The invention relates to a retainer for controlling the payout of wire from a wire container, in particular of welding wire from a welding wire container. The invention further relates to a wire container comprising such retainer.
Welding wire is often supplied in the form of a coil contained in a container, the central axis of the coil being arranged vertically. The welding wire is withdrawn from the container by pulling the welding wire upwardly through a central opening of the container. Typically, a retainer is used which is placed on top of the coil and which prevents that the upper turns of the welding wire change their position in an uncontrolled manner such that tangles and knots could occur in the welding wire.
Automated welding and other industrial applications often require large quantities of wires to be stored in these containers, also referred to as bulk containers (drums or boxes with polygonal cross-section) with the scope of minimizing the production interruptions caused by pack changeovers. These bulk packs can, in some instances, carry up to 1,400 kg (approx. 3,000 lbs) of wire, and the wire can have diameters of up to 4.00 mm ( 5/32″). Since their introduction years ago, these bulk packages containing large quantities of twist-free torsion-less wires have become increasingly popular in many applications that exploit the benefits of robotic and automation in welding processes like GMAW (Gas Metal Arc welding) and SAW (Submerged Arc Welding) or have found their use in the metal spraying of wires for surface treatments and several other industrial applications.
Employing packs with larger dimensions in order to accommodate larger diameter wires involves however also the necessity to overcome a few technical problems like the difficulty to effectively maintain all the wire strands in control while a single wire is being paid out from the pack, and prevent them from exiting the packs simultaneously and uncontrolled with consequent tangles and unwanted production stops which would offset the downtime savings achieved by bulk quantities in the pack. Weld bead interruptions caused by poor feeding or tangled wires can, in some cases, negatively affect the mechanical properties of the finished welded parts rendering them unfit for sale with considerable economic damages for the manufacturer. As previously explained, tangling can occur when a few wire strands are not properly grasped by the retainer and they can freely fall into the center of the drum or pack from where they feed in an uncontrolled and disorderly manner.
It is obvious that the larger the inner diameter of the drums or containers, the more and more difficult it is to control the strands of wire with the conventional retainers known so far.
Bulk pack retainers are commonly employed today in the industry and they come in different forms ranging from ring shaped plane plates to cone shaped plates and metal cages but they all have in common the fact that they are rigid pieces. Consequently, especially with thicker and therefore stiffer wires which exert a lot of pressure upward, the wire being paid out from the pack can lift the one-piece rigid retainer and involuntarily cause the uncontrolled release of other wire strands which can freely escape from underneath the retainer itself, and jam.
Some of the prior art solutions like those shown in U.S. Pat. Nos. 5,746,380 or 7,004,318 attempt to provide a dynamic retainer which interacts with the payout of the wire. However, in order to function and for the retainer and the retaining elements not to be dragged or fall into the center of the drum or pack, they must rely on a centre core provided in the container, which represents itself a feeding obstacle for the wire, specially in the lower half of the drum/pack. More specifically, both solutions shown in these documents appear to be totally useless with thick wires which are characterized by a high “columnar” strength, since these retainers are not strong enough to keep the wire strands down and under control. If the retainer weight however is intentionally increased in an attempt to compensate the increased pressure strength of thicker wires, they end up deforming the single wire strand being paid out with a negative effect on the precision of the weld placement. Testing at Wind Tower manufacturing sites showed that softer Submerged Arc welding wire, like SAW UNI EN 756:04 grade S2 (AWS A5.17:07 grade EM12K) even in a 4.00 mm diameter can easily be bent and deformed by a rigid heavy retainer with consequent “wavy” defects and irregular weld beads, which are totally unacceptable for the quality and safety standards required by such application.
US 2011/0114523 shows a solution which, although it comes with benefit that a centre core is not required, proposes a self-adapting rubber retainer with multiple flexible stripes. However, manufacturing costs are an issue here since, in order to stay placed on the wire coil and not to slip into the centre of the drum/pack, it must be attached to a supportive outer rigid frame. The cost of molding or assembling two materials (one rigid and one flexible) for the same retainer would negatively impact the price of the wire contained in the pack. Moreover, the rigid outer supporting frame still makes the flexible retainer behave like a rigid one and such solution is technically impossible with packs having a diameter as large as 1,000 mm (3.28 ft).
US 2011/0094011 shows a rigid panel with four flexible rubber fingers at the corners. This solution also requires a composed retainer which is more expensive to produce but it is definitely unsuitable for controlling and braking of thicker wires ranging from 2.00 to 4.00 mm in diameter, as normally used in the SAW (Submerged Arc Welding) applications.
Accordingly, there is a need for a retainer which can be produced at low costs but at the same time allows to reliably prevent entanglement and unintentional lifting of the upper turns of the wire from the coil.
The invention provides a retainer for controlling the payout of wire from a wire container. The retainer has at least three segments. Each segment is connected to the adjacent segment so as to allow a relative movement of adjacent segments with respect to each other. The entirety of the segments form a contact surface adapted for contacting the wire contained in the wire container. The invention is based on the idea of forming a retainer which, by means of its weight in total, reliably sits on top of the wire coil and prevents unintended displacement and/or entanglement of the wire turns on top of the coil. At the same time, the wire currently withdrawn must lift only the respective segment of the retainer (or the respective two adjacent segments) in order to be pulled from the upper surface of the coil, which does not require significant forces in view of the segments being moveable with respect to each other. Further, the retainer presents a simple and inexpensive but efficient solution, because the retainer is formed through the assembly of many segments or “tiles” which are being held together by a locking mechanism but are, at the same time, free to independently move upward to meet the pressure exerted by the passage of the payout wire and free to rapidly fall back onto the wire coil after the paying wire is no longer in contact with them. The movement which is thus generated is comparable to “The Wave” or “La Ola”, namely a wave of spectators in a packed sport stadium which briefly stand and raise their arms, and then return to their usual seated position, thereby creating the visual effect of a wave traveling through the crowd.
By forming the retainer from a plurality of segments, a modular retainer plate is formed for dynamically controlling the wires strands contained in a bulk pack by partially engaging with the single strand of wire being paid out and at the same time self-adapting to the shape of the wire coil. Thanks to its particular configuration the retainer plate, while holding its segments or “tiles” connected to one another, still allows each individual segment (or two adjacent segments) to react independently to the force exerted by the passage of the wire being paid out and to be lifted upward, while the other segments of the retainer stay down in direct contact with the coil to better control the remaining wire strands and to prevent them from being inadvertently pulled and tangled.
Preferably, the segments are identical. This reduces the manufacturing costs as a single mold is sufficient for producing all the segments.
According to a preferred embodiment of the invention, each segment comprises a first connection section and a second connection section, the first and second connection sections being arranged at opposite ends of the segment, the first connection section of one of the segments being connected to the second connection section of an adjacent one of the segments. This allows joining the segments in a chain-like manner so as to form a closed ring.
Preferably, the first connection section and the second connection section mechanically engage into each other. Having the segments engage each other mechanically ensures that they are reliably connected to each other such that unintentional separation is prevented.
According to a preferred embodiment of the invention, the segments overlap each others, preferably with the second connection section being arranged on top of the first connection section. In this manner, it is ensured that the wire withdrawn from under the retainer cannot get caught in a gap between the segments but reliably slides from one segment onto the adjacent one.
Preferably, the first connection section comprises a projection and the second connection section comprises an opening into which the projection engages. This solution allows to achieve a strong connection between adjacent segments.
For reliably and quickly connecting the segments to each other, the projection can be formed as at least one latch.
Preferably, the segments of the retainer form a ring, the inner circumference of the ring comprising a shoulder which is arranged at a level which is different from a level defined by the contact surface. The shoulder provides an additional holding effect for the upper strands or turns of the wire coil, thereby preventing them from unintentionally falling into the center space of the coil.
In order to increase the retaining effect of the retainer on the wire of the wire coil, the contact surface comprises roughened portions.
According to an embodiment of the invention, at least one of the segments is provided with a weight element. The weight element increases the weight of the retainer, thereby increasing the retaining effect on the wire. This allows adapting the retainer to different wires. For thinner wires, a retainer is used which is formed from the segments only. For thicker wires, the retainer can be equipped with an appropriate number of weights of with weights having the appropriate mass.
Preferably, the weight element is formed from metal. Due to the high specific weight of metal, a significant mass can be obtained while still having a compact weight element.
According to an embodiment of the invention, the weight element is mechanically connected to the segment in order to prevent unintentional separation of the weight element from the segment which could result in the weight element falling into the center space of the coil where it possibly is an obstacle to smooth withdrawal of the wire.
The retainer preferably comprises a fixture for the weight element so that it can be attached to the segment easily.
Preferably, the fixture comprises at least one elastic latch for releasably attaching the weight element to the segment. Thereby, the weight element can be attached to and removed from the segment without tools.
According to a preferred embodiment, the segments are made from plastics. This allows manufacturing the segments at low costs. It is of course possible to use other materials as well.
In order to allow using corner reinforcements in the wire container, the segments form a ring, and the outer edge of the ring comprises recessed portions for accommodation of corner reinforcements of the wire container.
The invention further provides a wire container which has a reception space for a wire coil and a wire coil arranged in the reception space. The wire forms an annular end face of the wire coil from which the wire is withdrawn from the wire container. Further, a retainer for controlling the payout of wire from a wire container is provided. The retainer has at least three segments. Each segment is connected to the adjacent segment so as to allow a relative movement of adjacent segments with respect to each other. The entirety of the segments form a contact surface adapted for contacting the wire contained in the wire container.
According to an embodiment of the invention, the wire, in a direction from a free end towards the wire coil, defines a winding direction of the wire coil and the segments overlap each other such that, in the winding direction, the preceding segment extends under the succeeding segment. This features makes sure that the wire when “travelling” along the contact surface of the retainer smoothly passes from one segment to the next segment without there being a risk of being caught in a gap between adjacent segments.
The invention will now be explained with reference to the enclosed drawings. In the drawings,
Wire coil 18 is formed from a continuous wire which is laid in a plurality of turns so that a coil with a center space is formed. The central axis of the coil is arranged vertically. The wire is withdrawn from coil 18 by withdrawing the uppermost turn or layer of the coil. The portion currently withdrawn is designated in the drawings with reference numeral 22.
In order to allow smooth withdrawal of the wire from the coil in a vertical direction, the wire is wound to the coil in a pre-twisted condition. Accordingly, the wire is pretensioned when being held in the form of a coil. The pretension results in a certain tendency of the welding wire to entangle, in particular at the upper end face of the coil where the upper strands are not restrained by further strands sitting on top of them. In order to prevent unintentional entanglement, a retainer 24 is arranged on top of the wire coil. Retainer 24 rests on the upper end face of coil 18 simply by its own weight and descends downwardly towards the floor of the container when the welding wire is withdrawn from the container.
Retainer 24 (please see in particular
Each segment 26 (please see in particular
Both the first connection section 30 and the second connection section 32 are provided with recessed portions 32 whose dimensions are adapted to corner reinforcements 20 of container 10.
First connection section 30 and second connection section 32 are arranged at different levels so that the different connection sections of adjacent segments 26 can be arranged in an overlapping manner while achieving a smooth, continuous contact surface 27. In other words, the upper surface of first connection section 30 (as viewed in
Each segment 26 comprises a shoulder 38 which defines a level which is further away from hooks 34 than contact surface 27.
The center portion 28 of each segment 26 features a fixture or accommodation for a weight element, the fixture being formed by a plurality of elastic latches 40. The fixture is adapted to receive a weight element 42 in the form of a rectangular metal plate.
For forming retainer 24, a plurality of segments are connected to each other by engaging hooks 34 of one segment into opening 36 of an adjacent segment. In the particular embodiment shown in the drawings, eight segments 26 are joined so that the closed ring forming the retainer is achieved. As can be seen in
Retainer 24 is placed on the upper surface of coil 18 so that contact surface 27 of retainer 24 contacts the upper strands of the coil while shoulder 38 protrudes inwardly and downwardly into the center space of coil 18. As can be seen in
When welding wire is withdrawn from the container, wire portion 22 currently lifted from coil 18 “travels” in a peripheral direction along the upper face of coil 18. Since hooks 34 are larger than the wall thickness of second connection portion 32, segments 26 can be displaced with respect to each other in a direction which is perpendicular to the plane defined by retainer 24. In other words, the wire currently withdrawn from the coil is able to lift the segment which he currently contacts, while the remaining segments continue to sit flatly on the coil. Looking at
Hooks 34 allow a lifting movement of one segment relative to the adjacent one which is at least equivalent to the distance with which shoulder 38 extends downwards over surface 27, so as to prevent any excessive bending of the wire currently withdrawn from the coil. The allowed upward travel of the segments ensures that the wire can be withdrawn first in a radial direction and then upwardly, rather than being first forced downwardly by shoulder 38 and then withdrawn upwardly.
Depending from the thickness and the rigidity of the wire from which coil 18 is formed, weight elements 42 with an appropriate mass can be fixed to the upper surface of each of the segments. This allows using one and the same segment in different applications with different wires.
Segments 26 are preferably formed from a plastics material so that they can be injection-molded. This results in low manufacturing costs. Further, hooks 34 and opening 36 for mechanically connecting segments 26 to each other can be formed integrally in the injection-molding process. It is of course possible to use other materials for forming the segments and to use separate components attached to the segments for connecting the segments to each other.
As an alternative to hooks 34 and openings 36, a flexible rubber strip attached to the segments could be used for forming retainer ring 24.
Contact surface 27 is preferably formed with a high surface roughness which can be easily implemented when injection-molding the segments.
The retainer described above has a couple of advantages regarding construction, storage, transport and recycling.
Each segment can be made with a smaller and therefore inexpensive mold with limited dimensions, while a one piece retainer plate of large dimensions would require a huge mold and massive equipment to produce.
The individual retainer segments can be easily transported from the supplier to assembly area, since they occupy little space and can also be shipped as replacement spare parts to end user customers in case of urgent need, allowing them to easily assemble their own retainers.
Before assembly, the segments forming the retainer can be easily stored thus avoiding the deformation which can occur with very large and relatively thin one piece retainers.
Disassembled segments after use can be easily gathered in one container and returned to the wire manufacturer for recycling, with space saving during storage and return transport.
Further, the retainer described above has a couple of advantages regarding the performance.
The relatively small weight of each individual segment, as opposed to the overall weight of the complete retainer, does not plastically deform the wire strand being paid out and this is very positive for those welding applications that require extreme accuracy and precision of weld placement. A deformed welding wire can cause “wavy” welds or can miss the “true tool point” where the weld is intended to be placed.
The segments, after the wire has passed, fall back onto the wire coil duly controlling the other strands which are not involved in the payout, and this prevents tangling and consequent unwanted production stops.
In other words, through this innovative construction and design, the retainer function is not any longer to force the payout wire to adapt itself to the retainer (a likely scenario with thinner and softer wires but absolutely impossible to achieve with large diameter and strong wires), but to have the retainer adapt itself to the wire payout by using a number of floating elements, connected together to form one retainer, that follow the wire and match its movements regardless of its “columnar” strength and size, while still effectively blocking and controlling the rest of the wire coil contained in the bulk pack.
The difference between the first and the second embodiment relates to the connection between the segments, and to the accommodation of weight elements 42.
Instead of hooks 34, elastic latch tabs 50 are used which are provided with a rounded collar 52 (please see in particular
For holding the weight elements, the retainer according to the second embodiment is provided with a fixture 54 which is formed from two rail-like elements 56 arranged parallel to each other, and an abutment 58. The dimensions of rail-like elements 56 are chosen such that weight elements 42 are held by frictional forces.
In
The difference between the second and the third embodiment relates to the connection between adjacent segments 26. In the third embodiment, a mechanical locking system is used which allows connecting the segments when they are in a particular orientation with respect to each other, and mechanically locking the segments to each other when the segments assume a position with respect to each other which is different from the particular orientation which allows connecting them.
As can be seen in particular in
Instead of the particular design with triangles 64 and triangular recesses in opening 36, other designs are possible which feature a retaining element which is non-circular. It is simply necessary that the mounting of the segments is possible in one orientation of the segments with respect to each other while a locking effect is achieved when the segments are in the position with respect to each other which they assume when forming the ring-like retainer.
Number | Name | Date | Kind |
---|---|---|---|
318062 | Warren | May 1885 | A |
532565 | Kilmer | Jan 1895 | A |
617353 | Redmond | Jan 1899 | A |
627722 | Edwards | Jun 1899 | A |
932808 | Pelton | Aug 1909 | A |
1276117 | Riebe | Aug 1918 | A |
1468994 | Cook | Sep 1923 | A |
1508689 | Glasser | Sep 1924 | A |
1640368 | Obetz et al. | Aug 1927 | A |
1821354 | Meyer | Sep 1931 | A |
1907051 | Emery | May 1933 | A |
2027670 | Broeren | Jan 1936 | A |
2027674 | Broeren | Jan 1936 | A |
2059462 | Jungmann | Nov 1936 | A |
2329369 | Haver | Sep 1943 | A |
2366101 | Grothey | Dec 1944 | A |
2407746 | Johnson | Sep 1946 | A |
2457910 | McLaren et al. | Jan 1949 | A |
2477059 | Hill | Jul 1949 | A |
2483760 | Duncan | Oct 1949 | A |
2579131 | Tinsley | Dec 1951 | A |
2580900 | Epstein | Jan 1952 | A |
2679571 | Chappel | May 1954 | A |
2694130 | Howard | Nov 1954 | A |
2713938 | Snyder | Jul 1955 | A |
2724538 | Schweich | Nov 1955 | A |
2752108 | Richardson | Jun 1956 | A |
2838922 | Gift | Jun 1958 | A |
2849195 | Richardson | Aug 1958 | A |
2864565 | Whearley | Dec 1958 | A |
2869719 | Hubbard | Jan 1959 | A |
2880305 | Baird | Mar 1959 | A |
2911166 | Haugwitz | Nov 1959 | A |
2929576 | Henning | Mar 1960 | A |
2966258 | Krafft | Dec 1960 | A |
2974850 | Mayer | Mar 1961 | A |
2984596 | Franer | May 1961 | A |
3022415 | Francois | Feb 1962 | A |
3096951 | Jenson | Jul 1963 | A |
3108180 | Linnander | Oct 1963 | A |
3119042 | Bond | Jan 1964 | A |
3185185 | Pfund | May 1965 | A |
3244347 | Jenk | Apr 1966 | A |
3274850 | Tascio | Sep 1966 | A |
3283121 | Bernard et al. | Nov 1966 | A |
3284608 | McDonald | Nov 1966 | A |
3344682 | Bratz | Oct 1967 | A |
3352412 | Draving et al. | Nov 1967 | A |
3433504 | Hanes | Mar 1969 | A |
3463416 | Quenot | Aug 1969 | A |
3478435 | Cook | Nov 1969 | A |
3491876 | Zecchin | Jan 1970 | A |
3512635 | Lang | May 1970 | A |
3536888 | Borneman | Oct 1970 | A |
3565129 | Field | Feb 1971 | A |
3567900 | Nelson | Mar 1971 | A |
3576966 | Sullivan | May 1971 | A |
3595277 | Lefever | Jul 1971 | A |
3648920 | Stump | Mar 1972 | A |
3690567 | Borneman | Sep 1972 | A |
3724249 | Asbeck et al. | Apr 1973 | A |
3729092 | Marcell | Apr 1973 | A |
3730136 | Okada | May 1973 | A |
3799215 | Willems | Mar 1974 | A |
3815842 | Scrogin | Jun 1974 | A |
3823894 | Frederick et al. | Jul 1974 | A |
3939978 | Thomaswick | Feb 1976 | A |
4000797 | Ducanis | Jan 1977 | A |
4043331 | Martin et al. | Aug 1977 | A |
4044583 | Kinney, Jr. | Aug 1977 | A |
4074105 | Minehisa et al. | Feb 1978 | A |
4097004 | Reese | Jun 1978 | A |
4102483 | Ueyama et al. | Jul 1978 | A |
4113795 | Izawa et al. | Sep 1978 | A |
4127590 | Endo et al. | Nov 1978 | A |
4157436 | Endo et al. | Jun 1979 | A |
4161248 | Kalmanovitch | Jul 1979 | A |
4171783 | Waltemath | Oct 1979 | A |
4172375 | Rushforth et al. | Oct 1979 | A |
4188526 | Asano | Feb 1980 | A |
4222535 | Hosbein | Sep 1980 | A |
4254322 | Asano | Mar 1981 | A |
4274607 | Priest | Jun 1981 | A |
4280951 | Saito et al. | Jul 1981 | A |
4293103 | Tsukamoto | Oct 1981 | A |
4354487 | Oczkowski et al. | Oct 1982 | A |
4392606 | Fremion | Jul 1983 | A |
4396797 | Sakuragi et al. | Aug 1983 | A |
4429001 | Kolpin et al. | Jan 1984 | A |
4451014 | Kitt et al. | May 1984 | A |
4464919 | Labbe | Aug 1984 | A |
4500315 | Pieniak et al. | Feb 1985 | A |
4540225 | Johnson et al. | Sep 1985 | A |
4546631 | Eisinger | Oct 1985 | A |
4575612 | Prunier | Mar 1986 | A |
4582198 | Ditton | Apr 1986 | A |
4585487 | Destree et al. | Apr 1986 | A |
4623063 | Balkin | Nov 1986 | A |
4737567 | Matsumoto et al. | Apr 1988 | A |
4742088 | Kim | May 1988 | A |
4826497 | Marcus et al. | May 1989 | A |
4855179 | Bourland et al. | Aug 1989 | A |
4869367 | Kawasaki et al. | Sep 1989 | A |
4891493 | Sato et al. | Jan 1990 | A |
4916282 | Chamming et al. | Apr 1990 | A |
4918286 | Boyer | Apr 1990 | A |
4949567 | Corbin | Aug 1990 | A |
4974789 | Milburn | Dec 1990 | A |
5051539 | Leathers-Wiessner | Sep 1991 | A |
5061259 | Goldman et al. | Oct 1991 | A |
5078269 | Dekko et al. | Jan 1992 | A |
5100397 | Poccia et al. | Mar 1992 | A |
5105943 | Lesko et al. | Apr 1992 | A |
5109983 | Malone et al. | May 1992 | A |
5147646 | Graham | Sep 1992 | A |
5165217 | Sobel et al. | Nov 1992 | A |
5201419 | Hayes | Apr 1993 | A |
5205412 | Krieg | Apr 1993 | A |
5215338 | Kimura et al. | Jun 1993 | A |
5227314 | Brown et al. | Jul 1993 | A |
5261625 | Lanoue | Nov 1993 | A |
5277314 | Cooper et al. | Jan 1994 | A |
5314111 | Takaku et al. | May 1994 | A |
5368245 | Fore | Nov 1994 | A |
5372269 | Sutton et al. | Dec 1994 | A |
5452841 | Sibata et al. | Sep 1995 | A |
5485968 | Fujioka | Jan 1996 | A |
5494160 | Gelmetti | Feb 1996 | A |
5530088 | Sheen et al. | Jun 1996 | A |
5553810 | Bobeczko | Sep 1996 | A |
5562646 | Goldman et al. | Oct 1996 | A |
5585013 | Truty | Dec 1996 | A |
5586733 | Miura et al. | Dec 1996 | A |
5590848 | Shore et al. | Jan 1997 | A |
5629377 | Burgert et al. | May 1997 | A |
5665801 | Chang et al. | Sep 1997 | A |
5692700 | Bobeczko | Dec 1997 | A |
5714156 | Schmidt et al. | Feb 1998 | A |
5738209 | Burr et al. | Apr 1998 | A |
5739704 | Clark | Apr 1998 | A |
5746380 | Chung | May 1998 | A |
5758834 | Dragoo et al. | Jun 1998 | A |
5778939 | Hok-Yin | Jul 1998 | A |
5816466 | Seufer | Oct 1998 | A |
5819934 | Cooper | Oct 1998 | A |
5845862 | Cipriani | Dec 1998 | A |
5847184 | Kleiner | Dec 1998 | A |
5865051 | Otzen et al. | Feb 1999 | A |
5921391 | Ortiz et al. | Jul 1999 | A |
5931408 | Ishii et al. | Aug 1999 | A |
5971308 | Boulton | Oct 1999 | A |
5988370 | Roemer et al. | Nov 1999 | A |
5990377 | Chen et al. | Nov 1999 | A |
6016911 | Chen | Jan 2000 | A |
6019303 | Cooper | Feb 2000 | A |
6103358 | Bruggermann et al. | Aug 2000 | A |
6159591 | Beihoffer et al. | Dec 2000 | A |
6237768 | Cipriani | May 2001 | B1 |
6245880 | Takeuchi et al. | Jun 2001 | B1 |
6255371 | Schlosser et al. | Jul 2001 | B1 |
6260781 | Cooper | Jul 2001 | B1 |
6301944 | Offer | Oct 2001 | B1 |
6322016 | Jacobsson et al. | Nov 2001 | B1 |
6340522 | Burke et al. | Jan 2002 | B1 |
6408888 | Baeumer et al. | Jun 2002 | B1 |
6409116 | Brown | Jun 2002 | B1 |
6417425 | Whitmore et al. | Jul 2002 | B1 |
6425549 | Bae et al. | Jul 2002 | B1 |
6464077 | Liu | Oct 2002 | B1 |
6481892 | Agostini | Nov 2002 | B1 |
6498227 | Horie | Dec 2002 | B1 |
6524010 | Derman | Feb 2003 | B1 |
6547176 | Blain et al. | Apr 2003 | B1 |
6564943 | Barton et al. | May 2003 | B2 |
6613848 | Wang et al. | Sep 2003 | B1 |
6636776 | Barton et al. | Oct 2003 | B1 |
6648141 | Land | Nov 2003 | B2 |
6649870 | Barton et al. | Nov 2003 | B1 |
6708864 | Ferguson, III et al. | Mar 2004 | B2 |
6715608 | Moore | Apr 2004 | B1 |
6745899 | Barton | Jun 2004 | B1 |
6749139 | Speck | Jun 2004 | B2 |
6750262 | Hahnle et al. | Jun 2004 | B1 |
6753454 | Smith et al. | Jun 2004 | B1 |
6821454 | Visca et al. | Nov 2004 | B2 |
6831142 | Mertens et al. | Dec 2004 | B2 |
6872275 | Ko et al. | Mar 2005 | B2 |
6889835 | Land | May 2005 | B2 |
6913145 | Barton et al. | Jul 2005 | B2 |
6938767 | Gelmetti | Sep 2005 | B2 |
6977357 | Hsu et al. | Dec 2005 | B2 |
7004318 | Barton | Feb 2006 | B2 |
7108916 | Ehrnsperger et al. | Sep 2006 | B2 |
7147176 | Rexhaj | Dec 2006 | B2 |
7152735 | Dragoo et al. | Dec 2006 | B2 |
7156334 | Fore et al. | Jan 2007 | B1 |
7178755 | Hsu et al. | Feb 2007 | B2 |
7198152 | Barton et al. | Apr 2007 | B2 |
7220942 | Barton et al. | May 2007 | B2 |
7309038 | Carroscia | Dec 2007 | B2 |
7377388 | Hsu et al. | May 2008 | B2 |
RE40351 | Cipriani | Jun 2008 | E |
7398881 | Barton et al. | Jul 2008 | B2 |
7410111 | Carroscia | Aug 2008 | B2 |
7441657 | Gelmetti | Oct 2008 | B2 |
7441721 | Bae et al. | Oct 2008 | B2 |
7533906 | Luettgen et al. | May 2009 | B2 |
7563840 | Ye | Jul 2009 | B2 |
7748530 | Hsu et al. | Jul 2010 | B2 |
7950523 | Gelmetti | May 2011 | B2 |
8207475 | Minato et al. | Jun 2012 | B2 |
8235210 | De Lacerda et al. | Aug 2012 | B2 |
20010014706 | Sprenger et al. | Aug 2001 | A1 |
20020000391 | Kawasai et al. | Jan 2002 | A1 |
20020003014 | Homma | Jan 2002 | A1 |
20020014477 | Lee et al. | Feb 2002 | A1 |
20020039869 | Achille | Apr 2002 | A1 |
20020120178 | Tartaglia et al. | Aug 2002 | A1 |
20030042162 | Land | Mar 2003 | A1 |
20030042163 | Cipriani | Mar 2003 | A1 |
20030052030 | Gelmetti | Mar 2003 | A1 |
20030184086 | Christianson | Oct 2003 | A1 |
20040020041 | Ferguson, III et al. | Feb 2004 | A1 |
20040050441 | Roschi | Mar 2004 | A1 |
20040133176 | Muthiah et al. | Jul 2004 | A1 |
20040155090 | Jensen | Aug 2004 | A1 |
20040176557 | Mertens et al. | Sep 2004 | A1 |
20040186244 | Hatsuda et al. | Sep 2004 | A1 |
20040201117 | Anderson | Oct 2004 | A1 |
20040241333 | Cielenski et al. | Dec 2004 | A1 |
20040265387 | Hermeling et al. | Dec 2004 | A1 |
20050008776 | Chhabra et al. | Jan 2005 | A1 |
20050261461 | Maeda et al. | Nov 2005 | A1 |
20060027699 | Bae et al. | Feb 2006 | A1 |
20060074154 | Harashina et al. | Apr 2006 | A1 |
20060155254 | Sanz et al. | Jul 2006 | A1 |
20060247343 | Kishimoto et al. | Nov 2006 | A1 |
20060258824 | Oshima et al. | Nov 2006 | A1 |
20060278747 | Carroscia | Dec 2006 | A1 |
20070175786 | Nicklas | Aug 2007 | A1 |
20070272573 | Gelmetti | Nov 2007 | A1 |
20070284354 | Laymon | Dec 2007 | A1 |
20080156925 | Cooper | Jul 2008 | A1 |
20080257875 | De Keizer | Oct 2008 | A1 |
20080300349 | Fuchikami et al. | Dec 2008 | A1 |
20080314876 | Pinsonneault et al. | Dec 2008 | A1 |
20090014572 | Weissbrod et al. | Jan 2009 | A1 |
20090014579 | Bender et al. | Jan 2009 | A1 |
20090200284 | Sanchez | Aug 2009 | A1 |
20100116803 | Gelmetti | May 2010 | A1 |
20110073703 | Gelmetti et al. | Mar 2011 | A1 |
20110094911 | Gelmetti | Apr 2011 | A1 |
20110114523 | Gelmetti | May 2011 | A1 |
20110114617 | Gelmetti et al. | May 2011 | A1 |
20110132880 | Kossowan | Jun 2011 | A1 |
20130193259 | Weissbrod et al. | Aug 2013 | A1 |
Number | Date | Country |
---|---|---|
1466469 | Jan 2004 | CN |
1626423 | Jun 2005 | CN |
1011840 | Jul 1957 | DE |
1082215 | Nov 1957 | DE |
1 154 624 | Sep 1963 | DE |
2122958 | Nov 1972 | DE |
2 148 348 | Apr 1973 | DE |
2202177 | Jul 1973 | DE |
2525938 | Dec 1976 | DE |
26 46 218 | Apr 1977 | DE |
28 16 100 | Oct 1978 | DE |
36 09 839 | Oct 1989 | DE |
19909214 | Mar 1999 | DE |
199 10 128 | Jan 2001 | DE |
19958697 | Jun 2001 | DE |
100 06 592 | Aug 2001 | DE |
10292831 | Jan 2002 | DE |
103 60 466 | Jul 2005 | DE |
102007015946 | Feb 2008 | DE |
202011104120 | Jan 2012 | DE |
2 267 255 | Apr 1974 | EP |
0408259 | Apr 1992 | EP |
0519424 | Dec 1992 | EP |
2 264 482 | Sep 1993 | EP |
584056 | Feb 1994 | EP |
0665 166 | Jan 1995 | EP |
0686439 | Dec 1995 | EP |
0806429 | Nov 1997 | EP |
1 057 751 | Dec 2000 | EP |
1 070 754 | Jan 2001 | EP |
1 275 595 | Jan 2003 | EP |
1 295 813 | Mar 2003 | EP |
1 471 024 | Oct 2004 | EP |
1 698 421 | Jun 2006 | EP |
1 974 846 | Oct 2008 | EP |
1974846 | Oct 2008 | EP |
2 256 064 | Jan 2010 | EP |
2 354 039 | Jan 2010 | EP |
2 168 706 | Mar 2010 | EP |
2 286 950 | Feb 2011 | EP |
2695696 | Feb 2014 | EP |
1215111 | Apr 1960 | FR |
2055181 | May 1971 | FR |
2595674 | Mar 1988 | FR |
2 888 825 | Jan 2007 | FR |
880502 | Oct 1961 | GB |
1168928 | Oct 1969 | GB |
1229913 | Apr 1971 | GB |
1 575 157 | Sep 1980 | GB |
2059462 | Apr 1981 | GB |
2 332 451 | Jun 1999 | GB |
49-13065 | Feb 1974 | JP |
54-035842 | Mar 1979 | JP |
54-043856 | Apr 1979 | JP |
55-054295 | Apr 1980 | JP |
55-156694 | Dec 1980 | JP |
56-023376 | Mar 1981 | JP |
57-102471 | Jun 1982 | JP |
58-035068 | Mar 1983 | JP |
58-70384 | May 1983 | JP |
59-197386 | Nov 1984 | JP |
59-229287 | Dec 1984 | JP |
59-732669 | Dec 1984 | JP |
60-021181 | Feb 1985 | JP |
60-032281 | Feb 1985 | JP |
60-082275 | May 1985 | JP |
60-082276 | May 1985 | JP |
60-184422 | Sep 1985 | JP |
60-223664 | Nov 1985 | JP |
61-162541 | Jul 1986 | JP |
61-293674 | Dec 1986 | JP |
62-009774 | Jan 1987 | JP |
62-111872 | May 1987 | JP |
62-287055 | Dec 1987 | JP |
63-147781 | Jun 1988 | JP |
1-65265 | Apr 1989 | JP |
1-240222 | Sep 1989 | JP |
3-264169 | Nov 1991 | JP |
03264169 | Nov 1991 | JP |
4-112169 | Apr 1992 | JP |
04-133973 | May 1992 | JP |
4-274875 | Sep 1992 | JP |
5-178538 | Jul 1993 | JP |
7-247058 | Sep 1995 | JP |
8-40642 | Feb 1996 | JP |
08-150492 | Jun 1996 | JP |
08-267274 | Oct 1996 | JP |
2000-202630 | Jul 2000 | JP |
2000-225468 | Aug 2000 | JP |
2000-263239 | Sep 2000 | JP |
2001-26375 | Jan 2001 | JP |
2001-150187 | Jun 2001 | JP |
2001-323268 | Nov 2001 | JP |
KR 2002-0077857 | Oct 2002 | JP |
2004-025242 | Jan 2004 | JP |
2004-025243 | Jan 2004 | JP |
2004025220 | Jan 2004 | JP |
2005-169499 | Jun 2005 | JP |
2007-927 | Jan 2007 | JP |
2007-29971 | Feb 2007 | JP |
20040059894 | Dec 2002 | KR |
1020040059891 | Jul 2004 | KR |
793678 | Jan 1981 | SU |
1412830 | Jul 1988 | SU |
WO 8103319 | Nov 1981 | WO |
WO 8810230 | Dec 1988 | WO |
WO 94-00493 | Jan 1994 | WO |
WO 9419258 | Sep 1994 | WO |
WO 9700878 | Jan 1997 | WO |
WO 9852844 | Nov 1998 | WO |
WO 00-50197 | Aug 2000 | WO |
WO 0127365 | Apr 2001 | WO |
WO 02094493 | Nov 2002 | WO |
WO 03106096 | Dec 2003 | WO |
WO 2005005704 | Jan 2005 | WO |
WO 2005061168 | Jul 2005 | WO |
2006091075 | Aug 2006 | WO |
WO 2007010171 | Jan 2007 | WO |
WO 2007112972 | Oct 2007 | WO |
WO 2007149689 | Dec 2007 | WO |
WO 2009007845 | Jan 2009 | WO |
WO 2009143917 | Dec 2009 | WO |
WO 2011147565 | Dec 2011 | WO |
WO 2013092658 | Jun 2013 | WO |
Entry |
---|
Search Report received in Applicant's counterpart European Patent Application Serial No. 08017572.2-2302. |
Search Report received in Applicant's counterpart European Patent Application Serial No. 10014216.5-1256 (8 pages), dated Apr. 14, 2011. |
Search Report received in Applicant's counterpart European Patent Application Serial No. 11000892.7-2302 (8 pages), dated Jul. 19, 2011. |
Search Report received in Applicant's counterpart European Patent Application Serial No. 11000236.7 (8 pages), dated Aug. 4, 2011. |
Italian Search Report issued in related application No. MI20121423, dated Apr. 29, 2013 (2 pgs). |
Office Action issued in related U.S. Appl. No. 13/382,491, dated Jul. 11, 2013 (15 pgs). |
U.S. Office Action issued in related U.S. Appl. No. 12/572,994, dated Sep. 17, 2013 (13 pgs). |
Notice of Allowance dated Mar. 18, 2013 issued in U.S. Appl. No. 12/994,686 (10 pgs). |
Office Action issued in related U.S. Appl. No. 12/572,994, dated Apr. 24, 2013 (22 pgs). |
Extended European Search Report issued in related application No. 13179908.2, dated Nov. 13, 2013 (6 pgs). |
“International Plastics Flammability Handbook” Jurgen Troitzsch, 2nd edition, 1990, pp. 33, 43-49 and 59. |
Chinese Official Action dated Mar. 17, 2010. |
EPO Office Action issued for related application No. 09753572.8, dated May 2, 2012 (5 pgs). |
European Office Action for corresponding application No. 10 014 553.1-2302, dated Apr. 3, 2012 (4 pgs). |
European Office Action issued for 09777298.2, dated Aug. 31, 2012 (4 pgs). |
European Search Report, dated Mar. 2, 2011 (7 pgs). |
European Search Report, dated Sep. 17, 2008. |
Hansen et al., “Water Absorption and Mechanical Properties of Electrospun Structured Hydrogels”, Journal of Applied Polymer Science, vol. 95, pp. 427-434 (2005). |
International Preliminary Report on Patentability issued for related application No. PCT/EP2009/001285, dated Nov. 30, 2010 (7 pgs). |
International Preliminary Report on Patentability, dated Sep. 16, 2010 (5 pgs). |
International Preliminary Report, PCT/IPEA/409, 7 pages, Jul. 3, 2008. |
International Search Report and Written Opinion issued in corresponding PCT Appln. No. PCT/EP2009/005246, dated Apr. 6, 2010 (9 pgs). |
International Search Report issued in Applicants' underlying PCT Application Serial No. PCT/EP09/001285, dated Feb. 24, 2009 (3 pgs). |
International Search Report, dated Jul. 6, 2009 (3 pgs). |
Korean Official Action dated May 16, 2011, Appln. No. 2008-7005433, (3 pgs). |
Office Action issued for related U.S. Appl. No. 12/618,250, dated Apr. 26, 2012 (11 pgs). |
PCT International Search Report, dated Nov. 6, 2008. |
Plaza et al., Preparation of ethylenebis(nitrilodimethylene)tetrakis(phenylphosphinic acid), Inorganic Synthesis, vol. 16, No. 199, abstract, one page, Jan. 5, 2007. |
Ullmanns Encyclopedia of Industrial Chemistry, Sulfuric Acid & Sulfur Trioxide to Tetrahydrofuran, Superabsorbents, 6th Edition, vol. 35, pp. 73, 80, 86 and 89 (2003. |
US Official Action dated Feb. 13, 2012, issued in U.S. Appl. No. 12/917,320 (14 pgs). |
US Official Action dated Dec. 14, 2012, issued in U.S. Appl. No. 12/994,686 (17 pgs). |
US Official Action dated Mar. 5, 2013 issued in U.S. Appl. No. 13/382,491 (33 pgs). |
Notice of Allowance dated Mar. 5, 2013 issued in U.S. Appl. No. 12/593,271 (15 pgs). |
Number | Date | Country | |
---|---|---|---|
20130153705 A1 | Jun 2013 | US |