Remote actuation of a downhole tool

Information

  • Patent Grant
  • 9115573
  • Patent Number
    9,115,573
  • Date Filed
    Thursday, September 22, 2005
    18 years ago
  • Date Issued
    Tuesday, August 25, 2015
    8 years ago
Abstract
A method and apparatus for operating a downhole tool is disclosed. The method involves providing a conduit for the passage of fluid. The conduit includes at least one reader which can read data and is arranged for the passage of fluid. A downhole tool is coupled to the reader and has at least one tag capable of containing data. The tag is moved within the conduit and at least partially through the reader such that the reader can read data from the tag when the tag passes. This enables remote operation of the downhole tool. An antenna is provided for use in a downhole tubular. The antenna comprises a generally cylindrical housing and a coiled conductor located within a portion of the housing and separated therefrom by insulating material. The portion of housing has a greater internal diameter than an external diameter of the coiled conductor.
Description
FIELD OF THE INVENTION

The present invention relates to remote actuation of a downhole tool. In particular, the invention utilises RFID technology to communicate data and operating instructions to/from static readers coupled to a downhole tool such as a valve or sliding sleeve.


BACKGROUND OF THE INVENTION

During downhole drilling operations, mud and drilling fluids are circulated within the wellbore by being pumped down through the drill string and returning to the surface via the borehole annulus. Drill cuttings produced during drilling are carried up to the surface through the annulus by the drilling mud. However, in extended reach wells and/or highly deviated or slim diameter wells, the pressure of the drilling mud along the circulation path can drop from that at the surface, which results in a lower cutting lifting performance which in turn can lead to restrictions/obstructions arising in the annulus caused by accumulating cuttings.


In order to alleviate this problem, it is conventional to include one or more downhole circulating subs in the drill string which allow fluid circulation rates to be varied by selectively opening a path from the interior of the drill string to the annulus. Ports in the circulating subs can be opened and closed to enable the flow path of drilling fluids to take a different course, thereby altering the circulation time.


Conventional circulating subs typically comprise a ball seat and, in the event of a restriction in the circulation path at a location in the annulus above that of the circulating sub, a ball, of greater diameter than the seat at its narrowest point, is dropped or pumped through the drill string such that it lands on the ball seat. Once in position, the area above the ball and ball seat becomes sufficiently pressurised to move the ball seat downwards thereby uncovering the ports which enables the drilling fluids to flow through ports in the sidewall of the circulating sub and string into the annulus.


Typically, a series of circulating subs is provided within the drill string at vertically spaced apart points. In view of the method of operation of the ball seats, vertically higher ball seats necessarily have a greater inner diameter than vertically lower ball seats allowing smaller balls destined for the lower seats to bypass higher circulating subs when dropped downhole. Due to the progressively narrower inner diameter required towards the bottom of the casing, a drill string can usually only accommodate a maximum of six such circulating subs.


The aim of the present invention is to provide an improved circulation sub and an improved method of actuating downhole tools which alleviates problems associated with the prior art described hereinbefore and also provides a means of sending instructions and/or data from/to downhole tools.


BRIEF SUMMARY OF THE INVENTION

According to a first aspect of the present invention there is provided apparatus for operating a downhole tool located in a conduit for the passage of fluid therethrough, the apparatus comprising:—

    • at least one reader associated with the conduit, wherein the at least one reader is arranged to read data and wherein the at least one reader is also arranged for the passage of fluid therethrough;
    • a downhole tool coupled to the at least one reader; and at least one tag moveable through at least a portion of the conduit and the reader wherein the or each tag is capable of containing data;
    • such that the reader is capable of reading data from the tag when the tag passes through the reader, thereby enabling remote actuation of the tool.


The inner diameter of the reader can be similar to the inner diameter of the conduit such that the reader does not cause a restriction in the conduit.


The conduit can comprise any downhole tubing string such as a drill string. One example of the downhole tool may be any valve such as a sliding sleeve. “Sliding sleeve” as used herein is intended to refer to any device that can be operated to selectively provide and prevent a flow path between the drill string and the annulus. Sliding sleeves incorporate one or more ports that can be opened or closed by a sliding component and can be used as a circulation sub.


Preferably, the reader can also transmit data and information to the tag regarding operating conditions of the tool or the external environment.


The at least one tag is preferably added to fluid circulating through the conduit. The tag may be recoverable after use in the conduit.


Two or more readers and respective coupled tools can be provided, the readers being individually identifiable or selectable, wherein the tags may be selectively coded with data, such that data from each tag is capable of being received by an individual reader. Therefore, the apparatus may preferably comprise several readers coupled to respective downhole tools and a plurality of tags, with certain tags encoded with data which may be read only by a particular reader with a unique identity for operation of a specific tool.


According to a second aspect of the present invention there is provided a method for operating a downhole tool comprising the steps of:


a) providing a conduit for the passage of fluid therethrough, the conduit comprising at least one reader also arranged for the passage of fluid therethrough, wherein the at least one reader can read data;


b) coupling a downhole tool to the or each reader;


c) providing at least one tag wherein the or each tag is capable of containing data; and


d) moving the or each tag within the conduit and at least partially through the reader such that the reader is capable of reading data from the tag, when the tag passes through the reader, enabling remote operation of the tool.


The method typically comprises the step of running the downhole conduit into a borehole in between steps b) and c) or c) and d)


The method may further comprise the step of matching the inner diameter of the reader and conduit such that the inner diameter of the conduit is not restricted by the reader.


The tool coupled to a reader may be any valve such as a sliding sleeve. The conduit can be a drill string. The reader may also be arranged to transmit data.


Fluid may be circulated through the conduit and the at least one reader. Tags can be added to the circulating fluid. The method may comprise the additional step of recovering the tag after use.


Several readers may be arranged in series. The readers may have portions of conduit therebetween. The method may further comprise the step of providing each reader with a unique identity and selectively coding each tag such that a particular tag is arranged to communicate with a reader having a particular identity. In this way it is possible to target specific tools and send different operating instructions to each tool.


According to a third aspect of the present invention there is provided an antenna for use in a downhole tubular, the antenna comprising:

    • a generally cylindrical housing;
    • and a coiled conductor located within a portion of the housing and being separated from the portion of the housing by insulating material,
    • wherein the portion of the housing has a greater internal diameter than the external diameter of the coiled conductor.


At least one antenna can be provided for arrangement in a tubular.


The insulating material can be any suitable non-conducting material, such as air, glass fibre, rubber or ceramic. The antenna may further comprise a liner, wherein the coiled conductor is located or wrapped around the liner, preferably in a helical coaxial manner. Preferably, the housing and liner form a seal around the coiled conductor and insulating material. The housing can be made of steel. Preferably the liner should be non-magnetic and non-conductive to prevent eddy currents. Since the antenna is provided for use downhole, all components comprising the antenna are preferably capable of withstanding the high temperatures and pressures experienced downhole.


The antenna may operate in the frequency range 50 to 200 Khz. The optimum frequency band for the downhole work is 100 to 200 Khz. The most preferable frequency operating band is 125 to 134 Khz. The antenna should be of sufficient length to charge and read the RFID tag while passing through the antenna, allowing all data to be transferred. Preferably the length of the antenna is less than 10 m.


The antenna according to the third aspect of the invention can be used as the reader for the apparatus and method according to the first and second aspects of the invention.





BRIEF DESCRIPTION OF SEVERAL VIEWS OF THE DRAWINGS

Embodiments of the invention will be described with reference to and as shown in the accompanying drawings in which:—



FIG. 1 is a sectional view of a borehole with drill string inserted therein, the drill string having attached apparatus according to the present invention;



FIG. 2 shows a sectional view of circulation sub apparatus in accordance with the present invention;



FIG. 3 is a top sectional view of the circulation sub of FIG. 2;



FIG. 4 is a perspective view of liner and coiled conductor required for construction of an antenna according to the present invention; and



FIG. 5 is a sectional view through the antenna of FIG. 4.





DETAILED DESCRIPTION OF THE INVENTION


FIG. 1 shows a borehole 10 lined in the upper region with a casing 12. A drill string 14 made up of lengths of drill pipe 26 is provided within the borehole 10. A drill bit 16 attached to the lower end of the drill string 14 is acting to drill the borehole 10 to thereby extend the borehole 10. The drill string 14 shown in FIG. 1 has four circulation subs 18a, 18b, 18c and 18d provided therein with drill pipe 26 therebetween. It should be noted that FIG. 1 is not to scale and that there may be many lengths of drill pipe 26 provided in between each of the circulating subs 18. The drill pipe 26 and circulation subs 18 are joined by conventional threaded torque pin and box connections. Each circulation sub 18 shown in FIG. 1 comprises a sliding sleeve valve 20, a port 22 and an antenna 24.



FIG. 2 shows a more detailed sectional view of the circulation sub 18. The circulation sub 18 has three main sections; a top sub 36, hydraulic housing 58 and bottom sub 66.


Towards the upper (in use) end of the circulation sub 18 there is provided the top sub 36 in which the antenna 24 is located where the antenna is typically in the region of 10 meters or less in length. As shown in the perspective view of FIG. 4 and sectional view of FIG. 5, the antenna 24 comprises an inner liner 38 located in an enlarged bore portion of the top sub 36, where the liner 38 is formed from a non-magnetic and non-conductive material such as fibreglass, moulded rubber or the like, having a bore 96 extending longitudinally therethrough. The inner bore 96 is preferably no narrower than the inner bore of the drill string 14. A coiled conductor (not shown) typically formed of, for example, a length of copper wire is concentrically wound around the liner 38 within grooves 94 in a helical coaxial manner. Referring again to FIG. 2, insulating material 40 formed from fibreglass, rubber or the like separates the coiled conductor 94 from the recessed bore of the top sub 36 in the radial direction. The antenna 24 is formed such that the insulating material 40 and coiled conductor are sealed from the outer environment and the inner throughbore by the inner liner 38 and the inner bore of the recess of the top sub 36.


The top sub 36 is joined to the hydraulic housing 58 via a pin and box threaded torque connection 42. O-ring seals 44 are also provided to create a fluid tight seal for the connection 42.


Within the hydraulic housing 58, a bulkhead 32 is positioned between outlet ports 70, 71. The outlet ports 70, 71 are ports for a hydraulic pump 46 which lies adjacent a gearbox 48. A motor 50 is connected to an electronics pack 52, both of which are powered by a battery pack 54.


The lower end of the hydraulic housing 58 is connected to a bottom sub 66 which has ports 22 extending through its side wall such that the throughbore of the bottom sub 66 can be in fluid communication with the annulus 28 (shown in FIG. 1) when the ports 22 are uncovered by the sliding sleeve 20. The bottom sub 66 is attached to the hydraulic housing 58 in the usual manner, by threaded connection 42 which are sealed with an O-ring 44. The sliding sleeve 20 is shown in a first position in FIG. 2 covering ports 22.


The inner diameter of the bottom sub 66 is stepped inwardly to create a shoulder 68 against which a piston 60 abuts in the first position when the fluid channel provided by the ports 22 between the throughbore of the bottom sub 66 and the annulus 28 is closed. The piston 60 can also occupy a second position in which the piston 60 abuts a shoulder 56 provided towards the lower end of hydraulic housing 58. FIG. 2 shows the piston 60 occupying the first position with the piston 60 in abutment with the shoulder 68 thereby creating a piston chamber 62. The piston chamber 62 is bordered by the sliding sleeve 20, piston 60, a portion of the hydraulic housing 58 and the shoulder 56. Piston seals 64U and 64M are used to create a fluid tight seal for the chamber 62.



FIG. 3 is a top view of a portion of the hydraulic housing 58 of the circulation sub 18. Connecting lines 78 connect the first pump outlet port 70 with a first hydraulic line 72 and the second pump outlet port 71 with a second hydraulic line 73. At one end, the hydraulic lines 72, 73, 78 are sealed by plugs 88. The other ends of the first and second hydraulic lines 72, 73 are provided with a first chamber opening 76 and a second chamber opening 74 respectively. The openings 74, 76 are arranged such that they are always located within the piston seals 64U, 64L.


The hydraulic line 72 is in fluid communication with a floating piston 80 having a screw plug 82 at one end thereof.


RFID tags (not shown) for use in conjunction with the apparatus described above can be those produced by Texas Instruments such as a 32 mm glass transponder with the model number RI-TRP-WRZB-20 and suitably modified for application downhole. The tags should be hermetically sealed and capable of withstanding high temperatures and pressures. Glass or ceramic tags are preferable and should be able to withstand 20 000 psi (138 MPa). Oil filled tags are also well suited to use downhole, as they have a good collapse rating.


In operation, a drill string 14 as shown in FIG. 1 is positioned downhole. The drill bit 16 suspended on the end of drill string 14 is rotated to extend the borehole 10. Nozzles (not shown) provided on the drill bit 16 expel fluid/mud at high velocity. The drilling fluid/mud is used for bit lubrication and cooling and is also circulated up the annulus created between the outside of the drill string 14 and the inner surface of the borehole to retrieve cuttings from the bottom of the borehole 10. If higher circulation rates are desired, ports 22 can be opened to create a path between the throughbore of the drill string 14 and the annulus 28 at the location of the respective ports 22. This can be achieved using the method and apparatus of the present invention, as described below.


Initially, the ports 22 are closed as they are covered by the sliding sleeve 20, shown in FIG. 1 and in greater detail in FIG. 2.


An RFID tag (not shown) is programmed at the surface by an operator to generate a unique signal in a frequency range which is preferably 125-134 Hz. Similarly, each of the electronics packs 52 coupled to the respective antenna 24, prior to being included in the drill string 14 at the surface, is separately programmed to respond to a specific signal within the preferred frequency range 125-134 Hertz. The RFID tag comprises a miniature electronic circuit having a transceiver chip arranged to receive and store information and a small antenna within the hermetically sealed casing surrounding the tag.


The pre-programmed RFID tag is then weighted, if required, and dropped or flushed into the well with the drilling fluid. After travelling through the inner bore of the drill string 14, the selectively coded RFID tag reaches the specific circulation sub 18 the operator wishes to actuate and passes through the inner liner 38 thereof. During passage of the RFID tag (not shown) through the top sub 36 in the upper end of the circulation sub 18, the antenna 24 housed therein is of sufficient length to charge and read data from the tag. The tag then transmits certain radio frequency signals, enabling it to communicate with the antenna 24. The data transmitted by the tag is received by the adjacent receiver antenna 24. This data is processed by electronics pack 52.


As an example the RFID tag in the present embodiment has been programmed at the surface by the operator to transmit information instructing that a particular sliding sleeve 20 (such as that of the second from bottom circulating sub 18c) is moved into the open position. The electronics pack 52 processes the data received by the antenna 24 as described above and recognises a flag in the data which corresponds to an actuation instruction data code stored in the electronics pack 52. The electronics pack 52 then instructs motor 50, powered by battery pack 54, to drive the hydraulic pump 46 of that circulating sub 18c. Hydraulic fluid is then pumped out of pump outlet 70, through connecting line 78 and hydraulic line 72 and out of chamber opening 76 to cause the space between piston seals 64M and 64L to fill with fluid thereby creating a new hydraulic fluid containing chamber (not shown). The volume of hydraulic fluid in first chamber 62 decreases as the piston 60 is moved towards the shoulder 56. Fluid exits the chamber 62 via chamber opening 74, along hydraulic line 73 and is returned to a hydraulic fluid reservoir (not shown). When this process is complete the piston 60 abuts the shoulder 56. This action therefore results in the sliding sleeve 20 moving towards the hydraulic housing 58 of the circulation sub 18 to uncover port 22 and opens a path from the interior of the drill string 14 to the annulus 26.


Therefore, in order to actuate a specific tool, for example sliding sleeve 20b, a tag programmed with a specific frequency is sent downhole. Sliding sleeve 20b is part of circulating sub 18b and is coupled to an antenna 24 responsive to the specific frequency of the tag. In this way tags can be used to selectively target certain tools by pre-programming readers to respond to certain frequencies and programming the tags with these frequencies. As a result several different tags may be provided to target different tools.


Several tags programmed with the same operating instructions can be added to the well, so that at least one of the tags will reach the desired antenna 24 enabling operating instructions to be transmitted. Once the data is transferred the other RFID tags encoded with similar data can be ignored by the antenna 24.


The tags may also be designed to carry data transmitted from antennas 24, enabling them to be re-coded during passage through the borehole 10. In particular, useful data such as temperature, pressure, flow rate and any other operating conditions of the tool etc can be transferred to the tag. The antenna 24 can emit a radio frequency signal in response to the RF signal it receives. This can re-code the tag with information sent from the antenna 24. The tag is typically recoverable from the cuttings lifted up the annulus from the borehole 10.


Modifications and improvements may be made to the embodiments hereinbefore described without departing from the scope of the invention. For example the sliding sleeve can be replaced by other types of movable tools that require remote actuation. In this case the tools may be operable directly by electrical power from the battery 54, rather than by hydraulic actuation.

Claims
  • 1. A method for operating a downhole tool comprising steps of: providing a conduit having a bore for passage of fluid therethrough, the conduit comprising at least one reader, wherein the at least one reader has a bore for the passage of fluid therethrough, the at least one reader including a conductor coiled around a substantially cylindrical liner, the at least one reader is on an inner surface of the conduit so as to be exposed to the bore of the conduit, the liner being substantially non-conducting, wherein the at least one reader is adapted to read data, the conduit including an electronics pack adapted to process the data read by the at least one reader, the electronics pack is housed within an internal recess in a wall of the conduit;providing a coupling between the electronics pack in the internal recess and the at least one reader to transmit the data from the at least one reader to the electronics pack in the internal recess, wherein an inner diameter of the bore of the at least one reader is no narrower than an inner diameter of the bore of the conduit;coupling the downhole tool to the conduit and making a coupling between the downhole tool and the electronics pack in the internal recess;providing a tag containing first data;moving the tag within the conduit and at least partially through the bore of the at least one reader, such that the at least one reader reads the first data from the tag when the tag is within the bore of the at least one reader;transmitting the first data from the at least one reader to the electronics pack in the internal recess through the coupling between the at least one reader and the electronics pack;processing the first data read from the tag in the electronics pack;generating an instruction corresponding to the processed first data, and passing the instruction from the electronics pack to the downhole tool through the coupling between the electronics pack in the internal recess and the downhole tool to operate the downhole tool.
  • 2. The method according to claim 1, further comprising a step of running the conduit into a borehole.
  • 3. The method according to claim 1, further comprising a step of matching the inner diameter of the bore of the at least one reader and the inner diameter of the bore of the conduit such that the inner diameter of the bore of the at least one reader is the same as the inner diameter of the bore of the conduit.
  • 4. The method according to claim 1, further comprising a step of coupling a valve to the at least one reader.
  • 5. The method according to claim 4, further comprising a step of coupling a sliding sleeve valve to the at least one reader.
  • 6. The method according to claim 1, further comprising a step of arranging the at least one reader to transmit the data.
  • 7. The method according to claim 1, further comprising a step of circulating the fluid through the conduit and the at least one reader.
  • 8. The method according to claim 7, further comprising a step of adding the tag to the fluid that is circulating through the conduit and the at least one reader and flushing the tag through the conduit using the fluid.
  • 9. The method according to claim 8, further comprising a step of recovering the tag after use.
  • 10. The method according to claim 1, wherein there are at least two readers, and the method further comprising a step of arranging the at least two readers in series along the conduit.
  • 11. The method according to claim 10, wherein the step of arranging the at least two readers such that there is a portion of the conduit therebetween.
  • 12. The method according to claim 11, further comprising a step of providing each reader of the at least two readers with a particular identity.
  • 13. The method according to claim 12, further comprising a step of selectively encoding the tag such that the tag communicates with said each reader of the at least two readers having the particular identity.
  • 14. Apparatus for operating a downhole tool located in a conduit having a bore for passage of fluid therethrough, the apparatus comprising: at least one reader associated with the conduit, wherein the at least one reader is arranged to read data;an electronics pack housed within an internal recess in a wall of the conduit, the electronics pack having a coupling with the at least one reader, and the electronics pack is configured to receive and process said data from the at least one reader, wherein the at least one reader is arranged for the passage of the fluid therethrough, and the at least one reader includes a conductor coiled around a substantially cylindrical liner, the at least one reader is on an inner surface of the conduit so as to be exposed to the bore of the conduit, the liner being substantially non-conducting, wherein an inner diameter of a bore of the at least one reader is no narrower than an inner diameter of the bore of the conduit;the downhole tool is coupled to a sub forming at least a portion of the conduit, the downhole tool having a coupling with the electronics pack in the internal recess for transmission of an instruction between the electronics pack and the downhole tool; anda tag moveable through at least a portion of the conduit and the at least one reader, wherein the tag contains first data;wherein the at least one reader is adapted to read the first data from the tag when the tag is within the at least one reader, and the at least one reader is configured to transmit the first data to the electronics pack in the internal recess, and wherein the electronics pack is configured to generate an operation instruction to the downhole tool corresponding to the first data received by the at least one reader, and to pass the operation instruction to the downhole tool via a coupling between the at least one reader and the downhole tool to operate the downhole tool.
  • 15. The apparatus according to claim 14, wherein the at least one reader is in fluid communication with the bore of the conduit.
  • 16. The apparatus according to claim 14, wherein the inner diameter of the bore of the at least one reader is the same as the inner diameter of the bore of the conduit.
  • 17. The apparatus according to claim 14, wherein the conduit comprises a downhole tubing string.
  • 18. The apparatus according to claim 14, wherein the downhole tool comprises a valve.
  • 19. The apparatus according to claim 18, wherein the valve is a sliding sleeve valve.
  • 20. The apparatus according to claim 14, wherein the at least one reader is configured to transmit data to the tag.
  • 21. The apparatus according to claim 14, wherein at least two readers and respective coupled downhole tools are provided and wherein each reader of the at least two readers is individually identifiable.
  • 22. The apparatus according to claim 21, wherein the tag is selectively encoded with data, and wherein said each individually identifiable reader of the at least two readers is adapted to receive the selectively encoded data from the tag.
  • 23. The apparatus according to claim 14, wherein the at least one reader is an antenna, the antenna comprising a generally cylindrical housing, the coiled conductor located within a portion of the housing and being separated from the portion of the housing by an insulating material, wherein the portion of the housing has a greater internal diameter than an external diameter of the coiled conductor.
  • 24. The apparatus according to claim 23, wherein the coiled conductor is helically coiled around the liner and co-axial therewith.
  • 25. The apparatus according to claim 23, wherein the housing and the liner form a seal around the coiled conductor and the insulating material.
  • 26. The apparatus according to claim 23, wherein the liner is non-magnetic.
  • 27. The apparatus according to claim 23, wherein the antenna is operable in a frequency range from 50 to 200 kHz.
  • 28. The apparatus according to claim 23, wherein the antenna is operable in a frequency range between 125 and 134 kHz.
  • 29. The apparatus according to claim 23, wherein the antenna is of sufficient length to charge and read tag when the tag passes therethrough.
  • 30. The apparatus according to claim 23, wherein the antenna has a length of less than 10 meters.
  • 31. The apparatus according to claim 14, wherein the liner has an inner surface and an outer surface, and wherein the coiled conductor is coiled around the outer surface of the liner.
  • 32. A method for operating a downhole tool comprising steps of: providing a conduit for passage of fluid through the conduit, the conduit comprising at least one reader arranged for the passage of fluid through the at least one reader, the at least one reader including a conductor coiled around a substantially cylindrical liner, the at least one reader housed in a recess on an inner surface of the conduit the liner being substantially non-conducting, wherein the at least one reader reads data, and the at least one reader has a power supply, and wherein the conduit includes an electronics pack which processes the data read by the at least one reader, the electronics pack is housed within an internal recess in a wall of the conduit;making a coupling between the electronics pack in the internal recess and the at least one reader to transmit the data from the at least one reader to the electronics pack, wherein an inner diameter of a bore of the at least one reader is no narrower than an inner diameter of a bore of the conduit;coupling the downhole tool to the at least one reader and making a coupling between the downhole tool and the electronics pack in the internal recess;loading data onto at least one tag;moving the at least one tag through the conduit on a fluid flow and at least partially through the at least one reader;charging the at least one tag using energy from the power supply of the at least one reader when the at least one tag passes through the at least one reader, whereby the at least one tag transmits the data to the at least one reader;transmitting the data from the at least one reader to the electronics pack through the coupling between the at least one reader and the electronics pack in the internal recess;processing the data read from the at least one tag in the electronics pack;generating an operation instruction for the downhole tool in the electronics pack, the operation instruction corresponding to the processed data, and passing the operation instruction from the electronics pack to the downhole tool through the coupling between the electronics pack in the internal recess and the downhole tool to operate the downhole tool.
Priority Claims (1)
Number Date Country Kind
0425008.0 Nov 2004 GB national
PCT Information
Filing Document Filing Date Country Kind 371c Date
PCT/GB2005/003668 9/22/2005 WO 00 5/9/2007
Publishing Document Publishing Date Country Kind
WO2006/051250 5/18/2006 WO A
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Related Publications (1)
Number Date Country
20070285275 A1 Dec 2007 US