combination of both.
In the view of the present inventors, even when employing these complex reinforcing configurations, the success rate for samples that can trap large magnetic fields is limited due to the rather low tensile strength of the material.
Efforts have been made to improve mechanical strength of these materials. Addition of silver (whose melting point is lower than the Tp of (RE)BCO, thereby addressing unwanted nucleation/sub-grain problems) has helped in improving the mechanical strength of (RE)BCO as the silver partially fills the pores and cracks present in the ceramic material and thereby helps to prevent crack initiations and propagations to some extent when the material is exposed to large magnetic fields [45-48].
In the view of the present inventors, the addition of any other material must be carefully considered in view of the possibility of adversely affecting the chemistry of the superconducting phase and thereby affecting the likely superconducting performance of the material. Furthermore, the addition specifically of high melting point materials (higher melting point compared to (RE)BCO) must be carefully considered since otherwise there can be a severe effect on the ability to provide single grain formation, due to the creation of unwanted sub-grain nucleations.
The present invention is based on the inventors' insight that fibre reinforcement may be used to enhance the mechanical strength of (RE)BCO materials without deleteriously affecting the superconducting properties of such materials.
The present invention has been devised in light of the above considerations.
Accordingly, in a first preferred aspect, the present invention provides a bulk superconductor device comprising a single grain RE-BCO element incorporating reinforcing fibres.
In a second aspect, the present invention provides a method of manufacturing a bulk superconductor device, the method comprising:
As will be discussed in further detail below, the preferred embodiments of the invention allow successful reinforcement of (RE)BCO materials (including (RE)BCO—Ag materials) with fibres which can significantly improve the mechanical strength of these ceramic materials while maintaining the superconducting properties. For this purpose, the fibres can be distributed randomly in the bulk in order to enhance the tensile strength of the bulk isotropically.
The first and/or second aspect of the invention may have any one or, to the extent that they are compatible, any combination of the following optional features.
The term “single grain” as used in the present disclosure is widely used in the technical literature. It refers to the superconductor element having a matrix phase having an aligned crystalline orientation extending across substantially the whole element without the intervention of grain boundaries between different parts of the matrix phase. However, it is permitted for there to be heterogeneous boundaries in the superconductor element, to allow the incorporation of precipitates, other non-superconducting phases, reinforcing fibres (in the present disclosure) and also to allow the presence of at least some defects in the superconductor element.
In one preferred embodiment, the rare earth barium copper oxide is an yttrium barium copper oxide (YBCO, such as YBa2Cu3O7-δ but may be Y2Ba4Cu7O14-x or YBa2Cu4O8), erbium barium copper oxide, samarium barium copper oxide, neodymium barium copper oxide, europium barium copper oxide, gadolinium barium copper oxide, ytterbium barium copper oxide, or mixed rare-earth superconductors including (Y,Gd)BCO, (Y,Sm)BCO, (Nd,Sm)BCO, (Nd,Eu,Gd)BCO, (Nd,Sm,Gd)BCO and further suitable combinations as will be apparent to the skilled person.
Preferably, the superconductor element is a superconductor at a temperature of Tc(˜92/93 K) or below, at least in zero or substantially zero applied magnetic field.
The single grain (RE)BCO element may comprise RE-211 pinning sites distributed in a RE-123 matrix. It is therefore understood that the expression “single grain” does not necessarily require a “single crystal” structure, given that there may be phase boundaries within the single grain. Such pinning sites enhance the superconducting properties of the material via magnetic flux pinning, in magnetic fields (including self-field).
The single grain (RE)BCO element may further comprise Ag. Preferably, the element comprises at least 1 wt. % Ag, more preferably at least 2 wt. % Ag, more preferably at least 3 wt. % Ag, more preferably at least 4 wt. % Ag, more preferably at least 5 wt. % Ag. The incorporation of Ag can improve the mechanical strength against fracture, without significant deleterious effect on superconducting properties. Preferably, the element comprises not more than 20 wt. % Ag.
The single grain RE-BCO element may further comprise a grain refining agent. The grain refining agent may be selected for example from Pt or CeO2.
The reinforcing fibres may comprise a ceramic. The reinforcing fibres may comprise a refractory metal. The reinforcing fibres may be composite or hybrid fibres comprising a ceramic and a refractory metal. In some embodiments, the reinforcing fibres may comprise a refractory metal core and a ceramic cladding surrounding the core. For example, the ceramic may be SiC. For example, the refractory metal may be W. The present inventors consider that such embodiments are advantageous because the SiC, being the clad of the fibre, integrated well with the matrix and the W core retained its properties and contributed a significant enhancement of the mechanical strength of the reinforced bulk element.
The element may have a minimum dimension of at least 5 mm. This dimension may be at least 10 mm or at least 15 mm.
The element may have a maximum dimension of at least 10 mm. This dimension may be at least 20 mm, at least 30 mm, at least 40 mm or at least 50 mm.
The element may have a volume of at least 1000 mm3. The element may more preferably have a volume of at least 1500 mm3, at least 2000 mm3, at least 5000 mm3, or at least 10000 mm3.
The reinforcing fibres have a length of at least 1 mm, more preferably at least 5 mm. Such a length limitation may apply to the reinforcing fibres on average. Alternatively, such a length limitation may apply to all of the reinforcing fibres in the element.
The bulk superconductor device may further comprise external reinforcement. Such external reinforcement may be selected from one or more of:
resin and/or fibre reinforced resin reinforcement;
metallic jacket reinforcement; and
shrink-fit reinforcement.
The melt processing may be a top seeded melt growth (TSMG) process. The precursor powder may comprise a mixture of RE-123 and RE-211.
The melt processing may be a top seeded infiltration growth (TSIG) process in which the precursor body is disposed on a liquid source precursor. The precursor powder may comprise RE-211.
The present inventors have confirmed experimentally that embodiments of the invention work using the TSMG process and using the TSIG process. In the TSIG process the reinforcing fibres are incorporated in the precursor body.
A buffer pellet may be disposed between a seed crystal and the precursor body during melt processing. The inventors consider that there are three primary advantages possible due to the employment of a buffer pellet. Firstly, the seed crystal is shielded from the liquid phase component, thereby increasing the reliability of single grain growth. Secondly, it is possible to reduce or prevent cracks/unwanted defects arising from lattice-mismatch effects (Seed-Sample) from penetrating into the main (RE)BCO material. Thirdly, the buffer pellet may reduce or prevent diffusion of a seed crystal element (e.g. Nd/Sm) into main (RE)BCO element.
The invention includes the combination of the aspects and optional features described except where such a combination is clearly impermissible or expressly avoided.
Further optional features of the invention are set out below.
As will be understood, the manufacture of high temperature superconductor (HTS) materials such as RE-BCO typically requires a complex production process, with multiple calcinations of precursor materials ingredients at high temperatures (e.g. ranging from 800° C. to 950° C.) for several hours followed by sintering or melt processing. Furthermore, HTS materials require heat treatment (e.g. at about 400-850° C.) in an oxygen-containing atmosphere, optionally with associated controlled cooling, in order to control the required oxygen stoichiometry for the desired superconducting properties.
The complex role of oxygen in the manufacturing process prohibits the use of many reinforcing materials. This is because nearly all potential reinforcing materials that are suitably stable at the processing temperatures (e.g. many metals, carbon, etc.) will react/oxidize during the manufacturing process and interfere with formation of the required HTS material. Such reaction/oxidation may either create impurities or deplete oxygen at a critical time in the production process. Each of these effects can deleteriously affect the development of the required HTS properties.
Some attempts to develop useful HTS materials focus on external reinforcement such as packing-in-tube (PIT) wire production, encasing HTS in steel, or additive processes such as attempting to apply HTS as a coating on tape substrates. Both PIT and external encasing are difficult to produce economically in shapes and constructions for practical applications. Techniques which attempt to grow HTS on reinforcement substrates are experimental and, to date, far from producing significantly large HTS components for practical applications.
Attempts have been made to internally reinforce HTS using discontinuous metal fibers (Cu, Ag, Au, etc.) and particles. These have generally failed due to a) contamination during production and/or b) agglomeration of the discontinuous particles/fibres during the melt phase of production. The agglomeration can produce crack and fault planes which reduces the strength of, or even causes disintegration of, the final HTS element.
In the preferred embodiments of the present invention, reinforcing fibre comprising SiC is used. Such fibre may be long fibres or even continuous fibre. This is used for physical internal reinforcement of a HTS material to prevent cracking and contamination, which can otherwise cause the HTS material to fail. The SiC fiber with its high-aspect ratio is distributed through the pre-sintering powder then processed with the HTS sample through its normal sintering cycle.
The insight of the present inventors is that carbon fibre can be a strong reinforcing material which is stable over the wide range of temperatures involved in processing and sintering bulk HTS. However, carbon is highly reactive with oxygen which prohibits the use of most carbon fiber for internal HTS reinforcement. SiC fibre creates a durable layer of silicon dioxide SiO2 from the reaction of the silicon with oxygen. This SiO2 layer prohibits further reaction with oxygen during the remaining HTS production process. The use of continuous and/or long fiber SiC prevents the agglomeration of discontinuous fibers/particles which weakens and disintegrates the HTS crystal.
Other aspects and embodiments of the invention provide the aspects and embodiments described above with the term “comprising” replaced by the term “consisting of” and the aspects and embodiments described above with the term “comprising” replaced by the term “consisting essentially of”.
“and/or” where used herein is to be taken as specific disclosure of each of the two specified features or components with or without the other. For example “A and/or B” is to be taken as specific disclosure of each of (i) A, (ii) B and (iii) A and B, just as if each is set out individually herein.
Embodiments and experiments illustrating the principles of the invention will now be discussed with reference to the accompanying figures in which:
Aspects and embodiments of the present invention will now be discussed with reference to the accompanying figures. Further aspects and embodiments will be apparent to those skilled in the art. All documents mentioned in this text are incorporated herein by reference.
Rare-earth based high temperature ‘(RE)BCO’ superconductors have been well known not only for their fascinating properties (like zero resistance and perfect diamagnetism, below certain critical parameters) but also for the potential to be used in several real scale engineering and technological applications such as trapped field magnets, rotating electrical machines, magnetic bearings and flywheel energy storage systems. (RE)BCO ceramic superconducting materials have been well researched for the last 30 years and potential fabrication methodologies have been developed to grow single grains out of these materials which, with engineered microstructures for enhanced flux pinning, then enable the trapping of large magnetic fields as required for practical applications out of these materials. Due to the extensive work carried out on these materials, the superconducting properties such as current carrying ability (Jc) and their field dependence Jc(H), associated irreversibility fields (Hirr) have been tuned and enhanced to satisfactory levels via tuning of processing parameters and addition of suitable dopants/additives for enhanced flux pinning strength. However, their mechanical properties remain weak due to their inherent ceramic nature capped further with varieties of defects such as porosity, cracks, lattice mismatch associated stacking fault defects and more. Very often, these materials when exposed to large magnetic fields end up cracking due to enormous tensile forces that are generated due to Lorentz forces. In the present work, the inventors now disclose a powerful reinforcement methodology. In some examples of the implementation of the invention, hybrid SiC fibres containing W-core are used as reinforcing fibres, which improve the mechanical properties of these materials significantly while retaining their superconducting properties.
By the present disclosure, it is shown that fibres can enhance the internal mechanical strength of (RE)BCO materials. The intent of fibre introduction in bulk superconductors is primarily to provide additional mechanical strength by forming a composite structure, and to prevent crack growth and propagation. The mechanical strength enhancement to be achieved in bulk superconductors must be significant while simultaneously overcoming any negative effects on the current carrying capabilities of the sample. It is of interest to consider the effectiveness of the integration of the fibres into the bulk material and the manner in which the fibres are bonded to the matrix within the material.
Experimental
Different sets of YBCO single grain bulks of 16 mm, 20 mm and 25 mm in diameter were fabricated with added fibres employing the top seeded melt growth (TSMG) technique. The fibres studied in the present work are of three types: (i) metallic tungsten fibre, (ii) SiC fibres and (iii) hybrid fibres containing SiC as clad and tungsten as core. In order to prepare the single grain YBCO samples, precursor powder comprising of 75 wt. % Y-123+25 wt. % Y-211+0.5 wt. % CeO2 was used. Y-123 and Y-211 powders each of 99.9% purity were procured from Toshima Manufacturing Co. Ltd., Japan and CeO2 of 99.9% purity purchased from Sigma Aldrich were used. All the fibres studied in the present work were procured from American elements, Los Angeles, USA and were introduced into precursor powder during the compaction stage either in the mixed form or in the configurations as will be discussed in Section 3. For a fair comparison, test samples with no added fibres were also prepared in each of the sets, under similar conditions.
The influence of the added fibres on the peritectic temperature of the mixed precursor powder (comprising 75 wt % Y-123+25 wt % Y-211+0.5 wt % CeO2+fibres) was studied by subjecting the powder samples to thermal scans, employing Thermogravimetry/Differential thermal analysis (TG-DTA), to temperatures of 1200° C. with heating and cooling rates of 10° C. per minute. For single grain fabrication, the pressed pellets were capped with a 5 mm diameter buffer pellet comprising 75 wt. % Y-123+25 wt. % Y-211 and then a NdBCO or generic seed crystal [49, 50] was placed on the top of the buffer pellet. The entire assembly was then melt processed following a standard heat profile disclosed elsewhere [51]. Typically, the heat treatment comprised heating the sample assembly in a box furnace to a temperature of 1055° C. (a temperature above the Tp of Y-123 phase to promote the incongruent melting of Y-123 phase to form solid Y-211 and copper-rich liquid phase BaCuO2 and CuO). The sample assembly was then slowly cooled at the rate of 0.5-0.7° C./h through the Tp of the compound to 980° C. and then furnace cooled. This heat treatment enabled single grain growth formation. The samples thus grown were subsequently oxygenated in a tube furnace maintained at a temperature of 450° C. with and oxygen gas flow rate of 100 ml/min. The oxygenation process was carried out for 150 hours to completely transform the tetragonal, non-superconducting Y-123 phase to the orthorhombic, superconducting phase.
In order to measure the trapped field ability of the samples, each of them was field cooled to liquid nitrogen temperature (77 K) in an electromagnet (with applied field of 1.4 T). The applied external field was then removed and then the trapped field in the sample was measured employing a purpose built 3D rotating Hall sensor facility. More details of the trapped field measurement facility and methodology followed can be found elsewhere [52]. The mechanical tensile strength of the YBCO bulk superconductors with and without fibres was measured by the Brazilian technique [53-55]. For each of the samples, the circumferential surface of the oxygenated samples were polished in order to remove any irregularities. The samples were then subjected to a mechanical test by applying a compressive force parallel to the growth sector directions, as shown in
The indirect tensile strength ‘σ’ was then computed following:
Here, P is the applied load on sample when it fractures, and d and t are the diameter and thickness of the sample respectively. Samples were sliced using a diamond saw and polished down to micron-level finish, using grinding foils and colloidal suspensions containing diamond particles. The microstructure of the fractured or polished samples at every stage was observed using either a scanning electron microscope (with EDX facility) or an optical microscope equipped with polarizer. The composition of the fibre was analysed with EDX spectrometer installed on the scanning electron microscope.
Results and Discussion
YBCO single grained bulks with and without fibres in each of the sets were fabricated following the BA-TSMG technique. Details from each of these sample sets are provided in the following sections of this disclosure. It can be seen from these sections that in spite of the presence of fibres (which have higher melting point compared to the processing temperature), it remained possible to grow the samples into single grains.
W-Fibre Added YBCO
W-metallic fibres of 50 micron in diameter, were chopped into lengths of 1-6 mm and mixed with YBCO precursor powder containing 75 wt. % Y-123+25 wt. % Y-211+0.5 wt. % CeO2, using an agate mortar and pestle for 1 hour. This mixed powder was subsequently pre-sintered at 900° C. for 2 hours. The powder with and without added W-fibres were subjected to thermal scans employing TG-DTA. The results are shown in
The sintered powder containing W-fibers was compacted into pellets of 25 mm in diameter, in a steel die and supported with a NdBCO seed crystal and then subjected to BA-TSMG process which enabled them to grow into single grains. Single grained samples were thus obtained after the heat treatment and were subsequently oxygenated. They were subjected to testing in order to measure both their superconducting and mechanical properties. Trapped field measured in both the samples (YBCO with and without W-fibres) at 77 K are shown in
YBCO samples containing W-fibre when polished and further examined under scanning electron microscope (
Without wishing to be bound by theory, the present inventors propose that the reason for the deterioration of mechanical properties is likely to be due to the fact that the W-fibers have reacted completely with the aggressive liquid phase (comprising BaCuO2 and CuO) forming Y-2411 phase. The intention for adding fibres into (RE)BCO i.e. for improvement of mechanical strength was therefore not satisfied by the addition of W-fibres. This motivated the inventors to use alternative fibers that may have better phase stability with the aggressive liquid phase. The inventors therefore proposed to use a fibre such as SiC fibre. The employment of such fibres in (RE)BCO is discussed in the subsequent sections of this disclosure.
Multi-Filamentary SiC-Fibres Added YBCO
A stack of 500 multi-filamentary SiC fibres, each of the fibres being 1.5 μm in dimeter were chosen to introduce into YBCO in two different configurations:
Configuration (i)
For the first configuration, the multi-filamentary SiC fibers were chopped into lengths of 1-4 mm and were mixed with YBCO precursor powder such that the composition resulted as 75 wt. % Y-123+25 wt. % Y-211+0.5% CeO2+X wt. % SiC fibre (X=0, 0.25, 0.5 and 1) and subsequently pre-sintered at 900° C. for 2 hours, followed by through mixing in agate mortar and pestle for 1 hour. DTA scans measured in the YBCO precursor powder with and without 0.25 wt. % SiC fibres are shown in
The mixed YBCO powder containing dispersed multi-filaments of SiC-fibres was compacted into a pellet and capped with a buffer pellet and further with an NdBCO seed crystal. The entire sample assembly was then heat treated in a box furnace employing the Buffer-assisted TSMG technique. The sample of about 20 mm in diameter grew into single grain.
Trapped field (both 3-D profile and 2-D contour map) measured in the YBCO samples containing 0.25 wt % SiC fibres are shown in
Mechanical tensile strength measured in the SiC fibre-reinforced YBCO samples is shown in
Configuration (ii)
For the second configuration, the multi-filament SiC fiber stack was chopped to lengths of about 20 mm and placed at the center of the preform compact as shown in
Trapped field measured in these samples at 77 K are shown in
Mono-Filamentary Hybrid SiC Fibre Added YBCO
A composite fibre with W-core of diameter about 15 μm encapsulated in SiC cladding accounting to 100 μm diameter was examined for reinforcement of (RE)BCO. Three of these mono-filamentary SiC fibres were arranged at the center of the preform compact as shown in
Samples containing these composite fibres successfully grew into single grains. Unlike the samples reported above for configuration (ii), no major macro-cracks were formed at the side walls of the samples. These samples were oxygenated and subsequently machined for measuring the tensile strength employing the Brazilian technique. Results of the tensile strength property along with that measured in standard YBCO sample can be seen in
The sample after mechanical tests was polished and the cross-section was observed under a scanning electron microscope. This study revealed good adherence of the fibre with the YBCO matrix as can be seen from
The fact that the incorporated fibres have not created sub-grains, even in the local regions, is considered by the inventors to be impressive from the aspects of crystal growth and macro-superconducting properties. Thus it can be seen that the YBCO samples reinforced with composite SiC fibres not only retained the superconducting properties but improved the internal mechanical strength of bulk YBCO ceramics. This makes such devices suitable for many applications of the type discussed above.
The approach of providing internal reinforcement as discussed above does not rule out the advantages of providing additional external reinforcement, such as resin impregnation and/or shrink-fitting inside a reinforcing shell (e.g. of stainless steel) as discussed above. Such complementary reinforcement techniques make the device suitable for challenging applications such as motors and bearings where these products can be subjected to large rpm (rotations per minute).
Batch Processing of Fibre Reinforced YBCO—Check for Reproducibility/Repeatability
Several YBCO and GdBCO samples of different dimensions in the range 16 mm to 32 mm were successfully reinforced with the composite SiC fibres reported above. The samples were grown employing the top seeded melt growth and top seeded infiltration growth techniques. This work confirms the reproducible and repeatable nature of the reinforcement and its compatibility with the top seeded melt growth technique for forming single grain devices.
Rare-earth based high temperature superconductors have significant potential in a range of engineering and technological applications, including but not limited to, compact electric motors, friction-free self-stabilizing bearings for energy storage fly wheels and trapped field magnets. These materials in single grain form are of great interest due to the fact that they can trap magnetic fields that are almost ten times greater than similar-sized permanent magnets. Considerable work has already been devoted by various researchers to improve the superconducting properties through introduction of selective additivities/dopants/defects which improved the flux pinning strength of these composites. However, in general, the mechanical properties of these superconducting ceramics have been poor and hence have been of serious concern with respect to their practical applications. In particular, when these materials are exposed to large magnetic fields, the magnetic stresses generated (proportional to B2), can very easily fracture the materials by cracking them and forming two or more grains resulting in greatly reduced ability for them to trap magnetic field. In this context, a few efforts have been made in literature to externally reinforce the bulk superconductors by wrapping them in carbon fiber followed by complex resin impregnation, optionally further fitting the devices with steel tubes. For some applications, this is not practical from the point of view of efficient industrial production. Additionally, shrink-fitting has been employed to pre-stress the bulk superconductors in order to improve their mechanical strength.
In the present work, we have examined a relatively simple reinforcing methodology that enables internal reinforcement improving the tensile strength of the bulk (RE)BCO ceramics. Reinforcing fibres are mixed with the precursor powder. A pressed powder and fibre compact is then subjected to melt growth techniques to obtain single grains. Three different varieties of fibres were tested in the present work (a) W-metallic fibres, (b) SiC fibres and (c) composite SiC fibres containing W in its core. The single grained (RE)BCO bulks reinforced with the composite SiC fibres showed enhancement both in the superconducting and mechanical properties in comparison to the standard (RE)BCO ceramics. The combination of properties achieved by employing SiC and tungsten as reinforcing agents is found to enable better phase stability with the material while retaining the properties of tungsten since SiC has successfully shielded W from reaction with the aggressive liquid phase. Without wishing to be bound by theory, the inventors consider that this is the reason for the enhanced internal mechanical strength in these reinforced ceramic composites. These materials when further subjected to external reinforcement such as by using with stainless steel rings via shrink-fit technique can deliver robust products as required for real-scale applications.
The features disclosed in the foregoing description, or in the following claims, or in the accompanying drawings, expressed in their specific forms or in terms of a means for performing the disclosed function, or a method or process for obtaining the disclosed results, as appropriate, may, separately, or in any combination of such features, be utilised for realising the invention in diverse forms thereof.
While the invention has been described in conjunction with the exemplary embodiments described above, many equivalent modifications and variations will be apparent to those skilled in the art when given this disclosure. Accordingly, the exemplary embodiments of the invention set forth above are considered to be illustrative and not limiting. Various changes to the described embodiments may be made without departing from the spirit and scope of the invention.
For the avoidance of any doubt, any theoretical explanations provided herein are provided for the purposes of improving the understanding of a reader. The inventors do not wish to be bound by any of these theoretical explanations.
Any section headings used herein are for organizational purposes only and are not to be construed as limiting the subject matter described.
Throughout this specification, including the claims which follow, unless the context requires otherwise, the word “comprise” and “include”, and variations such as “comprises”, “comprising”, and “including” will be understood to imply the inclusion of a stated integer or step or group of integers or steps but not the exclusion of any other integer or step or group of integers or steps.
It must be noted that, as used in the specification and the appended claims, the singular forms “a,” “an,” and “the” include plural referents unless the context clearly dictates otherwise. Ranges may be expressed herein as from “about” one particular value, and/or to “about” another particular value. When such a range is expressed, another embodiment includes from the one particular value and/or to the other particular value. Similarly, when values are expressed as approximations, by the use of the antecedent “about,” it will be understood that the particular value forms another embodiment. The term “about” in relation to a numerical value is optional and means for example +/−10%.
A number of publications are cited above in order to more fully describe and disclose the invention and the state of the art to which the invention pertains. Full citations for these references are provided below. The entirety of each of these references is incorporated herein.
Number | Date | Country | Kind |
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1908788.1 | Jun 2019 | GB | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2019/078582 | 10/21/2019 | WO | 00 |
Number | Date | Country | |
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62766485 | Oct 2018 | US |