The present application relates to the field of energy recovery and in particular to the use of shape memory alloys (SMA) for same.
Low grade heat, which is typically considered less than 100 degrees, represents a significant waste energy stream in industrial processes, power generation and transport applications. Recovery and re-use of such waste streams is desirable. An example of a technology which has been proposed for this purpose is a Thermoelectric Generator (TEG). Unfortunately, TEG's are relatively expensive. Another largely experimental approach that has been proposed to recover such energy is the use of Shape Memory Alloys.
A shape-memory alloy (SMA) is an alloy that “remembers” its original, cold-forged shape which once deformed returns to its pre-deformed shape upon heating. This material is a lightweight, solid-state alternative to conventional actuators such as hydraulic, pneumatic, and motor-based systems.
The three main types of shape-memory alloys are the copper-zinc-aluminium-nickel, copper-aluminium-nickel, and nickel-titanium (NiTi) alloys but SMAs can also be created, for example, by alloying zinc, copper, gold and iron.
The memory of such materials has been employed or proposed since the early 1970's for use in heat recovery processes and in particular by constructing SMA engines which recover energy from heat as motion.
In a first type, referred to as a crank engine, of which U.S. Pat. No. 468,372 is an example, convert the reciprocating linear motion of an SMA actuator into continuous rotary motion, by eccentrically connecting the actuator to the output shaft. The actuators are often trained to form extension springs. Some configurations require a flywheel to drive the crank through the mechanism's limit positions. A related type are Swash Plate Engines, which are similar to cranks except that their axis of rotation is roughly parallel to the direction of the applied force, instead of perpendicular as for cranks.
A second type are referred to as a pulley engines, an example of which is U.S. Pat. No. 4,010,612. In pulley engines, continuous belts of SMA wire is used as the driving mechanism. A pulley engine may be unsynchronized or synchronized. In unsynchronized engines, the pulleys are free to rotate independently of one another. The only link between different elements is rolling contact with the wire loops. In contrast, in synchronized engines, the pulleys are constrained such that they rotate in a fixed relationship. Synchronization is commonly used to ensure that two shafts turn at the same speed or keep the same relative orientation.
A third type of SMA engine may be referred to as field engines, an example of which is U.S. Pat. No. 4,027,479. In this category, the engines work against a force, such as a gravitational or magnetic field.
A fourth type of SMA engine is that of Reciprocating Engines of which U.S. Pat. No. 4,434,618 in an example. These reciprocating engines operate linearly, in a back-and-forth fashion, as opposed to cyclically.
A fifth type of SMA engine is that of Sequential Engines of which U.S. Pat. No. 4,938,026 is an example. Sequential engines move with small, powerful steps, which sum to substantial displacements. They work like an inchworm, extending the front part by a small step and then pulling the back part along. With the back part nearby, the front part can extend again.
A sixth type of SMA engine is shown in U.S. Pat. No. 5,150,770A, assigned to Contraves Italiana S.p.A., and discloses a spring operated recharge device. There are two problems with the Contraves device, namely it is difficult to recharge quickly in a reciprocating manner and secondly it is difficult to discharge the energy to a transmission system without losses occuring.
A seventh type of SMA engine is shown in US patent publication number US2007/261307A1, assigned to Breezway Australia Pty Limited, and discloses an energy recovery charge system for automated window system. Breezway discloses a SMA wire that is coupled to a piston which is used to pump fluid to a pressurised accumulator. The piston therefore moves in tandem with the SMA wire as it contracts and expands. By coupling the SMA wire to the piston in this manner, the SMA wire is in indirect communication with the energy accumulator via the pumped fluid which is ineffiecient and the Breezway system suffers from the same problems as Contraves.
In addition one of the difficulties with each of these types of SMA engines has been that of the cycle period of the SMA material. SMA material is generally relatively slow to expand and contract (10's of RPM). It has been and remains difficult to achieve a worthwhile reciprocating frequency that might be usefully employed in an industrial application (100's to 1000's of RPM). This is not a trivial task and generally is complicated and involves significant parasitic power losses.
Another problem in a drive incorporating a SMS engine is pressure fluctuation due to the contraction of Shape Memory Alloy (SMA) components contained within the power producing cores of the drive. This uniform contraction of the SMA components is caused by Bain strain, and results in a volumetric increase within the cores during the heating phase of the SMA. This volumetric change occurs in a system with an incompressible fluid present, and hence, may cause significant pressure variation which may result in system failure. Other patent publications in the art include U.S. Pat. No. 4,037,411 and U.S. Pat. No. 4,030,298.
The present application is directed to solving at least one of the above mentioned problems.
According to the invention there is provided, as set out in the appended claims, an energy recovery device comprising:
In one embodiment there is provided an energy recovery device comprising:
In one embodiment the invention links two cores volumetrically, and by operating them in opposing heating cooling cycles will allow for these volumetric fluctuations to cancel each other out.
The invention solves the problem of pressure fluctuation occurring in a drive caused by volumetric contraction and expansion of SMA wire contained within a closed immersed chamber. The invention disclosed offers a simple effective method of removing this issue with minimal additional components. The shrinking of the SMA wires causes a pressure drop in this instance, the pressure relief systems hereinbefore described therefore act in the opposite way to those for the linear systems.
In one embodiment the first and second cores are in fluid communication via an adjoining piston or hydraulic line.
In one embodiment a constant volume in each core is maintained through a piston connection between the first and second cores.
In one embodiment the first or second SMA core is linked with a moveable piston in the chamber; wherein the piston is configured with a shaft that has a substantially same Cross Sectional Area (CSA) that will displace the same combined volume of the linear and/or radial contractions of the SMA core over the length of one expansion or contraction.
In one embodiment the first or second SMA core is linked with a moveable first piston in the chamber; a second piston adapted to operate in a non-synchronous manner with the first piston.
In one embodiment the first or second immersion chamber is configured with an additional chamber comprising a biasing means, such as a spring, wherein on the SMA core expanding in said chamber the biasing means allows fluid to flow into the additional chamber.
In another embodiment there is provided an energy recovery device comprising:
In a further embodiment there is provided an energy recovery device comprising:
The invention provides a number of mechanical embodiments that remove issues associated with attempting to solve the pressure pulsing issue using hydraulic linkages through the working fluid. These methods will share the pressure pulse with other pressure vessels in the system, which are not capable of withstanding rapid pressure variations. A mechanical linkage method does not incorporate these issues, as it will maintain a constant volume at all times.
The invention provides a mechanical volume exchange embodiment that reduces the required inventory when compared with pressure relief methods whereby each individual core contains a mechanism which allows for pressure regulation independent of other cores in the system. Therefore, this represents an advantage for the mechanical volumetric exchange concept over these approaches, as it will require one pressure relief mechanism for every two cores in the system. This concept will also partition the fluid within coupled cores, preventing mixing of hot and cold fluid flows. This offers an advantage over other methods which require an exchange of fluid to take place, as the mixing of fluid with different temperatures may have a negative effect on the operation of the SMA components contained within cores. An example of this may be a cold flow entering a heating core, where this cold flow would reduce the temperature in the core and thereby increase the time required to fully contract the SMA wire contained within said core.
In one embodiment there is provided a plurality of rotary stacked cores on a shaft where the net effect is a total accumulated movement of the shaft without the cumulative movement of the stacked cores themselves. This is made possible by the use of the over-running clutches at the centre of the core.
The invention will be more clearly understood from the following description of an embodiment thereof, given by way of example only, with reference to the accompanying drawings, in which:—
It will be appreciated that while SMA material/core is substantially described herein with respect to the Figures, the invention can be applied to a class of materials more generally known as ‘active material’ or Negative Thermal Expansion (NTE) materials. NTE materials include those compositions that can exhibit a change in stiffness properties, shape and/or dimensions in response to an activation signal, which can be an electrical, magnetic, thermal or a like field depending on the different types of active materials. Preferred active materials include but are not limited to the class of shape memory materials, and combinations thereof. Shape memory materials, a class of active or NTE materials, also sometimes referred to as smart materials, refer to materials or compositions that have the ability to remember their original shape, which can subsequently be recalled by applying an external stimulus (i.e., an activation signal).
An embodiment of the power producing cores is a rotary arrangement, as shown in
The operation of a single module as it transitions from a cold state to a heated state is illustrated. This process results in the SMA wire undergoing a phase change from martensite to austenite. This change results in the wire contracting uniformly due to Bain strain as it rotates the central shaft. As mentioned previously, this contraction alters the volume of the core. The operation of a single module of the rotary core is shown in
It can be seen from
It can be concluded from
Hydraulic methods of pressure relief rely on the working fluid within the system to operate mechanisms which alter the volume of the system in order to counter act the volume changes caused by the SMA. There are multiple arrangements which this aspect of the invention maybe embodied, which are now described:
It has been concluded above that the volume of each core will increase during heating, and decrease during cooling. In one embodiment the invention links two cores volumetrically, and by operating them in opposing heating cooling cycles will allow for these volumetric fluctuations to cancel each other out. This link allows for the excess volume created by a cooling core to be “passed on” to a heating core in order to cancel out the volumetric change caused by the contracting wire located in the heating core. This operation is illustrated in
The method illustrated in
In order to appropriately size a Pressure Relief Piston (PRP) for this application, the volumetric displacements caused by the SMA components must first be identified. The contraction undergone by the SMA wire is caused by Bain strain. This results in the wire contracting in all directions. In the case of a wire the contractions occur linearly and radially. This is shown in
In order to determine the correct diameter of the piston shaft, the following procedure should be followed:
V
1
=A
1(lm−la)
V2=A2la
V
SMA=(V1+V2)N
The total volume displaced by the SMA wires can now be implemented to assist in specifying an appropriate PRP link. The main factors which must be considered for designing the PRP head are the Cross Sectional Area (CSA) of the head, and the required level of deflection. Both of these factors will be functions of the displaced volume of the SMA components within the core.
Using the equation for volume of a cylinder, the dimensions of the pressure relief piston head can be calculated, provided either the allowable deflection or piston face diameter of the component is known. This methodology can be applied to designing a piston head for use with the hydraulic line of a motorbike master cylinder, for example. In such a device there is an allowable movement of roughly 10mm. Assuming the required volume to be displaced has already been calculated, and an allowable deflection is imposed, the following procedure can be followed to determine an appropriate piston face diameter, where Ah is the CSA of the PRP face.
The above procedure may be manipulated to determine the required allowable deflection for a specified face diameter. An example of when this may be appropriate could be designing the device for use with standard piston parts.
Another method of hydraulic pressure relief is through fluid exchange, where the displaced volumes of fluid are passed between cores thereby eliminating the pressure pulse. The volume exchange would be achieved through a direct link to each core, where fluid will be free to flow. This will lead to pressure being relieved, as excess volume from a cooling core can be passed on to a heating core, compensating for this increase in volume. The connection can be attached at the core outlets to the next cores inlet. This results in excess volume being forced though the outlet, and volume being added to the inlet. This is preferable as the volume displacements will be in line with the flow of the working fluid.
In the most basic embodiment of the invention a drive comprising two SMA cores are provided, heating and cooling in opposing sequences.
It may be said that the exchange of fluid between two cores as shown in
The one-way valves used in the mechanism can be pressure sensitive, in that they must act as a closed valve at normal operating pressure, but then act as an open one-way valve when this pressure increases due to the expanding SMA. Therefore, it may be required to define the pressure pulse in order to spec this valve. The pulse can be determined using the bulk modulus formula. The bulk modulus can be used as a method of measuring the amount of compression a material will undergo under a given pressure.
The bulk modulus, B, is defined by the following equation;
Where P is pressure in Pascals (Pa), and V is volume in m3.
Therefore, the change in pressure or pressure pulse can be found by supplying the above equation with the initial volume of the system, the change in volume, and the bulk modulus of the fluid contained therein.
The drive may use various different fluids for different applications, and hence the bulk modulus of these various fluids would need to be identified. For example in some embodiments this fluid may be water, whose bulk modulus is 2.2×109 N/m2. The initial volume of the system can be found by determining the total volume contained within all cores, all piping used, reservoirs etc. Finally, the change in volume can be found by determining the volumetric displacement caused by the SMA, as discussed above. Once the value for the pressure drop is determined, an appropriately sensitive valve can be specified.
Appropriate alterations to the power producing cores can allow for mass to be moved about said core in such a way which would facilitate a decrease in the volume of the core, which can offset the variation caused by the contracting SMA. This may be applied to various configurations of the Drive.
The use of compression spring resisted pistons within the Piston Housing (PH) provides a solution to the pressure variation issue. These pistons allow for volumetric increases and decreases when needed within the core in order to counteract the volume changes caused by the expanding and contracting SMA wire, as illustrated in
As can be seen in
Using Hooke's Law, it is possible to define the required spring constant (k) which would be used to determine a spring which would allow the required deflections which it must undergo. Hooke's Law can be expressed via the equation;
F=−kx
Where F is the force applied to the spring, and x is the resulting deflection of the spring.
Since the primary function of the spring will be to displace a specific volume based on its piston face surface area, it is necessary to determine the correct value for the spring constant (k) based on the piston's required displacement. This can be achieved as follows.
F
i
=−kx
i [1]
F
f
=−kx
f [2]
F
f
=−k(xi−xd)
Another arrangement which this embodiment can take is one in which power is drawn from the pressure variations. This can be achieved by mating a hydraulic line with a transmission, which can be used for various applications, including contributing to the power output of the system, or operating a valve train. The arrangement consists of a piston, a return spring, and a transmission, as illustrated in
As can be seen from
Mechanical methods of pressure relief that rely on means which are isolated from the working fluid to alter the volume of the system in order to counter act the volume changes caused by the SMA. There are multiple arrangements which this concept may appear. These are discussed as follows.
In one embodiment the device uses a piston with a threaded shaft to offer a mechanism for pressure relief. The piston can be coupled with the output shaft located in the centre of the core, and would convert the rotary movement of this shaft into linear, in order to regulate the volume. The operation of such a device is shown in
It can be seen from
Multiple methods of preventing the piston from rotating within its housing may be employed. One such method could be to manufacture a notch into the housing which would be used as a rail for sliding the piston linearly, while preventing its rotation. This would be achieved by including a boss on the piston head which would correspond to the notch in the housing. A 3D mock-up of this mechanism is shown in
In order for this pressure relief mechanism to operate correctly, it should displace an equal volume to that caused by the SMA contraction. Therefore a method of determining an appropriate piston size must be devised. It can be said that if the PRP displaces a volume equal to VSMA during its upstroke (during core heating), then it will cancel out the volume increase caused by the SMA contraction. Assuming the allowable distance which the piston can travel due to geometrical constraints within the core is known as well as the volume associated with the SMA contraction, a suitable piston size can be found, by following the procedure outlined below.
where dR is the diameter of the piston rod.
Therefore it can be said that, using the above procedure, it is possible to specify an appropriately sized PRP head based on the geometries of the core.
In addition to the considerations given above when defining an appropriate piston size, attention must be given to the suitability of the thread located on the piston shaft. This thread should be capable of producing the desired linear displacement to the piston for a set rotation. This property is dependent upon the geometries of the screw. Such geometries are the distance between threads along the screw (pitch), and the linear distance along the screw which it will travel in one revolution (lead). The lead can be increased by either increasing the pitch or using additional starts (more individual ridges).
The use of bevel gears and a rack and pinion allows for the rotational movement of the output shaft to be converted to linear movement. This can then be used to operate a pressure relief piston in a similar method to the threaded piston and spring piston concepts. This piston will alter the volume of the core appropriately in order to maintain a constant pressure.
It can be seen from
This method of pressure relief can operate by maintaining a constant volume in each core through a piston connection between two cores operating in an antagonistic or opposing fashion. The movement of this piston (or pistons) will be governed by a mechanical linkage between it and the output shafts of the cores. An example of such an arrangement is shown in
As can be seen in
The PRP can displace the correct volume of fluid. This volume will have to be of equal magnitude as that displaced by the SMA contraction.
As can be seen from
VSMA=VP
Considering this relationship, the following procedure may be followed in order to define a suitable piston size.
Where dR is the diameter of the piston rod.
Therefore it can be said that, using the above procedure, it is possible to specify an appropriately sized PRP head based on the SMA volumetric contraction.
The words comprises/comprising when used in this specification are to specify the presence of stated features, integers, steps or components but does not preclude the presence or addition of one or more other features, integers , steps, components or groups thereof.
The invention is not limited to the embodiments hereinbefore described but may be varied in both construction and detail.
Number | Date | Country | Kind |
---|---|---|---|
1310531.7 | Jun 2013 | GB | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2014/062395 | 6/13/2014 | WO | 00 |