Information
-
Patent Grant
-
6565315
-
Patent Number
6,565,315
-
Date Filed
Wednesday, March 14, 200123 years ago
-
Date Issued
Tuesday, May 20, 200321 years ago
-
Inventors
-
Original Assignees
-
Examiners
Agents
- Oblon, Spivak, McClelland, Maier & Neustadt, P.C.
-
CPC
-
US Classifications
Field of Search
US
- 415 203
- 415 206
- 415 2082
- 415 2112
- 415 915
- 415 220
- 415 221
- 416 198 R
- 416 235
- 416 236 R
- 417 366
- 417 572
- 417 4231
-
International Classifications
-
Abstract
A rotation device including first and second passages and a rotor shaft with a rotor which connects onto the first passage with a third passage which branches into rotor channels from the third to a fourth passage. The end zones of the third and fourth passages extend axially. The rotation device has a stator including a first central body with an outer surface which co-bounds a passage space with stator blades which have on one end zone forming a fifth passage a direction differing from the axial direction and on another end zone forming a sixth passage a direction differing little from the axial direction. The fifth passage connects onto the fourth passage and the sixth passage connects onto the second passage. The stator includes a second central body where between the sixth passage and the second passage extend manifold channels bounded by the second central body and the housing.
Description
BACKGROUND OF THE INVENTION
Rotation devices are known in many embodiments.
A centrifugal pump is for instance known with an axial inlet and a rotor with blades for flinging a liquid for pumping radially outward under the influence of centrifugal forces, and one or more for instance tangential outlets.
Further known is an axial compressor having groups of rotor and stator blades ordered in cascade. The structure comprises many thousands of components of extremely complex form which must moreover comply with high standards of dimensional accuracy and mechanical strength. An example hereof is a gas turbine, wherein in this case gaseous medium under pressure is delivered by a source intended for this purpose and is directed onto the blades of a rotor such that this rotor is driven with force, for instance to rotatingly drive a machine such as an electric generator.
These known devices display flow instabilities, particularly at low flow rates. These usually cause an imbalance in the rotor load which gives rise to heavy vibrations, uncontrollable variations in rotation speed and very heavy mechanical loads on bearings, shafts and blades.
All known rotation devices also have further certain technical shortcomings.
The efficiency is for instance often relatively low and greatly dependent on the speed of rotation.
The known devices are moreover usually voluminous, heavy and expensive.
In the use of casting techniques to manufacture a rotor the blades must have a certain minimal wall thickness, which gives rise to undesirable reductions in the effective through-flow volume and losses due to release and wake-forming. The blade wall thickness and the required blade form moreover limit the number of blades which can be accommodated. In addition, the casting technique unavoidably results in undesired surface roughness and imbalance as a consequence of unintended and unmanageable differences in density, for instance as a result of inclusions.
The tensile strength of cast metals and alloys is also limited.
Known centrifugal pumps are further affected by so-called slippage, the phenomenon of the flow having little adhesion to the suction side of the flow channel bounded by adjoining blades. Owing to the expansion angle between the blades there is a slippage area or an area with “stagnant” water in which a large-scale stationary turbulence is located, whereby the through-flow in that area is zero. The outlet pressure of the centrifugal pump is strongly pulsating as a result.
In addition, known devices are constructed such that they produce a great deal of noise during operation.
All known devices operating for instance as water pumps have a limited pressure capacity. For applications as fire service pump for instance, pumps are therefore often placed in cascade with one another in order to realize the required pressure, also expressed as lift of the water for pumping.
In the known rotation devices it is sometimes also perceived as a drawback that medium inlet and medium outlet do not have the same direction but are directed for instance at right angles to each other. In determined conditions it may be desired to at least have the option of giving the inlet and the outlet the same direction.
Known devices are further unable to operate with media having greatly varying viscosities.
In known devices the flow speeds of the through-flowing media vary very considerably during through-flow of a device. Noise production and efficiency loss result as a consequence of the accelerations which occur. It would be desirable in this respect to keep the through-flow speed of media flowing through a rotation device constant under all conditions, for instance within a range of 0.2-5 times a target value.
SUMMARY OF THE INVENTION
It is an object of the invention to provide a rotation device which either does not possess the above stated problems and limitations of the prior art or at least does so to a lesser extent.
In respect of the above the invention generally provides a rotation device.
The device can for instance be employed as pump or compressor.
The device relates to a device operating as a motor.
The invention can relate to different media for pumping. The term “two-phase medium” relates for instance to media which may be liquid and/or gaseous depending on operating temperature and operating pressure. Such media are much used in cooling systems. Examples are freons, ammonia, alkanes.
The present invention defines in general terms a possible form of the rotor channels and gives increasing preferences for the number of rotor channels.
The present invention relates to a structure of the rotation device which prevents strong periodic pressure pulsations during operation. Such a structure ensures a low-noise and uniform flow.
The invention further relates to the application of an infeed propellor in the medium inlet in the case of a rotation device serving as medium pump. The infeed propellor ensures that the medium enters the rotor channels without release at a certain pressure and speed.
A very practical embodiment relating to a light and easily manufactured rotor is described herein.
Since it is important that in the region of the third medium passage no discontinuity occurs which could cause large-scale swirling and turbulences, release and noise production, the structure according to the present invention can be advantageous.
The invention provides a structure of the rotation device wherein a relatively large number of baffles can be used without the thickness of the baffles at the position of the third medium passage substantially reducing the passage for medium at that position. As a result of the transverse dimension becoming wider in radial direction relative to the axial direction of the rotor channels, additional space is available for interwoven placing of a second group of second baffles at a distance from the third medium passage. As far as is necessary, a third group of baffles can also be placed between the interwoven first and second baffles. These baffles are in turn shorter than the second baffles and extend in the direction of the third to the fourth medium passages as far as the fourth medium passage at a distance from the end of the second baffles directed to the third medium passage. This structure enables a very good flow guiding without this essentially having an adverse effect on the effective passage of the medium.
The invention also relates to the form of the stator blades. Since all stator blades are placed in angularly equidistant manner, their mutual distance is always the same in any axial position. Rheologically however, it is essential that, as seen in the direction from the fifth medium passage to the sixth medium passage, an effective fanning out occurs in a direction as seen along a flow line in a stator channel. Perpendicularly of such a flow line an angle of progression can be defined at any position along this flow line between the blades. The structure has the advantage of a considerably improved efficiency.
The use of plate material for manufacture of the dishes and the blades according to the invention has the advantage that the rotor can be very light. Plate material can further be very light, smooth and dimensionally reliable. The choice of material will be further determined by considerations of wear-resistance (depending on the medium passing through), bending stiffness, mechanical strength and the like. For the rotor, the dishes of which have the described double-curved form, it is important that the principal form is retained, even when the material is subjected to centrifugal forces as a result of high rotation speeds. In this respect attention is drawn to the fact that the blades, which are arranged between the dishes and rigidly coupled thereto, contribute to a considerable degree towards stiffening of the rotor. For this reason also it is important to use a large number of blades. A rotor can also be manufactured with very high dimensional accuracy and negligible intrinsic imbalance.
The invention also provides options relating to choices of material under specific conditions.
Depending on the dimensions of the rotor and the rotation speed, the described plate material can have a desired value. An appropriate choice lies generally in the range stated herein. In respect of the possibility of a small imbalance, the mass moment of inertia of the rotor is preferably as small as possible, particularly in the case of media with low density such as gases. In this context it is recommended to choose the technically smallest possible thickness.
The invention provides several possible techniques with which the rotor baffles can be coupled to the dishes.
The invention provides possible choices of material for the stator blades. The technical considerations forming the basis of this choice are by and large the same as those for the rotor baffles.
The invention relates to the material choices of or at least the materials on the cylindrical inner surface of the housing and of the stator blades. By setting the thermal expansion coefficients of these materials, thermal stresses are avoided and it is ensured that the mutual connection and the correct shape of the stator channels also remain preserved in the case of extreme temperature variations.
The invention provides as a specific development of the described technical principle the possibility of the materials being the same. It will be apparent that in a further development not only the cylindrical inner surface of the housing must be of the relevant material but this can also be the case for the whole cylindrical jacket of the housing, or even the whole housing.
The invention relates to the form of the stator channels.
As already described above, the mass moment of inertia, and therewith the danger of a certain imbalance of the rotor, is preferably as small as possible.
The invention further relates to this same aspect and applies particularly to gas as medium, which after all makes no appreciable contribution to the mass moment of inertia. Although as a result of the small radial dimensions the shaft should have a considerable weight in order to have a mass moment of inertia in the same order of magnitude as that of the rotor, it should nevertheless be understood that the contribution in question can be substantial in respect of the length of the shaft which in some conditions is relatively great. In addition, the rotor will preferably take the lightest possible form so that for this reason its mass moment of inertia will also be relatively small.
The invention provides several possibilities for forming the rotor dishes.
The invention also provides a very specific method of forming a rotor.
Particularly in the case of a very hot or very cold medium, the structure according to an embodiment of the invention is significant.
The invention provides a very advantageous embodiment wherein an effective sealing is combined with a friction which practically amounts to zero.
The invention provides in increasing preference possible numbers of stator blades. In By the design of the rotation device according to the invention account must be taken of the fact that a local flow tube is then only controllable over a wide flow range if the flow tube is elongate.
The invention provides further characterizations of the rotation device in terms of the ratio of the total cross-sectional surface of all fourth medium passages and the third medium passage. The relevant choice is greatly dependent on design requirements.
The present invention further provides options relating to the ratio of the diameter of the ring of fourth medium passages and the diameter of the third medium passage. The relevant choice depends on the pressure ratio to be generated between the inlet and outlet in the case of a pump or the expansion ratio in the case of a turbine.
In the pump according to the inventio there is still strong rotation in the region of the fourth and fifth medium passages. This results locally in a relatively low static pressure, in contrast to the known centrifugal pump. As a resuly of the local relatively low pressure relatively small demands are made of the thicknesses of the relevant walls and the local seals, whereby use can for instance be made of simple seals such as labyrinth seals, which in particular conditions are considered low-grade. As is known, because of its nature a labyrinth seal is not completely closed. As a consequence of the relatively low local pressure the seal is nevertheless sufficient when labyrinth seals are used.
Said small wall thicknesses enable manufacture by deep-drawing.
The device according to the invention can be applied very widely. As pump it displays a very even pressure and efficiency characteristic and a more~or less monotonous power characteristic, whereby one pump is suitable for many very varied applications, while in usual pumps different dimensioning is required for different applications.
The said monotonous, substantially linear characteristic at any rotation speed provides the important option, by means of a very simple adjustment of the driving power, of achieving an output performance corresponding substantially unambiguously therewith. The prior art requires for this purpose a complicated and expensive adjustment based on the momentary values of a number of relevant parameters. This is the reason why such adjustments are not applied in practice.
For pumping of media with very varying viscosities only a limited number of differently dimensioned pumps is necessary as a consequence of the small dependence of the properties of the device on the viscosity of the medium.
In the use as pump, one device can realize a very large flow rate and/or a very high pressure comparable to the cascading of a plurality of pumps as according to the prior art.
In order to reverse the operation of a pump to that of a motor or vice versa, some modification of the dimensioning of stator channels and rotor channels will generally be desirable.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention will now be elucidated with reference to the annexed drawings. In the drawings:
FIG. 1
shows partly in cross section and partly in cut away side view a first embodiment of a rotation device;
FIG. 2
is a partly broken away perspective view of the device of
FIG. 1
which is schematized to illustrate the spatial structure;
FIG. 3
shows a variant of a manifold;
FIG. 4
is a partly broken away perspective view of a second embodiment of a rotation device;
FIG. 5A
shows a developed view of a part of a stator with stator blades bounding stator channels;
FIG. 5B
shows a developed view of a stator blade;
FIG. 5C
shows a view corresponding with
FIG. 5A
of two stator blades for the purpose of elucidating the geometric proportions;
FIG. 5D
shows a straight-line view of the stator channel according to
FIG. 5C
;
FIG. 5E
shows a graph of the channel width as a function of the channel distance;
FIG. 5F
shows the enclosed angle as a function of the channel distance;
FIG. 6A
shows a schematic cross-section of a third embodiment of a rotation device;
FIG. 6B
shows a view corresponding with
FIG. 6A
of a variant;
FIG. 7
shows a perspective exploded view from the underside of the internal structure with rotor and stator of a fourth embodiment of a rotation device, with omission of the housing and the lower rotor dish;
FIG. 8
shows a view from the top of the stator according to
FIG. 7
, with omission of the housing and the rotor;
FIG. 9
shows a perspective exploded view from the underside, corresponding with
FIG. 7
, of the rotor;
FIG. 10A
shows a perspective view corresponding with
FIG. 8
of the stator part of a fifth embodiment, wherein the manifold is embodied differently;
FIG. 10B
shows a view corresponding with
FIG. 10A
of a variant;
FIG. 10C
shows a view corresponding with
FIG. 10B
of a variant;
FIG. 10D
is a graphic representation of the relation between the tangential distance between two blades and the axial position;
FIG. 10E
shows the channel width as a function of the channel position;
FIG. 10F
is a graphic representation of the enclosed angle as a function of the channel position;
FIG. 11
is a partly broken away perspective view of a part of a sixth embodiment of a rotation device;
FIG. 12A
is a partly schematic perspective view of a mould for forming rotor blades;
FIG. 12B
shows a cross-section along the line B—B in
FIG. 12A
;
FIG. 12C
shows a schematic exploded view of a device for manufacturing a stator blade;
FIG. 12D
is a perspective view of the device of
FIG. 12C
;
FIG. 13A
shows a highly schematic exploded view of a device for assembling a rotor according to
FIG. 9
;
FIG. 13B
is a schematic, partly perspective view of an arrangement of a number of conducting blocks in the manufacturing phase of a stator;
FIG. 13C
is a partly broken away perspective view drawn under
FIG. 13B
of the stator manufactured as according to
FIG. 13B
;
FIG. 13D
shows an assembly of blocks conducting heat and electricity as according to
FIG. 13B
;
FIG. 14
shows a schematic graph comparing the efficiency as a function of the relative flow rate of a known rotation device and a device according to the present patent application;
FIG. 15
shows the pressure to be generated by a device according to the invention as a function of the flow rate at different rotation speeds, as compared to a known pump;
FIG. 16
is a graphic representation corresponding with
FIG. 15
of another embodiment;
FIG. 17
is a perspective view of a further embodiment of the rotation device according to the invention;
FIG. 18
is a cut-away perspective view of the device according to
FIG. 17
;
FIG. 19
shows an exploded view of the device of
FIG. 17
;
FIG. 20
is a perspective view of the motor;
FIG. 21
is a perspective view of the unit of flow channels extending between the sixth medium passage and the second medium passage;
FIG. 22
shows a top view of the unit according to
FIG. 21
; and
FIG. 23
is a cut-away perspective view of a variant.
DETAILED DESCRIPTION OF THE INVENTION
FIG. 1
shows a rotation device
1
. This comprises a housing
2
with a central, axial first medium passage
3
and three axial second medium passages
4
,
5
,
6
. The device
1
further comprises a shaft
7
which extends in said housing
2
and outside of this housing
2
and which is mounted for rotation relative to housing
2
and supports a rotor
8
accommodated in housing
2
, which rotor will be specified hereinbelow. Rotor
8
connects with a central third medium passage
9
to the first medium passage
3
. The third medium passage
9
branches into a plurality of angularly equidistant rotor channels
10
which each extend in a respectively at least more or less radial main plane from the third medium passage
9
to a respective fourth medium passage
11
. The end zone of the third medium passage
9
and the end zone of the fourth medium passage
11
each extend substantially in axial direction. As
FIG. 1
shows, each rotor channel
10
has a generally slight S-shape roughly corresponding with a half-cosine function, and has a middle part
12
which extends in a direction having at least a considerable radial component. Each rotor channel has a cross-sectional surface which enlarges from the third medium passage to the fourth medium passage.
Rotation device
1
further comprises a stator
13
accommodated in housing
2
. This stator
13
comprises a first central body
14
and a second central body
23
.
The first central body
14
has on its zone adjoining rotor
8
a cylindrical outer surface
15
which, together with a cylindrical inner surface
16
of housing
2
, bounds a generally cylindrical medium passage space
17
with a radial dimension of a maximum of 0.2 times the radius of the cylindrical outer surface
15
, in which medium passage space
17
are accommodated a plurality of angularly equidistant stator blades
19
which in pairs bound stator channels
18
, and which stator blades
19
each have on their end zone
20
directed toward rotor
8
and forming a fifth medium passage
24
a direction differing substantially, in particular at least 60°, from the axial direction
21
, and on their other end zone
22
forming a sixth medium passage
25
a direction differing little, in particular a maximum of 15°, from the axial direction
21
, which fifth medium passages
24
connect onto the fourth medium passages
11
and which sixth medium passages
25
connect to the three second medium passages
4
,
5
,
6
.
The second central body is embodied such that between the sixth medium passage
25
and the second medium passages
4
,
5
,
6
three manifold channels
26
extend tapering in the direction from the sixth medium passages
25
to the second medium passages
4
,
5
,
6
. These manifold channels are also bounded by the outer surface
29
of the second central body
23
and the cylindrical inner surface
16
of housing
2
.
FIG. 1
shows a general medium through-flow path
27
with arrows. This path
27
is defined between the first medium passage
3
and the second medium passages
4
,
5
,
6
through respectively: first medium passage
3
, third medium passages
9
, rotor channels
10
, fourth medium passages
11
, stator channels
18
, sixth medium passages
25
, manifold channels
26
, second medium passages
4
,
5
,
6
, with substantially smooth transitions between the said parts. It is noted that in
FIG. 1
the flow of the medium according to arrows
26
is shown in accordance with a pumping action of device
1
, for which purpose the shaft
7
is driven rotatingly by motor means (not shown). If medium under pressure were to be admitted with force via medium passages
4
,
5
,
6
into the second medium passages
4
,
5
,
6
, the medium flow would then be reversed and the rotor
8
would be driven rotatingly, also while driving shaft
7
rotatably, by the structure of the device
1
to be described hereinbelow.
The structure of the device is such that during operation there is a mutual force coupling between the rotation of rotor
8
, and thus the rotation of the shaft, on the one hand and the speed and pressure in the medium flowing through said medium through-flow path
27
.
The device can therefore generally operate as pump, in which case shaft
7
is driven and the medium is pumped as according to arrows
27
, or as turbine/motor, in which case the medium flow is reversed and the medium provides the driving force.
FIG. 2
shows device
1
in highly schematic cut-away perspective. It will be apparent that manifold channels
26
are formed by a second central body
23
which can be deemed an insert piece which is situated above the first central body
14
and has three recesses
30
forming the manifold channels
26
. These recesses have rounded shapes and connect on their underside to the sixth medium passages
25
for guiding the medium as according to arrows
27
to the second medium passages
4
,
5
,
6
.
FIG. 3
shows the insert piece
23
in partly broken away perspective view. In this random embodiment the insert piece
23
is formed from sheet-metal. It can however also consist of other suitable materials such as solid, optionally reinforced plastic and the like.
FIG. 4
shows a device
31
which corresponds functionally with the device
1
. Device
31
comprises a drive motor
28
.
As can be seen more clearly in
FIG. 4
than in
FIG. 1
, an infeed propellor
32
with a plurality of propellor blades
33
is arranged in the third medium passage
9
serving as medium inlet.
In anticipation of the discussion of the rotor according to
FIG. 9
, which corresponds with rotor
8
according to
FIG. 1
, it is noted here that rotor
34
in the device
31
according to
FIG. 4
has a number of additional strengthening shores
35
which are absent in the rotor
8
.
As shown in
FIG. 9
, rotor
8
comprises a plurality of separate components which are mutually integrated in the manner to be described below. Rotor
8
comprises a lower dish
36
, an upper dish
37
, twelve relatively long baffles
38
and twelve relatively short baffles
39
placed interwoven therewith, which in the manner shown form equidistant boundaries of respective rotor channels
10
. Baffles
38
,
39
each have a curved form and edges
40
,
41
bent at right angles for medium-tight coupling to dishes
36
,
37
. Baffles
38
,
39
are preferably connected to the dishes by welding and thus form an integrated rotor. In the central third medium passage
9
is placed infeed propellor
32
. This has twelve blades which connect to the long rotor baffles
38
without a Theologically appreciable transition. A downward tapering streamlining element
42
is placed in the middle of infeed propellor
32
.
FIG. 4
in particular clearly shows the operation of the device
31
operating for instance as liquid pump. By driving shaft
7
with co-displacing of rotor
34
liquid is pressed into the rotor channels through the action of propellor
32
. Partly as a result of the centrifugal acceleration which occurs, a strong pumping action is obtained which is comparable to that of centrifugal pumps. However, centrifugal pumps operate with fundamentally differently formed rotor channels. The liquid flowing out of rotor channels
10
displays a strong rotation and takes the form of an annular flow having both a tangential or rotational direction component and an axial direction component. Stator blades
19
remove the rotation component and lead the initially axially introduced flow once again in axial direction inside the manifold channels
26
, where the part-flows are collected and supplied to respective medium outlets
4
,
5
,
6
. If desired, the medium can be pumped further via one conduit in the manner shown in
FIG. 2
by means of combining the three outlets
4
,
5
,
6
into one conduit
43
. In anticipation of
FIG. 10
it is noted that other embodiments are also possible, wherein the outlet also extends in practically exactly axial direction.
FIG. 5A
shows that stator blades
19
have a bent edge
44
on their infeed side. This edge has a rheological function. It provides a smooth, streamlined transition to the stator channels
18
from the strongly rotating medium flow generated by the rapidly rotating rotor
34
.
The described rotors consist in this embodiment of stainless steel components, with reference to
FIG. 9
the dishes
36
,
37
, the baffles
38
,
39
, the propellor
32
.
FIG. 5A
shows in developed form the outer surface of the first central body and the stator blades
19
.
FIG. 5B
shows a view of a baffle
19
along the broken line B-B in FIG.
5
A.
FIG. 5C
shows a set of stator blades
19
together bounding a set of stator channels
18
.
FIG. 5D
shows a working drawing of channel
18
with the definition of the mutual angles in accordance with the successive lines
46
which, as
FIG. 5D
shows, all have mutual distances along the axis of about 5 mm, in this embodiment at least. The outlet width of each stator channel is about 15 mm, as shown in FIG.
5
C.
FIG. 5D
shows the different positions with the associated half angles between the blades
19
at the positions indicated.
FIG. 5E
shows the channel width as a function of the positions as according to
FIGS. 5C and 5D
.
FIG. 5F
shows the enclosed angle as according to the view in FIG.
5
D. It is important to note that this angle nowhere exceeds the Theologically significant value of about 15° and even remains under the value of 14°.
In FIG.
1
and
FIG. 4
can be clearly seen that the respective rotors
8
,
34
in the region of the third medium passage and the fourth medium passage are sealed relative to housing
2
by respective labyrinth seals
45
,
46
. The shaft is mounted relative to the housing by means of at least two bearings, only one of which is drawn in
FIGS. 1 and 4
. This bearing is designated with reference numeral
47
.
FIG. 6A
shows a rotation device with a slightly different structure. This structure involves a continuous unit of manifold channels since there is a space
49
which is bounded by a second central body
50
together with the wall
51
of housing
52
. There is therefore only one medium outlet
4
.
FIG. 6B
shows a rotation device
48
′, the structure of which corresponds practically wholly with the structure of device
48
according to FIG.
6
A. Other than in device
48
, device
48
′ comprises an electric motor. This comprises a number of stator windings designated with reference numeral
90
which are arranged in stationary position, and a rotor anchor
91
fixedly connected to upper dish
37
of rotor
8
.
The connecting wires of the stator windings are not drawn. They can very suitably extend upward via the unused space inside stator blades
19
and exit device
48
′ at a desired suitable position.
FIG. 7
shows the internal structure of rotor
8
with omission of the lower dish
36
. Reference is made in this respect to FIG.
9
. Particularly important in this FIG. is the structure of the second central body
53
. Comparison with
FIG. 2
in particular will make clear how this embodiment differs from the structure of device
1
. The second central body
53
is provided with three insert pieces
54
bounding recesses
55
which connect the outlet openings of stator channels
18
to medium outlets
4
,
5
,
6
. Recesses
55
are provided with flow guiding baffles which, although they have different shapes, are all designated with the reference numeral
56
for the sake of convenience. A very calm, turbulence-free flow is likewise realized due to this structure.
FIG. 8
shows the stator
57
according to
FIG. 7
from the other side.
FIG. 10A
shows a part of a fifth embodiment. Stator
61
is constructed to a large extent regularly and symmetrically and differs in this sense from the embodiments shown particularly clearly in
FIGS. 2 and 7
. In the embodiment of
FIG. 10A
manifold channels
62
are formed in analogous manner on stator channels
18
. Manifold channels
62
are bounded on one side by a surface
63
of a second central body
64
tapering in the direction of outlet
4
and on the other side by the inner surface of a housing (not drawn). Channels
62
are mutually separated by dividing walls
65
. As shown, about 2.7 stator channels are combined on average to form one manifold channel
62
.
FIG. 10B
shows a variant of FIG.
10
A. Stator
61
′ according to
FIG. 10B
differs from the embodiment of
FIG. 10A
to the extent that channels
62
′ are mutually separated by a surface
63
′ and baffles
65
′ with shapes differing from the relevant components in stator
61
. The consequence hereof is that the medium passage
93
′ according to
FIG. 10B
has a larger passage than medium passage
93
in FIG.
10
A. The difference in speed over channels
62
′ is therefore smaller than the difference in speed over channels
62
. This may be desirable in some conditions.
FIG. 10C
shows a further variant in which stator
61
″ comprises not only the relatively long baffles
19
but also shorter baffles
19
′ placed interwoven therewith. The effect hereof will be explained with reference to the following
FIGS. 10D
,
10
E and
10
F. Stator
61
″ otherwise substantially corresponds with stator
61
′. It is pointed out that the lower end zones of baffles
19
and
19
′ are folded over. A good streamline form with increased stiffness, strength and erosion-resistance is hereby ensured.
FIG. 10D
shows the tangential distance between the adjacent baffles
19
and
19
′ according to FIG.
10
C and the baffles
19
according to
FIGS. 10A and 10B
. The tangential distance is shown as a function of the axial position. Curves I and II correspond to adjacent baffles.
FIG. 10E
relates to the embodiment of FIG.
10
C. The graph shows the channel width as a function of the channel position. The influence of the interwoven placing of relatively long and relatively short baffles is apparent. This influence is recognizable from the jump in the graph. If this jump were not present, the part designated II would then connect smoothly onto the part designated I, whereby the channel width in region II would become substantially larger. This would have a considerable effect on the elongate character of the stator channels, and thereby affect the performance of the device in question.
FIG. 10F
shows the enclosed angle as a function of the channel position. A comparison with
FIG. 5F
shows that through the choice of interwoven placing of short and long baffles the enclosed angle, which in
FIG. 5F
amounts to almost 14°, is always smaller than 10° in the structure according to FIG.
10
C.
FIG. 11
shows a sixth embodiment. The rotation device
66
comprises a rotor
67
with a plurality of rotor channels
68
which are bounded by sheet-metal walls. This rotor can be formed by explosive deformation, by means of internal medium pressure, by means of a rubber press or other suitable known techniques. Manifold channels
69
are bounded by baffles
70
extending roughly helically in the drawn area.
FIG. 12
shows the manner in which the spatially very complicated form of the stator blades
19
can be manufactured from respective strips of stainless steel.
FIG. 12A
shows very schematically a mould
71
for forming a stator blade
19
from a flat strip of steel of determined length. The mould comprises two mould parts
72
,
73
which are rotatable with force relative to each other and which in a closed rotation position have two mutually facing separating surfaces, the shapes of which are substantially identical, which shapes correspond with the shape of a blade
19
. The separating surface in question is situated at the position designated
74
where such a blade
19
is drawn in accordance with the reality during forming of a blade, wherein the adjoining parts of mould parts
72
,
73
are drawn in broken away view. Shown at the bottom is the relevant separating surface
75
which continues in the shape of the blade
19
. Arrows
76
show the relative rotatability of mould parts
72
,
73
. Guide blocks
76
,
77
serve as guide for mould parts
72
,
73
during the rotation. The mentioned means for rotatingly driving mould parts
72
,
73
are not drawn.
In the open position of the mould, which is not drawn in
FIG. 12
a,
a straight stainless steel strip is inserted. This strip is wholly flat and straight. The mould parts are then mutually rotated such that the moulding surfaces approach each other. Engaging of the strip hereby takes place with simultaneous deformation thereof. Reference is made in this respect to
FIG. 12
b,
where the mutually co-acting mould parts
72
,
73
are shown. As will be apparent, mould part
73
has on its underside adjoining support cylinder
77
a recess
78
corresponding with the bent lower edge
79
of strip
19
, while a similar recess
80
remains present on the top side between the upper surface of mould part
72
and mould part
73
when the mould cavity is closed. The final closure of the mould cavity is determined exclusively by the thickness of the metal of blade
19
. Recess
80
corresponds with the upper bent edge
81
.
FIGS. 12C and 12D
show an alternative device or mould
871
for forming a stator blade
819
from a flat strip of steel
801
with the curved form of determined length shown in FIG.
12
D. Mould
871
comprises two mould parts
872
,
873
which are rotatable with force relative to each other and which in a closed rotation position have two mutually facing separating surfaces, the shapes of which are substantially identical, which shapes correspond with the shape of a blade
819
. The mutual rotation of said mould parts
872
,
873
can take place by rotating mould part
873
by means of handle
802
, wherein mould part
872
remains stationary because it is formed integrally with a frame
803
which is fixed to a work surface. A second handle
804
is fixed to a substantially cylindrical element
805
provided with a more or less triangular opening
806
which serves for placing of strip
801
and removal of a formed blade
819
. The respective components
805
and
814
are mutually coupled for rotation by means of a key
808
fitting into a key way
807
.
Said separating surfaces
810
,
811
serve to impart to strip
801
the double curved principal shape, although without the bent edges
812
,
813
which serve for connection of a blade deformation of a stator to respective cylindrical bodies. After this form has been obtained by rotation by middle handle
802
, the bent edges
812
,
813
can be formed by a further rotation by handle
804
. During this further rotation the intended bending of said edges takes place due to rotation of central part
814
which, as stated, is coupled for rotation to element
805
and is provided with a bending edge
815
. A second bending edge
816
is arranged on the inside of element
805
.
With a very simple operation using device
871
a blade
819
can thus be made from the pre-formed metal strip
801
.
It is noted that strip
801
is manufactured by laser cutting. A very accurate and chip- and burr-free sheet-metal element can hereby be obtained which is free of internal stresses. The narrowed end zone
820
can be folded over as according to arrow
823
to the position designated with
820
′. Blade
819
is thereby ready to serve as component of a stator. Such a stator is shown for instance in FIG.
13
C.
FIG. 13A
shows a possible and very practical method of manufacturing rotor
8
. The starting point is lower dish
36
, upper dish
37
and the rotor baffles
38
,
39
for placing therebetween and connecting fixedly thereto (see also FIG.
9
).
In the exploded view of
FIG. 13A
is also shown that chains of similarly formed blocks
82
conducting electricity and heat can be incorporated in the three-dimensionally formed baffles
38
,
39
. These blocks are joined by wires
83
to form respective chains and can serve to conduct the current which can be conducted by an electrical power supply
86
via an upper electrode
84
and a lower electrode
85
through respectively dish
37
, blocks
82
, baffles
38
,
39
, lower dish
36
and lower electrode
85
. By means of pressing means (not drawn) the dish-shaped electrodes
84
,
85
, the respective shapes of which correspond with respectively upper dish
37
and lower dish
36
, are pressed with force to one another with corresponding pressing of the components mentioned and drawn in
FIG. 3
at a mutual distance. Profiled zones
86
serving as pressing points are arranged in upper electrode
84
. Corresponding zones
87
are arranged in lower electrode
84
. During transmitting of a sufficiently large current, a large current will be conducted through the relevant current path via the pressing zones
86
,
87
, which are in register with baffles
38
,
39
. An effective spot welding of baffles
38
,
39
to dishes
36
,
37
hereby takes place. The for instance copper blocks
82
are essential for a good electrical conduction without adverse thermal effects on baffles
38
,
39
. After a spot-welding operation is thus completed, the relevant chains of blocks can be removed by pulling on wires
83
. After this operation the rotor is in principle finished. As
FIG. 1
shows, a fixing disc
90
can also be welded to upper dish
37
and with cover
91
this forms the fixing of the rotor to shaft
7
. After the spot-welding operation as described above with reference to
FIG. 13
, the rotor according to
FIG. 4
is provided with shores
35
, whereafter shaft
37
is fixed.
FIG. 13B
shows in greatly simplified manner and with the omission of a number of components an arrangement
830
for manufacturing a stator
831
as shown in FIG.
13
C. For a good understanding of the arrangement of
FIG. 13B
, reference is first made to FIG.
13
C. Stator
831
comprises a cylindrical inner wall
832
and a cylindrical outer wall
833
. In this embodiment these walls are made of stainless steel. Outer wall
833
is relatively thick, while inner wall
832
is relatively thin. The stator blades
819
(see
FIG. 12
) of relatively great length and the blades
819
′ of shorter length placed interwoven therewith are placed in the desired position and fixed with the bent edges
812
and
813
to respectively inner wall
832
and outer wall
833
by welding. It will hereby be apparent that the shapes of these bent edges
812
and
813
must fit precisely onto the relevant cylindrical surfaces. The devices shown in
FIG. 12
are specially designed herefor.
FIG. 13B
shows, with the omission of cylinders
832
,
833
, an arrangement of equidistantly placed chains of copper blocks, which for the sake of convenience are all designated
834
and which take the form shown in
FIG. 13D
corresponding with the form of blades
819
respectively
819
′. The blocks are mechanically connected to each other and electrically separated from each other by means of a lace
835
. A rubber cushion
836
has a form such that the total structure
837
, consisting of blocks
834
, lace
835
and cushion
836
, fits precisely between blades
819
,
819
′ of a stator
831
. Blocks
834
have a general U-shape. The edges
812
,
813
can hereby be mutually connected for electrical conduction and thermal conduction without the electrical conduction taking place via the middle plate of a blade
819
. Comparison of
FIGS. 13B and 13C
shows the relative placing of blocks
834
and blades
819
,
819
′.
FIG. 13B
is drawn in simplified manner in the sense that only the foremost group of chains
837
is shown, while the cylindrical jackets
832
,
833
have also been omitted for the sake of clarity. An outer electrode
838
is placed outside outer jacket
833
, while an inner electrode
839
is placed inside inner jacket
832
. These electrodes are adapted to simultaneously transmit currents through spot-welding zones, which for the sake of convenience are all designated
840
. For this purpose electrodes
838
,
839
are connected to a power source
841
. After ordering of blades
819
,
819
′ with interposing of chains
837
over the whole periphery with placing of both inner cylinder
832
and outer cylinder
833
, the inner electrodes
839
and outer electrodes
838
are placed, whereafter the current flow is effected, which has the consequence that the bent edges
812
,
813
are spot-welded at the current flow positions to inner cylinder
832
and outer cylinder
833
. The respective chains
837
are subsequently pulled out from the top of the structure on laces
835
, whereafter stator
831
is finished.
FIG. 14
shows a graphic representation of the efficiency “EFF” expressed in a percentage as a function of the relative flow rate Q of respectively a device according to the prior art (graph I) and as measured on a device of the above described type according to
FIG. 1
(graph II) and, finally, as according to
FIGS. 7
,
8
,
9
,
10
. It will be apparent that the efficiency curve of the structure according to the invention is substantially higher than that of the prior art and has a considerably flatter progress. Particularly at lower rotation speeds the improvement is spectacular. This improvement explains why one device can be employed for many very varying applications. In the prior art different devices are usually required for different applications.
FIG. 15
likewise shows the performance of a device according to the invention operating as a pump. The graphs shown in
FIG. 15
relate to the pump pressure as a function of the flow rate of a device according to the invention compared to an eight-stage standard centrifugal pump with a dimensioning comparable to the device according to the invention. The graph I indicated with circular measurement points relates to the measurement on a known pump NOVA PS 1874. The other graphs relate to measurements on a pump according to the invention at the following rotation speeds of respectively: 1500, 3000, 4000, 5000, 5500, 6000 revolutions per minute.
FIG. 16
shows measurement results in a comparison between two types of pump according to the invention and two types of pump according to the prior art. Graphs I and II relate to an eight-stage centrifugal pump of usual type at 3000 revolutions per minute. Graph I relates to an inlet of 58 mm while graph II relates to an inlet of 80 mm.
The drawn graphs with the indications of respectively 1500, 3000, 4000, 5000, 6000 revolutions per minute relate to a one-stage device according to the invention with a housing of 170 mm diameter, a rotor diameter of 152 mm and an inlet diameter of 38 mm. The graphs drawn in dashed lines likewise relate to a one-stage device according to the invention with a housing having a diameter of 170 mm, a rotor diameter of 155 mm and an inlet diameter of 60 mm.
The respective lines III and IV designate the respective cavitation boundaries of the first type of pump according to the invention as described and the second type of pump according to the invention as described.
It will be seen from the foregoing that the described new structure of a rotation device produces substantially better results than similar known devices. With particular reference to
FIGS. 15 and 16
, attention is once again drawn to the fact that the comparisons relate to a one-stage device according to the invention and an eight-stage device according to the prior art, i.e. eight known rotation devices connected in cascade.
FIG. 17
shows a unit
901
comprising a rotation device
902
and a motor
903
. The unit is designed to operate as a pump. On the underside is situated a first medium passage
904
serving as inlet and on the side is situated the second medium passage
905
serving as outlet.
FIG. 18
shows schematically the structure of unit
901
. At variance with the embodiment of for instance
FIG. 4
, in which the unit consists of a motor and a pump which in principle is connected inseparably thereto, unit
901
is constructed from two separate components. For this purpose motor shaft
906
has an end tapering towards the outside with a conical screw thread
907
on the end, while rotor shaft
908
has a corresponding complementary form. In this manner motor
903
and pump
902
are mutually coupled in releasable and power-transmitting manner, while a very easy release is nevertheless ensured. Particular reference will further be made below to the structure of a component of pump
902
with reference to
FIGS. 21 and 22
.
FIG. 19
shows in exploded view the manner in which the constituent main components are mutually connected and interrelated. It is important to note that upper component
909
of pump
902
, in which the stator is situated, is constructed differently from the relevant components in the above described and shown embodiments. Rotor
910
and inlet components
911
correspond with the above described embodiments.
FIG. 20
shows motor
903
with a coupling piece
912
on the underside for coupling to a corresponding coupling sleeve
913
on outlet component
909
.
FIGS. 21 and 22
show a component
914
of outlet component
909
. Component
914
comprises a sheet-metal funnel
915
with a central opening
916
. Arranged against the wall in funnel
915
are flow guiding baffles which are ordered in the manner shown in
FIGS. 21
,
22
and which, although they possess different forms, are all designated for convenience with the reference numeral
917
. Baffles
917
are members of one parametric family.
An inner funnel
918
, likewise of sheet-metal, is situated inside funnel
915
such that flow guiding baffles
917
are bounded by the respective funnels
915
and
918
and thus form flow guiding channels
919
. These latter all debouch into outlet
905
and ensure a controlled flow pattern with very low friction losses. Flow guiding baffles
917
can be made in a manner which is related to the manner in which the stator blades and/or the rotor baffles can be made. Reference is made to
FIGS. 12 and 13
in respect of possible manufacturing methods.
The structure of unit
901
requires no further discussion. Both structure and operation will be apparent from the discussion of the foregoing embodiments.
Flow guiding channels
919
correspond functionally with manifold channels
62
and
62
′ of respectively
FIGS. 10A and 10B
. At variance with
FIG. 10
, the structure of unit
903
is such that outlet
905
extends on the side of unit
903
. This simplifies the structure of the critical coupling between motor
903
and pump
902
. It is however noted that in this respect the embodiment according to for instance
FIGS. 1
,
2
and
4
could also be applied.
FIG. 23
shows a pump
1001
with electric motor
1002
which drives rotor
1003
. Inlet
1004
of stator
1005
connects onto a lateral inlet
1006
via a rotation-symmetrical transition zone
1007
. Via a second rotation-symmetrical transition zone
1008
rotor
1003
connects onto a lateral outlet
1009
, which in this embodiment is located coaxially relative to inlet
1006
. Zones
1007
and
1008
lie in enveloping coaxial relation.
Attention is drawn to the fact that determined components such as blades and baffles are not drawn in FIG.
23
.
Arrows
1010
show the medium flow.
Claims
- 1. A rotation device, comprising:(a) a housing with a central, substantially axial first medium passage and at least one substantially axial second medium passage; (b) a rotor shaft which extends in this housing and outside of this housing and which is mounted for rotation relative to this housing and supports a rotor accommodated in this housing, which rotor connects with a central third medium passage to said first medium passage, which third medium passage branches into a plurality of angularly equidistant rotor channels which each extend in a respectively generally radial main plane from the third medium passage to a respective fourth medium passage, wherein the end zone of the third medium passage and the end zone of the fourth medium passage each extend substantially axially and each rotor channel has a curved form with a middle part which extends in a direction having at least a considerable radial component, and each rotor channel has a flow tube cross-sectional surface which increases in the direction from the third medium passage to the fourth medium passage from a relative value of 1 to a relative value of at least 4; (c) a stator accommodated in this housing and comprising: (c.1) a first central body which has a substantially rotation-symmetrical outer surface with a smooth form which together with an inner surface of the housing bounds a generally substantially rotation-symmetrical medium passage space with a radial dimension of a maximum of 0.4 times the radius of said outer surface, in which medium passage space are accommodated a plurality of angularly equidistant stator blades which in pairs bound stator channels and which stator blades each have on their end zone directed toward the rotor and forming a fifth medium passage a direction differing substantially, in particular at least 60°, from the axial direction, and on their other end zone forming a sixth medium passage a direction differing little, in particular a maximum of 15°, from the axial direction; which fifth medium passages connect onto the fourth medium passages for medium flow in substantially axial direction and are placed at substantially the same radial positions, and which sixth medium passages connect onto the at least one second medium passage; (c.2) a second central body, wherein between the sixth medium passage and the at least one second medium passage a plurality of manifold channels extend tapering in the direction from the sixth medium passages to the at least one second medium passage and bounded by the outer surface of the second central body and the cylindrical inner surface of the housing; wherein a general medium through-flow path is defined between the first medium passage and the at least one second medium passage through respectively the first medium passage, the third medium passages, the rotor channels, the fourth medium passages, the stator channels, the sixth medium passages, the manifold channels, the second medium passages, and the vice versa, with substantially smooth and continuous transitions between parts during operation; and wherein the structure is such that during operation there is a mutual force coupling between the rotation of the rotor, and thus the rotation of the shaft and the pressure in the medium flowing through said medium through-flow path.
- 2. A device as claimed in claim 1, wherein the shaft is coupled for driving to a motor and the first medium passage is the medium inlet and the second medium passage is the medium outlet.
- 3. A device as claimed in claim 2, wherein an infeed propellor with a plurality of propellor blades is arranged in the third medium passage serving as medium inlet.
- 4. A device as claimed in claim 3, wherein each propellor blade connects to a baffle.
- 5. A device as claimed in claim 1, wherein the second medium passage is the medium inlet and is coupled to a source of medium under pressure and the first medium passage is the medium outlet.
- 6. A device as claimed in claim 1, wherein the medium is a liquid, suspension, or emulsion.
- 7. A device as claimed in claim 1, wherein the medium is a gas.
- 8. A device as claimed in claim 1, wherein the medium is a two-phase medium.
- 9. A device as claimed in claim 1, wherein the axial cross-section of each rotor channel has a form which corresponds generally to a half-cosine function.
- 10. A device as claimed in claim 1, wherein the number of rotor channels amounts to at least ten.
- 11. A device as claimed in claim 10, wherein the number of rotor channels amounts to at least twenty.
- 12. A device as claimed in claim 11, wherein the number of rotor channels amounts to at least forty.
- 13. A device as claimed in claim 1, wherein the number of rotor channels differs from the number of stator channels such that position coincidence of the fourth medium passages and the fifth medium passages is absent during rotation and therewith associated periodic pressure fluctuations in the medium flowing through the rotation device are thus prevented.
- 14. A device as claimed in claim 1, wherein the rotor comprises two dishes which, together with baffles also serving as spacers, bound the rotor channels.
- 15. A device as claimed in claim 14, wherein a first group of first baffles extends from the third medium passage to the fourth medium passage and at least one second group of second baffles is placed interwoven therewith, which second baffles extend from a position at a distance from the third medium passage to the fourth medium passage.
- 16. A device as claimed in claim 15, wherein said angle reaches a maximum value of 10°.
- 17. A device as claimed in claim 14, wherein the angle between a set of stator blades together forming a stator channel reaches a maximum value of 20° in a region between the fifth medium passage and the sixth medium passage.
- 18. A device as claimed in claim 17, wherein said angle reaches a maximum value of 10°.
- 19. A device as claimed in claim 14, wherein the dishes and the baffles consist of plate material made of at least one of plastic, plastic reinforced with fibres, aluminum, aluminum alloy, stainless steel and spring steel.
- 20. A device as claimed in claim 19, wherein the ratio of the rotor diameter and the thickness of the plate material has a value of 50-1600.
- 21. A device as claimed in claim 14, wherein the baffles are coupled to the dishes by at least one of welding, spot welding, glueing, soldering, magnetic forces, by means of screw connections, and lip/hole connections.
- 22. A device as claimed in claim 14, wherein the dishes are formed from metal by at least one of deep drawing, rolling, forcing, hydroforming, explosive deformation, and by means of a rubber press.
- 23. A device as claimed in claim 14, wherein the dishes are formed from plastic by at least one of injection moulding, thermo-forming, and thermovacuum-forming.
- 24. A device as claimed in claim 14, wherein each propellor blade connects to a baffle.
- 25. A device as claimed in claim 1, wherein the baffles extend from the third medium passage to a zone at a distance from the end zones of the dishes co-bounding the fourth medium passages.
- 26. A device as claimed in claim 1, wherein all surfaces coming into contact with medium are resistant to chemical and/or mechanical action by the medium.
- 27. A device as claimed in claim 1, wherein all surfaces coming into contact with medium are manufactured from materials and mutually connected for electrical conduction such that spark-forming is effectively prevented.
- 28. A device as claimed in claim 1, wherein all surfaces coming into contact with medium are made smooth in advance by at least one of grinding, polishing, honing and application of a coating of a carbide, a nitride, a titanium nitride, a boron nitride, glass, a silicate, high-grade plastics, or a polyimide.
- 29. A device as claimed in claim 1, wherein the stator blades consist of plate material made of at least one of plastic, plastic reinforced with fibres, aluminum, aluminum alloy, stainless steel and spring steel.
- 30. A device as claimed in claim 1, wherein the thermal expansion coefficients of the materials of the inner surface of the housing and of the stator blades are substantially the same.
- 31. A device as claimed in claims 30, wherein at least the inner surface of the housing consists of the same material as the stator blades.
- 32. A device as claimed in claim 1, wherein the stator channels are formed such that the distances between their mutually opposite walls are substantially the same at each axial position in a peripheral plane extending transversely of the axial direction.
- 33. A device as claimed in claim 1, wherein the shaft is solid and thus makes a substantial contribution to the mass moment of inertia of the rotatable unit comprising this shaft and said rotor.
- 34. A device as claimed in claim 1, wherein the rotor is manufactured from sheet-metal which is laid in at least two layers one over the other in a mould with a mould cavity having a form corresponding with the desired form of the rotor, between which two layers medium under pressure is admitted to cause expanding of the sheet material during plastic deformation against the wall of said mould cavity for forming of the rotor.
- 35. A device as claimed in claim 1, wherein the shaft is mounted for rotation relative to the housing in bearings which are located a great distance from the medium through-flow path such that possible large change in temperature of the through-flowing medium has no more than a negligible effect on the temperature of these bearings.
- 36. A device as claimed in claim 1, wherein the rotor is sealed relative to the housing by at least two labyrinth seals, whereof the one is situated in the region of the third medium passage and the other is situated in the region of the fourth medium passage.
- 37. A device as claimed in claim 1, wherein the number of stator blades amounts to at least 10.
- 38. A device as claimed in claim 37, wherein the number of stator blades amounts to at least 20.
- 39. A device as claimed in claim 1, wherein the ratio of the total cross-sectional surface of all fourth medium passages and the third medium passage amounts to at least 1.
- 40. A device as claimed in claim 39, wherein the ratio of the total cross-sectional surface of all fourth medium passages and the third medium passage amounts to at least 3.
- 41. A device as claimed in claim 40, wherein the ratio of the total cross-sectional surface of all fourth medium passages and the third medium passage amounts to at least 10.
- 42. A device as claimed in claim 1, wherein the ratio of the diameter of the ring of the fourth medium passages and the diameter of the third medium passage amounts to at least 1.5.
- 43. A device as claimed in claim 42, wherein the ratio of the diameter of the ring of the fourth medium passages and the diameter of the third medium passage amounts to at least 10.
- 44. A device as claimed in claim 43, wherein the ratio of the diameter of the ring of the fourth medium passages and the diameter of the third medium passage amounts to at least 20.
Priority Claims (1)
Number |
Date |
Country |
Kind |
1009759 |
Jul 1998 |
NL |
|
PCT Information
Filing Document |
Filing Date |
Country |
Kind |
PCT/EP99/05493 |
|
WO |
00 |
Publishing Document |
Publishing Date |
Country |
Kind |
WO00/06907 |
2/10/2000 |
WO |
A |
US Referenced Citations (4)