This invention relates to new and useful improvements in kilns, and has particular reference to a kiln for use in the detoxification of soil or earth containing toxic and hazardous chemicals The contamination of soil or earth with various toxic and hazardous chemicals is becoming more and more common. The use of such materials as PCB, TNT, and solvents such as toluene, xylene, and trichloroethane in agricultural and industrial applications, is becoming more and more common, and often leads to the contamination thereby of soil or earth, which must then be classified as extremely hazardous material. The decontamination and detoxification of such material presents certain problems. While the chemicals themselves may be combustible, or capable of being destroyed or rendered harmless by extreme heat, the soil is not. The soil is largely inorganic material, and is not capable of autogenous combustion, so that it cannot be burned, and as a result will often protect the chemicals intermixed therein from combustion, or from the heat necessary to render them harmless, if attempts are made to "burn" the earth or otherwise to subject it to high degrees of heat. A device which will perform this decontamination and detoxification efficiently and reliably would obviously be a substantial and valuable contribution to the art. The principal object of the present invention is the provision of a kiln in which the feedstock, earth or the like, is moved continuously through the kiln in the form of a tumbling bed, adn is subjected for the whole time it remains in the kiln to flame jets provided by an external fuel such as natural gas, oxygen or propane The flame jets not only raise the feedstock temperature to the very high level required for calcining, perhaps 2500-3000 deg. Fahr., but also stir or agitate the material in the bed to insure that the substantially incombustible material will be very thoroughly pulverized to fine particle size, which in turn insures that all of the contaminating chemicals mixed with the earth are thoroughly exposed to maximum heat for the combustion or thermal destruction thereof. I have elected to denote the process as calcination, which is believed to be accurate. Another object is the provision of a calcining kiln of the character described into longitudinally successive zones of which fuel gas and combustion air may be introduced in independently regulatable amounts. In this manner the heat requirements dictated by the stage to which the calcination has advanced in each kiln zone may be accomodated. A further object is the provision of a calcining kiln of the character described having means operable to direct cooling gases, such as air or nitrogen, into the kiln to cool the fuel gas and combustion air supply means, in order to protect the structural integrity of these elements against the extreme heat of calcination, without at the same time preventing the application of the calcining heat to the feedstock. A still further object is the provision of a kiln of the character described which may alternatively be used to treat combustible material capable of augtogeneous flame, the extreme heat being useful in guaranteeing a complete burnout of the carbon of such materials. Other objects are simplicity and economy of construction, and efficiency and dependability of operation.
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