The present invention relates to a package having a sealing device, and more particularly to resealable closure for a metal beverage container.
Beverage containers typically comprise a metal can body which is closed by means of an easy open can end. Such ends are generally opened by raising a metal tab, the nose of which presses onto a scored panel, which is thus forced open to provide a pouring aperture. Such easy open ends are, however, not re-sealable.
Hinged, resealable closures for metal can ends are shown in pages 2746-2747 of the Amtsblatt des Kantons Graubünden, published on 13th Sep., 1996, and in U.S. Pat. Nos. 4,369,888; 5,622,273; 4,361,244; and 5,199,618. None of these closures have achieved significant commercial success. There is a need for improved resealable closures that can easily be opened and resealed.
A can end combination includes a metal can end and resealable closure coupled to the can end. The can end includes a peripheral wall and a center panel having an upper surface, an opposing lower surface, and an aperture formed therethrough. The closure includes a base plate that is coupled to the can end center panel and includes a recess formed therein and an opening formed therein; a middle plate that includes a plug and is connected to the base plate by a first hinge; and a top plate that includes at least one prong and is connected to the middle plate by a second hinge. At least one of the can end aperture and the closure base plate form a pour opening.
The closure has (i) a fully closed position in which the base plate, middle plate, and top plate are in mutually contact, the plug is located in the pour opening to obstruct the pour opening, and the at least one prong of the top plate is located in the recess of the base plate, (ii) a intermediate position in which at least the top plate is in an oblique position relative to horizontal, (iii) a fully open position in which the plug is spaced apart from the pour opening and the prong is spaced apart from the recess, and (iv) a reclosed position that is enabled after initial opening and in which the plug is located in the pour opening to obstruct the pour opening, and the at least one prong is located in the recess. The prong enhances the opening and closing processes of the closure.
In a first embodiment, an extension of the closure base plate extends through the aperture in the end and includes a hoop having a sidewall that defines the pour opening, and the plug is located in the pour opening when the closure is in its fully closed position. In a second embodiment, the base plate includes a rim at a periphery of the opening, and the can end includes a curl that extends over at least a portion of the inner periphery. The curl defines the pour opening such that the plastic plug contacts the metal curl when the closure is in its fully closed position. The plastic to metal contact that forms the seal may diminish the effect of the reweld location of the base plate.
Preferably, the plug has a sidewall having a bead capable of contacting the curl when the closure is in its fully closed position. Preferably, the plug panel includes a ramp, and a portion of a rim of the ring of the top plate contacts the ramp to enhance insertion of the plug into the pour opening while the closure is moved toward the reclosed position.
Preferably, the base plate includes an overhang that forms the recess, and the at least one prong contacts a bottom surface of the recess as the top plate is moved from its fully closed position to its intermediate position. Preferably, the bottom surface of the recess is formed by the upper surface of the can end center panel. The at least one prong preferably is a pair of prongs at a foot of the top plate and the recess is a pair of recess formed at a rear of the base plate. Distal tips of the prongs slide on the upper surface of the end while the top plate moves from its fully closed position to the intermediate position. The top plate pivots and upwardly translates while the top plate moves from its fully closed position to the intermediate position such that the movement of the top plate toward the intermediate position lifts at least a portion of the plug from the pour opening. Preferably, the at least one prong is inserted into the recess and an upper surface of the prong contacts the underside surface of the recess during the closing process to the reclosed position.
Preferably, the top plate includes a ring extending downwardly from an underside thereof, and the ring contacts an inside surface of the plug while the closure is in the fully closed position. The plug includes a plug panel and a peripheral sidewall, and the plug panel has a radial thickness that is greater than a radial thickness of the plug sidewall. Also, the plug sidewall has an outside diameter that is less than an inner diameter of the pour opening. The top plate includes a ring extending downwardly from an underside thereof. The ring has an outside diameter that is greater than an inside diameter of the plug sidewall, and the ring has a radial thickness that is greater than the radial thickness of the plug sidewall. The ring extends into the plug while the closure in its fully closed position such that an outside surface of the ring urges the plug sidewall radially outwardly into contact with the pour opening sidewall.
Preferably, the middle plate includes a vent hole and the top plate includes a vent hole stopper that is located in the vent hole to seal the vent hole while the closure is in its fully closed position. The ring includes vents formed therein for enabling communication across the ring for releasing pressure upon release of the vent hold stopper from the vent hole.
The prongs may contact a seam that couples the can end to the can body such that the top plate and middle plate are releasably retained and spaced apart from the pour opening. Or a foot of the top plate may contact a seam that couples the can end to the can body such that the top plate and middle plate are releasably retained and spaced apart from the pour opening.
The closure has features that exploit a cold deformation process. In this regard, in the first embodiment, the base plate includes a downwardly extending hoop that extends through the aperture in the can end center panel. The hoop has a bottom flange that extends radially outwardly to clamp the base plate to the can end center panel. The bottom surface of the flange has alternating peaks and valley formed therein during application of the closure to the can end, whereby clamping is enhanced. The peaks and valleys encompass any relatively high portions adjacent relatively low portions.
The base plate includes an upwardly protruding stake (protruding from the base plate) that engages the top plate while the closure is in the fully closed position. The stake becomes disengaged from the top plate upon moving the top plate from the fully closed position toward the intermediate position, thereby providing tamper evidence. The stake preferably includes a rivet head that protrudes through an aperture in the top plate to engage the top plate. The aperture may include a countersink in which the rivet head is disposed while the closure is in its fully closed position. In a first embodiment, the rivet head is pulled through the aperture upon moving the closure from its fully closed position toward its intermediate position. The rivet head is not insertable back into the countersink after initial opening of the closure such that the head is not located in the countersink while the closure is in the reclosed position. Alternative to the first embodiment tamper evident feature above, the top plate may include a web in which at least a part of the aperture is formed. A rivet head is located in or above the web while the closure is in its fully closed position, such that the web is ruptured upon moving the closure from its fully closed position toward its intermediate position.
An injection mold having a cavity for forming the closure describe above is also provided.
According to another aspect of the invention, a closure includes an unapplied state and an applied state in which the closure is applied to an aperture in a center panel of a metal can end. The closure in its unapplied state comprises: a base plate including an opening sidewall forming an aperture therein; a middle plate including a plug and connected to the base plate by a first hinge; a top plate connected to the middle plate by a second hinge; and a stake protruding upwardly from the base plate through an aperture in the top plate. The stake in its unapplied state has a hollow distal portion. In its initially applied state, the stake distal portion is deformed into a rivet-shaped head that is located over a portion of the top plate, and the base plate, the middle plate, and the top plate are in mutual contact.
According to another aspect of the invention, a method for applying a resealable closure to a metal can end comprises the steps of: providing a resealable closure (described below); providing a metal can end including a center panel having an aperture formed therein and a curl located at the periphery of the aperture; placing the closure onto an upper surface of the metal end such that the base plate hoop extends through the can end aperture; providing a cool deforming tool that includes alternating peaks and valleys; and contacting the tool against a lower portion of the hoop in a cool state to deform a portion of the hoop in a peaks and valley pattern, whereby the closure is clamped onto the can end. The closure includes a base plate including a hoop that forms an opening; a middle plate including a plug and connected to the base plate by a first hinge; a top plate connected to the middle plate by a second hinge; and a stake protruding upwardly from the base plate through an aperture in the top plate. Preferably, the curl directly extends from a substantially horizontal portion of a center panel of the can end, and the contacting step includes forming a recess in which the curl is at least partially located.
According to another aspect of the invention, a method for making a resealable can end comprises the steps of: providing a closure that includes a base plate including a rim that defines an opening therein, a middle plate including a plug and connected to the base plate by a first hinge, and a top plate connected to the middle plate by a second hinge; providing a metal can end including a peripheral curl and center panel having an aperture that is defined by an edge; locating the can end relative to the closure; and forming the can end edge into a curl that grips the base plate rim to secure the can end and closure together. Preferably, the step of providing a metal can end includes pressing the edge into an upstanding position, and the step of forming the can end edge includes crimping the upstanding edge downwardly and radially outwardly over the closure rim.
According to another aspect of the present invention, a method of forming a tamper-evidence feature on a closure comprises the steps of: providing a closure that includes a base plate including an opening sidewall forming a pour opening, a middle plate including a plug and connected to the base plate by a first hinge, a top plate having an aperture and connected to the middle plate by a second hinge; and a stake protruding upwardly from the base plate. The stake has a hollow distal tip. Then, the method includes positioning the top plate relative to the base plate such that the stake protrudes through at least a portion of an aperture; providing a cool deforming tool; and contacting the tool against the stake tip and deforming the tip into a rivet-shape head while the stake is cool, whereby the stake head is located over a portion of the top plate while the closure is in its initial fully closed position. The step of providing the closure includes providing a top plate having a top plate panel, a tab, and a hinge coupling the panel and the tab. The aperture is formed in the tab such that the head is capable of being pulled through the aperture upon initial opening. The tamper evident features may be as described above.
According to another aspect of the invention, a method of applying a resealable closure to a metal can end comprises the steps of: providing a closure that includes a base plate including a hoop that forms an opening, a middle plate including a plug and connected to the base plate by a first hinge, a top plate connected to the middle plate by a second hinge, and a stake protruding upwardly from the base plate through an aperture in the top plate; providing a metal can end including a center panel having an aperture formed therein and a curl located at the periphery of the aperture; placing the closure onto an upper surface of the metal end such that the base plate hoop extends through the can end aperture; providing a cool deforming tool that includes alternating peaks and valleys; and contacting the tool against a lower portion of the hoop in a cool state to deform a portion of the hoop in a peaks and valley pattern, whereby the closure is clamped onto the can end. Preferably, the curl directly extends from a substantially horizontal portion of a center panel of the can end, and the contacting step includes forming a recess in which the curl is at least partially located.
The combination includes various features that enhance the resealability, easy of use, manufacturing, and the like. The present invention, however, is not limited to any configuration having any particular advantages or to any configuration or function identified as an aspect of the invention.
A package 10 includes a can body 12, a can end 14, and a closure 16. Preferably, can body 12 is a conventional metal can used for carbonated or non-carbonated beverages and includes a seam 18 joining can body 12 to end 14.
As shown for example in
As shown in
Base plate 20 includes top portion 22 and a downwardly descending hoop 24 that forms a pour opening 26, as best illustrated by
On the underside of base plate 20, hoop 24 includes an outwardly extending flange 34 that is formed by deforming hoop 24 such that flange 34 clamps against an underside of curl 212. Preferably, hoop 24 and sealing rim 30 form a radially outwardly facing recess 38 for receiving curl 212.
As illustrated by dashed lines in
A pair of opposing recesses 44 are formed in upper portion 22 at the rear of base 20. Each recess 44 preferably is formed by an overhang 46 that has a front-facing opening. Preferably, recess 44 is formed by a floor 48, which preferably is the upper surface 42 (FIG. 9B) of the panel of end 14, and an underside 50 of overhang 46. The front edge of overhang 46 forms a front lip or front face 52.
A pair of opposing, approximately planar wings or extensions 54 extend opposite recesses 44. A stake 56 extends upwardly from each extension 54. Preferably, each stake includes a rivet-like head 62.
Middle plate 70 includes a plug 72 from which a flange 73 extends. Flange 73 is connected to base plate 20 by hinge 99a. Plug 72 includes a plug panel 74 that is approximately circular, and a peripheral plug sidewall 76 that extends upwardly from plug panel 74. Panel 74 is raised relative to the bottom end of sidewall 76 such that a circumferential groove 92 extends around panel 74.
A rear portion of plug panel 74 has is an incline or ramp 90 that is inclined relative to the relatively horizontal portion (that is, as oriented in the closure's fully closed position) of panel 74. As best shown in
Plug sidewall has an inner surface 78 and an outer surface 80, which preferably includes a circumferential rib 82 that protrudes from the surface of outer surface 80. A vent hole 84 preferably is formed through plug panel 74. Preferably, vent hole 84 has circular cross section and is defined by a sealing surface 84 that has a bead or rib 88 about its inner circumference. Preferably, the thickness of sidewall 76 is significantly less than the thickness of panel 74 to enable plug 72 to deform, as explained more fully below.
Top plate 100, which is connected to middle plate 70 by a hinge 99b, includes a top panel 102 having a lip or edge 104 at a front portion thereof. A circular support ring 106 extends downwardly from the underside of panel 102, and a cylindrical stopper 118 extends downwardly from the underside of panel 102 within the circumference of ring 106. Ring 106 preferably is circular and sized to fit within groove 92 about the periphery of plug panel 74. Preferably, ring 106 terminates in a rim 114 that is circular and parallel to top plane panel 102. An outer surface 108 of ring 106 includes channels 110. Stopper 118 has a tapered tip 119.
A tab 120 extends from the front edge 104 of top plate 100. Tab 120 is connected to top plate 100 by a pair of opposing hinges 99c. A hollow or cutout 122 is formed between the body of tab 120 and top plate front edge 104. A pair of wings 124 extend outwardly from the body of tab 120. Each wing 124 includes an aperture 126 having a contact surface 128 for receiving stake head 62. Preferably, and as best shown in
A pair of prongs 115 extends from the rear of top plate panel 102. Each prong 115 has a body 116 that terminates in a distal tip 117. Body 116 preferably is short protrusion that extends downwardly and outwardly from panel 102, or outwardly from an underside of panel 102. The prongs 115 are spaced apart by nearly the entire width of panel 102. Prongs 115 are sized in cross section to fit into recess 44 formed in the top plate. Each prong 115 has a length (that is, the distance that prong 115 extends from top plate panel 102) such that its distal tip 117 contacts recess floor 48 during the opening process. In this regard, the length of each prong 115 preferably is less than the height of recess 44, which in the embodiment shown may be defined by the distance from recess floor 48 to the underside 50 of overhang 46.
Flange 73 of middle plate 70 may contact base plate main portion 22, and plug 72 is located in the pour opening 26 such that outer surface 80 of plug sidewall 76 contacts hoop inner sidewall 28 of base 20. Plug sidewall rib 82 is located beneath sealing rim 30 of base 20. Preferably, the rib 82 is engaged with sealing rim 30 to enhance the seal between plug 72 and hoop inner sidewall 28. Preferably, the diameter of sidewall outer surface 80 is less than the inner diameter of hoop inner sidewall 28.
The support ring 106 of top plate 100 is located in the groove 92 of plug 72. Preferably, the support ring outer surface 108 has a diameter that is larger than the diameter of plug sidewall inner surface 78 such that support ring 106 expands plug 72 against hoop inner sidewall 28 to enhance the seal between the plug and the base. Vent stopper 118 is located in vent hole 84 and in contact with vent hole sealing surface 86. Rib 88 on sealing surface 84 enhances the seal between stopper 118 and sealing surface 86.
Stakes 56 are located within and protrude through holes 126 in tab 120. Heads 62 preferably are in contact with conical surfaces 128 to retain tab 120 in its fully closed position, which is flat against or near base 20 or inline with top plate panel 102.
Prongs 115 are located at least partly in recesses 44. Preferably, a lower surface of each prong 115 is in contact with can end upper surface 207, and an upper surface of each prong is spaced apart from underside 50 of overhang 46 to enable movement of prong 115 within recess 44.
The user may position his finger within cutout 122 or contact edge 104 of top plate 100 to continue the opening process.
As top plate 100 is moved from its first opening position (
As top plate 100 moves from its fully closed position, stopper 118 is pulled from vent hole 84, which releases pressure (if any) from the interior of package 10. Preferably, plug 72 is engaging hoop sidewall 28 at this stage, and the channels 110 provide venting to the atmosphere.
From the position shown in
To reclose closure 16, a user unclips top plate 100 from seam 18 and guides or folds plug 72 into opening 26. Plug 72 readily fits into aperture 26 because the outer diameter of aperture 26 is less than the inner diameter of aperture. Taper 32 of hoop inner sidewall 28 guides plug 72 to aperture 26 if necessary, and the relatively thin plug sidewall 76 enables some deformation of plug 72 if necessary. The tapered tip 119 of stopper 118 and the tapered surface of the upper portion of vent hole 84 guide stopper 118 into vent hole 84
Prongs 115 may be inserted into recesses 44. Then upon pushing down on top plate 100, a lever with great mechanical advantage is formed as body 116 of prong 115 pivots on the underside 50 or front rim 52 of overhang 46. This lever action enables closing of closure 16 even by users with slight hand strength. Further, the rear portion of support ring lip 114 contact ramp 90 and may impart a force (with large mechanical advantage) on the rear portion of plug 72 to urge plug 72 into opening 26.
Closure 16 only closes to the first open position (as illustrated in
A method of applying closure 16 to an unseamed can end begins with closure 16 in its as molded state, which will be referred numeral 16′. Closure 16′ is positioned on the unseamed can end 14′ such that (as yet) undeformed hoop 24′ is located in aperture 206. A cylindrical tool in inserted into hoop 24′ to prevent or limit inward deflection, and opposing tools deform hoop 24 to form flange 34. An upper tool contacts the upper surface 207 and a punch contacts the bottom of hoop 24′. Preferably, the punch has alternating peaks and valleys, which enables deformation of hoop 24′ at a lower total force. Preferably, both the tool and the closure are at or near ambient temperature (and are unheated), which simplifies application of closure 16′. The lower application force (compared with a punch having a flat face rather than peaks and valleys) is beneficial to prevent or diminish the deformation of curl 212 caused by radially outward deformation of hoop 24′.
Center panel 204a includes an upper surface 207a and a lower surface 208a. A curl 212a is formed about the inner periphery of aperture 206a. Preferably, curl 212a extends directly from a planar and horizontal portion of center panel 204a without a raised or vertical wall section (in transverse cross section). Curl 212a is more fully described below. The present invention encompasses can ends of any configuration, including for example can ends having a spout portion on which the curl is formed, ends that form a dome shape, and other configurations. Accordingly, the term “center panel” as used herein is not limited to flat or planar surfaces of a conventional beverage can ends.
As shown in
As best shown in
Recesses 44a are formed in upper portion 22a at the rear of base 20a. Recess 44a is shown schematically in dashed lines in
Middle plate 70a includes a plug 72a from which a flange 73a extends. Flange 73a is connected to base plate 20a by hinge 99a. Plug 72a includes a plug panel 74a that is approximately circular, and a peripheral plug sidewall 76a that extends upwardly from plug panel 74a. Panel 74a is raised relative to the bottom end of sidewall 76a such that a circumferential groove 92a extends around panel 74a.
Plug panel 74a has a vent hole 84a, an incline or ramp 90a, like corresponding vent hole 84a and ramp 90a described for first embodiment closure 16. As best shown in
Top plate 100a is connected to middle plate 70a by a hinge 99b, and includes a top panel 102a having a lip or edge 104a at a front portion thereof, a circular support ring 106a, and a cylindrical stopper 118a as described for first embodiment top plate 100. Second embodiment 16a is shown without stakes, although stakes and like tamper evident features may be employed. A pair of prongs 115a extends from the rear of top plate panel 102a, as described for first embodiment top plate 100a.
To form closure 16a, and can end (not shown in its finished state) is formed having and an aperture is cut in the center panel 204a. A ring-like vertical wall is formed at the periphery of the aperture. Closure 16a is positioned on upper surface 207a of center panel 204a, and the vertical wall is crimped radially outwardly and downwardly over rim 23a to form curl 212a secure closure 16a to center panel 204a.
The closure, such as closure 16a, preferably is formed by injection molding with a single sprue location on plug panel 74a. The plastic flows splits to flow around the opening and rim 23a of base plate 20a to meet at a reweld location 27a, as indicated on
Referring generally to the figures, and particularly to
The present invention is illustrated by referring to the embodiments described herein. Features of any of the embodiments may be added or subtracted to any other embodiment, as the description of the embodiments is illustrative. The present invention is not limited to the particular structure or function of the embodiments, but rather encompasses the structure and function defined in the claims, as will be understood by persons familiar with plastic closures and metal beverage cans in view of the present disclosure.
Number | Name | Date | Kind |
---|---|---|---|
3250425 | Stec et al. | May 1966 | A |
3262612 | Tabor | Jul 1966 | A |
3287053 | Stec et al. | Nov 1966 | A |
3386613 | Traynor | Jun 1968 | A |
3406867 | Westphal et al. | Oct 1968 | A |
3447713 | Stec et al. | Jun 1969 | A |
3450301 | Stec et al. | Jun 1969 | A |
3520440 | Kinnavy et al. | Jul 1970 | A |
3622034 | Lutzker et al. | Nov 1971 | A |
3705670 | Douty | Dec 1972 | A |
3744662 | Zundel | Jul 1973 | A |
3788512 | Brahler | Jan 1974 | A |
3871544 | Peyser | Mar 1975 | A |
3910410 | Shaw | Oct 1975 | A |
3952911 | Bozek et al. | Apr 1976 | A |
4054205 | Blow, Jr. et al. | Oct 1977 | A |
4098439 | Blow, Jr. et al. | Jul 1978 | A |
4122970 | Amabili | Oct 1978 | A |
4127221 | Vere | Nov 1978 | A |
4136797 | Potts | Jan 1979 | A |
4150777 | Cyr et al. | Apr 1979 | A |
4266688 | Reid | May 1981 | A |
4361244 | Walter | Nov 1982 | A |
4369888 | Walter | Jan 1983 | A |
4397400 | Walter | Aug 1983 | A |
4397403 | Guimarin | Aug 1983 | A |
4407423 | Walter | Oct 1983 | A |
4431110 | Roth | Feb 1984 | A |
4440310 | Heyn | Apr 1984 | A |
4462504 | Roth et al. | Jul 1984 | A |
4540611 | Henderson | Sep 1985 | A |
4576306 | Kelsey et al. | Mar 1986 | A |
4681238 | Sanchez | Jul 1987 | A |
4746032 | Huang | May 1988 | A |
4821912 | Wells | Apr 1989 | A |
4915290 | Robichaud et al. | Apr 1990 | A |
4930654 | Thibeault et al. | Jun 1990 | A |
4951835 | DeMars et al. | Aug 1990 | A |
5085338 | Inagaki | Feb 1992 | A |
5148935 | Lyon | Sep 1992 | A |
5199591 | Thibeault et al. | Apr 1993 | A |
5199618 | Reil et al. | Apr 1993 | A |
5242073 | Willis et al. | Sep 1993 | A |
5335808 | Lee | Aug 1994 | A |
5351853 | Shock | Oct 1994 | A |
5622273 | Kelly | Apr 1997 | A |
5692633 | Gordon | Dec 1997 | A |
5711447 | Plester | Jan 1998 | A |
5813561 | Chang et al. | Sep 1998 | A |
5829610 | Rohr et al. | Nov 1998 | A |
5947317 | Hall | Sep 1999 | A |
6065634 | Brifcani et al. | May 2000 | A |
6105806 | Stasiuk | Aug 2000 | A |
6581264 | Ohori et al. | Jun 2003 | B2 |
6588617 | Majcen et al. | Jul 2003 | B1 |
6763963 | Martin | Jul 2004 | B1 |
7152766 | Walsh et al. | Dec 2006 | B1 |
7168586 | Jeon | Jan 2007 | B2 |
7198168 | Mizuma | Apr 2007 | B2 |
20020050493 | Ball et al. | May 2002 | A1 |
20030062370 | Ball et al. | Apr 2003 | A1 |
20030178433 | Adams | Sep 2003 | A1 |
20050051553 | Li et al. | Mar 2005 | A1 |
20050115977 | Dibdin et al. | Jun 2005 | A1 |
20050150889 | Perra | Jul 2005 | A1 |
20050173453 | Azodi | Aug 2005 | A1 |
20060163253 | Steadman | Jul 2006 | A1 |
20070068943 | Ramsey | Mar 2007 | A1 |
20070145055 | Gardiner | Jun 2007 | A1 |
20070164026 | Morrissey | Jul 2007 | A1 |
20070215620 | Kasper | Sep 2007 | A1 |
20070262079 | Paris | Nov 2007 | A1 |
20080053997 | Perra | Mar 2008 | A1 |
20080314904 | Perra | Dec 2008 | A1 |
20090173737 | Ramsey | Jul 2009 | A1 |
20090179033 | Ramsey | Jul 2009 | A1 |
Number | Date | Country |
---|---|---|
0 088 185 | Sep 1983 | EP |
0305598 | Mar 1989 | EP |
0828663 | Dec 1999 | EP |
1767464 | Mar 2007 | EP |
1434827 | Jun 1966 | FR |
2154561 | Sep 1985 | GB |
2320008 | Jun 1998 | GB |
61-48128 | May 1994 | JP |
2003-054549 | Feb 2003 | JP |
2003-112735 | Apr 2003 | JP |
2000-17742 | Apr 2000 | KR |
WO 9110600 | Jul 1991 | WO |
WO 9504709 | Feb 1995 | WO |
WO 9609968 | Apr 1996 | WO |
WO 9836987 | Aug 1998 | WO |
0128875 | Apr 2001 | WO |
WO 0200512 | Jan 2002 | WO |
WO 03062084 | Jan 2003 | WO |
2007039367 | Apr 2007 | WO |
WO 2007128810 | Nov 2007 | WO |
WO 2008054636 | May 2008 | WO |
WO 2008068169 | Jun 2008 | WO |
WO 2009062004 | May 2009 | WO |
Number | Date | Country | |
---|---|---|---|
20080110887 A1 | May 2008 | US |