The present preferred embodiment relates to reclosable seals for substantially environmentally impermeable, reversible sealing as well as for substantially environmentally impermeable filling and/or decanting of bulk material from containers or tube elements and docking systems containing these reclosable seals.
In addition, the preferred embodiment relates to multiple coupling seals containing the inventive reclosable seals, as well as to multiple docking systems containing these multiple coupling seals.
As a rule very high demands with respect to ongoing reliability and environmental sealing are placed on seals or respectively coupling seals, which are used for decanting of bulk material made of e.g. flexible containers. For many bulk materials in minimal quantities are already toxic for the human organism. In addition, certain bulk materials are very sensitive to air and moisture and must be kept completely separate from surrounding air at every processing stage and naturally also during decanting. Bulk materials for further processing also frequently have to satisfy very high purity criteria and in no way may be contaminated from the outside by any contamination. The necessity to work contamination-free in particular in the food-processing, chemical or pharmaceutical industries results in high equipment and safety-related expense, which inevitably manifests in manufacturing costs.
Bulk material can be decanted for example environmentally impermeably from containers by means of double valve technology, such as described in DE 695 04 581 T2. Such docking mechanisms according to double valve technology are structurally highly intricate and thus generally also costly.
Structurally simpler docking mechanisms, such as those disclosed in PCT/EP02/12010, use e.g. elastically deformable coupling elements, which in each case have a superimposed slot, which is closed in the basic state and can be opened by application of pressure. With this configuration of a docking mechanism particular care is to be exercised that the slots of the juxtaposed coupling elements are of the same length and are superimposed exactly over one another.
The unpublished German patent application with file reference 103 21 814.9 on the other hand discloses a coupling element for environmentally insulated decanting, filling and/or emptying of containers, composed substantially of two flush sealing strips, having at their ends mutually engaging articulated bodies, which can be rotated about common bearing axis elements. The articulated axis elements or respectively articulated caps have to be precisely matched to the shape and size of the bearing element of the sealing strips so as to be able to function permanently and reliably as axis bearings. Opening and closing of this coupling element is accomplished by the opposite articulated bodies being moved towards or respectively away from one another. However, only one limited angle of opening can be achieved with this construction.
For trouble-free operation of conventional docking mechanisms it is not only of significance that the coupling seals of the individual containers in each case can implicitly be closed environmentally impermeably. Rather, it is also of major significance that the coupling seals or elements can be docked problem-free and environmentally impermeably on corresponding coupling elements or seals. This succeeds all the better the smaller and more rigid the individual coupling elements or respectively their constituents, e.g. sealing strips, are. In particular, with structurally simple coupling seals, with large-size coupling seals and with coupling seals formed out of very flexible components, docking onto corresponding coupling seals frequently involves problems, is time-intensive and does not always result in environmentally impermeable docking mechanisms.
An object is to provide seals for environmentally impermeable filling and/or decanting or emptying of bulk material from containers or conveying equipment, which ensure problem-free and reliable sealing independently of the size and flexibility or respective rigidity of the materials used. An object-is also to provide seals for environmentally impermeable filling and/or decanting or emptying of bulk material from containers or conveying equipment, which can be joined reliably and environmentally impermeably and reversibly to corresponding seals of similar or identical construction, independent of the size and flexibility or respectively rigidity of the materials used.
A docking seal system has a first flexible enclosure with a first coupling seal and a second flexible enclosure with a second coupling seal. Each of the coupling seals has first and second sealing strips. A first zip slide is engageable with the first and second sealing strips of the first coupling seal and a second zip slide is engageable with the first and second sealing strips of the second coupling seal so that the respective first and second coupling seals can be opened and closed. The first and second zip slides are each combined with a respective portion of a coupling slide to form respective combined slides. When the combined slides are combined together, the respective portions of the coupling slides mate together to form the coupling slide, the coupling slide engaging or disengaging the first and second coupling seals so as to dock or separate the first and second flexible enclosures from one another.
For the purposes of promoting an understanding of the principles of the invention, reference will now be made to preferred embodiment illustrated in the drawings and specific language will be used to describe the same. It will nevertheless be understood that no limitation of the scope of the invention is thereby intended, such alterations and further modifications in the illustrated device, and such further applications of the principles of the invention as illustrated therein being contemplated as would normally occur to one skilled in the art to which the invention relates.
A reclosable zip seal for reversible sealing of a coupling seal was accordingly found, comprising a coupling seal for substantially environmentally impermeable, reversible sealing as well as for substantially environmentally impermeable filling and/or decanting of bulk material from in particular flexible containers or tube elements, comprising at least one first flexible sealing strip, comprising an inner side and a top side, with at least a first, in particular continuous sealing element, in particular a spring, on its inner side, and at least one second flexible sealing strip, comprising an inner side and a top side, with at least one second, in particular continuous, sealing element on its inner side, in particular a groove, which is complementary to the first sealing element, so that first and second sealing elements can be engaged, and enable reversible, tight sealing of the coupling seal with a further, corresponding coupling seal, whereby the first and the second sealing strip, are connected to one another in particular via their respective end sections, in particular by forming a closed periphery, and whereby the top side of the first sealing strip has at least a third, in particular continuous, sealing element for reversible docking on a complementary sealing element and the top side of the second sealing strip has at least a fourth, in particular continuous, sealing element for reversible docking on a complementary sealing element; and at least one zip slide for opening and closing of the coupling seal, which can be moved along the coupling seal, with a separation end and a compression end and opposite side walls as well as a separating element at the separating end, which can be slid between the first and second sealing elements of the first and second sealing strips, whereby the first and the second sealing element can be engaged in one another in reaction to the movement of the zip slide in a sealing direction from the open position into the closed position and in reaction to the movement of the zip slide can be brought in a direction of opening from the closed position into an open position. The first and second sealing strip of the seal of the preferred embodiment can be interconnected directly or indirectly. By way of example the respective endings or respectively end sections of first and second sealing strip can be connected to one another forming a flexible opening in pairs. In addition, it is possible for the ends of first and second sealing strip to merge into a, for example monobloc, end block, on which the zip slide can be placed in a normal position if necessary. As a consequence, such an end section can also have an end stop for the zip slide. Such an end section can be present on both sides of the opposite ends of first and second sealing strip.
Zip seals for e.g. plastic bags are known e.g. from DE 698 09 569 T2, DE 697 18 439 T2 and DE 696 19 983 T2 and can be used as a starting basis to arrive at a reclosable zip seal of the preferred embodiment. No longer only the inner sides of the first and second sealing strips now have sealing elements corresponding to one another, but likewise their top sides are fitted with sealing elements, which enable environmentally impermeable joining to a second seal of the preferred embodiment, environmentally impermeable filling and/or decanting of bulk material can also be ensured with very flexible bag and/or bead materials. By way of example the coupling seal can be a constituent of a plastic bag and be in the vicinity of the circular opening edge of the same.
The zip seal of the preferred embodiment is suited in particular for filling and/or decanting of bulk material from flexible containers, e.g. plastic bag or sacks. Accordingly, such a zip seal in an embodiment already has a flexible bag or tube, whereof the opening edge is connected separately or monobloc to the first and second sealing strip. The coupling seal can consequently be both an integral constituent of the flexible bags, in particular in the vicinity of the opening edge of this bag, and in retrospect can be connected to a bag reversibly or irreversibly.
The zip slide for opening or closing of the reclosable zip seal generally encroaches on the first and second sealing strip of a coupling seal. The separating element can be slid in between the sealing elements of the first and second sealing strip to open the zip seal. In an embodiment the side walls of the zip slide extend from the sealing face downwards to a point under the first or respectively second sealing strips, so that these sealing strips are held between the side walls. The first and second sealing strips connected to one another at their respective ends or closed positions can also form an end stop. There can also be a fixed station in this position. In a further embodiment the first and second sealing strips of a coupling seal can at least on one side exceed the periphery of a bag or tube connected to this coupling seal, in particular to take up the zip seal in the closed position. This ensures that the coupling seal is sealed over the entire length completely environmentally impermeably.
In the zip slide the sealing elements of the first and second sealing strip are meshed at the compression end. In any case at the compression end the inner distance between the opposite side walls is dimensioned such that it approximately matches the width of the coupled coupling seal. The separated and compression end of the zip slide can of course also be within the zip slide and must not necessarily match the opposite delimiting faces of the zip slide.
In a further embodiment it can be provided that the zip slide, which can be moved between a closed position and an open position along the first and second sealing strips, comprises an upper sealing wall as well as opposite side walls which extend from opposite sides of the sealing wall downwards and which accommodate the first and second sealing strip between them, whereby the side walls run from the separating end to the compression end of the zip slide and are arranged at a greater distance at the separating end than at the compression end, whereby the side walls at the compression end are spaced sufficiently narrowly that when the zip slide moves to the closed position they press the first and second sealing element into mutual engagement, and whereby the separating element protrudes at the separating end from the upper sealing wall between the side walls and past the first and second sealing element.
The underlying object of the preferred embodiment is furthermore solved by a reclosable docking seal for reversible docking of two coupling seals for substantially environmentally impermeable, reversible sealing as well as for substantially environmentally impermeable filling and/or decanting of bulk material from containers or tube elements, comprising a coupling seal, having at least one first flexible sealing strip, comprising an inner side and a top side, with at least a first, in particular continuous, sealing element, in particular a spring, on its inner side and at least one second flexible sealing strip, comprising an inner side and a top side, with at least a second, in particular continuous, sealing element on its inner side, in particular a groove, complementary to the first sealing element and enabling reversible, tight sealing with the first sealing element, whereby first and second sealing elements can be meshed, whereby the first and the second sealing strip, in particular are connected to one another via their respective end sections, in particular by forming closed circumference, and whereby the top side of the first sealing strip has at least a third, in particular continuous, sealing element for reversible docking on a complementary sealing element and the top side of the second sealing strip has at least a fourth, in particular continuous, sealing element for reversible docking on a complementary sealing element; and at least one coupling slide element, encroaching on the first and second sealing strip in sections and which can be moved along the coupling seal, suited for coupling and uncoupling the sealing strips of the coupling seal with the sealing strips of another coupling seal, containing sealing elements, in each case complementary to the third and fourth sealing elements of the sealing strips of the coupling seal of the docking seal.
A preferred configuration of the docking seal of the preferred embodiment is characterized in that the coupling slide element comprises a sealing wall as well as opposite first and second side walls, extending downwards from opposite sides of the sealing wall and taking up the first and second sealing strips between them, a first wall section, lying opposite the sealing wall and going away from the first side wall in the direction of the opposite second side wall, and encroaching on at least a section of the underside of the first flexible sealing strip at least in sections, a second wall section, lying opposite the sealing wall and going away from the second side wall in the direction of the opposite first side wall and encroaching on at least a section of the underside of the second flexible sealing strip at least in sections, whereby at least a gap remains between the first and second wall sections, at least one guide channel for the first and second sealing strip, formed from the opposite side walls, the sealing wall and the first and second sections of walls, and a front wall surface with an inlet opening of the channel and a rear wall surface with a discharge opening of the channel, whereby the inlet and the discharge opening as well as the channel between inlet and discharge opening are suitable for accommodating the first and second sealing strips, whereby that edge of the inlet opening, adjacent to the top sides of first and second sealing strips, is at a distance from the outer surface of the sealing wall and whereby the inner surface of the sealing wall, a constituent of the channel, approaches the outer surface of the sealing wall at least in sections from the inlet opening in the direction of the discharge opening and merges into the latter at the latest at the discharge opening, so that the sealing wall or areas of the sealing wall are no longer there at least over the width of the top sides of the first and second sealing strips, and whereby the height of the channel corresponds approximately to the height of the flexible first and/or second sealing elements at least at the place where the sealing wall assumes zero thickness.
The coupling slide element encroaches on the first and second sealing strip and can be guided along these sealing strips. The channel in the coupling slide element is formed at least in sections such that the meshing first and second sealing strips of the coupling seal substantially are enclosed and fitting precisely. The cross-section of the channel is in each case then only slightly bigger than the cross-section of the coupling seal, so that unhindered gliding through of the coupling seal is still always possible via the coupling slide element. During gliding through of the coupling seal by the coupling slide element the position of the top sides of the sealing strips changes relative to the outer surface of the sealing wall, i.e. reduces from movement in the direction of docking. The top sides of the sealing strips are brought to the height of the outer surface of the sealing wall or respectively then lie in the same plane as that, effectively meaning that the sealing wall has an opening or through-hole. In similar fashion as the channel of the outer surface approaches the sealing wall, the course or respectively the thickness of the first and second sections of wall changes, so that these sections of wall are constantly indirectly adjacent to the respective undersides of the first and second sealing strips. In this way a sealing element present at the top side of the sealing strip, e.g. a spring, can be brought into a corresponding sealing element of an adjacent sealing, e.g. a groove.
By shifting the coupling slide element over or respectively along the sealing strips, each area of the top sides of these sealing strips is in any case brought into a position, so as to be able to be meshed with a corresponding coupling seal of a corresponding seal, likewise fitted with such a coupling slide element.
In a further configuration the reclosable docking seal of the preferred embodiment also comprises at least one zip slide for opening and closing of the coupling seal, which can be moved along the coupling seal, with a separated and a compression end and opposite side walls as well as a separating element at the separating end, which can be slid in between the first and second sealing elements, whereby in reaction to the movement of the zip slide the first and the second sealing element can be meshed together in a sealing direction from the open position into the closed position and in reaction to the movement of the zip slide can be brought in a direction of opening from the closed position into an open position.
In this embodiment, both a coupling slide element and a zip slide, in each case as described hereinabove, can be moved along the first and second sealing strip of the coupling seal. Both these slides can be guided independently of one another, but also together via the coupling seal, resulting in a very large handling clearance for coupling and filling or respectively decanting of containers.
Naturally it is likewise possible that the coupling slide element and the zip slide can be interconnected, in particular reversibly, or that the coupling slide element and the zip slide are integrated in a uniform slide. In the case of an integrated slide both the characteristics of a coupling slide element and the characteristics of a zip slide are present. If such an integrated slide is actuated, two corresponding seals can be joined together by forming a docking mechanism, and at the same time the respective seals can be opened or respectively closed.
In addition, a seal can be provided, which already has a flexible bag or tube, whereof the opening edge is connected tightly to the first and second sealing strip, separately or monobloc.
The danger of contamination can preferably also be further reduced by at least the inner side and/or the top side of the first and/or second sealing strip of the coupling seal having an adhesive layer at least in sections.
In order to simplify and reliably create handling of the coupling seals of the preferred embodiment, it is also an advantage if the first and/or second sealing strip, in particular on the outside, has or respectively have at least one operating grip.
In an effective configuration it is provided that the first and second sealing strip and/or the first and second sealing element are substantially the same length.
The underlying object of the of the preferred embodiment with respect to the environmentally impermeable decanting of bulk material is further solved by a docking system of the preferred embodiment, comprising a first zip seal or a first docking seal and a second zip seal or respectively a second docking seal, whereby the third and fourth sealing elements of the top sides of first and second sealing strip of the first coupling seal of first zip or docking seal are complementary to the third and fourth sealing elements of the top sides of first and second sealing strip of the second coupling seal of second zip or respectively docking seal, so that the first and second sealing strips of first and second coupling seal, in particular environmentally impermeable, can be connected together reversibly and whereby the zip slide of first and second seals and/or the coupling slide elements of first and second seals can be set on one another and/or coupled to one another.
Those embodiments, in which the zip slide of first and second seals and/or the coupling slide elements of first and second seals can be coupled reversibly via corresponding structures, in particular in, at or on their sealing walls, have proven particularly advantageous.
By way of example the zip slide of the first seal can have on its sealing wall a pinched section, into which a bulged section present on the sealing wall of the zip slide of the second seal can be reversibly snap-locked. Meshing zip slide or coupling slide elements of first and second seals permit particularly uncomplicated and reliable handling for opening or respectively closing or docking of containers to be decanted. Of course, e.g. the outer surfaces of the sealing walls of a slide or a coupling slide element of first and second seal can also be fitted with a Velcro seal or a magnet so as to effect temporary connection via this structure.
Accordingly, the docking system of the preferred embodiment comprises two zip seals. Furthermore it is possible to use docking systems, comprising two inventive docking seals, in each case equipped only with at least one coupling slide element. It is particularly advantageous to employ docking systems, in which the first and second seals to be coupled both have at least one zip seal and at least one coupling slide element. Of course, it is likewise possible if only e.g. the first seal has a zip slide and a coupling slide element and the second seal is fitted only with one coupling slide element. The coupling seal, which has in this case no zip seal, can e.g. be opened or closed via operating grips or operating elements arranged on the sealing strips. Furthermore, such docking systems are also of advantage, in which at least one first seal has a zip slide, joined to a coupling slide element or contains the latter as integral constituent. It is of course particularly advantageous if both seals of the docking system are fitted with such coupled or integrated slides.
In addition, it can be provided according to the present preferred embodiment that the first and second coupling seals of first and second seal, the zip slide of first or second seal and/or the coupling slide elements of first and second seal are formed substantially identical or mirror-image.
The object of the preferred embodiment is furthermore solved by a multiple coupling seal for substantially environmentally impermeable, reversible sealing as well as for substantially environmentally impermeable filling and/or decanting of bulk material from flexible and/or rigid containers or conveying structure, comprising at least two first and second seals connected to one another or which can be connected at least in sections in each case via flexible first conveying structure, in each case comprising coupling seals, which can be coupled with coupling seals of corresponding first and second seals, whereby the opening face, in particular the inner diameter, of the opened coupling seal of the first seal is bigger than the outer circumference and/or opening face, in particular the outer and/or inner diameter, of the coupling seal of the second seal, whereby, when the coupling seal of the first seal is opened, the second seal can be docked with a corresponding seal inside the conveying structure and/or at least when entering through the opening of the coupling seal of the first seal in sections by forming a docking mechanism, whereby at least the first seal constitutes a zip seal or a docking seal of the preferred embodiment.
At the same time it is generally provided that the second seal, in particular environmentally impermeable, can be connected or is connected at least in sections to flexible second conveying structure. The second conveying structure accordingly makes a connection, insofar as required, between the second seal and a connected, in particular rigid, container or conveying structure. In a further embodiment it is likewise possible that the first conveying structure is not connected indirectly to the second seal, in particular environmentally impermeable, but that the latter makes a particularly environmentally impermeable connection with the second conveying structure.
Another configuration of the multiple coupling seal of the preferred embodiment provides that the second seal or respectively coupling seal includes a closure flap having a first connecting piece, whereby the closure flap can be brought into a closed position, in which the first end of the connecting piece can be sealed off tightly from the atmosphere. Such systems are disclosed e.g. in DE 695 04 581 T2. Such seals, as disclosed in DE 195 20 409 C1, DE 43 42 962 C1, WO 02/18248 and WO 02/18247 can basically also be used in particular as second seals or respectively coupling seals for the multiple coupling seal of the preferred embodiment. Also, systems as described in WO 03/037756, WO 03/037717 and the unpublished German patent application with the file number 103 21 814.9 are furthermore considered as suitable seals or respectively coupling seals for the multiple coupling seal of the preferred embodiment. Appropriate second seals or respectively coupling seals are likewise described in the still unpublished DE 103 35 325.9.
The multiple coupling seals of the preferred embodiment accordingly have a first coupling seal, forming the inlet opening, and a second or additional coupling seal, to which a container or conveying structure, e.g. a tube, is attached. In the case of the multiple coupling seals adjacent coupling seals are designated such that the one with the larger inner diameter or respectively the larger opening face represents the first coupling seal and the one with the smaller inner surface represents the second coupling seal. Of course, within a multiple coupling seal the adjacent first and second coupling seals can be both of identical structure and different in structure. It is likewise possible that if more than two coupling seals form an inventive multiple coupling seal, the conveying means or respectively tubes connecting the adjacent coupling seals can e.g. be made identical and also different in type, size or length.
In an effective configuration a multiple coupling seal comprises at least one in particular reversible and/or environmentally impermeable connecting device, in particular a Triclamp connection, on at least one coupling seal or a basic element or container connected to a coupling seal, with which the first or second conveying structure can be connected or are connected directly or indirectly, in particular environmentally impermeably, to a coupling seal or the basic element or container connected to this coupling seal.
Two multiple coupling seals can be joined together by forming a multiple docking device. At the same time the actual bulk material transfer takes place via the opened second docking mechanism, i.e. the docking mechanism formed in each case from second coupling seals. The conveying structure or respectively tubes connected to one another via the in each case first coupling seals form a protective sheath, which hermetically shields the first docking mechanism from the outer world at least during the decanting procedure.
The object of the present preferred embodiment therefore likewise includes a multiple docking device, in particular a double docking mechanism, for filling and/or decanting of bulk material, comprising a first and a second multiple coupling seal, whereby the adjacent first seals of first and second multiple coupling seal are coupled or can be coupled to one another by forming a first docking system, in particular environmentally impermeable, and whereby the second seals of first and second multiple coupling seals are coupled or can be coupled to one another by forming a second docking system, in particular environmentally impermeably.
The object of the present preferred embodiment is likewise a container, in particular a flexible container, as well as the conveying structure, in particular a tube, comprising in each case at least one seal.
The object of the present preferred embodiment further comprises a container, in particular a flexible container, which comprises a multiple coupling seal, whereby the coupling seal can be connected or is connected on the discharge opening of the multiple coupling seal to the container indirectly or via a flexible tube element or is an integral constituent of same.
According to a further aspect of the present preferred embodiment the task underlying this preferred embodiment is solved by a method for, in particular environmentally impermeable, filling, decanting and/or emptying of containers and/or with conveying structure, comprising the steps of:
At the same time according to the present preferred embodiment it can be provided that with forming and/or separating the docking system the coupling slide elements and the zip slide of first and second seal are moved at the same time, whereby the coupling slide element and the zip slide of the first seal and/or the coupling slide element and the zip slide of the second seal are preferably adjacent indirectly or directly and/or whereby the zip slide of first and second seal abut one another.
In a particularly preferred configuration of the method of the preferred embodiment it is provided that the coupling slide element and the zip slide of the first seal and/or the coupling slide element and the zip slide of the second seal are integrated into one slide.
In a further configuration it is provided that the lengths of first and second sealing strip of the first seal and the lengths of first and second sealing strip of the second seal substantially match.
The underlying task of the preferred embodiment is solved according to a further aspect also by a method for, in particular environmentally impermeable, filling, decanting and/or emptying of containers and/or with conveying structure, comprising the steps of:
Here it is of particular advantage that the coupling slide elements and the zip slide of the first seals of first and second multiple coupling seal are moved at the same time with forming and/or separating of the first docking system, whereby the coupling slide element and the zip slide of the seal of the first multiple coupling seal and/or the coupling slide element and the zip slide of the seal of the second multiple coupling seal are adjacent preferably indirectly or directly.
A particularly preferred further development also takes into consideration that the coupling slide element and the zip slide of the seal of the first multiple coupling seal and/or the coupling slide element and the zip slide of the seal of the second multiple coupling seal are integrated in one slide.
It is of particular advantage in the zip seal that it first enables coupled or respectively docked containers to be opened and closed unproblematically and reliably in one motion by way of actuating a slide. With the docking seals it is surprisingly simple and operationally secure to receive environmentally impermeable docking systems for flexible containers and tubes. Also, the concept of multiple coupling seals has surprisingly been further developed by integrating the inventive zip and docking seals. The seal or respectively docking systems basically succeeds in also using simple flexible containers, independently of their size, for environmentally impermeable filling and/or decanting actions, which up to now has not been possible in a correspondingly simple, uncomplicated and all the same reliable way. For operating safety and reliability as well as for maintaining the integrity of the containers and seals and docking systems used, in particular for ongoing use, it is also a factor that really only the zip slide, coupling slide elements and if necessary end stops are to be operated. Neither the sealing elements or beads nor the flexible containers are to be activated manually for closing or docking.
The seals 200 and 202 of first and second container 50, 52 can be laid on one another via the respective outer surfaces of their sealing walls 108, 110, which preferably match one another in size and shape, as shown in
If the superimposed first and second slides 100 and 102 are moved along the sealing strips of the combined seals 200, 202 on the one hand, as shown in
In
The characteristics of the invention disclosed in the abovementioned description, the diagrams as well as in the claims can be essential for carrying out the invention in its various embodiments both individually and also in any combination.
While the invention has been illustrated and described in detail in the drawings and foregoing description, the same is to be considered as illustrative and not restrictive in character, it being understood that only the preferred embodiment has been shown and described and that all changes and modifications that come within the spirit of the invention are desired to be protected.
Number | Date | Country | Kind |
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10 2004 003 511 | Jan 2004 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/DE2005/000084 | 1/21/2005 | WO | 00 | 7/17/2008 |
Publishing Document | Publishing Date | Country | Kind |
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WO2005/070776 | 8/4/2005 | WO | A |
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4485534 | Pilie et al. | Dec 1984 | A |
5664299 | Porchia et al. | Sep 1997 | A |
20020184740 | Meager | Dec 2002 | A1 |
20050084181 | Koch et al. | Apr 2005 | A1 |
Number | Date | Country |
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695 04 581 | Apr 1999 | DE |
WO 03037717 | May 2003 | WO |
Number | Date | Country | |
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20080276435 A1 | Nov 2008 | US |