Embodiments of the present disclosure relate to rollers for transporting a flexible substrate. Further, embodiments of the disclosure relate to apparatuses and methods for flexible substrate processing, particularly coating of flexible substrates with thin layers, using a roll-to-roll process. In particular, embodiments of the disclosure relate to rollers employed for transportation of flexible substrates in apparatuses and methods for coating the flexible substrate with a stack of layers, e.g. for thin-film solar cell production, thin-film battery production, or flexible display production.
Processing of flexible substrates, such as plastic films or foils, is in high demand in the packaging industry, semiconductor industries and other industries. Processing may consist of coating a flexible substrate with a material, such as a metal, a semiconductor and a dielectric material, etching and other processing actions conducted on a substrate for the respective applications. Systems performing this task typically include a coating drum, e.g. a cylindrical roller, coupled to a processing system with a roller assembly for transporting the substrate, and on which at least a portion of the substrate is coated.
For example, a coating process such as a CVD process, a PVD process or an evaporation process can be utilized for depositing thin layers onto flexible substrates. Roll-to-roll deposition apparatuses are understood in that a flexible substrate of a considerable length, such as one kilometer or more, is uncoiled from a supply spool, coated with a stack of thin layers, and recoiled again on a wind-up spool. In particular, in the manufacture of thin film batteries, e.g. lithium batteries, the display industry and the photovoltaic (PV) industry, roll-to-roll deposition systems are of high interest. For example, the increasing demand for flexible touch panel elements, flexible displays, and flexible PV modules results in an increasing demand for depositing suitable layers in roll-to-roll-coaters.
For achieving high quality coatings on flexible substrates, various challenges with respect to flexible substrate transportation have to be mastered. For example, providing an appropriate substrate tension as well as a good substrate-roller contact and substrate cooling during the processing of the moving flexible substrate under vacuum conditions remain challenging.
Accordingly, there is a continuous demand for improved substrate transportation rollers, improved roll-to-roll processing apparatuses and methods therefor.
In light of the above, a roller for transporting a flexible substrate, a vacuum processing apparatus for processing a flexible substrate, a method of manufacturing a roller for guiding a flexible substrate, a method of processing a flexible substrate, and a method of manufacturing a coated flexible substrate according to the independent claims are provided. Further aspects, advantages, and features are apparent from the dependent claims, the description, and the accompanying drawings.
According to an aspect of the present disclosure, a roller for transporting a flexible substrate is provided. The roller includes a main body having a plurality of gas supply slits provided in an outer surface of the main body. The plurality of gas supply slits extends in a direction of a central rotation axis of the roller. Further, the roller includes a sleeve provided circumferentially around and in contact with the main body. The sleeve has a plurality of gas outlets provided above the plurality of gas supply slits. Further, the sleeve includes a metal layer embedded within isolating material.
According to another aspect of the present disclosure, a roller for transporting a flexible substrate is provided. The roller includes a main body having a plurality of gas supply slits provided in an outer surface of the main body. The plurality of gas supply slits extends in a direction of a central rotation axis of the roller. Additionally, the roller includes a sleeve provided circumferentially around and in contact with the main body. The sleeve includes a plurality of insets of isolating material with a plurality of gas outlets. The plurality of gas outlets is provided above the plurality of gas supply slits.
According to a further aspect of the present disclosure, a vacuum processing apparatus for processing a flexible substrate is provided. The vacuum processing apparatus includes a processing chamber including a plurality of processing units having at least one deposition unit. Further, the vacuum processing apparatus includes a roller according to any embodiments described herein for guiding the flexible substrate past the plurality of processing units. In particular, the roller is connected to an electrical potential application device.
According to another aspect of the present disclosure, a method of manufacturing a roller for guiding a flexible substrate is provided. The method includes producing a sleeve having a plurality of gas outlets by using laser drilling. The sleeve includes at least one of a metal layer embedded within isolating material and a plurality of insets of isolating material. Further, the method includes providing the sleeve circumferentially around and in contact with a main body of the roller having a plurality of gas supply slits provided in an outer surface of the main body such that the plurality of gas outlets is arranged above the plurality of gas supply slits.
According to a further aspect of the present disclosure, a method of processing a flexible substrate is provided. The method includes guiding the flexible substrate past one or more processing units by using a roller for transporting the flexible substrate according to any embodiments described herein. Further, the method includes controlling a temperature of the flexible substrate by providing gas to the flexible substrate through the plurality of gas outlets of the roller.
According to another aspect of the present disclosure, a method of manufacturing a coated flexible substrate is provided. The method includes using at least one of a roller according to any embodiments described herein, a vacuum processing apparatus according to any embodiments described herein, and a method of processing a flexible substrate according to any embodiments described herein.
Embodiments are also directed at apparatuses for carrying out the disclosed methods and include apparatus parts for performing each described method aspect. These method aspects may be performed by way of hardware components, a computer programmed by appropriate software, by any combination of the two or in any other manner. Furthermore, embodiments according to the disclosure are also directed at methods for operating the described apparatus. The methods for operating the described apparatus include method aspects for carrying out every function of the apparatus.
So that the manner in which the above recited features of the present disclosure can be understood in detail, a more particular description of the disclosure, briefly summarized above, may be had by reference to embodiments. The accompanying drawings relate to embodiments of the disclosure and are described in the following:
Reference will now be made in detail to the various embodiments of the disclosure, one or more examples of which are illustrated in the figures. Within the following description of the drawings, the same reference numbers refer to same components. Only the differences with respect to individual embodiments are described. Each example is provided by way of explanation of the disclosure and is not meant as a limitation of the disclosure. Further, features illustrated or described as part of one embodiment can be used on or in conjunction with other embodiments to yield yet a further embodiment. It is intended that the description includes such modifications and variations.
With exemplary reference to
Typically, the plurality of gas outlets 105 extends in a radial direction R. Further, the sleeve includes comprising a metal layer 106 embedded within isolating material 11.
Accordingly, compared to the prior art, beneficially an improved roller for transporting a flexible substrate is provided. In particular, embodiments of the roller described herein provide for the possibility to employ electrostatic interaction between a roller and a flexible substrate in order to increase the contact pressure, particularly in combination with a gas cooling of the flexible substrate. Further, due to the possibility of increasing the contact pressure between the roller and the flexible substrate, a higher gas pressure for substrate cooling can be used resulting in an improved cooling efficiency. Moreover, the particular configuration of the embodiments of the roller as described herein, e.g. providing an outer surface of the roller with an isolating material, means that detrimental effects such as current leakages or arcing caused by applying an electrical potential to the roller can be avoided.
Before various further embodiments of the present disclosure are described in more detail, some aspects with respect to some terms used herein are explained.
In the present disclosure, a “roller” can be understood as a drum or a roller having a substrate support surface for contacting the flexible substrate. The expression “substrate support surface for contacting the flexible substrate” can be understood in that the outer surface of the roller, e.g. the outer surface of the sleeve as described herein, is configured for contacting the flexible substrate during the guiding or transportation of the flexible substrate. Typically, the support surface is a curved outer surface, particularly a cylindrical outer surface, of the roller. Accordingly, typically the roller is rotatable about a rotation axis and includes a substrate guiding region. Typically, the substrate guiding region is a curved substrate support surface, e.g. a cylindrically symmetric surface, of the roller. The curved substrate support surface of the roller may be adapted to be (at least partly) in contact with the flexible substrate during the guiding of the flexible substrate. The substrate guiding region may be defined as an angular range of the roller in which the substrate is in contact with the curved substrate support surface during the guiding of the substrate, and may correspond to the enlacement angle of the roller. For instance, the enlacement angle of the roller may be 120° or more, particularly 180° or more, or even 270° or more. According to some embodiments, which can be combined with other embodiments described herein, the roller 100 is cylindrical and has a length L of 0.5 m≤L≤8.5 m. Further, the roller 100 may have a diameter D of 1.0 m≤D≤3.0 m. Accordingly, beneficially the roller is configured for guiding and transporting flexible substrates having a large width.
In the present disclosure, a “flexible substrate” can be understood as a bendable substrate. For instance, the “flexible substrate” can be a “foil” or a “web”. In the present disclosure the term “flexible substrate” and the term “substrate” may be synonymously used. For example, the flexible substrate as described herein may be made of or include materials like PET, HC-PET, PE, PI, PU, TaC, OPP, BOOP, CPP, one or more metals (e.g. copper), paper, combinations thereof, and already coated substrates like Hard Coated PET (e.g. HC-PET, HC-TaC) and the like. In some embodiments, the flexible substrate is a COP substrate provided with an index matched (IM) layer on both sides thereof. For example, the substrate thickness can be 1 μm or more and 1 mm or less, particularly 500 μm or less, or even 200 μm or less. The substrate width WS can be 0.3 m≤W≤8 m. The substrate may be a transparent or non-transparent substrate.
In the present disclosure, a “main body” of the roller can be understood as a cylindrical body, particularly a cylindrical shell body of solid material. Typically, the main body is made of a material having a high thermal conductivity λ, particularly λ≥50 W/(m·K), more particularly λ≥100 W/(m·K). For instance, the main body can be made of a material including copper such as copper alloys. In particular, the main body can be made of copper. It is to be understood that alternatively the main body may be made of any other suitable material having high thermal conductivity λ.
In the present disclosure, a “gas supply slit” can be understood as a slit configured for supplying gas to a plurality of gas outlets as described herein. In particular, typically a “gas supply slit” as described herein is provided in an outer surface of the main body and extends parallel to a central rotation axis of the roller. Typically, the central rotation axis of the roller corresponds to the central rotation axis of the main body. Moreover, typically a “gas supply slit” as described herein is connected to a gas supply. According to embodiments which can be combined with other embodiments described herein, the distance dG between gas supply slits in the circumferential direction can be selected from a range between a lower limit dGL and an upper limit dGU, i.e dGL≤dG≤dGU. The distance dG is exemplarily indicated in
In the present disclosure, a “sleeve” can be understood as a sleeve being in contact with an outer surface of a main body as described herein. Accordingly, the sleeve can be a shell provided circumferentially around and in contact with the main body. Typically, during transportation of the flexible substrate, the sleeve is at least partially in contact with the flexible substrate. In particular, the sleeve can provide the substrate support surface as described herein. Typically, the sleeve is made of a metal sheet. The sleeve can have a thickness T selected from a range between a lower limit TL and an upper limit TU, i.e. TL≤T≤TU. The lower limit TL can be TL=0.5 mm, particularly TL=1.0 mm, more particularly TL=1.5 mm. The upper limit TU can be TU=2.0 mm, particularly TU=2.5 mm, more particularly TU=3.0 mm.
In the present disclosure, a “gas outlet” can be understood as an outlet configured for providing gas to a flexible substrate during substrate transportation by the roller as described herein. Accordingly, a gas outlet as described herein can be understood as a gas discharge hole. The outlet diameter Dout of a gas outlet according to the present disclosure can be selected from a range between a lower limit DL and an upper limit DU, i.e. DL≤Dout≤DU. The lower limit DL can be DL=30 μm, particularly DL=40 μm, more particularly DL=60 μm. The upper limit DU can be DU=150 μm, particularly DU=100 μm, more particularly DU=80 μm. Typically, a gas outlet as described herein is created by using a laser drilling method. Laser drilling may also be referred to as laser firing. Typically, a “gas outlet” as described herein has a cylindrical inner surface having an inner diameter corresponding to the outlet diameter Dout of the gas outlet as described herein. In other words, a “gas outlet” as described herein can be understood as a cylindrical outlet having a constant outlet diameter Dout along the outlet axis, typically extending in the radial direction.
According to embodiments which can be combined with other embodiments described herein, the distance dC between neighbouring gas outlets in the circumferential direction can be selected from a range between a lower limit dCL and an upper limit dCU, i.e dCL≤dC≤dCU. The lower limit dCL can be dCL=4 mm, particularly dCL=6 mm, more particularly dCL=8 mm. The upper limit dCU can be dCU=10 mm, particularly dCU=12 mm, more particularly dCU=15 mm. For instance, the distance dC can be 10 mm. The distance dC between neighbouring gas outlets 105 in the circumferential direction is exemplarily indicated in
According to embodiments which can be combined with other embodiments described herein, the distance dA between neighbouring gas outlets in the axial direction can be selected from a range between a lower limit dAL and an upper limit dAU, i.e dAL≤dA≤dAU. The lower limit dAL can be dAL=4 mm, particularly dAL=6 mm, more particularly dAL=8 mm. The upper limit dAL can be dAL=10 mm, particularly dAL=12 mm, more particularly dAL=15 mm. For instance, the distance dA can be 10 mm.
According to embodiments which can be combined with other embodiments described herein, the distance dC between neighbouring gas outlets in the circumferential direction corresponds to the distance dA between neighbouring gas outlets in the axial direction, i.e. dC=dA. In other words, the plurality of gas outlets as described herein may be regularly distributed in the sleeve.
In the present disclosure, a “metal layer embedded within isolating material” can be understood as a layer of metal surrounded by an isolating material. For instance, the metal layer can have a thickness TM selected from a range between a lower limit TML, and an upper limit TMU, i.e. TML≤TM≤TMU. The lower limit TML can be TML=10 μm, particularly TML=20 μm, more particularly TML=30 μm. The upper limit TMU can be TMU=200 μm, particularly TMU=150 μm, more particularly TMU=100 μm.
It is to be understood that the metal layer embedded within isolating material as described herein may function as an E-chuck. Typically, an E-chuck is understood as a device configured for providing an electrostatic charge for holding a substrate by electrostatic force. Accordingly, the E-chuck is configured for providing an attraction force for holding the flexible substrate in contact with the curved surface of the roller. Accordingly, a constant and homogenous contact force between the flexible substrate and the roller may be further improved.
In the present disclosure, an “isolating material” can be understood as an electrically isolating material. Accordingly, an “isolating material” may be understood as an electrically non-conductive material, e.g. having very low electrical conductivity or negligible electrical conductivity. For instance, the isolating material may be a ceramic material or a polymeric material.
With exemplary reference to
As exemplarily shown in
With exemplary reference to
According to embodiments which can be combined with any other embodiments described herein, the metal layer 106 is connected to an electrical potential application device 140, as schematically indicated in
In the present disclosure, an “electrical potential application device” can be understood as a device being configured to apply an electrical potential to the roller, particularly to the metal layer of the roller. In particular, the electrical potential application device as described herein can be configured to provide a middle frequency (MF) electrical potential. For instance, the middle frequency (MF) electrical potential can be from 1 kHz to 100 kHz. Typically, the electrical potential application device is connected to the roller via a physical contact, e.g. an electrical contact. Accordingly, an electrical contact can be provided between the electrical potential application device and the roller. For instance, the electrical contact can be an electrical sliding contact or an electrical brush contact. According to another example, the electrical contact can be a plug contact. Accordingly, the electrical potential application device can be understood as a charging device configured for providing an electrical charge to the roller, particularly the metal layer embedded in isolating material. It is to be understood that typically electrical connection lines to the embedded metal layer are provided.
According to embodiments which can be combined with any other embodiments described herein, the electrical potential application device is configured for applying an electrical potential having a middle frequency (MF), particularly a frequency of 1 kHz to 100 kHz. In other words, the electrical potential provided from the electrical potential application device can be an electrical potential having a frequency of 1 kHz to 100 kHz. In particular, a middle frequency electric potential can be understood as an electrical potential with an alternating polarity at a frequency selected from the range of 1 kHz to 100 kHz. It has been found that applying a MF electrical potential to the coating drum has the advantage that a charge up of the substrate, particularly of the layer deposited on the substrate, can substantially be avoided or even eliminated. Accordingly, layers with higher quality (e.g. higher uniformity, less defects, etc.) can be deposited on the substrate.
With exemplary reference to
As schematically shown in
According to embodiments which can be combined with any other embodiments described herein, the surfaces of the gas supply slits 103 can be coated with isolating material. In other words, the gas supply slits 103 may include an isolating coating 103C, as exemplarily shown in
With exemplary reference to
As exemplarily shown in
As exemplarily shown in
Additionally, as exemplarily shown in
With exemplary reference to the block diagram shown in
According to embodiments, which can be combined with any other embodiments described herein, the method 300 further includes providing (represented by block 330 in
With exemplary reference to the block diagram shown in
According to embodiments, which can be combined with any other embodiments described herein, the method 400 further includes applying (represented by block 430 in
In view of the embodiments described herein, it is to be understood that, according to an aspect of the present disclosure, a method of manufacturing a coated flexible substrate can be provided. The method includes using at least one of a roller 100 according to any embodiments described herein, a vacuum processing apparatus 200 according to any embodiments described herein, and a method 400 of processing a flexible substrate according to any embodiments described herein.
In view of the above, it is to be understood that, compared to the state of the art, embodiments as described herein provide for improved flexible substrate transportation and substrate cooling, such that beneficially thinner and wider flexible substrates can be processed with improved processing results.
While the foregoing is directed to embodiments, other and further embodiments may be devised without departing from the basic scope, and the scope is determined by the claims that follow.