Claims
- 1. A resinous dental composition, which is photochemically or thermally curable in the presence of initiators, or self curable in the presence of a redox catalyst, comprising/polymerisable polysiloxanes which are obtained by hydrolytic condensation of
- a) one or more hydrolytically condensable compounds of silicon; and
- b) if desired, elements selected from the group consisting of B, Ba, Ti, Zr, Al, Sn, and/or transition metals; and
- c) if desired, precondensates of the hydrolytically condensable compounds in (a) and/or the elements in (b);
- if appropriate in the presence of a catalyst and/or of a solvent, by the action of water or moisture; wherein 1 to 100 mol % of the polymerisable polysiloxanes are based on monomeric compounds of silanes of the general formula (I)
- Y.sub.n SiX.sub.m R.sub.4-(n+m) (I)
- in which the radicals X, Y and R are identical or different and have the following meaning:
- R=alkyl, alkenyl, aryl, alkylaryl or arylalkyl,
- X=hydrogen, halogen, hydroxyl, alkoxy, acyloxy, alkylcarbonyl, alkoxycarbonyl or NR'.sub.2, where R'=hydrogen, alkyl or aryl,
- Y=a substituent which contains a substituted or unsubstituted 1,4,6-trioxaspiro (4.4) nonane radical
- n=1,2 or 3,
- m=1, 2 or 3, where n+m.ltoreq.4;
- and of silanes of the general formula (II)
- {X.sub.n R.sub.k Si(R.sup.2 (A).sub.l).sub.4-(n+k) }.sub.t D(II)
- in which the radicals A, R, R.sup.2 and X are identical or different and have the following meaning:
- A=O, S, PR', POR', NHC(O)O or NHC(O)ONR',
- where R'=hydrogen, alkyl, or aryl,
- D=a straight-chain or branched organic radical which is derived from a compound D' having at least one (for l=1 and A=NHC(O)O or NHC(O)NR') or at least two C.dbd.C double bonds and 5 to 50 carbon atoms, where R'=hydrogen, alkyl or aryl,
- R=alkyl, alkenyl, aryl, alkylaryl or arylalkyl,
- R.sup.2 =alkylene, arylene or alkylenearylene,
- X=hydrogen, halogen, hydroxyl, alkoxy, acyloxy, alkylcarbonyl, alkoxycarbonyl or NR'.sub.2, where R'=hydrogen, alkyl or aryl,
- n=1, 2 or 3,
- k=0, 1 or 2
- l=0 or 1,
- t=an integer whose maximum value corresponds to the number of double bonds in the compound D' minus 1, or is equal to the number of double bonds in the compound D' when l=1 and A represents NHC(O)O or NHC(O)NR'.
- 2. The resinous dental composition according to claim 1 wherein when said silanes of the general formula (I) are present at from about 5 mole % to about 100% mole % based on monomeric compounds.
- 3. Resinous dental composition according to claim 1, wherein the silanes of the general formula (I) are those in which Y is equal to ##STR8## where the radical Z are identical or different and denote hydrogen, hydroxyl, alkyl, alkenyl, aryl, alkylaryl, arylalkyl, alkylcarbonyl, alkoxycarbonyl, acryloxy, methacryloxy or halogen.
- 4. Resinous dental composition according to claims 1, wherein the silanes of the general formula (II) are those in which the radicals and indices have the following meaning:
- t=(C.sub.1 -C.sub.4)-alkoxy, preferably methoxy and ethoxy, or halogen, preferably chlorine;
- R=(C.sub.1 -C.sub.4)-alkyl, preferably methyl and ethyl;
- R.sup.2 =(C.sub.1 -C.sub.4)-alkylene, preferably methylene and propylene;
- A=O or S;
- n=1, 2 or 3;
- l=0 or 1;
- 4-(n+k)=0 for l=0 and 1 for l=1; D and x formulated as in claim 1.
- 5. Resinous dental composition according to claim 3, wherein the silanes of the general formula (II) are those in which the unit having the index t is selected from triethoxysilyl, methyldiethoxysilyl, methyl-dichlorosilyl, 3-methyl-dimethoxysilylpropylthio, 3-triethoxysilylpropylthio, ethoxydimethylsilylmethylthio and methyldiethoxy-silylmethylthio.
- 6. Resinous dental composition according to claim 1 wherein the silanes of the general formula (II) are those in which the compound D' contains one (for l=1 and A=NHC(O)O or NHC(O)NR') C.dbd.C double bond.
- 7. Resinous dental composition according to claim 1, wherein the silanes of the general formula (II) are those in which the compound D' contains (for l=1 and A=NHC(O)O or NHC(O)NR') at least three C.dbd.C double bonds.
- 8. Resinous dental composition according to claim 1, wherein the silanes of the general formula (II) are those in which D is derived from a substituted or unsubstituted compound D' having two or more acrylate and/or methacrylate groups.
- 9. Resinous dental composition according to claim 7, wherein D is derived from acrylic acid esters or trimethylolpropane, pentaerythritol, dipentaerythritol, C.sub.2 -C.sub.6 -alkanediols, polyethylene glycols, polypropylene glycols or optionally substituted and/or alkoxylated bisphenol A.
- 10. Resinous dental composition according to claim 1, wherein the silanes of the general formula (II) are those in which t has the value 1 or 2.
- 11. Resinous dental composition according to claim 1, wherein the hydrolytically condensable compounds of silicon selected are one or more compounds of the general formula (III)
- R.sub.a (R"Z').sub.b SiX.sub.4-(a+b) (III)
- if appropriate in precondensed form, in which the radicals R, R" and Z' are identical or different and have the following meaning:
- R=alkyl, alkenyl, aryl, alkylaryl or arylalkyl,
- R"=alkylene or alkenylene, where these radicals can be interrupted by oxygen or sulphur atoms or NH groups,
- x=hydrogen, halogen, hydroxyl, alkoxy, acyloxy, alkylcarbonyl, alkoxycarbonyl or NR'.sub.2,
- where R'=hydrogen, alkyl or aryl,
- Z'=halogen or an optionally substituted amino, amide, aldehyde, alkylcarbonyl, carboxyl, mercapto, cyano, alkoxy, alkoxycarbonyl, sulphonic acid, phosphoric acid, acryloxy, methacryloxy, epoxy or vinyl group,
- a=0, 1, 2 or 3,
- b=0, 1, 2 or 3, where a+b =1, 2 or 3.
- 12. Resinous dental composition according to claim 1, wherein the hydrolytically condensable components are selected from the group consisting of barium, titanium and zirconium compounds which are soluble in the reaction medium, if appropriate in precondensed form, of the general formula
- BaR".sub.2 or MX.sub.w R.sub.u
- in which M denotes titanium or zirconium, the radicals R", R and X are identical or different, R" represent alkoxy or acyloxy, w is an integer form 1 to 4, in particular 2 to 4, u represents 0, 1, 2 or 3, and x and R are defined as in the case of the general formula (I).
- 13. The resinous dental composition according to claim 12 wherein u represents 0, 1 or 2.
- 14. Resinous dental composition according to claims 1, wherein it additionally contains one or more monomers which are copolymerisable by free radicals and/or catonically.
- 15. Resinous dental composition according to claim 14, wherein it contains acrylates, methacrylates, mono- or oligoepoxides, vinyl ethers, spiro-orthoesters, spiro-orthocarbonates, bicyclic spiro-orthoesters or methacryloyl spiro-orthoesters as polymerisable monomers.
- 16. The resinous dental composition according to claim 1, comprising an adhesive or adhesion promoter to enamel and dentine, a coposition for the surface-sealing of conventional composites, an adhesion promoter for dental fillers and a coating composition in the dental field.
- 17. Pasty dental material, which is photochemically or thermally curable in the presence of initiators or self-curing, composed of one or more resinous dental compositions and, optionally, one or more finely divided fillers, comprising from about 20% to about 100% by volume of the resinous dental composition according to claim 1.
- 18. Pasty dental material, which is photochemically or thermally curable in the presence of initiators or self-curing, composed of one or more resinous dental compositions and, optionally, one or more finely divided fillers, comprising from about 20% to about 100% by volume of the resinous dental composition according to claim 2.
- 19. The pasty dental material according to claim 17 wherein said resinous dental composition is present at from about 30% to about 70% by volume.
- 20. The pasty dental material according to claim 18 wherein said resinous dental composition is present at from about 30% to about 70% by volume.
- 21. A pasty dental material according to claim 17, wherein an optional finely divided filler, if present, comprises a finely divided resinous dental composition according to claim 2.
- 22. The pasty dental material according to claim 17, wherein an optional finely divided filler, if present, comprises a finely divided resinous dental composition according to claim 3.
Priority Claims (1)
Number |
Date |
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Kind |
41 33 494.9 |
Oct 1991 |
DEX |
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Parent Case Info
This is a continuation of application Ser. No. 08/211,479, filed as PCT/US92/08530, Oct. 7, 1992, now abandoned.
US Referenced Citations (11)
Foreign Referenced Citations (1)
Number |
Date |
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29 22 932 A1 |
Dec 1979 |
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Continuations (1)
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211479 |
Nov 1994 |
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