The present disclosure relates to a resin-covered cord and a pneumatic tire.
Japanese Patent Application Laid-Open (JP-A) No. 2014-210487 discloses a tire in which a reinforcing cord member (a resin-covered cord) is formed by covering a reinforcing cord with a resin covering layer, and the reinforcing cord member is wound in a spiral pattern around a crown portion of a tire frame member to form a belt layer. Tires in which a belt layer (resin-covered belt layer) is formed using resin in this manner have a higher out-of-plane rigidity at the crown portion than tires in which a belt layer (rubber-covered belt layer) is formed using rubber.
In order to form a resin-covered belt layer such as that disclosed in JP-A No. 2014-210487, an adhesive resin is preferably provided at the periphery of the reinforcing cord in order to raise the level of integration between the reinforcing cord and a covering resin of the resin-covered cord. However, depending on the shape and the elastic modulus of the adhesive resin, it may be difficult to secure in-plane rigidity of the resin-covered cord and of the resin-covered belt layer formed using the resin-covered cord.
The present disclosure secures in-plane rigidity of a resin-covered cord and in-plane rigidity of a member formed using the resin-covered cord.
A resin-covered cord of a first aspect includes n number of individual cords, disposed so as to be mutually spaced apart from each other, a covering resin that covers the cords, and an adhesive resin that is disposed between the cords and the covering resin and that has a greater tensile elastic modulus than the covering resin. The following Equation (1) is satisfied, in which A is a total value of a width direction dimension of a portion where the cords and the adhesive resin are disposed, and B is a maximum value of a thickness direction dimension.
B<(A/n) (n≥1) Equation (1).
In the resin-covered cord of the first aspect, the adhesive resin is used to adhere the cord and the covering resin together. The n individual cords are embedded within the covering resin, and A, namely “the total value of the width direction dimension of the portion where the cord and the adhesive resin are disposed” divided by n is greater than B, namely “the maximum value of the thickness direction dimension of the portion where the cord and the adhesive resin are disposed”.
Namely, on a cord-by-cord basis, the adhesive resin has a larger width direction dimension than thickness direction dimension. Moreover, the tensile elastic modulus of the adhesive resin is greater than that of the covering resin. The rigidity of the resin-covered cord along the width direction (namely in-plane rigidity) is thus greater than it would be in a case in which the width direction dimension were not greater than the thickness direction dimension on a cord-by-cord basis.
In a resin-covered cord of a second aspect, the adhesive resin is continuous in the width direction.
In the resin-covered cord of the second aspect, the adhesive resin covering the n individual cords is continuous in the width direction. Rigidity can accordingly be improved since there are fewer portions with a low tensile elastic modulus than would be present in cases in which the adhesive resin were not continuous.
A pneumatic tire of a third aspect includes a carcass that is formed spanning a pair of bead cores, and a resin-covered belt layer that is disposed at a tire radial direction outside of the carcass and that is formed by winding the resin-covered cord of claim 1 or claim 2 in a spiral pattern.
In the pneumatic tire of the third aspect, the resin-covered belt layer is formed by winding the resin-covered cord of claim 1 or claim 2 in a spiral pattern. The ring rigidity is therefore higher than it would be were a cord to be covered in rubber to configure a rubber-covered belt layer, or were a resin-covered belt layer to be configured without winding the resin-covered cord in a spiral pattern. An annular surface of a tread running in the tire circumferential direction and the tire width direction is thus less susceptible to out-of-plane deformation, thereby suppressing deformation of the pneumatic tire.
Moreover, due to the high in-plane rigidity of the resin-covered cord of the first aspect or the second aspect, the resin-covered belt layer applied with the resin-covered cord is less susceptible to shear deformation, and cornering power is enhanced.
Furthermore, since peripheral cracking of the resin-covered cord of the first aspect or the second aspect is suppressed, out-of-plane deformation of the resin-covered belt layer can be suppressed. Moreover, the durability of the pneumatic tire is raised since ingress of water into the resin-covered cord through such cracks is also suppressed.
A pneumatic tire of a fourth aspect includes a pair of bead cores, each formed by winding the resin-covered cord of claim 1 or claim 2 in a spiral pattern, a carcass that is formed spanning the bead cores, and a belt layer that is disposed at a tire radial direction outside of the carcass.
In the pneumatic tire of the fourth aspect, the bead core is formed by winding the resin-covered cord of claim 1 or claim 2 in a spiral pattern. The twisting rigidity of the bead core is thus higher than it would be for a bead core configured from a rubber-covered cord. This makes a bead portion less susceptible to rim detachment.
Moreover, since peripheral cracking of the resin-covered cord of the first aspect or the second aspect is suppressed, out-of-plane deformation can also be suppressed. This enables rim detachment of the bead portion to be suppressed.
The present disclosure is capable of securing in-plane rigidity of a resin-covered cord and in-plane rigidity of a member formed using the resin-covered cord.
In the present exemplary embodiment, a tire radial direction side toward the rotation axis of the tire 10 is referred to as the tire radial direction inside, and a tire radial direction side further away from the rotation axis of the tire 10 is referred to as the tire radial direction outside. A tire width direction side toward the tire equatorial plane CL is referred to as the tire width direction inside, and a tire width direction side further away from the tire equatorial plane CL is referred to as the tire width direction outside.
Tire
As illustrated in
Bead Portions
The bead cores 12A are each configured from a wire bundle, and are embedded in the respective pair of bead portions 12. The carcass ply 14 straddles between the bead cores 12A. Various structures, for example structures with circular or polygonal shaped cross-section profiles, may be adopted for the bead cores 12A. A hexagonal shape may be adopted as an example of a polygonal shape; however, in the present exemplary embodiment a four-sided shape is employed.
In each of the bead portions 12, the bead filler 12B is embedded in a region enclosed by the carcass ply 14 anchored to the corresponding bead core 12A. The bead filler 12B extends from the bead core 12A toward the tire radial direction outside so as to gradually decrease in thickness on progression toward the tire radial direction outside. Each of the bead portions 12 is configured by a portion of the tire 10 spanning from a tire radial direction outside end 12BE of the corresponding bead filler 12B toward the tire radial direction inside.
Carcass
The carcass 16 is a configured of a sheet of the carcass ply 14 formed by covering plural cords with covering rubber. The carcass ply 14 configures a tire frame extending in a toroid shape from one of the bead cores 12A to the other of the bead cores 12A. End portion sides of the carcass ply 14 are anchored to the respective bead cores 12A. Specifically, the carcass ply 14 includes a main portion 14A straddling from the one bead core 12A to the other bead core 12A, and folded-back portions 14B that are folded back on themselves toward the tire radial direction outside around the respective bead cores 12A.
Note that the carcass ply 14 of the present exemplary embodiment is a radial carcass. There is no particular limitation to the material employed for the carcass ply 14, and Rayon, Nylon, polyethylene naphthalate (PEN), polyethylene terephthalate (PET), an aramid, glass fibers, carbon fibers, steel, or the like may be employed therefor. From the perspective of weight reduction, an organic fiber cord is preferable. Although a range of from 20 to 60 strands per 50 mm are incorporated in the carcass, there is no limitation to this range. Moreover, although the carcass 16 is configured of a single sheet of the carcass ply 14 in the present exemplary embodiment, the carcass 16 may be configured of plural carcass ply sheets.
An inner liner 22 formed of rubber is disposed at the tire radial direction inside of the carcass 16. A side rubber layer 24 formed of rubber is disposed at the tire width direction outsides of the carcass 16. In the present exemplary embodiment, a tire case 25 is configured by the bead cores 12A, the carcass 16, the bead filler 12B, the inner liner 22, and the side rubber layer 24. In other words, the tire case 25 configures a tire frame member forming a frame of the pneumatic tire 10.
Resin-Covered Belt Layer
The resin-covered belt layer 40 is laid at the outside of a crown portion of the carcass 16, in other words at the tire radial direction outside of the carcass 16. As illustrated in
As illustrated in
The resin layer 46 is bonded so as to fuse together mutually adjacent locations thereof in the tire width direction. The resin-covered belt layer 40 is formed from the reinforcing cord 44 covered by the resin layer 46 in this manner.
The resin layer 46 is formed of an adhesive resin 46A and a covering resin 46B. The adhesive resin 46A is an adhesive layer for increasing the level of integration between the reinforcing cord 44 and the covering resin 46B. As illustrated in
B<A (1-1)
Note that the thickness direction is a direction aligned with the tire radial direction when the resin-covered cord 42 has been laid on the outer circumferential surface of the carcass 16. The width direction is a direction aligned with the tire width direction. In cases in which plural reinforcing cords 44 are embedded inside the resin layer 46 (described in detail later), the width direction is a direction that substantially corresponds to an array direction of the reinforcing cords 44.
The tensile elastic modulus of the covering resin 46B (as defined in JIS K7113: 1995) is preferably no less than 100 MPa. An upper limit of the tensile elastic modulus of the covering resin 46B is preferably no greater than 1000 MPa. Note that the tensile elastic modulus of the covering resin 46B is particularly preferably within a range of from 200 MPa to 700 MPa. The tensile elastic modulus of the adhesive resin 46A is preferably set greater than the tensile elastic modulus of the covering resin 46B, and specifically set one to five times greater than the tensile elastic modulus of the covering resin 46B.
The covering resin 46B is configured by a thermoplastic resin. Note that exemplary embodiments of the present disclosure are not limited thereto, and for example a thermoplastic elastomer, a thermosetting resin, a general purpose resin such as a (meth)acrylic-based resin, an EVA resin, a vinyl chloride resin, a fluorine-based resin, or a silicone-based resin, or an engineering plastic (encompassing super engineering plastics) may be employed as this resin material. Note that these resin materials do not include vulcanized rubber.
Thermoplastic resins (including thermoplastic elastomers) are polymer compounds of materials that soften and flow with increased temperature, and that adopt a relatively hard and strong state when cooled. In the present specification, out of these, polymer compounds forming materials that soften and flow with increasing temperature, that adopt a relatively hard and strong state on cooling, and that have a rubber-like elasticity are considered to be thermoplastic elastomers. Polymer compounds forming materials that soften and flow with increasing temperature, that adopt a relatively hard and strong state on cooling, and do not have a rubber-like elasticity are considered to be non-elastomer thermoplastic resins.
Examples of thermoplastic resins (thermoplastic elastomers included) include thermoplastic polyolefin-based elastomers (TPO), thermoplastic polystyrene-based elastomers (TPS), thermoplastic polyamide-based elastomers (TPA), thermoplastic polyurethane-based elastomers (TPU), thermoplastic polyester-based elastomers (TPC), and dynamically crosslinking-type thermoplastic elastomers (TPV), as well as thermoplastic polyolefin-based resins, thermoplastic polystyrene-based resins, thermoplastic polyamide-based resins, and thermoplastic polyester-based resins.
For example, a material with deflection temperature under load (namely under a load of 0.45 MPa) as defined in ISO 75-2 and ASTM D648 of 78° C. or above, a tensile yield strength as defined in JIS K7161 of 10 MPa or above, a tensile elongation at break as also defined in JIS 7161 of 50% or above, and a Vicat softening temperature as defined in JIS K7206 (method A) of 130° C. may be employed as the above thermoplastic material.
Thermosetting resins are curable polymer compounds that form a 3 dimensional mesh structure with increasing temperature. Examples of thermosetting resins include phenolic resins, epoxy resins, melamine resins, and urea resins.
Note that instead of thermoplastic resins (including thermoplastic elastomers) or thermosetting resins such as those described above, a general purpose resin such as a (meth)acrylic-based resin, an EVA resin, a vinyl chloride resin, a fluorine-based resin, or a silicone-based resin may be employed as the covering resin 46B.
A material that is less susceptible to moisture permeation, in other words that is less susceptible to moisture absorption, than the covering resin 46B is employed as the adhesive resin 46A. Examples of an adhesive configuring the adhesive resin 46A include materials having as a main component (main agent) one type or two or more types of thermoplastic resin out of a modified olefin-based resin (a modified polyethylene-based resin, a modified polypropylene-based resin, or the like), a polyamide-based resin, a polyurethane-based resin, a polyester-based resin, a modified polyester-based resin, an ethylene-ethyl acrylate copolymer, an ethylene-vinyl acetate copolymer, or the like.
Of these, from the perspective of adhesive properties between a metal member (the reinforcing cord 44) and a resin layer (the covering resin 46B), preferably a hot melt adhesive is employed containing at least one item selected from the group consisting of a modified olefin-based resin, a polyester-based resin, a modified polyester-based resin, an ethylene-ethyl acrylate copolymer, and an ethylene-vinyl acetate copolymer. More preferably employed is a hot melt adhesive containing at least one item selected from the group consisting of a modified polyester-based resin and a modified polyester-based resin. Even more preferably employed from out of these is a hot melt adhesive containing at least one item selected from the group consisting of an acid-modified olefin-based resin (a modified olefin-based resin subjected to acid modification using unsaturated carboxylic acid) and a modified polyester-based resin, and particularly preferably employed is a hot melt adhesive containing an acid-modified polyester-based resin.
Note that “a modified olefin-based resin subjected to acid modification using unsaturated carboxylic acid” refers to a modified olefin-based resin copolymer in which unsaturated carboxylic acid has been graft copolymerized to a polyolefin.
The reinforcing cord 44 of the resin-covered belt layer 40 is configured from a steel cord, the outer peripheral surface of which is cobalt-plated. This steel cord has a main component of steel and may include a minor amount of various other substances, such as carbon, manganese, silicon, phosphorus, sulfur, copper, or chromium. The plating material is not limited to cobalt, and nickel or the like may be employed therefor.
A width BW of the resin-covered belt layer 40 as measured along the tire axial direction (namely the distance between belt ends 40EW) is preferably no less than 75% of a ground contact width TW of the tread 60 as measured along the tire axial direction. This enables rigidity to be raised in the vicinity of shoulders 39. Note that an upper limit of the width BW of the resin-covered belt layer 40 is preferably 110% of the ground contact width TW. This enables an increase in the weight of the tire 10 to be suppressed.
Note that the ground contact width TW of the tread 60 refers to when the tire 10 is fitted to a standard rim, as defined in the 2018 edition of the Japan Automobile Tyre Manufacturers Association (JATMA) Year Book, inflated to an internal pressure of 100% air pressure (maximum air pressure) corresponding to the maximum load capacity (load shown in bold in the internal pressure-load capacity correspondence table) for the applicable JATMA Year Book size/ply rating, disposed such that the rotation axis lies parallel with a horizontal flat plate when stationary, and applied with weight corresponding to the maximum load capacity. In cases in which TRA standards or ETRTO standards apply in the location of use or manufacturing location, then the corresponding standards are adhered to.
Note that exemplary embodiments of the present disclosure are not limited to the above, and the steel cord employed as the reinforcing cord 44 of the resin-covered belt layer 40 may employ a monofilament cord, or cord in which plural filaments are twisted together. Alternatively, organic fibers of an aramid or the like, or of carbon or the like, may be employed as the material instead of steel. Various twisting structure designs may be adopted, and various cross-section structures, twisting pitches, twisting directions, and distances between adjacent filaments may be employed. Furthermore, cord in which filaments of different materials are twisted together may be employed, and there is no particular limitation to the cross-section structure thereof, for which various twisting structures, such as single twists, layered twists, compound twists, or the like may be adopted.
Tread
As illustrated in
Operation
In the resin-covered cord 42 according to the present exemplary embodiment of the present disclosure, the adhesive resin 46A is used to adhere the covering resin 46B to the reinforcing cord 44. As per Equation (1-1), a cross-section of the adhesive resin 46A including the reinforcing cord 44 has a greater width direction dimension than thickness direction dimension. The adhesive resin 46A also has a greater tensile elastic modulus than the covering resin 46B.
The rigidity of the resin-covered cord 42 along the width direction (W direction) (namely in-plane rigidity) is thus higher than it would be in a case in which the width direction dimension of the adhesive resin 46A were not greater than the thickness direction dimension thereof. Moreover, the change in the tensile elastic modulus (namely a step change in rigidity) at the periphery of the reinforcing cord 44 is smoother than it would be in a case in which the tensile elastic modulus of the adhesive resin 46A were not greater than the tensile elastic modulus of the covering resin 46B, thereby enabling cracking at the periphery of the reinforcing cord 44 to be suppressed.
Moreover, in the tire 10 according to the present exemplary embodiment of the present disclosure, the resin-covered cord 42 is wound in a spiral pattern to form the resin-covered belt layer 40. The ring rigidity is therefore higher than it would be were the reinforcing cord 44 to be covered in rubber to configure a rubber-covered belt layer, or were a resin-covered belt layer to be configured without winding the resin-covered cord 42 in a spiral pattern. An annular surface of the tread 60 running in the tire circumferential direction and the tire width direction is therefore less susceptible to out-of-plane deformation, thereby suppressing deformation of the tire 10.
Moreover, the in-plane rigidity of the resin-covered cord 42 is increased by forming the adhesive resin 46A such that the width direction dimension is greater than the thickness direction dimension thereof. The resin-covered belt layer 40 applied with the resin-covered cord 42 is therefore less susceptible to shear deformation, and cornering power is enhanced.
Furthermore, cracking of the resin-covered cord 42 is suppressed as a result of smoothing the change in the tensile elastic modulus at the periphery of the reinforcing cord 44, enabling out-of-plane deformation of the resin-covered belt layer 40 to be suppressed. Moreover, the durability of the tire 10 is raised since ingress of water into the resin-covered cord 42 through such cracks is also suppressed.
Furthermore, the adhesive resin 46A that is less susceptible to moisture permeation than the covering resin 46B is provided at the outer periphery of the reinforcing cord 44. This enables corrosion (rusting) of the reinforcing cord 44 to be suppressed compared to cases in which an adhesive layer that is readily permeable to moisture is provided.
As illustrated in
For example, as illustrated in
Alternatively, plural reinforcing cords 44 may be embedded in the resin-covered cord 42.
When the adhesive resin 46A covering plural of the reinforcing cords 44 is continuous in this manner, in-plane rigidity can be improved since there are fewer portions with a low tensile elastic modulus than would be present in cases in which the adhesive resin 46A were not continuous. In such cases also, a cross-section of the adhesive resin 46A including the reinforcing cords 44 has a width direction dimension A than thickness direction dimension B, such that the previously described equation (1-1) is satisfied.
In cases in which plural of the reinforcing cords 44 are covered by the resin layer 46 to form the resin-covered cord 42 as illustrated in
B<(A/n) (1-2)
Note that “a maximum value of a thickness direction dimension” refers to the maximum dimension of a straight line drawn along the thickness direction of the adhesive resin 46A so as to intersect the portion where the reinforcing cords 44 and the adhesive resin 46A are disposed.
Note that in cases in which plural of the reinforcing cords 44 are embedded in the resin-covered cord 42, the adhesive resin 46A at the periphery of the respective reinforcing cords 44 does not necessarily have to be continuous. For example, as illustrated in
In the example illustrated in
Similarly, in
Alternatively, exemplary embodiments of the present disclosure may be configured such that both continuous and discrete locations of the adhesive resin 46A covering the reinforcing cords 44 are present locally along the extension direction of the resin-covered cord 42. Namely, for example, the profile illustrated in
In such cases, as illustrated in
In the present exemplary embodiment, the resin-covered cord 42 is employed to form the resin-covered belt layer 40. However, exemplary embodiments of the present disclosure are not limited thereto. For example, the resin-covered cord 42 may be employed to form the bead cores 12A illustrated in
In such cases, as illustrated in
The disclosure of Japanese Patent Application No. 2018-119352, filed on Jun. 22, 2018, is incorporated in its entirety by reference herein. All cited documents, patent applications, and technical standards mentioned in the present specification are incorporated by reference in the present specification to the same extent as if each individual cited document, patent application, or technical standard was specifically and individually indicated to be incorporated by reference.
Number | Date | Country | Kind |
---|---|---|---|
2018-119352 | Jun 2018 | JP | national |
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/JP2019/023516 | 6/13/2019 | WO | 00 |